Harmless treatment device for electrolytic manganese residues

By designing a harmless treatment device for electrolytic manganese slag, mixing electrolytic manganese slag with quicklime and condensed ammonia gas, the pollution problem in electrolytic manganese slag treatment is solved, and the harmless treatment of manganese slag and the reduction of environmental pollution is achieved.

CN222326222UActive Publication Date: 2025-01-10SCI RES ACADEMY OF GUANGXI ENVIRONMENTAL PROTECTION
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Patent Information

Application Number
CN202421099171.X
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-05-20
Publication Date
2025-01-10
Estimated Expiration
2034-05-20

AI Technical Summary

Technical Problem

The existing electrolytic manganese slag treatment methods lead to soil, groundwater and surface water pollution, and open-pit storage causes air pollution, lacking effective harmless treatment technology.

Method used

A harmless treatment device for electrolytic manganese slag is designed, including a reaction tank, a steam processor, a condenser, an ammonia tank, a pump and an acid sink. By mixing the electrolytic manganese slag with quicklime, ammonia gas is generated and condensed into ammonia water. Reduce the content of soluble manganese and ammonia nitrogen.

Benefits of technology

It significantly improves the recovery efficiency of ammonia nitrogen, reduces the content of soluble manganese and ammonia nitrogen in the treated manganese slag, realizes harmless treatment of electrolytic manganese slag, and reduces environmental pollution.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model discloses a harmless treatment device for electrolytic manganese residues. The harmless treatment device comprises a reaction tank, a steam treater, a condenser, an ammonia water tank, a sucking pump and an acid water tank which are distributed and mounted on a support frame, the reaction tank is provided with a feeding part and a first stirring part, the bottom of the reaction tank is provided with a first discharging valve, and the first discharging valve is connected with the steam treatment tank through a material guiding part; the steam treatment tank is provided with a second stirring piece and a partition plate, the bottom is provided with a second discharging valve, the partition plate and the inner side face of the steam treatment tank form a closed steam interlayer, a plurality of through holes are distributed in the partition plate, and the steam pipe is provided with a steam valve and connected with the steam interlayer; the condenser is provided with an air inlet pipe, a guide pipe and an exhaust pipe, the guide pipe is connected with the ammonia water tank, and the exhaust pipe is connected with the acid water tank through an exhaust pump; two ends of the first conveying pipe are respectively connected with the reaction tank and the gas inlet pipe; two ends of the second conveying pipe are respectively connected with the steam treatment tank and the air inlet pipe; and the controller is electrically connected with the electric equipment.
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Description

Technical Field

[0001] The utility model relates to a harmless treatment device for electrolytic manganese slag. Background Art

[0002] At present, the domestic electrolytic manganese slag is mainly treated by dry open-air storage. Open-air storage not only wastes a lot of land resources, but also causes soil acidification, damages soil structure and biodiversity. Some manganese slag storage sites have irregular anti-seepage measures or even no anti-seepage treatment, resulting in soluble heavy metal ions and ammonia nitrogen and other pollutants in the manganese slag being washed into rivers or infiltrated into the ground with rainwater, causing soil, groundwater and surface water pollution. In addition, the manganese slag in the open-air storage yard will gradually enter the air with the movement of air flow after years of sun and wind erosion, aggravating air pollution. Utility Model Content

[0003] The utility model aims to provide a harmless treatment device for electrolytic manganese slag in view of the defects of the prior art.

[0004] In order to achieve the above-mentioned purpose of the utility model, the following technical solutions are adopted:

[0005] A harmless treatment device for electrolytic manganese slag, comprising a support frame, on which a reaction tank, a steam treatment device, a condenser, an ammonia water tank, a vacuum pump and an acid water tank are distributed and installed; the reaction tank is equipped with a feed piece and a first stirring piece, a first discharge valve is installed at the bottom, and the first discharge valve is connected to the steam treatment tank through a material guide piece; the steam treatment tank is equipped with a second stirring piece and a partition, a second discharge valve is installed at the bottom, the partition and the inner side of the steam treatment tank form a closed steam interlayer, the partition is distributed with a plurality of through holes, a steam pipe, the steam pipe is equipped with a steam valve, and is connected to the steam interlayer; The condenser is provided with an air inlet pipe, a guide pipe and an air extraction pipe, the guide pipe is connected to the ammonia water tank, the air extraction pipe is connected to one end of the air extraction pump, and the other end of the air extraction pump is connected to the acid water tank; a first delivery pipe, the first delivery pipe is equipped with a first control valve, one end of which is connected to the reaction tank, and the other end is connected to the air inlet pipe; a second delivery pipe, the second delivery pipe is equipped with a second control valve, one end of which is connected to the steam treatment tank, and the other end is connected to the air inlet pipe; and a controller, the feeding member, the first stirring member, the first discharge valve, the second stirring member, the second discharge valve, the steam valve, and the air extraction pump are electrically connected to the controller respectively.

[0006] Furthermore, the feed member includes a first material guide pipe, the first material guide pipe is equipped with a feed valve and is obliquely installed on the reaction tank; and a hopper, the hopper is connected to the first material guide pipe; wherein the feed valve is electrically connected to the controller.

[0007] Furthermore, the material guiding member includes a first discharge hopper, one end of which is connected to the first discharge valve; and a second material guiding pipe, one end of which is connected to the steam treatment tank and the other end of which is connected to the other end of the first discharge hopper.

[0008] Furthermore, the utility model provides a harmless treatment device for electrolytic manganese slag, which also includes an air supply pipe and a check valve; one end of the air supply pipe is connected to the vacuum pump, and the other end extends into the acid water tank, and the check valve is installed on the air supply pipe.

[0009] Furthermore, the utility model provides a harmless treatment device for electrolytic manganese slag, which further includes a first discharge valve and a second discharge valve; the first discharge valve is installed on the guide pipe, and the second discharge valve is installed on the discharge port of the ammonia water tank.

[0010] Furthermore, the utility model of a harmless treatment device for electrolytic manganese slag also includes a liquid level sensor, and the liquid level sensor is installed in the ammonia water tank.

[0011] Furthermore, the harmless treatment device for electrolytic manganese slag of the utility model also includes a second discharge hopper, and the second discharge hopper is connected to a second discharge valve.

[0012] Furthermore, the utility model provides a harmless treatment device for electrolytic manganese slag, which also includes a water pipe, a water valve and a nozzle; the water pipe is equipped with a water valve, and is inserted into the reaction tank and connected to the nozzle.

[0013] Furthermore, the first stirring member includes a first driving motor, a first auxiliary frame, a first rotating shaft and a first spiral sheet. The first driving motor is installed in the reaction tank. One end of the first rotating shaft is transmission-connected to the first driving motor, and the other end is inserted into the reaction tank and penetrates the first auxiliary frame to be connected to the first spiral sheet.

[0014] Furthermore, the second stirring member includes a second drive motor, a second auxiliary frame, a second rotating shaft and a second spiral sheet. The second drive motor is installed in the steam treatment tank. One end of the second rotating shaft is transmission-connected to the second drive motor, and the other end is inserted into the steam treatment tank and penetrates the second auxiliary frame to be connected to the second spiral sheet.

[0015] The present invention has the following improvements over the prior art:

[0016] The utility model has the function of timely extracting ammonia generated by mixing electrolytic manganese slag and quicklime, and condensing and liquefying the extracted ammonia into ammonia water and storing it in an ammonia water tank. The residual materials of the reaction are sent to the steam treatment tank. During the steam treatment, the ammonia mixed gas generated in the steam treatment tank can be extracted and sent to the condenser for condensation, and the condensed liquid is sent to the ammonia water tank for storage. The utility model can not only greatly improve the recovery efficiency of ammonia nitrogen, but also ensure that the harmless treatment of electrolytic manganese slag achieves good results, so that the content of soluble manganese in the manganese slag after the harmless treatment is greatly reduced, and the ammonia nitrogen leaching rate is greatly reduced. BRIEF DESCRIPTION OF THE DRAWINGS

[0017] In order to more clearly illustrate the specific implementation of the utility model or the technical solution in the prior art, the following is a brief introduction to the drawings required for the specific implementation or the prior art description. In all the drawings, similar elements or parts are generally identified by similar reference numerals. In the drawings, each element or part is not necessarily drawn according to the actual scale.

[0018] Figure 1 This is a schematic diagram of the structure of a harmless treatment device for electrolytic manganese slag according to the utility model;

[0019] Figure 2 It is a schematic diagram of the structure of the connection between the reaction tank, the condenser and the ammonia water tank in the utility model;

[0020] Figure 3 It is a structural schematic diagram of the steam treatment tank in the utility model;

[0021] The names and serial numbers of the components in the figure are: 1-support frame, 2-first discharge hopper, 3-second material guide pipe, 4-first rotating shaft, 5-first spiral sheet, 6-first auxiliary frame, 7-first material guide pipe, 8-hopper, 9-feed valve, 10-nozzle, 11-water pipe, 12-water valve, 13-first drive motor, 14-first control valve, 15-first delivery pipe, 16-first support, 17-intake pipe, 18-second delivery pipe, 19-condenser, 20-exhaust pipe, 21-exhaust pump, 22-first discharge valve, 23-liquid level sensor device, 24-ammonia water tank, 25-check valve, 26-air supply pipe, 27-second discharge valve, 28-acid water tank, 29-support platform, 30-steam pipe, 31-steam valve, 32-controller, 33-second discharge hopper, 34-second discharge valve, 35-steam interlayer, 36-second control valve, 37-second rotating shaft, 38-second spiral sheet, 39-partition, 40-second auxiliary frame, 41-second drive motor, 42-conducting pipe, 43-first discharge valve, 44-second support, 45-steam treatment tank, 46-reaction tank. DETAILED DESCRIPTION

[0022] In order to enable those skilled in the art to better understand the technical solution in the present application, the technical solution of the present utility model will be clearly and completely described below in conjunction with the drawings and embodiments. Obviously, the described embodiments are only part of the embodiments of the present application. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without making creative work should fall within the scope of protection of the present application.

[0023] Embodiment 1:

[0024] like Figure 1-3 As shown, a harmless treatment device for electrolytic manganese slag is used for harmless treatment of electrolytic manganese slag, effectively reducing the pollution caused by electrolytic manganese to the environment. The adopted structure includes a support frame 1, a steam pipe 30, a first conveying pipe 15, a second conveying pipe 18 and a controller 32. The support frame 1 is distributed with a reaction tank 46, a steam treatment device 45, a condenser 19, an ammonia tank 24, a vacuum pump 21 and an acid water tank 28; the reaction tank 46 is installed with a feed member and a first stirring member, and a first discharge valve 43 is installed at the bottom thereof, and the first discharge valve 43 is connected to the steam treatment tank 45 through a material guide member; the steam treatment tank 45 is installed with a second stirring member and a partition 39, and a second discharge valve 34 is installed at the bottom, and the partition 39 and the inner side of the steam treatment tank 45 form a closed steam interlayer 35, and a plurality of through holes are distributed on the partition 39. The steam pipe 30 is provided with a steam valve 31 and connected to the steam interlayer 35; the condenser 19 is provided with an air inlet pipe 17, a delivery pipe 42 and an air extraction pipe 20, the delivery pipe 42 is connected to the ammonia water tank 24, the air extraction pipe 20 is connected to one end of the air extraction pump 21, and the other end of the air extraction pump 21 is connected to the acid water tank 28. The first delivery pipe 15 is provided with a first control valve 14, one end of the first delivery pipe 15 is connected to the reaction tank 46, and the other end is connected to the air inlet pipe 17; the second delivery pipe 18 is provided with a second control valve 36, one end of the second delivery pipe 18 is connected to the steam treatment tank 45, and the other end is connected to the air inlet pipe 17. The feed member, the first stirring member, the first discharge valve 43, the second stirring member, the second discharge valve 34, the steam valve 31, and the air extraction pump 21 are electrically connected to the controller 32 respectively.

[0025] The vacuum pump 21 extracts the gas in the condenser 19 to form a negative pressure. The condenser 19 can extract the ammonia and other gases produced by the reaction in the reaction tank 46 through the first delivery pipe 15 and extract the mixed gas such as ammonia and steam in the steam treatment tank through the second delivery pipe 18.

[0026] The first stirring member includes a first driving motor 13, a first auxiliary frame 6, a first rotating shaft 4 and a first spiral blade 5. The first driving motor 13 is installed on the reaction tank 46. One end of the first rotating shaft 4 is transmission-connected to the first driving motor 13, and the other end is inserted into the reaction tank 46 and penetrates the first auxiliary frame 6 to be connected with the first spiral blade 5.

[0027] The first auxiliary frame 6 is provided with a first support 6, and the first rotating shaft 4 passes through the first support 6 and is rotatably connected with the first support 6. The first support 6 may be provided with a rolling bearing, and the first support 6 and the first rotating shaft 4 are rotatably connected through the rolling bearing.

[0028] like Figure 1 and 2 As shown, the number of first auxiliary racks installed can be 1 or 2. When two are installed, the two first auxiliary racks are installed in the reaction tank 46 at intervals. It should be noted that the two first auxiliary racks do not hinder the rotation of the first spiral sheet. It is understandable that the first spiral sheet is discontinuous at the first auxiliary rack installed in the middle of the reaction tank. The first rotating shaft can stably rotate in the reaction tank under the support of the first auxiliary rack.

[0029] The first stirring member can stir the materials in the reaction tank so that the materials are mixed evenly.

[0030] Working mode of the first stirring element:

[0031] Material mixing: The first drive motor 13 starts to work, drives the first rotating shaft 4 to rotate counterclockwise, drives the first spiral blade to rotate counterclockwise, and the first spiral blade drives the electrolytic manganese slag and quicklime mixed materials in the reaction tank to be lifted upward, so as to realize the movement of the electrolytic manganese slag and quicklime mixed materials in the reaction tank, so that the electrolytic manganese slag and quicklime are evenly mixed, promote the maximum reaction of the electrolytic manganese slag and quicklime, and effectively degrade the ammonia nitrogen content in the electrolytic manganese slag.

[0032] Discharging: When the remaining reaction materials in the reaction tank need to be discharged, the first discharging valve is opened, the first driving motor drives the first rotating shaft to rotate clockwise, and the first spiral blade pushes the remaining reaction materials downward to be discharged through the first discharging valve.

[0033] The second stirring member includes a second driving motor 41, a second auxiliary frame 40, a second rotating shaft 37 and a second spiral blade 38. The second driving motor 41 is installed on the steam treatment tank 45. One end of the second rotating shaft 37 is transmission-connected to the second driving motor 41, and the other end is inserted into the steam treatment tank 45 and penetrates the second auxiliary frame 40 to be connected with the second spiral blade 38.

[0034] The second auxiliary frame 40 is provided with a second support 44, and the second rotating shaft 37 passes through the second support 44 and is rotatably connected to the second support 44. The second support 44 may be provided with a rolling bearing, and the second support 44 and the second rotating shaft 37 are rotatably connected through the rolling bearing.

[0035] like Figure 1 and 3As shown, the number of second auxiliary racks installed can be 1 or 2. When two are installed, the two second auxiliary racks are installed in the steam treatment tank 45 at intervals. It should be noted that the two second auxiliary racks do not hinder the rotation of the second spiral plate. It is understandable that the second spiral plate is discontinuous at the second auxiliary rack installed in the middle of the steam treatment tank. The second rotating shaft can stably rotate in the steam treatment tank under the support of the second auxiliary rack.

[0036] The second stirring member can stir the reaction residual material in the steam treatment tank 45, so that the reaction residual material can be evenly contacted with the steam sprayed from the steam interlayer through the multiple through holes on the partition, so that the reaction residual material is evenly heated.

[0037] Working mode of the second stirring element:

[0038] Material stirring: The second drive motor 41 drives the second shaft 37 to rotate counterclockwise, and the second shaft 37 drives the second spiral blade to rotate counterclockwise, driving the material in the steam treatment tank to circulate and move upward, so that the material is evenly contacted with the steam, thereby giving the material uniform heating and achieving steam harmless treatment.

[0039] It should be noted that the electrolytic manganese slag is granular electrolytic manganese slag. The quicklime can be powder.

[0040] In some embodiments of the present disclosure, a structure of a feed member is provided. The feed member includes a first feed pipe 7 and a hopper 8. The first feed pipe 7 is provided with a feed valve 9, which is obliquely installed on the reaction tank 46; the hopper 8 is connected to the first feed pipe 7; wherein the feed valve 9 is electrically connected to the controller 32.

[0041] The first guide pipe 7 is obliquely installed on the reaction tank 46 to facilitate the delivery of electrolytic manganese slag and quicklime into the reaction tank.

[0042] The hopper is used to store the electrolytic manganese slag and quicklime fed into the reaction tank.

[0043] The controller can control the operation of the feed valve.

[0044] How the feed piece works:

[0045] Electrolytic manganese slag or quicklime is placed in the hopper 8, and the feed valve 9 is opened by the controller 32, so that the electrolytic manganese slag or quicklime falls from the hopper 8 into the first material guide pipe 7, and then is guided into the reaction tank 46 through the first material guide pipe 7.

[0046] After the feeding is completed, the controller controls the feed valve 9 to close and controls the first stirring member to work. The first stirring member stirs the electrolytic manganese slag particles and quicklime in the reaction tank to mix them, so that the electrolytic manganese slag and quicklime are evenly mixed, promoting the full reaction of the electrolytic manganese slag and quicklime to maximize the production of ammonia.

[0047] In some embodiments of the present disclosure, a structure of a material guide is provided. Figure 1 As shown, the material guide member includes a first discharge hopper 2 and a second material guide pipe 3. One end of the first discharge hopper 2 is connected to the first discharge valve 43; one end of the second material guide pipe 3 is connected to the steam treatment tank 45, and the other end is connected to the other end of the first discharge hopper 2.

[0048] The first discharge hopper 2 is used to collect the reactants remaining after the reaction in the reaction tank discharged from the first discharge valve 43 , and then discharge them into the second guide pipe 3 through the first discharge hopper, and the second guide pipe 3 then guides the reactants to the steam treatment tank 45 .

[0049] In some embodiments of the present disclosure, a connection structure between an air pump and an acid water tank is provided, and an air supply pipe 26 and a check valve 25 are additionally installed. Figure 1 and 2 As shown, one end of the air supply pipe 26 is connected to the air pump 21 , and the other end extends into the acid water tank 28 , and the check valve 25 is installed on the air supply pipe 26 .

[0050] The check valve can prevent the acid water in the acid water tank from flowing back into the vacuum pump through the air supply pipe.

[0051] In some embodiments of the present disclosure, a control discharge structure on an ammonia water tank is provided, and a first discharge valve 22 and a second discharge valve 27 are additionally installed. Figure 1 and 2 As shown, the first discharge valve 22 is installed on the guide pipe 42 , and the second discharge valve 27 is installed on the discharge port of the ammonia water tank 24 .

[0052] In some embodiments of the present disclosure, in order to facilitate the acquisition of the liquid level height of the ammonia water tank, a liquid level sensor 23 is additionally installed. Figure 1 and 2 As shown, the liquid level sensor 23 is installed on the ammonia water tank 24. The liquid level sensor 23 is electrically connected to the controller 32, and the liquid level data information monitored by the liquid level sensor 23 in the ammonia water tank is transmitted to the controller 32 in real time. The controller 32 has a touch screen, and the liquid level data information monitored by the liquid level sensor is transmitted to the controller, and the controller then displays the corresponding liquid level data information through the touch screen.

[0053] In some embodiments of the present disclosure, a second discharge hopper 33 is additionally installed. Figure 1 and 3 As shown, the second discharge hopper 33 is connected to the second discharge valve 34 .

[0054] The second discharge hopper is in an inverted cone structure, which can be convenient for collecting the residual reaction materials discharged by the second discharge valve for unified discharge.

[0055] In some embodiments of the present disclosure, in order to facilitate water replenishment to the reaction tank, a water pipe 11, a water valve 12 and a nozzle 10 are additionally installed. Figure 1 and 2 As shown, the water delivery pipe 11 is installed with a water valve 12 and is inserted into the reaction tank 46 and connected to the nozzle 10 .

[0056] Working method:

[0057] When water needs to be added to the reaction tank, the water valve 12 is opened, and the water in the water pipe 11 is sprayed into the reaction tank through the nozzle 10.

[0058] The nozzle sprays in an atomized form. It is understandable that when replenishing water, the vacuum pump does not extract the gas in the reaction tank.

[0059] According to the above embodiments, the working mode of the utility model is as follows:

[0060] The controller 32 controls the feeding piece to be opened, and the electrolytic manganese slag particles and quicklime can be respectively put into the reaction tank 46. After the electrolytic manganese slag particles and quicklime are fed, the feeding piece is closed by controlling the controller.

[0061] The controller 32 controls the first drive motor 13 to start working, drives the first rotating shaft 4 to rotate counterclockwise, drives the first spiral blade to rotate counterclockwise, and the first spiral blade drives the electrolytic manganese slag particles and quicklime mixed materials in the reaction tank to be lifted upward, realizes the movement of the electrolytic manganese slag particles and quicklime mixed materials in the reaction tank 46, makes the electrolytic manganese slag and granular quicklime mixed evenly, promotes the maximum reaction of the electrolytic manganese slag and quicklime, can effectively reduce the amount of ammonia nitrogen in the electrolytic manganese slag, and produces the maximum amount of ammonia gas.

[0062] The controller starts the vacuum pump 21 and opens the first control valve 14. The vacuum pump 21 extracts the gas in the condenser 19 through the vacuum pipe 20 to generate negative pressure, so that the condenser 19 extracts the mixed gas such as ammonia in the reaction tank 46 through the first delivery pipe 15. The mixed body enters the condenser 19 through the first delivery pipe 15. The condenser 19 condenses the mixed gas entering, and the ammonia is condensed into ammonia water, which is introduced into the ammonia water tank 24 for storage through the guide pipe 42. The remaining gas enters the vacuum pump through the condenser, and is then transported to the acid water tank 28 by the vacuum pump. The acid water tank can remove the small amount of residual ammonia to prevent the ammonia from being discharged into the atmosphere and causing air pollution.

[0063] Unloading is performed after the reaction is completed: when the remaining reaction materials obtained from the reaction in the reaction tank need to be discharged, the first unloading valve 43 is opened, the first driving motor 13 drives the first rotating shaft 4 to rotate clockwise, and the first spiral blade 5 pushes the remaining reaction materials downward to be discharged through the first unloading valve 43, fall into the first unloading hopper 2, and enter the steam treatment tank 46 through the second material guide pipe 3.

[0064] After the reaction tank is unloaded, the controller controls the first drive motor 13 to stop working, the first discharge valve 43 and the first control valve 14 are closed, and the controller 32 controls the second control valve 36 and the steam valve 31 to open and the second drive motor 41 to start. The second drive motor 41 drives the second shaft 37 to rotate counterclockwise, and the second shaft 37 drives the second spiral blade 38 to rotate counterclockwise. The second spiral blade 38 pushes the reaction residual material from the bottom of the steam treatment tank to the top of the circulation, so that the reaction residual material is effectively in contact with the steam sprayed from the partition 39, so that the reaction residual material is evenly heated. The temperature of the steam can be 150-220°C, and the steam treatment time can be 2-8 hours. The mixed gas in the steam treatment tank 45 enters the air inlet pipe 17 through the second conveying pipe 18 and the second control valve 36, and then enters the condenser 19 through the air inlet pipe 17. The first discharge valve 22 is opened, and the condensed liquid generated in the condenser enters the ammonia tank 24 for storage through the guide pipe 42 and the first discharge valve 22.

[0065] After the processing time reaches the set steam processing time, the steam valve 31 and the second control valve 36 are closed through the controller 332, the vacuum pump 21 is stopped, the second discharge valve 35 is opened, the second drive motor 41 is reversed, and the second spiral blade rotates clockwise to push the harmless electrolytic manganese slag obtained by the steam treatment tank to the second discharge valve 35, and the slag falls into the second discharge hopper 33 through the second discharge valve 35 for discharge.

[0066] After the unloading of the steam treatment tank is completed, the controller 32 controls the second driving motor 41 to stop working and the second unloading valve 34 to close.

[0067] Obviously, the above embodiments are merely examples for the purpose of clear explanation, and are not intended to limit the implementation methods. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. The obvious changes or modifications derived from these are still within the scope of protection of the invention of the utility model.

Claims

1. A harmless treatment device for electrolytic manganese slag, characterized in that: include A support frame (1), wherein the support frame (1) is distributedly mounted with a reaction tank (46), a steam treatment device (45), a condenser (19), an ammonia water tank (24), a vacuum pump (21) and an acid water tank (28); The reaction tank (46) is equipped with a feed member and a first stirring member, and a first discharge valve (43) is installed at the bottom thereof, and the first discharge valve (43) is connected to the steam treatment tank (45) through a material guide member; The steam treatment tank (45) is equipped with a second stirring member and a partition (39), and a second discharge valve (34) is installed at the bottom. The partition (39) and the inner side surface of the steam treatment tank (45) form a closed steam sandwich (35), and a plurality of through holes are distributed on the partition (39); A steam pipe (30), wherein the steam pipe (30) is provided with a steam valve (31) and is connected to the steam interlayer (35); The condenser (19) is provided with an air inlet pipe (17), a guide pipe (42) and an air extraction pipe (20), wherein the guide pipe (42) is connected to an ammonia water tank (24), the air extraction pipe (20) is connected to one end of an air extraction pump (21), and the other end of the air extraction pump (21) is connected to an acid water tank (28); A first delivery pipe (15), wherein the first delivery pipe (15) is provided with a first control valve (14), one end of the first delivery pipe (15) is connected to the reaction tank (46), and the other end of the first delivery pipe (15) is connected to the air intake pipe (17); A second delivery pipe (18), wherein the second delivery pipe (18) is installed with a second control valve (36), one end of which is connected to the steam treatment tank (45), and the other end of which is connected to the air intake pipe (17); and The controller (32) is electrically connected to the feed element, the first stirring element, the first discharge valve (43), the second stirring element, the second discharge valve (34), the steam valve (31), and the air extraction pump (21).

2. The harmless treatment device for electrolytic manganese slag according to claim 1, characterized in that: The feed member comprises A first material guide pipe (7), the first material guide pipe (7) is equipped with a feed valve (9), and is obliquely installed on the reaction tank (46); and A hopper (8), wherein the hopper (8) is connected to the first material guide pipe (7); Wherein, the feed valve (9) is electrically connected to the controller (32).

3. The harmless treatment device for electrolytic manganese slag according to claim 1, characterized in that: The material guide member comprises A first discharge hopper (2), one end of which is connected to a first discharge valve (43); as well as A second material guiding pipe (3), one end of the second material guiding pipe (3) is connected to the steam treatment tank (45), and the other end is connected to the other end of the first discharge hopper (2).

4. The harmless treatment device for electrolytic manganese slag according to claim 1, characterized in that: It also includes an air supply pipe (26) and a check valve (25); one end of the air supply pipe (26) is connected to the air pump (21), and the other end extends into the acid water tank (28); the check valve (25) is installed on the air supply pipe (26).

5. The harmless treatment device for electrolytic manganese slag according to claim 1, characterized in that: It also includes a first discharge valve (22) and a second discharge valve (27); the first discharge valve (22) is installed on the guide pipe (42), and the second discharge valve (27) is installed on the discharge port of the ammonia water tank (24).

6. The harmless treatment device for electrolytic manganese slag according to claim 5, characterized in that: It also includes a liquid level sensor (23), wherein the liquid level sensor (23) is installed on the ammonia water tank (24).

7. The harmless treatment device for electrolytic manganese slag according to claim 1, characterized in that: It also includes a second discharge hopper (33), wherein the second discharge hopper (33) is connected to a second discharge valve (34).

8. The harmless treatment device for electrolytic manganese slag according to any one of claims 1 to 7, characterized in that: It also comprises a water pipe (11), a water valve (12) and a nozzle (10); the water pipe (11) is installed with a water valve (12), and is inserted into the reaction tank (46) and connected to the nozzle (10).

9. The harmless treatment device for electrolytic manganese slag according to claim 8, characterized in that: The first stirring member comprises a first driving motor (13), a first auxiliary frame (6), a first rotating shaft (4) and a first spiral sheet (5); the first driving motor (13) is installed on a reaction tank (46); one end of the first rotating shaft (4) is drivingly connected to the first driving motor (13), and the other end is inserted into the reaction tank (46) and penetrates the first auxiliary frame (6) to be connected to the first spiral sheet (5).

10. The harmless treatment device for electrolytic manganese slag according to claim 8, characterized in that: The second stirring member comprises a second driving motor (41), a second auxiliary frame (40), a second rotating shaft (37) and a second spiral sheet (38); the second driving motor (41) is installed on the steam treatment tank (45); one end of the second rotating shaft (37) is transmission-connected to the second driving motor (41), and the other end is inserted into the steam treatment tank (45) and penetrates the second auxiliary frame (40) to be connected to the second spiral sheet (38).