A raw coal alcohol liquefaction and clean thermal combustion equipment and method based on RSG engineering technology effect

Abstract

The present invention discloses a raw coal alcohol liquefaction process and thermal clean combustion method based on RSG engineering technology effect, including a standard alcohol fuel R unit 1, a temperature-resistant alcohol catalyst is loaded in the primary synthesis gas catalytic chamber 30, and a sulfur-resistant alcohol catalyst is loaded in the circulating synthesis gas catalytic chamber 34 to solve the energy cleanliness; a special combustion equipment S unit 2 is provided with an alcohol fuel special monitor 22 in a two-dimensional mode to monitor the flame, an alcohol fuel special fuel pump 23 for high-pressure fine atomization of the fuel, and an alcohol fuel special air distributor 24 to solve the combustion safety, high efficiency and stability in the heat energy conversion in the alcohol fuel special combustion device 20; an enhanced combustion process G unit 3 is provided with an internal reentry reforming channel 40 on the peripheral wall of the infrared radiation armor 38 to mix part of the flue gas with the sheath and introduce it into the free state to convert NO X The molecules disintegrate and recombine to become CO2 and N2O. The special flue gas condensation device 28 condenses the flue gas and releases chemical energy to solve the pollution control problem efficiently, reliably and economically.

Description

Technical Field

[0001] The present invention relates to the technical field of raw coal liquefaction secondary clean energy and energy-saving and emission-reduction clean thermal combustion, and in particular to a raw coal alcohol liquefaction and clean thermal combustion equipment and method based on RSG engineering technology effects. Background Art

[0002] China is rich in coal, poor in oil, and short of natural gas. Its coal reserves rank second in the world, its total consumption accounts for 50%, and its energy consumption structure accounts for 62%. As of 2012, my country's external dependence on oil reached 70% and natural gas reached 45%. The lack of clean energy has become a hidden danger to my country's energy security. Problems with the use of "coal liquefaction fuel" as a secondary energy source in the thermal combustion of small and medium-sized industrial boilers and kilns in my country's water-coal slurry projects: ① Physical methods have not solved the problem of "sulfur and silicate" fuel pollution in coal slurry; ② Traditional combustion technology refers only to thermal combustion and still requires a large flue gas treatment system to compensate for the technical defects of water-coal slurry components; ③ The operation of dedicated combustion and heating devices is environmentally friendly and cannot meet the basic requirements of flue gas emission indicators in my country's key pollution control areas: "dust 10mmg / Nm3, SO2 20mmg / Nm3, NOX 50mmg / Nm3".

[0003] GB16663-1996 "Alcohol-based liquid fuel" is designed to blend industrial methanol materials into secondary clean energy. The pilot results in thermal industrial boilers and kilns and civilian catering stoves have made positive contributions to my country's replacement of diesel and gasoline and elimination of raw coal, water-coal slurry, and biomass high-pollution fuels, and have reached the level of engineering application technology; however, if traditional alternative engineering applications are still adopted, the common problems of low thermal energy efficiency and high system operating costs will continue, and the carbon steel series metals of the heating device will be corroded, causing safety hazards to the pressure equipment. The production cost of pure industrial-grade methanol chemical materials is high, and the price is affected by the chemical market. The price fluctuation is large, so there are still great limitations in the application of thermal combustion. Although my country currently has many methods of adding a variety of heat enhancers to solve the problem of low calorific value of alcohol-based fuels: adding waste gas, diesel, coal, engine oil, tar, tire oil, kitchen waste oil, etc. to alcohol-based fuels to increase calorific value, and adding nitric acid, ferrocene, potassium permanganate, etc. to alcohol-based fuels to increase chemical reaction speed in order to solve the problem of corrosiveness of flue gas condensate, it will inevitably lead to excessive emissions of SO2, NOX, and dust or lose the economy of clean fuels. Therefore, they are unable to undertake the heavy task of industrializing clean thermal combustion of secondary clean energy from raw coal liquefaction in the industrial field.

[0004] To this end, it is very necessary to develop a secondary clean energy source from coal that is suitable for my country's national conditions, has abundant local resources, is inexpensive and of good quality, and to timely develop advanced clean combustion process technologies for safe, energy-saving, efficient and environmentally friendly systems. "RSG Engineering" is the abbreviation of "years of practice precipitation technology" for the application technology of "alcohol fuel" clean thermal combustion system for coal liquefaction in my country. Its ideal goal is to develop "standard clean fuels, special combustion equipment, and enhanced combustion processes" for the clean treatment of ordinary raw coal, and to achieve "safe, environmentally friendly, efficient, and economical" load-added reduction of thermal combustion pollution from coal resources through the benign superposition of multidisciplinary technologies; its technical purpose is to make up for part of the clean energy needed for the rapid development of my country's national economy and to accelerate the scientificization of systematic engineering technology for ecological environmental restoration; RSG engineering technology has been widely practiced and applied in thermal combustion fields such as small and medium-sized industrial boilers and kilns, mining area heating, etc. in my country, aiming to create a scientific and advanced system engineering technology system for the clean application of my country's coal resources. Summary of the Invention

[0005] The technical problem to be solved by the present invention is to address the above-mentioned deficiencies in the existing engineering technologies for water-coal slurry fuel and alcohol-based fuel, to create a scientific and advanced industrial technology system for the clean application of coal resources, and to provide a raw coal liquefaction alcohol fuel preparation process and furnace alcohol liquid fuel to solve the problem of clean coal energy; a special combustion and heating equipment and process technology for alcohol fuel to solve the problems of combustion safety, high efficiency and stability; and an enhanced combustion process technology for alcohol fuel to solve the problems of pollution control and heat exchange safety, stability, high efficiency, reliability and economy.

[0006] The present invention is designed to provide a process for preparing raw coal liquefied alcohol fuel and alcohol liquid fuel for furnaces, which comprises the following steps: pyrolysis and gasification of raw coal and organic matter into a mixed gas of "CO, H2, etc.", physical removal of "silicate" solid matter in the material, separation of the mixed gas by bathing, synthesis of sulfur from "H2S" gas, chemical recovery of "sulfur" in the material, and preparation of crude synthesis gas, which is catalytically synthesized from the crude synthesis gas into "alcohol liquid fuel" clean energy, achieving the fundamental goal of energy cleanliness and economy in the production process of coal-to-series standard alcohol liquid fuel products by the standard alcohol fuel R unit; a special combustion and heating equipment and process technology for alcohol fuel, undertaken by professional logistics units for "alcohol fuel" For "material transportation", users configure "alcohol fuel special reserve" and furnace safety transportation and fire-fighting facilities to ensure the safety of alcohol fuel in transportation, storage and use. The alcohol fuel special controller of the alcohol fuel special combustion device "accepts and edits" the combustion operation program that adapts to the various working conditions of the heating device, realizing the high adaptability of the special combustion equipment. The alcohol fuel special monitor continuously monitors the working conditions of the alcohol fuel combustion flame in a two-dimensional logical mode, and ensures the consistency of the actual combustion flame and the detection output signal, ensuring the correctness of the commands issued by the alcohol fuel special controller and the safety of the system operation. The alcohol fuel special fuel pump supports the "high-pressure fine" atomization of the alcohol fuel, realizing the high uniformity of the alcohol fuel premixed fuel flow. The uniformity and sufficiency of the combustion airflow field of the alcohol fuel are ensured to be high stable. The "tertiary air" form of the alcohol fuel special air distributor is combined with the "high-pressure fine" atomization and suspended premixing of the fuel to enhance the combustion and support the combustion of the premixed fuel flow, so as to achieve more complete fuel premixing and high combustion rate, and ensure a very high fuel burnout rate. In the form of technical superposition, the S unit of the special combustion equipment is achieved in conjunction with the heating device to support fuel combustion and heat energy conversion to solve the key goals of combustion safety, high efficiency and stability; an alcohol fuel enhanced combustion process technology is designed to generate an accumulation-induced energy level transition effect by the enhanced combustion process device, so as to compress the combustion heat energy to the "infrared" electromagnetic wave band and use "radiation" as the main heat exchange to ensure stable and extremely The high fuel burnout rate also creates conditions for efficient pollution control. The "radiant heat energy" that supports enhanced combustion is coordinated by the re-entry flue gas reforming device to stimulate oxygen-lean free oxygen-rich secondary enhanced combustion, and realize "particle thermal ionization" of the fuel to form an "ion sheath" to suppress and reduce NOX and CO2, ensuring the stability of the ultra-low emission parameters of the flue gas. The dedicated flue gas condensing device supports the flue gas multi-effect condensation air heat exchange, and realizes the centralized discharge of flue gas condensate, ensuring effective prevention of equipment corrosion and further improving the energy efficiency of the system, so as to achieve the goal of solving the core pollution control and heat exchange safety, stability, efficiency, reliability and economy of the "coupled combustion and heating device" of the thermal enhanced combustion process of the G unit in the process of chemical energy release and conversion.

[0007] The technical solution adopted to solve the technical problem of the present invention is to propose a raw coal alcohol liquefaction process and thermal clean combustion method based on the RSG engineering technology effect, including a standard alcohol fuel R unit transported by a pipeline and a tank train or a tank car and connected to a special combustion equipment S unit, benefiting from the point-to-point fuel supply mode, and an enhanced combustion process G unit connected by a heating device and a special combustion equipment S unit, forming a basic process technology structure of raw coal liquefaction clean alcohol fuel, special equipment that burns alcohol fuel safely and reliably and efficiently, and alcohol fuel energy enhanced conversion is stable and efficient, and flue gas emissions are ultra-low.

[0008] Preferably, a raw coal alcohol liquefaction process and thermal clean combustion method based on the RSG engineering technology effect is used, in which the standard alcohol fuel R unit is responsible for converting coal into alcohol liquid fuel to solve the problem of "coal energy cleanliness", the special combustion equipment S unit is responsible for supporting the combustion of alcohol fuel with special combustion equipment in cooperation with the heating device to solve the problem of "safe, efficient and stable combustion of alcohol fuel", and the enhanced combustion process G unit is responsible for the "coupling combustion and heating device" of the thermal enhanced combustion process to solve the problem of "safe, stable, efficient, reliable and economical pollution control and heat exchange" in the process of chemical energy release and conversion. A typical raw coal liquefaction clean thermal combustion RSG engineering technology can be a benign superposition process route model.

[0009] Preferably, the standard alcohol fuel R unit includes a raw coal liquefaction alcohol fuel preparation process and furnace alcohol liquid fuel, and is equipped with an organic resource library, a material preparation device and a material gasification device, which are connected in sequence by a solid material conveying mechanism to form a one-way channel for storage, preparation, conveying and input of solid organic matter; an air separation device, a material gasification device and a slag disposal system are connected in sequence by a gas and solid material conveying mechanism to form a one-way channel for oxygen preparation, input and slag output; a material gasification device, a crude synthesis gas CO conversion device, a heat recovery device, a low-temperature methanol washing system, a compressed synthesis gas buffer device and a primary synthesis gas inlet of the alcohol fuel synthesis device are connected in sequence by a gas material conveying mechanism to form a one-way channel for regulating and conveying synthesis gas; a circulating synthesis gas outlet and a circulating synthesis gas inlet of the alcohol fuel synthesis device and a synthesis gas circulation device, They are connected by a gas material conveying mechanism to form a two-way channel for synthesis gas circulation regulation, input and output; the heat recovery device, low-temperature methanol washing system, methanol synthesis gas sulfur recovery device, and purge gas combustion device are respectively provided with a gas material conveying mechanism connected to the material preparation device for conveying H2O+CO2 gas raw materials. The low-temperature methanol washing system is provided with a set of one-way output pipes connected to the methanol synthesis gas sulfur recovery device for conveying H2S gas, and the H2S gas is burned by the diversion method to recover sulfur. The methanol synthesis gas sulfur recovery device is provided with a set of one-way output pipes connected to the crude synthesis gas CO conversion device for conveying CO2 gas, which is beneficial to the utilization of the system's self-produced CO2 gas, makes up for the demand for partial balance of the CO conversion CO+H2O⇋CO2+H2 process, reduces the cost of production raw materials, and constitutes a typical coal liquefaction alcohol liquid fuel process technology structure.

[0010] It is further preferred that the alcohol fuel synthesis device is provided with two synthesis gas catalytic chambers, and a "temperature-resistant alcohol family" catalyst is loaded in the primary synthesis gas catalytic chamber to improve the catalytic rate and catalyst service life, thereby increasing the alcoholization capacity of the primary synthesis gas and achieving the purpose of reducing production costs; and a "sulfur-resistant alcohol family" catalyst is loaded in the circulating synthesis gas catalytic chamber to improve the catalytic properties of multiple varieties of selective alcohol family in the circulating synthesis gas and resist sulfur dioxide poisoning of the catalyst in the high-sulfur component synthesis gas, thereby further increasing the alcoholization capacity of the circulating synthesis gas and achieving the purpose of further reducing production costs.

[0011] Preferably, the alcohol fuel outlet is connected to the product buffer storage tank in the production area by a pipeline, which is beneficial to the continuous transportation in the production link, and then transported by pipeline and tank train or tank car, which is beneficial to the intermittent transportation in the use link. It is connected to the fuel inlet of the alcohol fuel storage depot of the special combustion equipment S unit. The special combustion device for alcohol fuel is set as an electromechanical integrated device, which is beneficial to improve the stability of the special combustion device. It is connected to the alcohol fuel user reserve depot by a pipeline for transporting alcohol fuel for furnace application.

[0012] A special combustion equipment S unit for a raw coal alcohol liquefaction process and a thermal clean combustion method based on the RSG engineering technology effect includes a special combustion and heating equipment and process technology for alcohol fuels, and is equipped with an alcohol fuel storage depot, an alcohol fuel distribution depot, and a tank truck transport connection with the alcohol fuel user storage depot; the special combustion equipment for alcohol fuels is designed as an electromechanical integrated device, and the pipelines, communication lines and power cables connected to the alcohol fuel user storage depot are connected by the output end of the special air distributor for alcohol fuels and the thermal inlet of the special heating device for alcohol fuels of the special combustion equipment S unit, forming a typical "pre-coupling" special combustion equipment process technology structure for burning alcohol liquid fuels.

[0013] Preferably, the alcohol fuel-specific combustion device has an alcohol fuel-specific program controller integrated with the machine in terms of safety and self-control, so that the physical and chemical parameters of the alcohol fuel series can be matched with the working conditions of the heating device, and the parameter values ​​that can be specially operated can be input in a programmable form, so as to improve the safety, stability and reliability of the thermal combustion system operation and have wider adaptability; in terms of flame safety inspection, it has an alcohol fuel-specific monitor integrated with the machine, which converts the thermoelectric potential value detected in the combustion flame field into a quantum beam value output, realizes the state detection of the "position and presence or absence" of the continuous flame in a two-dimensional logic mode, and achieves the consistency of the random combustion flame working condition and the detection output signal. The signal is connected to the alcohol fuel-specific program controller and the alcohol fuel-specific monitor by a cable to ensure the correctness of the safety command issued by the alcohol fuel-specific program controller; in terms of fuel atomization, it has an alcohol fuel-specific fuel pump integrated with the machine, and the volumetric structure balances the adverse effects of the "cavitation effect of the adjustment + high-pressure delivery" on the stability of the special atomizing pump. By using bionic flexible interference sliding fit and metabolic self-repairing motion wear technology, the motion sealing and service life of the potential energy loading mechanism can be improved, and the pressure, flow, accuracy, stability and adjustability of the output alcohol fuel medium can be achieved, thereby improving the stability of the operation of the special combustion equipment. In terms of combustion-supporting air distribution, a special air distributor for alcohol fuel is integrated with this machine, and the output end of the special air distributor for alcohol fuel is connected to the thermal inlet of the special heating device for alcohol fuel of the special combustion equipment S unit. A premixed fuel flow is formed by tangential mixing of primary air and fuel atomization angle, secondary air is tangentially mixed with the premixed flame to form a spiral vortex to participate in combustion-supporting enhanced combustion, and tertiary air is mixed with fuel particles free at the vortex boundary. The combustion chamber must be strengthened to stimulate high-temperature oxygen-poor free oxygen-rich secondary enhanced combustion to achieve secondary enhanced combustion, thereby achieving not only improving the fuel burnout rate, but also constructing a sheath lining with an external reentry effect for ultra-low emissions or near-zero emissions, thereby creating a coupled basic structural condition for pollution control of the heating device.

[0014] A G unit of an enhanced combustion process for a raw coal alcohol liquefaction process and a thermal clean combustion method based on the RSG engineering technology effect includes an alcohol fuel enhanced combustion process technology, and is provided with various input connections between an alcohol fuel-specific combustion device and an alcohol fuel-specific heating device for conveying materials; one end of a heating device combustion chamber of the alcohol fuel-specific heating device is connected to an alcohol fuel-specific air distributor of the alcohol fuel-specific combustion device for receiving combustion heat energy, and the other end is connected to a flue gas condensing device for receiving flue gas; the space in the combustion chamber of the heating device is coupled with the alcohol fuel-specific combustion device for organizing the basic structure of the alcohol fuel enhanced combustion process, constituting a typical enhanced combustion process and a space for accommodating the structure of a re-entry flue gas reforming device.

[0015] Preferably, in the coupled intensified combustion process of the alcohol fuel-specific heating device, an infrared radiation armor is arranged parallel to the central axis of the alcohol fuel-specific heating device, the tail end of the infrared radiation armor is connected to the combustion chamber of the heating device, and the head end is connected to the alcohol fuel-specific combustion device, and the internal space forms a space for heat-collecting combustion of fuel in the enhanced combustion chamber of the ion sheath formed by radiant heat energy to excite the fuel particles for oxygen-rich secondary intensified combustion, so as to realize heat storage energy level of the armor body reaching transition and transfer heat energy by infrared band radiation, so as to achieve the purpose of releasing heat to the heating device and forming a fuel intensified combustion chamber, so as to improve the fuel burnout rate and the thermal energy efficiency of the heating device, and constitute a typical RSG high-temperature oxygen-poor excitation oxygen-rich gain effect intensified combustion structure.

[0016] Preferably, in terms of pollution control of the alcohol fuel-specific heating device coupled to the alcohol fuel-specific combustion device, the enhanced combustion process is provided with a re-entry flue gas reforming device for reducing the NOx value. The tail end of the infrared radiation armor is connected to the combustion chamber of the heating device, and the head end is connected to the alcohol fuel-specific combustion device, so that the infrared band radiation heat energy can excite the thermal ionization of the fuel particles in the oxygen-enriched secondary enhanced combustion of the fuel, achieve high-speed combustion tending towards the plasma state, and form an ion sheath, forming a typical enhanced combustion high-temperature zone structure, and creating the basic conditions for high-temperature physical reactions for pollution control.

[0017] It is further preferred that the peripheral wall of the head end of the infrared radiation armor is provided with an internal re-entry reforming channel for combustion space and delivery of ultra-high temperature flue gas, which connects the combustion chamber of the heating device with the enhanced combustion chamber, and serves as a channel for gas circulation, so that part of the high-temperature flue gas enters the enhanced combustion chamber from the internal re-entry reforming channel and is mixed with the sheath and introduced into a free state to sub-disintegrate the NOX molecules, so that some of the oxygen molecules therein participate in the free state combustion of more active C, CO, and H2 compounds, and when the oxygen covalent bond of N2O3 is sub-broken, it is promptly sub-bound by other molecules or atoms, and the competitive reaction becomes a new substance, such as C atoms are recombined to become CO2 and N2O, thereby creating a place for chemical reaction for pollution control, forming a load-increasing inhibition and reduction of flue gas pollutants.

[0018] It is further preferred that an appropriate space is provided between the outer wall of the infrared radiation armor and the inner wall of the combustion chamber of the heating device to form a high-temperature flue gas re-entry reforming channel, which is connected to the alcohol fuel-specific combustion device by the reforming flue gas delivery pipe to deliver part of the high-temperature circulating flue gas, so as to realize the pre-mixing of the high-temperature circulating flue gas with the fuel flow, thereby achieving the purpose of enhancing the efficient combustion of low α values ​​in the combustion chamber, pollution suppression and reforming reduction, improving the utilization rate of the combustion aid, and reducing the heat loss of the flue gas.

[0019] Preferably, the head end of the dedicated flue gas condensation device is communicated with the combustion chamber of the heating device, and the tail end is directly emptied or connected to the chimney of the dedicated heating device for alcohol fuels. A honeycomb air condensation bundle tube is provided to support the heat exchange between the flue gas and the air, thereby realizing the centralized discharge of flue gas condensate water, thereby achieving the purpose of reducing white smoke plume, preventing equipment corrosion and further improving the energy efficiency of the system, forming an synergistic treatment of flue gas pollutants, and solving the problem of condensate water corroding the heating device.

[0020] The present invention has the following beneficial effects: The present invention proposes a coal liquefaction alcohol fuel preparation process and furnace alcohol liquid fuel based on RSG engineering technology effect, which solves the fundamental energy cleanliness problem by using the standard alcohol fuel R unit. The coal-to-alcohol chemical technology process route produces low-carbon alcohol CH4O~ C4H10O clean liquid fuel can be widely used in 90% of my country's raw coal varieties. Its superimposed catalytic proprietary technology and mixed alcohol catalytic process can increase the catalytic yield by more than 30%, and reduce the product production cost by more than 20% compared with methanol. The standard calorific value of its alcohol products is 20.93MJ≈5000kcal / kg~29.30MJ≈7000kcal / kg, which can fully meet the technical index requirements of clean liquid fuel for "thermal flame combustion" of industrial boilers and kilns; a special combustion and heating equipment and process technology for alcohol fuels, which solves the key problems of combustion safety, high efficiency and stability by using a special combustion equipment S unit. A special program controller can programmatically support the synchronization of the special operating parameter values ​​of the alcohol fuel special fuel pump and the heating device, promoting the fuel burnout rate to reach more than 99%; a two-dimensional logic mode continuously monitors the fire The flame is ensured to be correct, safe and stable in combustion program control; the tertiary air special air distributor is coupled with the heating device, and the enhanced combustion process is used to construct an ultra-low emission or near-zero emission structure. The design specifications of the special combustion and heating equipment series can reach 2100MW / h, which can fully meet the key technical requirements of special equipment for thermal flame combustion of boilers and kilns in the industrial field; an alcohol fuel enhanced combustion process technology, in which the enhanced combustion process G unit solves the core pollution control and heat exchange safety, stability, efficiency, reliability and economy issues. The infrared radiation armor realizes the radiation transfer of heat energy with energy level jump, promoting the system energy efficiency to >93%; the enhanced combustion chamber is coupled with a special combustion device to re-enter the flue gas and the sheath in a mixed free state for combustion, promoting the initial flue gas concentration emission to reach the ultra-low emission indicators of dust ≤10mg / Nm3, SO2 ≤20mg / Nm3, and NOX ≤30mg, which can fully meet the current core indicators of extreme protection of thermal flame combustion around the world. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] Figure 1 This is a process principle flow chart of a raw coal alcohol liquefaction process and a thermal clean combustion method based on the RSG engineering technology effect of the present invention.

[0022] Figure 2 It is a cross-sectional schematic diagram of the alcohol fuel synthesis device of the standard alcohol fuel R unit process of the present invention.

[0023] Figure 3 This is a schematic cross-sectional view of the alcohol fuel-specific heating device of the G unit of the enhanced combustion process of the present invention.

[0024] Figure: 1. Standard Alcohol Fuel R Unit 2. Special Combustion Equipment S Unit 3. Enhanced Combustion Process G Unit 4. Organic Resource Repository 5. Air Separation Unit 6. Material Preparation Unit 7. Material Gasification Unit 8. Crude Synthesis Gas CO Shift Unit 9. Heat Recovery Unit 10. Slag Disposal System 11. Low-Temperature Methanol Washing System 12. Methanol Synthesis Gas Sulfur Recovery Unit 13. Compressed Synthesis Gas Buffer Unit 14. Alcohol Fuel Synthesis Unit 15. Synthesis Gas Circulation Unit 16. Purge Gas Combustion Unit 17. Alcohol Fuel Storage Depot 18. Alcohol Fuel Distribution Depot 19. Alcohol Fuel User Reserve 20. Alcohol Fuel Special Combustion Unit 21. Alcohol Fuel Special Programmable controller 22. Alcohol fuel-specific monitor 23. Alcohol fuel-specific fuel pump 24. Alcohol fuel-specific air distributor 25. Alcohol fuel-specific heating device 26. Re-entry flue gas reforming device 27. Enhanced combustion process device 28. Flue gas condensing device 29. Primary synthesis gas inlet 30. Primary synthesis gas catalyst chamber 31. Mixed alcohol stabilization chamber 32. Alcohol fuel outlet 33. Recycled synthesis gas inlet 34. Recycled synthesis gas catalyst chamber 35. Recycled synthesis gas outlet 36. Heating device combustion chamber 37. Enhanced combustion chamber 38. Infrared radiation armor 39. Flue gas re-entry reforming channel 40. Internal re-entry reforming channel 41. Reformed flue gas conveying pipe. DETAILED DESCRIPTION

[0025] In order to enable those skilled in the art to better understand the technical solution of the present invention, the following is a further detailed description of a raw coal alcohol liquefaction process and thermal clean combustion method based on RSG engineering technology effects proposed by the present invention, combined with the accompanying drawings and an implementation case.

[0026] See Figure 1 This embodiment discloses a raw coal alcohol liquefaction process and thermal clean combustion method based on RSG engineering technology effect, including a standard alcohol fuel R unit (1) to liquefy coal into low-carbon alcohol CH4O~ C4H10O clean energy is transported by pipelines and tank trains or tank cars and connected to the special combustion equipment S unit (2); the special combustion equipment S unit (2) uses special combustion and heating equipment tailored to the characteristics of alcohol fuel to improve the safety of fuel use and the burnout rate, and is coupled with the enhanced combustion process to construct the conditions for high-temperature physical reaction of pollution control; the enhanced combustion process G unit (3) is connected by the heating equipment and the special combustion equipment S unit (2), and is used to transfer heat energy by infrared radiation tailored to the characteristics of alcohol fuel, improve the thermal energy efficiency of the heating device, and is coupled with the special combustion device to construct a place for high-temperature chemical reaction of pollution control; the basic process technology structure of raw coal liquefaction clean alcohol fuel, safe and reliable special equipment, efficient combustion of alcohol fuel, stable and efficient energy enhanced conversion of alcohol fuel, and ultra-low flue gas emissions, that is, a typical clean thermal combustion RSG engineering technology process technology route system with a benign superposition effect.

[0027] See Figure 1 、 Figure 2 The standard alcohol fuel R unit (1) applies the process route of raw coal liquefaction clean thermal combustion RSG engineering technology to transform coal into alcohol liquid fuel and solve the problem of "clean coal energy". It includes an organic resource library (4), a material preparation device (6) for preparing organic solid materials and a material gasification device (7) for generating gaseous materials, which are connected in sequence by a solid material conveying mechanism to form a one-way channel for storage, preparation, conveying and input of solid organic matter; an air separation device (5) separates O2 in the air, a material gasification device (7) for generating gaseous materials and separating silicate substances in coal organic materials and a slag disposal system (10) which is connected in sequence by gas and solid material conveying mechanisms to form a one-way channel for oxygen input and slag output; the crude synthesis gas generated by the material gasification device (7) is adjusted in gas composition by a crude synthesis gas CO conversion device (8), and a heat recovery device (9) is used to convert CO into The heat energy generated by the exchange is used to generate electricity and provide the heat energy required for material preparation. The low-temperature methanol washing system (11) is used to separate sulfides. The compressed synthesis gas buffer device (13) is used to generate potential energy and to synthesize the alcohol fuel product with the catalyst of the alcohol fuel synthesis device (14). The primary synthesis gas inlet (29) is connected in sequence by a gas material conveying mechanism to form a one-way channel for conveying synthesis gas; the circulating synthesis gas outlet (35) and the circulating synthesis gas inlet (33) of the alcohol fuel synthesis device (14) are connected to the synthesis gas circulation device (15) by a gas material conveying mechanism to form a two-way channel for synthesis gas circulation input and output, which is used for the circulation and transportation of synthesis gas; the heat recovery device (9), the low-temperature methanol washing system (11), the methanol synthesis gas sulfur recovery device (12), and the purge gas combustion device (16) are respectively provided with a gas material conveying mechanism to connect to the material preparation device (6) for conveying H2O+CO2 gas raw materials.

[0028] The low-temperature methanol washing system (11) is provided with two sets of one-way output pipes connected to the crude synthesis gas CO conversion device (8) and the material preparation device (6) for conveying CO2 and H2O steam gas, and sending the excess CO2 and H2O gas to the material preparation device (6) for the material gasification device to carry out the CO2+H2O+C pyrolysis reforming treatment. Another set of one-way output pipes is provided to communicate with the methanol synthesis gas sulfur recovery device (12) for conveying H2S gas.

[0029] The synthesis gas circulation device (15) is provided with a set of one-way output pipes connected to the purge gas combustion device (16) for conveying the purge mixed gas; the purge gas combustion device (16) is provided with a one-way output pipe connected to the raw synthesis gas CO conversion device (8) and the material preparation device (6) for conveying CO2 gas, and sending the excess CO2 gas to the material preparation device (6) for the material gasification device to carry out the CO2+H2O+C pyrolysis reforming treatment.

[0030] The alcohol fuel synthesis unit (14) is provided with two synthesis gas catalytic chambers. A "heat-resistant alcohol" catalyst is loaded in the primary synthesis gas catalytic chamber (30), which is beneficial to improving the service life of the catalyst and used for catalyzing the synthesis of alcohol fuel products from high-temperature synthesis gas, thereby increasing the alcoholization capacity of the primary synthesis gas; and a "sulfur-resistant alcohol" catalyst is loaded in the circulating synthesis gas catalytic chamber (34), which is beneficial to improving the service life of the catalyst and used for catalyzing the synthesis of alcohol fuel products from circulating synthesis gas, thereby improving the catalytic performance of multiple varieties of selective alcohols in the circulating synthesis gas and resisting sulfur dioxide poisoning of the catalyst in the high-sulfur component synthesis gas, thereby further increasing the alcoholization capacity of the circulating synthesis gas, and improving the catalytic efficiency and capacity of the alcohol fuel synthesis unit (14), and reducing production costs.

[0031] The alcohol fuel outlet (32) is connected to the buffer storage tank in the production area by a pipeline, and then connected to the fuel inlet of the alcohol fuel storage tank (17) of the dedicated combustion equipment S unit (2) by a pipeline and a tank train or tank truck, which is beneficial to large-scale point-to-point supply.

[0032] See Figure 1 The special combustion equipment S unit (2) applies the RSG engineering technology process route of raw coal liquefaction clean thermal combustion, and the special combustion equipment including the heating device is responsible for solving the safety, efficiency and stability problems of clean combustion of alcohol liquid fuel, including the alcohol fuel storage warehouse (17) for large-scale storage of alcohol fuel, the alcohol fuel distribution warehouse (18) for small-scale storage of alcohol fuel and the alcohol fuel user storage warehouse (19) for terminal user storage of alcohol fuel. The alcohol fuel is connected by tank truck transportation, which is beneficial to decentralized small-scale point-to-point supply; the alcohol fuel special combustion device (20) is used for the safe and efficient combustion of alcohol fuel, is designed as an electromechanical integrated device, is beneficial to automatic control, and is equipped with a pipeline to connect with the alcohol fuel user storage warehouse (19).

[0033] In terms of safety and automatic control, the alcohol fuel-specific combustion device (20) is equipped with an alcohol fuel-specific program controller (21) integrated with the machine, which facilitates automated program communication between the burner and the centralized control center.

[0034] In terms of flame safety inspection, the alcohol fuel-specific combustion device (20) is equipped with an alcohol fuel-specific two-dimensional logic monitor (22) integrated with the machine, which helps to ensure the reliability and safety of the combustion system flame detection.

[0035] In terms of fuel atomization, the alcohol fuel-specific combustion device (20) is provided with an alcohol fuel-specific fuel pump (23) integrated with the machine, which helps to ensure the stability of the working pressure of the alcohol fuel atomizer.

[0036] The alcohol fuel-specific combustion device (20) is provided with an alcohol fuel-specific air distributor (24) integrated with the machine in terms of combustion-supporting air distribution; the output end of the alcohol fuel-specific air distributor (24) is connected to the thermal inlet of the alcohol fuel-specific heating device (25) of the dedicated combustion equipment S unit (2) for inputting the premixed fuel flow.

[0037] See Figure 1 、 Figure 3 The enhanced combustion process G unit (3) applies the RSG engineering technology process route of raw coal liquefaction clean thermal combustion, undertakes the infrared radiation heat energy transfer of alcohol liquid fuel, and couples the combustion device to solve the problem of enhanced energy conversion of alcohol fuel and energy saving and emission reduction of flue gas pollutants, including the technical support of the alcohol fuel-specific combustion device (20) and the various input connections of the alcohol fuel-specific heating device (25); one end of the heating device combustion chamber (36) of the alcohol fuel-specific heating device (25) is connected to the alcohol fuel-specific air distributor (24) of the alcohol fuel-specific combustion device (20) for organizing the flame shape, and the other end is connected to the flue gas condensing device (28); the space of the heating device combustion chamber (36) is coupled with the alcohol fuel-specific combustion device (20) to form an enhanced combustion process (27) and a space for accommodating the structure of the re-entry flue gas reforming device (26).

[0038] Among them, the re-entry flue gas reforming device (26) is used for reforming flue gas, and is provided with an infrared radiation armor (38) for constructing an enhanced combustion chamber. The head end of the infrared radiation armor (38) is provided with an internal re-entry reforming channel (40) for constituting a flue gas reforming place, which connects the heating device combustion chamber (36) and the enhanced combustion chamber (37) to form a gas circulation channel.

[0039] Among them, the alcohol fuel-specific heating device (25) is used to receive the chemical heat energy of the alcohol fuel combustion. In terms of the enhanced combustion process, an infrared radiation armor (38) is provided in the body and is arranged parallel to the central axis of the alcohol fuel-specific heating device (25). The inner space of the infrared radiation armor (38) constitutes an enhanced combustion chamber (37) to form a fuel heat-gathering combustion space. After the heat storage energy level of the armor body reaches a transition, the infrared band radiation transfers heat energy to achieve heat release to the heating device and form a fuel enhanced combustion chamber.

[0040] Among them, the alcohol fuel-specific heating device (25) is provided with a re-entry flue gas reforming device (26) for pollution control in conjunction with the alcohol fuel-specific combustion device (20) in terms of enhanced combustion process. The tail end of the infrared radiation armor (38) is connected to the combustion chamber (36) of the heating device, and the head end is connected to the alcohol fuel-specific combustion device (20), forming infrared band radiation heat energy to stimulate the thermal ionization of fuel particles for oxygen-poor free oxygen-rich secondary enhanced combustion, achieving the purpose of high-speed combustion toward plasma state to form an ion sheath, and establishing a high-temperature tool for reducing pollutants.

[0041] The infrared radiation armor (38) is provided with an inner re-entry reforming channel (40) on the peripheral wall of the front end, which is beneficial to the production of the complete set of equipment. The inner re-entry reforming channel connects the combustion chamber (36) of the heating device with the enhanced combustion chamber (37), and serves as a channel for gas circulation, so that part of the flue gas re-enters the enhanced combustion chamber (37) from the inner re-entry reforming channel (40) and is mixed with the sheath and introduced into the free state to sub-disintegrate the NOX molecules for N times of combustion, wherein part of the oxygen molecules participate in the combustion of C, CO, and H2 in the free state with higher activity, so as to achieve the purpose of being sub-bound by other molecules or atoms when the oxygen covalent bond of N2O3 is sub-broken, and the competitive reaction is transformed into new substances, such as C atoms are re-combined to become CO2 and N2O.

[0042] Among them, an appropriate space is provided between the outer wall of the infrared radiation armor (38) and the inner wall of the combustion chamber (36) of the heating device, forming a flue gas re-entry reforming channel (39) which is connected to the alcohol fuel dedicated combustion device (20) by the reforming flue gas delivery pipe (41), and delivers part of the circulating flue gas to achieve pre-mixing of the circulating flue gas with the fuel flow, so as to achieve the purpose of enhancing the high-efficiency combustion with a low α value of 1.01 in the combustion chamber (37), pollution suppression and reforming reduction.

[0043] The head end of the dedicated flue gas condensing device (28) is connected to the combustion chamber (36) of the heating device, and the tail end is directly emptied or connected to the chimney of the dedicated heating device (25) for alcohol fuel. A honeycomb air condensation bundle tube is provided to support the heat exchange between the flue gas and the air, so as to realize the centralized discharge of the flue gas condensate, thereby achieving the purpose of reducing white smoke plume, preventing equipment corrosion and further improving the energy efficiency of the system.

[0044] The operation process of the above-mentioned raw coal alcohol liquefaction process and thermal clean combustion method based on the RSG engineering technology effect is as follows.

[0045] Standard alcohol fuel R unit (1) operates on solid organic matter liquefied alcohol liquid fuel.

[0046] See Figure 1As shown, the preferred channels for head-end resources should be open-pit coal mines, raw coal from pit-mouth mining areas, and organic matter from agricultural reclamation areas, which are classified and input into the organic resource library (4), and are measured and transported by the solid material conveying mechanism into the material preparation device (6) for routine preparation; the materials that meet the process requirements are then input into the material gasification device (7) by the solid material conveying mechanism for pyrolysis and gasification; CO2 + H2O carbon dioxide and water vapor from the heat recovery device (9), low-temperature methanol washing system (11), methanol synthesis gas sulfur recovery device (12), and exhaust gas combustion device (16) are fed into the material gasification device (7) as part of the gasifying agent to undergo pyrolysis and gasification reaction with the hot materials to produce a crude mixed gas.

[0047] The O2 oxygen produced by the air separation unit (5) is introduced into the material gasification unit (7) by the gas material conveying mechanism, and is used as a part of the gasifying agent to carry out a pyrolysis and gasification reaction with the hot material fed into the material gasification unit (7). The silicate mixed solid material remaining after the pyrolysis is conveyed into the slag disposal system (10) by the solid material conveying mechanism to produce light building material products for sale in the social market, thereby achieving the goal of eliminating the secondary pollution of the slag in the production process and the comprehensive utilization of waste; the first goal of this chemical reaction section is to remove silicate substances so that the flue gas dust emission indicators of the downstream clean fuel products in the thermal combustion meet the environmental protection requirements.

[0048] The crude mixed gas from the material gasification device (7) is subjected to a CO+H2O ⇋CO2+H2 process conversion by the crude synthesis gas CO conversion device (8) to achieve a balance of process parameters of the crude synthesis gas; the crude synthesis gas is passed through a heat recovery device (9) to replace part of the heat energy, and the heat work is used to generate electricity and provide the heat energy required for material preparation, and part of the water vapor is used as the main gasification agent for CO2+H2O+C pyrolysis reforming; the crude synthesis gas is then removed by a low-temperature methanol washing system (11) to remove CO2, H2S and organic sulfur impurities in the conversion gas, and at the same time remove the saturated water brought into the conversion gas. The low-temperature methanol washing system (11) is provided with a set of one-way output pipes connected to the methanol synthesis gas sulfur recovery device (12), and the H2S gas is transported to recover sulfur by burning the H2S gas by a diversion method, and the qualified primary synthesis gas is input into the compressed synthesis gas buffer device (13); when the heat recovery device (9), the low-temperature methanol washing system (11), and the methanol synthesis gas sulfur recovery device (12) are in operation, the excess CO2 and H2O gases are sent to the material preparation device (6), and the material gasification device performs CO2+H2O+C thermal decomposition and reforming treatment; the first goal of the chemical reaction section is to remove S organic sulfur substances, so that the SO2 emission index of the flue gas of the thermal combustion of the downstream clean fuel product meets the environmental protection requirements, thereby reducing the raw material cost in the production process link and improving the cleanliness of the fuel production link.

[0049] See Figure 1 、 Figure 2As shown, the primary synthesis gas from the compressed synthesis gas buffer device (13) is introduced into the alcohol fuel synthesis device (14) through the primary synthesis gas inlet (29) to react with the "temperature-resistant alcohol family" catalyst loaded in the primary synthesis gas catalytic chamber (30), and the synthesized alcohol family compounds are collected in the mixed alcohol stabilization chamber (31). The synthesis gas that escapes after the primary catalysis is forced to circulate by the synthesis gas circulation device (15) by connecting the circulating synthesis gas outlet (35) of the alcohol fuel synthesis device (14) and the circulating synthesis gas inlet (33). The circulating synthesis gas reacts with the "sulfur-resistant alcohol family" catalyst loaded in the circulating synthesis gas catalytic chamber (34), and the synthesized alcohol family compounds are collected in the mixed alcohol stabilization chamber (31) to increase the synthesis rate. The first goal of this chemical reaction section is to increase the synthesis rate of alcohol family materials, increase production capacity, and reduce production costs. The above-mentioned routine route of liquefying solid organic matter into alcohol family liquid fuel is one of the process technology routes with a typical clean thermal combustion RSG engineering technology that can achieve a benign superposition effect.

[0050] The alcohol materials in the mixed alcohol stabilization bin (31) are transported from the alcohol fuel outlet (32) through a pipeline to the buffer storage tank in the production area or the alcohol fuel storage depot (17) of the dedicated combustion equipment S unit (2); those transported over long distances are then transported by pipeline and tank train or tank truck and connected to the fuel inlet of the alcohol fuel storage depot (17) of the dedicated combustion equipment S unit (2), completing the transportation of the alcohol fuel from the production area to the use area.

[0051] Special combustion equipment S unit (2) Special alcohol liquid fuel combustion equipment operation.

[0052] See Figure 1 、 Figure 3 As shown, the alcohol fuel storage depot (17), the alcohol fuel distribution depot (18) and the alcohol fuel user reserve depot (19) are connected by tank trucks and transported to the terminal user's reserve depot. The alcohol fuel is stored in the alcohol fuel user reserve depot (19) for standby use in accordance with relevant requirements; the alcohol fuel is transported to the furnace by a dedicated transport mechanism and connected to the alcohol fuel dedicated combustion device (20) to ensure the supply of alcohol fuel in front of the furnace.

[0053] According to the type of the heating device (25) and the requirements of the combustion process technical parameters, the operating procedures and related parameters of the alcohol fuel special program controller (21) are set to ensure the stability of the operation of the special equipment.

[0054] According to the type of the heating device (25) and the combustion process, specific parameters of the flame safety inspection of the alcohol fuel dedicated combustion device (20) during operation are set, such as setting the flame root safety extension distance Xmm and the flame intensity quantum beam safety self-locking value X beam of the alcohol fuel dedicated monitoring instrument (22) to ensure the safety of the dedicated equipment operation.

[0055] According to the type of the heating device (25) and the output required by the load of the alcohol fuel dedicated combustion device (20), the specific parameters of the alcohol fuel dedicated combustion device (20) in terms of fuel atomization are set, such as the output pressure value kgf / cm2 and the output flow value L / h of the alcohol fuel dedicated fuel pump (23), to ensure the uniformity and stability of the atomization of the dedicated equipment during operation.

[0056] According to the type of the heating device (25) and the requirements of the load output and flame shape of the alcohol fuel dedicated combustion device (20), the specific parameters of the alcohol fuel dedicated combustion device (20) in terms of combustion-supporting air distribution are set, such as the wind speed m / s and the total mixed flow rate Nm3 / h of the alcohol fuel dedicated air distributor (24), to ensure that the premixed fuel flow is coupled with the heating device to produce the set enhanced combustion. The routine setting of the above-mentioned dedicated alcohol liquid fuel combustion equipment is a typical combustion method that can achieve a benign superposition effect of clean thermal combustion RSG engineering technology.

[0057] The alcohol fuel-specific combustion device (20) is allowed to start, and the alcohol fuel-specific fuel pump (23) loads potential energy for the alcohol fuel medium and sprays it out from the atomizer, and pre-mixes it with the mixed combustion agent added by the alcohol fuel-specific air distributor (24) to form a fuel flow. The fuel flow is ignited by the ignition, and under the connection between the output end of the alcohol fuel-specific air distributor (24) and the heat inlet of the alcohol fuel-specific heating device (25), a flame shape is formed according to the set parameter values, and it burns safely, stably and continuously, generating a chemical energy heat source for the end user.

[0058] Enhanced combustion process G unit (3) Alcohol liquid fuel enhanced combustion operation.

[0059] See Figure 1 、 Figure 3 The enhanced combustion process G unit (3) includes support for various enhanced combustion parameters of the alcohol fuel-specific combustion device (20) and is connected to various inputs of the alcohol fuel-specific heating device (25), forming an enhanced combustion process structure with a benign superposition effect of clean thermal combustion RSG engineering technology; one end of the heating device combustion chamber (36) of the alcohol fuel-specific heating device (25) is connected to the alcohol fuel-specific air distributor (24) of the alcohol fuel-specific combustion device (20), and receives the alcohol fuel-specific air distributor (24) from the dedicated combustion equipment S unit (2) to support the combustion flame into the enhanced combustion chamber (37) for safe, stable and continuous heat release.

[0060] In terms of the enhanced combustion process of the alcohol fuel-specific heating device (25), the infrared radiation armor (38) provided in the body constitutes an enhanced combustion chamber (37) to form a fuel heat-gathering combustion space. The combustion flame enters the enhanced combustion chamber (37) and releases heat stably and continuously. When the heat storage energy level of the armor body reaches a transition, it will generate infrared radiation to transfer heat energy to the heating device combustion chamber (36), thereby releasing heat to the heating device and forming enhanced combustion of the premixed fuel, forming a typical RSG high-temperature oxygen-poor excitation oxygen-rich gain effect enhanced combustion structure, releasing heat energy to the water medium in the heating device, and the water vapor generated by the water medium is used for downstream production.

[0061] The flue gas that has undergone primary enhanced combustion in the enhanced combustion chamber (37) all enters the combustion chamber (36) of the heating device for flue gas convection heat exchange, and a portion of the flue gas re-enters the reforming channel (39) for secondary enhanced combustion and convection heat release to the alcohol fuel-specific heating device (25) before serving as the external re-entry flue gas medium.

[0062] Part of the flue gas from the flue gas re-entry reforming channel (39) is transported to the alcohol fuel dedicated combustion device (20) through the reforming flue gas delivery pipe (41), and the pre-mixed fuel flow is coupled to promote the radiation of thermal energy in the infrared band, stimulate the thermal ionization of the fuel particles in the oxygen-rich secondary enhanced combustion, and achieve high-speed combustion in the plasma state to form an ion sheath, thereby creating high-temperature physical conditions for flue gas reforming.

[0063] Part of the flue gas from the flue gas re-entry reforming channel (39) enters the enhanced combustion chamber (37) through the internal re-entry reforming channel (40) provided on the peripheral wall of the front end of the infrared radiation armor (38) to mix with the ion sheath to achieve internal re-entry reforming. The flue gas is introduced into the free state by the high-temperature sheath to sub-disintegrate the NOX molecules and perform N cycles of enhanced combustion, so that some of the oxygen molecules therein participate in the combustion of C, CO, and H2 in a free state with higher activity. When the oxygen covalent bond of N2O3 is sub-broken, it is sub-bound by other molecules or atoms and competitively reacts to become new substances. For example, C atoms are re-combined to become CO2 and N2O, thereby achieving the suppression of NOX and partial reforming.

[0064] Part of the flue gas from the flue gas re-entering reforming channel (39) is transported by the reforming flue gas delivery pipe (41) to the alcohol fuel dedicated combustion device (20), and the premixed fuel flow is coordinated to promote high-temperature excitation of oxygen-poor free oxygen-rich enhanced combustion. The recycled flue gas participates in the premixing of the fuel flow, and when the low α value of 1.01 is reached in the enhanced combustion chamber (37), oxygen-poor and efficient enhanced combustion can still be achieved, thereby achieving the goal of maximizing the reduction of combustion aid consumption, reducing flue gas emissions and suppressing NOX synthesis.

[0065] All the flue gases from the combustion chamber (36) of the heating device are supported by the honeycomb air condensation bundle tubes provided in the special flue gas condensation device (28) for heat exchange between the flue gas and the air, so as to realize the centralized discharge of the flue gas condensate, thereby achieving the purpose of reducing white smoke plume, preventing equipment corrosion and further improving the energy efficiency of the system. The tail end of the special flue gas condensation device (28) is connected to the chimney of the alcohol fuel special heating device (25) or is directly emptied. The initial concentration of the discharged flue gas can reach the ultra-low emission indicators of dust ≤10mg / Nm3, SO2 ≤20mg / Nm3, and NOX ≤30mg, which is completely superior to the core requirements of extreme protection of thermal flame combustion around the world.

[0066] It should be understood that the implementation of the embodiment is merely an exemplary implementation adopted to illustrate the process equipment structure and the principle of enhanced combustion technology of the present invention, and therefore the present invention is not limited thereto.

[0067] For example, a standard alcohol fuel R unit (1) is a solid organic matter liquefied alcohol liquid fuel, and the raw materials for gasification can also be biomass including agricultural and forestry organic waste, urban life organic waste, petroleum coke powder, coal gangue, oil shale, etc.

[0068] Alcohol fuel products can also be used to synthesize high-carbon alcohol fuel products; they can also be blended into clean fuels for volumetric pulse power combustion; they can also be directly used in industries such as stoves in folk catering.

[0069] Therefore, we should understand that for ordinary technicians in this field, various modifications and improvements can be made without departing from the spirit and essential principles of the present invention. However, these modifications and improvements should be regarded as within the scope of protection of the present invention.

Claims

1. A raw coal alcohol liquefaction and clean thermal combustion equipment based on RSG engineering technology, comprising: The standard alcohol fuel R unit (1) is connected to the special combustion equipment S unit (2) by pipeline and tank train or tank car transportation, and the heating equipment of the enhanced combustion process G unit (3) is connected to the special combustion equipment S unit (2); the standard alcohol fuel R unit (1) is responsible for converting coal into alcohol liquid fuel, the special combustion equipment of the special combustion equipment S unit (2) cooperates with the heating device to support the combustion of the alcohol fuel, and the enhanced combustion process G unit (3) is responsible for the process of chemical energy release and conversion of the "coupled combustion and heating device" of the thermal enhanced combustion process; it is characterized by: The standard alcohol fuel R unit (1) comprises: an organic resource library (4), a material preparation device (6) and a material gasification device (7) connected in sequence by a solid material conveying mechanism; an air separation device (5), a material gasification device (7) and a slag disposal system (10) connected in sequence by a gas and solid material conveying mechanism; a material gasification device (7), a crude synthesis gas CO conversion device (8), a heat recovery device (9), a low-temperature methanol washing system (11), a compressed synthesis gas buffer device (13) and a primary synthesis gas inlet of the alcohol fuel synthesis device (14) The ports (29) are sequentially connected by a gas material conveying mechanism, and the circulating synthesis gas outlet (35) and the circulating synthesis gas inlet (33) of the alcohol fuel synthesis device (14) are connected to the synthesis gas circulation device (15) by the gas material conveying mechanism, forming a two-way channel for the synthesis gas circulation input and output. The heat recovery device (9), the low-temperature methanol washing system (11), the methanol synthesis gas sulfur recovery device (12), and the relaxation gas combustion device (16) respectively convey H2O+CO2 gas raw materials to the material preparation device (6) through the provided gas material conveying mechanism. The enhanced combustion process G unit (3) comprises: a heating device (25) dedicated for alcohol fuel, wherein a heating device combustion chamber (36) is provided; one end of the heating device combustion chamber (36) is connected to the alcohol fuel dedicated air distributor (24) of the alcohol fuel dedicated combustion device (20) for organizing the flame shape, and the other end is connected to the flue gas condensing device (28); An infrared radiation armor (38) is also provided in the body of the alcohol fuel-specific heating device (25). The infrared radiation armor (38) is arranged parallel to the central axis of the alcohol fuel-specific heating device (25). The infrared radiation armor (38) is accommodated inside the combustion chamber (36) of the heating device; the tail end of the infrared radiation armor (38) is connected to the combustion chamber (36) of the heating device, and the head end is connected to the alcohol fuel-specific combustion device (20). The inner space of the infrared radiation armor (38) constitutes an enhanced combustion chamber (37) and forms a fuel heat-gathering combustion space, so that after the heat storage energy level of the infrared radiation armor (38) body reaches a transition, heat energy is transferred by infrared radiation to release heat to the heating device.

2. The raw coal alcohol liquefaction and clean thermal combustion equipment based on RSG engineering technology effect according to claim 1 is characterized in that The dedicated combustion equipment S unit (2) includes: an alcohol fuel storage depot (17), an alcohol fuel distribution depot (18), and an alcohol fuel user storage depot (19), which are connected by tank trucks; and an alcohol fuel dedicated combustion device (20) is configured as a mechatronics integrated device, which is connected to the alcohol fuel user storage depot (19) through a pipeline.

3. The raw coal alcohol liquefaction and clean thermal combustion equipment based on RSG engineering technology effect according to claim 2 is characterized by The alcohol fuel-specific combustion device (20) is equipped with an alcohol fuel-specific program controller (21), an alcohol fuel-specific monitoring device (22), an alcohol fuel-specific fuel pump (23), and an alcohol fuel-specific air distributor (24) integrated with the machine. The output end of the alcohol fuel-specific air distributor (24) is connected to the heat inlet of the alcohol fuel-specific heating device (25) of the enhanced combustion process G unit (3).

4. The raw coal alcohol liquefaction and clean thermal combustion equipment based on RSG engineering technology effect according to claim 3 is characterized by: An inner reentry reforming channel (40) is provided on the peripheral wall of the front end of the infrared radiation armor (38), connecting the combustion chamber (36) of the heating device with the enhanced combustion chamber (37), and part of the high-temperature flue gas enters the enhanced combustion chamber (37) through the inner reentry reforming channel (40).

5. The raw coal alcohol liquefaction and clean thermal combustion equipment based on RSG engineering technology effect according to claim 4 is characterized in that The head end of the flue gas condensation device (28) is communicated with the combustion chamber (36) of the heating device, and is provided with a honeycomb air condensation bundle pipe to support heat exchange between the flue gas and the air. The flue gas condensate is discharged centrally, and the tail end is directly emptied or connected to the chimney.

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