A cobalt-iron layered double hydroxide electrode and a preparation method and application thereof

By preparing cobalt-iron layered double hydroxide electrodes through electrochemical methods, the performance deficiencies of cathode materials in aqueous zinc-ion batteries were solved, achieving high-capacity and low-cost electrochemical performance enhancement.

CN122417754APending Publication Date: 2026-07-17HAINAN NORMAL UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing aqueous zinc-ion battery cathode materials suffer from problems such as low discharge voltage, poor cycle stability, narrow electrochemical window, and insufficient energy density. Furthermore, the high cost and limited reserves of Co and Ni restrict their large-scale application.

Method used

Graphene sheets were prepared by electrochemical exfoliation using a three-electrode system, and cobalt-iron layered double hydroxide electrodes were prepared by electrochemical deposition and activation methods. The Fe/Co ratio in the deposition solution was controlled to form CoFe-LDH(v) to optimize the microstructure, hydrogen vacancy distribution and electronic structure of the material.

Benefits of technology

This improved the material's ion adsorption capacity, charge transfer kinetics, and structural stability, achieving electrochemical performance with high specific capacity and long cycle life while reducing material costs.

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Abstract

本发明公开了一种钴铁层状双氢氧化物电极及其制备方法与应用,属于电极材料技术领域,本发明通过调节沉积液中Fe / Co比例以及结合电化学沉积和电化学活化的方法制备了CoFe‑LDH(v)正极材料,并系统探究了Fe元素对CoFe‑LDH(v)的结构调控以及性能增强的作用机制。发现Co主要参与可逆氧化还原反应决定容量输出,而Fe虽发生微弱氧化还原反应辅助电荷存储,却在调控材料微观形貌、氢空位分布及诱导电子离域方面发挥关键作用。实验表征与理论计算均证实Fe的多氧化态与半满3d轨道特性,能有效重构局域电子分布、诱导电子离域化、优化M‑O键合强度,调控氢空位的分布与含量,进而显著提升材料的离子吸附能力、电荷转移动力学与结构稳定性。
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