A comprehensive cable for electronic detector
By adopting a central symmetric structure and a semiconductor-conductive shielding layer with a multi-layer spiral winding, combined with a ceramic fiber modified rubber sheath, the shortcomings of the existing integrated cables for electronic detectors in terms of anti-interference ability and convenience of use are solved, and efficient electromagnetic shielding and excellent mechanical properties are achieved.
Patent Information
- Application Number
- CN202211012449.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2022-08-23
- Publication Date
- 2025-03-28
- Estimated Expiration
- 2042-08-23
AI Technical Summary
The existing integrated cables for electronic detectors have shortcomings in terms of anti-interference ability and convenience of use, especially electromagnetic shielding and bending performance that need to be improved.
Comprehensive cables with a central symmetrical structure include a cable core, a semiconductor-conductive shielding layer with a multi-layer spiral wrap and a ceramic fiber-modified rubber sheath. The cable core consists of a reinforcement core, conductor and signal wire, and the wrap shield uses vertical graphene and semiconductor layers. The sheath material is modified by ceramic fibers and rare earth oxides to improve mechanical properties and corrosion resistance.
It realizes a comprehensive cable with small outer diameter, light weight and good bending performance, while improving electromagnetic shielding and service life, enhancing the mechanical properties and corrosion resistance of the sheath.
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Figure CN115376740B_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of cables, and in particular to a comprehensive cable for an electronic detector. Background Art
[0002] Electronic detectors refer to instruments, equipment and systems that use electronic technology to measure and observe electrical or non-electrical quantities, or light, electrical quantity and measuring accessories for measurement purposes. Measurement includes data acquisition, storage, display, printing, drawing, processing and transmission, etc., and are information products. Integrated cables refer to cables that combine different types of cables. They can not only connect power supplies, but also transmit audio and video signals. They are compact and easy to use, and can improve the sensitivity of electronic detectors.
[0003] Electronic detectors have high requirements for the anti-interference ability of cables. At present, improvements are generally made to the structure of the cables to improve the overall shielding effectiveness of the cables to resist external electromagnetic interference and internal crosstalk; for example, increasing the thickness and multi-level shielding are used to reduce the impact of electromagnetic induction. If the shielding layer is too thick, the cable will be heavier, the outer diameter will be thicker, and it will be difficult to bend, which will make it inconvenient to install and use. In addition, the electromagnetic shielding property will change greatly after bending and deformation, which needs to be improved urgently. Summary of the invention
[0004] The present invention aims to overcome at least one of the above-mentioned shortcomings and deficiencies of the prior art and provide a comprehensive cable for an electronic detector. The purpose of the present invention is achieved based on the following technical solutions:
[0005] The present invention provides an integrated cable for an electronic detector, which comprises a cable core, a wrapped shielding layer and a sheath from the inside to the outside. The cable core has a symmetrical structure, comprising a reinforcing core arranged in the center and conductive wires and signal wires alternately arranged around the surface of the reinforcing core. The reinforcing core, conductive wires and signal wires are twisted with each other. The wrapped shielding layer comprises a flexible insulating layer, a semiconductor layer and a vertical graphene layer from the inside to the outside. The vertical graphene layer grows on the surface of the semiconductor layer. The wrapped shielding layer is spirally wound on the outer surface of the cable core in multiple layers. The sheath is made of ceramic fiber and rare earth oxide-modified rubber.
[0006] The present invention adopts a central symmetrical structure in structural design, which not only has the advantages of small outer diameter, light weight, good bending performance and stable product structure, but also has excellent electrical performance, which is conducive to transportation and installation; a reinforcing core is arranged in the center, which improves the structural strength and service life of the integrated cable. The present invention constructs a multi-layer spirally wrapped semi-conductive-conductive shielding structure, which combines the structure and function of the traditional wrapping layer and the shielding layer into one, and has a novel structure; it can offset the electromagnetic effect layer by layer, and improve the electromagnetic shielding of the present invention; at the same time, the present invention uses vertical graphene instead of metal as a conductor shielding layer, and then cooperates with a semi-conductive layer, which greatly reduces the weight and has a better shielding effect; compared with planar graphene, vertical graphene can expose a larger effective specific surface area, so that both the basal surface and the edge reaction sites are improved, and the graphene layer is thinned, and the conductivity and light transmittance are also enhanced, and the carbon material itself has high stability, which greatly improves the shielding effect; the vertical graphene layer grows directly on the surface of the semiconductor layer, and the structure is more stable and reliable than bonding and other connection methods. The sheath adopts ceramic fiber and rare earth oxide modified rubber, the instantaneous crosslinking density is increased, the filling of ceramic fiber can further increase the crosslinking density and structural toughness, and finally improves the tensile strength and wind erosion resistance of the invention, so that the sheath of the invention has excellent mechanical properties and corrosion resistance.
[0007] Preferably, the conductive wire comprises a conductive core and a first insulating layer covering the conductive core, and the conductive core is formed by twisting a plurality of first conductors together.
[0008] Preferably, the signal line comprises two signal bodies and an aluminum-plastic composite tape wrapped around the two signal bodies, and each signal body comprises a second conductor located in the middle and a second insulating layer coated outside the second conductor.
[0009] Preferably, the material of the insulating layer includes one or more of polyethylene terephthalate, polyethylene naphthalate, polyether sulfone, polypropylene, polypropylene sulfide, polycarbonate, polyetherimide, polyphenylene sulfide, polyphenylene oxide, polysulfone, and polyphthalamide.
[0010] Preferably, the semiconductor layer is made of graphite foil or graphite cloth.
[0011] Preferably, the total thickness of the wrapped shielding layer is not higher than 5 mm.
[0012] Preferably, the method for preparing the wrapped shielding layer comprises the following steps:
[0013] 1) growing a vertical graphene layer on the surface of the semiconductor layer, and forming a bonding layer on the opposite surface of the semiconductor layer on which the vertical graphene layer is grown;
[0014] 2) when the adhesive layer is not cured or solidified, contacting one side edge of the surface of the flexible insulating layer with the adhesive layer, and placing the flexible insulating layer on the adhesive layer from the edge; and curing the adhesive layer.
[0015] Preferably, in step 1), a plasma in-situ growth method is used to grow a vertical graphene layer on the surface of the semiconductor layer.
[0016] After the graphite foil or graphite cloth is transformed into graphene through allotropy, it obtains optical, electrical and mechanical properties that are superior to those of graphite foil or graphite cloth. In addition, the graphene on the vertical substrate can expose more abundant active sites, and the three-dimensional interconnected structure forms channels that are conducive to ion transmission. The in-situ growth method is used to make the bonding force between the vertical graphene and the semiconductor layer (graphite foil or graphite cloth) stronger. Growing vertical graphene on the semiconductor layer can greatly reduce the thickness of the shielding layer.
[0017] Preferably, the conductor core is formed by twisting a plurality of silver-plated soft copper wires, and the first insulating layer is fluoroplastic.
[0018] Preferably, the method for preparing the material of the sheath comprises:
[0019] S1, mixing thermoplastic elastomer, styrene-butadiene rubber and chlorinated polyethylene at 80-130° C. to obtain mixture 1;
[0020] S2, mixing ceramic fiber, silane coupling agent, butanone, glycerol, EPDM rubber and rare earth oxide at 60-110° C. to obtain mixture 2;
[0021] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding triisobutyl aluminum, zinc oxide, zinc stearate, and a vulcanizing agent, mixing at 80-130° C., and extruding at 100-135° C. to obtain the sheath material.
[0022] Thermoplastic elastomers have good impact and fatigue resistance, high impact strength and good low-temperature flexibility, maintain good performance when the temperature rises, good resistance to chemicals, oils, solvents and weather, high tear strength and high friction resistance, easy processing and economical, good recyclability; can improve the mechanical strength, heat resistance and weather resistance of the sheath. Styrene-butadiene rubber, its physical structure properties, processing properties and product performance are close to natural rubber, and some properties such as wear resistance, heat resistance, aging resistance and vulcanization speed are better than natural rubber. Chlorinated polyethylene is a polymer synthetic material made by chlorination modification of polyethylene. Its molecules are linear saturated irregular structures, so it has excellent flexibility, heat aging resistance, weather resistance and ozone resistance. Because its molecular structure contains a considerable proportion of chlorine elements, it has good oil resistance, chemical resistance and flame retardancy. EPDM rubber has excellent oxidation resistance, ozone resistance and erosion resistance. Thermoplastic elastomer, styrene-butadiene rubber, chlorinated polyethylene and EPDM rubber are combined to greatly improve the mechanical strength, insulation, heat resistance, weather resistance and corrosion resistance of the resulting sheath.
[0023] Ceramic fiber has low thermal conductivity, excellent thermal stability and chemical stability, does not contain binders and is corrosive; it has high compressive strength, good toughness, excellent wind erosion resistance, and excellent machining performance. The special electronic structure of rare earth oxides makes it easy to form complexes. Ceramic fiber and rare earth oxide are combined with the main rubber material through silane coupling agent to enhance the compatibility between ceramic fiber, rare earth oxide and rubber molecules. Rare earth oxide can promote the rapid formation of crystals in rubber molecules, so that the instantaneous crosslinking density of the present invention is increased. The filling of ceramic fiber can further increase the crosslinking density and structural toughness, and finally improve the tensile strength of the present invention; rare earth oxide complexes can also prevent the movement of rubber molecules, combined with the wind erosion resistance of ceramic fiber, so that the sheath of the present invention has excellent mechanical properties and corrosion resistance. Using cyanopropyl zirconium metallocene chloride-methyl aluminum oxide composite catalyst, zinc oxide, zinc stearate, and vulcanizing agent as the vulcanization system, the crosslinking density of the present invention is enhanced, and the aging resistance, insulation performance and mechanical properties of the resulting sheath are greatly improved.
[0024] The sheath of the invention has excellent mechanical strength, insulation, heat resistance, weather resistance, corrosion resistance, aging resistance, no blistering and delamination, and high strength.
[0025] Preferably, the material of the sheath includes the following raw materials in parts by weight: 15-25 parts of thermoplastic elastomer, 15-25 parts of styrene-butadiene rubber, 25-45 parts of chlorinated polyethylene, 2-6 parts of dibenzoyl peroxide, 15-25 parts of ceramic fiber, 10-15 parts of silane coupling agent, 3-6 parts of butanone, 4-8 parts of glycerol, 25-45 parts of ethylene propylene diene rubber, 15-25 parts of rare earth oxide, 3-10 parts of cyanopropionyl zirconium metallocene chloride-methylaluminum oxide composite catalyst, 3-10 parts of zinc oxide, 1-5 parts of zinc stearate, and 8-15 parts of vulcanizing agent.
[0026] Preferably, the rare earth oxide is cerium oxide and / or lanthanum oxide.
[0027] The present invention can achieve at least one of the following beneficial effects:
[0028] The present invention adopts a central symmetrical structure in structural design, which not only has the advantages of small outer diameter, light weight, good bending performance and stable product structure, but also has excellent electrical performance, which is conducive to transportation and installation; a reinforcing core is arranged in the center, which improves the structural strength and service life of the integrated cable. The present invention constructs a multi-layer spirally wrapped semi-conductive-conductive shielding structure, which combines the structure and function of the traditional wrapping layer and the shielding layer into one, and has a novel structure; it can offset the electromagnetic effect layer by layer, and improve the electromagnetic shielding of the present invention; at the same time, the present invention uses graphene instead of metal as a conductor shielding layer, and then cooperates with a semi-conductive layer, which greatly reduces the weight and has a better shielding effect; compared with planar graphene, vertical graphene can expose a larger effective specific surface area, so that both the basal surface and the edge reaction sites are improved, and the graphene layer is thinned, and the conductivity and light transmittance are also enhanced, and the carbon material itself has high stability, which greatly improves the shielding effect; the vertical graphene layer grows directly on the surface of the semiconductor layer, and the structure is more stable and reliable than bonding and other connection methods. The sheath is made of ceramic fiber and rare earth oxide modified rubber, which instantly increases the crosslinking density. The filling of ceramic fiber can further increase the crosslinking density and structural toughness, and ultimately improve the tensile strength and wind erosion resistance, so that the sheath has excellent mechanical properties, flame retardant properties and corrosion resistance. BRIEF DESCRIPTION OF THE DRAWINGS
[0029] Figure 1 A schematic diagram of the structure of an integrated cable for an electronic detector according to a preferred embodiment of the present invention;
[0030] Figure 2 It is a schematic structural diagram of a wrapped shielding layer according to a preferred embodiment of the present invention. DETAILED DESCRIPTION
[0031] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0032] like Figures 1-2 As shown, a preferred embodiment of the present invention provides a comprehensive cable for an electronic detector, which includes a cable core 1, a wrapped shielding layer 23 and a sheath 3 from the inside to the outside, wherein:
[0033] The cable core 1 has a symmetrical structure, including a reinforcing core 101 arranged in the center and a conductor 102 and a signal line 103 arranged alternately around the surface of the reinforcing core 101. The reinforcing core 101, the conductor 102 and the signal line 103 are twisted together. The wrapped shielding layer 2 includes a flexible insulating layer 201, a semiconductor layer 202 and a vertical graphene layer 203 from the inside to the outside. The vertical graphene layer 203 grows on the surface of the semiconductor layer 202. The wrapped shielding layer 2 is wound in a multi-layer spiral shape on the outer surface of the cable core 1. The sheath 3 is made of ceramic fiber and rare earth oxide modified rubber. The conductor 102 includes a conductor core 104 and a first insulating layer 105 coated outside the conductor core 104. The conductor core 104 is formed by twisting a plurality of first conductors 110 (multiple strands of silver-plated soft copper wire) together. The signal line 103 includes two signal bodies 106 and an aluminum-plastic composite tape 107 wrapped around the two signal bodies. Each signal body 106 includes a second conductor 108 located in the middle and a second insulating layer 109 wrapped around the second conductor 108. The first insulating layer 105 is fluoroplastic. The total thickness of the wrapped shielding layer 2 is not more than 5 mm.
[0034] The material of the insulating layer 201 includes one or more of polyethylene terephthalate, polyethylene naphthalate, polyethersulfone, polypropylene, polypropylene sulfide, polycarbonate, polyetherimide, polyphenylene sulfide, polyphenylene oxide, polysulfone, and polyphthalamide. The material of the semiconductor layer 202 is graphite foil or graphite cloth.
[0035] The preparation method of the wrapped shielding layer 2 comprises the following steps:
[0036] 1) A vertical graphene layer 203 is directly grown on the surface of the semiconductor layer 202 by a plasma in-situ growth method (for the specific method, refer to patent CN2021101341959), and a bonding layer is formed on the opposite surface of the semiconductor layer 202 where the vertical graphene layer 203 is grown;
[0037] 2) When the adhesive layer is not cured or solidified, one side edge of the surface of the flexible insulating layer 201 is brought into contact with the adhesive layer, and the flexible insulating layer 201 is placed on the adhesive layer from the edge; and the adhesive layer is cured.
[0038] The preparation method of the sheath 3 material includes:
[0039] S1, mixing thermoplastic elastomer, styrene-butadiene rubber and chlorinated polyethylene at 80-130° C. to obtain mixture 1;
[0040] S2, mixing ceramic fiber, silane coupling agent, butanone, glycerol, EPDM rubber, and rare earth oxide at 60-110° C. to obtain mixture 2;
[0041] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding triisobutyl aluminum, zinc oxide, zinc stearate, and a vulcanizing agent, mixing at 80-130° C., and extruding at 100-135° C. to obtain the sheath 3 material.
[0042] The sheath 3 includes the following raw materials in parts by weight: 15-25 parts of thermoplastic elastomer, 15-25 parts of styrene-butadiene rubber, 25-45 parts of chlorinated polyethylene, 2-6 parts of dibenzoyl peroxide, 15-25 parts of ceramic fiber, 10-15 parts of silane coupling agent, 3-6 parts of butanone, 4-8 parts of glycerol, 25-45 parts of EPDM rubber, 15-25 parts of rare earth oxide, 3-10 parts of cyanopropionyl zirconium metallocene chloride-methylaluminum oxide composite catalyst, 3-10 parts of zinc oxide, 1-5 parts of zinc stearate, and 8-15 parts of vulcanizing agent. The rare earth oxide is cerium oxide and / or lanthanum oxide.
[0043] The following are specific embodiments.
[0044] Example 1
[0045] In the integrated cable for an electronic detector of the present embodiment, the insulating layer 201 is made of polyethylene terephthalate, the semiconductor layer 202 is made of graphite foil, and the total thickness of the wrapped shielding layer 2 is 5 mm.
[0046] The preparation method of the material of the sheath 3 includes:
[0047] S1, 25 parts of thermoplastic elastomer, 15 parts of styrene-butadiene rubber, 25 parts of chlorinated polyethylene, and 2 parts of dibenzoyl peroxide were mixed at 85° C. to obtain a mixture 1;
[0048] S2, 15 parts of ceramic fiber, 10 parts of vinyl triethoxysilane, 3 parts of butanone, 4 parts of glycerol, 45 parts of EPDM rubber, and 25 parts of cerium oxide were mixed at 70° C. to obtain a mixture 2;
[0049] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding 3 parts of triisobutyl aluminum, 3 parts of zinc oxide, 1 part of zinc stearate, and 8 parts of benzoyl peroxide, mixing at 90° C., and extruding at 100° C. to obtain the material of sheath 3.
[0050] Example 2
[0051] In the integrated cable for an electronic detector of the present embodiment, the insulating layer 201 is made of polyetherimide, the semiconductor layer 202 is made of graphite cloth, and the total thickness of the wrapped shielding layer 2 is 4.5 mm.
[0052] The preparation method of the material of the sheath 3 includes:
[0053] S1, 15 parts of thermoplastic elastomer, 25 parts of styrene-butadiene rubber, 45 parts of chlorinated polyethylene, and 6 parts of dibenzoyl peroxide were mixed at 130° C. to obtain a mixture 1;
[0054] S2, 25 parts of ceramic fiber, 15 parts of γ-mercaptopropyl-trimethoxysilane, 6 parts of butanone, 8 parts of glycerol, 45 parts of EPDM rubber, and 15 parts of lanthanum oxide were mixed at 110° C. to obtain a mixture 2;
[0055] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding 10 parts of triisobutyl aluminum, 9 parts of zinc oxide, 5 parts of zinc stearate, and 15 parts of benzoyl peroxide, mixing at 130°C, and extruding at 135°C to obtain the material of sheath 3.
[0056] Example 3
[0057] In the integrated cable for an electronic detector of the present embodiment, the insulating layer 201 is made of polyethylene naphthalate, the semiconductor layer 202 is made of graphite cloth, and the total thickness of the wrapped shielding layer 2 is 4 mm.
[0058] The preparation method of the material of the sheath 3 includes:
[0059] S1, 18 parts of thermoplastic elastomer, 20 parts of styrene-butadiene rubber, 35 parts of chlorinated polyethylene, and 3 parts of dibenzoyl peroxide were mixed uniformly at 100° C. to obtain a mixture 1;
[0060] S2, 20 parts of ceramic fiber, 12 parts of vinyl trimethoxysilane, 5 parts of butanone, 7 parts of glycerol, 40 parts of EPDM rubber, 10 parts of cerium oxide, and 12 parts of lanthanum oxide were mixed at 80° C. to obtain a mixture 2;
[0061] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding 7 parts of triisobutyl aluminum, 6 parts of zinc oxide, 3 parts of zinc stearate, and 13 parts of benzoyl peroxide, mixing at 100° C., and extruding at 105° C. to obtain the material of sheath 3.
[0062] Example 4
[0063] In the integrated cable for electronic detectors of this embodiment, the insulating layer 201 is made of a mixture of polypropylene sulfide and polycarbonate in a mass ratio of 1:1, the semiconductor layer 202 is made of graphite foil, and the total thickness of the wrapped shielding layer 2 is 4.5 mm.
[0064] The preparation method of the material of the sheath 3 includes:
[0065] S1, 18 parts of thermoplastic elastomer, 18 parts of styrene-butadiene rubber, 40 parts of chlorinated polyethylene, and 5 parts of dibenzoyl peroxide were mixed at 120° C. to obtain a mixture 1;
[0066] S2, 18 parts of ceramic fiber, 14 parts of γ-glycidylpropyl-trimethoxysilane, 4 parts of butanone, 6 parts of glycerol, 30 parts of EPDM rubber, and 18 parts of lanthanum oxide were mixed at 90° C. to obtain a mixture 2;
[0067] S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding 5 parts of triisobutyl aluminum, 5 parts of zinc oxide, 2 parts of zinc stearate, and 10 parts of benzoyl peroxide, mixing at 120°C, and extruding at 125°C to obtain the material of sheath 3.
[0068] Example 5
[0069] In the integrated cable for electronic detectors of this embodiment, the insulating layer 201 is made of a mixture of polypropylene, polyphenylene sulfide and polyphthalamide in a mass ratio of 1:1:1, the semiconductor layer 202 is made of graphite foil, and the total thickness of the wrapped shielding layer 2 is 3.5 mm.
[0070] The preparation method of the material of the sheath 3 includes:
[0071] S1, 22 parts of thermoplastic elastomer, 22 parts of styrene-butadiene rubber, 30 parts of chlorinated polyethylene, and 5 parts of dibenzoyl peroxide were mixed at 110° C. to obtain a mixture 1;
[0072] S2, 22 parts of ceramic fiber, 13 parts of γ-methacryloxypropyl-trimethoxysilane, 4 parts of butanone, 5 parts of glycerol, 35 parts of EPDM rubber, 10 parts of cerium oxide, and 10 parts of lanthanum oxide were mixed at 100° C. to obtain a mixture 2;
[0073] S3. Add mixture 1 and mixture 2 into an internal mixer, and then add 6.5 parts of triisobutyl aluminum, 6 parts of zinc oxide, 2.5 parts of zinc stearate, and 12 parts of benzoyl peroxide, mix at 110° C., and extrude at 115° C. to obtain the material of sheath 3.
[0074] Comparative Example 1
[0075] The wrapped shielding layer 2 is replaced by a multi-stage metal shielding layer, and the rest is the same as in Example 5. With the same shielding effectiveness (not less than 70 dB), the shielding layer thickness of the present invention is 3.5 mm, while the prior art cable using a multi-stage metal shielding layer requires a shielding layer of about 11 mm.
[0076] Comparative Example 2
[0077] The ceramic fibers are removed and the remaining raw materials are added in equal proportions to the materials for preparing the sheath, and the rest is the same as in Example 5.
[0078] Comparative Example 3
[0079] The rare earth oxide is removed and the remaining raw materials are added in equal proportion to the materials for preparing the sheath, and the rest is the same as in Example 5.
[0080] After the materials of the sheath 3 obtained in Examples 1 to 5 and Comparative Examples 2 to 3 were made into cable sheaths according to conventional methods, their mechanical properties (characterized by tensile strength and elongation at break) and flame retardancy (characterized by limiting oxygen index) were tested, and after aging at 135° C. for 168 h, their mechanical properties were tested. The test results are shown in Table 1.
[0081] Table 1
[0082]
[0083] From the data in Table 1, it can be seen that the sheath obtained by the present invention has excellent mechanical properties and flame retardant properties, high structural strength and long service life. Compared with Comparative Examples 2 to 3, it is found that rare earth oxides have a greater impact on mechanical properties (tensile strength, elongation at break), and ceramic fibers have a greater impact on flame retardant properties.
[0084] Finally, it should be noted that the above are only preferred embodiments of the present invention and are not intended to limit the present invention. Although the present invention has been described in detail with reference to the aforementioned embodiments, it is still possible for those skilled in the art to modify the technical solutions described in the aforementioned embodiments, or to make equivalent substitutions for some of the technical features therein. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the protection scope of the present invention.
Claims
1. A comprehensive cable for an electronic detector, characterized in that: The cable core (1) comprises, from the inside to the outside, a cable core (1), a wrapped shielding layer (2) and a sheath (3). The cable core (1) has a symmetrical structure and comprises a reinforcing core (101) arranged at the center and a conductor (102) and a signal line (103) arranged alternately around the surface of the reinforcing core (101). The reinforcing core (101), the conductor (102) and the signal line (103) are twisted together. The wrapped shielding layer (2) comprises, from the inside to the outside, a flexible insulating layer (201), a semiconductor layer (202) and a vertical graphene layer (203). The vertical graphene layer (203) grows on the surface of the semiconductor layer (202). The wrapped shielding layer (2) is wound in multiple layers in a spiral shape on the outer surface of the cable core (1). The sheath (3) is made of ceramic fiber and rare earth oxide-modified rubber.
2. The integrated cable for electronic detector according to claim 1, characterized in that: The conductive wire (102) comprises a conductive core (104) and a first insulating layer (105) covering the conductive core (104); the conductive core (104) is formed by twisting a plurality of first conductors (110) together.
3. The integrated cable for electronic detector according to claim 1, characterized in that: The signal line (103) comprises two signal bodies (106) and an aluminum-plastic composite tape (107) wrapped around the two signal bodies, and each signal body (106) comprises a second conductor (108) located in the middle and a second insulating layer (109) wrapped around the second conductor (108).
4. The integrated cable for electronic detector according to claim 1, characterized in that: The material of the insulating layer (201) includes one or more of polyethylene terephthalate, polyethylene naphthalate, polyether sulfone, polypropylene, polypropylene sulfide, polycarbonate, polyetherimide, polyphenylene sulfide, polyphenylene oxide, polysulfone, and polyphthalamide.
5. The integrated cable for electronic detector according to claim 1, characterized in that: The semiconductor layer (202) is made of graphite foil or graphite cloth.
6. The integrated cable for electronic detector according to claim 1, characterized in that: The total thickness of the wrapped shielding layer (2) is not greater than 5 mm.
7. The integrated cable for electronic detector according to claim 1, characterized in that: The method for preparing the wrapped shielding layer (2) comprises the following steps: 1) growing a vertical graphene layer (203) on the surface of the semiconductor layer (202), and forming a bonding layer on the opposite surface of the semiconductor layer (202) on which the vertical graphene layer (203) is grown; 2) when the adhesive layer is not cured or solidified, bringing one side edge of the surface of the flexible insulating layer (201) into contact with the adhesive layer, and placing the flexible insulating layer (201) on the adhesive layer from the edge; and curing the adhesive layer.
8. The integrated cable for electronic detector according to claim 7, characterized in that: In step 1), a vertical graphene layer (203) is grown on the surface of the semiconductor layer (202) using a plasma in-situ growth method.
9. The integrated cable for electronic detector according to claim 2, characterized in that: The conductor core (104) is formed by twisting a plurality of silver-plated soft copper wires, and the first insulating layer (105) is made of fluoroplastic.
10. The integrated cable for electronic detector according to claim 1, characterized in that: The method for preparing the material of the sheath (3) comprises: S1, mixing thermoplastic elastomer, styrene-butadiene rubber and chlorinated polyethylene at 80-130° C. to obtain mixture 1; S2, ceramic fiber, silane coupling agent, butanone, glycerol, EPDM rubber, cerium oxide, lanthanum oxide at 60-110℃ Mix well to obtain mixture 2; S3, adding mixture 1 and mixture 2 into an internal mixer, and then adding triisobutyl aluminum, zinc oxide, zinc stearate, and a vulcanizing agent, mixing at 80-130° C., and extruding at 100-135° C. to obtain the material of the sheath (3).
Citation Information
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