Microbiocidal tetrahydroisoquinoline compounds

Abstract

A compound of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts or N-oxides of those compounds, which can be used as fungicides.

Description

[0001] 109939 FF (83198) 1 MICROBIOCIDAL TETRAHYDROISOQUINOLINE COMPOUNDS The present invention relates to microbiocidal tetrahydroisoquinoline compounds, e.g., as active ingredients, which have microbiocidal activity, in particular fungicidal activity. The invention also relates to preparation of these tetrahydroisoquinoline compounds, to intermediates useful in the preparation of these tetrahydroisoquinoline compounds, to the preparation of these intermediates, to agrochemical compositions which comprise at least one of the tetrahydroisoquinoline compounds, to preparation of these compositions and to the use of the tetrahydroisoquinoline compounds or compositions in agriculture or horticulture for controlling or preventing infestation of plants, harvested food crops, seeds or non-living materials by phytopathogenic microorganisms, in particular fungi. According to a first aspect of the present invention, there is provided a compound of formula (I) wherein R1is selected from hydrogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, or C3-C6-cycloalkyl; R2is selected from cyano, hydroxy, amino, C1-C4-alkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6- cycloalkyloxy, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkylamino, di(C1- C4-alkyl)amino, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, or C1-C4-haloalkylsulfanyl; R3is selected from hydrogen, halogen, or C1-C4-alkyl; R4is selected from hydrogen, halogen, cyano, or C1-C4-alkyl; R5and R6are independently selected from hydrogen, or C1-C4-alkyl; R7is selected from hydrogen, C1-C4-alkyl, C1-C4-alkylcarbonyl, N-C1-C4-alkoxy-C-C1-C4-alkyl-carbonimidoyl, N-hydroxy-C-C1-C4-alkyl-carbonimidoyl, C1-C4-alkoxycarbonyl, N-methoxy-N-methyl-carbonyl, C1-C4- alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl, phenyl, a 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms independently selected from N, O or S, with the proviso that no more than one is O or S; and wherein any of said phenyl and 5- or 6- membered heteroaryl are unsubstituted or substituted with 1, 2 or 3 substituents independently selected from halogen, cyano, carboxy, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-alkoxy; and wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-alkoxy; B1is selected from CR10, or N; 109939 FF (83198) 2 B2is selected from CR11, or N; R8and R9are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1-C4- haloalkyl, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, or C3-C6-cycloalkyl; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1-C4- haloalkyl, C1-C4-haloalkoxy, C2-C4-alkenyloxy, C2-C4-alkynyloxy, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4- alkylsulfonyl, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, N-C1-C4-alkylamino, N,N-di(C1-C4- alkyl)amino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, N-C1-C4-alkoxy-C1-C4-alkyl-carbonimidoyl, N-hydroxy- C1-C4-alkyl-carbonimidoyl, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl, C1-C4- alkylcarbonylamino, C1-C4-alkylsulfonylamino, trifluoromethylsulfonyloxy, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C2- alkyl-C1-C4-alkoxy; A is selected from A1, A2, A3, A4, A5, A6, A7, or A8 wherein the (*) the nitrogen with the bond to the Z1group; R12a, R13aR14aare hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, or C2-C4-alkynyl; and Z1is selected from C1-C4-alkyl, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylsulfanyl, C1-C4- alkylsulfinyl, C1-C4-alkylsulfonyl, or C2-C4-alkynyl; or an agrochemically acceptable salt, or N-oxide thereof. Surprisingly, it has been found that the compounds of formula (I) have, for practical purposes, a very advantageous level of biological activity for protecting plants against diseases that are caused by fungi. According to a second aspect of the invention, there is provided an agrochemical composition comprising a fungicidally effective amount of a compound of formula (I) according to the invention. Such an agricultural 109939 FF (83198) 3 composition may further comprise at least one additional active ingredient and / or an agrochemically-acceptable diluent or carrier. According to a third aspect of the invention, there is provided a method of controlling or preventing infestation of useful plants by phytopathogenic microorganisms, wherein a fungicidally effective amount of a compound of formula (I) according to the invention, or a composition comprising the compound of formula (I), is applied to the plants, to parts thereof or the locus thereof. According to a fourth aspect of the invention, there is provided the use of a compound of formula (I) according to the invention as a fungicide. According to this particular aspect of the invention, the use may exclude methods for treatment of the human or animal body by surgery or therapy and diagnostic methods practiced on the human or animal body. The compounds of formula (I) or the intermediate compounds of formula (III) according to the invention, which have at least one basic center, can form, for example, acid addition salts, for example with strong inorganic acids such as mineral acids, for example perchloric acid, sulfuric acid, nitric acid, a phosphorus acid or a hydrohalic acid, with strong organic carboxylic acids, such as C1-C4-alkanecarboxylic acids which are unsubstituted or substituted, for example by halogen, for example acetic acid, such as saturated or unsaturated dicarboxylic acids, for example oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid or phthalic acid, such as hydroxycarboxylic acids, for example ascorbic acid, lactic acid, malic acid, tartaric acid or citric acid, or such as benzoic acid, or with organic sulfonic acids, such as C1-C4-alkane- or arylsulfonic acids which are unsubstituted or substituted, for example by halogen, for example methane- or p-toluenesulfonic acid. The compounds of formula (I) or the intermediate compounds of formula (III) according to the invention, which have at least one acidic group, can form, for example, salts with bases, for example mineral salts such as alkali metal or alkaline earth metal salts, for example sodium, potassium or magnesium salts, or salts with ammonia or an organic amine, such as morpholine, piperidine, pyrrolidine, a mono-, di- or tri-lower-alkylamine, for example ethyl-, diethyl-, triethyl- or dimethylpropylamine, or a mono-, di- or trihydroxy-lower-alkylamine, for example mono-, di- or triethanolamine. The presence of one or more possible asymmetric carbon atoms in a compound of formula (I) according to the invention means that the compounds may occur in chiral isomeric forms, i.e., enantiomeric or diastereomeric forms. Also, atropisomers may occur as a result of restricted rotation about a single bond. Formula (I) is intended to include all those possible isomeric forms and mixtures thereof. The present invention includes all those possible isomeric forms and mixtures thereof for a compound of formula (I) according to the invention. Likewise, a compound of formula (I) is intended to include all possible tautomers (including lactam-lactim tautomerism and keto-enol tautomerism) where present. The present invention includes all possible tautomeric forms for a compound of formula (I) according to the invention. In each case, the compounds of formula (I) according to the invention are in free form, in oxidized form as an N-oxide, in covalently hydrated form, or in salt form, e.g., an agronomically usable or agrochemically acceptable salt form. N-oxides are oxidized forms of tertiary amines or oxidized forms of nitrogen containing heteroaromatic 109939 FF (83198) 4 compounds. They are described for instance in the book “Heterocyclic N-oxides” by A. Albini and S. Pietra, CRC Press, Boca Raton 1991. N-oxides can be prepared by reacting a compound of formula (I) with a suitable oxidizing agent, for example the H2O2 / urea adduct, in the presence of an acid anhydride, e.g., trifluoroacetic anhydride. Such oxidations are known from the literature, for example from J. Med. Chem.1989, 32 (12), 2561- 73, or WO2000 / 15615. The compounds of formula (I) according to the invention also include hydrates, which may be formed during salt formation. As used herein, the term "halogen" or “halo” refers to fluorine (fluoro), chlorine (chloro), bromine (bromo) or iodine (iodo), preferably fluorine, chlorine or bromine. This also applies, correspondingly, to halogen in combination with other meanings, such as haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, and halocycloalkyl. As used herein, amino means a -NH2 group. As used herein, cyano means a -CN group. As used herein, the term “hydroxyl” or “hydroxy” means an -OH group. As used herein, the term “carboxylic acid” means a -COOH group. As used herein, the term "C1-Cn-alkyl” refers to a saturated straight-chain or branched hydrocarbon radical attached via any of the carbon atoms having 1 to n carbon atoms, for example, any one of the radicals methyl, ethyl, n-propyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2, 2-dimethylpropyl, 1-ethylpropyl, n-hexyl, n- pentyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl, or 1-ethyl-2- methylpropyl. As used herein, the term “C2-Cn-alkenyl” refers to a straight or branched alkenyl chain moiety having from two to n carbon atoms and one or two double bonds, for example, ethenyl, prop-1-enyl, but-2-enyl. As used herein, the term “C2-Cn-alkynyl” refers to a straight or branched alkynyl chain moiety having from two to n carbon atoms and one triple bond, for example, ethynyl, prop-2-ynyl, but-3-ynyl, As used herein, the term “C3-Cn-cycloalkyl” refers to three (3) to n membered cycloalkyl radical such as cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. As used herein, the term “C3-Cn-cycloalkyloxy” refers to three (3) to n membered cycloalkyl radical as mentioned above, which is attached via an oxygen atom. As used herein, the term "C1-Cn-alkoxy" refers to a straight-chain or branched saturated alkyl radical having one (1) to n carbon atoms (as mentioned above) which is attached via an oxygen atom, i.e., for example, any one of the radicals methoxy, ethoxy, n-propoxy, 1-methylethoxy, n-butoxy, 1-methylpropoxy, 2-methylpropoxy and 1,1-dimethylethoxy. The term “C2-Cn-alkenyloxy” as used herein refers to a straight-chain or branched alkenyl chain having two (2) to n carbon atoms (as mentioned above) which is attached via an oxygen atom. 109939 FF (83198) 5 As used herein, the term "C2-Cn-alkynyloxy" refers to a radical of the formula -ORa where Ra is a C2-Cn-alkynyl radical as generally defined above. As used herein, the term “C1-Cn-alkyl-C1-Cn-alkoxy” refers to a radical of the formula -Ra-ORb, where Ra is a C1-Cn-alkyl group as defined above, and Rb refers to an C1-Cn-alkyl group as defined above. Examples are methoxymethyl, methoxyethyl, ethoxymethyl and propoxymethyl. As used herein, the term "C1-Cn-haloalkyl" refers to a straight-chain or branched saturated alkyl radical attached via any of the carbon atoms having 1 to n carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these radicals may be replaced by fluorine, chlorine, bromine and / or iodine, i.e., for example, any one of chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2- iodoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro- 2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, 2-fluoropropyl, 3-fluoropropyl, 2,2-difluoropropyl, 2,3- difluoropropyl, 2-chloropropyl, 3-chloropropyl, 2,3-dichloropropyl, 2-bromopropyl, or 3-bromopropyl,. Similarly, the term “C1-Cn-haloalkoxy” as used herein refers to a C1-Cn-alkoxyl radical respectively substituted with one or more halogen atoms which may be the same or different. As used herein, the term “C1-Cn-alkylthio“ or “C1-Cn-alkylsulfanyl“refers to a C1-Cn-alkyl group linked through a sulfur atom. As used herein, the term “C1-Cn-haloalkylthio“ or “C1-Cn-haloalkylsulfanyl“refers to a C1-Cn-haloalkyl group linked through a sulfur atom. As used herein, the term “C1-Cn-alkylsulfinyl“ refers to a C1-Cn-alkyl group linked through the sulfur atom of a sulfinyl (or S(=O)-) group. As used herein, the term “C1-Cn-alkylsulfonyl“ refers to a C1-Cn-alkyl group linked through the sulfur atom of a sulfonyl (or S(=O)2-) group. As used herein, the term “C1-Cn-alkylsulfonyl-C1-Cn-alkyl” refers to an a C1-Cn-alkyl radical substituted with a C1-Cn-alkylsulfonyl group. As used herein, the term “C1-Cn-alkylcarbonyl” refers to a C1-Cn-alkyl group linked through the carbon atom of a carbonyl (C=O) group. As used herein, the term “C1-Cn-alkoxycarbonyl” refers to a C1-Cn-alkoxy moiety linked through a carbon atom of a carbonyl (or C=O) group. As used herein, the term “C1-Cn-alkylaminocarbonyl” refers to a C1-Cn-alkylamino group (or RaNHC(=O)-), wherein Ra is a C1-Cn-alkyl group linked through the carbon atom of a carbonyl (C=O) group. As used herein, the term “aminocarbonyl-C1-Cn-alkyl” refers to a C1-Cn-alkyl radical substituted by an aminocarbonyl (or NH2C(=O)-) group. 109939 FF (83198) 6 As used herein, the term “N-C1-Cn-alkylamino” refers to a radical of the formula -NH-Ra where Ra is a C1-Cn- alkyl radical as defined above. As used herein, the term "N,N-di(C1-Cn-alkyl)amino" refers to a radical of the formula -N(Ra)Ra where each Ra is a C1-Cn-alkyl radical, which may be the same or different, as defined above. As used herein, the term “N-C1-Cn-alkoxy-C-C1-Cn-alkyl-carbonimidoyl” refers to a radical of the formula - C(Ra)=NO(Rb) where Ra is a C1-Cn-alkyl radical as generally defined above, and Rb is a C1-Cn-alkyl radical as generally defined above. As used herein the term “N-hydroxy-C-C1-Cn-alkyl-carbonimidoyl” refers to a radical of the formula -C(Ra)=NOH where Ra is a C1-Cn-alkyl radical as generally defined above. As used herein, the term “heteroaryl" refers to a 5- or 6-membered aromatic monocyclic ring radical which comprises 1, 2, 3 or 4 heteroatoms independently selected from N, O or S. Examples of heteroaryl include, but are not limited to, furanyl, pyrrolyl, thienyl, pyrazolyl, imidazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, triazolyl, tetrazolyl, pyrazinyl, pyridazinyl, pyrimidyl or pyridyl. The term “heteroaryl-C1-Cn-alkyl” or “heteroaryl- C3-Cn-cycloalkyl” refers to an C1-Cn-alkyl or C3-Cn-cycloalkyl radical respectively substituted by a heteroaryl group. The heteroaryl-C1-Cn-alkyl or heteroaryl-C3-Cn-cycloalkyl radical may be substituted on heteroaryl, alkyl and / or cycloalkyl group as appropriate. As used herein, the term "controlling" refers to reducing the number of pests, eliminating pests and / or preventing further pest damage such that damage to a plant or to a plant derived product is reduced. As used herein, the term "pest" refers to insects, and molluscs that are found in agriculture, horticulture, forestry, the storage of products of vegetable origin (such as fruit, grain, and timber); and those pests associated with the damage of man-made structures. The term pest encompasses all stages in the life cycle of the pest. As used herein, the term "effective amount" refers to the amount of the compound, or a salt thereof, which, upon single or multiple applications provides the desired effect. An effective amount is readily determined by the skilled person in the art, using known techniques and by observing results obtained under analogous circumstances. In determining the effective amount, a number of factors are considered including, but not limited to the type of plant or derived product to be applied; the pest to be controlled and its lifecycle; the particular compound applied; the type of application; and other relevant circumstances. As used herein, the term “room temperature” or “RT” or “rt” or “ambient temperature” refer to a temperature of about 15°C to about 35°C. For example, rt can refer to a temperature of about 20°C to about 30°C. The following list provides definitions, including preferred definitions, for substituents R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, A, R12a, R13a, R14a, B1, B2, and Z1with reference to the compounds of formula (I) of the present invention. For any one of these substituents, any of the definitions given below may be combined with any definition of any other substituent given below or elsewhere in this document. 109939 FF (83198) 7 In one embodiment of the invention, R1is selected from hydrogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, or C3-C6-cycloalkyl. In another embodiment of the invention, R1is C1-C4-alkyl. Preferably R1is C1-C3-alkyl. More preferably, R1is methyl, ethyl, or isopropyl. Even more preferably, R1is methyl. In one embodiment of the invention, R2is selected from cyano, hydroxy, amino, C1-C4-alkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-cycloalkyloxy, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkylamino, di(C1-C4-alkyl)amino, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, or C1-C4- haloalkylsulfanyl. Preferably, R2is cyano, hydroxy, C1-C3-alkoxy, C3-C6-cycloalkyloxy, C1-C2-haloalkoxy, C1- C2-alkyl-C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2-alkyl)amino, C1-C2-alkylsulfanyl, or C1-C2-alkylsulfonyl. More preferably, R2is C1-C3-alkoxy, C1-C2-haloalkoxy, C1-C2-alkyl-C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2- alkyl)amino, or C1-C2-alkylsulfanyl. Even more preferably, R2is C1-C3-alkoxy, C1-C2-alkyl-C1-C4-alkoxy, or C1- C2-alkylsulfanyl. Still even more preferably, R2is methoxy, ethoxy, methylmethoxy, or methylsulfanyl. In one embodiment of the invention, R3is selected from hydrogen, halogen, or C1-C4-alkyl. In another embodiment R3is selected from hydrogen, halogen, or C1-C3-alkyl. Preferably R3is hydrogen, fluorine, chlorine or methyl. More preferably R3is hydrogen or methyl. Even more preferably R3is hydrogen. In another embodiment, R3is hydrogen or C1-C3-alkyl. In one embodiment of the invention, R4is selected from hydrogen, halogen, cyano, or C1-C4-alkyl. Preferably R4is hydrogen, fluorine, chlorine, cyano, or C1-C3-alkyl. More preferably, R4is hydrogen, fluorine, chlorine, or C1-C3-alkyl. Even more preferably R4is hydrogen or methyl. In one embodiment R4is hydrogen. In another embodiment R4is methyl. In one embodiment of the invention, R5and R6are independently selected from hydrogen, or C1-C4-alkyl. Preferably, R5and R6are independently selected from hydrogen, or C1-C3-alkyl. More preferably R5and R6are hydrogen. In one embodiment of the invention, R7is selected from hydrogen, C1-C4-alkyl, C1-C4-alkylcarbonyl, N-C1-C4- alkoxy-C-C1-C4-alkyl-carbonimidoyl, N-hydroxy-C-C1-C4-alkyl-carbonimidoyl, C1-C4-alkoxycarbonyl, N- methoxy-N-methyl-carbonyl, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl, phenyl, a 5- or 6- membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms independently selected from N, O or S, with the proviso that no more than one is O or S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted with 1, 2 or 3 substituents independently selected from halogen, cyano, carboxy, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4- alkoxy; and wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-alkoxy. Preferably, R7is hydrogen, C1-C3- alkyl, C1-C2-alkylcarbonyl, N-C1-C2-alkoxy-C-C1-C3-alkyl-carbonimidoyl, N-hydroxy-C-C1-C3-alkyl- carbonimidoyl, C1-C2-alkoxycarbonyl, N-methoxy-N-methyl-carbonyl, C1-C2-alkylaminocarbonyl, di(C1-C2- alkyl)aminocarbonyl, phenyl, a 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6- membered heteroaryl contains 1 or 2 heteroatoms independently selected from N, O or S, with the proviso that no more than one is O or S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted 109939 FF (83198) 8 or substituted with 1 or 2 substituents independently selected from fluoro, chloro, cyano, methyl, methoxy, trifluoromethyl; and wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 substituent selected from halogen, or cyano. More preferably, R7is hydrogen, C1-C3-alkyl, C1-C2-alkylcarbonyl, N-C1-C2-alkoxy-C- C1-C3-alkyl-carbonimidoyl, N-hydroxy-C-C1-C3-alkyl-carbonimidoyl, C1-C2-alkoxycarbonyl, N-methoxy-N- methyl-carbonyl, C1-C2-alkylaminocarbonyl, di(C1-C2-alkyl)aminocarbonyl, phenyl, a 5- or 6-membered heteroaryl, or cyclopropyl; wherein any of said 5- or 6-membered heteroaryl contains 1 heteroatom selected from N, O or S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted with 1 or 2 substituents independently selected from fluoro, chloro, cyano, methyl, methoxy, trifluoromethyl; and wherein said cyclopropyl is unsubstituted or substituted with 1 substituent selected from halogen, or cyano. Still more preferably, R7is selected from hydrogen, methyl, acetyl, C(CH3)=NOCH3, – C(CH3)=NOCH2CH3, –C(CH3)=NOH, methoxycarbonyl, ethoxycarbonyl, N-methoxy-N-methyl-carbonyl, methylaminocarbonyl, dimethylaminocarbonyl, phenyl, 2-cyanophenyl, 3-cyanophenyl, 4-cyanophenyl, [4- (trifluoromethyl)pyrazol-1-yl], [3-(trifluoromethyl)pyrazol-1-yl], (3-cyanopyrazol-1-yl), (4-cyanopyrazol-1-yl), (5- chloropyrazol-1-yl), (5-fluoropyrazol-1-yl), (3,5-dimethylpyrazol-1-yl), (5-methylpyrazol-1-yl), pyrazol-1-yl, cyclopropyl, or 1-cyanocyclopropyl. Still even more preferably, R7is selected from hydrogen, methyl, acetyl, C(CH3)=NOCH3, –C(CH3)=NOCH2CH3, –C(CH3)=NOH, phenyl, 4-cyanophenyl, pyrazol-1-yl, cyclopropyl, or 1- cyanocyclopropyl. In another embodiment of the invention, R7is selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4- alkoxy, or C3-C6-cycloalkyl, wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 substituent selected from halogen, or cyano. Preferably R7is hydrogen, C1-C3-alkyl, C1-C3-haloalkyl, C1-C3-alkoxy, or C3- C6-cycloalkyl, wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 substituent selected from halogen, or cyano. More preferably, R7is hydrogen, methyl, methoxy, trifluoromethyl, cyclopropyl, or 1- cyanocyclopropyl. Even more preferably R7is hydrogen, methyl, or cyclopropyl. In one embodiment R7is hydrogen or methyl. In another embodiment R7is hydrogen. In still another embodiment R7is methyl. In another embodiment of the invention, R7is selected from hydrogen, or C1-C4-alkyl. Preferably, R7is selected from hydrogen, or C1-C3-alkyl. In one embodiment of the invention, R8and R9are independently selected from hydrogen, halogen, cyano, C1- C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4- alkoxy, or C3-C6-cycloalkyl. Preferably, R8and R9are independently selected from hydrogen, halogen, cyano, C1-C3-alkyl, C1-C3-alkoxy, C1-C3-haloalkyl, C1-C3-haloalkoxy, C1-C2-alkyl-C1-C2-alkoxy, or C1-C2-alkoxy-C1-C2- alkoxy. More preferably, R8and R9are independently selected from hydrogen, halogen, cyano, C1-C3-alkyl, C1- C3-alkoxy. Even more preferably, R8and R9are independently selected from hydrogen, halogen, or cyano. Still even more preferably R8and R9are hydrogen. In one embodiment of the invention, B1is selected from CR10, or N; and B2is selected from CR11, or N. In another embodiment of the invention, B1is CR10; and B2is N. In another embodiment of the invention, B1is N; and B2is CR11. In another embodiment of the invention, B1is CR10; and B2is CR11. 109939 FF (83198) 9 In one embodiment of the invention, R10and R11are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C2-C4-alkenyloxy, C2-C4-alkynyloxy, C1-C4- alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, N- C1-C4-alkylamino, N,N-di(C1-C4-alkyl)amino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, N-C1-C4-alkoxy-C1-C4- alkyl-carbonimidoyl, N-hydroxy-C1-C4-alkyl-carbonimidoyl, C1-C4-alkylaminocarbonyl, di(C1-C4- alkyl)aminocarbonyl, C1-C4-alkylcarbonylamino, C1-C4-alkylsulfonylamino, trifluoromethylsulfonyloxy, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C2-alkyl-C1-C4-alkoxy. Preferably R10and R11are independently selected from hydrogen, chloro, fluoro, bromo, methyl, ethyl, trifluoromethyl, difluoromethyl, difluoromethoxy, 2,2-difluoroethoxy, 2,2,2- trifluoroethoxy, methoxy, ethoxy, propoxy, -allyloxy, prop-2-ynoxy, methylsulfanyl, methylsulfinyl, methylsulfonyl, methoxymethyl, ethoxymethyl, 2-methoxyethoxymethyl, methoxycarbonyl, ethoxycarbonyl, tert-butoxycarbonyl, acetyl, propanoyl, -C(CH3)=NOCH3, –C(CH3)=NOCH2CH3, –C(CH3)=NOH, methylaminocarbonyl, di(methylamino)carbonyl, trifluoromethylsulfonyloxy, cyano, carboxy, phenyl, 2- cyanophenyl, 3-cyanophenyl, 4-cyanophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, [4- (trifluoromethyl)pyrazol-1-yl], [3-(trifluoromethyl)pyrazol-1-yl], (3-cyanopyrazol-1-yl), (4-cyanopyrazol-1-yl), (5- chloropyrazol-1-yl), (4-chloropyrazol-1-yl), (3-chloropyrazol-1-yl), (5-fluoropyrazol-1-yl), (4-fluoropyrazol-1-yl), (3-fluoropyrazol-1-yl), (3,5-dimethylpyrazol-1-yl), (5-methylpyrazol-1-yl), (4-methylpyrazol-1-yl), (3- methylpyrazol-1-yl), pyrazol-1-yl, cyclopropyl, or 1-cyanocyclopropyl. More preferably R10and R11are independently selected from hydrogen, chloro, bromo, fluoro, methyl, methoxy, propoxy, allyloxy, methoxymethyl, 2-methoxyethoxymethyl, phenyl, 2-cyanophenyl, 3-cyanophenyl, 4-cyanophenyl, [4- (trifluoromethyl)pyrazol-1-yl], [3-(trifluoromethyl)pyrazol-1-yl], (3-cyanopyrazol-1-yl), (4-cyanopyrazol-1-yl), (5- chloropyrazol-1-yl), (4-chloropyrazol-1-yl), (3-chloropyrazol-1-yl), (5-fluoropyrazol-1-yl), (4-fluoropyrazol-1-yl), (3-fluoropyrazol-1-yl), (3,5-dimethylpyrazol-1-yl), (5-methylpyrazol-1-yl), (4-methylpyrazol-1-yl), (3- methylpyrazol-1-yl), pyrazol-1-yl, C(CH3)=NOCH3, –C(CH3)=NOCH2CH3, –C(CH3)=NOH, cyclopropyl, or 1- cyanocyclopropyl. In another embodiment of the invention, R10and R11are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, or C1-C4-alkoxy- C1-C4-alkoxy. Preferably, R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3-alkyl, C1-C3-alkoxy, C1-C3-haloalkyl, C1-C3-haloalkoxy, C1-C2-alkyl-C1-C2-alkoxy, or C1-C2-alkoxy-C1-C2-alkoxy. In another embodiment of the invention, R10and R11are independently selected from hydrogen, halogen, cyano, C1-C4 alkyl, or C1-C4 alkoxy. Preferably, R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3-alkoxy. More preferably, R10and R11are independently selected from hydrogen, cyano, or halogen. Even more preferably R10and R11are hydrogen. In an embodiment of the invention, A is selected from A1, A2, A3, A4, A5, A6, A7, or A8 109939 FF (83198) 10 wherein the (*) the nitrogen with the bond to the Z1group; R12a, R13aR14aare hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, or C2-C4-alkynyl. Preferably, A is selected from A1, A2, A3, A4, A5, A6, A7, or A8; and R12a, R13aand R14aare independently selected from hydrogen, halogen, methyl, or trifluoromethyl. More preferably, A is selected from A1, A2, A3, A4, A5, A6, A7, or A8; and R12a, R13aand R14aare hydrogen. In another embodiment of the invention, A is selected from A1, A2, A3, A4, or A5 wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1. Preferably, A is selected from A1, A2, or A3 wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1. More preferably, A is selected from A1 or A2, wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1. In one embodiment of the invention, R12a, R13aand R14aare independently selected from hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, or C2-C4-alkynyl. Preferably, R12a, R13aand R14aare independently selected from hydrogen, halogen, C1-C3-alkyl, or C1-C3-haloalkyl. More preferably, R12a, R13aand R14aare independently selected from hydrogen, halogen, methyl or trifluoromethyl. In one embodiment of the invention, Z1is selected from C1-C4-alkyl, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl, wherein any of said 5 or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said 109939 FF (83198) 11 phenyl, 5- or 6-membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4- haloalkoxy, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, or C2-C4-alkynyl. Preferably, Z1is selected from C1-C4-alkyl, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5 or 6-membered heteroaryl contains 1 or 2 heteroatoms independently selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6- cycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy, C1-C2-haloalkoxy, C1-C2-alkylsulfanyl, C1-C2-alkylsulfinyl, C1- C2-alkylsulfonyl, or C2-C4-alkynyl. More preferably, Z1is selected from C1-C4-alkyl, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5 or 6-membered heteroaryl contains 1 or 2 heteroatoms independently selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy, C1- C2-haloalkoxy, or C2-C4-alkynyl. Even more preferably, Z1is selected from 1-methylcyclopropyl, 1- methylpyrazol-4-yl, 2,3,4-trifluorophenyl, 2,3-difluoro-4-pyridyl, 2,3-difluorophenyl, 2,4,6-trifluorophenyl, 2,4- difluoro-3-pyridyl, 2,4-difluorophenyl, 2,4-difluoropyrimidin-5-yl, 2,5-difluoro-3-pyridyl, 2,5-difluoro-4-pyridyl, 2,5-difluorophenyl, 2,5-difluoropyrimidin-4-yl, 2,6-difluoro-3-pyridyl, 2,6-difluoro-4-pyridyl, 2,6-difluoropyrimidin- 4-yl, 2-chlorophenyl, 2-fluoro-3-pyridyl, 2-fluoro-4-methoxy-phenyl, 2-fluoro-4-methylsulfonyl-phenyl, 2-fluoro- 4-pyridyl, 2-fluorophenyl, 2-fluoropyrimidin-4-yl, 2-fluoropyrimidin-5-yl, 2-furyl, 2-methylphenyl, 2-thienyl, 3,4- difluoro-2-pyridyl, 3,4-difluorophenyl, 3,5-difluoro-2-furyl, 3,5-difluoro-2-pyridyl, 3,5-difluoro-2-thienyl, 3,5- difluoro-4-pyridyl, 3,5-difluorophenyl, 3,5-difluoropyridazin-4-yl, 3,6-difluoro-2-pyridyl, 3,6-difluoropyridazin-4- yl, 3-chlorophenyl, 3-fluoro-2-furyl, 3-fluoro-2-pyridyl, 3-fluoro-2-thienyl, 3-fluoro-4-pyridyl, 3-fluorophenyl, 3- fluoropyridazin-4-yl, 3-methoxyphenyl, 3-methylphenyl, 3-thienyl, 4,5-difluoro-2-pyridyl, 4,5-difluoropyridazin- 3-yl,4,5-difluoropyrimidin-2-yl, 4,6-difluoro-2-pyridyl, 4,6-difluoro-3-pyridyl, 4,6-difluoropyridazin-3-yl,4,6- difluoropyrimidin-2-yl, 4-chlorophenyl, 4-ethynyl-2-fluoro-phenyl, 4-fluoro-2-methoxy-phenyl, 4-fluoro-2- methoxy-phenyl, 4-fluoro-3-pyridyl, 4-fluorophenyl, 4-fluoropyridazin-3-yl, 4-fluoropyrimidin-2-yl, 4- fluoropyrimidin-5-yl, 4-methylphenyl, 5,6-difluoro-2-pyridyl, 5,6-difluoro-3-pyridyl, 5,6-difluoropyridazin-3-yl, 5,6-difluoropyridazin-4-yl, 5,6-difluoropyrimidin-4-yl, 5-fluoro-2-furyl, 5-fluoro-2-pyridyl, 5-fluoro-2-thienyl, 5- fluoro-3-pyridyl, 5-fluoropyridazin-3-yl, 5-fluoropyridazin-4-yl, 5-fluoropyrimidin-2-yl, 5-fluoropyrimidin-4-yl, 6- fluoro-2-pyridyl, 6-fluoro-3-pyridyl, 6-fluoropyridazin-3-yl, 6-fluoropyridazin-4-yl, 6-fluoropyrimidin-4-yl, cyclobutyl, cyclohexyl, cyclopentyl, cyclopropyl, methyl, or n-propyl. Still even more preferably, Z1is 1- methylcyclopropyl, cyclobutyl, cyclopropyl, methyl, n-propyl, phenyl, 4-fluorophenyl, 2,4-difluorophenyl, 5- fluoro-2-furyl, 3,5-difluoro-2-furyl, 5-fluoro-2-thienyl, 3,5-difluoro-2-thienyl, 2-fluoro-3-pyridyl, 3-fluoro-2-pyridyl, 3-fluoro-4-pyridyl, 4-fluoro-3-pyridyl, 5-fluoro-2-pyridyl, 6-fluoro-3-pyridyl, 2,6-difluoro-3-pyridyl, 3,4-difluoro-2- pyridyl, 3,5-difluoro-2-pyridyl, or 4,6-difluoro-3-pyridyl. In another embodiment of the invention, Z1is selected from phenyl, 5- or 6-membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl and 5- or 6-membered 109939 FF (83198) 12 heteroaryl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1- C4-alkylsulfonyl, or C2-C4-alkynyl. Preferably, Z1is selected from phenyl, or 5- or 6-membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, and 5- or 6- membered heteroaryl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy, C1-C2-haloalkoxy, C1-C2-alkylsulfanyl, C1-C2- alkylsulfinyl, C1-C2-alkylsulfonyl, or C2-C4-alkynyl. More preferably, Z1is selected from phenyl, or 5- or 6- membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 or 2 heteroatoms independently selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy, C1-C2-haloalkoxy, or C2-C4-alkynyl. Even more preferably, Z1is selected from phenyl, thienyl, furyl, pyridyl, pyridazin, or pyrimidin; and wherein any of said phenyl, thienyl, furyl, pyridyl, pyridazin, and pyrimidin are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2- alkoxy, C1-C2-haloalkoxy, or C2-C4-alkynyl. Even more preferably, Z1is selected from phenyl, thienyl, furyl, pyridyl, pyridazin, or pyrimidin; and wherein any of said phenyl, thienyl, furyl, pyridyl, pyridazin, and pyrimidin are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from chloro, fluoro, C1-C2- alkyl, C1-C2-alkoxy, or C2-C4-alkynyl. Still even more preferably, Z1is selected from 1-methylpyrazol-4-yl, 2,3,4- trifluorophenyl, 2,3-difluoro-4-pyridyl, 2,3-difluorophenyl, 2,4,6-trifluorophenyl, 2,4-difluoro-3-pyridyl, 2,4- difluorophenyl, 2,4-difluoropyrimidin-5-yl, 2,5-difluoro-3-pyridyl,2,5-difluoro-4-pyridyl, 2,5-difluorophenyl, 2,5- difluoropyrimidin-4-yl, 2,6-difluoro-3-pyridyl, 2,6-difluoro-4-pyridyl, 2,6-difluoropyrimidin-4-yl, 2-chlorophenyl, 2- fluoro-3-pyridyl, 2-fluoro-4-methoxy-phenyl, 2-fluoro-4-methylsulfonyl-phenyl, 2-fluoro-4-pyridyl, 2- fluorophenyl, 2-fluoropyrimidin-4-yl, 2-fluoropyrimidin-5-yl, 2-furyl, 2-methylphenyl, 2-thienyl, 3,4-difluoro-2- pyridyl, 3,4-difluorophenyl, 3,5-difluoro-2-furyl, 3,5-difluoro-2-pyridyl, 3,5-difluoro-2-thienyl, 3,5-difluoro-4- pyridyl, 3,5-difluorophenyl, 3,5-difluoropyridazin-4-yl, 3,6-difluoro-2-pyridyl, 3,6-difluoropyridazin-4-yl,3- chlorophenyl, 3-fluoro-2-furyl, 3-fluoro-2-pyridyl, 3-fluoro-2-thienyl, 3-fluoro-4-pyridyl, 3-fluorophenyl, 3- fluoropyridazin-4-yl, 3-methoxyphenyl, 3-methylphenyl, 3-thienyl, 4,5-difluoro-2-pyridyl, 4,5-difluoropyridazin- 3-yl,4,5-difluoropyrimidin-2-yl, 4,6-difluoro-2-pyridyl, 4,6-difluoro-3-pyridyl, 4,6-difluoropyridazin-3-yl,4,6- difluoropyrimidin-2-yl, 4-chlorophenyl, 4-ethynyl-2-fluoro-phenyl, 4-fluoro-2-methoxy-phenyl, 4-fluoro-2- methoxy-phenyl, 4-fluoro-3-pyridyl, 4-fluorophenyl, 4-fluoropyridazin-3-yl, 4-fluoropyrimidin-2-yl, 4- fluoropyrimidin-5-yl, 4-methylphenyl, 5,6-difluoro-2-pyridyl, 5,6-difluoro-3-pyridyl, 5,6-difluoropyridazin-3-yl, 5,6-difluoropyridazin-4-yl, 5,6-difluoropyrimidin-4-yl, 5-fluoro-2-furyl, 5-fluoro-2-pyridyl, 5-fluoro-2-thienyl, 5- fluoro-3-pyridyl, 5-fluoropyridazin-3-yl, 5-fluoropyridazin-4-yl, 5-fluoropyrimidin-2-yl, 5-fluoropyrimidin-4-yl, 6- fluoro-2-pyridyl, 6-fluoro-3-pyridyl, 6-fluoropyridazin-3-yl, 6-fluoropyridazin-4-yl, 6-fluoropyrimidin-4-yl. In another embodiment of the invention, Z1is selected from phenyl, or 5- or 6-membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 or 2 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl and 5- or 6-membered 109939 FF (83198) 13 heteroaryl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4- alkylsulfonyl, or C2-C4-alkynyl. Preferably, Z1is selected from phenyl, or 5- or 6-membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 heteroatom selected from N, O and S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted by 1 or 2 substituents independently selected from chloro, fluoro, C1-C2-alkyl, C1-C2-alkoxy, or C2-C4-alkynyl. More preferably, Z1is selected from phenyl, or 5- or 6-membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 heteroatom selected from N, O and S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted by 1 or 2 substituents independently selected from chloro or fluoro. Even more preferably, Z1is selected from 4-fluorophenyl, 2,4-difluorophenyl, 5-fluoro-2-furyl, 3,5-difluoro-2-furyl, 5-fluoro- 2-thienyl, 3,5-difluoro-2-thienyl, 2-fluoro-3-pyridyl, 3-fluoro-2-pyridyl, 3-fluoro-4-pyridyl, 4-fluoro-3-pyridyl, 5- fluoro-2-pyridyl, 6-fluoro-3-pyridyl, 2,6-difluoro-3-pyridyl, 3,4-difluoro-2-pyridyl, 3,5-difluoro-2-pyridyl, or 4,6- difluoro-3-pyridyl. Still even more preferably, Z1is 4-fluorophenyl, 2,4-difluorophenyl, 3-fluoro-2-pyridyl, 5- fluoro-2-pyridyl, 2,6-difluoro-3-pyridyl, 3,4-difluoro-2-pyridyl, or 3,5-difluoro-2-pyridyl. In another embodiment of the invention, Z1is selected from phenyl or pyridyl, wherein said phenyl and any of said pyridyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, C1- C2-alkyl, C1-C2-alkoxy, or C2-C4-alkynyl. Preferably, Z1is selected from phenyl or pyridyl, wherein said phenyl and any of said pyridyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen. The present invention, accordingly, makes available a compound of formula (I) having R1, R2, R3, R4, R5, R6, R7, R8, R9, B1, B2, R10, R11, R12a, R13a, R14a, A, and Z1as defined above in all combinations / each permutation. Embodiments according to the invention are provided as set out below. In one embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, A2, or A3; B1is CR10; and B2is CR11; wherein R10and R11are as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, A2, or A3; B1is CH; and B2is CH. In another embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, A2, or A3; B1is N; and B2is CR11; wherein R11is as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, A2, or A3; B1is N; and B2is CH. In another embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, 109939 FF (83198) 14 A2, or A3; B1is CR10; and B2is N; wherein R10is as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1, A2, or A3; B1is CH; and B2is N. In a preferred embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is CR10; and B2is CR11; wherein R10and R11are as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is CH; and B2is CH. In another preferred embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is N; and B2is CR11; wherein R11is as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is N; and B2is CH. In another preferred embodiment of the invention, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is CR10; and B2is N; wherein R10is as defined for the compounds of formula (I) according to the present invention. Preferably, in the compound of formula (I) R1, R2, R3, R4, R5, R6, R7, R8, R9and Z1are as defined for the compounds of formula (I) according to the present invention, A is selected from A1 or A2; B1is CH; and B2is N. Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CR10; and B2is CR11; and R2, R7, R8, R9, R10, R11, A, R12a, R13a, R14a, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CR10; and B2is N; and R2, R7, R8, R9, R10, A, R12a, R13a, R14a, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is N; and B2is N; and R2, R7, R8, R9, R10, A, R12a, R13a, R14a, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; and R2, R7, R8, R9, R10, R11, A, R12a, R13a, R14a, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3-alkyl; R8and R9 109939 FF (83198) 15 are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3- alkoxy; and R2, A, R12a, R13a, R14a, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3-alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3- alkoxy; A is selected from A1, A2, A3, A4, A5, A6, A7, or A8 and the star (*) the nitrogen with to Z1group; R12a, R13aR14aare and R2, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3-alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3alkyl, or C1-C3- alkoxy; A is selected from A1, A2, A3, A4, or A5 wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and R2, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3-alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3- alkoxy; A is selected from A1, A2, or A3; 109939 FF (83198) 16 wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and R2, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3-alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3- alkoxy; A is selected from A1, or A2; wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and R2, and Z1are as defined as for compounds of formula (I). Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R2is C1-C3-alkoxy, C1-C2-haloalkoxy, C1-C2-alkyl- C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2-alkyl)amino, or C1-C2-alkylsulfanyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3- alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3-alkoxy; A is selected from A1, A2, A3, A4, or A5 wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and Z1is phenyl or pyridyl, wherein said phenyl and any of said pyridyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, C1-C2-alkyl, C1-C2-alkoxy, or C2-C4- alkynyl. Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R2is C1-C3-alkoxy, C1-C2-haloalkoxy, C1-C2-alkyl- C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2-alkyl)amino, or C1-C2-alkylsulfanyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3- alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3alkyl, or C1-C3-alkoxy; A is selected from A1, A2, or A3; wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and Z1is phenyl or pyridyl, wherein said phenyl and any of said pyridyl are unsubstituted or 109939 FF (83198) 17 substituted by 1 or 2 substituents independently selected from halogen, C1-C2-alkyl, C1-C2-alkoxy, or C2-C4- alkynyl. Preferably, in a compound of formula (I) R1is C1-C3-alkyl; R2is C1-C3-alkoxy, C1-C2-haloalkoxy, C1-C2-alkyl- C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2-alkyl)amino, or C1-C2-alkylsulfanyl; R3is hydrogen or C1-C3-alkyl; R4is hydrogen or methyl; R5and R6are hydrogen or C1-C3-alkyl; B1is CH; and B2is CH; R7hydrogen or C1-C3- alkyl; R8and R9are hydrogen; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3-alkoxy; A is selected from A1, or A2; wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1; and Z1is phenyl or pyridyl, wherein said phenyl and any of said pyridyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, C1-C2-alkyl, C1-C2-alkoxy, or C2-C4- alkynyl. The presence of one or more possible asymmetric carbon atoms in any of the compounds selected from compounds of formula (I), or compounds selected from compounds listed in Tables C-1 to C-41, or Table P (below), according to the invention means that the compounds may occur in chiral isomeric forms, i.e., enantiomeric or diastereomeric forms. More preferably, the compound of formula (I) according to the invention is selected from compounds listed in any one of Tables C-1 to C-41. Even more preferably the compound of formula (I) according to the invention is selected from compounds listed in Table P (below). Even more preferably the compound of formula (I) according to the invention is selected from [1-(2,4- difluorophenyl)triazol-4-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4-dihydro-1H-isoquinolin-2-yl]methanone, or [2-(2,4-difluorophenyl)tetrazol-5-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4-dihydro-1H-isoquinolin-2- yl]methanone. The compounds of formula (I) according to the present invention can be made as shown in the following Schemes below, in which, unless otherwise stated, the definition of each variable is as defined above for a compound of formula (I). In any of the Schemes below, the presence of one or more possible asymmetric carbon atoms in a compound of formula (I) according to the invention means that the compounds may occur in chiral isomeric forms, i.e., enantiomeric or diastereomeric forms. Compounds of formula (I) may be prepared by a person skilled in the art following known methods. More specifically, compounds of formula (I) may be prepared from compounds of formula (III), or a salt thereof, 109939 FF (83198) 18 wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, B1and B2are as defined above for the compound of formula (I) by reaction with a compound of formula (II), wherein A and Z1are as defined above for the compound of formula (I). This reaction is shown in Scheme 1. In Scheme 1, compounds of formula (II), wherein A and Z1are as defined above for the compound of formula (I), are activated to compounds of formula (IIa) by methods known to a person skilled in the art and described, for example, in Tetrahedron 2005, 61 (46), 10827-10852. For example, compounds of formula (IIa), where X0is halogen, are formed by treatment of compounds of formula (II) with, for example, oxalyl chloride or thionyl chloride in the presence of catalytic quantities of N,N-dimethylformamide (DMF) in inert solvents such as dichloromethane (DCM) or tetrahydrofuran (THF) at temperatures between 20°C to 100°C, preferably 25°C. Treatment of compounds of formula (IIa) with compounds of formula (III), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, B1and B2are as defined above for the compound of formula (I), optionally in the presence of a base, e.g. triethylamine or pyridine, leads to compounds of formula (I). Alternatively, compounds of formula (I) may be prepared by treatment of compounds of formula (II) with dicyclohexyl carbodiimide (DCC), 1-ethyl-3-(3- dimethylaminopropyl)carbodiimide (EDC) or 1-[bis(dimethylamino)methylene]-1H-1,2,3-triazolo[4,5- b]pyridinium 3-oxide hexafluorophosphate (HATU) to give the activated compound of formula (IIa), wherein X0is G01, G02, or G03as set forth below, in an inert solvent, e.g. pyridine, DMF, acetonitrile, DCM, or THF, optionally in the presence of a base, e.g. triethylamine, at temperatures between 30°C and 180°C. Finally, a compound of formula (II) can also be activated by reaction with a coupling reagent such as propanephosphonic acid anhydride (T3P) to provide compounds of formula (IIa), wherein X0is G04as set forth below, as described for example in Synthesis 2013, 45, 1569. Further reaction with an amine (or a salt thereof) of the compound of formula (III) leads to compounds of formula (I). 109939 FF (83198) 19 Z1is as described in formula (I), and R0is C1-C4-alkyl, by ester hydrolysis. A variety of conditions can be used, as for example aqueous sodium hydroxide, or lithium hydroxide and an organic water miscible solvent like THF, or dimethoxyethane, or methanol, or ethanol. Such ester hydrolyses are well known to those skilled in the art. Compounds of formula (IIb) can also be directly converted to compounds of formula (I) by reacting compounds of formula (IIb) with compounds of formula (III) in the presence of trimethyl aluminium, or trimethyl aluminium- DABCO complex in an inert solvent such as toluene or DCM. Such reactions have been reported in the literature (see Tetrahedron Lett.1977, 4171-4174, and Tetrahedron Lett.2006, 5767-5769, and references cited therein). Compounds of formula (II) and (IIb) are commercially available or can be synthesized as described vide infra. Compounds of formula (IIIa), wherein R4and R6are hydrogen, R5is hydrogen, or methyl, and R1, R2, R3, R7, R8, R9, B1and B2are as defined above for the compound of formula (I), may be prepared by a person skilled in the art following known methods. For example, compounds of formula (IIIa), wherein R4and R6are hydrogen, R5is hydrogen, or methyl and R1, R2, R3, R7, R8, R9, B1and B2are as defined above for the compound of formula (I), may be prepared from compounds of formula (IVa), wherein R4and R6are hydrogen, R5is hydrogen, or methyl, and R1, R2, R3, R7, R8, R9, B1and B2are as defined above for the compound of formula (I), by treatment with a reducing agent such as NaBH3CN and an acid, for example hydrochloric acid, or acetic acid in a protic solvent such as methanol or ethanol and the like. Such reactions are well known in the literature and analogous reactions have been described for example in Deng, Zeping et al, CN103772278, and Synthesis 1979, 4, 281-3. Alternatively, compounds of formula (IIIa) may be prepared from compounds of formula (IVa) by reduction with hydrogen in the presence of a suitable metal catalyst, such as Pd, Ir, Rh with a suitable ligand, e.g., diphosphine [1,2- bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), or 1,4- bis(diphenylphosphino)butane (dppb)]. Similar reactions have been reported for example in React. Kinet. Catal. Lett.2007, 92, 99-104. This reaction is shown in Scheme 2. 109939 FF (83198) 20 Alternatively, compounds of formula (IIIa) may be prepared as shown in Scheme 3. As shown in Scheme 3, compounds of formula (IIIb), wherein R4, R6and R7are hydrogen, R5is hydrogen, or methyl, and R1, R2, R3, R8, R9, B1and B2are as defined above for the compound of formula (I), can be converted to compounds of formula (V), wherein R4, R6and R7are hydrogen, R5is hydrogen, or methyl, and R1, R2, R3, R8, R9, B1and B2are as defined above for the compound of formula (I), by treatment of compounds of formula (IIIb) with a compound of formula (VI), wherein X0is a leaving group, such as halogen, and R0is C1-C6alkyl, by methods known to a person skilled in the art and by those described in Scheme 1. Alternatively, compounds of formula (V) may be prepared by treatment with an anhydride of formula (R0CO)2O, wherein R0is C1-C6alkyl, in an inert solvent such as DCM, THF, or 2-methyl-THF, optionally in the presence of a base, such as triethylamine, or dimethylaminopyridine at temperatures between 0°C and 60°C. Compounds of formula (V) are then metalated with a base, for example an alkyl metal base, such as tert-butyl lithium, and an additive such as N,N,N′,N′- tetramethylethylendiamine (TMEDA) at low temperature, for example -78°C to room temperature, in an inert polar solvent such as THF, or 2-methyl-THF. Subsequent treatment of the anion of formula (V) formed under such conditions with an electrophile of formula RX-X0, wherein X0is as previously defined, and RXis C1-C4- alkyl, C1-C4-alkylcarbonyl, C1-C4-alkoxycarbonyl, N-methoxy-N-methyl-carbonyl, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl or C3-C6-cycloalkyl, wherein said C3-C6-cycloalkyl is unsubstituted or substituted by 1, 2, or 3 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4- alkoxy, yields compounds of formula (Va), wherein R4and R6are hydrogen, R5is hydrogen, or methyl, R0is C1-C6-alkyl, and R1, R2, R3, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I). This reaction is shown in Scheme 3. Compounds of formula (Va) may be converted to compounds of formula (IIIa), wherein R4and R6are hydrogen, R5is hydrogen, or methyl, and R1, R2, R3, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I), by methods known to a person skilled in the art. For example, compounds of formula (Va), 109939 FF (83198) 21 wherein R0is tert-butyl, may be treated with an organic or inorganic acid such as trifluoroacetic acid or HCl to give compounds of formula (IIIa). This reaction is shown in Scheme 4. Compounds of formula (IVa), wherein R4and R6are hydrogen, R5is hydrogen or methyl, and R1, R2, R3, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I), may be prepared by reacting compounds of formula (VIII), wherein R1, R2and R3are as defined above for the compound of formula (I) and X0is halogen, preferably chlorine, bromine or iodine, with compounds of formula (VII), wherein R5is hydrogen or methyl, and R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I), by means of a C-C bond formation reaction typically under palladium-catalyzed (alternatively nickel-catalyzed) cross- coupling conditions. This reaction is shown in Scheme 5. Suzuki–Miyaura cross-coupling reactions between compounds of formula (VIII) and compound of formula (VII) are well known to a person skilled in the art and are usually carried out in the presence of a palladium catalyst, such as tetrakis(triphenylphosphine)-palladium(0) or [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride dichloromethane complex, and a base, such as sodium or potassium carbonate, in a solvent, such as N,N-dimethylformamide, dioxane or dioxane-water mixtures, at temperatures between room temperature and 160°C, optionally under microwave heating conditions, and preferably under inert atmosphere. Such reactions have been reviewed for example in J. Organomet. Chem.1999, 576, 147-168. A person skilled in the art will also recognize that the reaction can be reversed, i.e. by reacting a compound of formula (X), wherein R1, R2and R3are as defined above for the compound of formula (I), with a compound of formula (IX), wherein R5is hydrogen or methyl, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and X0is halogen, preferably chlorine, bromine or iodine, to provide a compound of formula (IVa), wherein R4and R6are hydrogen, R5is hydrogen or methyl, and R1, R2, R3, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I). This reaction is shown in Scheme 6. 109939 FF (83198) 22 A further cross-coupling chemistry, namely C-H activation, can also be used to prepare compounds of formula (IVa), wherein R4and R6are hydrogen, R5is hydrogen or methyl, and R1, R2, R3, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) (Scheme 7). As shown in R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and X0is halogen, preferably chlorine, bromine or iodine, are reacted with compounds of formula (XI), wherein R1, R2and R3are as defined above for the compound of formula (I), in the presence of a palladium catalyst, typically palladium acetate Pd(OAc)2, a suitable ligand, for example 1,10-phenanthroline, in the presence of a base such as cesium carbonate or potassium carbonate, in inert solvents such as chlorobenzene, toluene or xylene at temperatures between rt and 180°C, optionally under microwave heating conditions, preferably under inert atmosphere. Similar reactions have been reported in the literature for example in Chem. Sci.2013, 4, 2374-2379. Also, compounds of formula (III) may be prepared from compounds of formula (V) (Scheme 8). 109939 FF (83198) 23 As shown in Scheme 8, compounds of formula (III) may be prepared by a person skilled in the art by a carbamate deprotection reaction of compounds of formula (V), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and R01may be a member of a common carbamate protecting group substituent, for example methyl, tert-butyl, allyl, 2,2,2-trichloroethyl or benzyl. For example, when R01is methyl, a suitable solvent such as DCM and a suitable reagent such as iodotrimethylsilane may be employed to afford the product upon heating at temperatures between rt and 200°C, preferably between 20°C and the boiling point of the reaction mixture as described, for example, in J. Am. Chem. Soc.1992, 114, 5959. The compounds of formula (III) thus obtained are converted to compounds of formula (I) (Scheme 1). Compounds of formula (Vb), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and wherein R01is as described above, may be formed by a Pictet-Spengler reaction between an aldehyde (including formaldehyde in its various forms) of formula (XII), wherein R7is as defined above for the compound of formula (I), and a compound of formula (XIII), wherein R1, R2, R3, R4, R5, R6, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and wherein R01is as described above, by combination with an acid in a suitable solvent, e.g., as described in Tetrahedron 1987, 43, 439 (Scheme 9). This Pictet-Spengler reaction is stereospecific when compounds of formula (XIII) wherein R1, R2, R3, R8, R9, are as described in formula (I), B1is CR10, B2is CR11, and R01is as described above, namely compounds of formula (XIIIa) are reacted with compounds of formula (XIIa), wherein R7is C1-C4alkyl, to give racemic compounds of formula rac-syn-(Vc) with a syn-relationship of the pyrazole ring and the R7substituent (Scheme 10).

[0002] 109939 FF (83198) 24 Scheme 10 A further consequence of the stereospecific formation of compounds of formula rac-syn-(Vc) in the Pictet- Spengler reaction is that if the synthesis begins with optically pure compounds of formula (XIIIa) then chiral compounds of formula (Vb) can be obtained. This is illustrated in scheme 11 for the case of compounds of formula (XIII), wherein R1, R2, are methyl, R8, R9, R10, and R11are hydrogen, and R0is methyl, namely (S)- (XIIIb), and (R)-(XIIIb), which after Pictet-Spengler reaction with (XIIb) in which R7is methyl, give (S,S)-syn- (Vc) and (R,R)-syn-(Vc), respectively. Compounds of formula (XIII), wherein R1, R2, R3, R4, R5, R6, R8, R9, B1and B2are as defined above for the compound of formula (I) and wherein R0is as described above, may be prepared by a reaction between amines of formula (XIV), wherein R1, R2, R3, R4, R5, R6, R8, R9, B1and B2are as defined above for the compound of formula (I), and a suitable protecting reagent such as methyl chloroformate, optionally in the presence of a base such as triethylamine or pyridine, in a suitable solvent such as DCM at temperatures between -20°C and the boiling point of the mixture, as for example described in Org. Biomol. Chem.201614, 6853 (Scheme 12). 109939 FF (83198) 25 Compounds of formula (XIV), or salts thereof, wherein R1, R2, R3, R4, R5, R6, R8, R9, B1and B2are as defined above for the compound of formula (I), may be prepared by a person skilled in the art by a reaction between nitriles of formula (XV), wherein R1, R2, R3, R4, R8, R9, B1and B2are as defined above for the compound of formula (I), and a suitable nucleophile such as (dimethyl sulfide)dihydroboron (BMS) in a suitable aprotic solvent such as THF, for example as described in J. Org. Chem.1981, 47, 3153. The nitriles of formula (XV) can also be reduced to the primary amines (XIV) with hydrogen in the presence of a catalyst, such as a Platinum salt, or Raney-Nickel in the presence of a hydrogen donor, for example ethanol or methanol. Many further conditions for reducing nitriles to primary amines which are well known to those skilled in the art. Alternatively, Grignard reagents R5MgBr or R6MgBr, wherein R5and R6are as defined above for the compound of formula (I), may be added as nucleophiles to compounds of formula (XV), sequentially or simultaneously, to allow more highly substituted amines of formula (XIV) to be prepared. Such Grignard additions to nitriles are carried out in an inert solvent such as diethyl ether, tert-butylmethyl ether, and cyclopentyl methyl ether in the presence of a Lewis acid such as Ti(O-iPr)4 (see Synlett (2007), (4), 652-654). This reaction is shown in Scheme 13. of formula (I), may be prepared by a person skilled in the art following known methods. More specifically, compounds of formula (XV), and intermediates thereof, may be prepared from compounds of formula (XVI) as shown in Scheme 14. 109939 FF (83198) 26 For example, compounds of formula (XV), wherein R1, R2, R3, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I) and R4is different from hydrogen, may be prepared by a person skilled in the art by deprotonation of compound of formula (XVa) wherein R1, R2, R3, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I), using a strong base such as n-butyl lithium or sodium hydride at cryogenic temperatures in an inert solvent such as THF, followed by addition of a suitable alkylating agent R4-X, wherein R4is C1-C4alkyl and X is halogen, for example iodomethane. Compounds of formula (XVa), wherein R4is hydrogen and R1, R2, R3, R8, R9, R10, R11, B1and B2are as defined above for the compound of formula (I), may be prepared from alcohols of formula (XVI) by treatment with cyanotrimethylsilane (TMSCN) in the presence of a base such as lithium carbonate in a nonpolar solvent such as DCM at temperatures between 0°C and the boiling point of the reaction mixture. Such transformations are well known in the literature under a variety of conditions, for example as described in Org. Lett.2008.10, 4570 and references therein. This reaction is shown in Scheme 14. Compounds of formula (XVI) can be prepared by Grignard reactions, as shown in Scheme 15. As shown in scheme 14, reaction of Grignard reagents of formula (XVII), wherein R8, R9, R10, R11, B1and B2are as defined as in formula (I), and X0is halogen, preferably bromine or iodine, with compounds of formula (XVIII), wherein R1, R2, and R3are as described as in formula (I) in an inert solvent such as THF, TBME, 2- methyl-THF, diethyl ether and the like, at temperatures between -78°C to rt lead to compounds of formula (XVI). Alternatively, the Grignard can be carried out with compounds of formula (XIX) and aldehydes of formula (XX) in an analogous matter to generate compounds of formula (XVI). Compounds of formula (XIX) are readily prepared from compounds of formula (XXI) by methods well known to those skilled in the art (Scheme 16). 109939 FF (83198) 27 Compounds of formula (XXI) are generally commercially available or prepared by methods know to those skilled in the art. Compounds of formula (XVIII) wherein R2is C1-C4-alkoxy, C1-C4-alkylamino, di(C1-C4-alkyl)amino, C1-C4-haloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C4-haloalkoxy, C3-C6-cycloalkyloxy, C1-C4- alkylsulfanyl, are readily prepared as shown in scheme 17: Scheme 17 As shown in Scheme 17, Vilsmeier-Haack reaction of compounds of formula (XXII) leads to compounds of formula (XVIIIa), which when treated with compounds Nu-R2a, wherein Nu is -OH, -SH, -NH2 or -NH(C1-C4- alkyl) and R2ais C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, or C3-C6-cycloalkyl, leads to compounds of formula (XVIIIb) by SnAr type reaction. Such Vilsmeier-Haack reactions to compounds of formula (XVIIIa) have been reported (see WO2008059370 and WO2017004674), as well as reactions of compounds of formula (XVIIIa) with oxygen (e.g., Synthesis 2013, 45 (23), 3211-3227), nitrogen (e.g., Tetrahedron Lett. 2014, 4568-4571), or sulfur nucleophiles (e.g., Sulfur Lett.1986, 4 (5), 175-83). Compounds of formula (II) are either commercially available or can be synthesized as described vide infra. Compounds of formula (IIb) wherein A is A1, Z1is as described for compounds of formula (I) of the present invention, and R0is C1-C6-alkyl,namely compounds of formula (IIba) diazonium salt of formula (XXIII) (XXIII) defined for compounds of formula (I) of the present invention and Y- being the counterion depending on the conditions in which the diazotation step is performed, for example Cl- or BF4-, and compounds of formula (XXIV), 109939 FF (83198) 28 reaction can be catalyzed with various silver salts, a preferred one being silver acetate, and performed in a variety of solvents, for example THF, DMF or toluene or a mixture thereof, usually at temperatures between 0°C and 25°C, in presence of at least one equivalent of a base, for example sodium carbonate. These dipolar [3 + 2] cycloadditions are highly regioselective and are described, for example in Tetrahedron 2020, 76(14), 131063. Compounds of formula (XXIII) as defined before, can be prepared from primary amines of formula (XXV) by reaction with a diazotation reagent, for example a salt of nitrous acid, for example sodium nitrite. The solvent can be an aqueous solution of an acid, for example diluted hydrochloric acid or tetrafluoroboric acid. The counter ion Y- is defined by the acid used. Diazotation reactions are commonly used in organic synthesis, even on industrial scale, and are known by the person skilled in the art. In order to reduce the risk of decomposition of the intermediates of formula (XXIII), the diazotation step and the cycloaddition steps can be performed sequentially, without the need of isolating (XXIII). This variant is also described in Tetrahedron 2020, 76(14), 131063 (Scheme 18). Scheme 18 Compounds of formula (XXV) are commercially available, as are compounds of formula (XXIV) (e.g., R0is methyl, CAS [6832-16-2]). Very similarly, compounds of formula (IIba), wherein A is A1, and Z1is as described in for formula (I), can be prepared by reacting a compound of formula (XXVI): Ar1is phenyl or p-tolyl, with compounds of formula (XXV), in the presence of a from -50°C to 50°C to yield compounds of formula (IIba). Such reactions have good precedence in the literature, for example Chem. Comm.2017, 53(69), 9620-9623, Ang. Chem. Int. Ed.2017, 56(47), 15044-15048, and J. Am. Chem. Soc.2016, 138(44), 14609-14615. Compounds of formula 109939 FF (83198) 29 (XXVIII) are prepared as described in the literature cited vide supra and exemplified in the preparation examples of the application. Alternatively, compounds of formula (IIba), wherein A is A1, and Z1is as defined in formula (I) can be obtained by coupling compounds of formula (XXVII), (XXVII) R0is as described vide supra, with a boronic acid derivative of formula (XXVIII), (XXVIII) is as defined in formula I. This Chan-Lam type coupling reaction is usually performed in a solvent like DCM, in presence of a catalytic amount of a copper-based catalyst under mild reaction temperatures, in presence of a base, such as potassium carbonate, under atmospheric air or oxygen. It is to be noted that compounds of formula (XXVIII), wherein A is A1, exist in tautomeric forms, viz; Persons skilled in the art could be either one of the regioisomers or a mixture thereof, but when the reaction conditions are chosen as described in J. Org. Chem. 2014, 79, 6703−6707, the reaction shows an excellent regioselectivity for compounds of the formula (IIba). Those skilled in the art will realize that this Chan-Lam coupling is a general method for preparation of compounds of formula (IIb). Examples have been shown in the literature for compounds of formula (IIbb) are as previously defined (see J. Med. Chem.2018, 61, 8, 3370–3388 and , of formula (IIbc) and (IIbd) formula (I) (see WO15 / 155626, 2015, EP2390252, 109939 FF (83198) 30 R0are as defined under formula (I) (see J. Med. Chem.2017, 60(14), 6166- , 1655, and Bio. Med. Chem. Lett.2009, 19(5), 1451-1456), as representative examples. A further method for the preparation of compounds of formula (IIba), wherein A is A1, and Z1is as defined in formula (I), is shown in Scheme 19. 1) NaNO2, HCl, H2O NH3 As shown in scheme 19, sequence begins with diazotation of compounds of formula (XXV) as previously described vide supra and then treatment of the diazionium salt with a compound of formula (XXIX), wherein R0is C1-C6alkyl, in the presence of in the presence of a mild base, for example sodium acetate to yield compounds of formula (XXX). Compounds of formula (XXX), wherein Z1and R0are as previously defined, are then treated with aqueous ammonia in a miscible organic solvent, for example THF or 2-methy-THF, at temperatures between 0°C to 30°C, to give compounds of formula (XXXI). Finally, diazotation of compounds of formula (XXXI) with a salt of nitrous acid, for example sodium nitrite, in a slightly acidic medium, for example acetic acid or aqueous hydrochloric acid at temperatures between -20°C to 0°C leads to spontaneous cyclization of the diazonium salt formed to the tetrazole compounds of formula (IIba). This sequence of reactions has been previously described in WO13 / 087805, 2013. Compounds of formula (IIb) may also be prepared by alkylation of compounds of formula (XXVII) 109939 FF (83198) 31 (XXXII) is as previously described under formula I and X0is halogen, preferably chlorine, bromine or iodine in the presence of a base, for example and alkaline earth metal base such as NaOH, KOH, LiOH, Cs2CO3, K2CO3 and the like, in inert aprotic or protic solvents. Such alkylation’s are well known to those skilled in the art and have been used in this context to prepare compounds of formula (IIb) as described for example in WO14 / 168221; WO10 / 043000; and WO14 / 32498. Those skilled in the art will relize this can lead to mixtures of regiosomeric compounds that can be separted by chromatographic techniques, or pure isomers can be obtained by the judicous choice of condtitions and additives (for example palladium catalysts for so called Buchwald aminations). For cases where Z1is heteraryl or aryl SnAr reactions (with or without copper catalysis) may be used to prepare compounds of formula (IIb) (see for example, Polyhedron 2019, 165, 22-30; US18 / 0170909; Org. Lett.2022, 24(20), 3620-3625, J.Org. Chem.2017, 82(14), 7420-7427, Chem. Comm. 2021, 57(57), 7047-7050, ACS Catalysis 2019, 9(12), 10674-10679, Synthesis 2017, 49(23), 5120-5130, J.Org. Chem.2019, 84(12), 8160-8167, and references cited therein). Compounds of formula (IIb) where A is A2, namely compounds of formula (IIbf); reaction of azide compounds of the formula (XXXIII) with acetylene (Scheme 20). Such formation of triazoles is well known to those skilled in the art. The are usually carried out in inert solvents such as DMF optionally in the presence of copper catalysts. 20 Such formation of triazoles is well known to those skilled in the art. The are usually carried out in inert solvents such as DMF optionally in the presence of copper catalysts (see Angew. Chem. Int. Ed.2002, 114, 2708-2711, and ACS Omega 2022, 7, 36945−36987). The reaction can give regisomeric products but the regioisomers if formed can be separated using chromatographic methods known to those skilled in the art. An example of such triazole syntheses is described in the experimental section. Salts of compounds of formula (I) may be prepared in a manner known per se. Thus, for example, acid addition salts of compounds of formula (I) are obtained by treatment with a suitable acid or a suitable ion exchanger reagent and salts with bases are obtained by treatment with a suitable base or with a suitable ion exchanger reagent. 109939 FF (83198) 32 Salts of compounds of formula (I) can be converted in the customary manner into the free compounds (I), acid addition salts, for example, by treatment with a suitable basic compound or with a suitable ion exchanger reagent and salts with bases, for example, by treatment with a suitable acid or with a suitable ion exchanger reagent. Salts of compounds of formula (I) can be converted in a manner known per se into other salts of compounds of formula (I), acid addition salts, for example, into other acid addition salts, for example by treatment of a salt of inorganic acid such as hydrochloride with a suitable metal salt such as a sodium, barium or silver salt, of an acid, for example with silver acetate, in a suitable solvent in which an inorganic salt which forms, for example silver chloride, is insoluble and thus precipitates from the reaction mixture. Depending on the procedure or the reaction conditions, the compounds of formula (I), which have salt-forming properties, can be obtained in free form or in the form of salts. The compounds of formula (I) and, where appropriate, the tautomer’s thereof, in each case in free form or in salt form, can be present in the form of one of the isomers which are possible or as a mixture of these, for example in the form of pure isomers, such as antipodes and / or diastereomers, or as isomer mixtures, such as enantiomer mixtures, for example racemates, or diastereomer mixtures, depending on the number, absolute and relative configuration of asymmetric carbon atoms which occur in the molecule and / or depending on the configuration of non-aromatic double bonds which occur in the molecule, the invention relates to the pure isomers and also to all isomer mixtures which are possible and is to be understood in each case in this sense hereinabove and herein below, even when stereochemical details are not mentioned specifically in each case. Diastereomeric mixtures or racemic mixtures of compounds of formula (I), in free form or in salt form, which can be obtained depending on which starting materials and procedures have been chosen can be separated in a known manner into the pure diastereomers or racemates on the basis of the physicochemical differences of the components, for example by fractional crystallization, distillation and / or chromatography. Enantiomeric mixtures, such as racemates, which can be obtained in a similar manner can be resolved into the optical antipodes by known methods, for example by recrystallization from an optically active solvent, by chromatography on chiral adsorbents, for example high-performance liquid chromatography (HPLC) on acetyl cellulose, with the aid of suitable microorganisms, by cleavage with specific, immobilized enzymes, via the formation of inclusion compounds, for example using chiral crown ethers, where only one enantiomer is com- plexed, or by conversion into diastereomeric salts, for example by reacting a basic end-product racemate with an optically active acid, such as a carboxylic acid, for example camphor, tartaric or malic acid, or sulfonic acid, for example camphorsulfonic acid, and separating the diastereomer mixture which can be obtained in this manner, for example by fractional crystallization based on their differing solubilities, to give the diastereomers, from which the desired enantiomer can be set free by the action of suitable agents, for example basic agents. Pure diastereomers or enantiomers can be obtained according to the invention not only by separating suitable isomer mixtures, but also by generally known methods of diastereoselective or enantioselective synthesis, for 109939 FF (83198) 33 example by carrying out the process according to the invention with starting materials of a suitable stereochemistry. It is advantageous to isolate or synthesize in each case the biologically more effective isomer, for example enantiomer or diastereomer, or isomer mixture, for example enantiomer mixture or diastereomer mixture, if the individual components have a different biological activity. As an example, compounds with more than one asymmetric carbon atoms may exist in diastereomeric forms which can be optionally separated using for example supercritical fluid chromatography (SFC) chromatography with chiral columns. Such diastereomers can show a different fungicidal activity profile, but all isomers and diastereomers form part of this invention. The compounds of formula (I) have three chiral carbon atoms, (three stereocenters, wherein the star (*) indicates the chiral carbon atom), such there are eight stereoisomers available. These eight stereoisomers consist of four sets of enantiomers. the relationship between enantiomers and diastereomers is illustrated in scheme 20. A person skilled in the art is well aware that these diastereomers and enantiomers of formula (I) (as shown in scheme 21) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, B1, B2, R10, R11, A, R12a, R13a, R14a, and Z1are as defined for formula (I) are within the scope if the invention.

[0003] 109939 FF (83198) 34 A person skilled in the art is well aware that above diastereomers and enantiomers of formula (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, B1, B2, R10, R11, A, R12a, R13a, R14a, and Z1are as defined for formula (I) are within the scope of the invention. The compounds of formula (I) and, where appropriate, the tautomers thereof, in each case in free form or in salt form, can, if appropriate, also be obtained in the form of hydrates and / or include other solvents, for example those which may have been used for the crystallization of compounds which are present in solid form. 109939 FF (83198) 35 As already indicated, surprisingly, it has now been found that the compounds of formula (I) of the present invention have, for practical purposes, a very advantageous level of biological activity for protecting plants against diseases that are caused by fungi. The compounds of formula (I) according to the invention can be used in the agricultural sector and related fields of use, e.g., as active ingredients for controlling plant pests or on non-living materials for the control of spoilage microorganisms or organisms potentially harmful to man. The novel compounds are distinguished by excellent activity at low rates of application, by being well tolerated by plants and by being environmentally safe. They have very useful curative, preventive and systemic properties and can be used for protecting numerous cultivated plants. The compounds of formula (I) can be used to inhibit or destroy the pests that occur on plants or parts of plants (fruit, blossoms, leaves, stems, tubers, roots) of different crops of useful plants, while at the same time also protecting those parts of the plants that grow later, e.g., from phytopathogenic microorganisms. The present invention further relates to a method for controlling or preventing infestation of plants or plant propagation material and / or harvested food crops susceptible to microbial attack by treating plants or plant propagation material and / or harvested food crops wherein an effective amount a compound of formula (I) according to the invention is applied to the plants, to parts thereof or the locus thereof. It is also possible to use a compound of formula (I) according to the invention as a fungicide. The term “fungicide” as used herein means a compound that controls, modifies, or prevents the growth of fungi. The term “fungicidally effective amount” where used means the quantity of such a compound or combination of such compounds that is capable of producing an effect on the growth of fungi. Controlling or modifying effects include all deviation from natural development, such as killing, retardation and the like, and prevention includes barrier or other defensive formation in or on a plant to prevent fungal infection. It may also be possible to use compounds of formula (I) according to the invention as dressing agents for the treatment of plant propagation material, e.g., seed, such as fruits, tubers or grains, or plant cuttings, for the protection against fungal infections as well as against phytopathogenic fungi occurring in the soil. The propagation material can be treated with a composition comprising a compound of formula (I) before planting: seed, for example, can be dressed before being sown. The active compounds of formula (I) can also be applied to grains (coating), either by impregnating the seeds in a liquid formulation or by coating them with a solid formulation. The composition can also be applied to the planting site when the propagation material is being planted, for example, to the seed furrow during sowing. The invention relates also to such methods of treating plant propagation material and to the plant propagation material so treated. Furthermore, the compounds of formula (I) according to the invention can be used for controlling fungi in related areas, for example in the protection of technical materials, including wood and wood related technical products, in food storage, in hygiene management. In addition, the invention could be used to protect non-living materials from fungal attack, e.g., lumber, wall boards, and paint. 109939 FF (83198) 36 The compounds of formula (I) according to the invention are for example, effective against fungi and fungal vectors of disease as well as phytopathogenic bacteria and viruses. These fungi and fungal vectors of disease as well as phytopathogenic bacteria and viruses are for example: Absidia corymbifera, Alternaria spp., Aphanomyces spp., Ascochyta spp., Aspergillus spp. including A. flavus, A. fumigatus, A. nidulans, A. niger, A. terrus, Aureobasidium spp. including A. pullulans, Blastomyces dermatitidis, Blumeria graminis, Bremia lactucae, Botryosphaeria spp. including B. dothidea, B. obtusa, Botrytis spp. inclusing B. cinerea, Candida spp. including C. albicans, C. glabrata, C. krusei, C. lusitaniae, C. parapsilosis, C. tropicalis, Cephaloascus fragrans, Ceratocystis spp., Cercospora spp. including C. arachidicola, Cercosporidium personatum, Cladosporium spp., Claviceps purpurea, Coccidioides immitis, Cochliobolus spp., Colletotrichum spp. including C. musae, Corynespora spp. including Corynespora cassiicola, Cryptococcus neoformans, Diaporthe spp. including Diaporthe miriciae (also known as Diaporthe ueckeri or Diaporthe ueckerae), Didymella spp., Drechslera spp., Elsinoe spp.,Epidermophyton spp., Erwinia amylovora, Erysiphe spp. including E. cichoracearum, Eutypa lata, Fusarium spp. including F. culmorum, F. graminearum, F. langsethiae, F. moniliforme, F. oxysporum, F. proliferatum, F. subglutinans, F. solani, Gaeumannomyces graminis, Gibberella fujikuroi, Gloeodes pomigena, Gloeosporium musarum, Glomerella cingulate, Guignardia bidwellii, Gymnosporangium juniperi-virginianae, Helminthosporium spp., Hemileia spp., Histoplasma spp. including H. capsulatum, Laetisaria fuciformis, Leptographium lindbergi, Leveillula taurica, Lophodermium seditiosum, Microdochium nivale, Microsporum spp., Monilinia spp., Mucor spp., Mycosphaerella spp. including M. graminicola, M. pomi, Oncobasidium theobromaeon, Ophiostoma piceae, Paracoccidioides spp., Penicillium spp. including P. digitatum, P. italicum, Petriellidium spp., Peronosclerospora spp. including P. maydis, P. philippinensis and P. sorghi, Peronospora spp., Phaeosphaeria nodorum, Phakopsora pachyrhizi, Phellinus igniarus, Phialophora spp., Phoma spp., Phomopsis viticola, Phytophthora spp. including P. infestans, Plasmopara spp. including P. halstedii, P. viticola, Pleospora spp., Podosphaera spp. including P. leucotricha, Polymyxa graminis, Polymyxa betae, Pseudocercosporella herpotrichoides, Pseudomonas spp., Pseudoperonospora spp. including P. cubensis, P. humuli, Pseudopeziza tracheiphila, Puccinia spp. including P. hordei, P. recondita, P. striiformis, P. triticina, Pyrenopeziza spp., Pyrenophora spp., Pyricularia spp. including P. oryzae, Pythium spp. including P. ultimum, Ramularia spp., Rhizoctonia spp., Rhizomucor pusillus, Rhizopus arrhizus, Rhynchosporium spp., Scedosporium spp. including S. apiospermum and S. prolificans, Schizothyrium pomi, Sclerotinia spp., Sclerotium spp., Septoria spp., including S. nodorum, S. tritici, Sphaerotheca macularis, Sphaerotheca fusca (Sphaerotheca fuliginea), Sporothorix spp., Stagonospora nodorum, Stemphylium spp., Stereum hirsutum, Thanatephorus cucumeris, Thielaviopsis basicola, Tilletia spp., Trichoderma spp. including T. harzianum, T. pseudokoningii, T. viride, Trichophyton spp., Typhula spp., Uncinula necator, Urocystis spp., Ustilago spp., Venturia spp. including V. inaequalis, Verticillium spp., and Xanthomonas spp.. The compounds of formula (I) according to the invention may be used for example on turf, ornamentals, such as flowers, shrubs, broad-leaved trees, or evergreens, for example conifers, as well as for tree injection, pest management and the like. Within the scope of present invention, target crops and / or useful plants to be protected typically comprise perennial and annual crops, such as berry plants for example blackberries, blueberries, cranberries, 109939 FF (83198) 37 raspberries and strawberries; cereals for example barley, maize (corn), millet, oats, rice, rye, sorghum triticale and wheat; fibre plants for example cotton, flax, hemp, jute and sisal; field crops for example sugar and fodder beet, coffee, hops, mustard, oilseed rape (canola), poppy, sugar cane, sunflower, tea and tobacco; fruit trees for example apple, apricot, avocado, banana, cherry, citrus, nectarine, peach, pear and plum; grasses for example Bermuda grass, bluegrass, bentgrass, centipede grass, fescue, ryegrass, St. Augustine grass and Zoysia grass; herbs such as basil, borage, chives, coriander, lavender, lovage, mint, oregano, parsley, rosemary, sage and thyme; legumes for example beans, lentils, peas and soya beans; nuts for example almond, cashew, ground nut, hazelnut, peanut, pecan, pistachio and walnut; palms for example oil palm; ornamentals for example flowers, shrubs and trees; other trees, for example cacao, coconut, olive and rubber; vegetables for example asparagus, aubergine, broccoli, cabbage, carrot, cucumber, garlic, lettuce, marrow, melon, okra, onion, pepper, potato, pumpkin, rhubarb, spinach and tomato; and vines for example grapes. The term "useful plants" is to be understood as also including useful plants that have been rendered tolerant to herbicides like bromoxynil or classes of herbicides (such as, for example, HPPD inhibitors, ALS inhibitors, for example primisulfuron, prosulfuron and trifloxysulfuron, EPSPS (5-enol-pyrovyl-shikimate-3-phosphate- synthase) inhibitors, GS (glutamine synthetase) inhibitors or PPO (protoporphyrinogen-oxidase) inhibitors) as a result of conventional methods of breeding or genetic engineering. An example of a crop that has been rendered tolerant to imidazolinones, e.g., imazamox, by conventional methods of breeding (mutagenesis) is Clearfield® summer rape (Canola). Examples of crops that have been rendered tolerant to herbicides or classes of herbicides by genetic engineering methods include glyphosate- and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady®, Herculex I® and LibertyLink®. The term "useful plants" is to be understood as also including useful plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesizing one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria, especially those of the genus Bacillus. Examples of such plants are: YieldGard® (maize variety that expresses a CryIA(b) toxin); YieldGard Rootworm® (maize variety that expresses a CryIIIB(b1) toxin); YieldGard Plus® (maize variety that expresses a CryIA(b) and a CryIIIB(b1) toxin); Starlink® (maize variety that expresses a Cry9(c) toxin); Herculex I® (maize variety that expresses a CryIF(a2) toxin and the enzyme phosphinothricin N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B® (cotton variety that expresses a CryIA(c) toxin); Bollgard I® (cotton variety that expresses a CryIA(c) toxin); Bollgard II® (cotton variety that expresses a CryIA(c) and a CryIIA(b) toxin); VIPCOT® (cotton variety that expresses a VIP toxin); NewLeaf® (potato variety that expresses a CryIIIA toxin); Nature-Gard® Agrisure® GT Advantage (GA21 glyphosate-tolerant trait), Agrisure® CB Advantage (Bt11 corn borer (CB) trait), Agrisure® RW (corn rootworm trait) and Protecta®. The term "crops" is to be understood as including also crop plants which have been so transformed using recombinant DNA techniques that they are capable of synthesizing one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria, especially those of the genus Bacillus. Toxins that can be expressed by such transgenic plants include, for example, insecticidal proteins from Bacillus cereus or Bacillus popilliae; or insecticidal proteins from Bacillus thuringiensis, such as delta-endotoxins, e.g., 109939 FF (83198) 38 Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), e.g., Vip1, Vip2, Vip3 or Vip3A; or insecticidal proteins of bacteria colonizing nematodes, for example Photorhabdus spp. or Xenorhabdus spp., such as Photorhabdus luminescens, Xenorhabdus nematophilus; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea lectins, barley lectins or snowdrop lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroidoxidase, ecdysteroid- UDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors, HMG-COA-reductase, ion channel blockers, such as blockers of sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, stilbene synthase, bibenzyl synthase, chitinases and glucanases. Further, in the context of the present invention there are to be understood by delta-endotoxins, for example Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), for example Vip1, Vip2, Vip3 or Vip3A, expressly also hybrid toxins, truncated toxins, and modified toxins. Hybrid toxins are produced recombinantly by a new combination of different domains of those proteins (see, for example, WO02 / 15701). Truncated toxins, for example a truncated Cry1Ab, are known. In the case of modified toxins, one or more amino acids of the naturally occurring toxin are replaced. In such amino acid replacements, preferably non-naturally present protease recognition sequences are inserted into the toxin, such as, for example, in the case of Cry3A055, a cathepsin-G-recognition sequence is inserted into a Cry3A toxin (see WO2003 / 018810). Examples of such toxins or transgenic plants capable of synthesizing such toxins are disclosed, for example, in EP-0374753, WO93 / 07278, WO95 / 34656, EP0427529, EP0451878 and WO03 / 052073. The processes for the preparation of such transgenic plants are generally known to a person skilled in the art and are described, for example, in the publications mentioned above. CryI-type deoxyribonucleic acids and their preparation are known, for example, from WO95 / 34656, EP0367474, EP0401979 and WO90 / 13651. The toxin contained in the transgenic plants imparts to the plants tolerance to harmful insects. Such insects can occur in any taxonomic group of insects but are especially commonly found in the beetles (Coleoptera), two-winged insects (Diptera) and butterflies (Lepidoptera). Transgenic plants containing one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are commercially available. Examples of such plants are: YieldGard® (maize variety that expresses a Cry1Ab toxin); YieldGard Rootworm® (maize variety that expresses a Cry3Bb1 toxin); YieldGard Plus® (maize variety that expresses a Cry1Ab and a Cry3Bb1 toxin); Starlink® (maize variety that expresses a Cry9C toxin); Herculex I® (maize variety that expresses a Cry1Fa2 toxin and the enzyme phosphinothricin N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B® (cotton variety that expresses a Cry1Ac toxin); Bollgard I® (cotton variety that expresses a Cry1Ac toxin); Bollgard II® (cotton variety that expresses a Cry1Ac and a Cry2Ab toxin); VipCot® (cotton variety that expresses a Vip3A and a Cry1Ab toxin); NewLeaf® (potato variety that expresses a Cry3A toxin); 109939 FF (83198) 39 NatureGard®, Agrisure® GT Advantage (GA21 glyphosate-tolerant trait), Agrisure® CB Advantage (Bt11 corn borer (CB) trait) and Protecta®. Further examples of such transgenic crops are: 1. Bt11 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalis and Sesamia nonagrioides) by transgenic expression of a truncated Cry1Ab toxin. Bt11 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 2. Bt176 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalis and Sesamia nonagrioides) by transgenic expression of a Cry1Ab toxin. Bt176 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 3. MIR604 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31790 St. Sauveur, France, registration number C / FR / 96 / 05 / 10. Maize which has been rendered insect-resistant by transgenic expression of a modified Cry3A toxin. This toxin is Cry3A055 modified by insertion of a cathepsin-G-protease recognition sequence. The preparation of such transgenic maize plants is described in WO2003 / 018810. 4. MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / DE / 02 / 9. MON 863 expresses a Cry3Bb1 toxin and has resistance to certain Coleoptera insects. 5. IPC 531 Cotton from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / ES / 96 / 02. 6.1507 Maize from Pioneer Overseas Corporation, Avenue Tedesco, 7 B-1160 Brussels, Belgium, registration number C / NL / 00 / 10. Genetically modified maize for the expression of the protein Cry1F for achieving resistance to certain Lepidoptera insects and of the PAT protein for achieving tolerance to the herbicide glufosinate ammonium. 7. NK603 × MON 810 Maize from Monsanto Europe S.A.270-272 Avenue de Tervuren, B 1150 Brussels, Belgium, registration number C / GB / 02 / M3 / 03. Consists of conventionally bred hybrid maize varieties by crossing the genetically modified varieties NK603 and MON 810. NK603 × MON 810 Maize transgenically expresses the protein CP4 EPSPS, obtained from Agrobacterium sp. strain CP4, which imparts tolerance to the herbicide Roundup® (contains glyphosate), and also a Cry1Ab toxin obtained from Bacillus thuringiensis subsp. kurstaki which brings about tolerance to certain Lepidoptera, include the European corn borer. The compounds of formula (I) according to the invention may be used in controlling or preventing phytopathogenic diseases, especially phytopathogenic fungi, especially phytopathogenic fungi on soybean plants. In one embodiment such soybean plants are genetically modified soybean plants. 109939 FF (83198) 40 In one embodiment the genetically modified plants are soybean plants. Examples of genetically modified plants of soybean are, but not limited to, Intacta®, Intacta®2, Intacta® Roundup Ready™ 2 Pro (Intacta®RR2 PRO), Intacta®2 Xtend™, Cultivance, Conkesta Soybean, Conkesta Enlist E3™ Soybean, Enlist™ Soybean, Enlist E3™ Soybean, Roundup Ready™ Soybean, Roundup Ready™ 2 Xtend™, Genuity® Roundup Ready™ 2 Xtend™, Genuity® Roundup Ready 2 Yield™, Herbicide-tolerant Soybean line, Optimum GAT™, Liberty Link™ Soybean, Vistive Gold™, Verdeca HB4 Soybean, Treus™, Plenish™. Transgenic soybean plants expressing toxins, for example insecticidal proteins such as delta-endotoxins, e.g., Cry1Ac (Cry1Ac Bt protein). Accordingly, this may include transgenic soybean plants comprising event MON87701 (disclosed in WO2009 / 064652), event MON87701 x MON89788 (disclosed in WO2014 / 170327, e.g. commercially available as Intacta RR2 PRO®soybean), event MON87751 (disclosed in WO2014 / 201235), event DAS-44406-6 (e.g., commercially available as Enlist E3TM, DAS-44406-6, disclosed in WO2012 / 075426), or event DAS-81419-2 (described in WO2013 / 016527, e.g., commercially available as ConkestaTMsoybean); event DAS-81419-2 x DAS-44406-6 (e.g., commercially available as Conkesta™ Enlist E3™ Soybean). Furthermore, such a list of transgenic events is provided by the United States Department of Agriculture's (USDA) Animal and Plant Health Inspection Service (APHIS) and can be found on their website on the World Wide Web at aphis.usda.gov. The compounds of formula (I) according to the invention may be used in controlling or preventing phytopathogenic diseases, especially phytopathogenic fungi such as Alternaria spp. in fruits, vegetables and potatoes; Botrytis cinerea in strawberries, tomatoes, sunflower, pulse crops, vegetables and grapes; Rhizoctonia solani in potatoes and vegetables; Uncinula necator in grapes; Cladosporium cucumerinum, Didymella bryoniae, Sphaerotheca fuliginea and Glomerella lagenarium in cucurbits; Leveillula taurica in cucurbits and solanaceous crops; Fusarium spp. in cereals; Leptosphaeria spp. in cereals; and Zymoseptoria spp. in cereals. The compounds of formula (I) and compositions comprising said compounds, are suitable for controlling the following fungal diseases on soybeans and genetically modified soybeans, for example Bt soybeans: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (Cercospora leaf spots), e.g., C. sojina or C. kikuchii Colletotrichum (teleomorph: Glomerella) spp. (anthracnose), e.g., C. truncatum or C. gloeosporioides)', Corynespora cassiicola (leaf spots); Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot); Diaporthe spp., e.g., Diaporthe miriciae (also known as Diaporthe ueckeri or Diaporthe ueckerae), (damping off); Fusarium (teleomorph: Gibberella) spp. (wilt, root or stem rot), e.g. F. tucumaniae and F. brasiliense each causing sudden death syndrome on soybeans; Macrophomina phaseolina (syn. phaseoli) (root and stem rot); Microsphaera diffusa (powdery mildew); Peronospora spp. (downy mildew), e.g., P. manshurica; Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phialophora spp., e.g., P. g reg ata'. stem rot; Phomopsis spp., e.g., stem rot: P. phaseoli (teleomorph: Diaporthe phaseolorum)’, Pythium spp. (damping-off); Phytophthora spp. (wilt, root, leaf, fruit and stem root), e.g., P. megasperma, syn. P. sojae)', Rhizoctonia spp., e.g., R. solani (root and stem rot); Sclerotinia spp. (stem rot or white mold); Septoria spp., e.g., S. glycines (brown spot); S. rolfsii (syn. Athelia rolfsii); Thielaviopsis spp. (black root rot). 109939 FF (83198) 41 The term “locus” as used herein means fields in or on which plants are growing, or where seeds of cultivated plants are sown, or where seed will be placed into the soil. It includes soil, seeds, and seedlings, as well as established vegetation. The term “plants” refers to all physical parts of a plant, including seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage, and fruits. The term “plant propagation material” is understood to denote generative parts of the plant, such as seeds, which can be used for the multiplication of the latter, and vegetative material, such as cuttings or tubers, for example potatoes. There can be mentioned for example seeds (in the strict sense), roots, fruits, tubers, bulbs, rhizomes, and parts of plants. Germinated plants and young plants which are to be transplanted after germination or after emergence from the soil, may also be mentioned. These young plants can be protected before transplantation by a total or partial treatment by immersion. Preferably “plant propagation material” is understood to denote seeds. The compounds of formula (I) according to the invention may be used in unmodified form or, preferably, together with the adjuvants conventionally employed in the art of formulation. To this end they may be conveniently formulated in known manner to emulsifiable concentrates, coatable pastes, directly sprayable or dilutable solutions or suspensions, dilute emulsions, wettable powders, soluble powders, dusts, granulates, and also encapsulations e.g., in polymeric substances. As with the type of the compositions, the methods of application, such as spraying, atomising, dusting, scattering, coating, or pouring, are chosen in accordance with the intended objectives and the prevailing circumstances. The compositions may also contain further adjuvants such as stabilizers, antifoams, viscosity regulators, binders or tackifiers as well as fertilizers, micronutrient donors or other formulations for obtaining special effects. Suitable carriers and adjuvants, e.g., for agricultural use, can be solid or liquid and are substances useful in formulation technology, e.g., natural or regenerated mineral substances, solvents, dispersants, wetting agents, tackifiers, thickeners, binders or fertilizers. Such carriers are for example described in WO1997 / 33890. Suspension concentrates are aqueous formulations in which finely divided solid particles of the active compound are suspended. Such formulations include anti-settling agents and dispersing agents and may further include a wetting agent to enhance activity as well an anti-foam and a crystal growth inhibitor. In use, these concentrates are diluted in water and normally applied as a spray to the area to be treated. The amount of active ingredient may range from 0.5% to 95% of the concentrate. Wettable powders are in the form of finely divided particles which disperse readily in water or other liquid carriers. The particles contain the active ingredient retained in a solid matrix. Typical solid matrices include fuller’s earth, kaolin clays, silicas and other readily wet organic or inorganic solids. Wettable powders normally contain from 5% to 95% of the active ingredient plus a small amount of wetting, dispersing or emulsifying agent. Emulsifiable concentrates are homogeneous liquid compositions dispersible in water or other liquid and may consist entirely of the active compound with a liquid or solid emulsifying agent, or may also contain a liquid carrier, such as xylene, heavy aromatic naphthas, isophorone and other non-volatile organic solvents. In use, 109939 FF (83198) 42 these concentrates are dispersed in water or other liquid and normally applied as a spray to the area to be treated. The amount of active ingredient may range from 0.5% to 95% of the concentrate. Granular formulations include both extrudates and relatively coarse particles and are usually applied without dilution to the area in which treatment is required. Typical carriers for granular formulations include sand, fuller’s earth, attapulgite clay, bentonite clays, montmorillonite clay, vermiculite, perlite, calcium carbonate, brick, pumice, pyrophyllite, kaolin, dolomite, plaster, wood flour, ground corn cobs, ground peanut hulls, sugars, sodium chloride, sodium sulfate, sodium silicate, sodium borate, magnesia, mica, iron oxide, zinc oxide, titanium oxide, antimony oxide, cryolite, gypsum, diatomaceous earth, calcium sulfate and other organic or inorganic materials which absorb or which can be coated with the active compound. Granular formulations normally contain 5% to 25% of active ingredients which may include surface-active agents such as heavy aromatic naphthas, kerosene and other petroleum fractions, or vegetable oils; and / or stickers such as dextrins, glue or synthetic resins. Dusts are free-flowing admixtures of the active ingredient with finely divided solids such as talc, clays, flours and other organic and inorganic solids which act as dispersants and carriers. Microcapsules are typically droplets or granules of the active ingredient enclosed in an inert porous shell which allows escape of the enclosed material to the surroundings at controlled rates. Encapsulated droplets are typically 1 to 50 microns in diameter. The enclosed liquid typically constitutes 50 to 95% of the weight of the capsule and may include solvent in addition to the active compound. Encapsulated granules are generally porous granules with porous membranes sealing the granule pore openings, retaining the active species in liquid form inside the granule pores. Granules typically range from 1 millimetre to 1 centimetre and preferably 1 to 2 millimetres in diameter. Granules are formed by extrusion, agglomeration or prilling, or are naturally occurring. Examples of such materials are vermiculite, sintered clay, kaolin, attapulgite clay, sawdust, and granular carbon. Shell or membrane materials include natural and synthetic rubbers, cellulosic materials, styrene-butadiene copolymers, polyacrylonitriles, polyacrylates, polyesters, polyamides, polyureas, polyurethanes and starch xanthates. Other useful formulations for agrochemical applications include simple solutions of the active ingredient in a solvent in which it is completely soluble at the desired concentration, such as acetone, alkylated naphthalenes, xylene and other organic solvents. Pressurized sprayers, wherein the active ingredient is dispersed in finely divided form as a result of vaporization of a low boiling dispersant solvent carrier, may also be used. Suitable agricultural adjuvants and carriers that are useful in formulating the compositions of the invention in the formulation types described above are well known to a person skilled in the art. Liquid carriers that can be employed include, for example, water, toluene, xylene, petroleum naphtha, crop oil, acetone, methyl ethyl ketone, cyclohexanone, acetic anhydride, acetonitrile, acetophenone, amyl acetate, 2- butanone, chlorobenzene, cyclohexane, cyclohexanol, alkyl acetates, diacetonalcohol, 1,2-dichloropropane, diethanolamine, p diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N-dimethyl formamide, dimethyl sulfoxide, 1,4- 109939 FF (83198) 43 dioxane, dipropylene glycol, dipropylene glycol methyl ether, dipropylene glycol dibenzoate, diproxitol, alkyl pyrrolidinone, ethyl acetate, 2-ethyl hexanol, ethylene carbonate, 1,1,1-trichloroethane, 2-heptanone, alpha pinene, d-limonene, ethylene glycol, ethylene glycol butyl ether, ethylene glycol methyl ether, gamma- butyrolactone, glycerol, glycerol diacetate, glycerol monoacetate, glycerol triacetate, hexadecane, hexylene glycol, isoamyl acetate, isobornyl acetate, isooctane, isophorone, isopropyl benzene, isopropyl myristate, lactic acid, laurylamine, mesityl oxide, methoxy-propanol, methyl isoamyl ketone, methyl isobutyl ketone, methyl laurate, methyl octanoate, methyl oleate, methylene chloride, m-xylene, n-hexane, n-octylamine, octadecanoic acid, octyl amine acetate, oleic acid, oleylamine, o-xylene, phenol, polyethylene glycol (PEG400), propionic acid, propylene glycol, propylene glycol monomethyl ether, p-xylene, toluene, triethyl phosphate, triethylene glycol, xylene sulfonic acid, paraffin, mineral oil, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, methanol, ethanol, isopropanol, and higher molecular weight alcohols such as amyl alcohol, tetrahydrofurfuryl alcohol, hexanol, octanol, etc., ethylene glycol, propylene glycol, glycerine and N- methyl-2-pyrrolidinone. Water is generally the carrier of choice for the dilution of concentrates. Suitable solid carriers include, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, kieselguhr, chalk, diatomaxeous earth, lime, calcium carbonate, bentonite clay, fuller’s earth, cotton seed hulls, wheat flour, soybean flour, pumice, wood flour, walnut shell flour and lignin. A broad range of surface-active agents are advantageously employed in both said liquid and solid compositions, especially those designed to be diluted with carrier before application. These agents, when used, normally comprise from 0.1% to 15% by weight of the formulation. They can be anionic, cationic, non-ionic, or polymeric in character and can be employed as emulsifying agents, wetting agents, suspending agents or for other purposes. Typical surface-active agents include salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; alkylarylsulfonate salts, such as calcium dodecylbenzenesulfonate; alkylphenol-alkylene oxide addition products, such as nonylphenol-C.sub.18 ethoxylate; alcohol-alkylene oxide addition products, such as tridecyl alcohol-C.sub.16 ethoxylate; soaps, such as sodium stearate; alkylnaphthalenesulfonate salts, such as sodium dibutylnaphthalenesulfonate; dialkyl esters of sulfosuccinate salts, such as sodium di(2 ethylhexyl) sulfosuccinate; sorbitol esters, such as sorbitol oleate; quaternary amines, such as lauryl trimethylammonium chloride; polyethylene glycol esters of fatty acids, such as polyethylene glycol stearate; block copolymers of ethylene oxide and propylene oxide; and salts of mono and dialkyl phosphate esters. Other adjuvants commonly utilized in agricultural compositions include crystallisation inhibitors, viscosity modifiers, suspending agents, spray droplet modifiers, pigments, antioxidants, foaming agents, anti-foaming agents, light-blocking agents, compatibilizing agents, antifoam agents, sequestering agents, neutralising agents and buffers, corrosion inhibitors, dyes, odorants, spreading agents, penetration aids, micronutrients, emollients, lubricants, and sticking agents. In addition, further, other biocidal active ingredients or compositions may be combined with the compositions of the invention and used in the methods of the invention and applied simultaneously or sequentially with the compositions of the invention. When applied simultaneously, these further active ingredients may be formulated together with the compositions of the invention or mixed in, for example, the spray tank. These further biocidal 109939 FF (83198) 44 active ingredients may be fungicides, herbicides, insecticides, bactericides, acaricides, nematicides and / or plant growth regulators. Pesticidal agents are referred to herein using their common name are known, for example, from "The Pesticide Manual", 15th Ed., British Crop Protection Council 2009. In addition, the compositions of the invention may also be applied with one or more systemically acquired resistance inducers (“SAR” inducer). SAR inducers are known and described in, for example, United States Patent No. US 6,919,298 and include, for example, salicylates and the commercial SAR inducer acibenzolar- S-methyl. The compounds of formula (I) according to the invention are normally used in the form of agrochemical compositions and can be applied to the crop area or plant to be treated, simultaneously or in succession with further compounds. These further compounds can be e.g., fertilizers or micronutrient donors or other preparations, which influence the growth of plants. They can also be selective herbicides or non-selective herbicides as well as insecticides, fungicides, bactericides, nematicides, molluscicides or mixtures of several of these preparations, if desired together with further carriers, surfactants or application promoting adjuvants customarily employed in the art of formulation. The compounds of formula (I) according to the invention may be used in the form of (fungicidal) compositions for controlling or protecting against phytopathogenic microorganisms, comprising as active ingredient at least one compound of formula (I) or of at least one preferred individual compound as defined herein, in free form or in agrochemical usable salt form, and at least one of the above-mentioned adjuvants. The invention therefore provides a composition, preferably a fungicidal composition, comprising at least one compound of formula (I) according to the invention, an agriculturally acceptable carrier and optionally an adjuvant. An agricultural acceptable carrier is for example a carrier that is suitable for agricultural use. Agricultural carriers are well known in the art. Preferably, said composition may comprise at least one or more pesticidal-active compounds, for example an additional fungicidal active ingredient in addition to the compound of formula (I). The compound of formula (I) according to the invention may be the sole active ingredient of a composition or it may be admixed with one or more additional active ingredients such as a pesticide, fungicide, synergist, herbicide, or plant growth regulator where appropriate. An additional active ingredient may, in some cases, result in unexpected synergistic activities. Examples of suitable additional active ingredients include the following: acycloamino acid fungicides, aliphatic nitrogen fungicides, amide fungicides, anilide fungicides, antibiotic fungicides, aromatic fungicides, arsenical fungicides, aryl phenyl ketone fungicides, benzamide fungicides, benzanilide fungicides, benzimidazole fungicides, benzothiazole fungicides, botanical fungicides, bridged diphenyl fungicides, carbamate fungicides, carbanilate fungicides, conazole fungicides, copper fungicides, dicarboximide fungicides, dinitrophenol fungicides, dithiocarbamate fungicides, dithiolane fungicides, furamide fungicides, furanilide fungicides, hydrazide fungicides, imidazole fungicides, mercury fungicides, morpholine fungicides, organophosphorous 109939 FF (83198) 45 fungicides, organotin fungicides, oxathiin fungicides, oxazole fungicides, phenylsulfamide fungicides, polysulfide fungicides, pyrazole fungicides, pyridine fungicides, pyrimidine fungicides, pyrrole fungicides, quaternary ammonium fungicides, quinoline fungicides, quinone fungicides, quinoxaline fungicides, strobilurin fungicides, sulfonanilide fungicides, thiadiazole fungicides, thiazole fungicides, thiazolidine fungicides, thiocarbamate fungicides, thiophene fungicides, triazine fungicides, triazole fungicides, triazolopyrimidine fungicides, urea fungicides, valinamide fungicides, and zinc fungicides. Examples of suitable additional active ingredients include the following: (4E,10Z)-tetradeca-4,10-dienyl acetate, (7E,9Z)-dodeca-7,9-dien-1-yl acetate, (E)-6-methylhept-2-en-4-ol, (E)-dec-5-en-1-yl acetate with (E)-dec-5-en- 1-ol, (E)-tridec-4-en-1-yl acetate, (S)-bioallethrin, (Z)-dodec-7-en-1-yl acetate, (Z)-hexadec-11-en-1-yl acetate, (Z)-hexadec-11-enal, (Z)-hexadec-13-en-11-yn-1-yl acetate, (Z)-icos-13-en-10-one, (Z)-tetradec-7-en-1-al, (Z)- tetradec-9-en-1-ol, (Z)-tetradec-9-en-1-yl acetate, 1,1-bis(4-chlorophenyl)-2-ethoxyethanol, 1-(2- chlorophenyl)-3,3-dimethyl-2-(1,2,4-triazol-1-ylmethyl)butan-2-ol, 1-(5-bromo-2-pyridyl)-2-(2,4-difluorophenyl)- 1,1-difluoro-3-(1,2,4-triazol-1-yl)propan-2-ol, 1-hydroxy-1H-pyridine-2-thione, 1-methylcyclopropene, 1- naphthaleneacetamide, 1-naphthylacetic acid, 2,2-dichlorovinyl 2-ethylsulfinylethyl methyl phosphate, 2,4-D, 2,4-DB, 2,6-dichloro-N-(4-trifluormethylbenzyl)benzamide, 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate, 2- (2-butoxyethoxy)ethyl piperonylate, 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate, 2- (difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl) pyridine-3-carboxamide, 2-(octylthio)-ethanol, 2-bromo-2- bromomethyl-pentanedinitrile, 2-chlorovinyl diethyl phosphate, 2-imidazolidone, 2-methyl(prop-2- ynyl)aminophenyl methylcarbamate, 2-thiocyanatoethyl laurate, 3-(4-chlorophenyl)-5-methylrhodanine, 3- (difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide, 3-(difluoromethyl)-N-(7-fluoro- 1,1,3,3-tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide, 3-(difluoromethyl)-N-(7-fluoro-1,1,3,3- tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide, 3-chloro-6-methyl-5-phenyl-4-(2,4,6- trifluorophenyl)pyridazine, 3-methyl-1-phenylpyrazol-5-yl dimethyl-carbamate, 3-phenylphenol, 4,5- dichlorodithiol-3-one, 4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyridazine-3-carbonitrile, 4-(2-bromo-4-fluoro- phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol-3-amine, 4-(quinoxalin-2- ylamino)benzenesulfonamide, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]- 3-pyridyl]oxy]benzonitrile, 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridyl)methoxy]pyridazin-3-one, 4-CPA, 4-methyl(prop-2-ynyl)amino-3,5-xylyl methylcarbamate, 4-methylnonan-5-ol with 4-methylnonan-5- one, 4-phenylphenol, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone, 5-amino-1,3,4-thiadiazole-2-thiol, 5- fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine, 5-hydroxy-6-methyl-4-(((E)-pyridin-3-ylmethylene)amino)-4,5- dihydro-1,2,4-triazin-3(2H)-one, 5-methyl-6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid, 8-hydroxyquinoline sulfate, 11-ethyl-10,12-dioxo-2,5,8-trithia-4,11-diazatricyclo[7.3.0.03,7]dodeca-1(9),3,6-triene-6-carbonitrile, 14-methyloctadec-1-ene, [(9Z,11E)-tetradeca-9,11-dienyl] acetate, [(Z)-dodec-9-enyl] acetate, abamectin, acephate, acequinocyl, acetamiprid, acethion, acetoprole, acibenzolar, acibenzolar-S-methyl, acrinathrin, Adoxophyes orana GV, Agrobacterium radiobacter, alanycarb, albendazole, aldicarb, allethrin, allosamidin, allyl alcohol, allyxycarb, alpha-ecdysone, alpha-multistriatin, Amblyseius spp., ametoctradin, amidithion, amidoflumet, amidothioate, aminocarb, amisulbrom, amiton, amiton hydrogen oxalate, amitraz, anabasine, Anagrapha falcifera NPV, Anagrus atomus, ancymidol, anilazine, anisiflupurin, anthraquinone, antu, Aphelinus 109939 FF (83198) 46 abdominalis, Aphidius colemani, Aphidoletes aphidimyza, athidathion, aureofungin, Autographa californica NPV, avermectin B1a, azaconazole, azadirachtin A, azafenidin, azamethiphos, azinphos-ethyl, azinphos- methyl, azithiram, azoxystrobin, Bacillus sphaericus (Neide), Bacillus thuringiensis, Bacillus thuringiensis delta endotoxin, Bacillus thuringiensis ssp. aizawai, baculovirus, barthrin, Beauveria brongniartii, benalaxyl, benalaxyl-M, benazepril, benclothiaz, benfuracarb, benomyl, bensultap, benthiavalicarb, benzalkonium chloride, benzamorf, benzothiostrobin, benzovindiflupyr, beta-cyfluthrin, beta-cypermethrin, bethoxazin, bifenazate, bifenthrin, binapacryl, bioallethrin, bioethanomethrin, biopermethrin, bioresmethrin, bisthiosemi, bistrifluron, bitertanol, bixafen, blasticidin-S, borax, bordeaux mixture, boscalid, brodifacoum, brofenvalerate, brofluthrinate, bromadiolone, bromfenvinfos, bromophos, bromophos-ethyl, bromuconazole, bufencarb, bupirimate, buprofezin, buserelin, busulfan, but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl- methylene]amino]oxymethyl]-2-pyridyl]carbamate, butacarb, butathiofos, butocarboxim, butonate, butopyronoxyl, butoxy(polypropylene glycol), butoxycarboxim, butylamine, cadusafos, calciferol, calcium phosphate, calcium polysulfide, cambendazole, captafol, captan, carbanolate, carbaryl, carbendazim, carbendazim hydrochloride, carbofuran, carbosulfan, carboxin, carprofen, carpropamid, cartap, cartap hydrochloride, cefalexin, cefovecin, cefquinome, ceftiour, cestex, cevadine, chinomethionat, chitosan, chlobenthiazone, chloralose, chlorantraniliprole, chlorbenside, chlordimeform, chlorethephon, chlorethoxyfos, chlorfenapyr, chlorfenazole, chlorfentazine, chlorfenvinphos, chlorfluazuron, chlormephos, chlormequat, chlorodimeform hydrochloride, chloroinconazide, chloromebuform, chloromethiuron, chloroneb, chlorothalonil, chlorphoxim, chlorprazophos, chlorpyrifos, chlorpyrifos-methyl, chlortetracycline, chlorthiophos, chlozolinate, cholecalciferol, chromafenozide, Chrysoperla carnea, cinerin, cinerin I, cinerin II, cis-jasmone, cis-resmethrin, cismethrin, clenbuterol, climbazole, cloethocarb, clofencet, clorsulon, clothianidin, clozylacon (acetamide), codlelure, copper acetate, copper hydroxide, copper naphthenate, copper octanoate, copper oleate, copper oxide, copper oxychloride, copper silicate, copper sulfate, copper(II) carbonate, coumachlor, coumafene, coumafuryl, Coumatetralyl, coumethoxystrobin (jiaxiangjunzhi), coumithoate, coumoxystrobin, cryolite, Cryptolaemus montrouzieri, cuelure, cufraneb, cuprous(I) oxide, cyanofenphos, cyanthoate, cyazofamid, cybutryne, cyclafuramid, cyclethrin, cyclobutrifluram, Cydia pomonella GV, cyenopyrafen, cyflufenamid, cyflumetofen, cyfluthrin, cyhalothrin, cymiazole, cymoxanil, cypermethrin (alphametrin), cyphenothrin, cyproconazole, cyprodinil, cyprodinil, cyromazine, cytokinins, D-tetramethrin, Dacnusa sibirica, DAEP, dazomet, DCPM, debacarb, decarbofuran, deltamethrin, demephion-O, demephion-S, demeton-O, demeton- S, demeton-S-methyl, demeton-S-methylsulphon, diafenthiuron, dialifos, diazinon, dibutyl adipate, dibutyl phthalate, dibutyl succinate, dicapthon, dichlobentiazox, dichlofluanid, dichlone, dichlorprop, dichlorvos, dichlozoline, diclocymet, diclomezine, dicloran, dicofol, dicresyl, dicrotophos, dicyclanil, dicyclopentadiene, diethofencarb, diethyltoluamide, difenacoum, difenoconazole, difenzoquat, difethialone, diflovidazin, diflubenzuron, diflumetorim, Diglyphus isaea, dimatif, dimefluthrin, dimetan, dimethachlon, dimethipin, dimethirimol, dimethoate, dimethomorph, dimethrin, dimethyl disulfide, dimethyl phthalate, dimetilan, dimoxystrobin, dinactin, diniconazole, diniconazole-M, dinobuton, dinocap, dinocton, dinoseb, dinotefuran, diofenolan, dioxabenzofos, diphenylamine, dipyrithione, disparlure, disulfiram, disulfoton, ditalimfos, dithianon, dithicrofos, dithiocarbamate, dodec-8-en-1-yl acetate, dodemorph, dodicin, dodine, dofenapyn, dominicalure, 109939 FF (83198) 47 doramectin, drazoxolon, DSP, ecdysterone, edifenphos, emamectin benzoate, EMPC, empenthrin, Encarsia formosa, endosulfan, endothal, endothion, enestroburin (enoxastrobin), enrofloxacin, entomopathogenic bacteria, entomopathogenic fungi, entomopathogenic virus, EPBP, epoxiconazole, eprinomectin, Eretmocerus eremicus, esfenvalerate, etaconazole, ethaboxam, ethiofencarb, ethion, ethiprole, ethirimol, ethoate-methyl, ethoprophos, ethoxyquin, ethyl 4-methyloctanoate, ethyl formate, ethyl hexanediol, etofenprox, etoxazole, etridiazole, etrimfos, eugenol, eurax, EXD, exo-brevicomin, famoxadone, famphur, farnesol with nerolidol, febantel, fenamidone, fenaminstrobin, fenamiphos, fenarimol, fenazaquin, fenbendazole, fenbuconazole, fenbutatin oxide, feneptamidoquin, fenethacarb, fenfluthrin, fenfuram, fenhexamid, fenitrothion, fenobucarb, fenopyramid, fenothiocarb, fenoxacrim, fenoxanil, fenoxycarb, fenpiclonil, fenpicoxamid, fenpirithrin, fenpropathrin, fenpropidin, fenpropimorph, fenpyrazamine, fenpyroximate, fensulfothion, fenthion, fenthion- ethyl, fentin, fentin acetate, fentin chloride, fentin hydroxide, fenvalerate, ferbam, ferimzone, ferric phosphate, fipronil, flocoumafen, flonicamid, florfenicol, florylpicoxamid, fluacrypyrim, fluazinam, fluazuron, flubendazole, flubendiamide, flubeneteram, flubenzimin, flucycloxuron, flucycloxuron, flucythrinate, fludioxonil, fluenetil, flufenerim, flufenoxuron, flufenoxystrobin, flufenprox, fluindapyr, flumetralin, flumetylsulforim, flumorph, fluopicolide, fluopimomide, fluopyram, fluoroimide, fluoxapiprolin, fluoxastrobin, fluoxytioconazole, flupyrazofos, fluquinconazole, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, fluxapyroxad, folpet, fonofos, forchlorfenuron, formaldehyde, formetanate, formetanate hydrochloride, formothion, formparanate, fosetyl, fosetyl-aluminium, fosmethilan, fosthiazate, fosthietan, frontalin, fuberidazole, furalaxyl, furametpyr, furathiocarb, furethrin, furfural, gibberellic acid, glyodin, glyphosate, grandlure I, grandlure II, grandlure III, grandlure IV, guazatine triacetate, halfenprox, halofenozide, hemel, heptenophos, Heterorhabditis bacteriophora and H. megidis, hexaconazole, hexadecyl cyclopropanecarboxylate, hexaflumuron, hexalure, hexamide, hexythiazox, Hippodamia convergens, huanjunzuo (rac-(1S,2S)-1-(4-chlorophenyl)-2-(1,2,4-triazol- 1-yl)cycloheptanol), hydramethylnon, hydrated lime (calcium hydroxide), hymexazol, hyquincarb, icaridin, imanin (hypericin), imazalil, imazalil sulfate, imibenconazole, imidacloprid, iminoctadine, indoxacarb, inpyrfluxam, iodocarb, ipconazole, ipfentrifluconazole, ipflufenoquin, iprobenfos (IBP), iprodione, iprovalicarb, ipsdienol, ipsenol, IPSP, isamidofos, isazofos, isocarbophos, isofetamid, isoflucypram, isolan, isoprocarb, isoprothiolane, isopyrazam, isothioate, isotianil, isoxathion, ivermectin, japonilure, jasmolin I, jasmolin II, juvenile hormone I, juvenile hormone II, juvenile hormone III, kadethrin, kanamycin, kasugamycin, kasugamycin hydrochloride hydrate, kinetin, kinoprene, kresoxim-methyl, kurstaki, lambda-cyhalothrin, Leptomastix dactylopii, leptophos, levamisole, lineatin, lirimfos, looplure, lufenuron, lvbenmixianan, lythidathion, m-cumenyl methylcarbamate, Macrolophus caliginosus, magnesium phosphide, malathion, maleic hydrazide, malonoben, Mamestra brassicae NPV, mancopper, mancozeb, mandestrobin, mandipropamid, maneb, mazidox, mebendazole, mecarbam, mecarphon, medlure, mefentrifluconazole, megatomoic acid, meloxicam, menazon, mepanipyrim, meperfluthrin, mephosfolan, mepiquat, mepronil, meptyldinocap, mesulfenfos, metaflumizone, metalaxyl, metalaxyl-M, metaldehyde, metam, metam-potassium, metam-sodium, Metaphycus helvolus, Metarhizium anisopliae var. acridum, Metarhizium anisopliae var. anisopliae, metarylpicoxamid, metconazole, methacrifos, methamidophos, methasulfocarb, methidathion, methiocarb, methiotepa, methocrotophos, methomyl, methoprene, methoquin-butyl, methothrin, methoxyfenozide, methyl apholate, methyl eugenol, 109939 FF (83198) 48 methyl iodide, methyl neodecanamide, metiram, metofluthrin, metolcarb, metominostrobin, metoxadiazone, metrafenone, metyltetraprole, mevinphos, mexacarbate, MGK 264, milbemycin, milbemycin oxime, monocrotophos, morantel tartrate, morzid, moxidectin, muscalure, myclobutanil, myclozolin, Myrothecium verrucaria composition, N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4- carboxamide, N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-[(2-isopropylphenyl)methyl]-1-methyl-pyrazole-4- carboxamide, nabam, naled, NC-170, nemadectin, Neodiprion sertifer NPV and N. lecontei NPV, niclosamide- olamine, nicotine, nicotine sulfate, nikkomycins, nitenpyram, nithiazine, nitrapyrin, nitrilacarb, nitrothal- isopropyl, norbormide, nornicotine, novaluron, noviflumuron, nuarimol, O,O,O',O'-tetrapropyl dithiopyrophosphate, octadeca-2,13-dien-1-yl acetate, octadeca-2,13-dien-1-yl acetate, octhilinone, ofurace, oleic acid, omethoate, orfralure, Orius spp., orysastrobin, osthol, ostramone, oxadixyl, oxamate, oxamyl, oxantel pamoate, oxasulfuron, oxathiapiprolin, oxfendazole, oxibendazole, oxine copper, oxolinic acid, oxpoconazole, oxycarboxin, oxydemeton-methyl, oxydeprofos, oxydisulfoton, oxytetracycline, oxytetracycline dihydrate, paclobutrazol, Paecilomyces fumosoroseus, paraoxon, parathion, parathion-methyl, parbendazole, pefurazoate, penconazole, pencycuron, penethamate, penflufen, penthiopyrad, permethrin, petroleum oils, PH 60-38, phenamacril, phenthoate, phorate, phosacetim, phosalone, phosfolan, phosglycin, phosmet, phosnichlor, phosphamidon, phosphocarb, phosphonic acid, phosphorus, phoxim, phoxim-methyl, phthalide, Phytoseiulus persimilis, picarbutrazox, picoxystrobin, pimobendan, pindone, piperalin, piperonyl butoxide, piprotal, pirimetaphos, pirimicarb, pirimiphos-methyl, polycarbamate, polynactin, polyoxin B, polyoxin d, potassium ethylxanthate, potassium hydroxyquinoline sulfate, praziquantel, precocene I, precocene II, precocene III, primidophos, probenazole, prochloraz, procymidone, profenofos, profluthrin, prohexadione, prohexadione-calcium, promacyl, promecarb, propamidine, propamocarb, propaphos, propargite, propetamphos, propiconazole, propineb, propionic acid, propoxur, propyl isomer, proquinazid, prothidathion, prothioconazole, prothiofos, prothoate, protrifenbute, pydiflumetofen, pymetrozine, pyraclofos, pyraclostrobin, pyrafluprole, pyrametostrobin, pyrantel pamoate, pyraoxystrobin, pyrapropoyne, pyraziflumid, pyrazophos, pyrazoxone, pyresmethrin, pyrethrin I, pyrethrin II, pyrethrins (natural products), pyrethroids (natural products), pyribencarb, pyridaben, pyridachlometyl, pyridalyl, pyridaphenthion, pyridin-4-amine, pyrifenox, pyrifluquinazon, pyrimethanil, pyrimidifen, pyrimorph, pyriofenone, pyriprole, pyriproxyfen, pyrisoxazole, pyroquilon, quassia, quinalphos, quinalphos-methyl, quinoclamine, quinofumelin, quinonamid, quinothion, quinoxyfen, quintozene, R-1492, R-metalaxyl, Reynoutria sachalinensis extract, ribavirin, rotenone, ryanodine (ryania), sabadilla, schradan, scilliroside, seboctylamine, sedaxane, selamectin, sesamex, sesamolin, siglure, silafluofen, silthiofam, simeconazole, sodium tetrathiocarbonate, sophamide, sordidin, spinetoram, spinosad, spirodiclofen, spiromesifen, spirotetramat, spiroxamine, Steinernema bibionis, Steinernema carpocapsae, Steinernema feltiae, Steinernema glaseri, Steinernema riobrave, Steinernema riobravis, Steinernema scapterisci, Steinernema spp., streptomycin, streptomycin sesquisulfate, sulcatol, sulcofuron, sulfiram, sulfur, sulprofos, tar oils, tau-fluvalinate, TCMTB, TDE, tebuconazole, tebufenozide, tebufenpyrad, tebufloquin, tebupirimfos, tecnazene, teflubenzuron, tefluthrin, temephos, terallethrin, terbam, terbufos, tetrachlorvinphos, tetraconazole, tetradec-11-en-1-yl acetate, tetradifon, tetramethrin, tetramethylfluthrin, tetranactin, thiabendazole, thiacloprid, thiadiazole copper, thiamethoxam, thiapronil, thicrofos, thicyofen, thidiazuron, 109939 FF (83198) 49 thifluzamide, thiocarboxime, thiocyclam, thiocyclam hydrogen oxalate, thiodicarb, thiofanox, thiometon, thiophanate, thiophanate-methyl, thioquinox, thiosultap, thiosultap-disodium, thiram, thuringiensin, tiadinil, tiamulin, tioxymid, tolclofos-methyl, tolfenpyrad, tolprocarb, tolylfluanid, tralomethrin, transpermethrin, tretamine, triadimefon, triadimenol, triarathene, triazamate, triazophos, triazoxide, tribufos, trichlorfon, trichlormetaphos-3, trichloronat, Trichogramma spp., triclabendazole, triclopyricarb, tricyclazole, tridemorph, trifenmorph, trifloxystrobin, triflumizole, triflumuron, triforine, trimedlure, trimedlure A, trimedlure B1, trimedlure B2, trimedlure C, trimethacarb, trinactin, trinexapac, trinexapac-ethyl, triprene, triticonazole, trunc-call, tulathromycin, Typhlodromus occidentalis, uniconazole, uredepa, validamycin, valifenalate, vamidothion, vaniliprole, veratridine, veratrine, verbutin, Verticillium lecanii, vinclozolin, XMC, xylenols, zeatin, zeta- cypermethrin, zhongshengmycin, zinc naphthenate, zinc thiazole, zineb, ziram, zolaprofos, zoxamide; 2- (difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675), methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1- methyl-2-(1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate (this compound may be prepared from the methods described in WO 2019 / 093522), methyl (2R)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4- triazol-1-yl)propanoate (this compound may be prepared from the methods described in WO 2019 / 093522), 5- [5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), aminopyrifen (this compound may be prepared from the methods describe WO 2014 / 006945), dipymetitrone (this compound may be prepared from the methods described in WO 2011 / 138281), 1-[6-(difluoromethyl)-5-methyl-3-pyridyl]-4,4- difluoro-3,3-dimethyl-isoquinoline (this compound may be prepared from the methods described in WO 2017 / 016915), 1-[4-(difluoromethoxy)-2-methyl-phenyl]-2-(1,2,4-triazol-1-yl)-1-[1- (trifluoromethyl)cyclopropyl]ethanol (this compound may be prepared from the methods described in WO 2021 / 249800), 1-[2-chloro-4-(difluoromethoxy)phenyl]-2-(1,2,4-triazol-1-yl)-1-[1- (trifluoromethyl)cyclopropyl]ethanol (this compound may be prepared from the methods described in WO 2021 / 249800), 1-(5,6-dimethyl-3-pyridyl)-4,4-difluoro-3,3-dimethyl-isoquinoline (this compound may be prepared from the methods described in WO 2017 / 016915), N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]benzenecarbothioamide (this compound may be prepared from the methods described in WO 2015 / 185485), 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide (this compound may be prepared from the methods described in WO 2017 / 178245), flufenoxadiazam, N-methyl-4-[5-(trifluoromethyl)- 1,2,4-oxadiazol-3-yl]benzamide (this compound may be prepared from the methods described in WO 2015 / 185485), (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (this compound may be prepared from the methods described in WO 2018 / 153707), (Z,2E)-5-[1-(4- chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (this compound may be prepared from the methods described in WO 2013 / 092224), methyl (2E)-2-methoxyimino-2-[3-methyl-2-[[(E)-1-[4- (trifluoromethyl)-2-pyridyl]ethylideneamino]oxymethyl]phenyl]acetate (this compound may be prepared from the methods described in WO 2022 / 033906), (2E)-2-methoxyimino-N-methyl-2-[3-methyl-2-[[(E)-1-[4- (trifluoromethyl)-2-pyridyl]ethylideneamino]oxymethyl]phenyl]acetamide (this compound may be prepared from the methods described in WO 2022 / 033906), (2E)-2-[2-[[(E)-[3-(4-fluorophenyl)-1-methyl-prop-2- 109939 FF (83198) 50 ynylidene]amino]oxymethyl]-3-methyl-phenyl]-2-methoxyimino-N-methyl-acetamide (this compound may be prepared from the methods described in WO 2021 / 249928), methyl (2E)-2-[2-[[(E)-[3-(4-fluorophenyl)-1- methyl-prop-2-ynylidene]amino]oxymethyl]-3-methyl-phenyl]-2-methoxyimino-acetate (this compound may be prepared from the methods described in WO 2021 / 249928), 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluoro- phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290), 3-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxy-propyl]imidazole-4- carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290), 2-[6-(4- bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179), 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1- (1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179), 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), 5-[5-(difluoromethyl)-1,3,4- oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), N-[1-(2-fluorophenyl)cyclopropyl]-5-[5-(trifluoromethyl)-1,3,4- oxadiazol-2-yl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), 2-(difluoromethyl)-5-[2-[1- (2,6-difluorophenyl)cyclopropoxy]pyrimidin-5-yl]-1,3,4-oxadiazole (this compound may be prepared from the methods described in WO 2021 / 255093), 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2- fluorophenyl)cyclopropyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093), 5-[(4-bromo-2-methyl-phenyl)methyl]-3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl-pyridazin- 4-yl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2021 / 255070), 3-[3-(3-cyclopropyl-2-fluoro-phenoxy)-6-methyl-pyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]- 5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2021 / 255070), N-(2,2,2-trifluoroethyl)-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]oxazole-4- carboxamide (this compound may be prepared from the methods described in WO 2022 / 133114), ethyl 1-[[4- [5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenoxy]methyl]pyrazole-4-carboxylate (this compound may be prepared from the methods described in WO 2022 / 133114), ethyl 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1- enoxy]phenyl]methyl]pyrazole-4-carboxylate (this compound may be prepared from the methods described in WO 2020 / 056090 and WO 2021 / 183707), ethyl 1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2- yl]methoxy]phenyl]methyl]pyrazole-4-carboxylate (this compound may be prepared from the methods described in WO 2020 / 056090 and WO 2021 / 183707), methyl N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2- methyl-phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012), methyl N-[[5-[1-(2,6-difluoro-4-isopropyl-phenyl)pyrazol-3-yl]-2-methyl- phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012), methyl N-[[5-[1-(4-cyclopropyl-2,6-difluoro-phenyl)pyrazol-3-yl]-2-methyl-phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012), methyl 2-[2-chloro-4-(4- chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4-triazol-1-yl)propanoate (this compound may be prepared from the 109939 FF (83198) 51 methods described in WO 2019 / 093522), 4,4,5-trifluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline, 5-fluoro- 3,3,4,4-tetramethyl-1-(3-quinolyl)isoquinoline, 2-methoxy-N-[methoxy-[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]-2-thienyl]methyl]acetamide (this compound may be prepared from the methods described in WO 2020 / 256113), N-[methoxy-[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]-2-methyl- propanamide (this compound may be prepared from the methods described in WO 2020 / 256113), N-[methoxy- [5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]butanamide (this compound may be prepared from the methods described in WO 2020 / 256113), 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4- yl]pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675), 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675), 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3- carboxamide, (5R)-3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl-pyridazin-4-yl]-5-[(2-chloro-4-methyl- phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070), (5S)-3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl-pyridazin-4-yl]-5-[(2- chloro-4-methyl-phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070), 3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl- pyridazin-4-yl]-5-[(2-chloro-4-methyl-phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070), methyl (Z)-3-methoxy-2-(2- methyl-5-phenyl-phenoxy)prop-2-enoate (this compound may be prepared from methods as described in WO01 / 00562, JP2023078251); 2-[(2,6-difluoro-4-pyridyl)-(2-methylpropanoyl)amino]-N-(2,2-dimethyl cyclobutyl)-5-methyl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[(2,6-difluoro-4-pyridyl)-(tetrahydropyran-4-carbonyl)amino]-N-(2,2- dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[cyano-(2,6-difluoro-4-pyridyl)amino]-5-methyl-N-spiro[3.4]octan- 3-yl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109509A1); 2-[cyano-(2,6- difluoro-4-pyridyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109509A1); 2-[(2,6-difluoro-4-pyridyl)-(2- methoxyacetyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[acetyl-(2,6-difluoro-4- pyridyl)amino]-5-methyl-N-spiro[3.4]octan-3-yl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4- oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide (this compound may be prepared from the methods described in WO 2017 / 055473); methyl (Z)-2-(5-cyclopentyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate (this 109939 FF (83198) 52 compound may be prepared from the methods described in WO2020 / 193387); methyl (Z)-2-(5-cyclohexyl-2- methyl-phenoxy)-3-methoxy-prop-2-enoate (this compound may be prepared from the methods described in WO2020 / 193387); N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (this compound may be prepared from the methods described in WO2017 / 153380); N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8- fluoroquinoline-3-carboxamide (this compound may be prepared from the methods described in WO2017 / 153380); 2-[(2,6-difluoro-4-pyridyl)-(oxetane-3-carbonyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl- thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[acetyl-(2,6-difluoro-4-pyridyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); N,2-dimethoxy-N-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, or the (R) or (S) enantiomer or mixtures thereof (this compound may be prepared from the methods described in WO 2017 / 055473). The compounds of the invention may also be used in combination with anthelmintic agents. Such anthelmintic agents include, compounds selected from the macrocyclic lactone class of compounds such as ivermectin, avermectin, abamectin, emamectin, eprinomectin, doramectin, selamectin, moxidectin, nemadectin and milbemycin derivatives as described in EP0357460, EP0444964 and EP0594291. Additional anthelmintic agents include semisynthetic and biosynthetic avermectin / milbemycin derivatives such as those described in US5,015,630, WO9415944 and WO9522552. Additional anthelmintic agents include the benzimidazoles such as albendazole, cambendazole, fenbendazole, flubendazole, mebendazole, oxfendazole, oxibendazole, parbendazole, and other members of the class. Additional anthelmintic agents include imidazothiazoles and tetrahydropyrimidines such as tetramisole, levamisole, pyrantel pamoate, oxantel or morantel. Additional anthelmintic agents include flukicides, such as triclabendazole and clorsulon and the cestocides, such as praziquantel and epsiprantel. The compounds of the invention may be used in combination with derivatives and analogues of the paraherquamide / marcfortine class of anthelmintic agents, as well as the antiparasitic oxazolines such as those disclosed in US5478855, US4639771 and DE-19520936. The compounds of the invention may be used in combination with derivatives and analogues of the general class of dioxomorpholine antiparasitic agents as described in WO9615121 and also with anthelmintic active cyclic depsipeptides such as those described in WO9611945, WO9319053, WO9325543, EP0626375, EP0382173, WO9419334, EP0382173, and EP0503538. The compounds of the invention may be used in combination with other ectoparasiticides; for example, fipronil; pyrethroids; organophosphates; insect growth regulators such as lufenuron; ecdysone agonists such as tebufenozide and the like; neonicotinoids such as imidacloprid and the like. The compounds of the invention may be used in combination with terpene alkaloids, for example those described in WO95 / 19363 or WO04 / 72086, particularly the compounds disclosed therein. 109939 FF (83198) 53 Other examples of such biologically active compounds that the compounds of the invention may be used in combination with include but are not restricted to the following: Organophosphates: acephate, azamethiphos, azinphos-ethyl, azinphos- methyl, bromophos, bromophos-ethyl, cadusafos, chlorethoxyphos, chlorpyrifos, chlorfenvinphos, chlormephos, demeton, demeton-S-methyl, demeton-S-methyl sulfone, dialifos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, ethoprophos, etrimfos, famphur, fenamiphos, fenitrothion, fensulfothion, fenthion, flupyrazofos, fonofos, formothion, fosthiazate, heptenophos, isazophos, isothioate, isoxathion, malathion, methacriphos, methamidophos, methidathion, methyl- parathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, paraoxon, parathion, parathion-methyl, phenthoate, phosalone, phosfolan, phosphocarb, phosmet, phosphamidon, phorate, phoxim, pirimiphos, pirimiphos- methyl, profenofos, propaphos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulprophos, temephos, terbufos, tebupirimfos, tetrachlorvinphos, thimeton, triazophos, trichlorfon, vamidothion. Carbamates: alanycarb, aldicarb, 2-sec-butylphenyl methylcarbamate, benfuracarb, carbaryl, carbofuran, carbosulfan, cloethocarb, ethiofencarb, fenoxycarb, fenthiocarb, furathiocarb, HCN-801, isoprocarb, indoxacarb, methiocarb, methomyl, 5-methyl-m-cumenylbutyryl(methyl)carbamate, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, UC-51717. Pyrethroids: acrinathin, allethrin, alphametrin, 5-benzyl-3-furylmethyl (E)-(1R)-cis-2,2-dimethyl-3-(2-oxothiolan- 3-ylidenemethyl)cyclopropanecarboxylate, bifenthrin, beta-cyfluthrin, cyfluthrin, a-cypermethrin, beta- cypermethrin, bioallethrin, bioallethrin((S)-cyclopentylisomer), bioresmethrin, bifenthrin, NCI-85193, cycloprothrin, cyhalothrin, cythithrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenfluthrin, fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate (D isomer), imiprothrin, cyhalothrin, lambda-cyhalothrin, permethrin, phenothrin, prallethrin, pyrethrins (natural products), resmethrin, tetramethrin, transfluthrin, theta-cypermethrin, silafluofen, t-fluvalinate, tefluthrin, tralomethrin, Zeta-cypermethrin. Arthropod growth regulators: a) chitin synthesis inhibitors: benzoylureas: chlorfluazuron, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron, buprofezin, diofenolan, hexythiazox, etoxazole, chlorfentazine; b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide; c) juvenoids: pyriproxyfen, methoprene (including S-methoprene), fenoxycarb; d) lipid biosynthesis inhibitors: spirodiclofen. Other antiparasitics: acequinocyl, amitraz, AKD-1022, ANS-118, azadirachtin, Bacillus thuringiensis, bensultap, bifenazate, binapacryl, bromopropylate, BTG-504, BTG-505, camphechlor, cartap, chlorobenzilate, chlordimeform, chlorfenapyr, chromafenozide, clothianidine, cyromazine, diacloden, diafenthiuron, DBI-3204, dinactin, dihydroxymethyldihydroxypyrrolidine, dinobuton, dinocap, endosulfan, ethiprole, etofenprox, fenazaquin, flumite, MTI- 800, fenpyroximate, fluacrypyrim, flubenzimine, flubrocythrinate, flufenzine, flufenprox, fluproxyfen, halofenprox, hydramethylnon, IKI-220, kanemite, NC-196, neem guard, nidinorterfuran, nitenpyram, SD-35651, WL-108477, pirydaryl, propargite, protrifenbute, pymethrozine, pyridaben, pyrimidifen, NC-1111, R-195, RH-0345, RH-2485, RYI-210, S-1283, S-1833, SI-8601, silafluofen, silomadine, spinosad, 109939 FF (83198) 54 tebufenpyrad, tetradifon, tetranactin, thiacloprid, thiocyclam, thiamethoxam, tolfenpyrad, triazamate, triethoxyspinosyn, trinactin, verbutin, vertalec, YI-5301. Biological agents: Bacillus thuringiensis ssp. aizawai, kurstaki, Bacillus thuringiensis delta endotoxin, baculovirus, entomopathogenic bacteria, virus, and fungi. Bactericides: chlortetracycline, oxytetracycline, streptomycin. Other biological agents: enrofloxacin, febantel, penethamate, moloxicam, cefalexin, kanamycin, pimobendan, clenbuterol, omeprazole, tiamulin, benazepril, pyriprole, cefquinome, florfenicol, buserelin, cefovecin, tulathromycin, ceftiofur, carprofen, metaflumizone, praziqantel, triclabendazole. The following mixtures of the compounds of formula (I) with active ingredients are preferred. The abbreviation “TX” means one compound selected from compounds of formula (I), or compounds selected from compounds listed in Tables C-1 to C-41, or compounds listed in Table P (below), and a compound selected from the group of substances consisting of (4E,10Z)-tetradeca-4,10-dienyl acetate + TX; (7E,9Z)-dodeca-7,9-dien-1-yl acetate + TX; (E)-6-methylhept-2-en-4-ol + TX; (E)-dec-5-en-1-yl acetate with (E)-dec-5-en-1-ol + TX; (E)-tridec-4-en- 1-yl acetate + TX; (S)-bioallethrin + TX; (Z)-dodec-7-en-1-yl acetate + TX; (Z)-hexadec-11-en-1-yl acetate + TX; (Z)-hexadec-11-enal + TX; (Z)-hexadec-13-en-11-yn-1-yl acetate + TX; (Z)-icos-13-en-10-one + TX; (Z)- tetradec-7-en-1-al + TX; (Z)-tetradec-9-en-1-ol + TX; (Z)-tetradec-9-en-1-yl acetate + TX; 1,1-bis(4- chlorophenyl)-2-ethoxyethanol + TX; 1-(2-chlorophenyl)-3,3-dimethyl-2-(1,2,4-triazol-1-ylmethyl)butan-2-ol + TX; 1-(5-bromo-2-pyridyl)-2-(2,4-difluorophenyl)-1,1-difluoro-3-(1,2,4-triazol-1-yl)propan-2-ol + TX; 1-hydroxy- 1H-pyridine-2-thione + TX; 1-methylcyclopropene + TX; 1-naphthaleneacetamide + TX; 1-naphthylacetic acid + TX; 2,2-dichlorovinyl 2-ethylsulfinylethyl methyl phosphate + TX; 2,4-D + TX; 2,4-DB + TX; 2,6-dichloro-N-(4- trifluormethylbenzyl)benzamide + TX; 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate + TX; 2-(2- butoxyethoxy)ethyl piperonylate + TX; 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate + TX; 2- (difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl) pyridine-3-carboxamide + TX; 2-(octylthio)-ethanol + TX; 2- bromo-2-bromomethyl-pentanedinitrile + TX; 2-chlorovinyl diethyl phosphate + TX; 2-imidazolidone + TX; 2- methyl(prop-2-ynyl)aminophenyl methylcarbamate + TX; 2-thiocyanatoethyl laurate + TX; 3-(4-chlorophenyl)- 5-methylrhodanine + TX; 3-(difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide + TX; 3-(difluoromethyl)-N-(7-fluoro-1,1,3,3-tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide + TX; 3- (difluoromethyl)-N-(7-fluoro-1,1,3,3-tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide + TX; 3-chloro- 6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine + TX; 3-methyl-1-phenylpyrazol-5-yl dimethyl-carbamate + TX; 3-phenylphenol + TX; 4,5-dichlorodithiol-3-one + TX; 4-(2,6-difluorophenyl)-6-methyl-5-phenyl- pyridazine-3-carbonitrile + TX; 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol- 3-amine + TX; 4-(quinoxalin-2-ylamino)benzenesulfonamide + TX; 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2- hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile + TX; 4-chloro-2-(2-chloro-2-methyl-propyl)-5- [(6-iodo-3-pyridyl)methoxy]pyridazin-3-one + TX; 4-CPA + TX; 4-methyl(prop-2-ynyl)amino-3,5-xylyl methylcarbamate + TX; 4-methylnonan-5-ol with 4-methylnonan-5-one + TX; 4-phenylphenol + TX; 5-(1,3- benzodioxol-5-yl)-3-hexylcyclohex-2-enone + TX; 5-amino-1,3,4-thiadiazole-2-thiol + TX; 5-fluoro-2-(p- tolylmethoxy)pyrimidin-4-amine + TX; 5-hydroxy-6-methyl-4-(((E)-pyridin-3-ylmethylene)amino)-4,5-dihydro- 109939 FF (83198) 55 1,2,4-triazin-3(2H)-one + TX; 5-methyl-6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid + TX; 8-hydroxyquinoline sulfate + TX; 11-ethyl-10,12-dioxo-2,5,8-trithia-4,11-diazatricyclo[7.3.0.03,7]dodeca-1(9),3,6-triene-6- carbonitrile + TX; 14-methyloctadec-1-ene + TX; [(9Z,11E)-tetradeca-9,11-dienyl] acetate + TX; [(Z)-dodec-9- enyl] acetate + TX; abamectin + TX; acephate + TX; acequinocyl + TX; acetamiprid + TX; acethion + TX; acetoprole + TX; acibenzolar + TX; acibenzolar-S-methyl + TX; acrinathrin + TX; Adoxophyes orana GV + TX; Agrobacterium radiobacter + TX; alanycarb + TX; albendazole + TX; aldicarb + TX; allethrin + TX; allosamidin + TX; allyl alcohol + TX; allyxycarb + TX; alpha-ecdysone + TX; alpha-multistriatin + TX; Amblyseius spp. + TX; ametoctradin + TX; amidithion + TX; amidoflumet + TX; amidothioate + TX; aminocarb + TX; amisulbrom + TX; amiton + TX; amiton hydrogen oxalate + TX; amitraz + TX; anabasine + TX; Anagrapha falcifera NPV + TX; Anagrus atomus + TX; ancymidol + TX; anilazine + TX; anisiflupurin + TX; anthraquinone + TX; antu + TX; Aphelinus abdominalis + TX; Aphidius colemani + TX; Aphidoletes aphidimyza + TX; athidathion + TX; aureofungin + TX; Autographa californica NPV + TX; avermectin B1a + TX; azaconazole + TX; azadirachtin A + TX; azafenidin + TX; azamethiphos + TX; azinphos-ethyl + TX; azinphos-methyl + TX; azithiram + TX; azoxystrobin + TX; Bacillus sphaericus (Neide) + TX; Bacillus thuringiensis + TX; Bacillus thuringiensis delta endotoxin + TX; Bacillus thuringiensis ssp. aizawai + TX; baculovirus + TX; barthrin + TX; Beauveria brongniartii + TX; benalaxyl + TX; benalaxyl-M + TX; benazepril + TX; benclothiaz + TX; benfuracarb + TX; benomyl + TX; bensultap + TX; benthiavalicarb + TX; benzalkonium chloride + TX; benzamorf + TX; benzothiostrobin + TX; benzovindiflupyr + TX; beta-cyfluthrin + TX; beta-cypermethrin + TX; bethoxazin + TX; bifenazate + TX; bifenthrin + TX; binapacryl + TX; bioallethrin + TX; bioethanomethrin + TX; biopermethrin + TX; bioresmethrin + TX; bisthiosemi + TX; bistrifluron + TX; bitertanol + TX; bixafen + TX; blasticidin-S + TX; borax + TX; bordeaux mixture + TX; boscalid + TX; brodifacoum + TX; brofenvalerate + TX; brofluthrinate + TX; bromadiolone + TX; bromfenvinfos + TX; bromophos + TX; bromophos-ethyl + TX; bromuconazole + TX; bufencarb + TX; bupirimate + TX; buprofezin + TX; buserelin + TX; busulfan + TX; but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)- phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate + TX; butacarb + TX; butathiofos + TX; butocarboxim + TX; butonate + TX; butopyronoxyl + TX; butoxy(polypropylene glycol) + TX; butoxycarboxim + TX; butylamine + TX; cadusafos + TX; calciferol + TX; calcium phosphate + TX; calcium polysulfide + TX; cambendazole + TX; captafol + TX; captan + TX; carbanolate + TX; carbaryl + TX; carbendazim + TX; carbendazim hydrochloride + TX; carbofuran + TX; carbosulfan + TX; carboxin + TX; carprofen + TX; carpropamid + TX; cartap + TX; cartap hydrochloride + TX; cefalexin + TX; cefovecin + TX; cefquinome + TX; ceftiour + TX; cestex + TX; cevadine + TX; chinomethionat + TX; chitosan + TX; chlobenthiazone + TX; chloralose + TX; chlorantraniliprole + TX; chlorbenside + TX; chlordimeform + TX; chlorethephon + TX; chlorethoxyfos + TX; chlorfenapyr + TX; chlorfenazole + TX; chlorfentazine + TX; chlorfenvinphos + TX; chlorfluazuron + TX; chlormephos + TX; chlormequat + TX; chlorodimeform hydrochloride + TX; chloroinconazide + TX; chloromebuform + TX; chloromethiuron + TX; chloroneb + TX; chlorothalonil + TX; chlorphoxim + TX; chlorprazophos + TX; chlorpyrifos + TX; chlorpyrifos-methyl + TX; chlortetracycline + TX; chlorthiophos + TX; chlozolinate + TX; cholecalciferol + TX; chromafenozide + TX; Chrysoperla carnea + TX; cinerin + TX; cinerin I + TX; cinerin II + TX; cis-jasmone + TX; cis-resmethrin + TX; cismethrin + TX; clenbuterol + TX; climbazole + TX; cloethocarb + TX; clofencet + TX; clorsulon + TX; clothianidin + TX; clozylacon (acetamide) + TX; codlelure + TX; copper 109939 FF (83198) 56 acetate + TX; copper hydroxide + TX; copper naphthenate + TX; copper octanoate + TX; copper oleate + TX; copper oxide + TX; copper oxychloride + TX; copper silicate + TX; copper sulfate + TX; copper(II) carbonate + TX; coumachlor + TX; coumafene + TX; coumafuryl + TX; Coumatetralyl + TX; coumethoxystrobin (jiaxiangjunzhi) + TX; coumithoate + TX; coumoxystrobin + TX; cryolite + TX; Cryptolaemus montrouzieri + TX; cuelure + TX; cufraneb + TX; cuprous(I) oxide + TX; cyanofenphos + TX; cyanthoate + TX; cyazofamid + TX; cybutryne + TX; cyclafuramid + TX; cyclethrin + TX; cyclobutrifluram + TX; Cydia pomonella GV + TX; cyenopyrafen + TX; cyflufenamid + TX; cyflumetofen + TX; cyfluthrin + TX; cyhalothrin + TX; cymiazole + TX; cymoxanil + TX; cypermethrin (alphametrin) + TX; cyphenothrin + TX; cyproconazole + TX; cyprodinil + TX; cyprodinil + TX; cyromazine + TX; cytokinins + TX; D-tetramethrin + TX; Dacnusa sibirica + TX; DAEP + TX; dazomet + TX; DCPM + TX; debacarb + TX; decarbofuran + TX; deltamethrin + TX; demephion-O + TX; demephion-S + TX; demeton-O + TX; demeton-S + TX; demeton-S-methyl + TX; demeton-S-methylsulphon + TX; diafenthiuron + TX; dialifos + TX; diazinon + TX; dibutyl adipate + TX; dibutyl phthalate + TX; dibutyl succinate + TX; dicapthon + TX; dichlobentiazox + TX; dichlofluanid + TX; dichlone + TX; dichlorprop + TX; dichlorvos + TX; dichlozoline + TX; diclocymet + TX; diclomezine + TX; dicloran + TX; dicofol + TX; dicresyl + TX; dicrotophos + TX; dicyclanil + TX; dicyclopentadiene + TX; diethofencarb + TX; diethyltoluamide + TX; difenacoum + TX; difenoconazole + TX; difenzoquat + TX; difethialone + TX; diflovidazin + TX; diflubenzuron + TX; diflumetorim + TX; Diglyphus isaea + TX; dimatif + TX; dimefluthrin + TX; dimetan + TX; dimethachlon + TX; dimethipin + TX; dimethirimol + TX; dimethoate + TX; dimethomorph + TX; dimethrin + TX; dimethyl disulfide + TX; dimethyl phthalate + TX; dimetilan + TX; dimoxystrobin + TX; dinactin + TX; diniconazole + TX; diniconazole-M + TX; dinobuton + TX; dinocap + TX; dinocton + TX; dinoseb + TX; dinotefuran + TX; diofenolan + TX; dioxabenzofos + TX; diphenylamine + TX; dipyrithione + TX; disparlure + TX; disulfiram + TX; disulfoton + TX; ditalimfos + TX; dithianon + TX; dithicrofos + TX; dithiocarbamate + TX; dodec-8-en-1-yl acetate + TX; dodemorph + TX; dodicin + TX; dodine + TX; dofenapyn + TX; dominicalure + TX; doramectin + TX; drazoxolon + TX; DSP + TX; ecdysterone + TX; edifenphos + TX; emamectin benzoate + TX; EMPC + TX; empenthrin + TX; Encarsia formosa + TX; endosulfan + TX; endothal + TX; endothion + TX; enestroburin (enoxastrobin) + TX; enrofloxacin + TX; entomopathogenic bacteria + TX; entomopathogenic fungi + TX; entomopathogenic virus + TX; EPBP + TX; epoxiconazole + TX; eprinomectin + TX; Eretmocerus eremicus + TX; esfenvalerate + TX; etaconazole + TX; ethaboxam + TX; ethiofencarb + TX; ethion + TX; ethiprole + TX; ethirimol + TX; ethoate- methyl + TX; ethoprophos + TX; ethoxyquin + TX; ethyl 4-methyloctanoate + TX; ethyl formate + TX; ethyl hexanediol + TX; etofenprox + TX; etoxazole + TX; etridiazole + TX; etrimfos + TX; eugenol + TX; eurax + TX; EXD + TX; exo-brevicomin + TX; famoxadone + TX; famphur + TX; farnesol with nerolidol + TX; febantel + TX; fenamidone + TX; fenaminstrobin + TX; fenamiphos + TX; fenarimol + TX; fenazaquin + TX; fenbendazole + TX; fenbuconazole + TX; fenbutatin oxide + TX; feneptamidoquin + TX; fenethacarb + TX; fenfluthrin + TX; fenfuram + TX; fenhexamid + TX; fenitrothion + TX; fenobucarb + TX; fenopyramid + TX; fenothiocarb + TX; fenoxacrim + TX; fenoxanil + TX; fenoxycarb + TX; fenpiclonil + TX; fenpicoxamid + TX; fenpirithrin + TX; fenpropathrin + TX; fenpropidin + TX; fenpropimorph + TX; fenpyrazamine + TX; fenpyroximate + TX; fensulfothion + TX; fenthion + TX; fenthion-ethyl + TX; fentin + TX; fentin acetate + TX; fentin chloride + TX; fentin hydroxide + TX; fenvalerate + TX; ferbam + TX; ferimzone + TX; ferric phosphate + TX; fipronil + TX; 109939 FF (83198) 57 flocoumafen + TX; flonicamid + TX; florfenicol + TX; florylpicoxamid + TX; fluacrypyrim + TX; fluazinam + TX; fluazuron + TX; flubendazole + TX; flubendiamide + TX; flubeneteram + TX; flubenzimin + TX; flucycloxuron + TX; flucycloxuron + TX; flucythrinate + TX; fludioxonil + TX; fluenetil + TX; flufenerim + TX; flufenoxuron + TX; flufenoxystrobin + TX; flufenprox + TX; fluindapyr + TX; flumetralin + TX; flumetylsulforim + TX; flumorph + TX; fluopicolide + TX; fluopimomide + TX; fluopyram + TX; fluoroimide + TX; fluoxapiprolin + TX; fluoxastrobin + TX; fluoxytioconazole + TX; flupyrazofos + TX; fluquinconazole + TX; flusilazole + TX; flusulfamide + TX; flutianil + TX; flutolanil + TX; flutriafol + TX; fluxapyroxad + TX; folpet + TX; fonofos + TX; forchlorfenuron + TX; formaldehyde + TX; formetanate + TX; formetanate hydrochloride + TX; formothion + TX; formparanate + TX; fosetyl + TX; fosetyl-aluminium + TX; fosmethilan + TX; fosthiazate + TX; fosthietan + TX; frontalin + TX; fuberidazole + TX; furalaxyl + TX; furametpyr + TX; furathiocarb + TX; furethrin + TX; furfural + TX; gibberellic acid + TX; glyodin + TX; glyphosate + TX; grandlure I + TX; grandlure II + TX; grandlure III + TX; grandlure IV + TX; guazatine triacetate + TX; halfenprox + TX; halofenozide + TX; hemel + TX; heptenophos + TX; Heterorhabditis bacteriophora and H. megidis + TX; hexaconazole + TX; hexadecyl cyclopropanecarboxylate + TX; hexaflumuron + TX; hexalure + TX; hexamide + TX; hexythiazox + TX; Hippodamia convergens + TX; huanjunzuo (rac-(1S,2S)-1-(4-chlorophenyl)-2-(1,2,4-triazol-1-yl)cycloheptanol) + TX; hydramethylnon + TX; hydrated lime (calcium hydroxide) + TX; hymexazol + TX; hyquincarb + TX; icaridin + TX; imanin (hypericin) + TX; imazalil + TX; imazalil sulfate + TX; imibenconazole + TX; imidacloprid + TX; iminoctadine + TX; indoxacarb + TX; inpyrfluxam + TX; iodocarb + TX; ipconazole + TX; ipfentrifluconazole + TX; ipflufenoquin + TX; iprobenfos (IBP) + TX; iprodione + TX; iprovalicarb + TX; ipsdienol + TX; ipsenol + TX; IPSP + TX; isamidofos + TX; isazofos + TX; isocarbophos + TX; isofetamid + TX; isoflucypram + TX; isolan + TX; isoprocarb + TX; isoprothiolane + TX; isopyrazam + TX; isothioate + TX; isotianil + TX; isoxathion + TX; ivermectin + TX; japonilure + TX; jasmolin I + TX; jasmolin II + TX; juvenile hormone I + TX; juvenile hormone II + TX; juvenile hormone III + TX; kadethrin + TX; kanamycin + TX; kasugamycin + TX; kasugamycin hydrochloride hydrate + TX; kinetin + TX; kinoprene + TX; kresoxim-methyl + TX; kurstaki + TX; lambda-cyhalothrin + TX; Leptomastix dactylopii + TX; leptophos + TX; levamisole + TX; lineatin + TX; lirimfos + TX; looplure + TX; lufenuron + TX; lvbenmixianan + TX; lythidathion + TX; m-cumenyl methylcarbamate + TX; Macrolophus caliginosus + TX; magnesium phosphide + TX; malathion + TX; maleic hydrazide + TX; malonoben + TX; Mamestra brassicae NPV + TX; mancopper + TX; mancozeb + TX; mandestrobin + TX; mandipropamid + TX; maneb + TX; mazidox + TX; mebendazole + TX; mecarbam + TX; mecarphon + TX; medlure + TX; mefentrifluconazole + TX; megatomoic acid + TX; meloxicam + TX; menazon + TX; mepanipyrim + TX; meperfluthrin + TX; mephosfolan + TX; mepiquat + TX; mepronil + TX; meptyldinocap + TX; mesulfenfos + TX; metaflumizone + TX; metalaxyl + TX; metalaxyl-M + TX; metaldehyde + TX; metam + TX; metam-potassium + TX; metam-sodium + TX; Metaphycus helvolus + TX; Metarhizium anisopliae var. acridum + TX; Metarhizium anisopliae var. anisopliae + TX; metarylpicoxamid + TX; metconazole + TX; methacrifos + TX; methamidophos + TX; methasulfocarb + TX; methidathion + TX; methiocarb + TX; methiotepa + TX; methocrotophos + TX; methomyl + TX; methoprene + TX; methoquin-butyl + TX; methothrin + TX; methoxyfenozide + TX; methyl apholate + TX; methyl eugenol + TX; methyl iodide + TX; methyl neodecanamide + TX; metiram + TX; metofluthrin + TX; metolcarb + TX; metominostrobin + TX; metoxadiazone + TX; metrafenone + TX; metyltetraprole + TX; mevinphos + TX; 109939 FF (83198) 58 mexacarbate + TX; MGK 264 + TX; milbemycin + TX; milbemycin oxime + TX; monocrotophos + TX; morantel tartrate + TX; morzid + TX; moxidectin + TX; muscalure + TX; myclobutanil + TX; myclozolin + TX; Myrothecium verrucaria composition + TX; N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4- carboxamide + TX; N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-[(2-isopropylphenyl)methyl]-1-methyl-pyrazole- 4-carboxamide + TX; nabam + TX; naled + TX; NC-170 + TX; nemadectin + TX; Neodiprion sertifer NPV and N. lecontei NPV + TX; niclosamide-olamine + TX; nicotine + TX; nicotine sulfate + TX; nikkomycins + TX; nitenpyram + TX; nithiazine + TX; nitrapyrin + TX; nitrilacarb + TX; nitrothal-isopropyl + TX; norbormide + TX; nornicotine + TX; novaluron + TX; noviflumuron + TX; nuarimol + TX; O,O,O',O'-tetrapropyl dithiopyrophosphate + TX; octadeca-2,13-dien-1-yl acetate + TX; octadeca-2,13-dien-1-yl acetate + TX; octhilinone + TX; ofurace + TX; oleic acid + TX; omethoate + TX; orfralure + TX; Orius spp. + TX; orysastrobin + TX; osthol + TX; ostramone + TX; oxadixyl + TX; oxamate + TX; oxamyl + TX; oxantel pamoate + TX; oxasulfuron + TX; oxathiapiprolin + TX; oxfendazole + TX; oxibendazole + TX; oxine copper + TX; oxolinic acid + TX; oxpoconazole + TX; oxycarboxin + TX; oxydemeton-methyl + TX; oxydeprofos + TX; oxydisulfoton + TX; oxytetracycline + TX; oxytetracycline dihydrate + TX; paclobutrazol + TX; Paecilomyces fumosoroseus + TX; paraoxon + TX; parathion + TX; parathion-methyl + TX; parbendazole + TX; pefurazoate + TX; penconazole + TX; pencycuron + TX; penethamate + TX; penflufen + TX; penthiopyrad + TX; permethrin + TX; petroleum oils + TX; PH 60-38 + TX; phenamacril + TX; phenthoate + TX; phorate + TX; phosacetim + TX; phosalone + TX; phosfolan + TX; phosglycin + TX; phosmet + TX; phosnichlor + TX; phosphamidon + TX; phosphocarb + TX; phosphonic acid + TX; phosphorus + TX; phoxim + TX; phoxim-methyl + TX; phthalide + TX; Phytoseiulus persimilis + TX; picarbutrazox + TX; picoxystrobin + TX; pimobendan + TX; pindone + TX; piperalin + TX; piperonyl butoxide + TX; piprotal + TX; pirimetaphos + TX; pirimicarb + TX; pirimiphos-methyl + TX; polycarbamate + TX; polynactin + TX; polyoxin B + TX; polyoxin d + TX; potassium ethylxanthate + TX; potassium hydroxyquinoline sulfate + TX; praziquantel + TX; precocene I + TX; precocene II + TX; precocene III + TX; primidophos + TX; probenazole + TX; prochloraz + TX; procymidone + TX; profenofos + TX; profluthrin + TX; prohexadione + TX; prohexadione-calcium + TX; promacyl + TX; promecarb + TX; propamidine + TX; propamocarb + TX; propaphos + TX; propargite + TX; propetamphos + TX; propiconazole + TX; propineb + TX; propionic acid + TX; propoxur + TX; propyl isomer + TX; proquinazid + TX; prothidathion + TX; prothioconazole + TX; prothiofos + TX; prothoate + TX; protrifenbute + TX; pydiflumetofen + TX; pymetrozine + TX; pyraclofos + TX; pyraclostrobin + TX; pyrafluprole + TX; pyrametostrobin + TX; pyrantel pamoate + TX; pyraoxystrobin + TX; pyrapropoyne + TX; pyraziflumid + TX; pyrazophos + TX; pyrazoxone + TX; pyresmethrin + TX; pyrethrin I + TX; pyrethrin II + TX; pyrethrins (natural products) + TX; pyrethroids (natural products) + TX; pyribencarb + TX; pyridaben + TX; pyridachlometyl + TX; pyridalyl + TX; pyridaphenthion + TX; pyridin-4-amine + TX; pyrifenox + TX; pyrifluquinazon + TX; pyrimethanil + TX; pyrimidifen + TX; pyrimorph + TX; pyriofenone + TX; pyriprole + TX; pyriproxyfen + TX; pyrisoxazole + TX; pyroquilon + TX; quassia + TX; quinalphos + TX; quinalphos-methyl + TX; quinoclamine + TX; quinofumelin + TX; quinonamid + TX; quinothion + TX; quinoxyfen + TX; quintozene + TX; R-1492 + TX; R-metalaxyl + TX; Reynoutria sachalinensis extract + TX; ribavirin + TX; rotenone + TX; ryanodine (ryania) + TX; sabadilla + TX; schradan + TX; scilliroside + TX; seboctylamine + TX; sedaxane + TX; selamectin + TX; sesamex + TX; sesamolin + TX; siglure + TX; silafluofen + TX; silthiofam + 109939 FF (83198) 59 TX; simeconazole + TX; sodium tetrathiocarbonate + TX; sophamide + TX; sordidin + TX; spinetoram + TX; spinosad + TX; spirodiclofen + TX; spiromesifen + TX; spirotetramat + TX; spiroxamine + TX; Steinernema bibionis + TX; Steinernema carpocapsae + TX; Steinernema feltiae + TX; Steinernema glaseri + TX; Steinernema riobrave + TX; Steinernema riobravis + TX; Steinernema scapterisci + TX; Steinernema spp. + TX; streptomycin + TX; streptomycin sesquisulfate + TX; sulcatol + TX; sulcofuron + TX; sulfiram + TX; sulfur + TX; sulprofos + TX; tar oils + TX; tau-fluvalinate + TX; TCMTB + TX; TDE + TX; tebuconazole + TX; tebufenozide + TX; tebufenpyrad + TX; tebufloquin + TX; tebupirimfos + TX; tecnazene + TX; teflubenzuron + TX; tefluthrin + TX; temephos + TX; terallethrin + TX; terbam + TX; terbufos + TX; tetrachlorvinphos + TX; tetraconazole + TX; tetradec-11-en-1-yl acetate + TX; tetradifon + TX; tetramethrin + TX; tetramethylfluthrin + TX; tetranactin + TX; thiabendazole + TX; thiacloprid + TX; thiadiazole copper + TX; thiamethoxam + TX; thiapronil + TX; thicrofos + TX; thicyofen + TX; thidiazuron + TX; thifluzamide + TX; thiocarboxime + TX; thiocyclam + TX; thiocyclam hydrogen oxalate + TX; thiodicarb + TX; thiofanox + TX; thiometon + TX; thiophanate + TX; thiophanate-methyl + TX; thioquinox + TX; thiosultap + TX; thiosultap-disodium + TX; thiram + TX; thuringiensin + TX; tiadinil + TX; tiamulin + TX; tioxymid + TX; tolclofos-methyl + TX; tolfenpyrad + TX; tolprocarb + TX; tolylfluanid + TX; tralomethrin + TX; transpermethrin + TX; tretamine + TX; triadimefon + TX; triadimenol + TX; triarathene + TX; triazamate + TX; triazophos + TX; triazoxide + TX; tribufos + TX; trichlorfon + TX; trichlormetaphos-3 + TX; trichloronat + TX; Trichogramma spp. + TX; triclabendazole + TX; triclopyricarb + TX; tricyclazole + TX; tridemorph + TX; trifenmorph + TX; trifloxystrobin + TX; triflumizole + TX; triflumuron + TX; triforine + TX; trimedlure + TX; trimedlure A + TX; trimedlure B1 + TX; trimedlure B2 + TX; trimedlure C + TX; trimethacarb + TX; trinactin + TX; trinexapac + TX; trinexapac-ethyl + TX; triprene + TX; triticonazole + TX; trunc-call + TX; tulathromycin + TX; Typhlodromus occidentalis + TX; uniconazole + TX; uredepa + TX; validamycin + TX; valifenalate + TX; vamidothion + TX; vaniliprole + TX; veratridine + TX; veratrine + TX; verbutin + TX; Verticillium lecanii + TX; vinclozolin + TX; XMC + TX; xylenols + TX; zeatin + TX; zeta- cypermethrin + TX; zhongshengmycin + TX; zinc naphthenate + TX; zinc thiazole + TX; zineb + TX; ziram + TX; zolaprofos + TX; zoxamide + TX; 2-(difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3- carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675) + TX; methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate (this compound may be prepared from the methods described in WO 2019 / 093522) + TX; methyl (2R)-2-[2-chloro- 4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4-triazol-1-yl)propanoate (this compound may be prepared from the methods described in WO 2019 / 093522) + TX; 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6- difluorophenyl)cyclopropyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; aminopyrifen (this compound may be prepared from the methods describe WO 2014 / 006945) + TX; dipymetitrone (this compound may be prepared from the methods described in WO 2011 / 138281) + TX; 1-[6-(difluoromethyl)-5-methyl-3-pyridyl]-4,4-difluoro-3,3-dimethyl-isoquinoline (this compound may be prepared from the methods described in WO 2017 / 016915) + TX; 1-[4-(difluoromethoxy)-2- methyl-phenyl]-2-(1,2,4-triazol-1-yl)-1-[1-(trifluoromethyl)cyclopropyl]ethanol (this compound may be prepared from the methods described in WO 2021 / 249800) + TX; 1-[2-chloro-4-(difluoromethoxy)phenyl]-2-(1,2,4-triazol- 1-yl)-1-[1-(trifluoromethyl)cyclopropyl]ethanol (this compound may be prepared from the methods described in 109939 FF (83198) 60 WO 2021 / 249800) + TX; 1-(5,6-dimethyl-3-pyridyl)-4,4-difluoro-3,3-dimethyl-isoquinoline (this compound may be prepared from the methods described in WO 2017 / 016915) + TX; N-methyl-4-[5-(trifluoromethyl)-1,2,4- oxadiazol-3-yl]benzenecarbothioamide (this compound may be prepared from the methods described in WO 2015 / 185485) + TX; 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide (this compound may be prepared from the methods described in WO 2017 / 178245) + TX; flufenoxadiazam + TX; N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide (this compound may be prepared from the methods described in WO 2015 / 185485) + TX; (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2- methoxyimino-N,3-dimethyl-pent-3-enamide (this compound may be prepared from the methods described in WO 2018 / 153707) + TX; (Z,2E)-5-[1-(4-chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3- enamide (this compound may be prepared from the methods described in WO 2013 / 092224) + TX; methyl (2E)-2-methoxyimino-2-[3-methyl-2-[[(E)-1-[4-(trifluoromethyl)-2- pyridyl]ethylideneamino]oxymethyl]phenyl]acetate (this compound may be prepared from the methods described in WO 2022 / 033906) + TX; (2E)-2-methoxyimino-N-methyl-2-[3-methyl-2-[[(E)-1-[4-(trifluoromethyl)- 2-pyridyl]ethylideneamino]oxymethyl]phenyl]acetamide (this compound may be prepared from the methods described in WO 2022 / 033906) + TX; (2E)-2-[2-[[(E)-[3-(4-fluorophenyl)-1-methyl-prop-2- ynylidene]amino]oxymethyl]-3-methyl-phenyl]-2-methoxyimino-N-methyl-acetamide (this compound may be prepared from the methods described in WO 2021 / 249928) + TX; methyl (2E)-2-[2-[[(E)-[3-(4-fluorophenyl)-1- methyl-prop-2-ynylidene]amino]oxymethyl]-3-methyl-phenyl]-2-methoxyimino-acetate (this compound may be prepared from the methods described in WO 2021 / 249928) + TX; 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2- fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290) + TX; 3-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxy- propyl]imidazole-4-carbonitrile (this compound may be prepared from the methods described in WO 2016 / 156290) + TX; 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179) + TX; 2-[6-(4-chlorophenoxy)- 2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound may be prepared from the methods described in WO 2017 / 029179) + TX; 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2- fluorophenyl)ethyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2- amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; N-[1-(2- fluorophenyl)cyclopropyl]-5-[5-(trifluoromethyl)-1,3,4-oxadiazol-2-yl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N- [1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; 2-(difluoromethyl)-5-[2-[1-(2,6-difluorophenyl)cyclopropoxy]pyrimidin-5-yl]-1,3,4- oxadiazole (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; 5-[5- (difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine (this compound may be prepared from the methods described in WO 2021 / 255093) + TX; 5-[(4-bromo-2-methyl-phenyl)methyl]-3- [3-(3-chloro-2-fluoro-phenoxy)-6-methyl-pyridazin-4-yl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2021 / 255070) + TX; 3-[3-(3-cyclopropyl-2-fluoro-phenoxy)-6- 109939 FF (83198) 61 methyl-pyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2021 / 255070) + TX; N-(2,2,2-trifluoroethyl)-2-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]oxazole-4-carboxamide (this compound may be prepared from the methods described in WO 2022 / 133114) + TX; ethyl 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenoxy]methyl]pyrazole-4-carboxylate (this compound may be prepared from the methods described in WO 2022 / 133114) + TX; ethyl 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1-enoxy]phenyl]methyl]pyrazole-4- carboxylate (this compound may be prepared from the methods described in WO 2020 / 056090 and WO 2021 / 183707) + TX; ethyl 1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy]phenyl]methyl]pyrazole-4- carboxylate (this compound may be prepared from the methods described in WO 2020 / 056090 and WO 2021 / 183707) + TX; methyl N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2-methyl-phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012) + TX; methyl N-[[5-[1-(2,6- difluoro-4-isopropyl-phenyl)pyrazol-3-yl]-2-methyl-phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012) + TX; methyl N-[[5-[1-(4-cyclopropyl-2,6-difluoro- phenyl)pyrazol-3-yl]-2-methyl-phenyl]methyl]carbamate (this compound may be prepared from the methods described in WO 2020 / 097012) + TX; methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4- triazol-1-yl)propanoate (this compound may be prepared from the methods described in WO 2019 / 093522) + TX; 4,4,5-trifluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline + TX; 5-fluoro-3,3,4,4-tetramethyl-1-(3- quinolyl)isoquinoline + TX; 2-methoxy-N-[methoxy-[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2- thienyl]methyl]acetamide (this compound may be prepared from the methods described in WO 2020 / 256113) + TX; N-[methoxy-[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]-2-methyl-propanamide (this compound may be prepared from the methods described in WO 2020 / 256113) + TX; N-[methoxy-[5-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]butanamide (this compound may be prepared from the methods described in WO 2020 / 256113) + TX; 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4- yl]pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675) + TX; 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide (this compound may be prepared from the methods described in WO 2014 / 095675) + TX; 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4- yl)pyridine-3-carboxamide + TX; (5R)-3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl-pyridazin-4-yl]-5-[(2-chloro-4- methyl-phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070) + TX; (5S)-3-[3-(3-chloro-2-fluoro-phenoxy)-6-methyl- pyridazin-4-yl]-5-[(2-chloro-4-methyl-phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070) + TX; 3-[3-(3-chloro-2-fluoro- phenoxy)-6-methyl-pyridazin-4-yl]-5-[(2-chloro-4-methyl-phenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine (this compound may be prepared from the methods described in WO 2020 / 127780, WO 2021 / 255070) + TX; methyl (Z)-3-methoxy-2-(2-methyl-5-phenyl-phenoxy)prop-2-enoate (this compound may be prepared from methods as described in WO01 / 00562, JP2023078251) +TX; 2-[(2,6-difluoro-4-pyridyl)-(2-methylpropanoyl)amino]-N- (2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[(2,6-difluoro-4-pyridyl)-(tetrahydropyran-4- 109939 FF (83198) 62 carbonyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[cyano-(2,6-difluoro-4- pyridyl)amino]-5-methyl-N-spiro[3.4]octan-3-yl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109509A1); 2-[cyano-(2,6-difluoro-4-pyridyl)amino]-N-(2,2-dimethylcyclobutyl)-5- methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109509A1); 2- [(2,6-difluoro-4-pyridyl)-(2-methoxyacetyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[acetyl-(2,6- difluoro-4-pyridyl)amino]-5-methyl-N-spiro[3.4]octan-3-yl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); N-methoxy-N-[[4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide (this compound may be prepared from the methods described in WO 2017 / 055473) +TX; methyl (Z)-2-(5-cyclopentyl-2-methyl- phenoxy)-3-methoxy-prop-2-enoate (this compound may be prepared from the methods described in WO2020 / 193387) +TX; methyl (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate (this compound may be prepared from the methods described in WO2020 / 193387) +TX; N-[(1R)-1-benzyl-1,3- dimethylbutyl]-8-fluoroquinoline-3-carboxamide (this compound may be prepared from the methods described in WO2017 / 153380) +TX; N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (this compound may be prepared from the methods described in WO2017 / 153380) +TX; 2-[(2,6-difluoro-4-pyridyl)- (oxetane-3-carbonyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); 2-[acetyl-(2,6-difluoro-4- pyridyl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-thiazole-4-carboxamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO2017207362A1, WO2019105933A1, WO2020109511A1, WO2021244952A1); N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4- oxadiazol-3-yl]phenyl]methyl]propanamide + TX; or the (R) or (S) enantiomer or mixtures thereof +TX (this compound may be prepared from the methods described in WO 2017 / 055473). The references in brackets behind the active ingredients, e.g., [3878-19-1] refer to the Chemical Abstracts Registry number. The above-described mixing partners are known. Where the active ingredients are included in "The Pesticide Manual" [The Pesticide Manual - A World Compendium; Thirteenth Edition; Editor: C. D. S. TomLin; The British Crop Protection Council], they are described therein under the entry number given in round brackets hereinabove for the particular compound; for example, the compound "abamectin" is described under entry number (1). Where "[CCN]" is added hereinabove to the particular compound, the compound in question is included in the "Compendium of Pesticide Common Names", which is accessible on the internet [A. Wood; 109939 FF (83198) 63 Compendium of Pesticide Common Names, Copyright © 1995-2004]; for example, the compound "acetoprole" is described under the internet address http: / / www.alanwood.net / pesticides / acetoprole.html. Most of the active ingredients described above are referred to hereinabove by a so-called "common name", the relevant "ISO common name" or another "common name" being used in individual cases. If the designation is not a "common name", the nature of the designation used instead is given in round brackets for the particular compound; in that case, the IUPAC name, the IUPAC / Chemical Abstracts name, a "chemical name", a "traditional name", a "compound name" or a "development code" is used or, if neither one of those designations nor a "common name" is used, an "alternative name" is employed. “CAS Reg. No” means the Chemical Abstracts Registry Number. The active ingredient mixture of the compound selected from compounds of formula (I), or compounds selected from compounds listed in Tables C-1 to C-41, or compounds listed in Table P (below), is preferably in a mixing ratio of from 100:1 to 1:100, especially from 50:1 to 1:50, more especially in a ratio of from 20:1 to 1:20, even more especially from 10:1 to 1:10, and still more especially from 5:1 to 1:5 Those mixing ratios are by weight. The mixtures as described above can be used in a method for controlling pests, which comprises applying a composition comprising a mixture as described above to the pests or their environment, with the exception of a method for treatment of the human or animal body by surgery or therapy and diagnostic methods practiced on the human or animal body. The mixtures comprising a compound selected from compounds of formula (I), or compounds selected from compounds listed in Tables C-1 to C-41, or compounds listed in Table P (below), and one or more active ingredients as described above can be applied, for example, in a single “ready-mix” form, in a combined spray mixture composed from separate formulations of the single active ingredient components, such as a “tank-mix”, and in a combined use of the single active ingredients when applied in a sequential manner, i.e. one after the other with a reasonably short period, such as a few hours or days. The order of applying a compound selected from compounds of formula (I), or compounds selected from compounds listed in Tables C-1 to C-41, or compounds listed in Table P (below), and the active ingredient(s) as described above, is not essential for working the present invention. The compositions according to the invention can also comprise further solid or liquid auxiliaries, such as stabilizers, for example unepoxidized or epoxidized vegetable oils (for example epoxidized coconut oil, rapeseed oil or soya oil), antifoams, for example silicone oil, preservatives, viscosity regulators, binders and / or tackifiers, fertilizers or other active ingredients for achieving specific effects, for example bactericides, fungicides, nematocides, plant activators, molluscicides, or herbicides. The compositions according to the invention are prepared in a manner known per se, in the absence of auxiliaries for example by grinding, screening and / or compressing a solid active ingredient and in the presence of at least one auxiliary for example by intimately mixing and / or grinding the active ingredient with the auxiliary (auxiliaries). These processes for the preparation of the compositions and the use of the compounds (I) for the preparation of these compositions are also a subject of the invention. 109939 FF (83198) 64 Another aspect of the invention is related to the use of a compound of formula (I) according to the invention or of a preferred individual compound as defined herein, of a composition comprising at least one compound of formula (I) or at least one preferred individual compound as defined herein, or of a fungicidal or insecticidal mixture comprising at least one compound of formula (I) or at least one preferred individual compound as defined herein, in admixture with other fungicides or insecticides as described above, for controlling or preventing infestation of plants, e.g., useful plants such as crop plants, propagation material thereof, e.g., seeds, harvested crops, e.g., harvested food crops, or non-living materials by insects, or by phytopathogenic microorganisms, preferably fungal organisms. A further aspect of invention is related to a method of controlling or preventing an infestation of plants, e.g., useful plants such as crop plants, propagation material thereof, e.g., seeds, harvested crops, e.g., harvested food crops, or of non-living materials by phytopathogenic or spoilage microorganisms or organisms potentially harmful to man, especially fungal organisms, which comprises the application of a compound of formula (I) according to the invention or of a preferred individual compound as defined herein as active ingredient to the plants, to parts of the plants or to the locus thereof, to the propagation material thereof, or to any part of the non-living materials. Controlling or preventing means reducing infestation by insects, or by phytopathogenic or spoilage microorganisms, or organisms potentially harmful to man, especially fungal organisms, to such a level that an improvement is demonstrated. A preferred method of controlling or preventing an infestation of crop plants by phytopathogenic microorganisms, especially fungal organisms, or insects which comprises the application of a compound of formula (I) according to the invention, or an agrochemical composition which contains at least one compound of formula (I), is foliar application. The frequency of application and the rate of application will depend on the risk of infestation by the corresponding pathogen or insect. However, the compounds of formula (I) according to the invention can also penetrate the plant through the roots via the soil (systemic action) by drenching the locus of the plant with a liquid formulation, or by applying the compounds in solid form to the soil, e.g., in granular form (soil application). In crops of water rice such granulates can be applied to the flooded rice field. The compounds of formula (I) may also be applied to seeds (coating) by impregnating the seeds or tubers either with a liquid formulation of the fungicide or coating them with a solid formulation. A formulation, e.g., a composition containing the compound of formula (I) according to the invention and, if desired, a solid or liquid adjuvant or monomers for encapsulating the compound of formula (I), may be prepared in a known manner, typically by intimately mixing and / or grinding the compound with extenders, for example solvents, solid carriers and, optionally, surface active compounds (surfactants). Advantageous rates of application are normally from 5 g to 2 kg of active ingredient (a.i.) per hectare (ha), preferably from 10 g to 1 kg^a.i. / ha, most preferably from 20 g to 600 g^a.i. / ha. When used as seed drenching agent, convenient dosages are from 10 mg to 1 g of active substance per kg of seeds. 109939 FF (83198) 65 The term “g a.i. / ha” as used herein refer to the application rate given in gram [g] of active ingredient [a.i.] per unit of surface [ha]. The unit hectare (symbol ha) is the metric unit of area that equals a square with 100 m side (1 hm2) or 10,000 square meters. Hectare is a commonly used unit of area in the metric system. When the combinations of the present invention are used for treating seed, rates of 0.001 to 50 g of a compound of formula (I) per kg of seed, preferably from 0.01 to 10 g per kg of seed are generally sufficient. Suitably, a composition comprising a compound of formula (I) according to the present invention is applied either preventative, meaning prior to disease development or curative, meaning after disease development. The compositions of the invention may be employed in any conventional form, for example in the form of a twin pack, a powder for dry seed treatment (DS), an emulsion for seed treatment (ES), a flowable concentrate for seed treatment (FS), a solution for seed treatment (LS), a water dispersible powder for seed treatment (WS), a capsule suspension for seed treatment (CF), a gel for seed treatment (GF), an emulsion concentrate (EC), a suspension concentrate (SC), a suspo-emulsion (SE), a capsule suspension (CS), a water dispersible granule (WG), an emulsifiable granule (EG), an emulsion, water in oil (EO), an emulsion, oil in water (EW), a micro- emulsion (ME), an oil dispersion (OD), an oil miscible flowable (OF), an oil miscible liquid (OL), a soluble concentrate (SL), an ultra-low volume suspension (SU), an ultra-low volume liquid (UL), a technical concentrate (TK), a dispersible concentrate (DC), a wettable powder (WP) or any technically feasible formulation in combination with agriculturally acceptable adjuvants. Such compositions may be produced in conventional manner, e.g., by mixing the active ingredients with appropriate formulation inerts (diluents, solvents, fillers, and optionally other formulating ingredients such as surfactants, biocides, anti-freeze, stickers, thickeners, and compounds that provide adjuvancy effects). Also, conventional slow-release formulations may be employed where long lasting efficacy is intended. Particularly formulations to be applied in spraying forms, such as water dispersible concentrates (e.g., EC, SC, DC, OD, SE, EW, EO and the like), wettable powders and granules, may contain surfactants such as wetting and dispersing agents and other compounds that provide adjuvancy effects, e.g., the condensation product of formaldehyde with naphthalene sulfonate, an alkyl aryl sulfonate, a lignin sulfonate, a fatty alkyl sulphate, and ethoxylated alkylphenol and an ethoxylated fatty alcohol. A seed dressing formulation is applied in a manner known per se to the seeds employing the combination of the invention and a diluent in suitable seed dressing formulation form, e.g., as an aqueous suspension or in a dry powder form having good adherence to the seeds. Such seed dressing formulations are known in the art. Seed dressing formulations may contain the single active ingredients or the combination of active ingredients in encapsulated form, e.g., as slow-release capsules or microcapsules. In general, the formulations include from 0.01 to 90% by weight of active agent, from 0 to 20% agriculturally acceptable surfactant and 10 to 99.99% solid or liquid formulation inerts, and adjuvant(s), the active agent consisting of at least the compound of formula (I) according to the invention optionally together with other active agents, particularly microbiocides or conservatives or the like. Concentrated forms of compositions generally contain in between about 2 to 80%, preferably between about 5 to 70% by weight of active agent. Application 109939 FF (83198) 66 forms of formulation may for example contain from 0.01 to 20% by weight, preferably from 0.01 to 5% by weight of active agent. Whereas commercial products will preferably be formulated as concentrates, the end user will normally employ diluted formulations. Whereas it is preferred to formulate commercial products as concentrates, the end user will normally use dilute formulations. The rates of application vary within wide limits and depend on the nature of the soil, the method of application, the crop plant, the pest to be controlled, the prevailing climatic conditions, and other factors governed by the method of application, the time of application and the target crop. As a general guideline, compounds may be applied at a rate of from 1 to 2000 L / ha, especially from 10 to 1000 L / ha. Preferred formulations can have the following compositions (weight %): Emulsifiable concentrates: active ingredient: 1 to 95 %, preferably 60 to 90 % surface-active agent: 1 to 30 %, preferably 5 to 20 % liquid carrier: 1 to 80 %, preferably 1 to 35 % Dusts: active ingredient: 0.1 to 10 %, preferably 0.1 to 5 % solid carrier: 99.9 to 90 %, preferably 99.9 to 99 % Suspension concentrates: active ingredient: 5 to 75 %, preferably 10 to 50 % water: 94 to 24 %, preferably 88 to 30 % surface-active agent: 1 to 40 %, preferably 2 to 30 % Wettable powders: active ingredient: 0.5 to 90 %, preferably 1 to 80 % surface-active agent: 0.5 to 20 %, preferably 1 to 15 % solid carrier: 5 to 95 %, preferably 15 to 90 % Granules: active ingredient: 0.1 to 30 %, preferably 0.1 to 15 % solid carrier: 99.5 to 70 %, preferably 97 to 85 % The disclosure in the present application makes available each and every combination of embodiments disclosed herein. The compounds according to the following Tables C-1 to C-41 may be prepared according to the methods described above. The examples which follow are intended to illustrate the invention and show preferred compounds of formula (I). In any of Tables C-1 to C-41 below, the presence of one or more possible asymmetric carbon atoms in a compound of formula (I) according to the invention means that the compounds may occur in chiral isomeric forms, i.e., enantiomeric or diastereomeric forms. 109939 FF (83198) 67 Table A: This table discloses 20 compounds of formula (Ia) according to the invention: G 1 [2-(2,4-difluorophenyl)tetrazole-5-carbonyl] 11 (1-phenyltriazole-4-carbonyl) 2 [1-(2,4-difluorophenyl)triazole-4-carbonyl] 12 [1-(2,4-difluorophenyl)pyrazole-4-carbonyl] 3 [2-(3,5-difluoro-2-pyridyl)tetrazole-5-carbonyl] 13 [1-(2,4-difluorophenyl)pyrazole-3-carbonyl] 4 [1-(3,5-difluoro-2-pyridyl)triazole-4-carbonyl] 14 [1-(2,4-difluorophenyl)-1,2,4-triazole-3-carbonyl] 5 [2-(4-fluorophenyl)tetrazole-5-carbonyl] 15 [2-(4,6-difluoro-3-pyridyl)tetrazole-5-carbonyl] 6 [2-(5-fluoro-2-pyridyl)tetrazole-5-carbonyl] 16 [1-(4,6-difluoro-3-pyridyl)triazole-4-carbonyl] 7 [1-(4-fluorophenyl)triazole-4-carbonyl] 17 [2-(2,6-difluoro-3-pyridyl)tetrazole-5-carbonyl] 8 [2-(2-fluorophenyl)tetrazole-5-carbonyl] 18 [1-(2,6-difluoro-3-pyridyl)triazole-4-carbonyl] 9 [1-(2-fluorophenyl)triazole-4-carbonyl] 19 [1-(2-fluoro-3-pyridyl)triazole-4-carbonyl] 10 (2-phenyltetrazole-5-carbonyl) 20 [1-(4-fluoro-3-pyridyl)triazole-4-carbonyl] The following compounds represent specific compounds or formula (Ia) as described in Tables C-1 to C-41 wherein G is as defined in Table A. Table C-1: This table provides 20 compounds C-1.G1 to C-1.G20 of formula (Ia) wherein R2is OCH3, R3is CH3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C- 1.G1 has the following structure: Compound C-1.G1 C-2.G1 to C-2.G20 of formula (Ia) wherein R2is OCH3, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-2.G4 has the following structure: 109939 FF (83198) 68 Compound C-2.G4 C-3.G1 to C-3.G20 of formula (I) wherein R2is OCH3, R4is CH3, R3, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-3.G15 has the following structure: Compound C-3.G15 compounds rac-syn-C-4.G1 to rac-syn-C-4.G20 of formula (I) wherein R2is OCH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-4.G4 has the following structure: Compound rac-syn-C-4.G4 C-5.G1 to C-5.G20 of formula (I) wherein R2is OCH3, R5 is CH3, R3, R4, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-6: This table provides 20 compounds C-6.G1 to C-6.G20 of formula (I) wherein R2is OCH3, R5 and R6are CH3, R3, R4, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-7: This table provides 20 compounds C-7.G1 to C-7.G20 of formula (Ia) wherein R2is OCH3, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-Cl and G is as defined in Table A. Table C-8: This table provides 20 compounds C-8.G1 to C-8.G20 of formula (Ia) wherein R2is OCH3, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-Br and G is as defined in Table A. For example, compound C-8.G13 has the following structure: 109939 FF (83198) 69 Compound C-8.G13 C-9.G1 to C-9.G20 of formula (Ia) wherein R2is OCH3, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-CN and G is as defined in Table A. Table C-10: This table provides 20 compounds C-10.G1 to C-1.G20 of formula (Ia) wherein R2is OCH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is N and G is as defined in Table A. For example, compound C-10.G11 has the following structure: Compound C-10.G11 20 compounds rac-syn-C-11.G1 to rac-syn-C-1.G20 of formula (Ia) wherein R2is OCH3 R7is CH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-Cl and G is as defined in Table A. For example, compound C-11.G1 has the following structure: Compound C-11.G1 rac-syn-C-12.G1 to rac-syn-C-12.G20 of formula (Ia) wherein R2is OCH3, R7is CH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-Br and G is as defined in Table A. Table C-13: This table provides 20 compounds rac-syn-C-13.G1 to rac-syn-C-13.G20 of formula (Ia) wherein R2is OCH3 R7is CH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-CN and G is as defined in Table A. Table C-14: This table provides 20 compounds C-14.G1 to C-14.G20 of formula (Ia) wherein R2is CN, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-14.G4 has the following structure: 109939 FF (83198) 70 Compound C-14.G4 rac-syn-C-15.G1 to rac-syn-C-15.G20 of formula (I) wherein R2is CN, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-15.G8 has the following structure: Compound rac-syn-C-15.G8 compounds C-16.G1 to C-16.G20 of formula (Ia) wherein R2is OH, R3R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-17: This table provides 20 compounds rac-syn-C-17.G1 to rac-syn-C-17.G20 of formula (I) wherein R2is OH, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-18: This table provides 20 compounds C-18.G1 to C-18.G20 of formula (Ia) wherein R2is OCHF2, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-19: This table provides 20 compounds rac-syn-C-19.G1 to rac-syn-C-19.G20 of formula (I) wherein R2is OCHF2, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-20: This table provides 20 compounds C-20.G1 to C-20.G20 of formula (Ia) wherein R2is OCH2CF3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-21: This table provides 20 compounds rac-syn-C-21.G1 to rac-syn-C-21.G20 of formula (I) wherein R2is OCH2CF3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-22: This table provides 20 compounds C-22.G1 to C-22.G20 of formula (Ia) wherein R2is OCH2CHF2, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-23: This table provides 20 compounds rac-syn-C-23.G1 to rac-syn-C-23.G20 of formula (I) wherein R2is OCH2CHF2, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-24: This table provides 20 compounds C-24.G1 to C-24.G20 of formula (Ia) wherein R2is OCH2CHF2, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-25: This table provides 20 compounds rac-syn-C-25.G1 to rac-syn-C-25.G20 of formula (I) wherein R2is OCH2CHF2, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. 109939 FF (83198) 71 Table C-26: This table provides 20 compounds C-26.G1 to C-26.G20 of formula (Ia) wherein R2is NH2, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-27: This table provides 20 compounds rac-syn-C-27.G1 to rac-syn-C-27.G20 of formula (I) wherein R2is NH2, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-28: This table provides 20 compounds C-28.G1 to C-28.G20 of formula (Ia) wherein R2is NHCH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-29: This table provides 20 compounds rac-syn-C-29.G1 to rac-syn-C-29.G20 of formula (I) wherein R2is NHCH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-30: This table provides 20 compounds C-30.G1 to C-30.G20 of formula (Ia) wherein R2is N(CH3)2, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-31: This table provides 20 compounds rac-syn-C-31.G1 to rac-syn-C-31.G20 of formula (I) wherein R2is N(CH3)2, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-32: This table provides 20 compounds C-32.G1 to C-32.G20 of formula (Ia) wherein R2is SCH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-33: This table provides 20 compounds rac-syn-C-33.G1 to rac-syn-C-33.G20 of formula (I) wherein R2is SCH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-34: This table provides 20 compounds C-34.G1 to C-34.G20 of formula (Ia) wherein R2is SOCH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-35: This table provides 20 compounds rac-syn-C-35.G1 to rac-syn-C-35.G20 of formula (I) wherein R2is SOCH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-36: This table provides 20 compounds C-36.G1 to C-36.G20 of formula (Ia) wherein R2is SO2CH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-37: This table provides 20 compounds rac-syn-C-37.G1 to rac-syn-C-37.G20 of formula (I) wherein R2is SO2CH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-38: This table provides 20 compounds C-38.G1 to C-38.G20 of formula (Ia) wherein R2is OCH2CH3, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-39: This table provides 20 compounds rac-syn-C-39.G1 to rac-syn-C-39.G20 of formula (I) wherein R2is OCH2CH3, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-40: This table provides 20 compounds C-40.G1 to C-40.G20 of formula (Ia) wherein R2is cyclopropoxy, R3, R4, R5, R6, R7, R8, R9, R10are H, B2is C-H and G is as defined in Table A. Table C-41: This table provides 20 compounds rac-syn-C-41.G1 to rac-syn-C-41.G20 of formula (I) wherein R2is cyclopropoxy, R7is CH3, R3, R4, R5, R6, R8, R9, R10are H, B2is C-H and G is as defined in Table A. For example, compound C-41.G2 has the following structure: 109939 FF (83198) 72 Compound rac-syn-C-41.G2 EXAMPLES The Examples which follow serve to illustrate the invention and are not meant in any way to limit the invention. The compounds of the invention can be distinguished from known compounds by virtue of greater efficacy at low application rates, which can be verified by a person skilled in the art using the experimental procedures outlined in the Examples, using lower application rates if necessary, for example 60 ppm, 20 ppm or 2 ppm. Compounds of formula (I) may possess any number of benefits including, inter alia, advantageous levels of biological activity for protecting plants against diseases that are caused by fungi or superior properties for use as agrochemical active ingredients (for example, greater biological activity, an advantageous spectrum of activity, an increased safety profile (including improved crop tolerance), improved physico-chemical properties, or increased biodegradability). FORMULATION EXAMPLES Wettable powders a) b) c) active ingredients 25 % 50 % 75 % sodium lignosulfonate 5 % 5 % - sodium lauryl sulfate 3 % - 5 % sodium diisobutylnaphthalenesulfonate - 6 % 10 % phenol polyethylene glycol ether (7-8 mol of ethylene oxide) - 2 % - highly dispersed silicic acid 5 % 10 % 10 % Kaolin 62 % 27 % - The combination is thoroughly mixed with the adjuvants, and the mixture is thoroughly ground in a suitable mill, affording wettable powders that can be diluted with water to give suspensions of the desired concentration. Powders for dry seed treatment a) b) c) active ingredients 25 % 50 % 75 % light mineral oil 5 % 5 % 5 % highly dispersed silicic acid 5 % 5 % - Kaolin 65 % 40 % - Talcum - - 20 % 109939 FF (83198) 73 The combination is thoroughly mixed with the adjuvants, and the mixture is thoroughly ground in a suitable mill, affording powders that can be used directly for seed treatment. Emulsifiable concentrate active ingredients 10 % octylphenol polyethylene glycol ether (4-5 mol of ethylene oxide) 3 % calcium dodecylbenzene sulfonate 3 % castor oil polyglycol ether (35 mol of ethylene oxide) 4 % Cyclohexanone 30 % xylene mixture 50 % Emulsions of any required dilution, which can be used in plant protection, can be obtained from this concentrate by dilution with water. Dusts a) b) c) Active ingredients 5 % 6 % 4 % Talcum 95 % - - Kaolin - 94 % - mineral filler - - 96 % Ready-for-use dusts are obtained by mixing the combination with the carrier and grinding the mixture in a suitable mill. Such dusts can also be used for dry dressings for seed. Extruder granules Active ingredients 15 % sodium lignosulfonate 2 % carboxymethylcellulose 1 % Kaolin 82 % The combination is mixed and ground with the adjuvants, and the mixture is moistened with water. The mixture is extruded and then dried in a stream of air. Coated granules Active ingredients 8% polyethylene glycol (mol. wt.200) 3 % Kaolin 89 % The finely ground combination is uniformly applied, in a mixer, to the kaolin moistened with polyethylene glycol. Non-dusty coated granules are obtained in this manner. Suspension concentrates active ingredients 40 % propylene glycol 10 % nonylphenol polyethylene glycol ether (15 mol of ethylene oxide) 6 % 109939 FF (83198) 74 Sodium lignosulfonate 10 % carboxymethylcellulose 1 % silicone oil (in the form of a 75 % emulsion in water) 1 % Water 32 % The finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion. Flowable concentrate for seed treatment active ingredients 40 % propylene glycol 5 % copolymer butanol PO / EO 2 % Tristyrenephenole with 10-20 moles EO 2 % 1,2-benzisothiazolin-3-one (in the form of a 20% solution in water) 0.5 % monoazo-pigment calcium salt 5 % Silicone oil (in the form of a 75 % emulsion in water) 0.2 % Water 45.3 % The finely ground combination is intimately mixed with the adjuvants, giving a flowable concentrate from which solutions of any desired dilution can be obtained by dilution with water, that can be used directly for seed treatment. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion. Slow-Release Capsule Suspension 28 parts of the combination are mixed with 2 parts of an aromatic solvent and 7 parts of toluene diisocyanate / polymethylene-polyphenylisocyanate-mixture (8:1). This mixture is emulsified in a mixture of 1.2 parts of polyvinylalcohol, 0.05 parts of a defoamer and 51.6 parts of water until the desired particle size is achieved. To this emulsion a mixture of 2.8 parts 1,6-diaminohexane in 5.3 parts of water is added. The mixture is agitated until the polymerization reaction is completed. The obtained capsule suspension is stabilized by adding 0.25 parts of a thickener and 3 parts of a dispersing agent. The capsule suspension formulation contains 28% of the active ingredients. The medium capsule diameter is 8-15 microns. The resulting formulation is applied to seeds as an aqueous suspension in an apparatus suitable for that purpose. Formulation types include an emulsion concentrate (EC), a suspension concentrate (SC), a suspo-emulsion (SE), a capsule suspension (CS), a water dispersible granule (WG), an emulsifiable granule (EG), an emulsion, water in oil (EO), an emulsion, oil in water (EW), a micro-emulsion (ME), an oil dispersion (OD), an oil miscible flowable (OF), an oil miscible liquid (OL), a soluble concentrate (SL), an ultra-low volume suspension (SU), an ultra-low volume liquid (UL), a technical concentrate (TK), a dispersible concentrate (DC), a wettable powder (WP), a soluble granule (SG) or any technically feasible formulation in combination with agriculturally acceptable adjuvants. 109939 FF (83198) 75 ABBREVIATIONS CDCl3 deuterated chloroform DCM dichloromethane DMF dimethylformamide DMSO dimethyl sulfoxide DMSO-d6 deuterated Dimethyl sulfoxide EtOAc ethylacetate HCl hydrochloric acid h / hrs hour / hours LC-MS Liquid Chromatography Mass Spectrometry (LC-MS, LCMS or LC / MS) MgSO4magnesium sulphate Na2SO4 sodium sulphate rh relative humidity rt room temperature Rt retention time sat. saturated ssp. subspecies TLC thin layer chromatography THF tetrahydrofuran PREPARATION EXAMPLES The compounds of formula (I) according to the invention may be prepared using the synthetic techniques described both above and below. Throughout this description, temperatures are given in degrees Celsius and “m.p.” means melting point. LC / MS means Liquid Chromatography Mass Spectroscopy and the description of the apparatus, and the methods is as follows.1H NMR and19F NMR measurements were recorded on a Bruker 400MHz spectrometer, chemical shifts are given in ppm relevant to a TMS (1H) and CFCl3 (19F) standard. Spectra measured in deuterated solvents as indicated. Either one of the LC-MS methods below was used to characterize the compounds. The characteristic LC-MS values obtained for each compound were the retention time (“Rt”, recorded in minutes) and the measured molecular ion (M+H)+or (M-H)-. The following LC-MS^methods were used for the analysis of the compounds LC-MS^Method A: Spectra were recorded on a Mass Spectrometer from Waters (Acquity QDa Mass Spectrometer) equipped with an electrospray source (Polarity: Positive and Negative Polarity Switch), Capillary: 0.8 kV, Cone range: 25 V, Extractor: V (No extractor voltage for QDa detector) Source Temperature: 120°C, Desolvation Temperature: 600°C, Cone Gas Flow: 50 L / h, Desolvation Gas Flow: 1000 L / h, Mass range: 110 109939 FF (83198) 76 to 850 Da) and an Acquity UPLC from Waters: Quaternary solvent manager, heated column compartment, diode-array detector. Column: Acquity UPLC HSS T3 C18, 1.8 µm, 30 x 2.1 mm, Temp: 40°C, DAD Wavelength range (nm): 200 to 400, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.05 % HCOOH: gradient: 0 min 10% B; 0.-0.2 min 10-50% B; 0.2-0.6 min 50-100% B; 0.6-1.3 min 100% B; 1.3-1.4 min 100-10% B; 1.4-1.6 min 10% B; Flow (mL / min) 0.6. LC-MS Method B: Spectra were recorded on a Mass Spectrometer from Agilent Technologies (MSD-IQ mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, MS2 Scan, Capillary: 3.5 kV, Fragmentor: 110 V, Desolvation Temperature: 325°C, Gas Flow: 13 L / min, Nebulizer Gas: 55 psi, Mass range: 110 to 850 Da) and a 1290 Series HPLC from Agilent: quaternary pump, heated column compartment and diode-array detector. Column: AGILENT POROSHELL 120 EC-C18, 1.9 µm, 50 x 2.1 mm, Temp: 40°C, DAD Wavelength range (nm): 190 to 400, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.1 % HCOOH: gradient: 0-0.5 min 10% B, 90%A; 1.2-1.5 min 95% B, 05 %A; 1.8-2.5 min 10%B, 90%A; Flow (mL / min) 0.8 LC-MS Method C: Spectra were recorded on a Mass Spectrometer from Agilent Technologies (6410 Triple Quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, MS2 Scan, Capillary: 4.00 kV, Fragmentor: 100 V, Desolvation Temperature: 350°C, Gas Flow: 11 L / min, Nebulizer Gas: 45 psi, Mass range: 110 to 1000 Da) and a 1200 Series HPLC from Agilent: quaternary pump, heated column compartment and VWD detector. Column: KINETEX EVO C18, 2.6 µm, 50 x 4.6 mm, Temp: 40°C, Detector VWD Wavelength: 254 nm, Solvent Gradient: A = water + 5% Acetonitrile + 0.1 % HCOOH, B= Acetonitrile + 0.1 % HCOOH: gradient: 0 min 10% B, 90%A; 0.9-1.8 min 100% B; 1.8-2.2 min 100-10% B; 2.2- 2.5 min 10%B; Flow (mL / min) 1.8. Example P-1: Preparation of [2-(2,4-difluorophenyl)tetrazol-5-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4- dihydro-1H-isoquinolin-2-yl]methanone (Compound P-2, Table P) Compound P-2, Table P pyrazol-4-yl)isoquinoline 4-bromoisoquinoline (1.94 g, 9.1mmol, CAS [1532-97-4]) in N,N-Dimethylacetamide (10 mL) was treated with 5-methoxy-1-methyl-pyrazole (1.0 g, 8.3 mmol, CAS [1350323-88-4]) and potassium acetate (1.64 109939 FF (83198) 77 g, 16.6 mmol) and then purged with nitrogen for 10 mins. To this mixture was added Pd(OAc)2, (98 mg, 0.41mmol) and the reaction mixture as added and the reaction mass was heated at 140°C for 2 h. Upon reaction completion (monitoring by LCMS) the mixture was diluted with water (20 mL), and extracted with EtOAc (2x10 mL). The combined organic layers were dried over anhydrous Na2SO4, filtered and concentrated in vacuo to obtain the crude product. This was purified by combiflash chromatography eluting with 60% EtOAc in cyclohexane to obtain the title compound. LCMS (Method A): retention time, 0.38 min; m / z = 240.2 (M+H) Step 2: Preparation of 4-(5-methoxy-1-methyl-pyrazol-4-yl)-1,2,3,4-tetrahydroisoquinoline^ 1-methyl-pyrazol-4-yl)isoquinoline (100 mg, 0.4 mmol) in methanol (4 mL) was treated with sodium cyanoborohydride (4 mmol, 0.3 g) portion wise at rt. This mixture was carefully treated with concentrated^ HCl (3 mmol, 2 mL) at rt (gas evolution) and the mixture was stirred further at this temperature monitoring by LCMS and TLC. Upon reaction completion, the pH of the reaction mixture was adjusted to 10-11 by careful addition of aqueous 10% NaOH. The reaction mixture was then diluted with water and extracted with EtOAc (3 x 30 mL). The combined organic layers were washed with brine, dried over Na2SO4, filtered and concentrated in vacuo to obtain the crude product. This was used in the next step without further purification.^ LCMS (Method A). Retention time; 0.17 min, m / z = 244.3 (M+H).^ Step 3: Preparation of ethyl (2E)-2-(p-tolylsulfonylhydrazono)acetate (CAS [1576-35-8], 2 g, 10.73 mmol) in ethanol (40 mL) was treated with ethyl 2-oxoacetate (2.63 g, 12.88 mmol) at rt. The reaction mixture was stirred for 1 hr and the ethanol was removed by concentration in vacuo. The residue obtained was diluted with water and extracted with EtOAc. The organic phase was separated, and the solvent was evaporated in vacuo to afford ethyl (2E)- 2-(p-tolylsulfonylhydrazono)acetate, which was used as such for the next step (step 2). LCMS (Method C): ret. time 1.04 min, m / z = 271 [M+H].1H NMR (400 MHz, CDCl3) δ ppm 9.31 (s, 1 H) 7.85 (d, J=8.31 Hz, 2 H) 7.34 (d, J=8.07 Hz, 2 H) 7.23 (s, 1 H) 4.27 (q, J=7.09 Hz, 2 H) 2.44 (s, 3 H) 1.23 - 1.37 (m, 3 H). Step 4: Preparation of ethyl 2-(2,4-difluorophenyl)tetrazole-5-carboxylate 109939 FF (83198) 78 (1 g, 7.74 mmol) was solubilized in aqueous 6M HCl (deionized water) (6 mL, 36 mmol) and ethanol (5 mL) and was cooled to 0°C. To that solution was added sodium nitrite (0.64 g, 9.29 mmol) and the resulting reaction mixture was stirred for 1 hr at 0°C, and then added dropwise to a solution of ethyl (2E)-2-(p-tolylsulfonylhydrazono)acetate (2.3g, 8.51 mmol) in pyridine (20 mL) at -20°C. The reaction mixture was slowly allowed to warm to rt and then stirred for 5 hrs. The resulting reaction mixture was diluted with 1N HCl and the aqueous layer was extracted with EtOAc (20 mL X3). The combined organic layers were dried over Na2SO4 and concentrated in vacuo to give the crude product which was purified by column chromatography eluting with 30% EtOAc in hexane to give ethyl 2-(2,4-difluorophenyl)tetrazole-5-carboxylate as a reddish oil. LCMS (Method B): [M+H+] not detected; retention time = 1.10 min;1H NMR (400 MHz, CDCl3) δ ppm 7.86 - 7.94 (m, 1 H) 7.11 - 7.21 (m, 2 H) 4.60 (q, J=7.21 Hz, 2 H) 1.51 (t, J=7.13 Hz, 3 H) Step 5: Preparation of 2-(2,4-difluorophenyl)tetrazole-5-carboxylic acid carboxylate (300 mg, 1.18 mmol) in THF (3 mL) and water (1.5 mL) was added LiOH.H2O (0.113 mg, 4.72) at rt and the reaction mixture was stirred at rt for 30 min. The organic solvent was removed by concentration in vacuo, and the aqueous residue diluted with 2N HCl, and then extracted with EtOAc (3x20 mL). The combined organic phases were dried over Na2SO4, filtered, and concentrated in vacuo to afford reddish solid 2-(2,4-difluorophenyl)tetrazole-5-carboxylic acid. LCMS (Method C): ret. time = 0.87-1.11 min, 227 [M+H];1H NMR (400 MHz, DMSO-d6) δ ppm 8.10 (td, J=8.69, 5.75 Hz, 1 H) 7.73 - 7.88 (m, 1 H) 7.40 - 7.50 (m, 1 H) 3.36 - 3.63 (m, 3 H) 3.07 - 3.35 (m, 3 H) 1.99 (s, 1 H) 1.91 (s, 1 H) 1.24 (s, 1 H) Step 6: Preparation of [2-(2,4-difluorophenyl)tetrazol-5-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4-dihydro- 1H-isoquinolin-2-yl]methanone (Compound P-2, table P) A suspension of 2-(2,4-difluorophenyl)tetrazole-5-carboxylic acid (89 mg, 0.39mmol) in EtOAc (1.6 mL), was treated sequentially with 4-(5-methoxy-1-methyl-pyrazol-4-yl)-1,2,3,4-tetrahydroisoquinoline (100 mg, 0.33 mmol), N,N-diisopropylethylamine (0.29 mL, 217 mg, 1.64 mmol) and 1-propanephosphonic anhydride (T3P, 523 mg, 0.82 mmol). The solution was stirred at rt monitoring by TLC and LCMS. Upon reaction completion, the mixture was diluted with water (10 mL) and extracted with EtOAc (2x 10 mL). The combined organic layers were dried over Na2SO4, filtered and concentrated in vacuo to obtain the crude compound. This was purified 109939 FF (83198) 79 using reverse phase combiflash chromatography, eluting with 60-40 % water in acetonitrile to yield the pure title compound as a white gummy mass. LCMS (Method A) ret. time :1.09mins; m / z=452 (M+H);1H NMR (400 MHz, CDCl3).3:2 mixture of rotamers: δ ppm 7.81 - 8.07 (m, 1 H, both rotamers), 7.11 - 7.34 (m, 6 H, both rotamers), 7.10 (s, 1 H, minor rotamer), 7.02 (s, 1 H, major rotamer), 4.97 - 5.36 (m, 2 H, both rotamers), 4.58 (ddd, J=12.9, 4.8, 0.8 Hz, 1 H, minor rotamer), 4.22 - 4.43 (m, 1 H, both rotamers and 1H, major rotamer), 4.03 (dd, J=13.3, 8.2 Hz, 1 H, both rotamers), 3.89 (s, 3 H, minor rotamer), 3.75 (s, 3 H, minor rotamer), 3.69 (s, 3 H, major rotamer), 3.65 (s, 3 H, major rotamer); 19F NMR,1H decoupled (377 MHz, CDCl3) δ ppm -103.7 (d, J=8.3 Hz, 1 F, both rotamers), -115.0 (d, J=8.3 Hz, 1 F, minor rotamer), -115.2 (d, J=9.7 Hz, 1 F, major rotamer) Example P2: Preparation of [1-(2,4-difluorophenyl)triazol-4-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4- dihydro-1H-isoquinolin-2-yl]methanone (Compound P-1, Table P) Compound P-1, Table P triazole-4-carboxylate benzene (0.30 g, 1.8 mmol) in methanol (3.6 mL) was treated successively with copper(II)sulfate anhydrous (0.053 g, 0.33 mmol), sodium ascorbate (0.46 g, 2.3 mmol) in water (3.6 mL), and then methyl prop-2-ynoate (0.14 g, 0.14 mL, 1.7 mmol) The reddish reaction mixture was stirred for 2 days at rt monitoring by LCMS. The reaction mixture was then concentrated in vacuo, and the residue taken up in water and EtOAc. The organic layer was separated, washed with brine, and the separated organic layer dried over MgSO4, filtered, and concentrated in vacuo. The crude product was adsorbed onto Isolute® and purified over a silica gel cartridge (Rf200), eluting with cyclohexane / EtOAc, to give the title compound as a white solid. LC / MS (Method A); ret. time 0.79 min, m / z=240 [M+H];1H NMR (400 MHz, CDCl3) δ ppm 4.02 (s, 3 H) 7.09 - 7.17 (m, 2 H) 7.96 - 8.05 (m, 1 H) 8.59 (d, J=2.57 Hz, 1 H) Step 2: Preparation of 1-(2,4-difluorophenyl)triazole-4-carboxylic acid 109939 FF (83198) 80 A sample of methyl 1-(2,4-difluorophenyl)triazole-4-carboxylate (0.31 g, 1.3 mmol) was dissolved in THF (6.5 mL) and water (3.2 mL) under argon to give a pale brown solution. Then LiOH.H2O (0.047 g, 1.9 mmol) was then added and the mixture was stirred at rt. After 3 hrs LC / MS (desired mass at rt=0.63 min and consumption of starting material. The sample was concentrated in vacuo and the residue taken up in water and EtOAc, and the mixture acidified with 2N HCl. The organic layer was separated, dried over Na2SO4, filtered, and concentrated in vacuo to give the title compound as a white solid. LC / MS (Method A): ret. time 0.63 min, m / z=226 [M+H];1H NMR (400 MHz, DMSO-d6) δ ppm 7.27 - 7.52 (m, 1 H) 7.73 (ddd, J=11.10, 8.71, 2.57 Hz, 1 H) 7.95 (td, J=8.80, 5.87 Hz, 1 H) 9.15 (d, J=1.47 Hz, 1 H) 13.26 - 13.60 (m, 1 H) Step 3: Preparation of [1-(2,4-difluorophenyl)triazol-4-yl]-[4-(5-methoxy-1-methyl-pyrazol-4-yl)-3,4-dihydro-1H- isoquinolin-2-yl]methanone (Compound P-1, Table P) Prepared analogously to the method described in example P-1, step 6, using 1-(2,4-difluorophenyl)triazole-4- carboxylic acid and 4-(5-methoxy-1-methyl-pyrazol-4-yl)-1,2,3,4-tetrahydroisoquinoline in EtOAc, with T3P and N,N-diisopropylethylamine. Purification with using reverse phase combiflash chromatography, eluting with 60- 40 % water in acetonitrile yielded the pure title compound as a white gum. LCMS (Method A) ret. time :1.08 mins; m / z=451 (M+H);1H NMR (400 MHz, CDCl3) 2:1 mixture of rotamers. δ ppm 8.58 (d, J=2.6 Hz, 1 H, minor rotamer), 8.47 (d, J=2.6 Hz, 1 H, major rotamer), 7.79 - 8.02 (m, 1 H, both rotamers), 6.99 - 7.28 (m, 7 H, both rotamers), 5.81 (d, J=17.0 Hz, 1 H, minor rotamer), 5.39 (d, J=17.0 Hz, 1 H, minor rotamer), 5.17 (d, J=17.2 Hz, 1 H, major rotamer), 4.94 (d, J=17.2 Hz, 1 H, major rotamer), 4.86 (dd, J=13.1, 4.5 Hz, 1 H, major rotamer), 4.51 (dd, J=12.6, 4.9 Hz, 1 H, minor rotamer), 4.45 (dd, J=7.9, 4.5 Hz, 1 H, major rotamer), 4.32 (dd, J=9.3, 5.0 Hz, 1 H, minor rotamer), 4.23 (dd, J=13.2, 8.4 Hz, 1 H, major rotamer), 3.90 (s, 3 H, both rotamers), 3.75 (s, 3 H, minor rotamer), 3.68 (s, 3 H, major rotamer);19F NMR,1H decoupled (377 MHz, CDCl3) δ ppm -106.2 (d, J=8.2 Hz, 1 F, major rotamer), -106.2 (d, J=8.2 Hz, 1 F, minor rotamer), - 118.4 (d, J=8.2 Hz, 1 F, minor rotamer), -118.4 (d, J=8.2 Hz, 1 F, major rotamer) Examples of synthesized compounds are shown in Table P. Table P: Synthesized compounds and spectral and physical chemical data ))dyrt in]nEIUPAC name Moleculem(H er d+usohTa teRM[ em M ( [1-(2,4- difluorophenyl)triazol-4-yl]- P-1 [4-(5-methoxy-1-methyl- pyrazol-4-yl)-3,4-dihydro- 1.08 451 A 1H-isoquinolin-2- yl]methanone 109939 FF (83198) 81 [2-(2,4- difluorophenyl)tetrazol-5- P-2 yl]-[4-(5-methoxy-1-methyl- pyrazol-4-yl)-3,4-dihydro- 1.09 452 A 1H-isoquinolin-2- yl]methanone BIOLOGICAL EXAMPLES Example B1: Mycosphaerella graminicola (Septoria tritici) / liquid culture (Septoria blotch) Conidia of the fungus from cryogenic storage are directly mixed into nutrient broth (PDB potato dextrose broth). After placing a (DMSO) solution of test compound into a microtiter plate (96-well format), the nutrient broth containing the fungal spores is added. The test plates are incubated at 24 °C and the inhibition of growth is determined photometrically 4 to 5 days after application. The following compounds gave at least 80% control of Mycosphaerella graminicola at 6 ppm when compared to untreated control under the same conditions, which showed extensive disease development: P-1, P-2 Example B2: Alternaria solani / tomato / leaf disc (early blight) Tomato leaf disks cv. Baby are placed on agar in multiwell plates (24-well format) and sprayed with the formulated test compound diluted in water. The leaf disks are inoculated with a spore suspension of the fungus 2 days after application. The inoculated leaf disks are incubated at 23 °C / 21°C (day / night) and 80% rh under a light regime of 12 / 12 h (light / dark) in a climate cabinet and the activity of a compound is assessed as percent disease control compared to untreated when an appropriate level of disease damage appears on untreated check disk leaf disks (5 to 7 days after application). The following compounds gave at least 80% control of Alternaria solani at 200 ppm when compared to untreated control under the same conditions, which showed extensive disease development: P-1, P-2 Example B3: Phaeosphaeria nodorum (Septoria nodorum) / wheat / (Glume blotch) Wheat leaf segments cv. Kanzler are placed on agar in a multiwell plate (24-well format) and sprayed with the formulated test compound diluted in water. The leaf disks are inoculated with a spore suspension of the fungus 2 days after application. The inoculated test leaf disks are incubated at 20°C and 75% rh under a light regime of 12 h light / 12 h darkness in a climate cabinet and the activity of a compound is assessed as percent disease control compared to untreated when an appropriate level of disease damage appears in untreated check leaf disks (5 to 7 days after application). The following compounds gave at least 80% control of Phaeosphaeria nodorum at 200 ppm when compared to untreated control under the same conditions, which showed extensive disease development: P-1, P-2

Claims

109939 FF (83198) 82 CLAIMS 1. A compound of formula (I) wherein 1R is selected from hydrogen, or C3-C6-cycloalkyl; R2is selected from cyano, hydroxy, amino, C1-C4-alkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6- cycloalkyloxy, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4- alkylamino, di(C1-C4-alkyl)amino, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, or C1-C4- haloalkylsulfanyl; R3is selected from hydrogen, halogen, or C1-C4-alkyl; R4is selected from hydrogen, halogen, cyano, or C1-C4-alkyl; R5and R6are independently selected from hydrogen, or C1-C4-alkyl; R7is selected from hydrogen, C1-C4-alkyl, C1-C4-alkylcarbonyl, N-C1-C4-alkoxy-C-C1-C4-alkyl- carbonimidoyl, N-hydroxy-C-C1-C4-alkyl-carbonimidoyl, C1-C4-alkoxycarbonyl, N-methoxy-N-methyl- carbonyl, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl, phenyl, a 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein any of said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms independently selected from N, O or S, with the proviso that no more than one is O or S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted with 1, 2 or 3 substituents independently selected from halogen, cyano, carboxy, C1-C4-alkyl, C1-C4- haloalkyl, or C1-C4-alkoxy; and wherein said C3-C6-cycloalkyl is unsubstituted or substituted with 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4- alkoxy; B1is selected from CR10, or N; B2is selected from CR11, or N; R8and R9are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1- C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, or C3-C6- cycloalkyl; R10and R11are independently selected from hydrogen, halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, C1- C4-haloalkyl, C1-C4-haloalkoxy, C2-C4-alkenyloxy, C2-C4-alkynyloxy, C1-C4-alkylsulfanyl, C1-C4- alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-alkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, N-C1-C4- alkylamino, N,N-di(C1-C4-alkyl)amino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, N-C1-C4-alkoxy-C1-109939 FF (83198) 83 C4-alkyl-carbonimidoyl, N-hydroxy-C1-C4-alkyl-carbonimidoyl, C1-C4-alkylaminocarbonyl, di(C1-C4- alkyl)aminocarbonyl, C1-C4-alkylcarbonylamino, C1-C4-alkylsulfonylamino, trifluoromethylsulfonyloxy, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl; wherein said 5- or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6-membered heteroaryl and C3-C6- cycloalkyl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C2-alkyl-C1-C4-alkoxy; A is selected from A1, A2, A3, A4, A5, A6, A7, or A8 wherein the star (*) thenitrogen to Z1group; R12a, R13aR14aare selected from hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, or C2-C4-alkynyl; and Z1is selected from C1-C4-alkyl, phenyl, 5- or 6-membered heteroaryl, or C3-C6-cycloalkyl, wherein any of said 5 or 6-membered heteroaryl contains 1, 2, or 3 heteroatoms individually selected from N, O and S, with the proviso that only one is selected from O or S; and wherein any of said phenyl, 5- or 6- membered heteroaryl and C3-C6-cycloalkyl are unsubstituted or substituted by 1, 2 or 3 substituents independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4- haloalkoxy, C1-C4-alkylsulfanyl, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, or C2-C4-alkynyl; or an agrochemically acceptable salt, or N-oxide thereof.

2. The compound according to claim 1, wherein R1is C1-C3-alkyl; and R5and R6are hydrogen.

3. The compound according to claim 1 or claim 2, wherein R3is hydrogen, or C1-C3-alkyl; and R4is hydrogen or methyl.

4. The compound according to any one of claims 1 to 3, wherein R2is C1-C3-alkoxy, C1-C2-haloalkoxy, C1-C2-alkyl-C1-C4-alkoxy, C1-C2-alkylamino, di(C1-C2-alkyl)amino, or C1-C2-alkylsulfanyl.109939 FF (83198) 84 5. The compound according to claim 4, wherein R2is C1-C3-alkoxy, C1-C2-alkyl-C1-C4-alkoxy, or C1-C2- alkylsulfanyl.

6. The compound according to any one of claims 1 to 5, wherein R8and R9are hydrogen; B1is CR10; and B2is CR11; and R10and R11are independently selected from hydrogen, halogen, cyano, C1-C3 alkyl, or C1-C3-alkoxy.

7. The compound of formula (I) according to any one of claims 1 to 6, wherein R7hydrogen or C1-C3- alkyl.

8. The compound according to any one of claims 1 to 7, wherein A is selected from A1, A2, A3, A4 or A5wherein the staggered line denotes the position attached to the carbonyl-group, and the star the position attached to Z1.

9. The compound according to claim 8, wherein A is selected from A1 or A2 denotes the position attached to the carbonyl-group, and the star theto Z1.

10. The compound according to any one of claims 1 to 9, wherein Z1is selected from phenyl, or 5- or 6- membered heteroaryl; wherein any of said 5 or 6-membered heteroaryl contains 1 heteroatom selected from N, O and S; and wherein any of said phenyl and 5- or 6-membered heteroaryl are unsubstituted or substituted by 1 or 2 substituents independently selected from halogen, C1-C2-alkyl, C1-C2-alkoxy, or C2-C4-alkynyl.

11. The compound according to claim 10, wherein Z1is 4-fluorophenyl, 2,4-difluorophenyl, 3-fluoro-2- pyridyl, 5-fluoro-2-pyridyl, 2,6-difluoro-3-pyridyl, 3,4-difluoro-2-pyridyl, or 3,5-difluoro-2-pyridyl.109939 FF (83198) 85 12. An agrochemical composition comprising a fungicidally effective amount of a compound as defined in any one of claims 1 to 11.

13. The agrochemical composition according to claim 12, further comprising at least one additional active ingredient and / or an agrochemically-acceptable diluent or carrier.

14. A method of controlling or preventing infestation of useful plants by phytopathogenic microorganisms, wherein a fungicidally effective amount of a compound as defined in any one of claims 1 to 11, or a composition comprising said compound, is applied to the plants, to parts thereof or the locus thereof.

15. Use of a compound according to any one of claims 1 to 11 as a fungicide.

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