Hair styling composition

Abstract

A hair styling composition containing: a) one or more anionic hair styling polymer(s), b) one or more alkalizing agents, c) one or more monoalcohols, wherein the total concentration of water in the hair styling composition is 10% by weight or less.

Description

[0001] The present invention relates to a hair styling composition and an aerosol sprayer.

[0002] The use of anionic polymers in hair styling products is widespread because they offer essential properties such as improved film formation and long-lasting hold. The challenge is keeping these polymers stable and functional in alcoholic media. Alkalizing agents are crucial in this process, converting the polymers into their soluble form by serving as a counterion to the anionic polymers.

[0003] A commonly used alkalizing agent in hair styling compositions is aminomethylpropanol.

[0004] The present invention aims to provide a hair styling composition in which the anionic polymers are neutralized by alternatives to aminomethylpropanol.

[0005] In particular, the object of the invention is to provide a hair styling product that can be sprayed as an aerosol, that dries quickly on the hair, provides good hold and shine, and can be washed out without leaving any residue.

[0006] Therefore, the first subject matter of the invention is a hair styling composition comprising: a) one or more anionic hair styling polymer(s), b) one or more alkalizing agents, c) one or more monoalcohols,wherein the total concentration of water in the hair styling composition is 10% by weight or less.

[0007] A second subject matter of the invention is an aerosol atomizer containing the hair styling composition defined above and a propellant.

[0008] Preferably, the one or more hair styling polymers are from the group a) Acrylates Octylacrylamide Copolymer, Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer, VA Crotonates / Vinyl Neodecanoate Copolymer, Acrylates Copolymer, Ethyl Ester of PVM / MA Copolymer, and / or their salts, and / or their mixtures.

[0009] It is further preferred that the total concentration of one or more hair styling polymers of group a) is in the range of 0.1 wt% to 20 wt%, preferably in the range of 0.2 wt% to 15 wt%, more preferably in the range of 0.5 wt% to 12 wt%, based on the total weight of the hair styling composition.

[0010] Preferably, the one or more alkalizing agents of group b) are alkali or alkaline earth hydroxides or alkanolamines, and / or their salts, and / or mixtures thereof, preferably the one or more alkalizing agents of group b) are sodium hydroxide, potassium hydroxide, monoethanolamine, triethanolamine, tris(hydroxymethyl)aminomethane, 2-dimethylamino-2-methyl-1-propanol, tetrahydroxypropyl ethylenediamine, 1-aminobutanol, 2-aminobutanol, 4-amino-1-butanol, amino methylisobutanol (CAS 13325-14-9), diisopropanolamine, triisopropanolamine, and / or their salts, and / or mixtures thereof.

[0011] It is also preferred that the total concentration of the one or more alkalizing agents of group b) is in the range of 0.1 wt% to 20 wt%, preferably in the range of 0.2 wt% to 15 wt%, more preferably in the range of 0.5 wt% to 12 wt%, based on the total weight of the hair styling composition.

[0012] Preferably, the degree of neutralization of the polymers of group a) with the alkalizing agent of group b) is 75% or more, preferably 90% or more, more preferably 95% or more, more preferably 99% or more, most preferably 100%, calculated on the amount of acid functions of the polymers of group a).

[0013] Preferably, the one or more monoalcohols of group c) are ethanol, n-propanol, isopropanol, or mixtures thereof, preferably the one or more monoalcohols of group c) is ethanol.

[0014] It is further preferred that the total concentration of one or more monoalcohols of group c) is 50 wt% to 99 wt%, preferably in the range of 75 wt% to 95 wt%, more preferably in the range of 85 wt% to 93 wt%, based on the total weight of the hair styling composition.

[0015] It is further preferred that the total concentration of water in the hair styling composition is 5 wt% or less, preferably 1 wt% or less, further preferably 0.1 wt% or less, based on the total weight of the hair styling composition, most preferably the hair styling composition is anhydrous.

[0016] It is further preferred that it additionally contains one or more lipophilic compound(s), preferably one or more vegetable or mineral oil(s), C 12 - to C 22 -Fatty alcohols, esters of C 3 - to C 22 -Alcohols with C 12 - to C 22 -fatty acids, C 8 - to C 22-fatty acids, one or more silicones and / or mixtures thereof, the compounds mentioned preferably being castor oil, olive oil, safflower oil, argan oil, almond oil, avocado oil, castor oil, coconut oil, palm oil, sesame oil, peanut oil, sunflower oil, peach kernel oil, wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, soybean oil, passiflora oil, black cumin oil, borage oil, grape seed oil, macadamia oil, rosehip oil, hemp seed oil, mineral oil, paraffinum perliquidium, paraffinum subliquidum, polydecene, lauryl alcohol, myristyl alcohol, stearyl alcohol, cetyl alcohol, cetearyl alcohol, behenyl alcohol, octyldodecanol, lauric acid, myristic acid, stearic acid, palmitic acid, behenic acid, isopropyl myristate, isostearyl lactate, isopropyl palmitate, myristyl myristate, Palmityl palmitate, isocetyl palmitate, octyl stearate, oleyl oleate, ethylhexyl hydroxystearate, myristyl myristate, behenyl behenate, oleic acid, linoleic acid, palmitic acid, silicones, such as aminated or non-aminated silicones, and / or mixtures thereof,wherein the compounds are preferably castor oil, mineral oil, isostearyl lactate, isopropyl myristate and / or mixtures thereof.

[0017] It is further preferred that the hair styling composition additionally contains one or more polyhydric alcohols, preferably glycerin, propylene glycol, and / or mixtures thereof.

[0018] It is further preferred that the total concentration of lipophilic substances and / or polyhydric alcohols in the hair styling composition is in the range of 0.001% to 95% by weight, preferably the range of 0.05% to 75% by weight, more preferably the range of 0.1% to 50% by weight, more preferably the range of 0.01% to 20% by weight, calculated on the total amount of the composition.

[0019] Preferably, the hair styling composition contains one or more further hair styling polymers which differ from group a), preferably non-ionic polymers, preferably non-ionic homo- or copolymers with units containing vinylpyrrolidones and / or vinyl acetates and / or biopolymers such as natural or chemically modified cellulose or starch.

[0020] It is further preferred that the non-ionic polymers are selected from vinylpyrrolidone / vinyl acetate copolymers or polyvinylpyrrolidone homopolymers, and / or mixtures thereof.

[0021] It is further preferred that the total concentration of the non-ionic polymers ranges from 0.01% to 10% by weight, preferably from 0.05% to 8% by weight, more preferably from 0.1% to 5% by weight, more preferably from 0.5% to 3% by weight, calculated on the total amount of the hair styling composition.

[0022] It is further preferred if the composition according to the present invention contains one or more surfactant(s), preferably an anionic, non-ionic, and / or zwitterionic surfactant.

[0023] From the viewpoint of wettability and mildness, it is preferred that one or more amphoteric surfactants are one or more alkyl betaine surfactants, one or more alkylamidoalkyl betaine surfactants, one or more alkyl amphoacetate surfactants, one or more sultaine surfactants, one or more hydroxysultaine surfactants and / or their salts and / or their mixtures.

[0024] From the viewpoint of mildness, it is preferred that one or more amphoteric surfactants are coco-betaine, cocoamidopropyl-betaine, coco-amphoacetate, hydroxy sultaine and / or their salt(s) and / or their mixtures.

[0025] From the point of view of wetting, one or more non-ionic surfactants is / are preferably one or more alkyl glucoside(s), one or more alkyl polyglycoside(s), one or more ethoxylated and / or propoxylated fatty alcohol(s), one or more ethoxylated and / or propoxylated vegetable oil(s), one or more N-alkyl polyhydroxyalkylamide surfactants.

[0026] Nicht einschränkende geeignete Beispiele für Fettalkoholethoxylate sind C9-11 Pareth-6, C9-11 Pareth-8, C9-15 Pareth-8, C11-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-5, C11-15 Pareth-7, C11-15 Pareth-9, C11-15 Pareth-12, C11-15 Pareth-15, C11-15 Pareth-20, C11-15 Pareth-30, C11-15 Pareth-40, C11-21 Pareth-10, C12-13 Pareth-5, C12-13 Pareth-6, C12-13 Pareth-7, C12-13 Pareth-9, C12-13 Pareth-10, C12-13 Pareth-15, C12-13 Pareth-23, C12-14 Pareth-5, C12-14 Pareth-7, C12-14 Pareth-9, C12-14 Pareth-11, C12-14 Pareth-12, C12-15 Pareth-5, C12-15 Pareth-7, C12-15 Pareth-9, C12-15 Pareth-10, C12-15 Pareth-11, C12-15 Pareth-12, C12-16 Pareth-5, C12-16 Pareth-7, C12-16 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-7, C14-15 Pareth-8, C14-15 Pareth-11, C14-15 Pareth-12, C14-15 Pareth-13, C20-22 Pareth-30, C20-40 Pareth-10, C20-40 Pareth-24, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, Beheneth-5, Beheneth-10, Beheneth-15, Beheneth-20, Beheneth-25, Beheneth-30, Ceteareth-5, Ceteareth-6,Ceteareth-7, Ceteareth-10, Ceteareth-11, Ceteareth-12, Ceteareth-15, Ceteareth-20, Ceteareth-25, Ceteareth-30, Ceteareth-35, Ceteareth-40, Laureth-5, Laureth-10, Laureth-15, Laureth-20, Laureth-25, Laureth-30, Laureth-40, Myreth-5, Myreth-10, Ceteth-5, Ceteth-10, Ceteth-15, Ceteth-20, Ceteth-25, Ceteth-30, Ceteth-40, Oleth-5, Oleth-10, Oleth-15, Oleth-20, Oleth-25, Oleth-30, Oleth-40, Steareth-5, Steareth-10, Steareth-15, Steareth-20, Steareth-25, Steareth-30, Steareth-35, and Steareth-40. They may also be included in the compositions as a mixture of more than one surfactant.

[0027] Suitable non-limiting examples are PPG-3 caprylyl ether, PPG-5 caprylyl ether, PPG-10 caprylyl ether, PPG-10 cetyl ether, PPG-20 cetyl ether, PPG-28 cetyl ether, PPG-30 cetyl ether, PPG-7 lauryl ether, PPG-10 lauryl ether, PPG-10 oleyl ether, PPG-20 oleyl ether, PPG-23 oleyl ether, PPG-30 oleyl ether, PPG-11 stearyl ether and PPG-15 stearyl ether.

[0028] Geeignete, nicht einschränkende Beispiele sind PEG-8 Behenate, PEG-8 Caprate, PEG-8 Caprylate, PEG-5 Cocoate, PEG-8 Cocoate, PEG-9 Cocoate, PEG-10 Cocoate, PEG-15 Cocoate, PEG-6 Isopalmitate, PEG-6 Isostearate, PEG-8 Isostearate,

[0029] PEG-9 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-6 Laurat, PEG-8 Laurat, PEG-9 Laurat, PEG-10 Laurat, PEG-12 Laurat, PEG-14 Laurat, PEG-20 Laurate, PEG-30 Laurate, PEG-8 Myristat, PEG-20 Myristat, PEG-5 Oleate, PEG-6 Oleate, PEG-7 Oleate, PEG-8 Oleate, PEG-9 Oleate, PEG-10 Oleate, PEG-11 Oleate, PEG-12 Oleate, PEG-15 Oleate, PEG-20 Oleate, PEG-30 Oleate, PEG-32 Oleate, PEG-6 Palmitate, PEG-18 Palmitate, PEG-20 Palmitate, PEG-5 Stearate, PEG-6 Stearate, PEG-7 Stearate, PEG-8 Stearate, PEG-9 Stearate, PEG-10 Stearate, PEG-12 Stearate, PEG-14 Stearate, PEG-15 Stearate, PEG-20 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-35 Stearate und PEG-40 Stearate.

[0030] Other suitable nonionic surfactants are ethoxylated vegetable oils. Well-known and frequently used examples are ethoxylated castor oil such as PEG-40 hydrogenated castor oil or PEG-60 hydrogenated castor oil.

[0031] The preferred nonionic surfactants are one or more alkyl glycosides, preferably one or more C8-C22 alkyl glucosides such as coco-glucoside, from the point of view of mildness. The most preferred compound(s) according to group b) are coco-glucoside, decyl glucoside, and lauryl glucoside.

[0032] The composition may preferably contain one or more alpha-sulfo fatty acid surfactants as anionic surfactants. From the point of view of mildness, it is preferred that the anionic surfactants comprise one or more sarcosinate surfactants, one or more glutamate surfactants, one or more isethionate surfactants, one or more ethersulfonate surfactants, one or more sulfosuccinate surfactants, one or more sulfoacetate surfactants, one or more glycinate surfactants, one or more alaninate surfactants, one or more carboxylate surfactants, one or more taurate surfactants, and / or mixtures thereof and / or salts thereof.

[0033] Preferably, the composition according to the invention contains the surfactants in a total concentration in the range of 0.01% to 35% by weight, preferably in the range of 0.1% to 30% by weight, calculated on the total amount of the composition.

[0034] The present invention also relates to an aerosol spray containing the hair styling composition described above and a propellant.

[0035] The preferred propellant is liquefied petroleum gas (LPG). Also suitable are dimethyl ether and 1,1-digluroethane, and / or mixtures thereof with or without LPG.

[0036] It is further preferred that in the aerosol atomizer the total concentration of hair styling composition is in the range of 10 wt% to 60 wt% and the total amount of propellant is in the range of 40 wt% to 90 wt%, based on the total amount of hair styling composition and propellant.

[0037] The following examples serve to illustrate the invention and in no way limit it. Examples

[0038] The following examples contain liquefied petroleum gas as a propellant, which is a mixture of n-propane, n-butane, and isobutane. Dimethyl ether (DME) can be used as an alternative or supplement. Example 1 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Glycerin 2.0 (0.1-10) NaOH / KOH qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 75% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF)

[0039] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0040] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0041] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 2 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Propylene glycol 2.0 (0.1-10) Monoethanolamine qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 90% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF)

[0042] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0043] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0044] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 3 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isopropyl myristate 2.0 (0.1-10) Tris(hydroxymethyl)aminomethane qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF)

[0045] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0046] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0047] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 4 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Ethyl Esters of PVM / MA Copolymer*** 5.0 (0.1-20) Dimethicone 2.0 (0.1-10) 1-aminobutanol / 2-aminobutanol / 4-amino-1-butanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF) ***Omnirez 2000 (Ashland)

[0048] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0049] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0050] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 5 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) castor oil 2.0 (0.1-10) Tetrahydroxypropyl ethylenediamine*** qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF) ***(BASF)

[0051] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0052] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0053] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 6 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Walnut oil 2.0 (0.1-10) Triisopropanolamine (TIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF)

[0054] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0055] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0056] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 7 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isostearyl lactate 2.0 (0.1-10) Diisopropanolamine (DIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E (BASF)

[0057] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0058] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0059] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 8 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) 2-dimethylamino-2-methyl-1-propanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0060] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0061] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 9 - Hair styling aerosol composition Ingredients % by weight Acrylates Octylacrylamide Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) Amino Methylisobutanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer HC (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0062] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0063] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 10 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Glycerin 2.0 (0.1-10) NaOH / KOH qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 75% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF)

[0064] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0065] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0066] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 11 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Propylene glycol 2.0 (0.1-10) Monoethanolamine qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 90% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF)

[0067] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0068] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0069] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 12 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isopropyl myristate 2.0 (0.1-10) Tris(hydroxymethyl)aminomethane qs up to a Degree of neutralization of the octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF)

[0070] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0071] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0072] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 13 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Ethyl Esters of PVM / MA Copolymer*** 5.0 (0.1-20) Dimethicone 2.0 (0.1-10) 1-aminobutanol / 2-aminobutanol / 4-amino-1-butanol qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF) ***Omnirez 2000 (Ashland)

[0073] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0074] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0075] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 14 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) castor oil 2.0 (0.1-10) Tetrahydroxypropyl ethylenediamine*** qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF) ***(BASF)

[0076] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0077] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0078] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 15 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Walnut oil 2.0 (0.1-10) Triisopropanolamine (TIPA) qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF)

[0079] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0080] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0081] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 16 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isostearyl lactate 2.0 (0.1-10) Diisopropanolamine (DIPA) qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E (BASF)

[0082] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0083] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0084] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 17 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) 2-dimethylamino-2-methyl-1-propanol qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0085] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0086] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 18 - Hair styling aerosol composition Ingredients % by weight Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) Amino Methylisobutanol qs up to a Degree of neutralization of the Octylacrylamide / Acrylate / B utylaminoethyl Methacrylate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Amphomer (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0087] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0088] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 19 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Glycerin 2.0 (0.1-10) NaOH / KOH qs up to a Degree of neutralization of the VA Crotonate / Vinyl Neodecanoate Copolymer >= 75% perfume 0.1 Ethanol to 100.0 * Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF)

[0089] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0090] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0091] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 20 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Propylene glycol 2.0 (0.1-10) Monoethanolamine qs up to a Degree of neutralization of the VA Crotonate / Vinyl Neodecanoate Copolymer >= 90% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF)

[0092] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0093] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0094] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 21 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isopropyl myristate 2.0 (0.1-10) Tris(hydroxymethyl)aminomethane qs up to a Degree of neutralization of the VA Crotonate / Vinyl Neodecanoate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF)

[0095] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0096] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0097] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 22 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer * 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Ethyl Esters of PVM / MA Copolymer*** 5.0 (0.1-20) Dimethicone 2.0 (0.1-10) 1-aminobutanol / 2-aminobutanol / 4-amino-1-butanol qs up to a Degree of neutralization of the VA Crotonate / Vinyl Neodecanoate Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF) ***Omnirez 2000 (Ashland)

[0098] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0099] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0100] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 23 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* * 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) castor oil 2.0 (0.1-10) Tetrahydroxypropyl ethylenediamine*** qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF) ***(BASF)

[0101] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0102] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0103] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 24 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Walnut oil 2.0 (0.1-10) Triisopropanolamine (TIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF)

[0104] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0105] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0106] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 25 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer * 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isostearyl lactate 2.0 (0.1-10) Diisopropanolamine (DIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E (BASF)

[0107] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0108] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0109] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 26 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer * 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) 2-dimethylamino-2-methyl-1-propanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0110] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0111] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 27 - Hair styling aerosol composition Ingredients % by weight VA Crotonates / Vinyl Neodecanoate Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) Amino Methylisobutanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Resyn 28-2930 (Nouryon) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0112] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0113] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 28 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Glycerin 2.0 (0.1-10) NaOH / KOH qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 75% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF)

[0114] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0115] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0116] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 29 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Propylene glycol 2.0 (0.1-10) Monoethanolamine qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 90% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF)

[0117] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0118] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0119] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 30 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isopropyl myristate 2.0 (0.1-10) Tris(hydroxymethyl)aminomethane qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF)

[0120] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0121] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0122] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 31 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Ethyl Esters of PVM / MA Copolymer*** 5.0 (0.1-20) Dimethicone 2.0 (0.1-10) 1-aminobutanol / 2-aminobutanol / 4-amino-1-butanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 **Luvimer 100P (BASF) **Luviskol VA 37 E (BASF) ***Omnirez 2000 (Ashland)

[0123] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0124] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0125] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 32 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) castor oil 2.0 (0.1-10) Tetrahydroxypropyl ethylenediamine*** qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF) ***(BASF)

[0126] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0127] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0128] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 33 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Walnut oil 2.0 (0.1-10) Triisopropanolamine (TIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF)

[0129] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0130] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0131] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 34 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isostearyl lactate 2.0 (0.1-10) Diisopropanolamine (DIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E (BASF)

[0132] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0133] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0134] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 35 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) 2-dimethylamino-2-methyl-1-propanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0135] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0136] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 36 - Hair styling aerosol composition Ingredients % by weight Acrylates Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) Amino Methylisobutanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Luvimer 100P (BASF) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0137] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0138] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 37 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Glycerin 2.0 (0.1-10) NaOH / KOH qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 75% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF)

[0139] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0140] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0141] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 38 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Propylene glycol 2.0 (0.1-10) Monoethanolamine qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 90% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF)

[0142] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0143] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0144] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 39 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isopropyl myristate 2.0 (0.1-10) Tris(hydroxymethyl)aminomethane qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF)

[0145] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0146] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0147] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 40 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Ethyl Esters of PVM / MA Copolymer*** 5.0 (0.1-20) Dimethicone 2.0 (0.1-10) 1-aminobutanol / 2-aminobutanol / 4-amino-1-butanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF) ***Omnirez 2000 (Ashland)

[0148] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0149] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0150] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 41 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) castor oil 2.0 (0.1-10) Tetrahydroxypropyl ethylenediamine*** qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF) ***(BASF)

[0151] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0152] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0153] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 42 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Walnut oil 2.0 (0.1-10) Triisopropanolamine (TIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF)

[0154] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0155] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0156] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 43 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) Isostearyl lactate 2.0 (0.1-10) Diisopropanolamine (DIPA) qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E (BASF)

[0157] A total water content of 10% by weight is permitted in the formulation. The formulation is preferably anhydrous.

[0158] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0159] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 44 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) 2-dimethylamino-2-methyl-1-propanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0160] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0161] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film. Example 45 - Hair styling aerosol composition Ingredients % by weight Ethyl Ester of PVM / MA Copolymer* 10.0 (0.1-20) VP / VA copolymer** 5.0 (0.1-20) PVP*** 3.0 (0.1-20) Glycerin 2.0 (0.1-10) Amino Methylisobutanol qs up to a Degree of neutralization of the acrylate Octylacrylamide Copolymer >= 95% perfume 0.1 Ethanol to 100.0 *Gantrez SP - 215 (Ashland) **Luviskol VA 37 E, Luviskol VA 37 I, Luviskol VA 55 I, Luviskol VA 64 Powder, Luviskol VA 64 W, Luviskol VA 73 E (all BASF) ***Luviskol K30, Luviskol K90 (all BASF)

[0162] 20 g of the composition were filled into an aerosol can, the can was crimped and filled with 80 g of liquefied petroleum gas (LPG) / DME, or 1,1-difluoroethane, so that a pressure of between 8 and 10 bar was built up.

[0163] The aerosol sprayed evenly onto the keratin fibers. The composition gave the fibers a firm hold without leaving a brittle film.

Claims

[1] A hair styling composition containing: a) one or more anionic hair styling polymer(s), b) one or more alkalizing agents, c) one or more monoalcohols, wherein the total concentration of water in the hair styling composition is 10% by weight or less. [2] The composition according to claim 1, characterized by that one or more hair styling polymers of group a) are Acrylates Octylacrylamide Copolymer, Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer, VA Crotonates / Vinyl Neodecanoate Copolymer, Acrylates Copolymer, Ethyl Ester of PVM / MA Copolymer, and / or their salts, and / or their mixtures. [3] The composition according to any one of the preceding claims, characterized in that the total concentration of one or more hair styling polymers of group a) is in the range of 0.1 wt% to 20 wt%, preferably in the range of 0.2 wt% to 15 wt%, more preferably in the range of 0.5 wt% to 12 wt%, based on the total weight of the hair styling composition. [4] The composition according to any one of the preceding claims, characterized bythat the one or more alkalizing agents of group b) are alkali or alkaline earth hydroxides or alkanolamines, and / or their salts, and / or their mixtures, preferably the one or more alkalizing agents of group b) are sodium hydroxide, potassium hydroxide, monoethanolamine, triethanolamine, tris(hydroxymethyl)aminomethane, 2-dimethylamino-2-methyl-1-propanol, tetrahydroxypropyl ethylenediamine, 1-aminobutanol, 2-aminobutanol, 4-amino-1-butanol, amino methylisobutanol, diisopropanolamine, triisopropanolamine, and / or their salts, and / or their mixtures. [5] Composition according to any one of the preceding claims, characterized by that the total concentration of the one or more alkalizing agents of group b) is in the range from 0.1 wt% to 20 wt%, preferably in the range from 0.2 wt% to 15 wt%, more preferably in the range from 0.5 wt% to 12 wt%, based on the total weight of the hair styling composition. [6] Composition according to any one of the preceding claims, characterized by that the degree of neutralization of the polymers of group a) with the alkalizing agents of group b) is 75% or more, preferably 90% or more, more preferably 95% or more, more preferably 99% or more, most preferably 100%, calculated on the amount of acid functions of the polymers of group a). [7] The composition according to any one of the preceding claims, characterized by that the one or more monoalcohols of group c) are ethanol, n-propanol, isopropanol, or mixtures thereof, preferably the one or more monoalcohols of group c) is ethanol. [8] The composition according to any one of the preceding claims, characterized bythat the total concentration of one or more monoalcohols of group c) is 50 wt% to 99 wt%, preferably in the range of 75 wt% to 95 wt%, more preferably in the range of 85 wt% to 93 wt%, based on the total weight of the hair styling composition. [9] The composition according to any one of the preceding claims, characterized by that the total concentration of water in the hair styling composition is 5 wt% or less, preferably 1 wt% or less, more preferably 0.1 wt% or less, based on the total weight of the hair styling composition, most preferably the hair styling composition is anhydrous. [10] The composition according to any one of the preceding claims, characterized by that it additionally contains one or more lipophilic compound(s), preferably one or more vegetable or mineral oil(s), C 12 - to C 22 -Fatty alcohols, esters of C 3- to C 22 -Alcohols with C 12 - to C 22 -fatty acids, C 8 - to C 22 -fatty acids, one or more silicones and / or mixtures thereof, wherein the compounds mentioned are preferably castor oil, olive oil, safflower oil, argan oil, almond oil, avocado oil, castor oil, coconut oil, palm oil, sesame oil, peanut oil, sunflower oil, peach kernel oil, wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, soybean oil, passiflora oil, black cumin oil, borage oil, grape seed oil, macadamia oil, Rosehip oil, hemp seed oil, mineral oil, paraffinum perliquidium, paraffinum subliquidum, polydecene, lauryl alcohol, myristyl alcohol, stearyl alcohol, cetyl alcohol, cetearyl alcohol, behenyl alcohol, octyldodecanol, lauric acid, myristic acid, stearic acid, palmitic acid, behenic acid, isopropyl myristate, isostearyl lactate, isopropyl palmitate, myristyl myristate, palmityl palmitate, isocetyl palmitate, octyl stearate, oleyl oleate, ethylhexyl hydroxystearate, myristyl myristate, behenyl behenate, oleic acid, linoleic acid, palmitic acid, silicones, such as aminated or non-aminated silicones, and / or mixtures thereof, wherein the compounds are preferably castor oil, mineral oil, isostearyl lactate, isopropyl myristate and / or mixtures thereof. [11] The composition according to any one of the preceding claims, characterized by that it additionally contains one or more polyhydric alcohols, preferably glycerol, propylene glycol, and / or mixtures thereof. [12] The composition according to any one of claims 10 and / or 11, characterized by that the total concentration of lipophilic substances and / or polyhydric alcohols in the hair styling composition is in the range of 0.001% to 95% by weight, preferably the range of 0.05% to 75% by weight, more preferably the range of 0.1% to 50% by weight, more preferably the range of 0.01% to 20% by weight, calculated on the total amount of the composition. [13] The composition according to any one of the preceding claims, characterized by that it contains one or more further hair styling polymers which differ from group a), preferably non-ionic polymers, preferably non-ionic homo- or copolymers with units containing vinylpyrrolidones and / or vinyl acetates and / or biopolymers such as natural or chemically modified cellulose or starch. [14] The composition according to claim 13, characterized bythat the non-ionic polymers are selected from vinylpyrrolidone / vinyl acetate copolymers or polyvinylpyrrolidone homopolymers, and / or mixtures thereof. [15] The composition according to any one of claims 13 to 14, characterized by that the total concentration of the non-ionic polymers ranges from 0.01% to 10% by weight, preferably from 0.05% to 8% by weight, more preferably from 0.1% to 5% by weight, more preferably from 0.5% to 3% by weight, calculated on the total amount of the hair styling composition. [16] An aerosol spray containing the hair styling composition according to any one of claims 1 to 15 and a propellant. [17] The aerosol atomizer according to claim 16, characterized in that the propellant is liquefied petroleum gas, dimethyl ether and / or 1,1-difluoroethane. [18] The aerosol atomizer according to any one of claims 16 and / or 17, characterized in that the total concentration of hair styling composition in the aerosol atomizer is in the range of 10 wt% to 60 wt% and the total amount of propellant is in the range of 40 wt% to 90 wt%, based on the total amount of hair styling composition and propellant.