Device and process for treating durene waste liquid
Through the designed equipment and process, the steps of flotation, sedimentation, ozone oxidation, anaerobic reaction and activated carbon adsorption are adopted to solve the safety and efficiency problems of tetramethylbenzene waste liquid treatment, and realize the efficient purification and safe discharge of waste liquid.
Patent Information
- Application Number
- CN202510674131.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2025-05-23
- Publication Date
- 2025-09-26
- Estimated Expiration
- 2045-05-23
AI Technical Summary
Existing technologies are unable to efficiently and safely treat durene waste liquid, resulting in environmental pollution and health risks.
A device and process for treating durene wastewater were designed, including a fixed support frame, an adsorption treatment body, a reaction tank, and a cleaning body. Through flotation, sedimentation, ozone oxidation, anaerobic reaction, and activated sludge method, combined with activated carbon adsorption and ultraviolet disinfection, deep treatment of the wastewater was achieved.
The waste liquid is fully pretreated and deeply purified, large particles of impurities and oil are removed, and the activated carbon particles are easy to replace and collect, ensuring that the effluent meets the standards, degrading organic matter and killing pathogenic microorganisms.
Smart Images

Figure CN120192062B_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of durene waste liquid treatment, in particular to a device and process for treating durene waste liquid. Background Art
[0002] Durene waste liquid is a waste liquid containing durene (1,2,4,5-tetramethylbenzene) generated during the chemical production process. It is a hazardous waste and needs to be strictly handled to avoid environmental pollution and health risks. However, the existing process cannot fully and safely treat the durene waste liquid, and it is not possible to use a device combined with a reasonable treatment process to efficiently and safely treat the durene waste liquid. Therefore, a device and process are needed to improve the above problems. Summary of the Invention
[0003] In view of the problems in the prior art, the present invention provides a device and process for treating durene waste liquid.
[0004] The technical solution adopted by the present invention to solve its technical problems is: a device and process for treating tetramethylbenzene waste liquid, including a fixed support stand, an adsorption treatment body, a fixed support base, a reaction tank, a discharge bucket and a cleaning body, the reaction tank is fixedly connected to the inside of the fixed support base, the fixed support stand is evenly fixedly installed on the upper parts of both sides of the fixed support base, the adsorption treatment body is arranged at the upper end of the fixed support stand, the cleaning body is fixedly connected to the upper end of the fixed support base, and the cleaning body is located above the adsorption treatment body, and the discharge bucket is arranged at the outer end of the cleaning body.
[0005] Specifically, the cleaning body includes a cleaning tank, a track plate, a first electric push rod, a movable adjustment frame, a solenoid valve, a discharge pipe, a suction pipe, an extraction hose, a lifting adjustment plate and a second electric push rod. The solenoid valve is evenly fixedly connected to the bottom end of the cleaning tank, the discharge pipe is fixedly connected to the bottom end of the solenoid valve, the track plate is fixedly installed on both sides of the cleaning tank by bolts, the two ends of the movable adjustment frame are slidably clamped in the inside of the track plate, the first electric push rod is fixedly installed on the upper end of the track plate, and the front end of the first electric push rod is fixedly connected to the end head of the movable adjustment frame, the second electric push rod is evenly fixedly installed on the movable adjustment frame, the lifting adjustment plate is fixedly connected to the bottom end of the second electric push rod, the suction pipe is evenly fixedly arranged on the bottom end of the lifting adjustment plate, and the extraction hose is evenly fixedly connected to the outer end of the lifting adjustment plate.
[0006] Specifically, a cleaning part is provided inside the cleaning tank, and the cleaning part includes a lifting plate, a motor, a support bracket, a third electric push rod and a screening and filtering frame. The lifting plate is fixedly connected to the middle part of the side end of the screening and filtering frame, and the support bracket is distributed on the outer side of the upper end of the lifting plate. The motor is fixedly installed on the outer end of the support bracket. The driving end of the motor is fixedly connected to the upper end of the lifting plate through a driving rod, and the upper end of the third electric push rod is fixedly connected to the bottom end of the support bracket.
[0007] Specifically, the adsorption processing body includes a fourth electric push rod, a track cross plate, a movable fixed plate, an adsorption filter cartridge, activated carbon particles, a limiting frame, an emptying hole, a first pulling handle and a baffle. The track cross plate is symmetrically distributed, and both sides of the movable fixed plate are slidably clamped in the interior of the track cross plate. The adsorption filter cartridge is evenly fixedly mounted on the movable fixed plate, and the activated carbon particles are evenly placed in the interior of the adsorption filter cartridge. The fourth electric push rod is fixedly mounted in the middle of the outer end of the track cross plate, and the front end of the fourth electric push rod is fixedly connected to the side end of the movable fixed plate. The limiting frame is fixedly connected to the bottom end of the adsorption filter cartridge, and the baffle is slidably clamped in the interior of the limiting frame. The emptying hole is opened in the middle of the baffle, and the first pulling handle is fixedly connected to the middle of the outer end of the baffle.
[0008] Specifically, the discharge hopper is tilted at 45 degrees, the discharge hopper is fixedly connected to the outer end of the cleaning tank, and the discharge pipe is located directly above the adsorption filter cartridge.
[0009] Specifically, the track cross plate is fixedly connected to the upper end of the fixed support base, the cleaning tank is fixedly connected to the upper end of the fixed support stand, and the reaction tank is located below the limit frame.
[0010] Specifically, the screening and filtering frame is located inside the cleaning tank, and the third electric push rod is fixedly installed in the middle of the outer end of the cleaning tank.
[0011] Specifically, an angle sensor is provided on the inner side of the upper end of the lifting plate.
[0012] Specifically, an auxiliary discharge part is provided inside the side of the fixed support base facing away from the reaction tank, and the auxiliary discharge part includes a side panel, a discharge plate, a baffle adjustment plate, a second pull-out handle and an auxiliary discharge groove. The side panels are fixedly connected to both sides of the discharge plate, and the auxiliary discharge groove is opened through the top of the discharge plate. The baffle adjustment plate is slidably engaged inside the bottom end of the discharge plate, and the baffle adjustment plate is slidably engaged inside the auxiliary discharge groove, and the second pull-out handle is fixedly connected to the middle of the outer end of the baffle adjustment plate.
[0013] A process for processing durene waste liquid comprises the following steps:
[0014] S1. Collect the durene waste liquid to avoid mixing with other wastewater to prevent the reaction from generating more complex pollutants. Use acid and alkali to adjust the pH of the waste liquid to 6-9 to reduce the corrosive and toxic effects in subsequent treatment. If the waste liquid contains oil or suspended matter, use flotation and sedimentation methods to remove it;
[0015] S2, under acidic conditions of pH 3, add Fe 2+ and H2O2, generating strong oxidizing hydroxyl radicals, decomposing durene into small molecular organic matter and H2O, Fe 2+ The concentration is 0.1-1.0 g / L, the amount of H2O2 added is adjusted according to the COD value, and the reaction time is 1-2 hours;
[0016] S3. Utilize the strong oxidizing property of ozone to directly decompose durene, improve efficiency through catalytic oxidation, control ozone dosage, use 10-50 g / m³ waste liquid and 30-60 minutes contact time;
[0017] S4. Under high temperature and high pressure greater than 374°C and greater than 22.1 MPa, the organic matter in the waste liquid is completely reacted with oxygen to generate CO2 and H2O, and the waste liquid after advanced oxidation is introduced into an anaerobic reactor, where anaerobic microorganisms are used to degrade small molecular organic matter to produce biogas. The temperature is 35-40°C, the pH is 6.8-7.2, and the residence time is 24-48 hours;
[0018] S5. Use activated sludge or biofilm methods to further degrade remaining organic matter. Use nanofiltration membranes to remove dissolved organic matter and salts from the wastewater. Use activated carbon to adsorb residual trace organic matter to ensure that the effluent meets the standards. Use ultraviolet light and sodium hypochlorite for disinfection to kill pathogenic microorganisms in the wastewater.
[0019] Beneficial effects of the present invention:
[0020] 1. The present invention can fully pre-treat the tetramethylbenzene waste liquid through the cleaning body set up, and can clean and discharge large particles of impurities and oil in the waste liquid. The adsorption treatment body set up can conveniently adsorb and fully remove impurities from the waste liquid, making it convenient for the waste liquid to be deeply reprocessed.
[0021] 2. During the use of the present invention, the impurities and sundries filtered out are convenient to clean and discharge, and the activated carbon particles discharged from the bottom of the limit frame can be guided for centralized transportation and treatment through the side plates and discharge plates, which makes it convenient to clean and replace the activated carbon particles inside the adsorption filter cartridge, so that the discharged activated carbon particles can be conveniently cleaned and collected in a centralized manner, and after the baffle adjustment plate is pulled out by the second pulling handle, the activated carbon particles can fall from the inside of the auxiliary discharge trough, so that the collection frame provided below the auxiliary discharge trough can facilitate the collection and treatment of the activated carbon particles. BRIEF DESCRIPTION OF THE DRAWINGS
[0022] The present invention will be further described below with reference to the accompanying drawings and examples.
[0023] Figure 1 This is a schematic diagram of the three-dimensional structure of the main body of the present invention from the front perspective;
[0024] Figure 2 This is a schematic diagram of the side-view three-dimensional structure of the main body of the present invention;
[0025] Figure 3 This is a schematic diagram of the cleaning body structure of the present invention;
[0026] Figure 4 This is a schematic structural diagram of the cleaning unit in the present invention;
[0027] Figure 5 Schematic diagram of the main structure of the adsorption treatment in the present invention;
[0028] Figure 6 It is a side perspective schematic diagram of the adsorption treatment body in the present invention;
[0029] Figure 7 This is a schematic structural diagram of the auxiliary discharge part of the present invention;
[0030] Figure 8 It is a schematic side view of the three-dimensional structure of the auxiliary discharge part in the present invention.
[0031] In the figure: 1-fixed support frame, 2-adsorption treatment body, 3-auxiliary discharge part, 4-fixed support base, 5-reaction tank, 6-discharge bucket, 7-cleaning body, 8-cleaning tank, 9-track plate, 10-first electric push rod, 11-movable adjustment frame, 12-solenoid valve, 13-discharge pipe, 14-suction pipe, 15-extraction hose, 16-lifting adjustment plate, 17-second electric push rod, 18-cleaning part, 19-lifting plate, 20-angle sensor Sensor, 21-motor, 22-support bracket, 23-third electric push rod, 24-screening filter frame, 25-fourth electric push rod, 26-track cross plate, 27-movable fixed plate, 28-adsorption filter cartridge, 29-activated carbon particles, 30-limiting frame, 31-emptying hole, 32-first pull-out handle, 33-partition plate, 34-side plate, 35-discharge plate, 36-partition adjustment plate, 37-second pull-out handle, 38-auxiliary discharge trough. DETAILED DESCRIPTION
[0032] In order to enable those skilled in the art to better understand the present invention, the following will clearly and completely describe the technical solutions in the embodiments of the present invention in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments in the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts should fall within the scope of protection of this application.
[0033] The present invention will be further described below with reference to the accompanying drawings.
[0034] Example 1, as Figure 1 、 Figure 2 and Figure 3As shown, a device and process for treating tetramethylbenzene waste liquid of the present invention include a fixed support stand 1, an adsorption treatment body 2, a fixed support base 4, a reaction tank 5, a discharge bucket 6 and a cleaning body 7, the reaction tank 5 is fixedly connected to the inside of the fixed support base 4, the fixed support stand 1 is evenly fixedly installed on the upper parts of both sides of the fixed support base 4, the adsorption treatment body 2 is arranged at the upper end of the fixed support stand 1, the cleaning body 7 is fixedly connected to the upper end of the fixed support base 4, and the cleaning body 7 is located above the adsorption treatment body 2, the discharge bucket 6 is arranged at the outer end of the cleaning body 7, the cleaning body 7 includes a cleaning tank 8, a track plate 9, a first electric push rod 10, a movable adjustment frame 11, a solenoid valve 12, a discharge pipe 13, a suction pipe 14, an extraction hose 15, a lifting adjustment plate 16 and a second electric push rod 17, the solenoid valve 12 is evenly fixedly connected to the bottom end of the cleaning tank 8, the discharge pipe 13 is fixedly connected to the bottom end of the solenoid valve 12, the track plate 9 is fixedly installed on both sides of the cleaning tank 8 by bolts, and the two ends of the mobile adjustment frame 11 are slidably clamped in the interior of the track plate 9, the first electric push rod 10 is fixedly installed on the upper end of the track plate 9, and the front end of the first electric push rod 10 is fixedly connected to the end of the mobile adjustment frame 11, the second electric push rod 17 is evenly fixedly installed on the mobile adjustment frame 11, the lifting adjustment plate 16 is fixedly connected to the bottom end of the second electric push rod 17, the suction pipe 14 is evenly fixedly set at the bottom end of the lifting adjustment plate 16, and the extraction hose 15 is evenly fixedly connected to the outer end of the lifting adjustment plate 16. Starting the first electric push rod 10 makes the mobile adjustment frame 11 slide along the track plate 9, so that each suction pipe 14 moves to the liquid surface, and then starting the second electric push rod 17 makes the suction pipe 14 move downward and insert it into the specified height of the liquid surface, and connect it to the external extraction pump through the extraction hose 15 so that each suction pipe 14 can slowly extract the oil layer floating on the liquid surface and discharge it.
[0035] like Figure 3 and Figure 4As shown, a cleaning portion 18 is provided inside the cleaning tank 8, and the cleaning portion 18 includes a lifting plate 19, a motor 21, a support bracket 22, a third electric push rod 23 and a screening and filtering frame 24. The lifting plate 19 is fixedly connected to the middle of the side end of the screening and filtering frame 24, and the support bracket 22 is distributed on the outer side of the upper end of the lifting plate 19. The motor 21 is fixedly installed on the outer end of the support bracket 22. The driving end of the motor 21 is fixedly connected to the upper end of the lifting plate 19 through the driving rod. The upper end of the third electric push rod 23 is fixedly connected to the support bracket 22. The bottom end of the bracket 22 is fixedly connected. Starting the third electric push rod 23 can lift the support bracket 22, thereby driving the motor 21, the lifting plate 19 and the screening and filtering frame 24 to rise, so that the screening and filtering frame 24 is lifted and discharged from the inside of the cleaning tank 8, and then starting the motor 21 to drive the lifting plate 19 to rotate a specified angle, so that the screening and filtering frame 24 is tilted, so that the larger impurities and debris intercepted and filtered inside the screening and filtering frame 24 slide from the inside of the screening and filtering frame 24 and are discharged to the inside of the discharge bucket 6.
[0036] like Figure 5 and Figure 6 As shown, the adsorption processing body 2 includes a fourth electric push rod 25, a track cross plate 26, a movable fixed plate 27, an adsorption filter cartridge 28, activated carbon particles 29, a limit frame 30, an emptying hole 31, a first pull-out handle 32 and a baffle 33. The track cross plate 26 is symmetrically distributed, and both sides of the movable fixed plate 27 are slidably connected to the inside of the track cross plate 26. The adsorption filter cartridge 28 is evenly fixed on the movable fixed plate 27, and the activated carbon particles 29 are evenly placed inside the adsorption filter cartridge 28. The fourth electric push rod 25 is fixedly installed at the middle of the outer end of the track cross plate 26, and the front end of the fourth electric push rod 25 is fixed to the side end of the movable fixed plate 27. The fixed connection is that the limit frame 30 is fixedly connected to the bottom end of the adsorption filter cylinder 28, the baffle plate 33 is slidably engaged with the inside of the limit frame 30, the emptying hole 31 is opened in the middle of the baffle plate 33, and the first pulling handle 32 is fixedly connected to the middle of the outer end of the baffle plate 33. The fourth electric push rod 25 is started to drive the movable fixed plate 27 to move along the adsorption filter cylinder 28, so that each adsorption filter cylinder 28 moves from the top of the reaction tank 5 to the outside, and then the baffle plate 33 is pulled out from the inside of the limit frame 30, so that the activated carbon particles 29 inside the adsorption filter cylinder 28 are discharged from the limit frame 30, so that the activated carbon particles 29 are easy to replace.
[0037] The discharge bucket 6 is set at a 45° tilt and is fixedly connected to the outer end of the cleaning tank 8. The discharge pipe 13 is located directly above the adsorption filter cylinder 28. The track cross plate 26 is fixedly connected to the upper end of the fixed support base 4. The cleaning tank 8 is fixedly connected to the upper end of the fixed support stand 1. The reaction tank 5 is located below the limit frame 30. The screening and filtration frame 24 is located inside the cleaning tank 8. The third electric push rod 23 is fixedly installed in the middle of the outer end of the cleaning tank 8. An angle sensor 20 is provided on the inner side of the upper end of the lifting plate 19, which can detect the angle of rotation.
[0038] A process for processing durene waste liquid comprises the following steps:
[0039] S1. Collect the durene waste liquid to avoid mixing with other wastewater to prevent the reaction from generating more complex pollutants. Use acid and alkali to adjust the pH of the waste liquid to 6-9 to reduce the corrosive and toxic effects in subsequent treatment. If the waste liquid contains oil or suspended matter, use flotation and sedimentation methods to remove it;
[0040] S2, under acidic conditions of pH 3, add Fe 2+ and H2O2, generating strong oxidizing hydroxyl radicals, decomposing durene into small molecular organic matter and H2O, Fe 2+ The concentration is 0.1-1.0 g / L, the amount of H2O2 added is adjusted according to the COD value, and the reaction time is 1-2 hours;
[0041] S3. Utilize the strong oxidizing property of ozone to directly decompose durene, improve efficiency through catalytic oxidation, control ozone dosage, use 10-50 g / m³ waste liquid and 30-60 minutes contact time;
[0042] S4. Under high temperature and high pressure greater than 374°C and greater than 22.1 MPa, the organic matter in the waste liquid is completely reacted with oxygen to generate CO2 and H2O, and the waste liquid after advanced oxidation is introduced into an anaerobic reactor, where anaerobic microorganisms are used to degrade small molecular organic matter to produce biogas. The temperature is 35-40°C, the pH is 6.8-7.2, and the residence time is 24-48 hours;
[0043] S5. Use activated sludge or biofilm methods to further degrade remaining organic matter. Use nanofiltration membranes to remove dissolved organic matter and salts from the wastewater. Use activated carbon to adsorb residual trace organic matter to ensure that the effluent meets the standards. Use ultraviolet light and sodium hypochlorite for disinfection to kill pathogenic microorganisms in the wastewater.
[0044] The working principle of Example 1 is as follows: first, pour the durene waste liquid into the cleaning tank 8 and let it stand for a specified time. At this time, the oil in the waste liquid floats on the top of the waste liquid. Then, start the first electric push rod 10 to make the movable adjustment frame 11 slide along the track plate 9, so that each suction pipe 14 moves to the liquid surface. Then, start the second electric push rod 17 to make the suction pipe 14 move downward and insert it into the liquid surface at a specified height. Through the extraction hose 15, it is connected to the external extraction pump so that each suction pipe 14 can slowly extract the oil layer floating on the liquid surface and discharge it. After the liquid is discharged, the third electric push rod 23 is started to lift the support bracket 22, thereby driving the motor 21, the lifting plate 19 and the screening and filtering frame 24 to rise, so that the screening and filtering frame 24 is lifted and discharged from the inside of the cleaning tank 8, and then the motor 21 is started to drive the lifting plate 19 to rotate a specified angle, so that the screening and filtering frame 24 is tilted, so that the larger impurities and debris intercepted and filtered inside the screening and filtering frame 24 slide from the inside of the screening and filtering frame 24 and are discharged into the inside of the discharge hopper 6, and are conveniently collected and processed after being guided by the discharge hopper 6;
[0045] After the pretreatment of the tetramethylbenzene waste liquid, the solenoid valve 12 is started to slowly discharge the tetramethylbenzene waste liquid from the inside of the discharge pipe 13 to the inside of the adsorption filter cartridge 28, so that the waste liquid flows slowly inside the adsorption filter cartridge 28 and stays inside the adsorption filter cartridge 28 for a sufficient time. The activated carbon particles 29 inside the adsorption filter cartridge 28 can fully adsorb and treat the waste liquid, and then the adsorbed liquid is discharged from the limit frame 30 to the inside of the reaction tank 5, and the pH of the waste liquid is adjusted to 6-9 using acid and alkali. When it is necessary to replace the activated carbon particles 29 inside the adsorption filter cartridge 28, the fourth electric push rod 25 is started to drive the movable fixed plate 27 to move along the adsorption filter cartridge 28, so that each adsorption filter cartridge 28 moves from the top to the outside of the reaction tank 5, and then the baffle plate 33 is pulled and discharged from the inside of the limit frame 30, so that the activated carbon particles 29 inside the adsorption filter cartridge 28 are discharged from the limit frame 30, making it easy to replace the activated carbon particles 29.
[0046] Example 2, based on Example 1, Figure 1 、 Figure 7 and Figure 8 As shown, an auxiliary discharge part 3 is provided inside the fixed support base 4 on the side facing away from the reaction tank 5. The auxiliary discharge part 3 includes a side panel 34, a discharge plate 35, a baffle adjustment plate 36, a second pull-out handle 37 and an auxiliary discharge groove 38. The side panels 34 are fixedly connected to both sides of the discharge plate 35. The auxiliary discharge groove 38 is opened through the top of the discharge plate 35. The baffle adjustment plate 36 is slidably engaged inside the bottom end of the discharge plate 35, and the baffle adjustment plate 36 is slidably engaged inside the auxiliary discharge groove 38. The second pull-out handle 37 is fixedly connected to the middle of the outer end of the baffle adjustment plate 36.
[0047] When implementing this embodiment, the side plates 34 and discharge plates 35 are provided to guide the activated carbon particles 29 discharged from the bottom of the limit frame 30 for centralized transportation and processing, so that the activated carbon particles 29 inside the adsorption filter cartridge 28 can be cleaned and replaced conveniently, and the discharged activated carbon particles 29 can be easily cleaned and centrally collected. Moreover, after the baffle adjustment plate 36 is pulled out by the second pull-out handle 37, the activated carbon particles 29 can fall from the inside of the auxiliary discharge trough 38, so that the collection frame provided below the auxiliary discharge trough 38 can facilitate the collection and processing of the activated carbon particles 29.
[0048] While embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions, and variations may be made to these embodiments without departing from the principles and spirit of the invention, and that the scope of the invention is defined by the appended claims and their equivalents.
Claims
1. A device for treating durene waste liquid, comprising a fixed support stand (1), an adsorption treatment body (2), a fixed support base (4), a reaction tank (5), a discharge hopper (6) and a cleaning body (7), characterized in that: The reaction tank (5) is fixedly connected to the inside of the fixed support base (4), the fixed support stand (1) is evenly fixedly installed on the upper parts of both sides of the fixed support base (4), the adsorption treatment body (2) is arranged at the upper end of the fixed support stand (1), the cleaning body (7) is fixedly connected to the upper end of the fixed support base (4), and the cleaning body (7) is located above the adsorption treatment body (2), the discharge hopper (6) is arranged at the outer end of the cleaning body (7), and the cleaning body (7) includes a cleaning tank (8), a track plate (9), a first electric push rod (10), a movable adjustment frame (11), a solenoid valve (12), a discharge pipe (13), a suction pipe (14), an extraction hose (1 5), a lifting adjustment plate (16) and a second electric push rod (17), the solenoid valve (12) is evenly fixedly connected to the bottom end of the cleaning tank (8), the discharge pipe (13) is fixedly connected to the bottom end of the solenoid valve (12), the track plate (9) is fixedly mounted on both sides of the cleaning tank (8) by bolts, the two ends of the movable adjustment frame (11) are slidably clamped inside the track plate (9), the first electric push rod (10) is fixedly mounted on the upper end of the track plate (9), and the front end of the first electric push rod (10) is fixedly connected to the end of the movable adjustment frame (11), the second electric push rod (17) is evenly fixedly mounted on the movable adjustment frame (11), the lifting adjustment plate (16) is fixed The suction pipe (14) is evenly fixedly arranged at the bottom end of the lifting adjustment plate (16), and the extraction hose (15) is evenly fixedly connected to the outer end of the lifting adjustment plate (16). A cleaning part (18) is provided inside the cleaning tank (8), and the cleaning part (18) includes a lifting plate (19), a motor (21), a support bracket (22), a third electric push rod (23) and a screening and filtering frame (24). The lifting plate (19) is fixedly connected to the middle part of the side end of the screening and filtering frame (24), the support bracket (22) is distributed on the outer side of the upper end of the lifting plate (19), and the motor (21) is fixedly mounted on the outer end of the support bracket (22). The driving end of the motor (21) is fixedly connected to the upper end of the lifting plate (19) through a driving rod, the upper end of the third electric push rod (23) is fixedly connected to the bottom end of the support bracket (22), and the adsorption processing body (2) includes a fourth electric push rod (25), a track cross plate (26), a movable fixed plate (27), an adsorption filter cartridge (28), activated carbon particles (29), a limit frame (30), an emptying hole (31), a first pull-out handle (32) and a baffle (33), the track cross plate (26) is symmetrically distributed, and both sides of the movable fixed plate (27) are slidably connected to the inside of the track cross plate (26), and the adsorption filter cartridge (28) is evenly fixedly mounted on the movable fixed plate (27).The activated carbon particles (29) are evenly placed inside the adsorption filter cartridge (28), the fourth electric push rod (25) is fixedly mounted on the middle of the outer end of the track cross plate (26), the front end of the fourth electric push rod (25) is fixedly connected to the side end of the movable fixed plate (27), the limit frame (30) is fixedly connected to the bottom end of the adsorption filter cartridge (28), the baffle plate (33) is slidably engaged with the inside of the limit frame (30), the emptying hole (31) is opened in the middle of the baffle plate (33), and the first pull handle (32) is fixedly connected to the middle of the outer end of the baffle plate (33).
2. A device for processing durene waste liquid according to claim 1, characterized in that: The discharge hopper (6) is tilted at 45 degrees, and the discharge hopper (6) is fixedly connected to the outer end of the cleaning tank (8). The discharge pipe (13) is located directly above the adsorption filter cartridge (28).
3. A device for processing durene waste liquid according to claim 2, characterized in that: The track cross plate (26) is fixedly connected to the upper end of the fixed support base (4), the cleaning tank (8) is fixedly connected to the upper end of the fixed support stand (1), and the reaction tank (5) is located below the limiting frame (30).
4. A device for processing durene waste liquid according to claim 3, characterized in that: The screening and filtering frame (24) is located inside the cleaning tank (8), and the third electric push rod (23) is fixedly mounted at the middle of the outer end of the cleaning tank (8).
5. A device for processing durene waste liquid according to claim 4, characterized in that: An angle sensor (20) is provided on the inner side of the upper end of the lifting plate (19).
6. A device for processing durene waste liquid according to claim 5, characterized in that: An auxiliary discharge portion (3) is provided inside the fixed support base (4) on a side facing away from the reaction tank (5), and the auxiliary discharge portion (3) includes a side plate (34), a discharge plate (35), a baffle adjustment plate (36), a second pull-out handle (37) and an auxiliary discharge groove (38), wherein the side plate (34) is fixedly connected to both sides of the discharge plate (35), the auxiliary discharge groove (38) is opened through the top of the discharge plate (35), the baffle adjustment plate (36) is slidably engaged inside the bottom end of the discharge plate (35), and the baffle adjustment plate (36) is slidably engaged inside the auxiliary discharge groove (38), and the second pull-out handle (37) is fixedly connected to the middle of the outer end of the baffle adjustment plate (36).
7. A process for treating durene waste liquid, suitable for the device for treating durene waste liquid according to claim 6, characterized in that: It includes the following steps: S1. Collect the durene waste liquid to avoid mixing with other wastewater to prevent the reaction from generating more complex pollutants. Use acid and alkali to adjust the pH of the waste liquid to 6-9 to reduce the corrosive and toxic effects in subsequent treatment. If the waste liquid contains oil or suspended matter, use flotation and sedimentation to remove it; S2. Under acidic conditions of pH 3, Fe²⁺ and H2O2 are added to generate strongly oxidizing hydroxyl radicals, which decompose durene into small molecular organic matter and H2O. The Fe²⁺ concentration is 0.1-1.0 g / L, and the amount of H2O2 added is adjusted according to the COD value. The reaction time is 1-2 hours. S3. Utilize the strong oxidizing property of ozone to directly decompose durene, improve efficiency through catalytic oxidation, control ozone dosage, use 10-50 g / m³ waste liquid and 30-60 minutes contact time; S4, under high temperature and high pressure greater than 374°C and greater than 22.1 MPa, allowing the organic matter in the waste liquid to completely react with oxygen to generate CO2 and H2O, introducing the waste liquid after advanced oxidation into an anaerobic reactor, utilizing anaerobic microorganisms to degrade small molecular organic matter to generate biogas, at a temperature of 35-40°C, a pH of 6.8-7.2, and a residence time of 24-48 hours; S5. Use activated sludge or biofilm methods to further degrade remaining organic matter. Use nanofiltration membranes to remove dissolved organic matter and salts from the wastewater. Use activated carbon to adsorb residual trace organic matter to ensure that the effluent meets the standards. Use ultraviolet light and sodium hypochlorite for disinfection to kill pathogenic microorganisms in the wastewater.
Citation Information
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