Silicon carbide power mosfet and method for manufacturing same

By forming a silicon-rich layer on a silicon carbide substrate and growing a gate oxide layer, the rough interface issue is addressed, leading to improved carrier mobility and device performance.

WO2025064962A1PCT designated stage expired Publication Date: 2025-03-27MICROCHIP TECHNOLOGY INC
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Patent Information

Application Number
PCT/US2024/047889
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-09-20
Filing Date
2024-09-22
Publication Date
2025-03-27

AI Technical Summary

Technical Problem

The rough interface between silicon carbide substrates and gate oxide layers in semiconductor devices degrades carrier mobility, limiting device performance.

Method used

A silicon-rich layer with a specific carbon to silicon ratio and silicon concentration is implanted on a silicon carbide substrate, followed by the growth of a gate oxide layer, which improves the interface smoothness and carrier mobility.

Benefits of technology

The smoother interface between the silicon-rich layer and the gate oxide layer enhances carrier mobility, thereby improving the performance of semiconductor devices.

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Abstract

A method of manufacturing a semiconductor device is provided. The method may include implanting a silicon-rich layer on a surface of a silicon carbide substrate, and growing a gate oxide layer on the silicon-rich layer on the surface of the silicon carbide substrate.
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Description

SILICON CARBIDE POWER MOSFET AND METHOD FOR MANUFACTURING SAMECROSS-REFERENCE TO RELATED APPLICATION

[0001] The present application claims priority to U.S. Non-Provisional Patent Application No. 18 / 891,853, filed on September 20, 2024, and U.S. Provisional Patent Application No. 63 / 539,754, filed on September 21, 2023, the contents of which are hereby incorporated by reference in their entirety.TECHNICAL FIELD

[0002] The present disclosure relates generally to methods for manufacturing semiconductor devices, and more specifically to manufacturing semiconductor devices with silicon carbide substrates and a gate oxide interface with the silicon carbide substrate.SUMMARY

[0003] According to an aspect of one or more examples, there is provided a method of manufacturing a semiconductor device. The method may include implanting a silicon-rich layer on a surface of a silicon carbide substrate, and growing a gate oxide layer on the silicon-rich layer. The silicon-rich layer may have a carbon to silicon ratio equal to or less than approximately 0.98. The silicon-rich layer may have a silicon concentration approximately between le19and 5e22atoms per cubic centimeter. Forming the gate oxide layer may include oxidizing silicon from the silicon- rich layer to form a gate oxide layer of silicon dioxide. The gate oxide layer of silicon dioxide may be formed or grown by a thermal oxidation process of the silicon-rich layer. The gate oxide layer of silicon dioxide may be formed or grown by a chemical vapor deposition (CVD) process of the silicon-rich layer. The silicon-rich layer may have a thickness that is approximately half athickness of the gate oxide layer. The silicon-rich layer may have a thickness that is approximately equal to a thickness of the gate oxide layer.

[0004] According to another aspect of one or more examples, there is provided a semiconductor device that may include a silicon carbide substrate, a silicon-rich layer formed on a surface of the silicon carbide substrate, and a gate oxide layer formed on the silicon-rich layer. The silicon-rich layer may have a carbon to silicon ratio equal to or less than approximately 0.98. The silicon-rich layer may have a silicon concentration approximately between le19and 5e22atoms per cubic centimeter. The silicon-rich layer may have a thickness that is approximately half the thickness of the gate oxide layer. The silicon-rich layer may have a thickness that is approximately equal to a thickness of the gate oxide layer.BRIEF DESCRIPTION OF DRAWINGS

[0005] FIG. 1 shows a method of manufacturing a semiconductor device according to one or more examples.DETAILED DESCRIPTION OF VARIOUS EXAMPLES

[0006] Reference will now be made in detail to the following various examples, which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout. The following examples may be embodied in various forms without being limited to the examples set forth herein.

[0007] FIG. 1 shows a method 100 of manufacturing a semiconductor device according to one or more examples. Silicon carbide (SiC) is often used as a substrate to create many semiconductor devices, and may result in reduced switching losses, higher power density, improved heat dissipation, and increase bandwidth as compared with other materials. Some semiconductor devices, such as metal -oxide-semiconductor field-effect transistors (MOSFETs)include a gate oxide layer that is a dielectric layer that separates the silicon carbide substrate from a gate electrode, which may be made of metal or other conductive material.

[0008] When forming the gate oxide layer on a silicon carbide substrate, the interface between the silicon carbide substrate and the gate oxide layer (for example, a gate oxide layer made of silicon dioxide) may be very rough. The rough interface between the gate oxide layer and the silicon carbide substrate may degrade carrier mobility in the silicon carbide substrate, which may limit device performance. Referring to FIG. 1, a silicon carbide substrate 110 is used as a base substrate. A silicon-rich layer 120 may be grown on a surface of the silicon carbide substrate 110 or implanted within an upper portion of the silicon carbide substrate 110. According to one or more examples, the silicon-rich layer 120 may be approximately 100A to 500A thick, though other thicknesses may be used depending on the application. For example, the amount of silicon used to create the silicon-rich layer 120 may depend on the thickness of the gate oxide layer 130 to be formed on the silicon-rich layer 120. According to one or more example embodiments, the thickness of the silicon-rich layer 120 may be approximately half the thickness of the gate oxide layer 130. According to one or more examples, the thickness of the silicon-rich layer 120 may be approximately equal to the thickness of the gate oxide layer 130. The silicon-rich layer 120 may be a high dose layer. For example, the silicon-rich layer 120 may have a silicon concentration approximately between le19and 5e22atoms per cubic centimeter. According to one or more example embodiments, the silicon-rich layer 120 may have a very low carbon to silicon ratio. For example, the carbon-silicon ratio may be equal to or less than approximately 0.98.

[0009] As shown in FIG. 1, a gate oxide layer 130 may be formed on the silicon-rich layer 120. For example, the gate oxide layer 130 may be a layer of silicon dioxide (SiCh), which may be formed or grown by a thermal oxidation process of the silicon-rich layer 120. In variousexamples, the gate oxide layer 130 may be a layer of S1O2, which may be formed or grown by a chemical vapor deposition (CVD) process of the silicon-rich layer 120. By forming the gate oxide layer 130 on a silicon-rich layer 120 having a higher concentration of silicon than, for example, the silicon carbide substrate 110, the interface between the gate oxide layer 130 and the silicon- rich layer 120 may be smoother, which may improve carrier mobility.

[0010] Various examples have been disclosed herein, in connection with the above description and the drawings. It will be understood that it would be unduly repetitious to literally describe and illustrate every combination and subcombination of these examples. Accordingly, all examples can be combined in any way and / or combination, and the present specification, including the drawings, shall be construed to constitute a complete written description of all combinations and subcombinations of the examples described herein, and of the manner and process of making and using them, and shall support claims to any such combination or subcombination.

[0011] It will be appreciated by persons skiliedin the art that the examples described herein are not limited to what has been particularly shown and described herein above. In addition, unless mention was made above to the contrary, it should be noted that all of the accompanying drawings are not to scale. A variety of modifications and variations are possible in light of the above teachings.

Claims

What is claimed is:

1. A method of manufacturing a semiconductor device, the method comprising: implanting a silicon-rich layer on a surface of a silicon carbide substrate; and growing a gate oxide layer on the silicon-rich layer on the surface of the silicon carbide substrate.

2. The method of claim 1, wherein the silicon-rich layer has a carbon to silicon ratio equal to or less than approximately 0.98.

3. The method of claim 1, wherein the silicon-rich layer has a silicon concentration approximately between le19and 5e22atoms per cubic centimeter.

4. The method of claim 1, wherein the forming of the gate oxide layer includes oxidizing silicon from the silicon-rich layer to form a gate oxide layer of silicon dioxide.

5. The method of claim 1, wherein the silicon-rich layer has a thickness that is approximately half a thickness of the gate oxide layer.

6. The method of claim 4, wherein the gate oxide layer of silicone dioxide is formed or grown by a thermal oxidation process of the silicon-rich layer.

7. The method of claim 4, wherein the gate oxide layer of silicone dioxide is formed or grown by a chemical vapor deposition (CVD) process of the silicon-rich layer.

8. The method of claim 1, wherein the silicon-rich layer has a thickness that is approximately equal to a thickness of the gate oxide layer.

9. A semiconductor device comprising: a silicon carbide substrate; a silicon-rich layer formed on a surface of the silicon carbide substrate; and a gate oxide layer formed on the silicon-rich layer.

10. The semiconductor device of claim 9, wherein the silicon-rich layer has carbon to silicon ratio equal to or less than approximately 0.98.

11. The semiconductor device of claim 9, wherein the silicon-rich layer has a silicon concentration approximately between le19and 5e22atoms per cubic centimeter.

12. The semiconductor device of claim 9, wherein the silicon-rich layer has a thickness that is approximately half a thickness of the gate oxide layer.

13. The semiconductor device of claim 9, wherein the silicon-rich layer has a thickness that is approximately equal to a thickness of the gate oxide layer.

Citation Information

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