Environmentally friendly seedling pot based on straw and cellar mud and its process
By pretreating and modifying straw and cellar mud and combining it with degradable materials, an environmentally friendly seedling bowl was prepared, which solved the problems of water permeability, poor breathability and difficulty in degradation of existing plastic seedling containers, and achieved improved mechanical properties and environmentally friendly degradability of seedling bowls.
Patent Information
- Application Number
- CN202310730149.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-06-20
- Publication Date
- 2025-03-21
- Estimated Expiration
- 2043-06-20
AI Technical Summary
现有塑料育苗容器透水性和透气性差,容易对幼苗根系生长产生不利影响,并且难以降解,导致环境污染。
The environmentally friendly seedling bowl process based on straw and cellar mud is adopted. By pretreating and modifying the straw and cellar mud, the mechanical properties of the seedling bowl are improved, and degradable materials such as algae, wood ash and polyvinyl alcohol are added.
It improves the mechanical properties and degradability of the seedling bowl, provides an environment that is beneficial to the growth of seedling roots, reduces environmental pollution, and reduces production costs.
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Figure BDA0004293955400000111 
Figure BDA0004293955400000121
Abstract
Description
Technical Field
[0001] The invention belongs to the technical field of environment-friendly seedling raising pots, and in particular relates to an environment-friendly seedling raising pot based on straw and cellar mud and a process method thereof. Background Art
[0002] In the field of agriculture and forestry, disposable plastic containers are often used for seedling cultivation due to production needs. With the continuous development of the petroleum industry and the plastics industry, environmental problems caused by the difficulty of plastic degradation have become increasingly prominent. The country has successively introduced many policies to restrict the use of disposable plastic products and formulated relevant inspection and testing standards. However, traditional plastic seedling containers are difficult to degrade in the natural environment and can only be partially degraded. In the natural environment, the accumulated plastic in the soil can be broken down into microplastic particles with a diameter of less than 5 mm through degradation such as photodegradation, thermal oxidation degradation or aging degradation, which has caused serious damage to the natural environment and seriously endangered people's health. It has no significant advantages in nature and society.
[0003] The main plastic seedling containers used in China are basically made of PE, PVC and other products. Their disadvantages are: (1) Plastic seedling containers have poor water permeability and air permeability, which can easily have an adverse effect on the growth of seedling roots; (2) Plastic has certain strength and toughness, which will hinder the extension of seedling roots during the growth and development of seedlings, resulting in the phenomenon of spiral root growth. The seedlings will gradually improve after a long time after planting; (3) Plastic is particularly difficult to degrade in the natural environment and will cause great pollution to the environment. Among all degradable seedling containers, plant fiber-based seedling containers are the most concerned and are also the key development direction in the future. At present, the preparation of plant fiber-based seedling containers mainly uses agricultural residues such as corn stalks, sorghum stalks, rice straw, wheat straw, cotton stalks and other plant fiber raw materials as reinforcing materials, and adds appropriate amounts of composite additives for production.
[0004] Chinese patent application No. 201510869187.3 discloses a nutrient pot for seedlings, which is made of a pot body and a nutrient matrix arranged in the pot body, wherein the pot body is made of the following components by weight: 100 kg corn stalks, 100 kg clay, 5 kg citric acid residue, 2 kg garlic leaves, 2 kg senna leaves, 2 kg bran, 0.5 kg salt, and 2 kg sesame leaves; the above-mentioned nutrient matrix is made of the following components by weight: 100 kg urea, 200 kg calcined loess powder, nitrogen Fertilizer 50kg, magnesium sulfate 10kg, plant ash 10kg, leaf humus 300kg, cellar mud 100kg, rooting powder 5kg, sea mud 20kg, erythromycin ointment 0.2kg, 1.8% avermectin emulsifiable concentrate 200ml, clove leaf dry powder 0.6kg, sodium selenite 2kg, saponin 0.2kg, potassium humate 1kg, potassium dihydrogen phosphate 30kg, seaweed micropowder 10kg; the nutrient matrix can not only provide the nutrients required for the normal growth of seedlings, but also reduce the occurrence of seedling diseases and insect pests. However, the patent directly adds straw, and the binding force between it and clay is not strong, which may lead to the instability of the structure of the seedling pot; at the same time, there is also uneven mixing of various materials, inconsistent materials of various parts of the container, resulting in poor mechanical properties, poor toughness and brittleness of the product, and high drop breakage rate. Chinese patent application No. 201710946606.8 discloses a degradable seedling tray and its preparation method, which is made of the following raw materials in parts by weight: 75-85 parts of deinked pulp, 50-60 parts of plant fiber, 0.5-1 parts of straw fermentation agent, 22-24 parts of modified starch, 4-6 parts of adhesive, 1-1.5 parts of release agent, 4-6 parts of nutrient agent, 0.8-1.2 parts of antibacterial agent, and 3-5 parts of waterproof film. The invention has a certain salt-alkali resistance to decomposition, is separated from the outside world during the adaptation period of the seedlings, and is degradable. After the seedlings adapt to the salt marsh environment, their roots can grow through the plug tray and eventually completely degrade. However, the amount of modified starch used in this patent is large, and the production cost is relatively high.
[0005] Based on this, this field urgently needs environmentally friendly, root growth-friendly, degradable seedling containers to fill the market. Summary of the invention
[0006] In view of the deficiencies in the prior art, the purpose of the present invention is to provide an environmentally friendly seedling raising pot based on straw and cellar mud and a process method thereof. The straw, cellar mud and other additives used in the environmentally friendly seedling raising pot are all degradable materials with low production cost and can be degraded. On the one hand, they provide partial nutrition for the seedlings in the stage, and on the other hand, they solve the recycling of agricultural waste and reduce environmental pollution.
[0007] To achieve the above object, the present invention provides the following technical solutions:
[0008] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0009] (1) Pretreatment of straw: the straw is washed and dried, crushed to 60 mesh, and then immersed in hydrogen peroxide and ferric chloride solution. After the immersion treatment, the residual liquid is discarded, and the straw is dried to a moisture content of no more than 10% to obtain pretreated straw;
[0010] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl, and then the irradiated straw is added to an alkaline solution for stirring and reacting. After the reaction is completed, the straw is filtered, washed, and dried to obtain modified straw;
[0011] (3) Pretreatment of pit mud: adding the pit mud to the aqueous solution of silane coupling agent, then placing it in a ball mill for ball milling, and drying it at 40-50° C. after the ball milling, to obtain the pretreated pit mud;
[0012] (4) Preparation of environmentally friendly seedling raising pots: The modified straw in step (2) and the pretreated pit mud in step (3) are mixed evenly, and then seaweed glue, wood ash, polyvinyl alcohol and water are added and stirred evenly. Then, the mixture is placed in a mold, subjected to compression molding, molding, demolding and sun drying to obtain the environmentally friendly seedling raising pots.
[0013] Preferably, the straw in step (1) is one or both of corn straw and rice straw, the mass concentration of the hydrogen peroxide is 10-15%, the concentration of the ferric chloride is 1-2 mol / L, and the volume ratio of the hydrogen peroxide to the ferric chloride solution is 1:1-2.
[0014] Preferably, the immersion temperature in step (1) is 50-60° C., and the immersion time is 0.5-1 h.
[0015] Preferably, the irradiation conditions in step (2) are: electron energy is 5-10 MeV, irradiation dose is 5-10 Mdelamin; and the alkali solution is 1-2 mol / L sodium hydroxide.
[0016] Preferably, the reaction temperature is 20-30°C and the reaction time is 20-40 min.
[0017] Preferably, the mass concentration of the silane coupling agent aqueous solution in step (3) is 3-6%, and the silane coupling agent is one of KH550, KH560, and KH570; the mass ratio of the pit mud to the silane coupling agent aqueous solution is 100:30-50.
[0018] Preferably, the ball milling speed in step (3) is 2000-3000 r / min, and the time is 30-50 min.
[0019] Preferably, the mass ratio of the modified straw, pretreated pit mud, seaweed glue, plant ash and polyvinyl alcohol in step (4) is 40-50:40-60:5-10:10-20:5-10:80-120.
[0020] Preferably, the stirring time in step (4) is 30-60 min.
[0021] The present invention also protects an environmentally friendly seedling pot based on straw and cellar mud prepared by the process method.
[0022] Compared with the prior art, the present invention has the following beneficial effects:
[0023] (1) The method for preparing an environmentally friendly seedling pot based on straw and cellar mud provided by the present invention comprises the following steps: pre-treating the straw, and then impregnating the straw with hydrogen peroxide and ferric chloride to effectively improve the adsorption capacity of the straw; then, electron beam irradiation and alkaline solution soaking are performed, and the straw is bombarded with high-energy electron beams to produce defects on the surface of the straw. Since these defects have greater reactivity than the normal carbon atoms on the surface of the straw, the subsequent reactivity of the straw is improved. At the same time, the alkaline solution also destroys the chemical bonds between cellulose and other components in the straw, causing a saponification reaction and dissolving impurities such as pectin in the straw, increasing the roughness of the straw surface, and improving the adsorption performance of the straw; pre-treating the cellar mud can introduce groups with higher reactivity to its surface, and at the same time, the ball milling method can effectively reduce the damage to microorganisms in the cellar mud compared with other chemical methods; the present invention modifies the straw and pre-treats the cellar mud, so that the straw and the cellar mud are combined in the form of covalent bonds, so that the connection between the straw and the cellar mud is tighter, thereby improving the mechanical properties of the environmentally friendly seedling pot.
[0024] (2) The method for preparing an environmentally friendly seedling pot based on straw and cellar mud provided by the present invention mainly selects straw and cellar mud as raw materials. The cellar mud contains a large number of active microorganisms, which promote the growth of plants. The addition of cellar mud can increase the water retention and wettability of the matrix, but the addition ratio should be between 40-60%. Too much addition will lead to poor air permeability. Corn straw and rice straw with high cellulose content are selected to facilitate the molding of the seedling pot. At the same time, the added raw materials such as alginate, wood ash and polyvinyl alcohol are degradable materials, and the production cost is low.
[0025] (3) The environmentally friendly seedling raising pots based on straw and cellar mud provided by the present invention have all degradable raw materials added, which can provide partial nutrition for the seedlings on the one hand, and solve the recycling of agricultural waste and reduce environmental pollution on the other hand; the prepared seedling raising pots do not need to be removed from the tray, do not damage the roots, and are more conducive to the survival of the seedlings. DETAILED DESCRIPTION
[0026] The technical solution of the present invention will be clearly and completely described below in conjunction with the embodiments. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0027] Example 1
[0028] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0029] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in a 10% mass concentration of hydrogen peroxide and a 1 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:1), the immersion temperature was 50°C, the immersion time was 1 h, and after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0030] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiation conditions are: electron energy of 5 MeV and irradiation dose of 5 mega-delatonium. The irradiated straw is then added to 1 mol / L sodium hydroxide and stirred for reaction. The reaction temperature is 20° C. and the reaction time is 40 min. After the reaction is completed, the straw is filtered, washed and dried to obtain modified straw.
[0031] (3) Pretreatment of pit mud: 100 g of pit mud was added to 30 g of a 6% KH550 aqueous solution, and then placed in a ball mill for ball milling at a speed of 2000 r / min for 50 min. After the ball milling was completed, the pit mud was dried at 40° C. to obtain pretreated pit mud;
[0032] (4) Preparation of environmentally friendly seedling pots: 40 g of the modified straw in step (2) and 40 g of the pretreated pit mud in step (3) were mixed evenly, and then 5 g of seaweed glue, 10 g of wood ash, 5 g of polyvinyl alcohol, and 80 g of water were added, stirred for 30 min, and then placed in a mold, pressed, molded, demolded, and then dried in the sun to obtain the environmentally friendly seedling pot.
[0033] Example 2
[0034] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0035] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in 10% hydrogen peroxide and 2 mol / L ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:1), the immersion temperature was 55°C, the immersion time was 1 h, after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0036] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiation conditions are: electron energy of 5 MeV and irradiation dose of 10 megadera. The irradiated straw is then added to 2 mol / L sodium hydroxide and stirred for reaction. The reaction temperature is 25° C. and the reaction time is 30 min. After the reaction is completed, the straw is filtered, washed and dried to obtain modified straw.
[0037] (3) Pretreatment of pit mud: 100 g of pit mud was added to 40 g of a 5% KH560 aqueous solution, and then placed in a ball mill for ball milling at a speed of 2500 r / min for 40 min. After the ball milling was completed, the pit mud was dried at 45° C. to obtain pretreated pit mud;
[0038] (4) Preparation of environmentally friendly seedling pots: 45 g of the modified straw in step (2) and 50 g of the pretreated pit mud in step (3) are mixed evenly, and then 5 g of seaweed glue, 15 g of wood ash, 5 g of polyvinyl alcohol, and 100 g of water are added, stirred for 40 min, and then placed in a mold, subjected to compression molding, molding, demolding, and then sun-drying to obtain the environmentally friendly seedling pot.
[0039] Example 3
[0040] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0041] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in a 15% mass concentration of hydrogen peroxide and a 1 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:2), the immersion temperature was 55°C, the immersion time was 0.5 h, and after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0042] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiation conditions are: electron energy of 10 MeV and irradiation dose of 5 mega-delatonium. The irradiated straw is then added to 2 mol / L sodium hydroxide and stirred for reaction. The reaction temperature is 25° C. and the reaction time is 30 min. After the reaction is completed, the straw is filtered, washed and dried to obtain modified straw.
[0043] (3) Pretreatment of pit mud: 100 g of pit mud was added to 40 g of a 5% KH570 aqueous solution, and then placed in a ball mill for ball milling at a speed of 2500 r / min for 40 min. After the ball milling was completed, the pit mud was dried at 45° C. to obtain pretreated pit mud;
[0044] (4) Preparation of environmentally friendly seedling pots: 45 g of the modified straw in step (2) and 60 g of the pretreated pit mud in step (3) are mixed evenly, and then 5 g of seaweed glue, 15 g of wood ash, 5 g of polyvinyl alcohol, and 100 g of water are added, stirred for 50 min, and then placed in a mold, subjected to compression molding, molding, demolding, and then sun-drying to obtain the environmentally friendly seedling pot.
[0045] Example 4
[0046] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0047] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in 15% mass concentration of hydrogen peroxide and 2 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:2), the immersion temperature was 60°C, the immersion time was 1 h, after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0048] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiation conditions are: electron energy of 10 MeV and irradiation dose of 10 mega-decalin. The irradiated straw is then added to 2 mol / L sodium hydroxide and stirred for reaction. The reaction temperature is 30° C. and the reaction time is 40 min. After the reaction is completed, the straw is filtered, washed and dried to obtain modified straw.
[0049] (3) Pretreatment of pit mud: 100 g of pit mud was added to 50 g of a 3% KH550 aqueous solution, and then placed in a ball mill for ball milling at a speed of 3000 r / min for 50 min. After the ball milling was completed, the pit mud was dried at 50° C. to obtain pretreated pit mud;
[0050] (4) Preparation of environmentally friendly seedling pots: 40 g of the modified straw in step (2) and 60 g of the pretreated pit mud in step (3) are mixed evenly, and then 10 g of seaweed glue, 20 g of wood ash, 10 g of polyvinyl alcohol, and 120 g of water are added, stirred for 60 min, and then placed in a mold, pressed, molded, demolded, and then dried in the sun to obtain the environmentally friendly seedling pot.
[0051] Comparative Example 1
[0052] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0053] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in a 15% mass concentration of hydrogen peroxide and a 1 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:2), the immersion temperature was 55°C, the immersion time was 0.5 h, and after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0054] (2) Pretreatment of pit mud: 100 g of pit mud was added to 40 g of a 5% KH570 aqueous solution, and then placed in a ball mill for ball milling at a speed of 2500 r / min for 40 min. After the ball milling was completed, the pit mud was dried at 45° C. to obtain pretreated pit mud;
[0055] (3) Preparation of environmentally friendly seedling pots: 45 g of pretreated straw in step (1) and 60 g of pretreated cellar mud in step (2) were mixed evenly, and then 5 g of seaweed glue, 15 g of wood ash, 5 g of polyvinyl alcohol, and 100 g of water were added, stirred for 50 min, and then placed in a mold, pressed, molded, demolded, and then dried in the sun to obtain the environmentally friendly seedling pot.
[0056] Comparative Example 2
[0057] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0058] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in a 15% mass concentration of hydrogen peroxide and a 1 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:2), the immersion temperature was 55°C, the immersion time was 0.5 h, and after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0059] (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiation conditions are: electron energy of 10 MeV and irradiation dose of 5 mega-delatonium. The irradiated straw is then added to 2 mol / L sodium hydroxide and stirred for reaction. The reaction temperature is 25° C. and the reaction time is 30 min. After the reaction is completed, the straw is filtered, washed and dried to obtain modified straw.
[0060] (3) Preparation of environmentally friendly seedling pots: 45 g of modified straw and 60 g of cellar mud in step (2) were mixed evenly, and then 5 g of seaweed gel, 15 g of wood ash, 5 g of polyvinyl alcohol, and 100 g of water were added, stirred for 50 min, and then placed in a mold, subjected to compression molding, molding, demolding, and then sun-drying to obtain the environmentally friendly seedling pot.
[0061] Comparative Example 3
[0062] A process for an environmentally friendly seedling raising pot based on straw and cellar mud comprises the following steps:
[0063] (1) Pretreatment of straw: The straw was washed and dried, crushed to 60 mesh, and then immersed in a 15% mass concentration of hydrogen peroxide and a 1 mol / L concentration of ferric chloride solution (the volume ratio of hydrogen peroxide to ferric chloride solution was 1:2), the immersion temperature was 55°C, the immersion time was 0.5 h, and after the immersion treatment was completed, the residual liquid was discarded, and the straw was dried to a moisture content of no more than 10%, thereby obtaining pretreated straw;
[0064] (2) Preparation of environmentally friendly seedling pots: 45 g of pretreated straw and 60 g of cellar mud in step (1) were mixed evenly, and then 5 g of seaweed glue, 15 g of wood ash, 5 g of polyvinyl alcohol, and 100 g of water were added, stirred for 50 min, and then placed in a mold, pressed, molded, demolded, and then dried in the sun to obtain the environmentally friendly seedling pot.
[0065] The environmentally friendly seedling pots prepared in Examples 1-4 and Comparative Examples 1-3 were subjected to performance tests, and the test results are shown in Table 1:
[0066] The test of the breaking rate is as follows: weigh the prepared environmentally friendly seedling pot, then drop it freely from a height of 1m to the horizontal ground for 50 consecutive drops, weigh the mass after the drop, and calculate the falling rate:
[0067] Breakdown rate = (M1-M2) / M1×100%
[0068] Where M1 is the mass g before the break, and M2 is the mass g after the break.
[0069] Water absorption test: Fill the environmentally friendly seedling pots with water, remove the water and weigh them after 24 hours, and calculate the water absorption:
[0070] Water absorption = (W2-W1) / W1×100%
[0071] Where W1 is the mass before water absorption, and W2 is the mass after water absorption.
[0072] Dry strength and wet strength test: The seedling pots were subjected to compression test using an electronic universal material testing machine at a compression speed of 20 mm / min. The maximum pressure of the seedling pots before fracturing was measured. The fracturing force obtained by measuring the sample in a dry state at room temperature was the dry strength of the seedling pots. The fracturing force obtained by measuring the sample after soaking it in water at (23±2)°C for 4 hours was the wet strength.
[0073] Table 1
[0074]
[0075]
[0076] It can be seen from the above table that the environmentally friendly seedling pot prepared by the present invention has a lower breakage rate and greater mechanical strength and wet strength. The breakage rate is below 1%. The material remains intact as a whole and can be transported and carried over long distances, which has good industrial application prospects.
[0077] The environmentally friendly seedling pots prepared in Example 3 and Comparative Examples 1-3 were used for seedling raising test, cucumbers were sown, and the growth of cucumbers was recorded regularly. The results are shown in Table 2:
[0078] Table 2
[0079] 10-day germination rate / % 20-day stem height / cm 30-day stem height / cm Example 3 99.8 15.2 31.9 Comparative Example 1 97.3 14.1 27.3 Comparative Example 2 97.7 13.8 27.9 Comparative Example 3 96.1 13.3 26.1
[0080] It can be seen from the above table that the environmentally friendly seedling raising pots produced by the present invention can increase the germination rate of plants, promote plant growth, and are green, environmentally friendly, and non-toxic.
[0081] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.
Claims
1. A process for producing an environmentally friendly seedling pot based on straw and cellar mud, characterized in that: The following steps are involved: (1) Pretreatment of straw: Wash and dry the straw, crush it into 60 mesh, and then soak it in hydrogen peroxide and ferric chloride solution. After the soaking treatment, discard the residual liquid and dry the straw until the moisture content is no more than 10% to obtain pretreated straw; (2) Straw modification: The pretreated straw in step (1) is placed in a sealed glass box and irradiated using an electron beam irradiation bowl. The irradiated straw is then added to an alkaline solution and stirred for reaction. After the reaction is completed, the straw is filtered, washed, and dried to obtain modified straw. (3) Pretreatment of pit mud: add the pit mud into the aqueous solution of silane coupling agent, then place it in a ball mill for ball milling, and dry it at 40-50°C after ball milling to obtain the pretreated pit mud; (4) Preparation of environmentally friendly seedling pots: the modified straw in step (2) and the pretreated pit mud in step (3) are mixed evenly, and then seaweed glue, plant ash, polyvinyl alcohol and water are added and stirred evenly, and then placed in a mold, subjected to compression molding, molding, demolding and then sun-drying to obtain the environmentally friendly seedling pots; In step (1), the straw is one or both of corn straw and rice straw, the mass concentration of the hydrogen peroxide is 10-15%, the concentration of the ferric chloride is 1-2 mol / L, and the volume ratio of the hydrogen peroxide to the ferric chloride solution is 1:1-2; The irradiation conditions in step (2) are: electron energy of 5-10 MeV, irradiation dose of 5-10 megadras; the alkali solution is 1-2 mol / L sodium hydroxide; The mass ratio of the modified straw, pretreated pit mud, seaweed glue, plant ash, polyvinyl alcohol and water in step (4) is 40-50:40-60:5-10:10-20:5-10:80-120.
2. The process for producing an environmentally friendly seedling pot based on straw and cellar mud according to claim 1, characterized in that: The immersion temperature in step (1) is 50-60°C, and the immersion time is 0.5-1h.
3. The process for producing an environmentally friendly seedling pot based on straw and cellar mud according to claim 1, characterized in that: The stirring reaction temperature in step (2) is 20-30°C and the reaction time is 20-40min.
4. The process for producing an environmentally friendly seedling pot based on straw and cellar mud according to claim 1, characterized in that: The mass concentration of the silane coupling agent aqueous solution in step (3) is 3-6%, and the silane coupling agent is one of KH550, KH560, and KH570; the mass ratio of the pit mud to the silane coupling agent aqueous solution is 100:30-50.
5. The process for producing an environmentally friendly seedling pot based on straw and cellar mud according to claim 1, characterized in that: The ball milling speed in step (3) is 2000-3000 r / min, and the time is 30-50 min.
6. The process for producing an environmentally friendly seedling pot based on straw and cellar mud according to claim 1, characterized in that: The stirring time in step (4) is 30-60 min.
7. An environmentally friendly seedling pot based on straw and cellar mud prepared by the process method according to any one of claims 1 to 6.
Citation Information
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