Detergent, corresponding method, corresponding kit and corresponding uses
A detergent composed of surfactant compounds from plant-based materials addresses the need for effective cleaning with minimal environmental impact by optimizing hydrocarbon residue proportions, achieving superior cleaning performance and adhering to consumer practices.
Patent Information
- Application Number
- PCT/EP2025/068549
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2024-07-09
- Filing Date
- 2025-06-30
- Publication Date
- 2026-01-15
AI Technical Summary
There is a need for detergents that are made wholly or partially from plant-based raw materials from temperate zones and exhibit good cleaning performance, while minimizing environmental impact and avoiding the use of biocides, with a composition that differs from surfactants derived from oil palm and coconut palm, and can be produced efficiently and used without requiring changes in consumer practices.
A detergent comprising a combination of surfactant compounds, including fatty acid salts, esters, ethers, and amides, derived from plant-based raw materials, with a specific proportion of hydrocarbon residues ranging from 7 to 23 carbon atoms, optimized to achieve good cleaning performance and minimal environmental footprint.
The detergent achieves superior cleaning performance while being produced from a high proportion of plant-based materials, reducing environmental impact, and adhering to consumer usage norms, without the need for biocides or significant process changes.
Smart Images

Figure EP2025068549_15012026_PF_FP_ABST
Abstract
Description
[0001] Detergents, corresponding processes, corresponding kits and corresponding uses
[0002] The present invention relates to a detergent containing a total amount of one or more surfactant compounds. The present invention further relates to a method for producing a detergent. The present invention also relates to a method for treatment, preferably cleaning, with a detergent. The present invention further relates to the use of a method for producing a detergent. The present invention further relates to the use of a method for treating, preferably cleaning, a surface. The present invention further relates to the use of a detergent for treating, preferably cleaning, a surface. The present invention further relates to a kit. The present invention further relates to the use of a kit for producing a detergent.The present invention also relates to the use of a kit for cleaning a surface. Furthermore, the present invention relates to the use of a kit in a process for producing a detergent. Details of each will become apparent from the appended claims and the following description. The present invention lies in the technical field of sustainable detergent preparations, i.e., detergent preparations that are based wholly or partially on renewable raw materials.
[0003] Document EP 2 592 134 B1 describes the use of a washing and cleaning agent in liquid or gel form for hard surfaces made of glass, mirrors, ceramics, plastics, metal or wood, both painted and unpainted, or textiles or fibers; rock or earth, in the household, industrial, commercial and institutional sectors, ships, port, sports and leisure facilities, oil and mining, particularly preferably in the household and commercial sectors; containing one or more surfactants selected from the groups comprising: a) alkali or ammonium salts of fatty acids with the general formula R(O)OM, where M is an alkali metal cation or ammonium; b) fatty acid esters with the general formula R(O)OR'; c) ethers of fatty alcohols with the general formula ROR'; d) fatty acid amides with the general formula R(O)NR'; e) fatty acid imines of the general formula R(NR')NR"R"'; f) secondary, tertiary, or quaternary fatty amines or fatty ammonium salts of the general formulas RNHR'.RNR'R" and (R)(R')(R")(R"')N+X-, g) and mixtures thereof, wherein i) R' to R'" represent organic or inorganic hydrophilic residues and X- represents an anion; ii) R represents the lipophilic part of the surfactant and consists of a linear, branched or unbranched, saturated or unsaturated hydrocarbon chain with 8 to 24 carbon atoms, and the proportion of hydrocarbon chains with 18 or more carbon atoms exceeds 60 wt.%, based on the total hydrocarbon chain content R of the surfactants contained in the detergent and cleaning agent; and the proportion of unsaturated hydrocarbon chains R is between 50-100 wt.%, based on the total hydrocarbon chain content R of the surfactants contained in the detergent and cleaning agent; and one or more surfactants selected from a)-g) based on plant-derived raw materials are included; and wherein 80-100 wt. % of the surfactants are based on vegetable oils, waxes, fats or resins from the temperate zone,Selected from the group of plants including: amaranth, anise, apple, apricot, arnica, avocado, cotton, borage, broccoli, hemp, hazelnut, beech, boxwood, thistle, spelt, peanut, tiger nut, lilac, garden cress, barley, pomegranate, oat, blueberry, elderberry, jasmine, currant, St. John's wort, jojoba, camellia, chamomile, cherry, caraway, carrot, coriander, mullein, crambe, cypress spurge, pumpkin, Iberian dragonhead, lavender, camelina, flaxseed, privet, lupin, alfalfa, corn, almond, mirabelle plum, mango, poppy, evening primrose, olive, oilseed radish, oilseed rocket, pecan, peach, plum, pistachio, cranberry, rapeseed, rice, calendula, turnip rape, safflower, sage, sea buckthorn, black cumin, sesame Sesame leaf, mustard, sunflower, soy, tobacco, walnut, grape, wheat, meadowsweet and wild rose,as well as their combinations based on the total content of surfactants contained in the washing and cleaning agent; and wherein one or more surfactants selected from a)-g) are based on a mixture of hydrocarbon chains R of different chain lengths and degrees of saturation corresponding to their occurrence in natural vegetable oil according to the list above, and wherein at least one surfactant selected from a) to g) is included which is not a soap.
[0004] Document PL 206 552 B1 discloses a washing agent for machines and engines, characterized in that it contains an aqueous solution of fatty acid methyl ester oxyethylates obtained by direct oxyethylation of fatty acid methyl esters from rapeseed oil with a chain length of C16-C20 and a concentration of 15-55 cg / g.
[0005] The book “Natural Soap - Pure Pleasure” by the author “Claudia Kasper”, ISBN: 978-3-902540-10-2, published in 2007 by Freya Verlag, reveals on pages 57 to 60 the production of a “soft soap from 1 kg of rapeseed oil” and its use for cleaning.
[0006] In total, a large number of soaps made from vegetable oils of the temperate zone are known to those skilled in the art in the field of the present invention.
[0007] Document WO 2023 / 052616 A1 discloses specified sugar amides and mixtures thereof.
[0008] In the field of the present invention, there is a need for detergents that are made wholly or partially from plant-based raw materials from temperate zones and that exhibit advantageously good cleaning performance. The cleaning performance of corresponding agents known from the prior art is considered insufficient in the field of the present invention.
[0009] Detergents that are wholly or partially derived from plant-based raw materials from temperate zones and exhibit advantageously good cleaning properties are often perceived as particularly beneficial by consumers in the field of the present invention and are in high demand. Therefore, there is a particularly high need for the supply of such detergents. Specifically, there is a need for detergents with advantageously good cleaning properties and the highest possible proportion of surfactants whose hydrophobic molecular component is derived from plant-based raw materials from temperate zones. There is also a need for detergents with advantageously good cleaning properties and the highest possible proportion of surfactants whose hydrophilic molecular component is derived from plant-based raw materials from temperate zones.There is a particular need for detergents with a beneficially good cleaning effect and with the highest possible proportion of surfactants that are made entirely from plant-based raw materials from the temperate zone.
[0010] In the field of the present invention, the use of detergents containing surfactants derived from plant-based raw materials obtained from the oil palm (including oil palm fruit) is often considered problematic. Similarly, in the field of the present invention, the use of detergents containing surfactants derived from plant-based raw materials obtained from the coconut palm (including coconut palm fruit) is often considered problematic. Therefore, there is a need for detergents with the lowest possible proportion of surfactants derived from plant-based raw materials obtained from the oil palm (including oil palm fruit) and also the lowest possible proportion of surfactants derived from plant-based raw materials obtained from the coconut palm (including coconut palm fruit).There is a need for detergents whose surfactant compounds have a composition that differs from surfactant compounds known from general technical knowledge and produced from oil palm and / or coconut palm. The use of surfactant compounds based on oil palm and / or coconut palm is increasingly common and is being strongly rejected in the field of the present invention.
[0011] In the field of the present invention, there is a need for detergents that are produced with the lowest possible overall environmental impact. Specifically, there is a need for detergents produced with the most favorable carbon footprint possible. Therefore, in temperate zones, there is a need for detergents containing surfactants produced from plant-based raw materials from temperate zones, particularly because this is associated with advantageously short transport routes and often advantageously low carbon emissions. In the field of the present invention, there is a need for detergents whose use and subsequent degradation are associated with the lowest possible overall environmental impact.Avoiding the release of surfactants after use in a cleaning task is often not preferred, as it involves an undesirably high level of equipment effort, which is often considered extremely disadvantageous in the field of the present invention.
[0012] In the field of the present invention, there is a need for detergents that can be added using the additives customary in the field of the present invention.
[0013] In the field of the present invention, there is a need for detergents that can be used by the respective consumer in the manner customary for the respective consumer, without requiring any disadvantageous changes in use compared to detergents known to the consumer. For example, in the field of the present invention, consumers regularly prefer to work at the usual temperatures and with the usual contact times.
[0014] The use of biocides is undesirable in many cases in the field of the present invention due to the associated disadvantages for the environment. Therefore, there is a need in the field of the present invention for detergents that do not contain added biocides.
[0015] In many cases, in the field of the present invention, there is a need for a uniform formulation concept for detergents, with which detergents can be produced for as many different uses and / or application areas as possible.
[0016] In the field of the present invention, there is a need for detergents that can be produced using a manufacturing process that is carried out with an advantageously low time expenditure and / or with an advantageously low energy requirement.
[0017] In the field of the present invention, there is a need for detergents that, after release into the environment, are degraded by environmental organisms with advantageously few negative effects on the environment. In the field of the present invention, there is a need for detergents that are advantageously well compatible with packaging made from renewable raw materials and / or packaging made from recycled materials.
[0018] In the field of the present invention, there is a particular need for detergents that fulfill as many of the aforementioned needs as possible and / or solve as many of the aforementioned problems as possible, while also exhibiting advantageously good cleaning performance.
[0019] Furthermore, in the field of the present invention there is a need for detergents that fulfill as many of the aforementioned needs as possible and / or solve as many of the aforementioned problems as possible, and can be produced without disadvantageously expensive conversion of production facilities that are set up for the production of detergents from the prior art.
[0020] The invention is defined in the appended claims. Preferred aspects of the present invention will also become apparent from the following description, including the examples. Where specific embodiments are designated as preferred for an aspect of the invention (detergent, method for producing a detergent, method for treating, preferably cleaning, a surface with a detergent, use of a method for producing a detergent, use of a method for treating, preferably cleaning, a surface, use of a detergent for treating, preferably cleaning, a more specifically identified surface, kit, use of a kit for producing a detergent, use of a kit for cleaning a surface, use of a kit in a method for producing a detergent), the corresponding embodiments shall also apply, mutatis mutandis, to the other aspects of the present invention.Preferred individual features of aspects of the invention (as defined in the claims and / or disclosed in the description) can be combined with each other and are preferably combined with each other, unless otherwise apparent to the person skilled in the art from the present text in the individual case.
[0021] Likewise, the disadvantages of the prior art mentioned above also apply to the other aspects of the present invention; the considerations set forth above regarding various problems apply accordingly. The primary problem of the present invention, as well as related further problems, are solved by a detergent comprising a total amount of one or more surfactant compounds, each independently selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula
[0022] R-CH2-OR 1 iv) Fatty acid amides with the general formula
[0023] RC(O)NR 1 R 2; each independently of the other
[0024] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total of 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein the total mass of the residues R of the surfactant compounds present in the detergent is one of the several surfactant compounds selected from i) to iv) a proportion of hydrocarbon residues R with a total of 17 to 23 carbon atoms in the range of 14 wt.% to 59 wt.% and a proportion of hydrocarbon residues R with a total of
[0025] comprising 7 to 10 carbon atoms, preferably 7 to 9 carbon atoms, of more than 30 wt.% and wherein R 1 and / or R 2 Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant.
[0026] Surprisingly, it has been shown that a detergent (as described above, preferably as referred to above as preferred) comprising a proportion of long-chain surfactants, such as those advantageously produced simply from plant-based raw materials of the temperate zone, in combination with a proportion of short-chain surfactants, such as those also produced from plant-based raw materials of the temperate zone by suitable chemical processes, solves the stated problems in a particularly positive manner and / or in a particularly positive combination within the range defined above, and avoids the problems known from the prior art in a particularly positive manner. The detergent according to the invention provides advantageously good washing and / or cleaning performance, and is advantageously produced simply from plant-based raw materials of the temperate zone.
[0027] The fact that the R group forms a hydrophobic part of the respective surfactant compound means that the corresponding surfactant compound contains other hydrophobic parts besides R. The fact that the R group forms the hydrophobic part of the respective surfactant compound means that R completely constitutes the hydrophobic part of the surfactant.
[0028] The terms “hydrophilic part” and “hydrophobic part” are known in the field of surfactant compounds from general technical knowledge; the person skilled in the art assigns the corresponding molecular parts in a unique way based on their general technical knowledge.
[0029] The term "detergent" in this text has the meaning defined in Regulation (EC) No 648 / 2004 of the European Parliament and of the Council of 31 March 2004 on detergents (Text with EEA relevance) (OJ L 104, 8.4.2004, p. 1). Within the context of the present invention, the term "detergent" therefore also encompasses the terms "washing agent" and "cleaning agent" (including cosmetic cleaning agents). Other terms used in this text also have the same meaning as in the aforementioned Regulation, unless the specific context indicates otherwise.
[0030] The term "surfactant compounds" (surfactants) describes a substance whose chemical structure is characterized by a nonpolar (hydrophobic) and a polar (hydrophilic) molecular part. This amphiphilic molecular structure of a surfactant compound results in a certain degree of solubility in both hydrophilic and hydrophobic liquids. Furthermore, this structure gives rise to the surface activity characteristic of surfactants. Through their surface activity, surfactants reduce surface tension, thereby promoting the wetting of surfaces (for example, the wetting of a surface to be cleaned and / or the wetting of contaminants by water) and improving the miscibility (emulsification) of two liquids (compared to the miscibility of these liquids in the absence of the surfactant compound).Surfactant compounds are known from the prior art, and a person skilled in the art can determine from their general technical knowledge and / or the prior art whether a substance is a surfactant compound or not. In particular, a multitude of surfactant compounds from the surfactant classes of anionic surfactants, nonionic surfactants, cationic surfactants, and amphoteric surfactants are known to the person skilled in the art.
[0031] In the production of surfactants made from plant-based raw materials, preferably from plant-based raw materials of temperate zones, and particularly preferably from vegetable oils of temperate zones, the manufacturing process often results in mixtures of surfactant compounds. This is frequently due, for example, to the fact that plant-based raw materials, especially vegetable oils, regularly contain fatty acids with varying chain lengths and degrees of saturation, and this pattern is partially retained during the production of surfactants.
[0032] For example, PEG-4 rapeseedamide (CAS number: 85536-23-8) is produced from rapeseed oil and is a mixture of surfactant compounds (because the various fatty acid residues present in rapeseed oil are also found wholly or partially in PEG-4 rapeseedamide), each selected from group iv). Thus, PEG-4 rapeseedamide contains several surfactant compounds. Within the scope of the present invention, it is preferred if the detergent (as described above, preferably as referred to above as preferred) comprises several surfactant compounds from a common subgroup i) to iv). In many cases, it is therefore preferred that the detergent (as described above, preferably as referred to above as preferred) comprises mixtures of surfactant compounds such as those resulting from the production of surfactants from vegetable oils.The CAS number, short for Chemical Abstracts Service number, is an internationally valid identification system for chemical substances. Every known chemical compound, as well as biosequences, alloys, and polymers, is assigned a specific CAS number that uniquely identifies the substance.
[0033] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, comprising a total amount of one or more surfactant compounds, each independently selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula
[0034] R-CH2-OR 1iv) Fatty acid amides with the general formula
[0035] RC(O)NR 1 R 2 ; each independently of the other
[0036] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total of 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein the total mass of the residues R of the one or more surfactant compounds present in the detergent selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total of 17 to 23 C atoms in the range of 14 wt.% to 59 wt.% and a proportion of hydrocarbon residues R with a total of 7 to 10 C atoms of over 30 wt.%, and wherein R 1 and / or R 2 Residues are those that form or comprise a hydrophilic molecular portion of the respective surfactant, and wherein preferably the residues R 1 and / or R 2open-chain residues are or the residue R 1 an open-chain residue and R 2 Hydrogen is.
[0037] The effects and advantages described above in connection with the detergent according to the invention are realized here in a particularly advantageous way.
[0038] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, comprising a total amount of one, two, three, or more surfactant compounds, each independently selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula
[0039] R-CH2-OR 1iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other
[0040] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total of 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein the total mass of the residues R of the one or more surfactant compounds present in the detergent selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total of 17 to 23 carbon atoms in the range of 14 wt.% to 59 wt.% and a proportion of hydrocarbon residues R with a total of
[0041] comprises 7 to 10 carbon atoms of over 30 wt.% and wherein R 1 and / or R 2Residues are those that form or comprise a hydrophilic molecular portion of the respective surfactant and wherein, preferably for surfactant compounds, selected from: iv) fatty acid amides with the general formula RC(O)NR 1 R 2 , applies:
[0042] - the remains R 1 and / or R 2 are open-chain residues or the residue R 1 is an open-chain residue and R 2 is hydrogen. The effects and advantages described above in connection with the detergent according to the invention are realized here in a particularly advantageous manner.
[0043] That preferably for surfactant compounds selected from: iv) fatty acid amides with the general formula RC(O)NR 1 R 2 , the following applies: the remainders R 1 and / or R 2 are open-chain residues or the residue R 1 is an open-chain residue and R 2The hydrogen content applies to all fatty acid amides in the detergent, provided that fatty acid amides are present in the detergent.
[0044] In many cases, a detergent (as described above, preferably referred to as preferred above) is preferred, wherein R is a hydrocarbon residue having 7 to 23 carbon atoms, and wherein R is selected from:
[0045] - linear hydrocarbon residue,
[0046] - branched hydrocarbon residue,
[0047] - monounsaturated hydrocarbon residue,
[0048] - doubly unsaturated hydrocarbon residue,
[0049] - triple unsaturated hydrocarbon residue,
[0050] - saturated hydrocarbon residue and
[0051] - possible combinations thereof.
[0052] In accordance with the usual understanding of those skilled in the art, within the scope of the present invention, the term "hydrocarbon residue" is understood to mean an organic residue consisting exclusively of carbon atoms and hydrogen atoms. R denotes a hydrocarbon residue and therefore, within the scope of the present invention, consists exclusively of carbon atoms and hydrogen atoms. Unless otherwise specified in a particular case, the term "hydrocarbon residue" within the scope of the present invention includes saturated hydrocarbon residues, monounsaturated hydrocarbon residues, polyunsaturated hydrocarbon residues, linear hydrocarbon residues, and branched hydrocarbon residues, as well as possible combinations thereof.
[0053] Alkali salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation (as described above, preferably referred to as preferred above) are known to those skilled in the art as soaps.
[0054] In the case of ammonium salts of fatty acids with the general formula RC(O)OM, wherein M is a profaned ammonia or a profaned primary, secondary or tertiary amine compound (as described above, preferably as referred to above as preferred), the following profaned primary, secondary or tertiary amine compounds are preferred within the scope of the present invention: profaned monoethanolamine (profaned MEA), profaned diethanolamine (profaned DEA), profaned triethanolamine (profaned TEA), profaned methyldiethanolamine (profaned MDEA), and profaned diisopropanolamine (profaned DIPA).
[0055] Fatty acid esters with the general formula RC(O)OR 1are known to experts.
[0056] Preferred fatty acid esters with the general formula RC(O)OR 1 (as described above, preferably as referred to above as preferred) are in many cases within the scope of the present invention:
[0057] Fatty acid alkyl ester ethoxylates;
[0058] Fatty acid alkyl ester ethoxylate / propoxylate (EO / PO);
[0059] Fatty acid acetates / fatty acid carboxymethyl esters; fatty acid ethoxylate acetates / fatty acid carboxymethyl ester ethoxylates;
[0060] Fatty acid monoesters of glycerol (monoglycerides);
[0061] Fatty acid diesters of glycerol (diglycerides);
[0062] Ethoxylated fatty acid monoesters of glycerol (monoglyceride EO ether);
[0063] Ethoxylated fatty acid diesters of glycerol (diglyceride EO ethers);
[0064] Monoglyceride EO ether acetates;
[0065] Diglyceride EO ether acetates;
[0066] Monoglyceride EO ether diacetate;
[0067] Fatty acid monoesters of higher polyols (C4, C5, C6), preferably erythritol, xylitol, sorbitol;
[0068] Ethoxylated fatty acid monoesters of higher polyols (C4, C5, C6), preferably erythritol, xylitol, sorbitol;
[0069] Ethoxylated fatty acid diesters of higher polyols (C4, C5, C6), preferably erythritol, xylitol, sorbitol;
[0070] Fatty acid monoesters of aldoses (C5, C6), ketoses (C5, C6) and discharides, preferably xylose, fructose, glucose, sucrose, trehalose, mannose erythritol;
[0071] Fatty acid monoesters of sorbitan;
[0072] Fatty acid diesters of sorbitan;
[0073] Ethoxylated fatty acid monoesters of sorbitan;
[0074] Ethoxylated fatty acid diesters of sorbitan.
[0075] Ethers of fatty alcohols with a general formula R-CH2-OR 1(as described above, preferably as referred to above as preferred) are known to those skilled in the art. Preferred ethers of fatty alcohols (as described above, preferably as referred to above as preferred) are, in many cases within the scope of the present invention:
[0076] Fatty alcohol alkoxylates (EO, EO / PO),
[0077] fatty alcohol alkoxylate acetates,
[0078] Fatty alcohol polyglycerol ethers / alkyl polyglycerols,
[0079] Alkyl glycosides, preferably alkyl polyglycosides,
[0080] Alkyl sulfates and
[0081] Alkyl ether sulfates.
[0082] The formula: R-CH2-OR 1 The compounds included in the present invention also include corresponding sulfuric acid esters. In some cases, a detergent (as described above, preferably as referred to above as preferred) is preferred that does not contain sulfuric acid esters of the formula R-CH2-OR.1 , preferably does not include any sulfuric acid esters at all.
[0083] Fatty acid amides with the general formula RC(O)NR 1 R 2 (as described above, preferably as referred to above as preferred) are known to the person skilled in the art.
[0084] Preferred fatty acid amides (as described above, preferably referred to as preferred above) are, in many cases within the scope of the present invention:
[0085] Fatty acid amide alkoxylates (EO, EO / PO),
[0086] N-Acyl-N-Alkyl-Glucamine,
[0087] Alkyl-amidopropyl betaine,
[0088] Alkyl-amidopropyl-N-oxide,
[0089] Amphoacetate,
[0090] Ammphodiacetate and
[0091] N-acyl amino acids. Compounds defined by the designation "N-acyl-N-alkyl-glucamines" are also known to those skilled in the art in the field of the present invention under the designation "glucamides".
[0092] With a detergent (as described above, preferably as referred to above as preferred) having a proportion of hydrocarbon residues R with 17 to 23 carbon atoms in the range of 14% to 59% and a proportion of hydrocarbon residues R with a combined total of 7 to 10 carbon atoms, preferably 7 to 9 carbon atoms, of over 30%, particularly advantageous cleaning results are achieved and at the same time many of the aforementioned requirements are met. Surprisingly, it has been possible to provide a detergent whose surfactants can be produced to an advantageously high proportion, preferably completely, from plant raw materials from plants of the temperate zone, and which at the same time exhibits better cleaning performance than is known from corresponding agents in the prior art.
[0093] Within the scope of the present invention, and in accordance with general technical knowledge, the term "open-chain" refers to residues consisting of a number of covalently bonded atoms, wherein the residues are non-cyclic and do not include any cyclic components. It is known to those skilled in the art that the term "open-chain" is used synonymously with the term "acyclic"—less commonly also "non-cyclic"—in general technical knowledge.
[0094] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 6.5 wt.%, preferably more than 10 wt.%, particularly preferably more than 20 wt.%, and most preferably more than 30 wt.%; and / or, in many cases preferably, wherein the total mass of the one or more surfactant compounds selected from i) to iv) with a hydrocarbon residue R having a total of 17 to 23 carbon atoms comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 50 wt.%, preferably more than 60 wt.%, and particularly preferably more than 70 wt.%.-%; and / or, in many cases preferably “and”, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with hydrocarbon residues R of a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, of more than 30 wt.%, preferably more than 32 wt.%, particularly preferably more than 35 wt.%, most preferably more than 38 wt.%.
[0095] In many cases, a detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 6.5 wt.%, preferably more than 10 wt.%, particularly preferably more than 20 wt.%, and most preferably more than 30 wt.%. This means that all the compounds selected from i) to iv) present in the detergent, considered together, have a proportion of unsaturated hydrocarbon residues R in the total mass of the hydrocarbon residues R present in the detergent (as described above, preferably referred to as preferred above) in the aforementioned ranges.
[0096] The corresponding surfactant compounds are regularly produced from plant-based raw materials from temperate zones, preferably from vegetable oils from temperate zones, in a particularly advantageous and simple manner. Since the corresponding vegetable oils have a correspondingly high proportion of unsaturated hydrocarbon chains, hardening (saturating the double bonds present in the vegetable oil with hydrogen) is generally unnecessary and, in many cases, also undesirable within the scope of the present invention. Vegetable oils from temperate zones are regularly used as the plant-based raw materials in the production of surfactant compounds from plant-based raw materials from temperate zones.
[0097] In many cases, a refined vegetable oil is preferably used in the production of surfactant compounds. However, in other cases, depending on the specific requirements (for example, if the production of the surfactant compounds is to be carried out in a particularly advantageous and simple manner and at the same time no high odor requirements are placed on the detergent), it is also preferable to use an unrefined vegetable oil for the production of the surfactant compounds.
[0098] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the one or more surfactant compounds selected from i) to iv) present in the detergent, having a hydrocarbon residue R with a total of 17 to 23 carbon atoms, comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 50 wt.%, preferably more than 60 wt.%, and particularly preferably more than 70 wt.%. Corresponding surfactant compounds are (as explained above) regularly produced in a particularly advantageously simple manner from vegetable raw materials of the temperate zone, preferably from vegetable oils of the temperate zone, and in many cases lead to embodiments of the detergent according to the invention that exhibit particularly good cleaning performance.
[0099] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with hydrocarbon residues R having a total number of 7 to 10 C atoms of more than 30 wt.%, preferably more than 32 wt.%, particularly preferably more than 35 wt.%, and most preferably more than 38 wt.%, wherein the total mass of the one or more surfactant compounds selected from i) to iv) having a hydrocarbon residue R having a total number of 17 to 23 C atoms preferably comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues of more than 50 wt.%, preferably more than 60 wt.%, and particularly preferably more than 70 wt.%.With the appropriate proportions, embodiments of the detergent according to the invention are obtained in many cases which exhibit particularly advantageous cleaning properties and / or particularly advantageous washing properties. A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with hydrocarbon residues R with a total number of 7 to 9 carbon atoms of more than 30 wt.%, preferably more than 32 wt.%, particularly preferably more than 35 wt.%, and most preferably more than 38 wt.%, and wherein the total mass of the one or more surfactant compounds selected from i) to iv) with a hydrocarbon residue R with a total number of 17 to 23 carbon atoms preferably comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues of more than 50 wt.%, preferably more than 60 wt.%.-%, particularly preferably over 70 wt.%. With the corresponding proportions, embodiments of the detergent according to the invention are obtained in many cases which exhibit particularly advantageous cleaning properties and / or particularly advantageous washing properties.
[0100] In the combination according to the invention with a proportion of hydrocarbon residues R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, of over 30 wt.%, particularly positive cleaning results are obtained in many cases with the above-defined proportions of surfactant compounds with unsaturated hydrocarbon residues R (as described above, preferably as referred to above as preferred).
[0101] The disadvantages known from the prior art that are associated with the presence of double bonds in surfactants are, in many cases, completely or partially avoided in the detergent according to the invention.
[0102] A preferred detergent (as described above, preferably as referred to above as preferred) further comprises a total amount of one or more surfactant compounds, each independently selected from the group consisting of: v) Secondary or tertiary fatty amines with the general formula RNR 1 R 2 , each independently of the other
[0103] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein R 1 and / or R 2 Residues are those that form or comprise the hydrophilic molecular component of the respective surfactant.
[0104] In many cases, within the scope of the present invention, it is preferred that a residue is selected from R 1 and R 2one H atom and the other residue selected from R 1 and R 2 a hydrophilic residue that is not a hydrogen atom.
[0105] All state-of-the-art products and combinations of the residues R, R 1 and R 2 In some cases, such combinations of the residues R, R are preferred within the scope of the present invention. 1 and R 2 , which lead to adverse cleaning results and / or adverse washing results of the detergent according to the invention, are in many cases less preferred within the scope of the present invention.
[0106] Secondary or tertiary fatty acids with the general formula RNR 1 R (as described above, preferably as referred to above as preferred) are known to the person skilled in the art.
[0107] Preferred secondary or tertiary fatty amines with the general formula RNR 1 R 2(as described above, preferably as referred to above as preferred) are in many cases within the scope of the present invention:
[0108] Alkyliminoacetates,
[0109] Alkyliminopropionate,
[0110] AI kyl amine od i acetate and
[0111] Alkyliminodipropionate.
[0112] A detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent additionally contains a total amount of one or more surfactant compounds selected independently from the group consisting of: v) Secondary or tertiary fatty amines with the general formula RNR 1 R 2 where the remainder R 1 a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; and / or the residue R 1a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound, and / or the residue R 1 a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound, and where the residue R 2 a hydrogen atom (H); and / or the residue R 1 a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound, and where the residue R 2 a hydrogen atom (H); and / or the residue R 1 a remainder according to the formula CH2COOM and where the remainder is R 2a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; and / or the residue R 1 a remainder according to the formula CH2CH2COOM and where the remainder is R 2 a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound.
[0113] A preferred detergent (as described above, preferably as referred to above as preferred) further comprises a total amount of one or more surfactant compounds, each independently selected from the group consisting of: v) Secondary or tertiary fatty amines with the general formula RNR 1 R 2 , each independently of the other
[0114] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein R 1 and / or R 2 Residues are those that form or comprise the hydrophilic molecular portion of the respective surfactant; and / or from the group consisting of: vi) Hydrotropic surfactants with a general formula selected from the group consisting of:
[0115] Ethers of fatty alcohols with the general formula R 5 -CH2-OR 1
[0116] Fatty acid amides with the general formula R 5 -C(O)NR 1 R 2
[0117] Secondary or tertiary fatty amines with the general formula R 5 NR 1 R 2 , where R 5a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total number of less than 7 carbon atoms, preferably less than 6 carbon atoms, which forms the hydrophobic part of the hydrotropic surfactant, and wherein R 1 and / or R 2 residues are those that form or comprise the hydrophilic molecular portion of the respective surfactant; and / or from the group consisting of: vii) microbial biosurfactants, preferably selected from the group consisting of: sophorolipids and rhamnolipids.
[0118] Designs of the remains R 1 and / or R 2 which are designated as preferred within the scope of the present invention are also referred to as residues R 1 and / or R 2 preferred in the hydrotropic surfactants defined above.
[0119] Within the scope of the present invention, the term "hydrotropic surfactants" describes surfactant compounds, i.e., compounds with an amphiphilic molecular structure, wherein a hydrocarbon residue (R) 5 ) with a total number of less than 7 carbon atoms forms the hydrophobic part of the hydrotropic surfactant.
[0120] Hydrotropic surfactants are known to those skilled in the art from their general knowledge as solubility enhancers for surfactants that do not dissolve satisfactorily in water without such solubilizers. Their use therefore facilitates the production of clear aqueous surfactant solutions in many cases, as are preferred in the field of the present invention. Furthermore, hydrotropic surfactants are often suitable for modifying the flow behavior and / or the temperature-dependent storage stability (clarity / turbidity).
[0121] Hydrotropic surfactants are known to those skilled in the art from their general knowledge and prior art. Hydrotropic surfactants from the class of anionic hydrotropic surfactants, the class of nonionic hydrotropic surfactants, the class of cationic hydrotropic surfactants, and the class of amphoteric hydrotropic surfactants are known to those skilled in the art. In many cases, within the scope of the present invention, it is preferred that a residue selected from R 1 and R 2 one H atom and the other residue selected from R 1 and R 2 a hydrophilic residue that is not a hydrogen atom.
[0122] Within the scope of the present invention, it is also preferred in many other cases that the detergent according to the invention is essentially free, preferably completely free, of surfactant compounds selected from the group consisting of: vi) hydrotropes with a general formula selected from the group consisting of:
[0123] Ethers of fatty alcohols with the general formula R 5 -CH2-OR 1
[0124] Fatty acid amides with the general formula R 5 -C(O)NR 1 R 2
[0125] Secondary or tertiary fatty amines with the general formula R 5 NR 1 R 2 , where R 5 a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total number of less than 7 carbon atoms, preferably less than 6 carbon atoms, which forms the hydrophobic part of the hydrotropic surfactant, and wherein R 1 and / or R 2 residues that form or comprise the hydrophilic molecular part of the respective surfactant; vii) microbial biosurfactants, preferably selected from the group consisting of: sophorolipids and rhamnolipids.
[0126] All producible combinations of the residues R, R 1 and R2 are preferred in some cases within the scope of the present invention. Only such combinations of the residues R, R 1 and R 2 , which lead to adverse cleaning results and / or adverse washing results of the detergent according to the invention, are in many cases less preferred within the scope of the present invention.
[0127] Secondary or tertiary fatty acids with the general formula RNR 1 R are known to those skilled in the art. Preferred secondary or tertiary fatty amines with the general formula RNR 1 R 2 are in many cases within the scope of the present invention:
[0128] Alkyliminoacetates,
[0129] Alkyliminopropionate,
[0130] AI kyl amine od i acetate and
[0131] Alkyliminodipropionate.
[0132] A detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent additionally contains a total amount of one or more surfactant compounds selected independently from the group consisting of: v) Secondary or tertiary fatty amines with the general formula RNR 1 R 2 , where the remainder R 1 a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia, or O is a profaned primary, secondary, or tertiary amine compound; and / or the residue R 1 a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia, O is a profaned primary, secondary or tertiary amine compound, and / or the residue R 1a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound, and where the residue R 2 a hydrogen atom (H); and / or the residue R 1 a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia, or O is a profaned primary, secondary, or tertiary amine compound, and where the residue R 2 a hydrogen atom (H); and / or the residue R 1 a remainder according to the formula CH2COOM and where the remainder is R 2 a residue according to the formula CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; and / or the residue R 1 a remainder according to the formula CH2CH2COOM and where the remainder is R 2a residue according to the formula CH2CH2COOM, where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound. and / or from the group consisting of: vi) Hydrotropic surfactants with a general formula selected from the group consisting of: Ethers of fatty alcohols with the general formula R 5 -CH2-OR 1
[0133] Fatty acid amides with the general formula R 5 -C(O)NR 1 R 2 ;
[0134] Secondary or tertiary fatty amines with the general formula R 5 NR 1 R 2 , where R 5 a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total number of less than 7 carbon atoms, preferably less than 6 carbon atoms, which forms the hydrophobic part of the hydrotropic surfactant, and wherein R 1 and / or R 2residues are those that form or comprise the hydrophilic molecular portion of the respective surfactant; and / or from the group consisting of: vii) microbial biosurfactants, preferably selected from the group consisting of: sophorolipids and rhamnolipids.
[0135] All producible combinations of the residues R, R 1 and R 2 are preferred in some cases within the scope of the present invention. Only such combinations of the residues R, R 1 and R 2 , which lead to adverse cleaning results and / or adverse washing results of the detergent according to the invention, are in many cases less preferred within the scope of the present invention.
[0136] A detergent (as described above, preferably as referred to above as preferred) is preferred, comprising one or more surfactant compounds selected from ii) to iv), each with a residue R 1, comprising nitrogen, oxygen, sulfur and / or phosphorus atoms and forming or comprising a hydrophilic molecular fraction of the respective surfactant, wherein preferably each residue R 1 Selected independently from the group consisting of:
[0137] (a) (C2H4O)XZ where Z is an alkyl group having 1 to 4 carbon atoms and where x is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0138] (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0139] (C) (C2H4O)x(C3H6O)yZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, and wherein x and y are selected independently of each other;
[0140] (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0141] (e) (C2H4O)XCH2COOM where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0142] (f) CH2CH(OH)CH2OH
[0143] (12) CH(CH2OH)2
[0144] (g) CH2CH(OH)CH2OR where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0145] (h) CH2CH(OR)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0146] (h2) CH(CH2OH)CH2OR where R is a hydrocarbon residue with 7 to 23 carbon atoms, (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4;
[0147] (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4;
[0148] (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3;
[0149] (l) (C2H4O)x(C3H6O) y H where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where x and y are selected independently of each other;
[0150] (m) [CH2CH(OH)CH-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30;
[0151] (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0152] (o) (C2H4O)XSO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10;
[0153] (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH
[0154] (q) CH2CH2CH2N + (CH3)2CH2COO-
[0155] (r) CH2CH2CH2N + (CH3)2O- (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0156] (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0157] (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0158] (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30;
[0159] (w) CH2CH(OH)CH2OR * (C2H4O) y H where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0160] (x) CH2CH(OR)CH2OH * (C2H4O)yH where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0161] (y) CH(CH2OR)CH2OH * (C2H4O)yH where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0162] (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e.g.) CH2CH(OH)CH2OR * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0163] (zc) CH2CH(OR)CH2OH * (C2H4O)yCH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0164] (zc2) CH(CH2OR)CH2OH * (C2H4O)yCH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0165] (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) Z CH3COOM where y is a number in the range of 3 to 30, where z is a number in the range of 3 to 30, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary, or tertiary amine compound;
[0166] (ze) CH2[CH(OH)]XCH2OH * (C2H4O) yH where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30;
[0167] (zf) CH2CH(OR)[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 1 to 3 and where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0168] (zg) Remainder according to the following formula 1 :
[0169] Formula 1: where m is a number in the range of 1 to 10;
[0170] (zh) Remainder according to the following formula 2: Formula 2: where m is a number in the range of 1 to 10;
[0171] (zi) Remainder according to the following formula 3:
[0172] Formula 3: , where R 3 Hydrogen is; (zj) A residue according to the formula 3 defined above is, where R 3 in two cases it is hydrogen and in one case a hydrocarbon residue with a total number of 7 to 23 carbon atoms;
[0173] (zk) A remainder according to the formula 3 defined above is, where R 3 (C2H4O) X H is, where x is a number in the range of 1 to 50; (zl) A remainder according to the formula defined above is 3, where R 3 in two cases (C2H4O) X H is, where x is a number in the range of 1 to 50; and where R 3 in one case a hydrocarbon residue with a total number of 7 to 23 carbon atoms; and wherein preferably the residue R 2 , if any, is selected from the group consisting of:
[0174] Alkyl group, preferably an alkyl group with 1 to 3 carbon atoms and
[0175] hydrogen atom; especially preferably any residue R 1 Selected independently from the group consisting of:
[0176] (a) (C2H4O)XZ where Z is an alkyl group having 1 to 4 carbon atoms and where x is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0177] (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0178] (c) (C2H4O)x(C3H6O)yZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, and wherein x and y are selected independently of each other;
[0179] (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0180] (e) (C2H4O)XCH2COOM where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0181] (f) CH2CH(OH)CH2OH
[0182] (12) CH(CH2OH)2
[0183] (g) CH2CH(OH)CH2OR where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0184] (h) CH2CH(OR)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0185] (h2) CH(CH2OH)CH2OR where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0186] (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4;
[0187] (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4;
[0188] (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3;
[0189] (l) (C2H4O)x(C3H6O) y H where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, and where x and y are selected independently of each other;
[0190] (m) [CH2CH(OH)CH-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30;
[0191] (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0192] (o) (C2H4O) X SO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10;
[0193] (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH
[0194] (q) CH2CH2CH2N + (CH3)2CH2COO-
[0195] (r) CH2CH2CH2N + (CH3)2O-
[0196] (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0197] (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0198] (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0199] (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30;
[0200] (w) CH2CH(OH)CH2OR * (C2H4O) y H where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0201] (x) CH2CH(OR)CH2OH * (C2H4O)yH where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0202] (y) CH(CH2OR)CH2OH * (C2H4O)yH where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms;
[0203] (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0204] (e.g.) CH2CH(OH)CH2OR * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0205] (zc) CH2CH(OR)CH2OH * (C2H4O)yCH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0206] (zc2) CH(CH2OR)CH2OH * (C2H4O)yCH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0207] (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) Z CH3COOM where y is a number in the range of 3 to 30, where z is a number in the range of 3 to 30, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary, or tertiary amine compound;
[0208] (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30;
[0209] (zf) CH2CH(OR)[CH(OH)]XCH2OH * (C2H4O) yH where x is a number in the range of 1 to 3 and where y is a number in the range of 1 to 30 and R is a hydrocarbon residue with 7 to 23 C atoms; and where preferably the residue R 2 , if any, is selected from the group consisting of:
[0210] Alkyl group, preferably an alkyl group with 1 to 3 carbon atoms and
[0211] hydrogen atom; especially preferably any residue R 1 Selected independently from the group consisting of:
[0212] (a) (C2H4O)XZ wherein Z is an alkyl group having 1 to 4 carbon atoms and where x is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0213] (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30;
[0214] (c) (C2H4O)x(C3H6O) yZ where Z is an alkyl group with 1 to 4 carbon atoms and where x is a number in the range of 1 to 30, preferably in the range of 3 to 30 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30 and where x and y are selected independently of each other;
[0215] (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0216] (e) (C2H4O)xCH2COOM where x is a number in the range of 1 to 30, preferably in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0217] (f) CH2CH(OH)CH2OH
[0218] (12) CH(CH2OH)2
[0219] (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4;
[0220] (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4;
[0221] (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3;
[0222] (l) (C2H4O)x(C3H6O)yH where x is a number in the range of 1 to 30, preferably in the range of 3 to 30 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30 and where x and y are selected independently of each other;
[0223] (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0224] (o) (C2H4O) X SO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10;
[0225] (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH
[0226] (q) CH2CH2CH2N + (CH3)2CH2COO-
[0227] (r) CH2CH2CH2N + (CH3)2O-
[0228] (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0229] (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0230] (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0231] (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30;
[0232] (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30 and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (zd) CH2CH(OH)CH2OH * (C2H4O) yCH3COOM * (C2H4O) Z CH3COOM where y is a number in the range of 3 to 30, where z is a number in the range of 3 to 30, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary, or tertiary amine compound;
[0233] (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30; and where preferably the remainder R 2 , if any, is selected from the group consisting of:
[0234] Alkyl group, preferably an alkyl group with 1 to 3 carbon atoms and
[0235] hydrogen atom.
[0236] A detergent (as described above, preferably as referred to above as preferred) is preferred, comprising one or more surfactant compounds selected from ii) to iv), each with a residue R 1, comprising nitrogen, oxygen, sulfur and / or phosphorus atoms and forming or comprising a hydrophilic molecular fraction of the respective surfactant, wherein preferably the R groups 1 and / or R 2 open-chain residues are or the residue R 1 an open-chain residue and R 2 hydrogen is; and / or wherein preferably for surfactant compounds selected from: iv) fatty acid amides with the general formula RC(O)NR 1 R 2 , the following applies: the remainders R 1 and / or R 2 are open-chain residues or the residue R 1 is an open-chain residue and R 2 is hydrogen; and / or wherein preferably any residue R 1 Selected independently from the group consisting of:
[0237] (a) (C2H4O)XZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0238] (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0239] (c) (C2H4O)x(C3H6O)yZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein x and y are selected independently of each other;
[0240] (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e) (C2H4O) XCH2COOM wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0241] (f) CH2CH(OH)CH2OH
[0242] (12) CH(CH2OH)2
[0243] (g) CH2CH(OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0244] (h) CH2CH(O(CO)R)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0245] (h2) CH(CH2OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0246] (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4;
[0247] (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4;
[0248] (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3;
[0249] (l) (C2H4O)x(C3H6O)yH where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where x and y are selected independently of each other;
[0250] (m) [CH2CH(OH)CH2-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0251] (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0252] (o) (C2H4O)XSO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10, particularly preferably in the range of 1 to 5;
[0253] (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH
[0254] (q) CH2CH2CH2N + (CH3)2CH2COO-
[0255] (r) CH2CH2CH2N + (CH3)2O-
[0256] (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0257] (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0258] (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0259] (w) CH2CH(OH)CH2O(CO)R * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0260] (x) CH2CH(O(CO)R)CH2OH * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0261] (y) CH(CH2O(CO)R)CH2OH * (C2H4O) yH where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0262] (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0263] (e.g.) CH2CH(OH)CH2O(CO)R * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0264] (zc) CH2CH(O(CO)R)CH2OH * (C2H4O)y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0265] (zc2) CH(CH2O(CO)R)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0266] (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) ZCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, wherein z is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0267] (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0268] (zf) CH2CH(O(CO)R)[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 1 to 3 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0269] (zg) Remainder according to the following formula 1 :
[0270] Formula 1: where m is a number in the range of 1 to 10, preferably in the range of 1 to 5, particularly preferably in the range of 1 to 3; (zh) remainder according to the following Formula 2:
[0271] Formula 2: where m is a number in the range of 1 to 10, preferably in the range of 1 to 5, particularly preferably in the range of 1 to 3;
[0272] (zi) Remainder according to the following formula 3:
[0273] Formula 3: where R 3 Hydrogen is;
[0274] (zj) A remainder according to the formula 3 defined above is, where R 3 in two cases hydrogen and in one case (CO)R 4 is, where R 4 a hydrocarbon residue with a total number of 7 to 23 carbon atoms; (Zk) A residue according to formula 3 defined above, where R 3 (C2H4O) XH is, where x is a number in the range of 1 to 50, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 15;
[0275] (zl) A remainder according to the formula 3 defined above is, where R 3 in two cases (C2H4O) X H is, where x is a number in the range of 1 to 50, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 15; and where R 3 in one case (CO)R 4 is, where R 4 a hydrocarbon residue with a total number of 7 to 23 carbon atoms; preferably selected from the group consisting of:
[0276] (a) (C2H4O)XZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0277] (b) (C2H4O) yH where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0278] (C) (C2H4O)x(C3H6O)yZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein x and y are selected independently of each other;
[0279] (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e) (C2H4O) XCH2COOM wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0280] (f) CH2CH(OH)CH2OH
[0281] (12) CH(CH2OH)2
[0282] (g) CH2CH(OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0283] (h) CH2CH(O(CO)R)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0284] (h2) CH(CH2OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms,
[0285] (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4;
[0286] (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4;
[0287] (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3;
[0288] (l) (C2H4O)x(C3H6O)yH where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where x and y are selected independently of each other;
[0289] (m) [CH2CH(OH)CH2-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0290] (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0291] (o) (C2H4O)XSO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10, particularly preferably in the range of 1 to 5;
[0292] (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH
[0293] (q) CH2CH2CH2N + (CH3)2CH2COO-
[0294] (r) CH2CH2CH2N + (CH3)2O-
[0295] (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0296] (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0297] (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0298] (w) CH2CH(OH)CH2O(CO)R * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0299] (x) CH2CH(O(CO)R)CH2OH * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0300] (y) CH(CH2O(CO)R)CH2OH * (C2H4O) yH where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms;
[0301] (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0302] (e.g.) CH2CH(OH)CH2O(CO)R * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0303] (zc) CH2CH(O(CO)R)CH2OH * (C2H4O)y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0304] (zc2) CH(CH2O(CO)R)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms;
[0305] (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) ZCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, wherein z is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound;
[0306] (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12;
[0307] (zf) CH2CH(O(CO)R)[CH(OH)]XCH2OH * (C2H4O) yH where x is a number in the range of 1 to 3 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; and / or where preferably the residue R 2 a surfactant of group iv), if present, is selected from the group consisting of: alkyl group, preferably an alkyl group with 1 to 3 carbon atoms and
[0308] Hydrogen.
[0309] Detergents comprising surfactant compounds with the hydrophilic residues R defined above 1 , in many cases lead to particularly advantageous cleaning and / or washing results with the detergent according to the invention.
[0310] The selection of the remains R 1 Each process occurs independently. This means that the selection of a first remainder R 1 no influence on the selection of any second residue R that may be present1 has. Likewise, the selection of a second remainder R also has 1 no influence on the selection of any third remainder R that may be present 1 .
[0311] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O) X Z (as defined above) are fatty acid alkyl ester ethoxylates.
[0312] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O) y H (as defined above) are fatty alcohol ethoxylates.
[0313] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O)x(C3HeO) y Z (as defined above) are fatty acid alkyl ester alkoxylates (with x = number of ethylene oxide units and y = number of propylene oxide units).
[0314] Examples of surfactants with a hydrophilic residue R 1CH2COOM (as defined above) is fatty alcohol carboxymethyl ether, fatty acid carboxymethyl ester.
[0315] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O) X CH2COOM (as defined above) are fatty alcohol (EO)x carboxymethyl ethers, fatty acid (EO)x carboxymethyl esters.
[0316] Examples of surfactants with a hydrophilic residue R 1 CH2CH(OH)CH2OH (as defined above) are fatty alcohol glycerol ethers, monoglycerides.
[0317] Examples of surfactants with a hydrophilic residue R 1 CH(CH2OH)2 (as defined above) is fatty alcohol glycerol ethers, monoglycerides.
[0318] Examples of surfactants with a hydrophilic residue R 1 The CH2CH(OH)CH2(O(CO)R) group (as defined above) consists of diglycerides. An example of surfactants with a hydrophilic R group is... 1CH2CH(O(CO)R)CH2(OH) (as defined above) are diglycerides.
[0319] Examples of surfactants with a hydrophilic residue R 1 CH(CH2O(CO)R)CH2(OH) (as defined above) is diglycerides.
[0320] Examples of surfactants with a hydrophilic residue R 1 the CH2[CH(OH)] x CH2OH (as defined above) are monoesters of higher polyols (C4 / C5 / C6 at x = 2 / 3 / 4).
[0321] Examples of surfactants with a hydrophilic residue R 1 the CH2[CH(OH)] X CHO (as defined above) are aldose esters (C5 / C6 at x= 3 / 4).
[0322] Examples of surfactants with a hydrophilic residue R 1 the CH2[CH(OH)] x C(O)CH2OH (as defined above) are ketose esters (C5 / C6 at x=2 / 3).
[0323] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O)x(C3HeO) yH (as defined above) are fatty alcohol alkoxylates (EO / PO), fatty acid alkoxylates (EO / PO), fatty acid amido alkoxylates (EO / PO).
[0324] Examples of surfactants with a hydrophilic residue R 1 the [CH2CH(OH)CH-O]xH (as defined above) are fatty alcohol polyglycerol ethers.
[0325] Examples of surfactants with a hydrophilic residue R 1 The SOsM (as defined above) are alkyl sulfates.
[0326] Examples of surfactants with a hydrophilic residue R 1 the (C2H4O) X SO3M (as defined above) are alkyl EO ether sulfates.
[0327] Examples of surfactants with a hydrophilic residue R 1 The CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH (as defined above) are glucamides (=N-acyl, N-alkyl-glucamines)
[0328] Examples of surfactants with a hydrophilic residue R 1 the CH2CH2CH2N +(CH3)2CH2COO' (as defined above) are alkylamidopropybetaines.
[0329] Examples of surfactants with a hydrophilic residue R 1 the CH2CH2CH2N + (CH3)2O _ (as defined above) are alkylamidopropyl N-oxides.
[0330] Examples of surfactants with a hydrophilic residue R 1 The CH2CH2N(C2H4OH)CH2COOM (as defined above) is an amphoacetate. Examples of surfactants with a hydrophilic R group include: 1 CH2CH2N(CH2COOM)CH2CH2OCH2COOM (as defined above) is ammphodiacetate.
[0331] Examples of surfactants with a hydrophilic residue R 1 CH(COOM)CH2CH2COOM (as defined above) is acylglutamates.
[0332] Examples of surfactants with a hydrophilic residue R 1 The CH2COOM (as defined above) consists of acylglycinates and acylsarcosines.
[0333] Examples of surfactants with a hydrophilic residue R 1 the CH2CH(OH)CH2OH * (C2H4O) y H (as defined above) are ethoxylated fatty acid monoesters of glycerol.
[0334] Examples of surfactants with a hydrophilic residue R 1 CH(CH2OH)2 * (C2H4O)yH (as defined above) are ethoxylated fatty acid monoesters of glycerol.
[0335] Examples of surfactants with a hydrophilic residue R 1 the CH2CH(OH)CH2(OR) * (C2H4O) y H (as defined above) are ethoxylated fatty acid diesters of glycerol.
[0336] Examples of surfactants with a hydrophilic residue R 1 the CH2CH(OR)CH2(OH) * (C2H4O) y H (as defined above) are ethoxylated fatty acid diesters of glycerol.
[0337] Examples of surfactants with a hydrophilic residue R 1CH(CH2OR)CH2OH * (C2H4O)yH (as defined above) are ethoxylated fatty acid diesters of glycerol.
[0338] Examples of surfactants with a hydrophilic residue R 1 the CH2CH(OH)CH2(OH) * (C2H4O) y CH3COOM (as defined above) are monoglyceride EO ether acetates.
[0339] Examples of surfactants with a hydrophilic residue R 1 the CH(CH2OH)2 * (C2H4O) y CH3COOM (as defined above) are monoglyceride EO ether acetates.
[0340] Examples of surfactants with a hydrophilic residue R 1 the CH2CH(OH)CH2(OR) * (C2H4O) y CH3COOM (as defined above) are diglyceride EO ether acetates.
[0341] Examples of surfactants with a hydrophilic residue R 1 The CH2CH(OR)CH2(OH) * (C2H4O)yCH3COOM (as defined above) are diglyceride EO ether acetates.
[0342] Examples of surfactants with a hydrophilic residue R 1 The CH(CH2OR)CH2OH * (C2H4O)yCH3COOM (as defined above) are diglyceride EO ether acetates. An example of surfactants with a hydrophilic residue R is... 1 the CH2CH(OH)CH2(OH) * (C2H4O) y CH3COOM * (C2H4O) Z CH3COOM (as defined above) are monoglyceride EO ether diacetates.
[0343] Examples of surfactants with a hydrophilic residue R 1 the CH(CH2OH)2 * (C2H4O) y CH3COOM * (C2H4O) Z CH3COOM (as defined above) are monoglyceride EO ether diacetates.
[0344] Examples of surfactants with a hydrophilic residue R 1 the CH2[CH(OH)] X CH2OH * (C2H4O) y H (as defined above) are ethoxylated fatty acid monoesters of higher polyols (C4, C5, C6 / erythritol, xylitol, sorbitol).
[0345] Examples of surfactants with a hydrophilic residue R 1the CH2CH(O(CO)R)[CH(OH)]XCH2OH * (C2H4O) y H (as defined above) are ethoxylates of fatty acid diesters of higher polyols (C4, C5, C6 / erythritol, xylitol, sorbitol).
[0346] Examples of surfactants with a hydrophilic residue R 1 According to the formula 1 defined above, , are alkyl polyglycosides.
[0347] Examples of surfactants with a hydrophilic residue R 1 According to the formula 2 defined above, alkyl polyglycosides are.
[0348] Examples of surfactants with a hydrophilic residue R 1 According to the formula defined above, 3 are fatty acid monoesters of sorbitan, fatty acid diesters of sorbitan, ethoxylated fatty acid monoesters of sorbitan and ethoxylated fatty acid diesters of sorbitan.
[0349] Our own experiments have shown: Detergents comprising surfactant compounds in which the R residues 1 and / or R 2 open-chain residues are or
[0350] R 1 an open-chain residue and R 2 The presence of hydrogen in the detergent according to the invention often leads to the realization of particularly advantageous combinations of properties. In particular, improved water solubility (compared to closed-chain R groups) is frequently observed. 1 and / or R 2 ) and more advantageous HLB values (compared with closed-chain residues R) 1 and / or R 2 ) on. This applies in particular to compounds selected from: iv) fatty acid amides with the general formula RC(O)NR 1 R 2 .
[0351] Detergents comprising surfactant compounds with the hydrophilic residues R defined above 1 and / or R 2 , in many cases lead to particularly advantageous cleaning and / or washing results with the detergent according to the invention.
[0352] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total number of 15 C atoms of at least 0.7 wt.%, preferably in the range of 0.8 wt.% to 15 wt.%, particularly preferably in the range of 1 wt.% to 10 wt.%, and most preferably in the range of 1.2 wt.% to 9 wt.%, in each case based on the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv);and / or, preferably “and” wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) comprises a proportion of hydrocarbon residues R with 17 to 23 C atoms in the range of 14 wt.% to 59 wt.%, preferably in the range of 17 wt.% to 59 wt.%, particularly preferably in the range of 20 wt.% to 59 wt.%, most preferably in the range of 25 wt.% to 59 wt.%, in each case based on the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv);and / or, preferably “and wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 11 to 13 C atoms to the total mass of the hydrocarbon residues R with a total number of 7 to 10 C atoms is in the range of 0 to 0.1, preferably in the range of 0 to 0.05, particularly preferably in the range of 0 to 0.03; and / or, preferably “and” wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 7 to 10 C atoms to the total mass of the hydrocarbon residues R with a total number of 17 to 23 C atoms is in the range of 0.52 to 6, preferably in the range of 0.53 to;
[0353] 5, particularly preferably in the range of 0.54 to 4; and / or, preferably “and” wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 15 C atoms to the total mass of the hydrocarbon residues R with a
[0354] The total number of 17 to 23 carbon atoms is in the range of 0.03 to 0.3, preferably in the range of 0.04 to 0.24, particularly preferably in the range of 0.05 to 0.18.
[0355] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total number of 15 C atoms of at least 0.7 wt.%, preferably in the range of 0.8 wt.% to 15 wt.%, particularly preferably in the range of 1 wt.% to 10 wt.%, and most preferably in the range of 1.2 wt.% to 9 wt.%, in each case based on the total mass of the residues R of the one or more surfactant compounds selected from i) to iv).
[0356] Surprisingly, it has been found that a detergent with a corresponding proportion of hydrocarbon residues R with a total of 15 carbon atoms exhibits particularly advantageous washing and / or cleaning properties. Furthermore, a corresponding proportion of hydrocarbon residues R with a total of 15 carbon atoms is found in many natural vegetable oils of temperate zones. The production of surfactant compounds from these temperate vegetable oils is particularly easy in many cases when a corresponding proportion of hydrocarbon residues R with a total of 15 carbon atoms is desired, as is preferred in many cases within the scope of the present invention.
[0357] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total number of 17 to 23 C atoms in the range of 14 wt.% to 59 wt.%, preferably in the range of 17 wt.% to 59 wt.%, particularly preferably in the range of 20 wt.% to 59 wt.%, and most preferably in the range of 25 wt.% to 59 wt.%, in each case based on the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv).
[0358] A detergent according to the invention with a corresponding mass fraction of hydrocarbon residues R with a total number of 17 to 23 C atoms of the surfactant compounds present therein selected from i) to iv) is in many cases particularly preferred, since such a detergent (as described above, preferably as referred to above as preferred) has particularly advantageous cleaning properties and / or washing properties.
[0359] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein in the total mass of the hydrocarbon residues R of one or more surfactant compounds selected from i) to iv), the ratio of the total mass of the hydrocarbon residues R with a total number of 11 to 13 C atoms to the total mass of the hydrocarbon residues R with 7 to 10 C atoms, preferably 7 to 9 C atoms, is in the range of 0 to 0.1, preferably in the range of 0.0001 to 0.05, particularly preferably in the range of 0.001 to 0.03.
[0360] Higher proportions of hydrocarbon residues R with a total of 11 to 13 carbon atoms are associated by consumers in the field of the present invention with the use of surfactants based on tropical plants (for example, based on palm oil and / or coconut oil) and are perceived as disadvantageous in the field of the present invention. The detergent according to the invention preferably does not contain higher proportions of hydrocarbon residues R with a total of 11 to 13 carbon atoms, yet still achieves highly satisfactory cleaning performance.
[0361] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the ratio of the total mass of the hydrocarbon residues R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, to the total mass of the hydrocarbon residues R with a total number of 17 to 23 C atoms is in the range of 0.52 to 6, preferably in the range of 0.53 to 5, particularly preferably in the range of 0.54 to 4;
[0362] In this way, in many cases a detergent with particularly advantageous cleaning and / or washing properties is obtained.
[0363] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the ratio of the total mass of the hydrocarbon residues R with a total number of 15 C atoms to the total mass of the hydrocarbon residues R with a total number of 17 to 23 C atoms is in the range of 0.03 to 0.3, preferably in the range of 0.04 to 0.24, and particularly preferably in the range of 0.05 to 0.18.
[0364] In this way, in many cases a detergent with particularly advantageous cleaning and / or washing properties is obtained, whereby the surfactants contained therein are produced in a particularly advantageously simple way from vegetable oils of the temperate zone.
[0365] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the detergent comprises one, two or more surfactant compounds selected from i) to iv), the hydrocarbon residues R of which have a ratio of 14 carbon atoms to 12 exhibits C atoms corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and wherein preferably the proportion of these surfactant compounds to the total mass of the surfactant compounds contained in the detergent is in the range of 80 wt.% to 100 wt.%, more preferably in the range of 85 wt.% to 100 wt.%, more preferably in the range of 90 wt.% to 100 wt.%; and / or, more preferably, wherein surfactant compounds from at least one of groups i) to iv) are present, each with at least two different chain lengths of the hydrocarbon chains R.
[0366] In many cases, a detergent is also preferred (as described above, preferably referred to as preferred above), wherein surfactant compounds with at least three different chain lengths of the hydrocarbon chains R are present from at least one of the groups i) to iv).
[0367] The radiocarbon method, and thus a method leading to unambiguous results for determining the ratio of 14 carbon atoms to 12 The ratio of carbon atoms in hydrocarbon residues, corresponding to an age of the respective hydrocarbon residues of less than 300 years (with a standard deviation of less than 50 years) since carbon dioxide fixation, is known to those skilled in the art from their general knowledge. Methods for calibrating corresponding measurements are also known to those skilled in the art. A ratio of 14 carbon atoms to 12C atoms, which corresponds to an age of the corresponding hydrocarbon residues of less than 300 years (with a standard deviation of less than 50 years) since carbon dioxide fixation, is characteristic of surfactants produced from renewable raw materials and excludes the possibility that the surfactant under investigation is a surfactant from a purely petrochemical (fossil) source.
[0368] A corresponding ratio of 14 carbon atoms to 12 C atoms, which corresponds to an age of the corresponding carbon atoms of less than 300 years (with a standard deviation of less than 50 years) since carbon dioxide fixation, is understood by the consumer in the field of the present invention as a crucial indication of a detergent with a proportion of surfactant compounds based on renewable raw materials, preferably plant-based raw materials.
[0369] A correspondingly high proportion of 80 wt.% to 100 wt.% of such surfactant compounds is therefore particularly preferred in many cases within the scope of the present invention.
[0370] The presence of surfactant compounds with at least two, preferably at least three, different chain lengths of the hydrocarbon chains R is also understood in the field of the present invention as an indication of origin from vegetable oil. It is particularly preferred if, in addition, proportions of unsaturated hydrocarbon residues R are present (as described above, preferably as referred to above as preferred), which indicate origin from a vegetable oil; this is perceived as particularly positive in many cases in the field of the present invention.
[0371] In many cases, it is preferred that at least two, preferably at least three, different chain lengths of the hydrocarbon chains R are present, as they occur in the oil of a plant selected from the group of plants consisting of: hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oil radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof.
[0372] A detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent comprises at least one surfactant compound selected from i) to iv) which is not a soap; and / or wherein the detergent
[0373] - comprises a monoglyceride; or
[0374] - is free of monoglycerides.
[0375] In many cases, preferably when the detergent is intended for use with hard water (from about 10° dH), it is preferred if the detergent comprises at least one surfactant compound selected from i) to iv) which is not a soap.
[0376] At water hardness levels above approximately 10° dH, the carboxyl group of soaps is regularly blocked by calcium and / or magnesium ions, forming insoluble lime soaps that have little or no washing power. This is generally highly undesirable in the field of the present invention. In many cases, soaps alone are not the preferred surfactant compound with regard to the washing results achievable with the detergent.
[0377] Soaps produced using simple saponification processes with vegetable oils from temperate zones contain monoglycerides. In many cases, particularly when soaps made from vegetable oils of temperate zones are used, it is preferable for the detergent to additionally comprise monoglycerides. In the field of the present invention, this is often understood as an indication that the soap was produced from the vegetable oil in a particularly advantageous and environmentally friendly manner and is therefore preferred. Such a soap is also preferred in many cases because it can be produced from vegetable oils of temperate zones with advantageously little effort in separating the components of the natural vegetable oil and / or the byproducts of the saponification process from the finished soap.
[0378] In many cases, particularly when the detergent does not contain a surfactant compound that is a soap, a detergent free of monoglycerides is preferred. The presence of monoglycerides in these cases is often associated with adverse cleaning and washing results and should therefore be regularly avoided.
[0379] The effects and advantages described above in connection with the detergent according to the invention are also preferably realized here.
[0380] A detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is in liquid or gel form or wherein the detergent is in solid form.
[0381] A detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is in liquid form or wherein the detergent is in solid form.
[0382] In many cases, a detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is in liquid form.
[0383] In many cases, a detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is in a solid embodiment.
[0384] Corresponding embodiments are regularly particularly preferred in the field of the present invention, since corresponding metering methods for such embodiments are known and widely accepted in the field of the present invention.
[0385] Detergents in the embodiments defined above are thus used by the respective consumer in the manner customary for the respective consumer, without the consumer having to make any disadvantageous changes in use compared to detergents known to them. This is preferred in the field of the present invention.
[0386] The transitions between liquid and gel-like embodiments are not clearly defined in the field of the present invention. Within the scope of the present invention, the term "liquid embodiment" also includes the term "gel-like embodiment".
[0387] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the detergent comprises at least one surfactant compound from group i), preferably at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, particularly preferably at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms selected from the group consisting of:
[0388] Sodium soaps, potassium soaps,
[0389] - Monoethanolamine soaps,
[0390] - Diethanolamine soaps,
[0391] - Triethanolamine soaps,
[0392] - Methyldiethanolamine soaps, and
[0393] - Diisopropanolamine soaps; and / or wherein the detergent comprises at least one surfactant compound from group ii), preferably at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, particularly preferably at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms selected from the group consisting of:
[0394] Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of:
[0395] - Fatty acid alkyl ester ethoxylates (EO),
[0396] - Fatty acid alkyl ester ethoxylate / propoxylate (EO / PO),
[0397] - Fatty acid carboxymethyl esters (fatty acid acetates),
[0398] - Fatty acid ethoxylate acetates (fatty acid carboxymethyl ester ethoxylates),
[0399] - Fatty acid monoesters of glycerol (monoglycerides),
[0400] - Fatty acid diesters of glycerol (diglycerides),
[0401] - Ethoxylated fatty acid monoesters of glycerol (monoglyceride EO ethers), Ethoxylated fatty acid diesters of glycerol (diglyceride EO ethers),
[0402] - monoglyceride EO ether acetates,
[0403] - Diglyceride EO ether acetates,
[0404] - Monoglyceride EO ether diacetate,
[0405] - Fatty acid esters of higher polyols (C4-C6), preferably erythritol, xylitol, sorbitol,
[0406] - Ethoxylated fatty acid esters of higher polyols (C4-C6), preferably erythritol, xylitol, sorbitol,
[0407] - Fatty acid esters of aldoses (C5 / C6), ketoses (C5 / C6) and disaccharides,
[0408] - Fatty acid monoesters of sorbitan,
[0409] - Fatty acid diesters of sorbitan,
[0410] - Ethoxylated fatty acid monoesters of sorbitan,
[0411] - Ethoxylated fatty acid diesters of sorbitan; and / or wherein the detergent comprises at least one surfactant compound from group iii), preferably at least one surfactant compound from group iii) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, particularly preferably at least one surfactant compound from group iii) with a hydrocarbon residue R of 17 to 23 C atoms selected from the group consisting of:
[0412] Fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0413] Fatty alcohol ethoxylates (EO),
[0414] Fatty alcohol ethoxylate / propoxylate (EO / PO), - Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0415] - fatty alcohol ethoxylate acetates,
[0416] - Fetta I ko ho I- Eth oxy lat / Pro poxy I at- Acetate,
[0417] - Alkyl glycosides (APG and APP),
[0418] - Alkyl sulfates, and
[0419] - Alkyl ether sulfates; and / or wherein the detergent comprises at least one surfactant compound from group iv), preferably at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, particularly preferably at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms selected from the group consisting of:
[0420] Fatty acid amide alkoxylates, preferably selected from the list consisting of:
[0421] - Fatty acid amide ethoxylates (EO), and / or
[0422] - Fatty acid amide ethoxylate / propoxylate (EO / PO),
[0423] - N-acyl-N-alkyl-glucamines (“glucamides”),
[0424] - Alkyl-amidopropyl betaine,
[0425] Alkyl-amidopropyl-N-oxide,
[0426] Amphoacetates, ammphodiacetates, and
[0427] - N-acyl amino acids.
[0428] Within the scope of the present invention, the terms ‘fatty acid alkyl ester alkoxylates’ and ‘fatty acid amide alkoxylates’ each encompass the corresponding EO (ethylene oxide), PO (propylene oxide) and EO / PO (ethylene oxide / propylene oxide copolymers) compounds.
[0429] Surfactant compounds that fall under the definitions above often yield particularly advantageous results. Furthermore, these surfactant compounds can often be produced from temperate vegetable oils in a particularly advantageous and simple manner.
[0430] A detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent comprises at least one surfactant compound from group v), preferably at least one surfactant compound from group v) having a hydrocarbon residue R with a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group v), having a hydrocarbon residue R with a total number of 17 to 23 carbon atoms, and is selected from the group consisting of:
[0431] Alkyliminoacetates,
[0432] Alkyliminodiacetates,
[0433] Alkyliminopropionate, and
[0434] Alkyliminodipropionate.
[0435] The effects and advantages described above in connection with the detergent according to the invention (as described above, preferably as designated above as preferred) are realized in many cases in a preferentially positive manner with the surfactant compounds defined above. In each specific case, the person skilled in the art identifies the most suitable surfactant compounds from the aforementioned list by means of simple manual experiments without unreasonable effort and / or based on their expert knowledge.
[0436] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the detergent comprises at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, preferably at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 C atoms selected from the group consisting of:
[0437] - Sodium soaps,
[0438] - Potassium soaps,
[0439] - Monoethanolamine soaps,
[0440] - Diethanolamine soaps,
[0441] - Triethanolamine soaps,
[0442] - Methyldiethanolamine soaps, and
[0443] - Diisopropanolamine soaps; and / or, preferably “and” wherein the detergent comprises at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, wherein preferably the residue R 1 this surfactant compound from group ii) is an open-chain residue; and / or wherein this surfactant compound from group ii) is selected from the group consisting of:
[0444] - Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of:
[0445] - Fatty acid alkyl ester ethoxylates,
[0446] - Fatty acid alkyl ester ethoxylates / propoxylates,
[0447] - Fatty acid carboxymethyl esters,
[0448] - Fatty acid ethoxylate acetates,
[0449] - Fatty acid monoesters of glycerol,
[0450] - Fatty acid diesters of glycerol,
[0451] - Ethoxylated fatty acid monoesters of glycerol,
[0452] - Ethoxylated fatty acid diesters of glycerol,
[0453] - monoglyceride EO ether acetates,
[0454] - Diglyceride EO ether acetates,
[0455] - Monoglyceride EO ether diacetate,
[0456] - Fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol,
[0457] - Ethoxylated fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol,
[0458] - Fatty acid esters of aldoses, ketoses and disaccharides,
[0459] Fatty acid monoesters of sorbitan,
[0460] Fatty acid diesters of sorbitan, ethoxylated fatty acid monoesters of sorbitan,
[0461] - Ethoxylated fatty acid diesters of sorbitan; preferably selected from the group consisting of:
[0462] - Fatty acid alkyl ester ethoxylates,
[0463] - Fatty acid monoesters of glycerol,
[0464] - Fatty acid diesters of glycerol,
[0465] - Ethoxylated fatty acid monoesters of glycerol,
[0466] - Ethoxylated fatty acid diesters of glycerol,
[0467] - monoglyceride EO ether acetates,
[0468] - Diglyceride EO ether acetates,
[0469] - Monoglyceride EO ether diacetate,
[0470] - Fatty acid monoesters of sorbitan,
[0471] - Fatty acid diesters of sorbitan,
[0472] - Ethoxylated fatty acid monoesters of sorbitan,
[0473] - Ethoxylated fatty acid diesters of sorbitan; and / or wherein the detergent comprises at least one surfactant compound from group iii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group iii) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, wherein preferably the residue R 1 this surfactant compound from group iii) is an open-chain residue; and / or wherein this surfactant compound from group iii) is selected from the group consisting of:
[0474] - Fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0475] - Fatty alcohol ethoxylates,
[0476] - fatty alcohol ethoxylate / propoxylates,
[0477] - Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0478] - fatty alcohol ethoxylate acetates,
[0479] - Fetta I ko ho I- Eth oxy lat / Pro poxy I at- Acetate,
[0480] - Fatty alcohol monoglycerol ethers
[0481] - Fatty alcohol polyglycerol ether
[0482] - Alkyl glycosides, preferably selected from the group consisting of:
[0483] - Alkyl polyglycosides (APG),
[0484] - Alkyl polypentosides (APP),
[0485] - Alkyl sulfates, and
[0486] Alkyl ether sulfates; preferably selected from the group consisting of: fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0487] Fetta I ko ho I- Eth oxy late ,
[0488] Fatty alcohol ethoxylate / propoxylates,
[0489] - Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0490] - fatty alcohol ethoxylate acetates,
[0491] - Fatty alcohol polyglycerol ether
[0492] - Alkyl sulfates, and
[0493] - Alkyl ether sulfates; and / or wherein the detergent comprises at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, wherein preferably
[0494] - the remains R 1 and / or R 2 of this surfactant compound from group iv) are open-chain residues or the residue R 1 this surfactant compound from group iv) is an open-chain residue and R 2 this surfactant compound from group iv) contains hydrogen and / or this surfactant compound of group iv) is selected from the group consisting of:
[0495] - Fatty acid amide alkoxylates, preferably selected from the list consisting of:
[0496] - Fatty acid amide ethoxylates, and / or
[0497] - Fatty acid amide ethoxylate / propoxylates,
[0498] - N-Acyl-N-Alkyl-Glucamine linear sugar,
[0499] - Alkyl-amidopropyl betaine,
[0500] - Alkyl-amidopropyl-N-oxide,
[0501] - Amphoacetates,
[0502] - Ammphodiacetate,
[0503] - Fatty acid amides of serinol and
[0504] - N-acyl amino acids; preferably selected from the group consisting of:
[0505] - Fatty acid amide alkoxylates, preferably selected from the list consisting of:
[0506] - Fatty acid amide ethoxylates, and / or
[0507] - Fatty acid amide ethoxylate / propoxylates,
[0508] N-acyl-N-alkyl-glucamine linear sugar, alkyl-amidopropyl betaines,
[0509] - Alkyl-amidopropyl-N-oxide,
[0510] - Amphoacetates,
[0511] - Amphodiacetates, and
[0512] - N-acyl amino acids; and / or wherein the detergent comprises at least one surfactant compound from group v) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group v) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, wherein preferably the residues R 1 and / or R 2 of this surfactant compound from group v) are open-chain residues or the residue R 1 this surfactant compound from group v) is an open-chain residue and R 2 this surfactant compound from group v) contains hydrogen and / or this surfactant compound from group v) is selected from the group consisting of:
[0513] Alkyliminoacetates,
[0514] Alkyliminodiacetates,
[0515] Alkyliminopropionate, and
[0516] Alkyliminodipropionate.
[0517] The effects and advantages described above in connection with the detergent according to the invention (as described above, preferably as designated above as preferred) are realized in many cases in a preferentially positive manner with the surfactant compounds defined above. In each specific case, the person skilled in the art identifies the most suitable surfactant compounds from the aforementioned list by means of simple manual experiments without unreasonable effort and / or on the basis of their general technical knowledge.
[0518] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent comprises at least one surfactant compound from group i) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of:
[0519] - Sodium soaps,
[0520] - Potassium soaps,
[0521] - Monoethanolamine soaps,
[0522] - Diethanolamine soaps,
[0523] - Triethanolamine soaps,
[0524] - Methyldiethanolamine soaps, and
[0525] - Diisopropanolamine soaps; and / or wherein the detergent comprises at least one surfactant compound from group ii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of:
[0526] Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of:
[0527] - Fatty acid alkyl ester ethoxylates and
[0528] - Fatty acid alkyl ester ethoxylates / propoxylates (EO / PO),
[0529] Fatty acid carboxymethyl esters (fatty acid acetates)
[0530] Fatty acid ethoxylate acetates (fatty acid carboxymethyl esters- ethoxylate),
[0531] Fatty acid monoesters of glycerol (monoglycerides),
[0532] Fatty acid diesters of glycerol (diglycerides),
[0533] Ethoxylated fatty acid monoesters of glycerol (monoglyceride EO ethers),
[0534] Ethoxylated fatty acid diesters of glycerol (diglyceride EO ethers),
[0535] M onog lyce rid-EO-Ether-Acetate,
[0536] Dig lyce rid-EO-Ether-Acetate,
[0537] Monoglyceride EO ether diacetates,
[0538] Fatty acid esters of higher polyols (C4-C6), preferably erythritol, xylitol, sorbitol
[0539] Ethoxylated fatty acid esters of higher polyols (C4-C6), preferably erythritol, xylitol, sorbitol
[0540] Fatty acid esters of aldoses (C5 / C6) and ketoses (C5 / C6) and disaccharides, fatty acid monoesters of sorbitan,
[0541] Fatty acid diesters of sorbitan,
[0542] Ethoxylated fatty acid monoesters of sorbitan,
[0543] Ethoxylated fatty acid diesters of sorbitan, and / or wherein the detergent comprises at least one surfactant compound from group iii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of:
[0544] Fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0545] - Fatty alcohol ethoxylates (EO) and
[0546] - Fatty alcohol ethoxylate / propoxylate (EO / PO) and / or
[0547] Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0548] - Fatty alcohol ethoxylate acetates and
[0549] - Fatty alcohol ethoxylate / propoxylate acetates and / or
[0550] Alkyl glycosides (APG and APP),
[0551] Alkyl sulfates, and
[0552] - Alkyl ether sulfates; and / or wherein the detergent comprises at least one surfactant compound from group iv) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of:
[0553] Fatty acid amide alkoxylates, preferably selected from the list consisting of:
[0554] - Fatty acid amide ethoxylates (EO), and / or
[0555] - Fatty acid amide ethoxylate / propoxylate (EO / PO),
[0556] - N-acyl-N-alkyl-glucamines (“glucamides”),
[0557] - Alkyl-amidopropyl betaine,
[0558] - Alkyl-amidopropyl-N-oxide,-
[0559] - Amphoacetates
[0560] - Ammphodiacetate and
[0561] N-acyl amino acids.
[0562] Surfactant compounds that fall under the definitions above often yield particularly advantageous results. Furthermore, these surfactant compounds can often be produced from temperate vegetable oils in a particularly advantageous and simple manner.
[0563] The effects and advantages described above in connection with the detergent according to the invention (as described above, preferably as designated above as preferred) are realized in many cases in a preferentially positive manner with the surfactant compounds defined above. In each specific case, the person skilled in the art identifies the most suitable surfactant compounds from the aforementioned list by means of simple manual experiments without unreasonable effort and / or based on their expert knowledge.
[0564] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the detergent comprises at least one surfactant compound from group i) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of:
[0565] - Sodium soaps,
[0566] - Potassium soaps,
[0567] - Monoethanolamine soaps,
[0568] - Diethanolamine soaps,
[0569] - Triethanolamine soaps,
[0570] - Methyldiethanolamine soaps, and
[0571] - Diisopropanolamine soaps; and / or wherein the detergent comprises at least one surfactant compound from group ii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and wherein preferably the residue R1 this surfactant compound from group ii) is an open-chain residue; and / or this surfactant compound from group ii) is preferably selected from the group consisting of:
[0572] Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of:
[0573] - Fatty acid alkyl ester ethoxylates and
[0574] - Fatty acid alkyl ester ethoxylates / propoxylates,
[0575] Fatty acid carboxymethyl esters
[0576] Fatty acid ethoxylate acetates,
[0577] Fatty acid monoesters of glycerol,
[0578] Fatty acid diesters of glycerol,
[0579] Ethoxylated fatty acid monoesters of glycerol,
[0580] Ethoxylated fatty acid diesters of glycerol,
[0581] M onog lyce rid-EO-Ether-Acetate,
[0582] Dig lyce rid-EO-Ether-Acetate,
[0583] Monoglyce rid-EO-Ether-Dia cetate,
[0584] Fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol
[0585] Ethoxylated fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol
[0586] Fatty acid esters of aldoses and ketoses and disaccharides, fatty acid monoesters of sorbitan,
[0587] Fatty acid diesters of sorbitan,
[0588] Ethoxylated fatty acid monoesters of sorbitan, and
[0589] Ethoxylated fatty acid diesters of sorbitan; preferably selected from the group consisting of:
[0590] Fatty acid alkyl ester ethoxylates
[0591] Fatty acid monoesters of glycerol, fatty acid diesters of glycerol,
[0592] Ethoxylated fatty acid monoesters of glycerol, Ethoxylated fatty acid diesters of glycerol, Mon og lyce rid-EO- Eth e r- Acetate ,
[0593] Dig lyce rid-EO-Ether-Acetate,
[0594] Monoglyce rid-EO-Ether-Dia cetate,
[0595] Fatty acid monoesters of sorbitan,
[0596] Fatty acid diesters of sorbitan,
[0597] Ethoxylated fatty acid monoesters of sorbitan, and
[0598] Ethoxylated fatty acid diesters of sorbitan; and / or wherein the detergent comprises at least one surfactant compound from group iii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and wherein preferably
[0599] - the rest R 1 this surfactant compound from group iii) is an open-chain residue; and / or this surfactant compound from group iii) is preferably selected from the group consisting of:
[0600] Fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0601] - Fatty alcohol ethoxylates and
[0602] - fatty alcohol ethoxylate / propoxylates,
[0603] Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0604] - Fatty alcohol ethoxylate acetates and
[0605] - Fatty alcohol ethoxylate / propoxylate acetates
[0606] - Fatty alcohol monoglycerol ethers
[0607] - Fatty alcohol polyglycerol ether
[0608] - Alkyl glycosides, preferably selected from the group consisting of:
[0609] - Alkyl polyglycosides (APG),
[0610] - Alkyl polypentosides (APP), alkyl sulfates, and
[0611] - Alkyl ether sulfates; preferably selected from the group consisting of:
[0612] Fatty alcohol alkoxylates, preferably selected from the group consisting of:
[0613] - Fatty alcohol ethoxylates and
[0614] - fatty alcohol ethoxylate / propoxylates,
[0615] Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of:
[0616] - Fatty alcohol ethoxylate acetates
[0617] - Fatty alcohol polyglycerol ether
[0618] - Alkyl sulfates, and
[0619] - Alkyl ether sulfates; and / or wherein the detergent comprises at least one surfactant compound from group iv) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and wherein preferably the residues R 1 and / or R 2 of this surfactant compound from group iv) are open-chain residues or the residue R 1 this surfactant compound from group iv) is an open-chain residue and R 2 this surfactant compound from group iv) contains hydrogen and / or this surfactant compound from group iv) is preferably selected from the group consisting of:
[0620] Fatty acid amide alkoxylates, preferably selected from the list consisting of:
[0621] - Fatty acid amide ethoxylates, and / or
[0622] - Fatty acid amide ethoxylate / propoxylates,
[0623] - N-Acyl-N-Alkyl-Glucamine linear sugar,
[0624] - Alkyl-amidopropyl betaine,
[0625] - Alkyl-amidopropyl-N-oxide,
[0626] - Amphoacetates
[0627] - Ammphodiacetate
[0628] - Fatty acid amides of serinol and
[0629] - N-acyl amino acids preferably selected from the group consisting of:
[0630] Fatty acid amide alkoxylates, preferably selected from the list consisting of: - Fatty acid amide ethoxylates, and / or
[0631] - Fatty acid amide ethoxylate / propoxylates,
[0632] N-Acyl-N-Alkyl-Glucamine linear sugar,
[0633] - Alkyl-amidopropyl betaine,
[0634] - Alkyl-amidopropyl-N-oxide,
[0635] - Amphoacetates
[0636] - Ammphodiacetate and
[0637] - N-acyl amino acids.
[0638] Surfactant compounds that fall under the definitions above often yield particularly advantageous results. Furthermore, these surfactant compounds can often be produced from temperate vegetable oils in a particularly advantageous and simple manner.
[0639] The effects and advantages described above in connection with the detergent according to the invention (as described above, preferably as designated above as preferred) are realized in many cases in a preferentially positive manner with the surfactant compounds defined above. In each specific case, the person skilled in the art identifies the most suitable surfactant compounds from the aforementioned list by means of simple manual experiments without unreasonable effort and / or on the basis of their general technical knowledge.
[0640] A detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent comprises at least one surfactant compound from group v), preferably at least one surfactant compound from group v) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, preferably at least one surfactant compound from group v), having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, and is selected from the group consisting of:
[0641] Alkyliminoacetates,
[0642] Alkyliminodiacetates,
[0643] Alkyliminopropionate, and
[0644] Alkyliminodipropionate.
[0645] Surfactant compounds that fall under the definitions above often yield particularly advantageous results. Furthermore, these surfactant compounds can often be produced from temperate vegetable oils in a particularly advantageous and simple manner.
[0646] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent comprises one, two, three or more surfactant compounds selected from i) to iv) having hydrocarbon residues R with a total number of 17 to 23 carbon atoms, the hydrocarbon residues R having a ratio of 14 carbon atoms 12exhibiting C atoms, which corresponds to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, and wherein preferably the mass fraction of surfactant compounds with hydrocarbon residues R with a total number of 7 to 23 C atoms, whose hydrocarbon residues R have a ratio of 14 carbon atoms 12exhibiting C atoms, corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, in the total mass of the surfactant compounds contained in the detergent in the range of 80 wt.% to 100 wt.%, preferably in the range of 85 wt.% to 100 wt.%, particularly preferably in the range of 90 wt.% to 100 wt.%; and / or, preferably “and”, wherein the detergent comprises one, two, three or more surfactant compounds selected from i) to iv) with hydrocarbon residues R having a total number of 7 to 10 C atoms, preferably having a total number of 7 to 9 C atoms, the hydrocarbon residues R having a total number of 7 to 10 C atoms, preferably having a total number of 7 to 9 C atoms, in a ratio of 14 carbon atoms 12exhibiting C atoms, corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, and wherein preferably the mass fraction of surfactant compounds with hydrocarbon residues R having a total number of 7 to 23 C atoms, whose hydrocarbon residues R have a ratio of 14 carbon atoms 12 exhibiting C atoms, corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, in the total mass of the surfactant compounds contained in the detergent in the range of 80 wt.% to 100 wt.%, preferably in the range of 85 wt.% to 100 wt.%, particularly preferably in the range of 90 wt.% to 100 wt.%; and / or, preferably “and”, wherein in the total mass of all surfactant compounds contained in the detergent selected from i) to iv) a total ratio of 14 C atoms to 12C atoms are present, which corresponds to an age of the corresponding total mass of all surfactant compounds present in the detergent of less than 300 years since carbon dioxide fixation.
[0647] In many cases, a detergent is preferred, comprising one, two, three or more surfactant compounds selected from i) to iv) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, wherein the hydrocarbon residue R having a total number of 17 to 23 C atoms has a ratio of 14 carbon atoms 12 exhibits C atoms, which corresponds to an age of the corresponding hydrocarbon residue of less than 300 years since carbon dioxide fixation.
[0648] This, in turn, is understood in the field of the present invention as an indication of the origin of a corresponding hydrocarbon residue R from renewable plant raw materials of the temperate zone and is therefore considered particularly preferred in the field of the present invention.
[0649] That the proportion of surfactant compounds with a corresponding ratio of 14 C atoms to 12The proportion of carbon atoms in the total mass of the surfactant compounds contained in the detergent is in the range of 80 wt.% to 100 wt.%, preferably in the range of 85 wt.% to 100 wt.%, and particularly preferably in the range of 90 wt.% to 100 wt.%, which is particularly preferred in many cases because in this way particularly advantageous combinations of advantageously good cleaning performance and / or washing performance of the detergent on the one hand and advantageously high proportions of surfactant compounds based on vegetable oils of the temperate zone on the other hand are regularly realized and recognizable in a particularly advantageously simple way.
[0650] In many cases, a detergent is preferred (as described above, preferably as referred to above as preferred), wherein all surfactant compounds contained in the detergent are selected from i) to iv) in a total ratio of 14 carbon atoms 12exhibiting C atoms, which corresponds to an age of the corresponding total amount of surfactant compounds contained in the detergent of less than 300 years since carbon dioxide fixation.
[0651] In the field of the present invention, this is understood as an indication that all carbon atoms contained in the detergent originate from renewable plant-based raw materials and is therefore considered particularly advantageous in the field of the present invention. The effects and advantages described above in connection with the detergent according to the invention are also preferably realized here.
[0652] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent is a washing agent; preferably a washing agent selected from the group consisting of:
[0653] - Laundry detergent,
[0654] - Color detergent,
[0655] - Delicate detergent, and
[0656] - Special detergent; and / or wherein the detergent is a cleaning agent, preferably a cleaning agent for hard surfaces, particularly preferably a cleaning agent for hard surfaces selected from the group of cleaning agents for hard surfaces consisting of:
[0657] - Toilet cleaner,
[0658] - All-purpose cleaner,
[0659] - Bathroom cleaner,
[0660] - Floor cleaner,
[0661] Oven cleaner,
[0662] - Grill cleaner,
[0663] - Glass cleaner, - Metal cleaner, and
[0664] - Special cleaner; and / or wherein the detergent is a cosmetic cleaner, preferably a cosmetic cleaner selected from the group of cosmetic cleaners consisting of:
[0665] Hand soap,
[0666] Shower gel
[0667] Hair shampoo, and
[0668] Facial cleanser; and / or wherein the detergent is a dishwashing liquid, preferably a
[0669] Hand dishwashing liquid and / or
[0670] Dishwashing detergent and / or wherein the detergent is a cleaning agent for textile surfaces, preferably a
[0671] - Upholstery cleaner and / or
[0672] - Carpet cleaner; and / or wherein the detergent is a cleaning agent for leather and / or imitation leather.
[0673] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a washing agent; preferably, the detergent is a washing agent selected from the group consisting of: heavy-duty detergents, color detergents, and delicate detergents. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a washing agent, preferably a washing agent selected from the group defined above. In many cases, the combination of advantageously high washing performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in washing agents.
[0674] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a cleaning agent, preferably a cleaning agent for hard surfaces, and particularly preferably a cleaning agent for hard surfaces selected from the group of cleaning agents consisting of: toilet cleaner, all-purpose cleaner, bathroom cleaner, floor cleaner, oven cleaner, grill cleaner, glass cleaner, and metal cleaner. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a cleaning agent, preferably a cleaning agent selected from the group defined above.In many cases, the combination of properties of advantageously high cleaning performance and a high proportion of renewable surfactants in the field of the present invention is perceived as particularly positive, especially in cleaning agents.
[0675] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a cosmetic cleanser, preferably a cosmetic cleanser selected from the group consisting of: hand soap, shower gel, shampoo, and facial cleanser. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a cosmetic cleanser, preferably a cosmetic cleanser selected from the group defined above. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in cosmetic cleansers.
[0676] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a dishwashing liquid, preferably a dishwashing liquid selected from the group consisting of: hand dishwashing liquids, machine dishwashing liquids, and combinations thereof, preferably selected from the group consisting of: hand dishwashing liquids and machine dishwashing liquids. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a dishwashing liquid, preferably a dishwashing liquid selected from the group defined above. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in dishwashing liquids.
[0677] In many cases, a detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent is a cleaning agent for textile surfaces, preferably a cleaning agent for textile surfaces selected from the group of cleaning agents for textile surfaces consisting of: upholstery cleaners, carpet cleaners and combinations thereof, particularly preferably selected from the group consisting of: upholstery cleaners and carpet cleaners. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferably positive manner with a detergent that is a cleaning agent for textile surfaces, preferably a cleaning agent for textile surfaces selected from the group defined above.In many cases, the combination of properties of advantageously high cleaning performance and a high proportion of renewable surfactants in the field of the present invention is perceived as particularly positive, especially in cleaning agents for textile surfaces.
[0678] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a cleaning agent for leather and / or artificial leather. The effects and advantages described above in connection with the detergent according to the invention are preferably realized in a positive manner with a detergent that is a cleaning agent for leather and / or artificial leather. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in cleaning agents for leather and / or artificial leather.
[0679] A detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is a component of a washing agent and / or is a washing agent; preferably
[0680] - Component of a detergent and / or
[0681] - a detergent selected from the group consisting of:
[0682] - Laundry detergent, preferably liquid laundry detergent,
[0683] - Color detergent, preferably liquid color detergent, and
[0684] - Detergent, preferably liquid; and / or wherein the detergent is a component of a cleaning agent, preferably a cleaning agent, preferably a cleaning agent for hard surfaces, particularly preferably a cleaning agent for hard surfaces selected from the group of cleaning agents for hard surfaces consisting of:
[0685] - Toilet cleaner, preferably liquid toilet cleaner,
[0686] - All-purpose cleaner, preferably liquid all-purpose cleaner,
[0687] - Bathroom cleaner, preferably liquid bathroom cleaner, - Kitchen cleaner, preferably liquid kitchen cleaner,
[0688] - Degreaser, preferably liquid degreaser,
[0689] - Floor cleaner, preferably liquid floor cleaner,
[0690] - Oven cleaner, preferably liquid oven cleaner,
[0691] - Grill cleaner, preferably liquid grill cleaner,
[0692] - Glass cleaner, preferably liquid glass cleaner, and
[0693] - Metal cleaner, preferably liquid metal cleaner; and / or wherein the detergent is a component of a cosmetic cleaner and / or is a cosmetic cleaner, preferably
[0694] - Component of a cosmetic cleanser and / or
[0695] - a cosmetic cleanser selected from the group of cosmetic cleansers consisting of:
[0696] Hand soap, preferably liquid hand soap,
[0697] Shower gel
[0698] Hair shampoo, preferably liquid hand shampoo, and
[0699] Facial cleanser, preferably liquid facial cleanser; and / or wherein the detergent is a component of a dishwashing liquid and / or is a dishwashing liquid, preferably
[0700] - Component of a dishwashing liquid and / or
[0701] - a dishwashing liquid selected from the group consisting of:
[0702] - Hand dishwashing detergent, preferably liquid hand dishwashing detergent and / or
[0703] - Dishwashing detergent, preferably liquid dishwashing detergent and / or wherein the detergent is a component of a cleaning agent for textile surfaces and / or is a cleaning agent for textile surfaces, preferably
[0704] - Component of a cleaning agent for textile surfaces and / or
[0705] - a cleaning agent for textile surfaces selected from the group consisting of: a
[0706] - Upholstery cleaner, preferably liquid upholstery cleaner, and / or
[0707] - Carpet cleaner, preferably liquid carpet cleaner; and / or wherein
[0708] - the detergent is a cleaning agent for leather and / or artificial leather, preferably a liquid cleaning agent for leather and / or artificial leather and / or
[0709] - the detergent is a component of a cleaning agent for leather and / or artificial leather, preferably a component of a liquid cleaning agent for leather and / or artificial leather.
[0710] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a washing agent; preferably, the detergent is a washing agent selected from the group consisting of: heavy-duty detergents, color detergents, and delicate detergents. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a washing agent, preferably a washing agent selected from the group defined above. In many cases, the combination of advantageously high washing performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in washing agents.
[0711] In many cases, a detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent is a cleaning agent, preferably a cleaning agent for hard surfaces, and particularly preferably a cleaning agent for hard surfaces selected from the group of cleaning agents consisting of: toilet cleaner, all-purpose cleaner, bathroom cleaner, kitchen cleaner, degreaser, floor cleaner, oven cleaner, grill cleaner, glass cleaner, and metal cleaner. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a cleaning agent, preferably a cleaning agent selected from the group defined above.In many cases, the combination of properties of advantageously high cleaning performance and a high proportion of renewable surfactants in the field of the present invention is perceived as particularly positive, especially in cleaning agents.
[0712] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a cosmetic cleanser, preferably a cosmetic cleanser selected from the group consisting of: hand soap, shower gel, shampoo, and facial cleanser. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a cosmetic cleanser, preferably a cosmetic cleanser selected from the group defined above. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in cosmetic cleansers.
[0713] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a dishwashing liquid, preferably a dishwashing liquid selected from the group consisting of: hand dishwashing liquids, machine dishwashing liquids, and combinations thereof, preferably selected from the group consisting of: hand dishwashing liquids and machine dishwashing liquids. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferentially positive manner with a detergent that is a dishwashing liquid, preferably a dishwashing liquid selected from the group defined above. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in dishwashing liquids.
[0714] In many cases, a detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent is a cleaning agent for textile surfaces, preferably a cleaning agent for textile surfaces selected from the group of cleaning agents for textile surfaces consisting of: upholstery cleaners, carpet cleaners and combinations thereof, particularly preferably selected from the group consisting of: upholstery cleaners and carpet cleaners. The effects and advantages described above in connection with the detergent according to the invention are realized in a preferably positive manner with a detergent that is a cleaning agent for textile surfaces, preferably a cleaning agent for textile surfaces selected from the group defined above.In many cases, the combination of properties of advantageously high cleaning performance and a high proportion of renewable surfactants in the field of the present invention is perceived as particularly positive, especially in cleaning agents for textile surfaces.
[0715] In many cases, a detergent (as described above, preferably as referred to above as preferred) is preferred, wherein the detergent is a cleaning agent for leather and / or artificial leather. The effects and advantages described above in connection with the detergent according to the invention are preferably realized in a positive manner with a detergent that is a cleaning agent for leather and / or artificial leather. In many cases, the combination of advantageously high cleaning performance and a high proportion of renewable surfactants is perceived as particularly positive in the field of the present invention, especially in cleaning agents for leather and / or artificial leather.
[0716] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein the detergent comprises surfactant compounds selected from i) to iv) having a monounsaturated hydrocarbon residue R with a total number of 15 to 23 C atoms, and wherein the proportion of monounsaturated hydrocarbon residues R is preferably in the range of 20 wt.% to 90 wt.%, more preferably in the range of 30 wt.% to 90 wt.%, based on the total mass of hydrocarbon residues R with a total number of 15 to 23 C atoms present in the detergent; and / or, preferably “and” wherein the detergent comprises surfactant compounds selected from i) to iv) with a monounsaturated hydrocarbon residue R having 16 to 23 C atoms, and wherein preferably the proportion of monounsaturated hydrocarbon residues R is in the range of 20 wt.% to 90 wt.%, preferably in the range of 30 wt.% to 90 wt.%.-%, based on the total mass of hydrocarbon residues R with 16 to 23 C atoms present in the detergent; and / or, preferably “and”, wherein the detergent comprises surfactant compounds selected from i) to iv) with a monounsaturated hydrocarbon residue R with 17 to 23 C atoms, and wherein preferably the proportion of monounsaturated hydrocarbon residues R is in the range of 20 wt.% to 90 wt.%, more preferably in the range of 30 wt.% to 90 wt.%, based on the total mass of hydrocarbon residues R with 17 to 23 C atoms present in the detergent.
[0717] A detergent according to the invention (as described above, preferably referred to as preferred above) is in many cases produced from vegetable oils of the temperate zone in a particularly advantageously simple manner (this means in particular: with advantageously few separation steps in the production of the surfactant compounds contained therein) and simultaneously possesses particularly advantageous washing and / or cleaning properties. This combination is frequently particularly preferred in the field of the present invention.
[0718] The effects and advantages described above in connection with the detergent according to the invention are also preferably realized here.
[0719] A preferred detergent (as described above, preferably as referred to above as preferred) is present in the detergent, wherein at least one of groups i) to iv) contains two different surfactant compounds which differ from each other with respect to their chemical composition solely by the different chain lengths of their hydrocarbon residues R; and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 7, 8, 9, 10, 15, 17, 19, 21 and 23; and / or wherein at least one of groups i) to iv) contains two different surfactant compounds which differ from each other with respect to their chemical composition solely by the different chain lengths of their hydrocarbon residues R;and wherein the hydrocarbon residues R are saturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 7, 8, 9, 10, 15, 17, 19, 21 and 23; and / or wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other in their chemical composition solely by the different chain lengths of their hydrocarbon chains R; and wherein the hydrocarbon residues R are unsaturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 9, 15, 17, 19, 21 and 23;and / or wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other in their chemical composition solely by their different chain lengths of the hydrocarbon residues R; and wherein the hydrocarbon residues R are monounsaturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 9, 15, 17, 19, 21 and 23;and / or wherein a total number of surfactant compounds from at least one of groups i) to iv) are present in the detergent, wherein the surfactant compounds are produced from a vegetable oil and, due to the manufacturing process, differ from one another with respect to their chemical composition solely by their different chain lengths of their hydrocarbon residues R, wherein preferably the chain lengths of the hydrocarbon residues R correspond to chain lengths as they occur in natural vegetable oil, preferably in the natural vegetable oil of a plant selected from the group of plants consisting of:;
[0720] Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof, preferably consisting of
[0721] Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, camelina, flax, almond, poppy, evening primrose, olive, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof.
[0722] A preferred detergent (as described above, preferably as referred to above as preferred) is selected, wherein at least one of groups i) to iv) comprises a surfactant compound having at least two different chain lengths of the hydrocarbon residues R, and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths: 7, 8, 9, 10, 15, 17, 19, 21, and 23 carbon atoms. With a suitable detergent, particularly advantageous combinations of properties are obtained in many cases; the person skilled in the art recognizes these advantageous combinations based on their general knowledge and the teachings of the present invention.
[0723] A preferred detergent (as described above, preferably as referred to above as preferred) is present, wherein at least one of groups i) to iv) comprises a surfactant compound having at least two different chain lengths of the hydrocarbon residues R, and wherein the hydrocarbon residues R are saturated hydrocarbon chains, and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths: 7, 8, 9, 10, 15, 17, 19, 21, and 23 carbon atoms. With a suitable detergent, particularly favorable combinations of properties are obtained in many cases; the person skilled in the art recognizes these favorable combinations of properties based on their general knowledge and the teachings of the present invention.
[0724] A preferred detergent (as described above, preferably referred to as preferred above) is present, wherein at least one of groups i) to iv) comprises a surfactant compound having at least two different chain lengths of hydrocarbon chains R, and wherein the hydrocarbon residues R are unsaturated hydrocarbon chains, and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths: 9 carbon atoms, 15 carbon atoms, 17 carbon atoms, 19 carbon atoms, 21 carbon atoms, and 23 carbon atoms. With a suitable detergent, particularly favorable combinations of properties are obtained in many cases; the person skilled in the art recognizes these favorable combinations of properties based on their general knowledge and the teachings of the present invention.A preferred detergent (as described above, preferably referred to as preferred above) is present, wherein at least one of groups i) to iv) comprises a surfactant compound having at least two different chain lengths of the hydrocarbon residues R, and wherein the hydrocarbon residues R are monounsaturated hydrocarbon chains, and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths: 9 carbon atoms, 15 carbon atoms, 17 carbon atoms, 19 carbon atoms, 21 carbon atoms, and 23 carbon atoms. With a suitable detergent, particularly favorable combinations of properties are obtained in many cases; the person skilled in the art recognizes these favorable combinations of properties based on their general knowledge and the teachings of the present invention.
[0725] A detergent (as described above, preferably referred to as preferred above) is preferred, wherein a surfactant compound is selected from at least one of groups i) to iv), which is produced from a vegetable oil and, due to the manufacturing process, has at least two different chain lengths of the hydrocarbon residues R that occur in the natural vegetable oil, preferably in the natural vegetable oil of a plant selected from the group of plants consisting of: hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip rape, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof.
[0726] Particularly preferred is a detergent (as described above, preferably referred to as preferred above), wherein a surfactant compound is selected from at least one of groups i) to iv), which is produced from a vegetable oil of the temperate zone and, due to the manufacturing process, has at least two different chain lengths of the hydrocarbon residues R that occur in the natural vegetable oil of the temperate zone, preferably in the natural vegetable oil of a plant of the temperate zone selected from the group of plants consisting of: hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, camelina, flax, almond, poppy, evening primrose, olive, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor bean, turnip rape, safflower, black cumin, sesame, sunflower, soybean, walnut, grape and combinations thereof.
[0727] With a suitable detergent, particularly favorable combinations of properties are often obtained; the person skilled in the art recognizes these favorable combinations based on their general technical knowledge and the teachings of the present invention. Furthermore, such a detergent can be produced in a particularly advantageous manner, and detergents made from the aforementioned raw materials are considered particularly advantageous in the field of the present invention.
[0728] A detergent is preferred (as described above, preferably referred to as preferred above), wherein the detergent additionally contains one, two, three or more substances selected from the group consisting of:
[0729] Abrasive materials, preferably marble dust, chalk, clay and / or pumice,
[0730] Adsorbent, preferably wood, cellulose and / or plastic flour,
[0731] Alkalis, preferably ammonia, organic amines, sodium carbonate, sodium hydroxide and / or potassium hydroxide,
[0732] Alcohols, preferably ethanol, n-propanol and / or isopropanol
[0733] Bitter substances,
[0734] Bleaching agents, preferably oxygen-based bleaching agents, - bleach activators, preferably tetraacetylethylenediamine (TAED),
[0735] Complexing agents, preferably citrates, tetrasodium N,N-bis(carboxymethyl)-L-glutamate (GLDA), methylglycine diacetic acid trisodium salt (MGDA), iminodisuccinate tetrasodium salt (IDS), ethylendiamine N,N'-disuccinate trisodium salt (EDDS),
[0736] Fragrances,
[0737] Enzymes, preferably amylases, cellulases, lipases and / or proteases,
[0738] Dyes,
[0739] Preservatives, corrosion inhibitors, organic solvents,
[0740] Oils, fats and / or waxes,
[0741] Optical brighteners,
[0742] Acid,
[0743] Sequestrants and framework materials, preferably polycarboxylates and / or zeolites
[0744] Polymers, preferably polyester, polyamide, polyglycol, polyurethane, polysaccharide, polypeptide and / or other biopolymers
[0745] Discoloration inhibitors, preferably polyvinylpyrrolidone, polyvinylpyrrolidone-polyvinylimidazole and / or polyvinylpyridine N-oxide and
[0746] Water.
[0747] Abrasive materials, preferably marble dust, chalk, clay, and / or pumice, are often preferentially used in the detergent according to the invention when the detergent is an abrasive, a metal polish, and / or a stove cleaner. Corresponding ingredients such as marble dust, chalk, clay, and / or pumice serve here as mechanical abrasive components (abrasives) and polishing components (polishing agents). Due to their abrasiveness (scouring action), the abrasives enhance the cleaning performance.
[0748] Adsorbents, preferably wood, cellulose, and / or plastic flour, are often preferred in the detergent according to the invention when the detergent is a cleaning agent for textile surfaces, particularly preferably a carpet cleaner. Wood, cellulose, and plastic flour are used, for example, in powdered carpet cleaners as absorbent carrier materials, which are impregnated with liquid surfactants and / or solvents for this purpose. Alkalis, preferably ammonia, organic amines, sodium carbonate, sodium hydroxide, and / or potassium hydroxide, are often preferred in the detergent according to the invention. Ammonia, soda, sodium hydroxide, and potassium hydroxide are the most important basic materials for dirt-dissolving alkalis, which remove particularly stubborn deposits and blockages. They ensure the removal of oils, greases, and varnishes, but cannot dissolve limescale.
[0749] Alcohols, preferably ethanol, n-propanol, and / or isopropanol, are often preferred in the detergent according to the invention, particularly when the detergent is a glass cleaner or a liquid washing agent. The use of alcohols is also preferred in some other cases; those skilled in the art can identify these cases independently based on their general technical knowledge. Glass cleaners and liquid washing agents frequently contain alcohols in addition to the surfactants. The alcohols perform several functions simultaneously. They act as solubilizers to keep the raw materials in solution without clouding. As solvents, lower alcohols enhance the dirt-dissolving effect of the surfactants. Additionally, at higher concentrations, they act as preservatives and increase the storage stability of enzymes.
[0750] Bitter substances are often preferred in the detergent according to the invention. Generally, washing, dishwashing, and cleaning agents should be kept out of the reach of children. To prevent children who nevertheless get hold of a washing or cleaning agent from drinking the product, a bitter substance is often added. This bitter substance is intended to cause the product to be spat out immediately.
[0751] Bleaching agents, preferably oxygen-based bleaching agents, and bleach activators, preferably tetraacetylethylenediamine (TAED), are often preferably used in the detergent according to the invention when the detergent is a washing agent. Bleaching agents oxidize the organic dyes present in the laundry soil and thereby decolorize them. Percarbonate is predominantly used as an oxygen-based bleaching agent, which releases bleach-active oxygen at higher temperatures. Bleach activators increase the effectiveness of bleaching agents at low washing temperatures. Complexing agents, preferably citrates, tetrasodium N,N-bis(carboxymethyl)-L-glutamate (GLDA), methylglycine diacetic acid trisodium salt (MGDA), iminodisuccinate tetrasodium salt (IDS), and ethylenediamine N,N'-disuccinate trisodium salt (EDDS), are often preferably used in the detergent according to the invention.Complexing agents, for example citrates, phosphates, phosphonates, carboxylates, EDTA (ethylenediaminetetraacetic acid), or NTA (tris(carboxymethyl)amine), are used to soften water and to enhance the cleaning action of products. Hard water makes the cleaning process more difficult, as the effectiveness of many surfactants is limited by the water hardness. Particularly in cases where the detergent according to the invention comprises surfactant compounds selected from group i), it is generally preferred if the detergent also includes complexing agents.
[0752] Fragrances are often preferably used in the detergent according to the invention. Fragrances in washing and cleaning agents (detergents) are intended to give the product a pleasant fragrance and simultaneously mask unpleasant odors of the components or the washing solution. Fragrances in laundry detergents or fabric softeners additionally impart a fragrance to the washed, damp laundry and the laundry ready for storage.
[0753] Enzymes, preferably amylases, cellulases, lipases, and / or proteases, are often used in the detergent according to the invention. Enzymes are proteins that can catalytically transform chemical substances. A specific enzyme can only cleave a specific chemical structure; the resulting products are then removed by the surfactants. Amylases remove starchy food residues from textiles or dishes. Cellulases indirectly improve the removal of dirt from cotton and other cellulose fibers because they break down amorphous cellulose components and protruding microfibril bundles. Lipases can break down natural fats and oils even at low temperatures on the surface to be cleaned and in the washing solution, making these soils significantly easier to remove. Proteases are the enzymes used longest and most frequently in detergents and machine dishwashing liquids.They break down protein-based stains such as blood, milk, egg, or cocoa, which are often very difficult to remove or wash off due to aging. Most enzymes work optimally in the temperature range of approximately 40° to 60°C.
[0754] Dyes are often preferably used in the detergent according to the invention. The purpose of dyes is to give the washing and cleaning agent (detergent) an appealing appearance, while simultaneously masking the variations in the inherent color caused by large-scale production.
[0755] Preservatives are often preferably used in the detergent according to the invention. To improve the shelf life of liquid or pasty (gel-like) washing agents and washing aids, they are sometimes supplemented with small amounts of chemical substances that prevent the development and growth of bacteria and fungi, such as mold and putrefactive organisms.
[0756] Corrosion inhibitors are often preferably used in the detergent according to the invention when the detergent is a washing agent. If aluminum parts come into contact with the strongly alkaline washing solution, corrosion damage results. Therefore, corrosion inhibitors such as silicates, organic salts, special surfactants, or fatty acids are often added to the washing agent.
[0757] Organic solvents are often preferred in the detergent according to the invention. Solvents are liquids that dissolve active ingredients without altering their composition, e.g., acetone, alcohol, gasoline, glycols, or water. They contribute to cleaning and evaporate after use. Solvents are particularly effective at removing stubborn dirt such as oil, grease, wax, tar, old layers of care products, paints, varnishes, and adhesives. They are also frequently necessary for the production of emulsions together with paraffin oil, fats, waxes, etc., in products for furniture, shoe, floor, and car care. Based on a voluntary agreement, manufacturers of cleaning and care products refrain from using highly effective but potentially harmful, volatile solvents such as chlorinated hydrocarbons. Water-immiscible solvents, e.g., gasoline, must not enter wastewater systems.
[0758] Oils, fats, and / or waxes are often preferred in the detergent according to the invention. Oils, fats, and waxes are components of care products and conditioning cleaning agents. They provide corrosion protection, repel water, facilitate polishing, and protect the material surface, for example, against burn-in damage.
[0759] Optical brighteners are often preferably used in detergents according to the invention when the detergent is a washing agent. The optical brighteners used as whitening agents / brighteners in washing agents adhere to the fibers and are able to convert ultraviolet light, invisible to the human eye, into visible blue light. This additional blue light, together with the complementary color yellow, gives the laundry a particularly brilliant white. Optical brighteners adhere to the fibers during washing and then remain on the laundry. Accordingly, they have no washing effect.
[0760] Acids are often preferentially used in the detergent according to the invention when the detergent is a bathroom cleaner and / or a cleaner for hard surfaces contaminated with limescale. Formic, sulfamic, citric, acetic, lactic, methanesulfonic, phosphoric, or hydrochloric acid are added to cleaning agents in suitable concentrations to remove limescale deposits. Some of them possess disinfectant properties. The organic acids are readily biodegradable.
[0761] Sequestrants and builders, preferably polycarboxylates and / or zeolites, are often preferred when the detergent is a washing powder. Polycarboxylates are the water-soluble salts of polycarboxylic acids. In phosphate-free washing powders, they are used in combination with zeolite A as co-builders (builders) to prevent the precipitation of sparingly soluble alkaline earth salts. This prevents deposits from forming on the laundry or the heating elements of the washing machine. Furthermore, as anti-graying agents, they improve the color vibrancy of the laundry.
[0762] Polymers, preferably polyesters, polyamides, polyglycols, polyurethanes, polysaccharides, polypeptides, and / or other biopolymers, are often preferred in the detergent according to the invention. Polymers preferably used in the detergent according to the invention are gloss-enhancing or protective plastics such as polystyrene, polyacrylates, polyurethanes, and polyethylenes, which are used as aqueous mixtures in care products. After the water evaporates, mechanically resistant protective films are formed, which are intended to prevent rapid resoiling. Polymers are only partially subject to biodegradation processes. They are bound to sewage sludge.
[0763] Discoloration inhibitors, preferably polyvinylpyrrolidone, polyvinylpyrrolidone-polyvinylimidazole, and / or polyvinylpyridine N-oxide, are often preferred in the detergent according to the invention when the detergent is a washing agent and / or a cleaning agent for textile surfaces. When washing textiles made of cellulose fibers, for example, cotton, linen, or viscose, the discoloration inhibitor generally prevents or reduces the staining of these textiles by leaching dyes. Water is often preferred in the detergent according to the invention when the detergent is in liquid (or gel) form. The water content is often used to adjust the viscosity of the detergent to a value that is considered preferred in the field of the present invention.
[0764] In many cases, a detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent additionally contains one, two, three or more substances selected from the group consisting of:
[0765] Abrasive materials, preferably marble dust, chalk, clay and / or pumice,
[0766] Alkalis, preferably ammonia, organic amines, sodium carbonate, sodium hydroxide and / or potassium hydroxide,
[0767] Alcohols, preferably ethanol, n-propanol and / or isopropanol
[0768] Complexing agents, preferably citrates, tetrasodium N,N-bis(carboxymethyl)-L-glutamate (GLDA), methylglycine diacetic acid trisodium salt (MGDA), iminodisuccinate tetrasodium salt (IDS), ethylendiamine N,N'-disuccinate trisodium salt (EDDS),
[0769] Fragrances,
[0770] Enzymes, preferably amylases, cellulases, lipases and / or proteases,
[0771] Dyes,
[0772] Preservatives, organic solvents,
[0773] Oils, fats and / or waxes,
[0774] Acids, sequestrants and framework materials, preferably polycarboxylates and / or zeolites
[0775] Polymers, preferably polyester, polyamide, polyglycol, polyurethane, polysaccharide, polypeptide and / or other biopolymers and
[0776] Water.
[0777] In many cases, a particularly favorable combination of properties is obtained with a suitable detergent; the person skilled in the art recognizes these favorable combinations of properties based on their general technical knowledge and the teachings of the present invention. The person skilled in the art independently applies the additional substances defined above based on their general technical knowledge and the requirements of the individual case.
[0778] A detergent is preferred (as described above, preferably as referred to above as preferred), wherein the detergent is substantially free, preferably completely free, of:
[0779] Abrasive material, preferably marble dust, chalk, clay and / or pumice and / or, preferably “and”
[0780] Adsorbent, preferably wood, cellulose and / or plastic flour and / or, preferably “and”
[0781] - Bitter substances and / or, preferably “and”
[0782] Bleaching agents, preferably oxygen-based, and / or, preferably, bleach activators, preferably tetraacetylethylenediamine (TAED), and / or, preferably, and
[0783] - Biocides and / or, preferably “and”
[0784] - Preservatives and / or, preferably “and”
[0785] - Corrosion inhibitors and / or, preferably “and”
[0786] - Solvents and / or, preferably “and”
[0787] - Oils, fats and / or waxes and / or, preferably “and”
[0788] - Optical brighteners and / or, preferably “and”
[0789] Sequestrants and framework materials, preferably polycarboxylates and / or zeolites and / or, preferably “and”
[0790] Polymers, preferably polyester, polyamide, polyglycol, polyurethane, polysaccharide, polypeptide and / or other biopolymers and / or, preferably, discoloration inhibitors, preferably polyvinylpyrrolidone, polyvinylpyrrolidone-polyvinylimidazole and / or polyvinylpyridine N-oxide.
[0791] In many cases, a detergent (as described above, preferably referred to as preferred above) is also preferred, wherein the detergent is essentially free, preferably completely free, of:
[0792] Abrasive material, preferably marble dust, chalk, clay and / or pumice and / or, preferably “and”
[0793] Adsorbent, preferably wood, cellulose and / or plastic flour and / or, preferably “and”
[0794] - Bitter substances and / or, preferably “and”
[0795] - Biocides and / or, preferably “and”
[0796] - Corrosion inhibitors and / or, preferably “and”
[0797] - Oils, fats and / or waxes and / or, preferably “and”
[0798] - Optical brighteners and / or, preferably “and
[0799] Discoloration inhibitors, preferably polyvinylpyrrolidone, polyvinylpyrrolidone-polyvinylimidazole and / or polyvinylpyridine N-oxide. The conjunction "and / or", preferably "and", within the scope of the present invention means that an and / or conjunction exists and, as a preferred embodiment, the "and / or" conjunction in question is replaced by an "and".
[0800] In many cases, the use of the substances defined above is not preferred in the field of the present invention. A detergent according to the invention in which these substances are not present is therefore preferred in many cases. That the detergent is substantially free of these substances means that it contains no more than the impurities with these substances typically occurring in the field of the present invention, but no additional amounts of these substances. That the detergent is completely free of these substances means that these substances are not detectable in the detergent using the analytical methods customary in the field of the present invention.
[0801] In many cases, a particularly favorable combination of properties is obtained with a suitable detergent; the person skilled in the art recognizes these favorable combinations of properties based on their general technical knowledge and the teachings of the present invention. The person skilled in the art independently applies the additional substances defined above based on their general technical knowledge and the requirements of the individual case.
[0802] The invention further relates to a method for producing a detergent, as described above, preferably as referred to above as preferred, comprising the following steps:
[0803] S1) Manufacture or provision of a first component comprising one or more surfactant compounds, each selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other
[0804] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 17 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound, and
[0805] R 1 and / or R 2Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant;
[0806] S2) Manufacture or provision of a second component comprising one or more surfactant compounds, each selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other
[0807] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 10, preferably with 7 to 9, carbon atoms, which forms the hydrophobic part of the respective surfactant compound and R 1and / or R 2 Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant.
[0808] 53) optional: Manufacturing or supplying one or more further components, comprising further additives;
[0809] 54) Contactful mixing of each quantity of the components produced and / or provided in steps S1) and S2), preferably those produced and / or provided in steps S1), S2) and S3), so that the detergent results.
[0810] The detergent according to the invention is produced in a particularly advantageous manner using the process according to the invention. Preferably, in many cases, the number of process steps is kept advantageously low. Preferably, in many cases, the required energy consumption is also kept advantageously low.
[0811] The effects and advantages described above in connection with the detergent according to the invention are also realized in a particularly preferred manner in connection with the process according to the invention.
[0812] The mixing of a quantity each of the components produced and / or provided in step S1) and in step S2), preferably the components produced and / or provided in steps S1), S2), and S3), so that a detergent results in step S4), is in many cases preferably carried out according to a predefined recipe. In these cases, the quantities are specified by the recipe and used accordingly during mixing.
[0813] A preferred method is (as described above, preferably referred to as preferred above) wherein the preparation or provision of the first component in step S1) comprises the preparation of one, two or more surfactant compounds, each in a method comprising the following steps:
[0814] S1-1 a) Manufacture or supply of a plant or part of a plant, wherein the plant is selected from the group of plants consisting of:
[0815] Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof;
[0816] S1-2a) Producing a vegetable oil from the plant produced or provided in step S1-1 a) or from the part of a plant produced or provided in step S1-1 a); such that a vegetable oil results;
[0817] S1-3a) Prepare a surfactant compound from the vegetable oil resulting from step S1-2a), such that a surfactant compound results.
[0818] The surfactant compound resulting from step S1-3a) is preferably the surfactant compound produced or provided in step S1). Corresponding manufacturing processes are known to those skilled in the art from general technical knowledge.
[0819] In this way, the inventive process advantageously and simply produces a detergent according to the invention which contains a proportion of surfactant compounds from plant-based raw materials of the temperate zone and preferably possesses a particularly positive cleaning and / or washing performance. Such a detergent and such a process for producing a detergent are particularly preferred in the field of the present invention.
[0820] A preferred method (as described above, preferably referred to as preferred above) is wherein the preparation or provision of the second component in step S2) comprises the preparation of one or more surfactant compounds, each in a method comprising the following steps: S2-1 a) Preparation or provision of a plant or part of a plant, wherein the plant is selected from:
[0821] Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof;
[0822] S2-2a) Producing a vegetable oil from the plant produced or made available in step S2-1 a) or from the part of a plant produced or made available in step S2-1 a); such that a vegetable oil results;
[0823] S2-3a) Carrying out a reaction, preferably
[0824] Performing a metathesis reaction so that metathesis products result; and / or, preferably “or”
[0825] Performing an oxidative cleavage reaction, preferably an ozonolysis reaction, such that oxidative cleavage products, preferably ozonolysis products, result;
[0826] S2-4a) Preparation of a surfactant compound from at least one of the metathesis products resulting in step S2-3a) or at least one of the oxidative cleavage products resulting in step S2-3a), preferably ozonolysis products, such that a surfactant compound results.
[0827] The surfactant compound resulting from step S2-4a) is preferably the surfactant compound produced or provided in step S2). Corresponding manufacturing processes are known from general technical knowledge.
[0828] In many cases, it is preferred to carry out a metathesis reaction in step S2-3a) so that metathesis products result.
[0829] In many other cases, it is preferred to carry out an oxidative cleavage reaction in step S2-3a), resulting in oxidative cleavage products.
[0830] In some cases it is preferred if a metathesis reaction and an oxidative cleavage reaction are carried out in step S2-3a), resulting in metathesis products and oxidative cleavage products.
[0831] In many cases, it is preferable to hydrolyze and / or derivatize the vegetable oil before carrying out the metathesis reaction. A person skilled in the art can identify these cases based on their general technical knowledge, the teachings of the present invention, and simple experiments that they can easily perform without undue effort.
[0832] In this way, the inventive process advantageously and simply produces a detergent according to the invention which contains a proportion of surfactant compounds from plant-based raw materials of the temperate zone and preferably possesses a particularly positive cleaning and / or washing performance. Such a detergent and such a process for producing a detergent are particularly preferred in the field of the present invention.
[0833] A preferred method (as described above, preferably as referred to above as preferred) is wherein, as the third, fourth, fifth, sixth or further component in step S3), two, three, four or more additives are produced or provided, preferably two, three, four or more additives which are independently selected from the group consisting of:
[0834] Abrasive materials, preferably marble flour, chalk, clay and / or pumice; adsorbents, preferably wood flour, cellulose flour and / or plastic flour;
[0835] Alkalis, preferably ammonia, sodium carbonate, sodium hydroxide and / or potassium hydroxide,
[0836] Alcohols, preferably ethanol, propanol and / or butanol,
[0837] Bitter substances,
[0838] Bleaching agents, preferably oxygen-based bleaching agents,
[0839] Bleach activators, preferably tetraacetylethylenediamine (TAED),
[0840] Complexing agents, preferably citrates, phosphates, phosphonates, carboxylates, ethylenedinitriletetraacetic acid (EDTA) and / or nitrilotriacetic acid (NTA),
[0841] Fragrances,
[0842] Enzymes, preferably amylases, cellulases, lipases and / or proteases,
[0843] Dyes,
[0844] Preservatives,
[0845] Corrosion inhibitors,
[0846] Solvents,
[0847] Oils, fats and / or waxes,
[0848] Optical brighteners,
[0849] Acids,
[0850] Polycarboxylates, polymers, preferably polystyrene, polyacrylate, polyurethane and / or polyethylene,
[0851] Discoloration inhibitors, preferably polyvinylpyrrolidone and
[0852] Water; and wherein these additives are present during the contact mixing in step S4) and are part of the detergent resulting in step S4).
[0853] The fact that the selection of the substances is independent of each other means that the selection of a first substance has no effect on the selection of the second substance and / or further substances.
[0854] In many cases, a process (as described above, preferably as referred to above as preferred) is also preferred, wherein, as the third, fourth, fifth, sixth or further component in step S3), two, three, four or more additives are produced or provided, preferably two, three, four or more additives which are independently selected from the group consisting of:
[0855] Abrasive materials, preferably marble dust, chalk, clay and / or pumice,
[0856] Alkalis, preferably ammonia, sodium carbonate, sodium hydroxide and / or potassium hydroxide,
[0857] Alcohols, preferably ethanol, propanol and / or butanol,
[0858] Complexing agents, preferably citrates, phosphates, phosphonates, carboxylates, ethylenedinitriletetraacetic acid (EDTA) and / or nitrilotriacetic acid (NTA),
[0859] Fragrances, enzymes, preferably amylases, cellulases, lipases and / or proteases,
[0860] Dyes,
[0861] Preservatives,
[0862] Solvents,
[0863] Oils, fats and / or waxes,
[0864] Acids,
[0865] Polycarboxylates,
[0866] Polymers, preferably polystyrene, polyacrylate, polyurethane and / or polyethylene, and
[0867] Water; and wherein these additives are present during the contact mixing in step S4) and are part of the detergent resulting in step S4).
[0868] The foregoing statements regarding the additives defined above in connection with the detergent according to the invention also apply here.
[0869] The invention further relates to a detergent (as described above, preferably as referred to above as preferred), producible, preferably produced, in a process as described above, preferably in a process as referred to above as preferred.
[0870] The invention further relates to a method for treating, preferably cleaning, with a detergent (as described above, preferably as referred to above as preferred), comprising the following steps: V1) Producing or providing, preferably by a method (as described above, preferably as referred to above as preferred), a detergent (as described above, preferably as referred to above as preferred);
[0871] V2) Providing a surface to be treated, preferably a surface to be cleaned; preferably selected from: glass, ceramic, plastic, metal, wood, stone and paint;
[0872] V3) Contact the surface to be cleaned, provided in step V2), with the detergent produced or provided in step V1);
[0873] V4) Treating, preferably cleaning, the surface using the detergent, so that a treated surface results, preferably so that a cleaned surface results.
[0874] A preferred method for cleaning with a detergent (as described above, preferably referred to as preferred above) comprising the following steps:
[0875] V1 a) Manufacturing or providing, preferably manufacturing or providing by a process (as described above, preferably as referred to above as preferred), a detergent (as described above, preferably as referred to above as preferred);
[0876] V2a) Providing a surface to be cleaned, preferably selected from: glass, ceramic, plastic, metal, wood, stone and paint;
[0877] V3a) Contact the surface to be cleaned, provided in step V2), with the detergent produced or provided in step V1);
[0878] V4a) Clean the surface using the detergent so that a clean surface results.
[0879] The treatment, preferably cleaning, is carried out in step V4) or step V4a) in many cases preferably by (simply) contact and / or with mechanical assistance (e.g., with a cloth, a brush, a nozzle, etc.). The use of the detergent according to the invention in the inventive method for treatment, preferably cleaning, yields particularly positive results. In the preferred cases where the treatment is cleaning, particularly advantageous cleaning results are achieved with the inventive method.
[0880] A preferred method is one for treating, preferably cleaning, with a detergent (as described above, preferably referred to as preferred above), further comprising one, two or all of the following steps:
[0881] V1-1) Before contacting the surface to be treated provided in step V2) with the detergent prepared or provided in step V1): contact mixing of the detergent prepared or provided in step V1) with water, resulting in an aqueous detergent solution; wherein, upon contact of the surface to be treated provided in step V2) with the detergent prepared or provided in step V1), the detergent prepared or provided in step V1) is present as part of the aqueous detergent solution resulting in step V1-1; and / or
[0882] V4-1) wherein the treatment, preferably the cleaning, of the surface using the detergent in step V4) is carried out with mechanical assistance, preferably with mechanical assistance by a washing machine, a hand, a cloth, a brush, a water jet and / or a jet of an aqueous detergent solution; and / or
[0883] V5) wherein the treated surface resulting from step V4), preferably a cleaned surface, is rinsed with water, resulting in a rinsed treated surface, preferably a rinsed cleaned surface; and / or
[0884] V6) wherein the treated surface resulting from step V4), preferably a cleaned surface, and / or the rinsed treated surface resulting from step V5), preferably a rinsed cleaned surface, is dried, so that a dried treated surface, preferably a dried cleaned surface, results.
[0885] A preferred method for cleaning with a detergent (as described above, preferably referred to as preferred above) further comprises one, two or all of the following steps:
[0886] V1-1 a) Before contacting the surface to be cleaned provided in step V2a) with the detergent resulting in step V1 a): contact mixing of the detergent produced or provided in step V1 a) with water, resulting in an aqueous detergent solution; wherein, upon contact of the surface to be cleaned provided in step V2a) with the detergent resulting in step V1 a), the detergent resulting in step V1 a) is present as part of the aqueous detergent solution resulting in step V1-1 a); and / or
[0887] V4-1 a) wherein the cleaning of the surface using the detergent in step V4a) is carried out with mechanical assistance, preferably with mechanical assistance by a washing machine, a hand, a cloth, a brush, a water jet and / or a jet of an aqueous detergent solution; and / or
[0888] V5-1 a) wherein the cleaned surface resulting from step V4a) is rinsed with water, resulting in a rinsed cleaned surface; and / or
[0889] V6) wherein the cleaned surface resulting from step V4a), and / or the rinsed cleaned surface resulting from step V5a), is dried, so that a dried cleaned surface results.
[0890] The advantages and effects described above in connection with other aspects of the present invention are realized to a particularly advantageous and efficient extent when carrying out the cleaning method according to the invention.
[0891] The invention also relates to the use of a method (as described above, preferably as referred to above as preferred) for the production of a detergent (as described above, preferably as referred to above as preferred).
[0892] The advantages and effects described above in connection with other aspects of the present invention are also preferably realized here.
[0893] The invention also relates to the use of a method (as described above, preferably as referred to above as preferred) for the treatment, preferably cleaning, of a surface, preferably a surface selected from: glass, ceramic, plastic, metal, wood, stone and lacquer.
[0894] The surfaces defined above yield particularly advantageous results in many cases. The advantages and effects described above in connection with other aspects of the present invention are also preferably realized here.
[0895] The invention further relates to the use of a detergent (as described above, preferably as referred to above as preferred) for the treatment, preferably cleaning, of a surface, preferably a surface selected from: glass, ceramic, plastic, metal, wood, stone and lacquer.
[0896] The advantages and effects described above in connection with other aspects of the present invention are also preferably realized here.
[0897] The invention further relates to a kit comprising: K1) in a first container: surfactant compound selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other
[0898] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 17 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound and
[0899] R 1 and / or R 2 residues are those that form or comprise a hydrophilic molecular fraction of the respective surfactant; and wherein the surfactant compounds present in the first container have a proportion of hydrocarbon residues R with a total number of 17 to 23 C atoms in the range of over 50 wt.%, based on the total mass of the hydrocarbon residues R present in the first container; and wherein preferably the surfactant compounds present in the first container have a ratio of in the total mass of their hydrocarbon residues R 14 carbon atoms 12exhibit C atoms corresponding to an age of the total mass of the hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and / or a ratio of 1 in the total mass of their hydrophilic residues 4 carbon atoms 12 exhibit C atoms corresponding to an age of the total mass of the hydrophilic residues of less than 300 years since carbon dioxide fixation; and / or exhibit a ratio of in the total mass of the surfactant compound of 14 carbon atoms 12 exhibiting C atoms, which corresponds to an age of less than 300 years for the total mass of the surfactant compounds present in the first container since carbon dioxide fixation; and
[0900] K2) in a second container: surfactant compound selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM where M is an alkali metal cation, an ammonium ion or a profaned primary, secondary or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other
[0901] R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound and
[0902] R 1 and / or R 2residues are those that form or comprise a hydrophilic molecular fraction of the respective surfactant; and wherein the surfactant compounds present in the second container have a proportion of hydrocarbon residues R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, of over 30 wt.%, preferably over 50 wt.%, particularly preferably over 60 wt.%, based on the total mass of the hydrocarbon residues R present in the second container, and wherein preferably the surfactant compounds present in the second container have a ratio of in the total mass of their hydrocarbon residues R 14 carbon atoms 12 exhibit C atoms corresponding to an age of the total mass of the hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and / or a ratio of 1 in the total mass of their hydrophilic residues 4 carbon atoms 12exhibit C atoms corresponding to an age of the total mass of the hydrophilic residues of less than 300 years since carbon dioxide fixation; and / or exhibit a ratio of in the total mass of the surfactant compound of 14 carbon atoms 12 exhibiting C atoms, which corresponds to an age of less than 300 years for the total mass of the surfactant compounds present in the second container since carbon dioxide fixation. The detergent according to the invention is produced particularly advantageously and efficiently with particularly advantageous results using the kit according to the invention. The process according to the invention is carried out particularly advantageously and efficiently with particularly advantageous results using the kit according to the invention.
[0903] The invention further relates to the use of a kit (as described above, preferably as referred to above as preferred) for the production of a detergent, preferably for the production of a detergent as described above, and particularly preferably for the production of a detergent as referred to above as preferred.
[0904] The effects and advantages described above in connection with other aspects of the present invention are also preferably realized here.
[0905] The invention further relates to the use of a kit (as described above, preferably as referred to above as preferred) for cleaning a surface, preferably in a method as described above, preferably as referred to above as preferred, preferably a surface selected from: glass, ceramic, plastic, metal, wood, stone and paint.
[0906] The effects and advantages described above in connection with other aspects of the present invention are also preferably realized here.
[0907] The invention further relates to the use of a kit (as described above, preferably as referred to above as preferred) in a process for producing a detergent, preferably in a process for producing a detergent as described above, preferably as referred to above as preferred.
[0908] Using the kit according to the invention, the method according to the invention is carried out with particularly advantageously good results.
[0909] The effects and advantages described above in connection with other aspects of the present invention are also preferably realized here.
[0910] The invention is described in more detail below with reference to illustrations.
[0911] Fig. 1 shows an experimental setup for a wiping test; Fig. 1 shows a tile (101) with a test soiling (102) and a single-track hand wiper (103) with a clamped cleaning textile (104) together with a rail (105) along which the single-track hand wiper can be pushed back and forth over the test soiling during wiping tests.
[0912] Fig. 2 shows an experimental setup for a wiping test from a different perspective compared to the perspective shown in Fig. 1; Fig. 2 shows a tile (201) with a test soiling (202) and a single-track hand wiper (2023) with a clamped cleaning textile (204) together with a rail (205) along which the single-track hand wiper can be moved back and forth over the test soiling during wiping tests.
[0913] The invention is described in more detail below using examples.
[0914] Example 1 (glass cleaner)
[0915] Example 1.1 Production of detergents and comparison detergents
[0916] The following were produced: a non-inventive comparative detergent 1-1 (VD1-1), a non-inventive comparative detergent 1-2 (VD1-2), a non-inventive comparative detergent 1-3 (VD1-3), a detergent 1-4 (D1-4) according to the invention, and a detergent 1-5 (D1-5) according to the invention; the compositions of each are shown in Table 1a. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are shown in Table 1b. Table 1a: Recipes in Example 1.1
[0917] VD1-1 VD1-2 VD1-3 D1-4 D1-5
[0918] Active ingredient content
[0919] Mass fraction (%) raw material
[0920] (%)
[0921] C16 / 18-glucamide (sunflower) a
[0922] C8 / 10-Glucamide b50 0.00 0.53 0.80 1.00 1.36
[0923] Isopropanol 99.5 12.0 12.0 12.0 12.0 12.0
[0924] dye
[0925] Water 0 ad 100 ad 100 ad 100 ad 100 ad 100 a C16 / 18 ratio 5 / 95 b C8 / C10 ratio 50 / 50 c demineralized.
[0926] Table 1b: Proportions of different hydrocarbon residues in Example 1.1
[0927] VD1-1 VD1-2 VD1-3 D1-4 D1-5
[0928] Proportion of hydrocarbon residues R with 17 and more C-
[0929] 95 76 65 56 38
[0930] atoms (wt%) d
[0931] Proportion of hydrocarbon residues R with 15 C atoms 5 4 3 3 2
[0932] (wt.%) d
[0933] Proportion of hydrocarbon residues R, with a number of 0 20 32 41 60
[0934] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) dd in each case based on the total mass of hydrocarbon residues present in the detergent R.
[0935] Example 1.2: Test method “wiping glass interior dirt”
[0936] The rapid mechanical cleaning performance (wiping method) against dirt type B ("interior dirt") from the IKW's "Recommendations for the Quality Assessment of Glass Cleaning Agents / Glass Cleaners" (dated January 31, 2022) was tested. The test procedure followed the IKW's "Recommendations for the Quality Assessment of Glass Cleaning Agents / Glass Cleaners" (dated January 31, 2022), with the following modifications being the only deviations from the procedure described therein:
[0937] - Instead of mirror tiles, ceramic tiles (101, 201) were used as the substrate for the test soiling; Villeroy & Boch 3135 floor tile, 30 cm x 30 cm: Villeroy & Boch AG, Head Office, P.O. Box 1 120, 66688 Mettlach, Tel: +49
[0938] 6864 81 -0;
[0939] - Instead of the described Sheen device, a single-track hand wiper made of stainless steel (dimensions: 2.7 x 8.0 cm, weight: 240 g) (103, 203) was used, which is designed for individually wiping single strips on the soiling. A precisely cut cleaning textile was used (as a covering (104, 204) of the single-track hand wiper (103, 203);
[0940] - Instead of visual inspection, the cleaned dirt monitors were photographed in a photo booth and evaluated using a PC, as described below in the present example.
[0941] For each experiment, the hand-held wiping device was fitted with a precisely cut cleaning textile (104, 204), and the cleaning textile (fitting) (104, 204) was soaked with 2.8 ml of the detergent under investigation or the reference detergent under investigation. The single-track hand-held wiping device was then moved back and forth along a rail (105, 205) over the soiling three times without additional pressure (corresponding to three "strokes").
[0942] For evaluation purposes, the cleaned tiles were photographed in a photo booth after drying. Using a suitable computer program, a percentage brightness value was calculated for each cleaned area from the photograph, compared to the brightness of a 100% clean surface (white; value corresponds to 100% cleaning performance) and a completely soiled surface (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[0943] Example 1.3: Performing tests according to the test method “wiping glass interior dirt”
[0944] Following the method from Example 1.2 above, the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D1-4 and D1-5) and reference detergents (VD1-1, VD1-2, and VD1-3) defined in Example 1.1 above. The results of these tests are given in Table 1c. Table 1c: Results of the cleaning tests in Example 1.3
[0945] VD1-1 VD1 -2 VD1 -3 D1 -4 D1 -5
[0946] Cleaning performance in % 40 49 63 70 90
[0947] The results from Table 1c show a significantly better cleaning performance of each of the detergents D1-4 and D1-5 according to the invention compared to each of the reference detergents VD1-1, VD1-2 and VD1-3. Example 2 (Degreaser r)
[0948] Example 2.1 Production of detergents and comparison detergents
[0949] The following were produced: a non-inventive comparative detergent 2-1 (VD2-1), a non-inventive comparative detergent 2-2 (VD2-2), a non-inventive comparative detergent 2-3 (VD2-3), a detergent 2-4 (D2-4) according to the invention, and a detergent 2-5 (D2-5) according to the invention. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 2b.
[0950] Table 2b: Proportions of different hydrocarbon residues in Example 2.1
[0951] VD2-1 VD2-2 VD2-3 D2-4 D2-5
[0952] Proportion of hydrocarbon residues R with 17 and more C-
[0953] 95 81 64 55 47
[0954] atoms (wt%) d
[0955] Proportion of hydrocarbon residues R with 15 C atoms 5 4 3 3 2
[0956] (wt.%) d
[0957] Proportion of hydrocarbon residues R with a number of 0 15 33 42 51
[0958] C atoms in the range of 7 to
[0959] 10 carbon atoms (wt%) d d in each case based on the total mass of the hydrocarbon residues R present in the detergent. C16 / 18-glucamide (with a C16 / 18 ratio of 5 / 95) and C8 / 10-glucamide (with a C8 / C10 ratio of 50 / 50) were used as required in each case. The finished detergents or reference detergents contained 1 wt% surfactant (total), 7.5 wt% 1,2-pentanediol, and 0.09 wt% tetrasodium N,N-bis(carboxylmethyl)-L-glutamate (GLDA), each based on the total mass of the respective detergent or reference detergent; the missing values to reach 100 wt% represent demineralized water. The finished detergents and the finished reference detergents were each adjusted to a pH of 9 using methanesulfonic acid.
[0960] Example 2.2: Test method “Wipe DT40.8”
[0961] The rapid mechanical cleaning performance (wiping method) against crosslinked dried grease and dust (III) from the "IKW Recommendation for Quality Assessment of Product Performance of All-Purpose Cleaners 2014" was tested. The procedure followed the "IKW Recommendation for Quality Assessment of Product Performance of All-Purpose Cleaners 2014", with the following modifications being the only deviations from the procedure described therein:
[0962] - Instead of the described Sheen device, a single-track hand wiper (103,
[0963] 203) made of stainless steel (dimensions 2.7 x 8.0 cm, weight: 240 g) is used, which is intended for individually wiping individual strips on the soiling.
[0964] - A precisely tailored cleaning textile was used (as a covering (104,
[0965] 204) of a single-track hand-held wiper (103, 203).
[0966] - Instead of visual inspection, the cleaned dirt monitors were photographed in a photo booth and evaluated using a PC, as described below in the present example.
[0967] For each experiment, the hand-held wiping device was fitted with a precisely cut cleaning textile (104, 204), and the cleaning textile (fitting) (104, 204) was soaked with 2.8 ml of the detergent under investigation or the reference detergent under investigation. The single-track hand-held wiping device was then moved back and forth along a rail (105, 205) over the soiling eight times without additional pressure (corresponding to eight "strokes").
[0968] For evaluation, the cleaned dirt monitors were photographed in a photo booth after drying. Using suitable PC software, a percentage brightness value was calculated for each wiped area from the photograph, compared to the brightness of a 100% cleaned area (white; value corresponds to 100% cleaning performance) and a completely soiled area (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[0969] Example 2.3: Test method “Exposure to DT40.60”
[0970] The self-acting cleaning performance (contact method) against crosslinking dried grease-dust dirt (III) from the KW recommendation for the quality assessment of the product performance of all-purpose cleaners 2014” is tested according to the test method “contact DT40.60” described here.
[0971] To determine the self-cleaning effect (contact method) against crosslinking dried grease-dust dirt (III) from the "IKW Recommendation for the Quality Assessment of Product Performance of All-Purpose Cleaners 2014", a glass fiber filter plate (VWR 691, diameter 21 mm) was soaked with 0.5 mL of the detergent under test or the reference detergent under test. The soaked glass fiber filter plates were then placed on the horizontally arranged, soiled surface and removed after 60 minutes (contact time).
[0972] During the contact time, the glass filter pads were covered with a watch glass to minimize evaporation of individual components. After the contact time (60 minutes), each filter pad was rinsed under running cold water (approx. 15 °C) using a soft, medium-pored foam sponge and applying only the minimum necessary pressure. The area of grease-dust contamination (III) where the filter pad had been placed during the contact time was evaluated. For this evaluation, the cleaned monitors were photographed in a photo booth after drying. Using suitable computer software, a percentage brightness value was calculated for each cleaned area from the photograph, compared to the brightness of a 100% cleaned area (white; value corresponds to 100% cleaning performance) and a completely soiled area (black; value corresponds to 0% cleaning performance).A higher percentage value therefore correlates with better cleaning performance and vice versa.
[0973] Example 2.4: Conducting tests according to the "Wipe DT40" test method
[0974] According to the method from the example 2.2 above (test method “wiping DT40”), the cleaning performance (wiping method) against crosslinking dried grease and dust dirt (III) from the “IKW recommendation for the quality assessment of the product performance of all-purpose cleaners 2014” was determined for the detergents (D2-4 and D2-5) and comparison detergents (VD2-1, VD2-2 and VD2-3) defined in the example 2.1 above.
[0975] The results of these tests are given in Table 2c.
[0976] Table 2c: Results of the cleaning tests according to the test method “Wipe DT40”
[0977] VD2-1 VD2-2 VD2-3 D2-4 D2-5 o R / unification as power a in 9 20 29 38 46
[0978] %
[0979] The results from Table 2c show a significantly better cleaning performance of each of the detergents D2-4 and D2-5 according to the invention compared to each of the comparison detergents VD2-1, VD2-2 and VD2-3.
[0980] Example 2.5: Conducting tests according to the test method “Exposure DT40.60”
[0981] According to the method from Example 2.3 above (test method “Contact DT40.60”), the cleaning performance (contact method) against crosslinked dried grease-dust soil (III) from the “IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014” was determined for the detergents (D2-4 and D2-5) and reference detergents (VD2-1, VD2-2 and VD2-3) defined in Example 2.1 above. The results of these tests are given in Table 2d. Table 2d: Results of the cleaning tests according to test method “Contact DT40.60”
[0982] VD2-1 VD2-2 VD2-3 D2-4 D2-5
[0983] Cleaning performance in12 26 3g 50
[0984] %
[0985] The results from Table 2d show an advantageously better cleaning performance of each of the detergents D2-4 and D2-5 according to the invention compared to each of the comparison detergents VD2-1, VD2-2 and VD2-3.
[0986] Example 3 (Alkaline all-purpose cleaner)
[0987] Example 3.1 Production of detergents and comparison detergents
[0988] The following were produced: a non-inventive comparative detergent 3-1 (VD3-1), a non-inventive comparative detergent 3-2 (VD3-2), a non-inventive comparative detergent 3-3 (VD3-3), a detergent 3-4 (D3-4) according to the invention, and a detergent 3-5 (D3-5) according to the invention. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 3b.
[0989] Table 3b: Proportions of different hydrocarbon residues in Example 3.1
[0990] VD3-1 VD3-2 VD3-3 D3-4 D3-5
[0991] Proportion of hydrocarbon residues R with 17 and more C atoms 85 73 65 58 43
[0992] (wt.%) d
[0993] Proportion of hydrocarbon residues R with 15 C atoms (wt. -%) d 15 13 11 10 7
[0994] Proportion of hydrocarbon residues
[0995] R with a number of C atoms 0 14 24 32 50 in the range of 7 to 10 C atoms
[0996] (wt.%) dd in each case based on the total mass of the hydrocarbon residues R present in the detergent. C16 / 18 sodium glutamate (olive) (with a C16 / 18 ratio of 15 / 85) and C8 / 10 sodium glutamate (with a C8 / 10 ratio of 50 / 50) were used in each case. The finished detergents and reference detergents contained 2 wt% surfactant (total) and 0.47 wt% tetrasodium N,N-bis(carboxylmethyl)-L-glutamate (GLDA), each based on the total mass of the respective detergent or reference detergent; the missing values to reach 100 wt% represent demineralized water. The finished detergents and the finished comparison detergents each had a pH value (adjusted with sodium hydroxide) of pH 11.
[0997] Example 3.2: Test method “Impact DT40.10”
[0998] The self-acting cleaning performance (contact method) against crosslinked dried grease-dust dirt (III) from the KW recommendation for the quality assessment of the product performance of all-purpose cleaners 2014 was tested. The test method "Contact DT40.10" corresponds to the test method "Contact DT40.60" (see example 2.3 above) except for one single difference; this single difference is that the contact time in the test method "Contact DT40.10" is 10 minutes and not 60 minutes as in the test method "Contact DT40.60" (see example 2.3 above).
[0999] Example 3.3: Conducting tests according to the test method “Exposure DT40.10”
[1000] According to the method from Example 3.2 above (test method “Contact DT40.10”), the cleaning performance (contact method) against crosslinked dried grease-dust dirt (III) from the “IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014” was determined for the detergents (D3-4 and D3-5) and reference detergents (VD3-1, VD3-2 and VD3-3) defined in Example 3.1 above. The results of these tests are given in Table 3d.
[1001] Table 3d: Results of the cleaning tests according to the test method “Exposure DT40.10”
[1002] VD3-1 VD3-2 VD3-3 D3-4 D3-5
[1003] Cleaning performance in 39 48 52 M 65
[1004] %
[1005] The results from Table 3d show an advantageously better cleaning performance of each of the detergents D3-4 and D3-5 according to the invention compared to each of the comparison detergents VD3-1, VD3-2 and VD3-3.
[1006] Example 3.4: Performing tests according to the test method “wiping glass interior dirt”
[1007] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D3-4 and D3-5) and comparison detergents (VD3-1, VD3-2 and VD3-3) defined in Example 3.1 above. The results of these tests are given in Table 3c.
[1008] Table 3c: Results of the cleaning tests according to the test method “wiping glass interior dirt”
[1009] VD3-1 VD3-2 VD3-3 D3-4 D3-5
[1010] Cleaning performance in 74 g: 81 83 87
[1011] %
[1012] The results from Table 3c show a significantly better cleaning performance of each of the detergents D3-4 and D3-5 according to the invention compared to each of the comparison detergents VD3-1, VD3-2 and VD3-3.
[1013] Example 4 (Cosmetic Cleaner)
[1014] Example 4.1 Production of detergents and comparison detergents
[1015] The following were produced: a non-inventive comparative detergent 4-1 (VD4-1), a non-inventive comparative detergent 4-2 (VD4-2), a non-inventive comparative detergent 4-3 (VD4-3), a detergent 4-4 (D4-4) according to the invention, and a detergent 4-5 (D4-5) according to the invention; the compositions of each are given in Table 4a. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 4b. Table 4a: Formulations in Example 4.1
[1016] VD4-1 VD4-2 VD4-3 D4-4 D4-5
[1017] Ingredient Active content Crude mass fraction (%)
[1018] Material (%)
[1019] Glycerin Oleate 100 2.00 1 .60 1 .17 0.98 0.79
[1020] (C16 / 18) * 7EO (SB) e
[1021] Glycerin 100 0.00 0.40 0.83 1.02 1.21
[1022] Ethanol 99 10 10 10 10 10
[1023] dye
[1024] perfume
[1025] preservatives
[1026] Water 9 ad 100 ad 100 ad 100 ad 100 ad 100 e C16 / 18 ratio 5 / 95. f C8 / C10 ratio 50 / 50. g demineralized.
[1027] Table 4b: Proportions of different hydrocarbon residues in Example 4.1
[1028] VD4-1 VD4-2 VD4-3 D4-4 D4-5
[1029] Proportion of hydrocarbon residues R with 17 and more C-
[1030] 95 83 67 59 50
[1031] atoms (wt%) d
[1032] Proportion of hydrocarbon residues R with 15 C atoms 5 4 4 3 3
[1033] (wt.%) d
[1034] Proportion of hydrocarbon residues R with a number of 0 13 29 38 47
[1035] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R.
[1036] Example 4.2: Conducting tests according to the "Wipe DT40" test method. According to the method from Example 2.2 above (test method "Wipe DT40"), the cleaning performance (wiping method) against crosslinked dried grease and dust (III) from the "IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014" was determined for the detergents (D4-4 and D4-5) and reference detergents (VD4-1, VD4-2 and VD4-3) defined in Example 4.1 above. The results of these tests are given in Table 4c.
[1037] Table 4c: Results of the cleaning tests in Example 4.2
[1038] VD4-1 VD4-2 VD4-3 D4-4 D4-5
[1039] Cleaning performance in % 49 58 72 82 93
[1040] The results from Table 4c show a significantly better cleaning performance of each of the detergents D4-4 and D4-5 according to the invention compared to each of the reference detergents VD4-1, VD4-2 and VD4-3. Example 5 (Soap Cleaner)
[1041] Example 5.1 Production of detergents and comparison detergents
[1042] The following were produced: a non-inventive comparative detergent 5-1 (VD4-1), a non-inventive comparative detergent 5-2 (VD4-2), a non-inventive comparative detergent 5-3 (VD5-3), an inventive detergent 5-4 (D5-4) and an inventive detergent 5-5 (D5-5); the proportions of hydrocarbon residues R with 17 and more C atoms, with 15 C atoms and with 7-10 C atoms are given in Table 5b.
[1043] Table 5b: Proportions of different hydrocarbon residues in Example 5.1
[1044] VD5-1 VD5-2 VD5-3 D5-4 D5-5
[1045] Proportion of hydrocarbon residues R with 17 and more C-
[1046] 85 71 65 55 30
[1047] atoms (wt%) d
[1048] Proportion of hydrocarbon residues R with 15 C atoms
[1049] 15 12 1 1 9 5
[1050] (wt.%) d
[1051] Proportion of hydrocarbon residues R with a number of
[1052] 0 17 24 36 65
[1053] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R.
[1054] In each case, C16 / 18 fatty acid sodium salt (olive) (with a C16 / 18 ratio of 15 / 85) and C9 fatty acid sodium salt were used. The finished detergents and reference detergents contained 2 wt% surfactant (total), based on the total mass of the respective detergent or reference detergent; the missing value to reach 100 wt% represents demineralized water. The finished detergents and reference detergents each had a pH value (adjusted with sodium hydroxide) of pH 9.8. Example 5.2: Conducting tests according to the test method "Wiping glass interior dirt"
[1055] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D5-4 and D5-5) and comparison detergents (VD5-1, VD5-2 and VD5-3) defined in Example 5.1 above. The results of these tests are given in Table 5c.
[1056] Table 5c: Results of the cleaning tests according to the test method “wiping glass interior dirt”
[1057] VD5-1 VD5-2 VD5-3 D5-4 D5-5
[1058] Cleaning and cleaning performance in 34 45 48 52 63
[1059] The results from Table 5c show a significantly better cleaning performance of each of the detergents D5-4 and D5-5 according to the invention compared to each of the comparison detergents VD5-1, VD5-2 and VD5-3.
[1060] Example 5.3: Test method “Wipe DT40.12”
[1061] The rapid mechanical cleaning performance (wiping method) against crosslinked dried grease and dust (III) from the "IKW Recommendation for Quality Assessment of Product Performance of All-Purpose Cleaners 2014" was tested. The procedure followed the "IKW Recommendation for Quality Assessment of Product Performance of All-Purpose Cleaners 2014", with the following modifications being the only deviations from the procedure described therein:
[1062] - Instead of the described Sheen device, a single-track hand wiper (103,
[1063] 203) made of stainless steel (dimensions 2.7 x 8.0 cm, weight: 240 g) is used, which is intended for individually wiping individual strips on the soiling.
[1064] - A precisely tailored cleaning textile was used (as a covering (104,
[1065] 204) of a single-track hand-held wiper (103, 203). - Instead of visual inspection, the cleaned dirt monitors were photographed in a photo booth and evaluated using a PC, as described below in the present example.
[1066] For each experiment, the hand-held wiping device was fitted with a precisely cut cleaning textile (104, 204), and the cleaning textile (fitting) (104, 204) was soaked with 2.8 ml of the detergent under investigation or the reference detergent under investigation. The single-track hand-held wiping device was then moved back and forth along a rail (105, 205) over the soiling 12 times without additional pressure (corresponding to 12 "strokes").
[1067] For evaluation purposes, the cleaned dirt monitors were photographed in a photo booth immediately after the cleaning attempt. Using suitable PC software, a percentage brightness value was calculated for each wiped area from the photograph, compared to the brightness of a 100% cleaned area (white; value corresponds to 100% cleaning performance) and a completely soiled area (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[1068] Example 5.4: Performing tests according to the test method “Wipe DT40.12”
[1069] According to the method from Example 5.3 above (test method “wiping DT40.12”), the cleaning performance (wiping method) against crosslinked dried grease and dust (III) from the “IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014” was determined for the detergents (D5-4 and D5-5) and reference detergents (VD5-1, VD5-2 and VD5-3) defined in Example 5.1 above. The results of these tests are given in Table 5c.
[1070] Table 5c: Results of the cleaning tests in Example 5.3
[1071] VD5-1 VD5-2 VD5-3 D5-4 D5-5
[1072] Cleaning performance in % 48 58 59 61 71
[1073] The results from Table 5c show a significantly better cleaning performance of each of the detergents D5-4 and D5-5 according to the invention compared to each of the reference detergents VD5-1, VD5-2 and VD5-3. Example 6 (Degreaser)
[1074] Example 6.1 Production of detergents and comparison detergents:
[1075] The following were produced: a non-inventive comparative detergent 6-1 (VD6-1), a non-inventive comparative detergent 6-2 (VD6-2), a detergent 6-3 (D6-3), a detergent 6-4 (D6-4) according to the invention, and a detergent 6-5 (D6-5) according to the invention; the compositions of each are given in Table 6a. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 6b.
[1076] Table 6a: Recipes in Example 6.1
[1077] VD6-1 VD6-2 D6-3 D6-4 D6-5
[1078] Ingredient Active content Crude mass fraction (%)
[1079] Material (%)
[1080] Fatty alcohol 100 2.00 1.61 1.41 1.19 0.84
[1081] C16 / 18:1* 18 EO h
[1082] Fatty alcohol C10 * 6 EO 100 0.00 0.39 0.59 0.81 1 .16
[1083] 1-Methoxy-2-propanol 99.5 2.5 2.5 2.5 2.5 2.5
[1084] NaOH 45 ad ad ad ad ad pH 11 pH 11 pH 11 pH 11 pH 11
[1085] dye
[1086] perfume
[1087] preservatives
[1088] Water' ad 100 ad 100 ad 100 ad 100 ad 100 h C16 / 18 ratio 14 / 86 . i demineralized. Table 6b: Proportions of different hydrocarbon residues in Example 6.1 _
[1089] VD6-1 VD6-2 D6-3 D6-4 D6-5
[1090] Proportion of hydrocarbon residues R with 17 and more C-
[1091] 86 64 55 45 30
[1092] atoms (wt%) d
[1093] Proportion of hydrocarbon residues R with 15 C atoms
[1094] 14 10 9 7 5
[1095] (wt.%) d
[1096] Proportion of hydrocarbon residues R with a number of
[1097] 0 25 36 48 65
[1098] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case in relation to the total mass of the detergent present
[1099] Hydrocarbon residues R.
[1100] Example 6.2: Conducting tests according to the "Exposure DT40.60" test method. According to the method from Example 2.3 above (Exposure DT40.60 test method), the cleaning performance (exposure procedure) against crosslinked dried grease-dust dirt (III) from the "IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014" was determined for the detergents (D6-3, D6-4 and D6-5) and reference detergents (VD6-1 and VD6-2) defined in Example 6.1 above. The results of these tests are given in Table 6c.
[1101] Table 6c: Results of the cleaning tests according to the test method “Exposure DT40.60” VD6-1 VD6-2 D6-3 D6-4 D6-5
[1102] Cleaning and service in " 9 16 25 29 46
[1103] The results from Table 6c show a significantly better cleaning performance of each of the detergents D6-3, D6-4 and D6-5 according to the invention compared to each of the reference detergents VD6-1 and VD6-2. Example 7 (Neutral all-purpose cleaner)
[1104] Example 7.1 Production of detergents and comparison detergents:
[1105] The following were produced: a non-inventive comparative detergent 7-1 (VD7-1), a non-inventive comparative detergent 7-2 (VD7-2), an inventive detergent 7-3 (D7-3) and an inventive detergent 7-4 (D7-4); the proportions of hydrocarbon residues R with 17 and more C atoms, with 15 C atoms and with 7-10 C atoms are given in Table 7b.
[1106] Table 7b: Proportions of different hydrocarbon residues in Example 7.1
[1107] VD7-1 VD7-2 D7-3 D7-4
[1108] Proportion of hydrocarbon residues R with 17 and more C- 86 69 51 34
[1109] atoms (wt%) d
[1110] Proportion of hydrocarbon residues R with 15 C atoms 14 11 8 6
[1111] (wt.%) d
[1112] Proportion of hydrocarbon residues R with a number of 0 20 41 60
[1113] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R.
[1114] Fatty alcohol C16 / 18:1 * 18 EO (with a C16 / 18 ratio of 14 / 86) and fatty alcohol C10 * 6 EO were used in each case as required.
[1115] The finished detergents or reference detergents contained 2 wt% surfactant (total) and 5 wt% 2-propanol, each based on the total mass of the respective detergent or the total mass of the respective reference detergent; the 100 wt.
[1116] The % of missing information represents demineralized water. The finished detergents and the finished reference detergents each had a pH value (adjusted with methanesulfonic acid) of pH 7. Example 7.2: Conducting tests according to the test method "wiping glass interior soil"
[1117] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D7-3 and D7-4) and comparison detergents (VD7-1 and VD7-2) defined in Example 3.1 above. The results of these tests are given in Table 7c.
[1118] Table 7c: Results of the cleaning tests according to the test method
[1119] "Wipe away dirt inside the glass" -
[1120] VD7-1 VD7-2 D7-3 D7-4
[1121] Cleaning performance in 81 8g g6
[1122] %
[1123] The results from Table 7c show a significantly better cleaning performance of each of the detergents D7-3 and D7-4 according to the invention compared to each of the comparison detergents VD7-1 and VD7-2.
[1124] Example 8.1 Production of detergents and comparison detergents:
[1125] The following were produced: a non-inventive comparative detergent 8-1 (VD8-1), a non-inventive comparative detergent 8-2 (VD8-2), a non-inventive comparative detergent 8-3 (VD8-3), a detergent 8-4 (D8-4) according to the invention, and a detergent 5-5 (D5-5) according to the invention; the proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 8b. Table 8b: Proportions of various hydrocarbon residues in Example 8.1
[1126] VD8-1 VD8-2 VD8-3 D8-4 D8-5
[1127] Proportion of hydrocarbon residues R with 17 and more C-
[1128] 86 70 65 53 37
[1129] atoms (wt%) d
[1130] Proportion of hydrocarbon residues R with 15 C atoms
[1131] 14 12 1 1 9 6
[1132] (wt.%) d
[1133] Proportion of hydrocarbon residues R with a number of
[1134] 0 18 24 38 57
[1135] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case in relation to the total mass of the detergent present
[1136] Hydrocarbon residues R.
[1137] Fatty alcohol C16 / 18:1 * 10.5 EO-CH3COOH (with a C16 / 18 ratio of 14 / 86) and fatty alcohol C10 * 6 EO-CH3COOH were used together with 2% citric acid. The finished detergents and reference detergents contained 2 wt% surfactant (total), based on the total mass of the respective detergent or reference detergent; the missing value to reach 100 wt% represents demineralized water. The finished detergents and reference detergents each had a pH of 2.0.
[1138] Example 8.3: Test method “Cleaning limescale soap (wiping)”
[1139] The rapid mechanical cleaning performance (wiping method) against limescale soap was tested. High-gloss, white tiles were soiled with the test dirt (calcium stearate suspension) described therein, following the procedure outlined in section 3.2 of the "Recommendation for Quality Assessment of Bathroom Cleaners: Quality Recommendations of the German Cosmetic, Toiletry, Perfumery and Detergent Association (IKW), Cleaning and Care Products Department, Frankfurt am Main (2002 edition)." Instead of the contact method described in section 3.2 of the IKW method, a single-track hand wiper made of stainless steel (dimensions 2.7 x 8.0 cm, weight: 240 g) was used to clean the soiling. This wiper is designed for individual wiping of single strips across the soiled area.
[1140] The hand-held wiping device was covered with a precisely cut cleaning cloth and soaked with 2.8 ml each of the detergent under investigation and the reference detergent under investigation. The single-track hand-held wiping device was then moved vertically back and forth along its track 15 times over the soiling (corresponding to 15 "strokes").
[1141] For evaluation purposes, the cleaned tiles were photographed in a photo booth after drying. Using a suitable computer program, a percentage brightness value was calculated for each cleaned area from the photograph, compared to the brightness of a 100% clean surface (white; value corresponds to 100% cleaning performance) and a completely soiled surface (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[1142] Example 8.4 Test method “Cleaning lime soap (soaking time)”
[1143] The self-cleaning performance (contact method) against lime soap was tested according to the procedure from section 3.2 of the “Recommendation for quality assessment for bathroom cleaners Quality recommendations of the German Cosmetic, Toiletry, Perfumery and Detergent Association (IKW), Department of Cleaning and Care Products, Frankfurt aM (Version 2002)”.
[1144] The exposure time was 2.5 minutes.
[1145] For evaluation purposes, the cleaned tiles (deviating from the visual assessment specified in section 3.2 of the IKW method) were photographed in a photo booth after drying. Using suitable computer software, a percentage brightness value was calculated for each wiped area from the photograph, compared to the brightness of a 100% cleaned surface (white; value corresponds to 100% cleaning performance) and a completely soiled surface (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance and vice versa. Example 8.5: Conducting tests according to the test method "Cleaning limescale soap (wiping)"
[1146] According to the method from Example 8.3 above (test method “Lime soap cleaning (wiping)”), the cleaning performance (wiping method) compared to lime soap was determined for the detergents (D8-4 and D8-5) and comparison detergents (VD8-1, VD8-2 and VD8-3) defined in Example 8.1 above. The results of these tests are given in Table 8c.
[1147] Table 8c: Results of the cleaning tests according to the test method “Cleaning limescale soap (wiping)”
[1148] VD8-1 VD8-2 VD8-3 D8-4 D8-5
[1149] Cleaning performance in 2
[1150] %
[1151] The results from Table 8c show a significantly better cleaning performance of each of the detergents D8-4 and D8-5 according to the invention compared to each of the comparison detergents VD8-1, VD8-2 and VD8-3.
[1152] Example 8.6: Conducting tests according to the test method “Cleaning with lime soap (impact)”
[1153] According to the method from Example 8.4 above (test method “Cleaning with lime soap (impact test)”), the cleaning performance (impact test) against lime soap was determined for the detergents (D8-4 and D8-5) and reference detergents (VD8-1, VD8-2 and VD8-3) defined in Example 8.1 above. The results of these tests are given in Table 8d.
[1154] Table 8d: Results of the cleaning tests according to the test method “Cleaning lime soap (contact)”
[1155] VD8-1 VD8-2 VD8-3 D8-4 D8-5
[1156] Cleaning performance in 0 0 8 20 81
[1157] % The results from Table 8d show an advantageously better cleaning performance of each of the detergents D8-4 and D8-5 according to the invention compared to each of the comparison detergents VD8-1 , VD8-2 and VD8-3.
[1158] Example 8.7: Performing tests according to the test method “wiping glass interior dirt”
[1159] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D8-4 and D8-5) and comparison detergents (VD8-1, VD8-2 and VD8-3) defined in Example 8.1 above. The results of these tests are given in Table 8e.
[1160] Table 8e: Results of the cleaning tests according to the test method “wiping glass interior dirt”
[1161] VD8-1 VD8-2 VD8-3 D8-4 D8-5 o R / einig aung asleistung a in 34 54 65 86 92
[1162] %
[1163] The results from Table 8e show a significantly better cleaning performance of each of the detergents D8-4 and D8-5 according to the invention compared to each of the comparison detergents VD8-1, VD8-2 and VD8-3.
[1164] Example 9 (maintenance cleaner, slightly alkaline)
[1165] Example 9.1 Production of detergents and comparison detergents:
[1166] The following were produced: a non-inventive comparative detergent 9-1 (VD9-1), a non-inventive comparative detergent 9-2 (VD9-2), a detergent 9-3 (D9-3) according to the invention, and a detergent 9-4 (D9-4) according to the invention; the compositions of each are given in Table 9b. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 9bb. Table 9b: Formulations in Example 9.1
[1167] VD9-1 VD9-2 D9-3 D9-4
[1168] Ingredient Active content Crude mass fraction (%)
[1169] Material (%)
[1170] Fatty alcohol 52 1 .00 0.65 0.42 0.00
[1171] C16 / 18-Glucamide
[1172] (sunflower) j
[1173] C16 / 18 glutamate 23 1 .30 1 .30 1 .30 1 .30
[1174] Sodium salt (olive) k
[1175] C8 / 10-glucamide' 50 0.36 0.72 0.96 0.40
[1176] NaOH(aq) 45 ad pH 9 ad pH 9 ad pH 9 ad pH 9
[1177] dye
[1178] perfume
[1179] preservatives
[1180] Water m ad 100 ad 100 ad 100 ad 100 j C16 / 18 ratio 5 / 95. k C16 / 18 ratio 15 / 85. I C8 / 10 ratio 50 / 50. m demineralized.
[1181] Table 9bb: Proportions of different hydrocarbon residues in Example 9.1
[1182] VD9-1 VD9-2 D9-3 D9-4
[1183] Proportion of hydrocarbon residues R with 17 and more C- 80 66 55 34
[1184] atoms (wt%) d
[1185] Proportion of hydrocarbon residues R with 15 C atoms 7 7 7 6
[1186] (wt.%) d
[1187] Proportion of hydrocarbon residues R with a number of 13 27 38 60
[1188] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R. Example 9.2: Performing tests according to the test method “wiping glass interior dirt”
[1189] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D9-3 and D9-4) and comparison detergents (VD9-1 and VD9-2) defined in Example 9.1 above. The results of these tests are given in Table 9c.
[1190] Table 9c: Results of the cleaning tests according to the test method
[1191] "Wipe away dirt inside the glass" -
[1192] VD9-1 VD9-2 D9-3 D9-4
[1193] Cleaning performance in O o OO OJ
[1194] % The results from Table 9c show a significantly better cleaning performance of each of the detergents D9-3 and D9-4 according to the invention compared to each of the comparison detergents VD9-1 and VD9-2.
[1195] Example 10 (All-purpose cleaner, alkaline) Example 10.1 Production of detergents and comparative detergents:
[1196] The following were produced: a non-inventive comparative detergent 10-1 (VD10-1), a non-inventive comparative detergent 10-2 (VD10-2), a detergent 10-3 (D10-3) according to the invention, and a detergent 10-4 (D10-4) according to the invention; the compositions of each are given in Table 10b. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 10bb.
[1197] Table 10b: Recipes in Example 10.1
[1198] VD10-1 VD10-2 D10-3 D10-4
[1199] Ingredient Active content Mass fraction (%)
[1200] Raw material (%)
[1201] C16 / 18-Glucamide (SB) 0 52 1 ,00 0,65 0.42 0,00
[1202] C16 / 18 glutamate sodium 23 1.30 1.30 1.30 1.30 um salt (olive) p
[1203] C8 / 10-Glucamide q 50 0.36 0.72 0.96 1.40
[1204] Tetrasodium N,N-bis(carboxylmethyl)-L-glutamate (GLDA) sodium hydroxide solution 45 ad ad ad ad pH 10.6 pH 10.6 pH 10.6 pH 10.6
[1205] dye
[1206] perfume
[1207] preservatives
[1208] Water (demineralized) ad 100 ad 100 ad 100 ad 100 o C16 / 18 ratio = 5 / 95. p C16 / 18 ratio = 15 / 85. q C8 / 10 ratio = 50 / 50. Table 10bb: Proportions of different hydrocarbon residues in Example 10.1
[1209] VD10-1 VD10-2 D10-3 D10-4
[1210] Proportion of hydrocarbon residues R with 17 and more C- 80 66 55 34
[1211] atoms (wt%) d
[1212] Proportion of hydrocarbon residues R with 15 C atoms 7 7 7 6
[1213] (wt.%) d
[1214] Proportion of hydrocarbon residues R with a number of 13 27 38 60
[1215] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R. Example 10.2: Test method “Exposure DT40.30”
[1216] The self-acting cleaning performance (contact method) against crosslinked dried grease and dust (III) from the KW recommendation for the quality assessment of the product performance of all-purpose cleaners 2014 was tested. The test method "Contact DT40.30" corresponds to the test method "Contact DT40.60" (see example 2.3 above) except for one single difference; this single difference is that the contact time for the test method "Contact DT40.30" is 30 minutes and not 60 minutes as in the test method "Contact DT40.60" (see example 2.3 above).
[1217] Example 10.3: Conducting tests according to the test method “Exposure DT40.30”
[1218] According to the method from Example 10.2 above (test method “Contact DT40.30”), the cleaning performance (contact method) against crosslinked dried grease-dust dirt (III) from the “IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014” was determined for the detergents (D10-3 and D10-4) and reference detergents (VD10-1 and VD10-2) defined in Example 10.1 above. The results of these tests are given in Table 10c.
[1219] Table 10c: Results of the cleaning tests according to the test method “Exposure DT40.30”
[1220] VD10-1 VD10-2 D10-3 D10-4
[1221] Cleaning performance in58 ß4 7Q Q2
[1222] %
[1223] The results from Table 10c show a significantly better cleaning performance of each of the detergents D10-3 and D10-4 according to the invention compared to each of the comparison detergents VD10-1 and VD10-2.
[1224] Example 11 (All-purpose cleaner, alkaline)
[1225] Example 11.1 Production of detergents and comparison detergents:
[1226] The following were produced: a non-inventive comparative detergent 11-1 (VD11-1), a non-inventive comparative detergent 11-2 (VD11-2), a detergent 11-3 (D11-3) according to the invention, and a detergent 11-4 (D11-4) according to the invention; the compositions of each are given in Table 11b. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 11bb.
[1227] Table 11b: Recipes in Example 11.1
[1228] VD11-1 VD11-2 D11-3 D11-4
[1229] Ingredient Active content Mass fraction (%)
[1230] Raw material (%)
[1231] C16 / 18 fatty acid sodium 100 1 ,26 0.90 0.66 0.16 salt (olive) r
[1232] C9 fatty acid sodium 100 0.14 0.50 0.74 1.24 sodium chloride
[1233] C16 / 18 glutamate sodium 23 2.61 2.61 2.61 2.61 um salt (olive) r
[1234] Caustic soda / ad pH ad pH ad pH ad pH
[1235] Methanesulfonic acid 9.5 9.5 9.5 9.5
[1236] perfume
[1237] dye
[1238] preservatives
[1239] Water, demineralized. ad 100 ad 100 ad 100 ad 100 r C16 / 18- ratio 15 / 85.
[1240] Table 11b: Proportions of different hydrocarbon residues in Example 11.1
[1241] VD11-1 VD11-2 D11-3 D11-4
[1242] Proportion of hydrocarbon residues R with 17 and more C- 80 66 55 32
[1243] atoms (wt%) d
[1244] Proportion of hydrocarbon residues R with 15 C atoms 14 11 9 5
[1245] (wt.%) d
[1246] Proportion of hydrocarbon residues R with a number of 6 23 36 63
[1247] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R. Example 11.2: Performing tests according to the test method “wiping glass interior dirt”
[1248] According to the method from Example 1.2 above (test method “wiping glass interior dirt”), the cleaning performance (wiping method) against dirt type B (“interior dirt”) was determined for the detergents (D11-3 and D11-4) and comparison detergents (VD11-1 and VD11-2) defined in Example 11.1 above. The results of these tests are given in Table 11c.
[1249] Table 11c: Results of the cleaning tests according to the test method
[1250] "Wipe away dirt inside the glass" -
[1251] VD11-1 VD11-2 D11-3 D11-4
[1252] Cleaning performance in 47 5ß
[1253] %
[1254] The results from Table 11 c show an advantageously better cleaning performance of each of the detergents D11-3 and D11-4 according to the invention compared to each of the comparison detergents VD11-1 and VD11-2.
[1255] Example 11.3: Performing tests according to the "Wipe DT40" test method
[1256] According to the method from Example 2.2 above (test method “wiping DT40”), the cleaning performance (wiping method) against crosslinked dried grease and dust (III) from the “IKW Recommendation on the Quality Assessment of Product Performance of All-Purpose Cleaners 2014” was determined for the detergents (D11-3 and D11-4) and reference detergents (VD11-1 and VD11-2) defined in Example 1.1 above. The results of these tests are given in Table 1.1d.
[1257] Table 11d: Results of the cleaning tests according to the test method
[1258] “Wipe DT40” _
[1259] VD11-1 VD11-2 D11-3 D11-4
[1260] Cleaning performance in / 00 oo / y
[1261] % The results from Table 11 d show an advantageously better cleaning performance of each of the detergents D11-3 and D11-4 according to the invention compared to each of the comparison detergents VD11-1 and VD11-2.
[1262] Example 12 (Detergents) Example 12.1 Production of detergents and comparative detergents:
[1263] The following were produced: a non-inventive comparative detergent 12-1 (VD12-1), a non-inventive comparative detergent 12-2 (VD12-2), a detergent 12-3 (D12-3), a detergent 12-4 (D12-4), a detergent 12-5 (D12-5), a detergent 12-6 (D12-6), and a detergent 12-7 (D12-7); the compositions of each are given in Table 12bi and 12bii, respectively. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7-10 carbon atoms are given in Table 12bbi and Table 12bbii, respectively.
[1264] Table 12bi: Recipes in Example 12.1
[1265] VD12-1 VD12-2 D12-3 D12-4
[1266] Ingredient Active content Mass fraction (%)
[1267] Raw material (%)
[1268] C16 / 18 fatty acid sodium
[1269] 100% salt (olive) s 5.00 2.50 2.50 0.00
[1270] Fat alcohol 100
[1271] C16 / 18*18:1EO' 10.00 10.00 5.00 5.00
[1272] C16 / 18 glutamate sodium 23 salt (olive) s 21.74 21.74 10.87 21.74
[1273] C9 fatty acid sodium salt 100 0.00 2.50 2.50 5.00
[1274] Fatty alcohol C10*6EO 100 0.00 0.00 5.00 5.00
[1275] C8 / 10-glutamate-sodium-37 salt u 0.00 0.00 6.76 0.00
[1276] Enzymes, optical brighteners,
[1277] Complexing agents
[1278] dye
[1279] perfume
[1280] preservatives
[1281] Water (demineralized) s C16 / 18 ratio 15 / 85. t C16 / 18 ratio 14 / 86. u C8 / 10 ratio 50 / 50.
[1282] Table 12bii: Recipes in Example 12.1
[1283] D12-5 D12-6 D12-7
[1284] Ingredient Active content Mass fraction (%)
[1285] Raw material (%)
[1286] C16 / 18 fatty acid sodium salt (olive)** 0.00 0.00 0.00
[1287] Fatty alcohol
[1288] C16 / 18*18:1 EO* 0.00 2.50 0.00
[1289] C16 / 18 glutamate sodium salt (olive)** 21.74 10.87 10.87
[1290] C9 fatty acid sodium salt 5.00 5.00 5.00
[1291] Fatty alcohol C10*6EO 10.00 7.50 10.00
[1292] C8 / 10 Glutamate Sodium Salt*** 0.00 6.76 6.76
[1293] Enzymes, optical brighteners,
[1294] Complexing agents
[1295] dye
[1296] perfume
[1297] preservatives
[1298] Water (demineralized) s C16 / 18 ratio 15 / 85. t C16 / 18 ratio 14 / 86. u C8 / 10 ratio 50 / 50.
[1299] Table 12bbi: Proportions of different hydrocarbon residues in Example 12.1
[1300] VD12-1 VD12-2 D12-3 D12-4
[1301] Proportion of hydrocarbon residues R with 17 and more C- 86 70 45 39
[1302] atoms (wt%) d
[1303] Proportion of hydrocarbon residues R with 15 C atoms 14 12 8 6
[1304] (wt.%) d
[1305] Proportion of hydrocarbon residues R with a number of 0 18 47 55
[1306] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of the hydrocarbon residues present in the detergent R. Table 12bbii: Proportions of different hydrocarbon residues in Example 12.1
[1307] D12-5 D12-6 D12-7
[1308] Proportion of hydrocarbon residues R with 17 and more C- 27 20 14
[1309] atoms (wt%) d
[1310] Proportion of hydrocarbon residues R with 15 C atoms 4 3 2
[1311] (wt.%) d
[1312] Proportion of hydrocarbon residues R with a number of 69 77 84
[1313] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R. Example 12.2: Test method ‘Grease stains on textile fabrics (washing)’
[1314] To determine the cleaning performance against grease stains on textiles (washing), a cotton swatch (5 x 5 cm; Fabric: C-01s, Mineral oil with carbon black; CFT) soiled with colored mineral oil was washed in a laboratory washing machine in a washing solution (150 ml; detergent plus demineralized water) for 45 minutes at 40°C. 25 steel pellets (0.635 cm diameter) were added to the load. Eight tests were performed. The washing solution, consisting of detergent and demineralized water, contained 5 g of detergent per 1 liter of demineralized water. After washing, the textile was rinsed with lukewarm water and dried.
[1315] For evaluation, the cleaned textile swatches were photographed immediately after drying in a photo booth. Using suitable computer software, a percentage brightness value was calculated for each wiped area from the photograph, compared to the brightness of a 100% clean textile swatch (white; value corresponds to 100% cleaning performance) and a completely soiled textile swatch (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[1316] Example 12.3: Conducting tests according to the test method “Grease stains on textile fabrics (washing)”
[1317] According to the method from Example 12.2 above, the washing performance (washing) against grease stains on textile fabrics was determined for the detergents (D12-3, D12-4, D12-5, D12-6 and D12-7) and comparison detergents (VD12-1 and VD12-2) defined in Example 12.1 above. The results of these tests are given in Tables 12ci and 12cii.
[1318] Table 12ci: Results of the cleaning tests in Example 12.3
[1319] VD12-1 VD12-2 D12-3 D12-4
[1320] Cleaning performance in % 50 49 54 55 Table 12cii: Results of the cleaning tests in Example 12.3
[1321] D12-5 D12-6 D12-7
[1322] Cleaning performance in % 57 58 63
[1323] The results from Tables 12ci and 12cii show a significantly better cleaning performance of each of the detergents D12-3, D12-4, D12-5, D12-6 and D12-7 according to the invention compared to each of the reference detergents VD12-1 and VD12-2. Example 13 (Dishwashing liquid)
[1324] Example 13.1 Production of detergents and comparison detergents:
[1325] The following were produced: a non-inventive comparative detergent 13-1 (VD13-1), a non-inventive comparative detergent 13-2 (VD13-2), a detergent 13-3 (D13-3), a detergent 13-4 (D13-4), a non-inventive comparative detergent 13-5 (VD13-5) and a non-inventive comparative detergent 13-6 (VD13-6), the compositions of which are shown in Table 13bi and 13bii, respectively. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms and with 7 to 10 carbon atoms are shown in Table 13bbi and Table 13bbii, respectively.
[1326] Table 13bi: Recipes in Example 13.1
[1327] VD13-1 VD13-2 D13-3 D13-4
[1328] Ingredient Active content Mass fraction (%)
[1329] Raw material (%)
[1330] C16 / 18-glutamate sodium
[1331] 23 14.35 10.00 10.00 10.00 salt (olive) v
[1332] C8 / 10-Glutamate-Sodium- 37 0.00 2.70 2.70 2.70 sodium chloride w
[1333] C16 / 18-Glucamide (SB) X 52 6.54 6.54 0.00 0.00
[1334] C8 / 10-Glucamide w 50 0.00 0.00 6.80 6.80
[1335] Glycerol Oleate
[1336] 100 3.30 3.30 3.00 0.00
[1337] (C16 / 18)*7EO (SB) X Glycerin caprylate / caprinate 100 0.00 0.00 0.30 3.30
[1338] (C8 / 10)*7EO W sodium hydroxide or ad pH ad pH ad pH ad pH
[1339] 45 / 70 Methanesulfonic acid w 7.0 7.0 7.0 7.0
[1340] Perfume dye
[1341] Preservative: Water (demineralized) 100% 100% 100% 100% 100% v C16 / 18 ratio 15 / 85. w C8 / C10 ratio 50 / 50. x C16 / 18 ratio 5 / 95. ww Active content sodium hydroxide 45%, active content methanesulfonic acid 70%; depending on requirements, one or both are used to adjust the pH to 7.0.
[1342] Table 13bii: Recipes in Example 13.1
[1343] VD13-5 VD13-6
[1344] Ingredient Active content Mass fraction (%)
[1345] Raw material (%)
[1346] C16 / 18 glutamate sodium 23 3.04 0.00 salt (olive) v
[1347] C8 / 10-Glutamate-Sodium- 37 7.03 8.92 umsalz w
[1348] C16 / 18-Glucamide (SB) X 52 0.00 0.00
[1349] C8 / 10-Glucamide w 50 6.80 6.80
[1350] Glycerol Oleate
[1351] 100 0.00 0.00
[1352] (C16 / 18)*7EO (SB) X
[1353] Glycerin caprylate / caprinate 100 3.30 3.30
[1354] (C8 / 10)*7EO W Sodium hydroxide / to pH to pH
[1355] 45 / 70
[1356] Methanesulfonic acid ww 7.0 7.0
[1357] perfume
[1358] dye
[1359] Preservative: Water (demineralized) ad 100; C16 / 18 ratio 15 / 85; C8 / C10 ratio 50 / 50; C16 / 18 ratio 5 / 95; Active content: sodium hydroxide 45%, methanesulfonic acid 70%; depending on requirements, one or both are used to adjust the pH to 7.0.
[1360] Table 13bbi: Proportions of different hydrocarbon residues in Example 13.1
[1361] VD13-1 VD13-2 D13-3 D13-4
[1362] Proportion of hydrocarbon residues R with 17 and more C- 92 85 53 31
[1363] atoms (wt%) d
[1364] Proportion of hydrocarbon residues R with 15 C atoms 8 7 6 5
[1365] (wt.%) d
[1366] Proportion of hydrocarbon residues R with a number of 0 8 41 64
[1367] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of the hydrocarbon residues present in the detergent R. Table 13bbii: Proportions of different hydrocarbon residues in Example 13.1 _
[1368] VD13-5 VD13-6
[1369] Proportion of hydrocarbon residues R with 17 and more C- 10 0
[1370] atoms (wt%) d
[1371] Proportion of hydrocarbon residues R with 15 C atoms 2 0
[1372] (wt.%) d
[1373] Proportion of hydrocarbon residues R with a number of 88 100
[1374] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) dd in each case based on the total mass of hydrocarbon residues present in the detergent R. Example 13.2: Test method “Emulsifying behavior”
[1375] To estimate the rinsing performance, the emulsifying behavior of the detergent is examined and its emulsifying ability is thus determined.
[1376] For this purpose, 66.67 g each of the detergent (previously diluted 1:20 with demineralized water) and the reference detergent were emulsified with 33.33 g of refined rapeseed oil for 2 minutes at 1200 rpm in a 400 ml tall beaker using a paddle stirrer. The mixture was transferred to a 250 ml graduated cylinder and observed. After a waiting period of 45 minutes, the volume (in mL) of the oil phase was recorded. Using this volume (mL) and the density (g / mL) of the edible oil relative to the weighed amount of oil (g), the percentage of emulsified oil was calculated.
[1377] Example 13.3: Conducting tests according to the test method “Emulsifying behavior”
[1378] According to the method from Example 13.2 above, the proportion of emulsified oil was determined for the detergents (D13-3 and D13-4) and reference detergents (VD13-1, VD13-2, VD13-5 and VD13-6) defined in Example 13.1 above. The results of these tests are given in Tables 13ci and 13cii.
[1379] Table 13ci: Results of the cleaning tests in Example 13.3
[1380] VD13-1 VD13-2 D13-3 D13-4
[1381] Percentage of emulsified oil: 100 100 100 100
[1382] Table 13cii: Results of the cleaning tests in Example 13.3
[1383] VD13-5 VD13-6
[1384] Percentage of emulsified oil: 75 56
[1385] The results from Tables 13ci and 13cii show a significantly better cleaning performance for each of the detergents D13-3 and D13-4 according to the invention compared to each of the reference detergents VD13-5 and VD13-6. The reference detergents VD13-1 and VD13-2 are cloudy solutions, which is regularly perceived as a disadvantage in the field of the present invention. The detergents D13-3 and D13-4 according to the invention are clear solutions without any disadvantageous cloudiness. Example 14 (All-purpose cleaner)
[1386] Example 14.1 Production of detergents and comparison detergents:
[1387] The following were produced: a non-inventive comparative detergent 14-1 (VD14-1), a non-inventive comparative detergent 14-2 (VD14-2), a detergent 14-3 (D14-3) according to the invention, and a detergent 14-4 (D14-4) according to the invention; the compositions of each are given in Table 14b. The proportions of hydrocarbon residues R with 17 or more carbon atoms, with 15 carbon atoms, and with 7 to 10 carbon atoms are given in Table 14bb.
[1388] Table 14b: Recipes in Example 14.1
[1389] VD14-1 VD14-2 D14-3 D14-4
[1390] Ingredient Active content Mass fraction (%)
[1391] Raw material (%)
[1392] Linseed oil fatty acid sodium 100 4.50 2.75 2.20 0.83 salt y
[1393] C9 fatty acid 100 0.00 1.75 2.30 3.67
[1394] C16 / 18 fatty acid amide*
[1395] 95 1,05 1,05 1,05 1,05
[1396] 3-4 mol EO (rapeseed) z
[1397] Alcohol (ethanol) 96 3.00 3.00 3.00 3.00
[1398] Tetrasodium N,N-bis(carboxymethyl)-L- 47 1.06 1.06 1.06 1.06 glutamate (GLDA)
[1399] Sodium gluconate 100 1 .00 1 .00 1 .00 1 .00
[1400] Caustic soda / methane sulphate ad pH ad pH ad pH ad pH
[1401] 45 fonic acid 10.4 10.4 10.4 10.4
[1402] perfume
[1403] dye
[1404] preservatives
[1405] Deionized water. 100 C16 / 18 ratio 7 / 93. C8 / C10 ratio 5 / 95. Table 14bb: Proportions of different hydrocarbon residues in Example 14.1
[1406] VD14-1 VD14-2 D14-3 D14-4
[1407] Proportion of hydrocarbon residues R with 17 and more C-
[1408] 93 67 57 32
[1409] atoms (wt%) d
[1410] Proportion of hydrocarbon residues R with 15 C atoms 7 5 4 2
[1411] (wt.%) d
[1412] Proportion of hydrocarbon residues R with a number of
[1413] 0 29 39 66
[1414] Carbon atoms in the range of 7 to 10 carbon atoms (wt%) d d in each case based on the total mass of hydrocarbon residues present in the detergent R.
[1415] Example 14.2: Test method “Wiping DT47” The rapid mechanical cleaning performance (wiping method) against a grease-gravy mixture (CFT - DT 47 dirt monitor) was tested.
[1416] To determine the rapid mechanical cleaning (wiping method) compared to the burnt-on grease-gravy mixture described above, the procedure follows the “IKW recommendation for the quality assessment of the product performance of all-purpose cleaners 2014”, whereby the only deviations from the procedure described therein are the following changes:
[1417] Altered soiling as described above (burnt-on fat-gravy mixture instead of crosslinking dried fat-dust soil (III)).
[1418] Instead of the described Sheen device, a single-track hand wiper (103, 203) made of stainless steel (dimensions 2.7 x 8.0 cm, weight: 240 g) was used, which is designed for individually wiping single strips on the soiled area. A precisely cut cleaning textile was used (as a covering (104, 204) of the single-track hand wiper (103, 203).
[1419] Instead of visual inspection, the cleaned dirt monitors were photographed in a photo booth and evaluated using a PC, as described below in the present example.
[1420] For each experiment, the hand-held wiping device was fitted with a precisely cut cleaning textile (104, 204), and the cleaning textile (fitting) (104, 204) was soaked with 2.8 ml of the detergent under investigation or the reference detergent under investigation. The single-track hand-held wiping device was then moved back and forth along a rail (105, 205) over the soiling six times without additional pressure (corresponding to six "strokes").
[1421] For evaluation, the cleaned dirt monitors were photographed in a photo booth after drying. Using suitable PC software, a percentage brightness value was calculated for each wiped area from the photograph, compared to the brightness of a 100% cleaned area (white; value corresponds to 100% cleaning performance) and a completely soiled area (black; value corresponds to 0% cleaning performance). A higher percentage value therefore correlates with better cleaning performance, and vice versa.
[1422] Example 14.3: Conducting tests according to the "Wipe DT47" test method
[1423] According to the method from Example 14.2 above (test method “wiping DT47”), the cleaning performance (wiping method) against burnt-on grease and gravy mixture was determined for the detergents (D14-3 and D14-4) and comparison detergents (VD14-1 and VD14-2) defined in Example 14.1 above. The results of these tests are given in Table 14c.
[1424] Table 14c: Results of the cleaning tests according to the test method
[1425] “Swipe DT47” _
[1426] VD14-1 VD14-2 D14-3 D14-4
[1427] Cleaning performance in52 7Q 81 g3
[1428] % The results from Table 14c show a significantly better cleaning performance of each of the detergents D14-3 and D14-4 according to the invention compared to each of the comparison detergents VD14-1 and VD14-2.
[1429] The procedure for the hydrolytic cleavage of surfactant compounds in detergents as well as the qualitative and guantitative determination of the mass content of their hydrophobic residues is described below.
[1430] Procedure for the hydrolytic cleavage of surfactant compounds in detergents as well as qualitative and guantitative determination of the mass content of their hydrophobic residues
[1431] For the acid hydrolytic cleavage of surfactants in a detergent, 5 g of the aqueous detergent are mixed with 5 g of fuming hydrochloric acid (37%), and this reaction mixture is transferred to a bomb tube. The bomb tube is sealed, placed in a steel protective casing, and then heated to 120 °C in a bomb furnace. The reaction mixture is held at 120 °C for 48 h. The hydrolytic cleavage breaks down the hydrophobic molecular parts of the surfactants with the general formulas RC(O)-OM and R-C(O)-OR. 1 and RC(O)-NR 1 R 2converted into the corresponding fatty acids RC(O)-OH. The hydrophobic residues of the surfactants have the general formulas R-CH2OR. 1 are converted into the fatty alcohols R-CH2OH.
[1432] After cooling, the bomb tube is opened and the reaction mixture is transferred to a separatory funnel. The mixture is extracted three times with 20 mL of n-hexane. During this process, the fatty acids and fatty alcohols hydrolytically cleaved from the surfactants are transferred into the n-hexane phase. The combined n-hexane phases are dried over anhydrous sodium sulfate. After filtering off the drying agent and rinsing with 50 mL of n-hexane, the filtrate is transferred to a round-bottom flask and the n-hexane is removed using a rotary evaporator.
[1433] The fatty acids and fatty alcohols remaining in the round-bottom flask are reconstituted with a defined amount of 100 g to 200 g of n-hexane. This solution (or a previously diluted solution, if necessary) is subjected to analytical liquid chromatography (LC) to separate the different fatty acids and fatty alcohols. Qualitative detection of the separated fatty acids and fatty alcohols is performed by coupled mass spectrometry (MS), and their quantitative determination is carried out using a refractive index detector (RDI).
[1434] From the mass concentrations of the individual long- and short-chain fatty acids and fatty alcohols determined in this way, the mass concentrations of the corresponding long- and short-chain hydrophobic residues R in the detergent can be determined. For this purpose, the determined mass concentrations of all fatty acids are reduced by the mass fraction of one -COOH unit, and the determined mass concentrations of all fatty alcohols are similarly reduced by the mass fraction of one -CH2-OH unit.
[1435] The distribution of these hydrophobic residue groups in the investigated detergent is derived from the mass contents of all short-chain (R = 7 to 10 C atoms), long-chain (R with 17 to 23 C atoms) and medium-chain (R = 11 to 16 C atoms) hydrophobic residues R determined in this way.
Claims
1. Detergent comprising a total amount of one or more surfactant compounds, each independently selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total of 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein the total mass of the residues R of the one or more surfactant compounds present in the detergent selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total of 17 to 23 carbon atoms in the range of 14 wt.% to 59 wt.% and a proportion of hydrocarbon residues R with a total of 7 to 10 carbon atoms of over 30 wt.% includes and where R 1 and / or R 2 Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant.
2. Detergent according to claim 1, wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 6.5 wt.%, preferably more than 10 wt.%, particularly preferably more than 20 wt.%, and most preferably more than 30 wt.%; and / or wherein the total mass of the one or more surfactant compounds selected from i) to iv) with a hydrocarbon residue R having a total of 17 to 23 carbon atoms comprises a proportion of surfactant compounds with unsaturated hydrocarbon residues R of more than 50 wt.%, preferably more than 60 wt.%, and particularly preferably more than 70 wt.%; and / or wherein the total mass of the one or more surfactant compounds selected from i) to iv) comprises a proportion of surfactant compounds with hydrocarbon residues R of a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, of more than 30 wt.%, preferably of more than 32 wt.%.-% particularly preferably above 35 wt.%, most preferably above 38 wt.%.
3. Detergent according to any of the preceding claims, additionally comprising a total amount of one or more surfactant compounds, each independently selected from the group consisting of: v) Secondary or tertiary fatty amines with the general formula RNR 1 R 2 , each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 23 carbon atoms, forming one or the hydrophobic part of the respective surfactant compound, and wherein R 1 and / or R 2 Residues are those that form or comprise the hydrophilic molecular portion of the respective surfactant; and / or from the group consisting of: vi) Hydrotropic surfactants with a general formula selected from the group consisting of: Ethers of fatty alcohols with the general formula R 5 -CH2-OR 1 Fatty acid amides with the general formula R 5 -C(O)NR 1 R 2 Secondary or tertiary fatty amines with the general formula R 5 NR 1 R 2 where R 5 a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with a total number of less than 7 carbon atoms, preferably less than 6 carbon atoms, which forms the hydrophobic part of the hydrotropic surfactant, and wherein R 1 and / or R 2 These are residues that form or comprise the hydrophilic molecular portion of the respective surfactant; and / or from the group consisting of: vii) microbial biosurfactants, preferably selected from the group consisting of: sophorolipids and rhamnolipids.
4. Detergent according to any one of the preceding claims, comprising one or more surfactant compounds selected from ii) to iv), each with a residue R 1 , comprising nitrogen, oxygen, sulfur and / or phosphorus atoms and forming or comprising a hydrophilic molecular fraction of the respective surfactant, and / or wherein preferably the R groups 1 and / or R 2 open-chain residues are or the residue R 1 an open-chain residue and R 2 hydrogen is and / or wherein preferably any residue R 1 Selected independently from the group consisting of: (a) (C2H4O)XZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (c) (C2H4O)x(C3H6O) y Z wherein Z is an alkyl group with 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein x and y are selected independently of each other; (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e) (C2H4O)xCH2COOM where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (f) CH2CH(OH)CH2OH (12) CH(CH2OH)2 (g) CH2CH(OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms, (h) CH2CH(O(CO)R)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms, (h2) CH(CH2OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms, (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4; (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4; (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3; (l) (C2H4O)x(C3H6O) y H where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where x and y are selected independently of each other; (m) [CH2CH(OH)CH2-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30; (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (o) (C2H4O)XSO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10, particularly preferably in the range of 1 to 5; (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH (q) CH2CH2CH2N + (CH3)2CH2COO- (r) CH2CH2CH2N + (CH3)2O- (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (w) CH2CH(OH)CH2O(CO)R * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (x) CH2CH(O(CO)R)CH2OH * (C2H4O) yH where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (y) CH(CH2O(CO)R)CH2OH * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (za) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM where y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and where M an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e.g.) CH2CH(OH)CH2O(CO)R * (C2H4O) yCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms; (zc) CH2CH(O(CO)R)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (zc2) CH(CH2O(CO)R)CH2OH * (C2H4O) yCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms; (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) Z CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, wherein z is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (zf) CH2CH(O(CO)R)[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 1 to 3 and where y is a number in range from 1 to 30, preferably in the range from 3 to 30, particularly preferably in the range from 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (zg) Remainder according to the following formula 1 : Formula 1: where m is a number in the range of 1 to 10, preferably in the range of 1 to 5, particularly preferably in the range of 1 to 3; (zh) Remainder according to the following formula 2: Formula 2: where m is a number in the range of 1 to 10, preferably in the range of 1 to 5, particularly preferably in the range of 1 to 3; (zi) Remainder according to the following formula 3: Formula 3: where R 3 Hydrogen is; (zj) A remainder according to the formula 3 defined above is, where R 3 in two cases hydrogen and in one case (CO)R 4 is, where R 4 a hydrocarbon residue with a total number of 7 to 23 carbon atoms; (zk) A remainder according to the formula 3 defined above is, where R 3 (C2H4O) X H is, where x is a number in the range of 1 to 50, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 15; (zl) A remainder according to the formula 3 defined above is, where R 3 in two cases (C2H4O) X H is, where x is a number in the range of 1 to 50, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; and where R 3 in one case (CO)R 4 is, where R 4a hydrocarbon residue with a total number of 7 to 23 carbon atoms; preferably selected from the group consisting of: (a) (C2H4O)XZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (b) (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (C) (C2H4O)x(C3H6O)yZ wherein Z is an alkyl group having 1 to 4 carbon atoms and wherein x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and wherein x and y are selected independently of each other; (d) CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e) (C2H4O)XCH2COOM where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (f) CH2CH(OH)CH2OH (12) CH(CH2OH)2 (g) CH2CH(OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms, (h) CH2CH(O(CO)R)CH2OH where R is a hydrocarbon residue with 7 to 23 carbon atoms, (h2) CH(CH2OH)CH2O(CO)R where R is a hydrocarbon residue with 7 to 23 carbon atoms, (i) CH2[CH(OH)]XCH2OH where x is a number in the range of 2 to 4; (j) CH2[CH(OH)]XCHO where x is the number 3 or the number 4; (k) CH2[CH(OH)]XC(O)CH2OH where x is the number 2 or the number 3; (l) (C2H4O)x(C3H6O) y H where x is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and where x and y are selected independently of each other; (m) [CH2CH(OH)CH2-O]XH where x is a number in the range of 2 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (n) SO3M where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (o) (C2H4O)XSO3M wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and wherein x is a number in the range of 1 to 20, preferably in the range of 1 to 10, particularly preferably in the range of 1 to 5; (p) CH2CH(OH)CH(OH)CH(OH)CH(OH)CH2OH (q) CH2CH2CH2N + (CH3)2CH2COO- (r) CH2CH2CH2N + (CH3)2O- (s) CH2CH2N(C2H4OH)CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (t) CH2CH2N(CH2COOM)CH2CH2OCH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (u) CH(COOM)CH2CH2COOM where M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (v) CH2CH(OH)CH2OH * (C2H4O) y H, where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (w) CH2CH(OH)CH2O(CO)R * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (x) CH2CH(O(CO)R)CH2OH * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (y) CH(CH2O(CO)R)CH2OH * (C2H4O) y H where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; (za) CH2CH(OH)CH2OH * (C2H4O) yCH3COOM where y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and where M an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (e.g.) CH2CH(OH)CH2O(CO)R * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms; (zc) CH2CH(O(CO)R)CH2OH * (C2H4O) yCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (zc2) CH(CH2O(CO)R)CH2OH * (C2H4O) y CH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound and R is a hydrocarbon residue with 7 to 23 C atoms; (zd) CH2CH(OH)CH2OH * (C2H4O) y CH3COOM * (C2H4O) ZCH3COOM wherein y is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, wherein z is a number in the range of 3 to 30, preferably in the range of 3 to 20, particularly preferably in the range of 3 to 12, and wherein M is an alkali metal cation or a profaned ammonia or a profaned primary, secondary or tertiary amine compound; (ze) CH2[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 2 to 4 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12; (zf) CH2CH(O(CO)R)[CH(OH)]XCH2OH * (C2H4O) y H where x is a number in the range of 1 to 3 and where y is a number in the range of 1 to 30, preferably in the range of 3 to 30, particularly preferably in the range of 3 to 12, and R is a hydrocarbon residue with 7 to 23 C atoms; and / or where preferably the residue R2 a surfactant of group iv), if available, is selected from the group consisting of: Alkyl group, preferably an alkyl group with 1 to 3 carbon atoms and Hydrogen.
5. Detergent according to any one of the preceding claims, wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) comprises a proportion of hydrocarbon residues R with a total of 15 C atoms of at least 0.7 wt.%, preferably in the range of 0.8 wt.% to 15 wt.%, particularly preferably in the range of 1 wt.% to 10 wt.%, most preferably in the range of 1.2 wt.% to 9 wt.%, in each case based on the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv); and / or wherein the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) a proportion of hydrocarbon residues R with 17 to 23 C atoms in the range of 14 wt.% to 59 wt.%, preferably in the range of 17 wt.% to 59 wt.%, particularly preferably in the range of 20 wt.% to 59 wt.%, most preferably in the range of 25 wt.% to 59 wt.%.-% comprises, in each case based on the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv); and / or wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 11 to 13 C atoms to the total mass of the hydrocarbon residues R with a total number of 7 to 10 C atoms is in the range of 0 to 0.1, preferably in the range of 0 to 0.05, particularly preferably in the range of 0 to 0.03; and / or wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 7 to 10 C atoms to the total mass of the hydrocarbon residues R with a. Total number of 17 to 23 carbon atoms in the range of 0.52 to 6, preferably in the range of 0.53 to 5, particularly preferably in the range of 0.54 to 4; and / or wherein in the total mass of the hydrocarbon residues R of the one or more surfactant compounds selected from i) to iv) the ratio of the total mass of the hydrocarbon residues R with a total number of 15 C atoms to the total mass of the hydrocarbon residues R with a total number of 17 to 23 C atoms is in the range of 0.03 to 0.3, preferably in the range of 0.04 to 0.24, particularly preferably in the range of 0.05 to 0.
18.
6. Detergent according to any one of the preceding claims, wherein the detergent comprises one, two or more surfactant compounds selected from i) to iv), the hydrocarbon residues R of which have a ratio of 14 carbon atoms to 12exhibiting C atoms corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and wherein preferably the proportion of these surfactant compounds to the total mass of the surfactant compounds contained in the detergent is in the range of 80 wt.% to 100 wt.%, more preferably in the range of 85 wt.% to 100 wt.%, more preferably in the range of 90 wt.% to 100 wt.%; and / or wherein surfactant compounds from at least one of groups i) to iv) are present, each with at least two different chain lengths of the hydrocarbon chains R.
7. Detergent according to any one of the preceding claims, wherein the detergent comprises at least one surfactant compound selected from i) to iv) which is not a soap; and / or wherein the detergent - comprises a monoglyceride; or - is free of monoglycerides.
8. Detergent according to any of the preceding claims, wherein the detergent is in liquid form or wherein the detergent is in solid form.
9. Detergent according to any of the preceding claims, wherein the detergent comprises at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms, preferably at least one surfactant compound from group i) with a hydrocarbon residue R having a total number of 17 to 23 carbon atoms selected from the group consisting of: - Sodium soaps, Potassium soaps, Monoethanolamine soaps, Diethanolamine soaps, - Triethanolamine soaps, - Methyldiethanolamine soaps, and - Diisopropanolamine soaps; and / or wherein the detergent comprises at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, preferably at least one surfactant compound from group ii) with a hydrocarbon residue R having a total number of 17 to 23 C atoms selected from the group consisting of: - Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of: - Fatty acid alkyl ester ethoxylates, - Fatty acid alkyl ester ethoxylates / propoxylates, - Fatty acid carboxymethyl esters, - Fatty acid ethoxylate acetates, - Fatty acid monoesters of glycerol, - Fatty acid diesters of glycerol, - Ethoxylated fatty acid monoesters of glycerol, Ethoxylated fatty acid diesters of glycerol, monoglyceride EO ether acetates, Dig lyce rid-EO-Ether-Acetate, - Monoglyceride EO ether diacetate, - Fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol, - Ethoxylated fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol, - Fatty acid esters of aldoses, ketoses and disaccharides, - Fatty acid monoesters of sorbitan, - Fatty acid diesters of sorbitan, - Ethoxylated fatty acid monoesters of sorbitan, - Ethoxylated fatty acid diesters of sorbitan; wherein preferably - the rest R 1 of this surfactant compound from group ii) is an open-chain residue; preferably selected from the group consisting of: - Fatty acid alkyl ester ethoxylates, - Fatty acid monoesters of glycerol, - Fatty acid diesters of glycerol, - Ethoxylated fatty acid monoesters of glycerol, - Ethoxylated fatty acid diesters of glycerol, - monoglyceride EO ether acetates, Dig lyce rid-EO-Ether-Acetate, Monoglyceride EO ether diacetate, Fatty acid monoesters of sorbitan, - Fatty acid diesters of sorbitan, - Ethoxylated fatty acid monoesters of sorbitan, - Ethoxylated fatty acid diesters of sorbitan; wherein preferably - the rest R 1 this surfactant compound from group ii) is an open-chain residue; and / or wherein the detergent comprises at least one surfactant compound from group iii) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, preferably at least one surfactant compound from group iii) with a hydrocarbon residue R having a total number of 17 to 23 C atoms selected from the group consisting of: - Fatty alcohol alkoxylates, preferably selected from the group consisting of: - Fatty alcohol ethoxylates, - fatty alcohol ethoxylate / propoxylates, - Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of: - fatty alcohol ethoxylate acetates, - Fetta I ko ho I- Eth oxy lat / Pro poxy I at- Acetate, - Fatty alcohol monoglycerol ethers Fatty alcohol polyglycerol ether Alkyl glycosides, preferably selected from the group consisting of: - Alkyl polyglycosides (APG), - Alkyl polypentosides (APP), - Alkyl sulfates, and - Alkyl ether sulfates; wherein preferably - the rest R 1 of this surfactant compound from group iii) is an open-chain residue; preferably selected from the group consisting of: Fatty alcohol alkoxylates, preferably selected from the group consisting of: Fetta I ko ho I- Eth oxy late , Fatty alcohol ethoxylate / propoxylates, - Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of: - fatty alcohol ethoxylate acetates, - Fatty alcohol polyglycerol ether - Alkyl sulfates, and - Alkyl ether sulfates; wherein preferably - the rest R 1 this surfactant compound from group iii) is an open-chain residue; and / or wherein the detergent comprises at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, preferably at least one surfactant compound from group iv) with a hydrocarbon residue R having a total number of 17 to 23 C atoms selected from the group consisting of: - Fatty acid amide alkoxylates, preferably selected from the list consisting of: - Fatty acid amide ethoxylates, and / or - Fatty acid amide ethoxylate / propoxylates, - N-Acyl-N-Alkyl-Glucamine linear sugar, - Alkyl-amidopropyl betaine, - Alkyl-amidopropyl-N-oxide, - Amphoacetate, - Ammphodiacetate, - Fatty acid amides of serinol and - N-acyl amino acids; wherein preferably - the remains R 1 and / or R 2 this surfactant compound from group iv) open-chain residues are or - the rest R 1 this surfactant compound from group iv) is an open-chain residue and R 2 this surfactant compound from group iv) hydrogen; preferably selected from the group consisting of: - Fatty acid amide alkoxylates, preferably selected from the list consisting of: - Fatty acid amide ethoxylates, and / or - Fatty acid amide ethoxylate / propoxylates, - N-Acyl-N-Alkyl-Glucamine linear sugar, - Alkyl-amidopropyl betaine, - Alkyl-amidopropyl-N-oxide, - Amphoacetate, - Amphodiacetates, and - N-acyl amino acids; wherein preferably - the remains R 1 and / or R 2of this surfactant compound from group iv) are open-chain residues or the residue R 1 this surfactant compound from group iv) is an open-chain residue and R 2 this surfactant compound from group iv) contains hydrogen; and / or wherein the detergent comprises at least one surfactant compound from group v) with a hydrocarbon residue R having a total number of 17 to 23 C atoms, preferably at least one surfactant compound from group v) with a hydrocarbon residue R having a total number of 17 to 23 C atoms selected from the group consisting of: - Alkyliminoacetates, - Alkyliminodiacetates, - Alkyliminopropionate, and - Alkyliminodipropionates; wherein preferably - the remains R 1 and / or R 2 this surfactant compound from group v) open-chain residues are or - the rest R 1this surfactant compound from group v) is an open-chain residue and R 2 This surfactant compound from group v) contains hydrogen.
10. Detergent according to any of the preceding claims, wherein the detergent comprises at least one surfactant compound from group i) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of: - Sodium soaps, Potassium soaps, Monoethanolamine soaps, - Diethanolamine soaps, - Triethanolamine soaps, - Methyldiethanolamine soaps, and - Diisopropanolamine soaps; and / or - wherein the detergent comprises at least one surfactant compound from group ii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of: Fatty acid alkyl ester alkoxylates, preferably selected from the group consisting of: - Fatty acid alkyl ester ethoxylates and - Fatty acid alkyl ester ethoxylates / propoxylates, Fatty acid carboxymethyl esters Fatty acid ethoxylate acetates, Fatty acid monoesters of glycerol, Fatty acid diesters of glycerol, Ethoxylated fatty acid monoesters of glycerol, Ethoxylated fatty acid diesters of glycerol, monoglyceride EO ether acetates, Dig lyce rid-EO-Ether-Acetate, Monoglyceride EO ether diacetate, Fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol Ethoxylated fatty acid esters of higher polyols, preferably erythritol, xylitol, sorbitol Fatty acid esters of aldoses and ketoses and disaccharides, Fatty acid monoesters of sorbitan, Fatty acid diesters of sorbitan, Ethoxylated fatty acid monoesters of sorbitan, and Ethoxylated fatty acid diesters of sorbitan, wherein preferably - the rest R 1 of this surfactant compound from group ii) is an open-chain residue; preferably selected from the group consisting of: Fatty acid alkyl ester ethoxylates Fatty acid monoesters of glycerol, Fatty acid diesters of glycerol, Ethoxylated fatty acid monoesters of glycerol, Ethoxylated fatty acid diesters of glycerol, monoglyceride EO ether acetates, Dig lyce rid-EO-Ether-Acetate, Monoglyceride EO ether diacetate, Fatty acid monoesters of sorbitan, Fatty acid diesters of sorbitan, Ethoxylated fatty acid monoesters of sorbitan, and Ethoxylated fatty acid diesters of sorbitan, wherein preferably - the rest R 1 this surfactant compound from group ii) is an open-chain residue; and / or wherein the detergent comprises at least one surfactant compound from group iii) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of: Fatty alcohol alkoxylates, preferably selected from the group consisting of: - Fatty alcohol ethoxylates and - fatty alcohol ethoxylate / propoxylates, Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of: - Fatty alcohol ethoxylate acetates and - Fatty alcohol ethoxylate / propoxylate acetates - Fatty alcohol monoglycerol ethers - Fatty alcohol polyglycerol ether - Alkyl glycosides, preferably selected from the group consisting of: - Alkyl polyglycosides (APG), - Alkyl polypentosides (APP), - Alkyl sulfates, and - Alkyl ether sulfates; wherein preferably - the rest R 1 of this surfactant compound from group iii) is an open-chain residue; preferably selected from the group consisting of: Fatty alcohol alkoxylates, preferably selected from the group consisting of: - Fatty alcohol ethoxylates and - fatty alcohol ethoxylate / propoxylates, Fatty alcohol alkoxylate acetates, preferably selected from the group consisting of: - Fatty alcohol ethoxylate acetates Fatty alcohol polyglycerol ether Alkyl sulfates, and - Alkyl ether sulfates; wherein preferably - the rest R 1this surfactant compound from group iii) is an open-chain residue; and / or wherein the detergent comprises at least one surfactant compound from group iv) having a hydrocarbon residue R with a total number of 7 to 10 C atoms, preferably with a total number of 7 to 9 C atoms, and is preferably selected from the group consisting of: - Fatty acid amide alkoxylates, preferably selected from the list consisting of: - Fatty acid amide ethoxylates, and / or - Fatty acid amide ethoxylate / propoxylates, - N-Acyl-N-Alkyl-Glucamine linear sugar, - Alkyl-amidopropyl betaine, - Alkyl-amidopropyl-N-oxide, - Amphoacetates - Ammphodiacetate - Fatty acid amides of serinol and N-acyl amino acids; preferably - the remains R 1 and / or R 2 this surfactant compound from group iv) open-chain residues are or - the rest R 1 this surfactant compound from group iv) is an open-chain residue and R 2 This surfactant compound from group iv) hydrogen is preferably selected from the group consisting of: Fatty acid amide alkoxylates, preferably selected from the list consisting of: - Fatty acid amide ethoxylates, and / or - Fatty acid amide ethoxylate / propoxylates, - N-Acyl-N-Alkyl-Glucamine linear sugar, - Alkyl-amidopropyl betaine, - Alkyl-amidopropyl-N-oxide, - Amphoacetates - Ammphodiacetate and - N-acyl amino acids, preferably - the remains R 1 and / or R 2 of this surfactant compound from group iv) open-chain residues are or - the rest R 1 this surfactant compound from group iv) is an open-chain residue and R 2 This surfactant compound from group iv) contains hydrogen.
11. Detergent according to any one of the preceding claims, wherein the detergent comprises one, two, three or more surfactant compounds selected from i) to iv) having hydrocarbon residues R with a total number of 17 to 23 carbon atoms, the hydrocarbon residues R having a ratio of 14 carbon atoms to 12 exhibiting C atoms, which corresponds to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, and wherein preferably the mass fraction of surfactant compounds with hydrocarbon residues R with a total number of 7 to 23 C atoms, whose hydrocarbon residues R have a ratio of 14 carbon atoms to 12exhibiting C atoms corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, in the range of 80 wt.% to 100 wt.% of the total mass of the surfactant compounds contained in the detergent, preferably in the range of 85 wt.% to 100 wt.%, particularly preferably in the range of 90 wt.% to 100 wt.%; and / or wherein the detergent comprises one, two, three or more surfactant compounds selected from i) to iv) with hydrocarbon residues R having a total number of 7 to 10 C atoms, preferably having a total number of 7 to 9 C atoms, the hydrocarbon residues R having a total number of 7 to 10 C atoms, preferably having a total number of 7 to 9 C atoms, a ratio of 14 carbon atoms to 12exhibiting C atoms, corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, and wherein preferably the mass fraction of surfactant compounds with hydrocarbon residues R having a total number of 7 to 23 C atoms, whose hydrocarbon residues R have a ratio of 14 carbon atoms to 12 exhibiting C atoms, corresponding to an age of the corresponding hydrocarbon residues R of less than 300 years since carbon dioxide fixation, in the total mass of the surfactant compounds contained in the detergent in the range of 80 wt.% to 100 wt.%, preferably in the range of 85 wt.% to 100 wt.%, particularly preferably in the range of 90 wt.% to 100 wt.%; and / or wherein in the total mass of all surfactant compounds contained in the detergent selected from i) to iv) a total ratio of 14 C atoms to 12C atoms are present, which corresponds to an age of the corresponding total mass of all surfactant compounds present in the detergent of less than 300 years since carbon dioxide fixation.
12. Detergent according to any of the preceding claims, wherein the detergent is a component of a washing agent and / or is a washing agent; preferably - Component of a detergent and / or - a detergent selected from the group consisting of: - Laundry detergent, preferably liquid laundry detergent, - Color detergent, preferably liquid color detergent, and - Delicate detergent, preferably liquid; and / or wherein the detergent is a component of a cleaning agent, preferably a cleaning agent, preferably a cleaning agent for hard surfaces, particularly preferably a cleaning agent for hard surfaces selected from the group of cleaning agents for hard surfaces consisting of: - Toilet cleaner, preferably liquid toilet cleaner, - All-purpose cleaner, preferably liquid all-purpose cleaner, - Bathroom cleaner, preferably liquid bathroom cleaner, - Kitchen cleaner, preferably liquid kitchen cleaner, - Degreaser, preferably liquid degreaser, - Floor cleaner, preferably liquid floor cleaner, - Oven cleaner, preferably liquid oven cleaner, - Grill cleaner, preferably liquid grill cleaner, - Glass cleaner, preferably liquid glass cleaner and - Metal cleaner, preferably liquid metal cleaner; and / or wherein the detergent is a component of a cosmetic cleaner and / or is a cosmetic cleaner, preferably - Component of a cosmetic cleanser and / or - a cosmetic cleanser selected from the group of cosmetic cleansers consisting of: - Hand soap, preferably liquid hand soap, - Shower gel, - Hair shampoo, preferably liquid hair shampoo, and - Facial cleanser, preferably liquid facial cleanser; and / or wherein the detergent is a component of a dishwashing liquid and / or is a dishwashing liquid, preferably - Component of a dishwashing liquid and / or a dishwashing liquid selected from the group consisting of: - Hand dishwashing detergent, preferably liquid hand dishwashing detergent and / or - Dishwashing detergent, preferably liquid dishwashing detergent and / or wherein the detergent is a component of a cleaning agent for textile surfaces and / or is a cleaning agent for textile surfaces, preferably - Component of a cleaning agent for textile surfaces and / or - a cleaning agent for textile surfaces selected from the group consisting of: a - Upholstery cleaner, preferably liquid upholstery cleaner, and / or - Carpet cleaner, preferably liquid carpet cleaner; and / or wherein - the detergent is a cleaning agent for leather and / or artificial leather, preferably a liquid cleaning agent for leather and / or artificial leather and / or - the detergent is a component of a cleaning agent for leather and / or artificial leather, preferably a component of a liquid cleaning agent for leather and / or artificial leather.
13. Detergent according to any of the preceding claims, wherein the detergent comprises surfactant compounds selected from i) to iv) with a monounsaturated hydrocarbon residue R having a total number of 15 to 23 C atoms, and wherein the proportion of monounsaturated hydrocarbon residues R is preferably in the range of 20 wt.% to 90 wt.%, preferably in the range of 30 wt.% to 90 wt.%, based on the total mass of hydrocarbon residues R having a total number of 15 to 23 C atoms present in the detergent; and / or wherein the detergent comprises surfactant compounds selected from i) to iv) with a monounsaturated hydrocarbon residue R having 16 to 23 C atoms, and wherein the proportion of monounsaturated hydrocarbon residues R is preferably in the range of 20 wt.% to 90 wt.%, preferably in the range of 30 wt.% to 90 wt.%.-%, based on the total mass of hydrocarbon residues R with 16 to 23 C atoms present in the detergent; and / or wherein the detergent comprises surfactant compounds selected from i) to iv) with a monounsaturated hydrocarbon residue R with 17 to 23 C atoms, and wherein preferably the proportion of monounsaturated hydrocarbon residues R is in the range of 20 wt.% to 90 wt.%, preferably in the range of 30 wt.% to 90 wt.%, based on the total mass of hydrocarbon residues R present in the detergent. Total mass of hydrocarbon residues R with 17 to 23 carbon atoms present.
14. Detergent according to any one of the preceding claims, wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other with respect to their chemical composition solely by the different chain lengths of their hydrocarbon residues R; and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 7, 8, 9, 10, 15, 17, 19, 21 and 23; and / or wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other with respect to their chemical composition solely by the different chain lengths of their hydrocarbon residues R;and wherein the hydrocarbon residues R are saturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 7, 8, 9, 10, 15, 17, 19, 21 and 23; and / or wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other in their chemical composition only by their differ from each other by different chain lengths of their hydrocarbon chains R; and wherein the hydrocarbon residues R are unsaturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 9, 15, 17, 19, 21 and 23; and / or wherein at least one of groups i) to iv) contains two different surfactant compounds in the detergent which differ from each other with respect to their chemical composition solely by their different chain lengths of the hydrocarbon residues R; and wherein the hydrocarbon residues R are monounsaturated hydrocarbon chains and wherein the different chain lengths of the hydrocarbon residues R are selected from the group of chain lengths with a total number of C atoms of: 9, 15, 17, 19, 21 and 23;and / or wherein a total number of surfactant compounds from at least one of groups i) to iv) are present in the detergent, wherein the surfactant compounds are produced from a vegetable oil and, due to the manufacturing process, differ from one another with respect to their chemical composition solely by their different chain lengths of their hydrocarbon residues R, wherein preferably the chain lengths of the hydrocarbon residues R correspond to chain lengths as they occur in natural vegetable oil, preferably in the natural vegetable oil of a plant selected from the group of plants consisting of:; Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof, preferably consisting of Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, camelina, flax, almond, poppy, evening primrose, olive, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof.
15. Detergent according to any of the preceding claims, wherein the detergent additionally comprises one, two, three or more substances selected from the group consisting of: Abrasive materials, preferably marble dust, chalk, clay and / or pumice, Alkalis, preferably ammonia, organic amines, sodium carbonate, sodium hydroxide and / or potassium hydroxide, Alcohols, preferably ethanol, n-propanol and / or isopropanol Complexing agents, preferably citrates, tetrasodium N,N-bis(carboxymethyl)-L-glutamate (GLDA), methylglycine diacetic acid trisodium salt (MGDA), iminodisuccinate tetrasodium salt (IDS), ethylendiamine N,N'-disuccinate trisodium salt (EDDS) Fragrances, Enzymes, preferably amylases, cellulases, lipases and / or proteases, Dyes, Preservatives, organic solvents, Oils, fats and / or waxes, Acids, Sequestrants and framework materials, preferably polycarboxylates and / or zeolites Polymers, preferably polyester, polyamide, polyglycol, polyurethane, polysaccharide, polypeptide and / or other biopolymers and Water.
16. Detergent according to any of the preceding claims, wherein the detergent is substantially free, preferably completely free, of: Abrasive material, preferably marble dust, chalk, clay and / or pumice, and / or Adsorbent, preferably wood, cellulose and / or plastic flour and / or - Bitter substances and / or - Biocides and / or - Corrosion inhibitors and / or - Oils, fats and / or waxes and / or - Optical brighteners and / or Discoloration inhibitors, preferably polyvinylpyrrolidone, polyvinylpyrrolidone-polyvinylimidazole and / or polyvinylpyridine N-oxide.
17. A method for producing a detergent according to any one of the preceding claims 1 to 16, comprising the following steps: S1) Manufacture or provision of a first component comprising one or more surfactant compounds, each selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 17 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound, and R 1 and / or R 2 Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant; S2) Manufacture or provision of a second component comprising one or more surfactant compounds, each selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 10, preferably with 7 to 9, carbon atoms, which forms the hydrophobic part of the respective surfactant compound and R 1 and / or R 2 Residues are those that form or comprise a hydrophilic molecular component of the respective surfactant. 53) optional: Manufacturing or supplying one or more further components, comprising further additives; 54) Contactful mixing of each quantity of the components produced and / or provided in steps S1) and S2), preferably those produced and / or provided in steps S1), S2) and S3), so that the detergent results.
18. The method of claim 17, wherein the preparation or provision of the first component in step S1) comprises the preparation of one, two or more surfactant compounds, each in a method comprising the following steps: S1-1 a) Manufacture or supply of a plant or part of a plant, wherein the plant is selected from the group of plants consisting of: Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof; S1-2a) Production of a vegetable oil from the plant produced or provided in step S1-1 a) or from the part of a plant produced or provided in step S1-1 a); so that a vegetable oil results; S1-3a) Production of a surfactant compound from the vegetable oil resulting from step S1-2a), such that a surfactant compound results.
19. A method according to any one of the preceding claims 17 to 18, wherein the preparation or provision of the second component in step S2) comprises the preparation of one or more surfactant compounds, each in a method comprising the following steps: S2-1 a) Manufacture or supply of a plant or part of a plant, wherein the plant is selected from: Hemp, hazelnut, thistle, peanut, tiger nut, jojoba, Iberian dragonhead, coconut palm, camelina, flax, almond, poppy, evening primrose, olive, oil palm, oilseed radish, oil rocket, pecan, pistachio, rapeseed, castor, turnip, safflower, black cumin, sesame, sunflower, soy, walnut, grape and combinations thereof; S2-2a) Producing a vegetable oil from the plant produced or provided in step S2-1 a) or from the part of a plant produced or provided in step S2-1 a); such that a vegetable oil results; S2-3a) Carrying out a reaction, preferably Performing a metathesis reaction so that metathesis products result; and / or Performing an oxidative cleavage reaction, preferably an ozonolysis reaction, such that oxidative cleavage products, preferably ozonolysis products, result; S2-4a) Preparation of a surfactant compound from at least one of the metathesis products resulting in step S2-3a) or at least one of the oxidative cleavage products resulting in step S2-3a), preferably ozonolysis products, such that a surfactant compound results.
20. A method according to any one of the preceding claims 17 to 19, wherein, as a third, fourth, fifth, sixth or further component in step S3), one, two, three, four or more additives are produced or provided, preferably one, two, three, four or more additives which are independently selected from the group consisting of: Abrasive materials, preferably marble dust, chalk, clay and / or pumice, Alkalis, preferably ammonia, sodium carbonate, sodium hydroxide and / or potassium hydroxide, Alcohols, preferably ethanol, propanol and / or butanol, Bitter substances, Complexing agents, preferably citrates, phosphates, phosphonates, carboxylates, ethylenedinitriletetraacetic acid (EDTA) and / or nitrilotriacetic acid (NTA), Fragrances, Enzymes, preferably amylases, cellulases, lipases and / or proteases, Dyes, Preservatives, Solvents, Oils, fats and / or waxes, Acids, Polycarboxylates, Polymers, preferably polystyrene, polyacrylate, polyurethane and / or polyethylene, and Water; and wherein these additives are present during the contact mixing in step S4) and are part of the detergent resulting in step S4).
21. Method for treating, preferably cleaning, with a detergent according to any one of claims 1 to 16, comprising the following steps: V1) Manufacturing or providing, preferably manufacturing or providing in a process according to one of claims 17 to 20, a detergent according to one of claims 1 to 16; V2) Providing a surface to be treated, preferably a surface to be cleaned; preferably selected from: glass, ceramic, plastic, metal, wood, stone and paint; V3) Contact the surface to be cleaned, provided in step V2), with the detergent produced or provided in step V1); V4) Treating, preferably cleaning, the surface using the detergent, so that a treated surface results, preferably so that a cleaned surface results.
22. The method of claim 21, further comprising one, two or all of the following steps: V1-1) Before contacting the surface to be treated provided in step V2) with the detergent prepared or provided in step V1): contact mixing of the detergent prepared or provided in step V1) with water, resulting in an aqueous detergent solution; wherein, upon contact of the surface to be treated provided in step V2) with the detergent prepared or provided in step V1), the detergent prepared or provided in step V1) is present as part of the aqueous detergent solution resulting in step V1-1); and / or V4-1) wherein the treatment, preferably the cleaning, of the surface using the detergent in step V4) is carried out with mechanical assistance, preferably with mechanical assistance by a washing machine, a hand, a rag, a brush, a jet of water and / or a jet of an aqueous detergent solution; and / or V5) wherein the treated surface resulting from step V4), preferably a cleaned surface, is rinsed with water, resulting in a rinsed treated surface, preferably a rinsed cleaned surface; and / or V6) wherein the treated surface resulting from step V4), preferably a cleaned surface, and / or the rinsed treated surface resulting from step V5), preferably a rinsed cleaned surface, is dried, so that a dried treated surface, preferably a dried cleaned surface, results.
23. Use of a method according to any one of the preceding claims 17 to 20 for the production of a detergent according to any one of claims 1 to 16.
24. Use of a method according to one of the preceding claims 21 or 22, for treating, preferably cleaning, a surface, preferably a surface selected from: glass, ceramic, plastic, metal, wood, stone and lacquer.
25. Use of a detergent according to any one of claims 1 to 16, for the treatment, preferably cleaning, of a surface, preferably a surface selected from: glass, ceramic, plastic, metal, wood, stone and lacquer.
26. Kit includes: K1) in a first container: surfactant compound selected from the group consisting of: i) Salts of fatty acids with the general formula RC(O)OM, where M is an alkali metal cation, an ammonium ion, or a profaned primary, secondary, or tertiary amine compound; ii) Fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 17 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound and R 1 and / or R 2 residues are those that form or comprise a hydrophilic molecular fraction of the respective surfactant; and wherein the surfactant compounds present in the first container have a proportion of hydrocarbon residues R with a total number of 17 to 23 C atoms in the range of over 50 wt.%, based on the total mass of the hydrocarbon residues R present in the first container; and wherein preferably the surfactant compounds present in the first container have a ratio of in the total mass of their hydrocarbon residues R 14 carbon atoms to 12exhibit C atoms, which corresponds to an age of the total mass of the hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and / or in the total mass of their hydrophilic residues a ratio of 1 4 carbon atoms to 12 exhibit C atoms corresponding to an age of the total mass of the hydrophilic residues of less than 300 years since carbon dioxide fixation; and / or exhibit a ratio of in the total mass of the surfactant compound of 14 carbon atoms to 12 exhibiting C atoms, which corresponds to an age of less than 300 years for the total mass of the surfactant compounds present in the first container since carbon dioxide fixation; and K2) in a second container: surfactant compound selected from the group consisting of: i) salts of fatty acids with the general formula RC(O)OM where M is an alkali metal cation, an ammonium ion or a profaned primary, secondary or tertiary amine compound; ii) fatty acid esters with the general formula RC(O)OR 1 iii) Ethers of fatty alcohols with the general formula R-CH2-OR 1 iv) Fatty acid amides with the general formula RC(O)NR 1 R 2 ; each independently of the other R is a saturated or unsaturated, branched or unbranched, aliphatic hydrocarbon residue with 7 to 23 carbon atoms, which forms one or the hydrophobic part of the respective surfactant compound and R 1 and / or R 2residues are those that form or comprise a hydrophilic molecular fraction of the respective surfactant; and wherein the surfactant compounds present in the second container have a proportion of hydrocarbon residues R with a total number of 7 to 10 C atoms, preferably 7 to 9 C atoms, of more than 30 wt.%, based on the total mass of the hydrocarbon residues R present in the second container, and wherein preferably the surfactant compounds present in the second container have a ratio of in the total mass of their hydrocarbon residues R 14 carbon atoms to 12 exhibit C atoms corresponding to an age of the total mass of the hydrocarbon residues R of less than 300 years since carbon dioxide fixation; and / or a ratio of 1 in the total mass of their hydrophilic residues 4 carbon atoms to 12exhibit C atoms corresponding to an age of the total mass of the hydrophilic residues of less than 300 years since carbon dioxide fixation; and / or exhibit a ratio of in the total mass of the surfactant compound of 14 carbon atoms to 12 exhibit C atoms, which corresponds to an age of less than 300 years since carbon dioxide fixation of the total mass of surfactant compounds present in the second container.
27. Use of a kit according to claim 26 for the production of a detergent, preferably for the production of a detergent according to any one of claims 1 to 16.
28. Use of a kit according to claim 26, in a process for producing a detergent, preferably in a process for producing a detergent according to any one of the preceding claims 17 to 20; particularly preferably in a process according to any one of claims 17 to 20 for producing a detergent according to any one of claims 1 to 16.