Dynamic luminescence system of light-controlled dissipative self-assembly, preparation method, reversible logic gate and application

Abstract

The present invention discloses a dynamic luminescent system of light-controlled dissipative self-assembly, a preparation method, a reversible logic gate and its application. The system comprises a sulfonic acid merocyanine that self-assembles with a surfactant in acidic water to form a light-controlled dissipative self-assembly system, and then a fluorescent dye is added to obtain the system. The sulfonic acid merocyanine can be photoisomerized to a spiropyran structure at 420±10nm, and then assembled with a surfactant in an acidic aqueous solution at room temperature into a spherical nanoparticle system. At the same time, the assembly system can achieve different dynamic changes in fluorescence by loading different fluorescent dyes. On this basis, a series of reversible logic signal gates that achieve dynamic changes in fluorescence based on different inputs have been developed. The preparation routes of the various light-controlled dissipative self-assembly systems are simple, and the dynamic changes in fluorescence can be achieved by simply changing the self-assembly system or changing the wavelength of the excitation light. This can be used as the design basis for logic signals, and has great application potential in the fields of information transmission and information storage, such as molecular computing and sensing.

Description

Technical Field

[0001] The present invention relates to a dynamic luminescent system, a preparation method, and various logic gates and applications, and in particular to a dynamic luminescent system of light-controlled dissipative self-assembly, a preparation method, and reversible logic gates and applications, belonging to the field of logic gates. Background Art

[0002] Logic gates are fundamental digital circuit elements used to perform logical operations. They typically consist of multiple inputs and a single output, whose output state depends on the logic state of the input signals. Different types of logic gates can perform different logical operations, such as AND, OR, NOT, and XOR. Logic gates play a crucial role in digital electronic circuits, enabling the implementation of a variety of digital logic circuits, such as computers, communications systems, and control systems. They are the foundation of digital electronic technology.

[0003] Molecular logic gates that modulate fluorescence intensity have been reported. While logic systems based on fluorescence intensity have been developed, they lack diversity and spatiotemporal complexity. While the use of fluorescence signals and changes as dynamic demonstration and imaging techniques has garnered significant attention, logic gates based on fluorescence still require further design and optimization. Some studies aimed at modulating fluorescence have encountered challenges, such as irreversibility and monotonic fluorescence changes. These issues urgently need to be addressed, particularly given the adverse effects of monotonic fluorescence changes on information transmission. Summary of the Invention

[0004] Purpose of the invention: The first purpose of the present invention is to provide a dynamic luminescent system of light-controlled dissipative self-assembly, the second purpose of the present invention is to provide a preparation method of the dynamic luminescent system of light-controlled dissipative self-assembly, the third purpose of the present invention is to provide a reversible logic gate comprising the dynamic luminescent system of light-controlled dissipative self-assembly, and the fourth purpose of the present invention is to provide the application of the dynamic luminescent system of light-controlled dissipative self-assembly or the reversible logic gate in information transmission and storage.

[0005] Technical solution: The light-controlled dissipative self-assembly dynamic luminescence system of the present invention comprises sulfonic acid merocyanine self-assembly with a surfactant in acidic water to form a light-controlled dissipative self-assembly system, and then adding a fluorescent dye to obtain the system.

[0006] Furthermore, the structure of the sulfonic acid merocyanine is shown in Formula I,

[0007]

[0008] Furthermore, the surfactant is dodecyltrimethylammonium chloride, tetradecyltrimethylammonium chloride or hexadecyltrimethylammonium chloride.

[0009] Furthermore, the structural formula of the dodecyltrimethylammonium chloride is shown in Formula II,

[0010]

[0011] Furthermore, the structural formula of the tetradecyltrimethylammonium chloride is shown in Formula III,

[0012]

[0013] Furthermore, the structural formula of the hexadecyltrimethylammonium chloride is shown in Formula IV,

[0014]

[0015] Furthermore, the fluorescent dye is disodium distyryl diphenyl disulfonate, eosin Y or sulforhodamine B.

[0016] Furthermore, the acidic water is prepared by adjusting the pH of the water with hydrochloric acid, because the sulfonic acid merocyanine will be ineffective under alkaline conditions, and it is difficult to have a very good effect under very low acidic conditions, so the pH of the acidic water is selected to be 4-6.

[0017] Furthermore, when the surfactant is dodecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.75-1.25 mmol / L, and the concentration of the sulfonic acid merocyanine is 0.12-0.16 mmol / L.

[0018] Furthermore, when the surfactant is tetradecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.1-0.4 mmol / L, and the concentration of the sulfonic acid merocyanine is 0.08-0.12 mmol / L.

[0019] Furthermore, when the surfactant is hexadecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.02-0.06 mmol / L, and the concentration of the sulfonic acid merocyanine is 0.7-0.11 mmol / L.

[0020] The preparation method of the light-controlled dissipative self-assembled dynamic luminescence system described in the present invention includes the following steps: dissolving sulfonic acid merocyanine solid dispersion in acidic water, ultrasonically dissolving, adding a surfactant and fully mixing to obtain a light-controlled dissipative self-assembled system, and adding a fluorescent dye to the light-controlled dissipative self-assembled system and stirring evenly to obtain the light-controlled dissipative self-assembled dynamic luminescence system.

[0021] The present invention also includes a reversible logic gate of light-controlled dissipative self-assembly loaded with fluorescent molecules, and the reversible logic gate includes the light-controlled dissipative self-assembly dynamic luminescence system of the present invention as a light-controlled dissipative system.

[0022] Furthermore, the reversible logic gate is an AND gate, an XNOR gate, or an XOR gate.

[0023] Furthermore, the reversible logic gate is a dual-input single-output mechanism, where input A is 420±10nm light irradiation or dark conditions, input B is various excitation lights or surfactants, and output C is the intensity of fluorescence change.

[0024] Furthermore, when it is an AND gate, the system obtained by adding the fluorescent dye disodium distyryl diphenyl disulfonate into the light-controlled dissipative self-assembly system of the surfactant dodecyltrimethylammonium chloride and sulfonic acid merocyanine is used as the light-controlled dissipative system, the input A is dark conditions or 420±10nm light irradiation, the input B is dark or 350±20nm light irradiation, and the output C is the strength of the fluorescence intensity of 440±10nm.

[0025] Furthermore, when it is an exclusive-NOR gate XNOR, the system obtained by adding the fluorescent dye Eosin Y into the light-controlled dissipative self-assembly system of the surfactant hexadecyltrimethylammonium chloride and sulfonic acid merocyanine or the light-controlled dissipative self-assembly system of the surfactant dodecyltrimethylammonium chloride and sulfonic acid merocyanine is used as the light-controlled dissipative system, the input A is darkness or 420±10nm light irradiation, the input B is the surfactant dodecyltrimethylammonium chloride or the surfactant hexadecyltrimethylammonium chloride, and the output C is the strength of the fluorescence intensity at 550±10nm.

[0026] Furthermore, when it is gate XOR, the system obtained by adding the fluorescent dye sulfonylrhodamine B into the light-controlled dissipative self-assembly system of the surfactant tetradecyltrimethylammonium chloride and sulfonic acid merocyanine is used as a light-controlled dissipative system, the input A is darkness or 420±10nm light irradiation, the input B is 365±10nm or 570±10nm light irradiation, and the output C is the strength of the fluorescence intensity of 590±10nm.

[0027] The application of the light-controlled dissipative self-assembled dynamic luminescence system or the reversible logic gate described in the present invention in information transmission and storage.

[0028] The present invention is based on the interaction between the light-responsive molecule sulfonic acid merocyanine and a series of cationic surfactants to form a light-dissipative self-assembly system, which is then loaded with a fluorescent dye to obtain a light-controlled dissipative self-assembled dynamic luminescence system. Sulfonic acid merocyanine can be photoisomerized to a spiropyran structure at 420±10nm, and then assembled with a surfactant in an acidic aqueous solution at room temperature into spherical nanoparticles, i.e., a light-controlled dissipative self-assembly system. At the same time, this type of light-controlled dissipative self-assembly system can achieve different dynamic changes in fluorescence by loading different fluorescent dyes. On this basis, a series of logic signal gates that achieve dynamic changes in fluorescence based on different inputs have been developed. The preparation routes of the various light-controlled dissipative self-assembled dynamic luminescence systems in the present invention are simple, and the dynamic changes in fluorescence only need to be achieved by changing the dynamic luminescence system or changing the wavelength of the excitation light and used as the design basis for the logic signal. It has great application potential in the fields of information transmission and information storage such as molecular computing and sensing.

[0029] Beneficial effects: Compared with the prior art, the present invention has the following significant advantages:

[0030] This invention designs a series of light-controlled dissipative self-assemblies and develops multiple dynamic luminescence systems with excellent reciprocity, high operability, and simplicity. These systems, as exemplary examples of fluorescence-dependent logic gates, lay the foundation for solving information transmission problems and for applications in organic systems with logic signals. They simplify basic logic gate designs within existing logic gates, enrich the application of organic systems in fluorescence logic gates, and optimize the reciprocity and non-monotonicity of fluorescence changes in the development of fluorescence logic gates. BRIEF DESCRIPTION OF THE DRAWINGS

[0031] Figure 1 To fix the concentration of dodecyltrimethylammonium chloride at 1mmol / L, the concentration of sulfonic acid merocyanine solution was gradually increased from 0 to 0.16mmol / L.

[0032] Figure 2 The UV transmission titration diagram shows that the concentration of sulfonic acid merocyanine is fixed at 0.14mmol / L and the concentration of dodecyltrimethylammonium chloride is gradually increased from 0 to 3mmol / L.

[0033] Figure 3 The UV transmittance titration diagram of the sulfonic acid merocyanine concentration gradually increasing from 0 to 0.1 mmol / L when the concentration of tetradecyltrimethylammonium chloride is fixed at 0.2 mmol / L.

[0034] Figure 4 The UV transmittance titration diagram is when the concentration of tetradecyltrimethylammonium chloride is gradually increased from 0 to 0.5 mmol / L when the concentration of sulfonic acid merocyanine is fixed at 0.1 mmol / L.

[0035] Figure 5 The UV transmittance titration diagram of the sulfonic acid merocyanine gradually increasing from 0 to 0.1 mmol / L when the concentration of hexadecyltrimethylammonium chloride is fixed at 0.04 mmol / L.

[0036] Figure 6 The UV transmittance titration diagram shows that the concentration of merocyanine sulfonate is fixed at 0.09 mmol / L and the concentration of hexadecyltrimethylammonium chloride is gradually increased from 0 to 0.08 mmol / L.

[0037] Figure 7 This is a scanning electron micrograph of spherical nanoparticles formed after irradiation of sulfonic acid merocyanine and dodecyltrimethylammonium chloride;

[0038] Figure 8 This is a transmission electron microscopy image of spherical nanoparticles formed after sulfonic acid merocyanine and dodecyltrimethylammonium chloride were irradiated with light;

[0039] Figure 9 The AND logic gate includes 0.01 mmol / L disodium distyryl diphenyl disulfonate, and the dynamic changes of fluorescence at 444 nm under 350 nm excitation before and after 420 nm illumination;

[0040] Figure 10 The logic gate XNOR includes 0.01mmol / L and 0.005mmol / L of the fluorescent dye Eosin Y, and the dynamic changes of fluorescence at 550nm under 520nm excitation before and after 420nm light irradiation;

[0041] Figure 11 This is a logic gate XOR, which includes 0.02 mmol / L of the fluorescent dye sulforhodamine B. The dynamic changes of fluorescence at 590 nm under excitation at 365 nm and 570 nm before and after irradiation with 420 nm light. DETAILED DESCRIPTION

[0042] The technical solution of the present invention is further described below with reference to the accompanying drawings. 1 μL of 1 mol / L hydrochloric acid is added to 25 mL of neutral water to adjust the pH of the water to obtain acidic water with a pH of 5.6-5.7;

[0043] A 0.5 mmol / L sulfonic acid merocyanine solution was prepared as the mother solution for subsequent experiments;

[0044] Example 1

[0045] The sulfonic acid merocyanine solid dispersion was dissolved in acidic water, and ultrasonic dissolution was performed to obtain concentrations of 0 mmol / L, 0.02 mmol / L, 0.04 mmol / L, 0.06 mmol / L, 0.08 mmol / L, 0.10 mmol / L, 0.12 mmol / L, 0.14 mmol / L and 0.16 mmol / L, respectively. The surfactant dodecyltrimethylammonium chloride was added and mixed thoroughly, and the concentration of dodecyltrimethylammonium chloride in the system was fixed at 1 mmol / L to obtain nine groups of light-controlled dissipative self-assembly systems.

[0046] The optical transmittance of the nine groups of light-controlled dissipative self-assembly systems at 650 nm was measured after irradiation with 420 nm light for 150 s. Figure 1 shown. Figure 1 To fix the concentration of dodecyltrimethylammonium chloride at 1mmol / L, the concentration of sulfonic acid merocyanine solution gradually increased from 0 to 0.16mmol / L. Figure 1 It can be seen that the concentration of sulfonic acid merocyanine gradually decreases with the increase of the concentration of sulfonic acid merocyanine, so on this basis, the concentration of sulfonic acid merocyanine solution was selected to be 0.14mmol / L for subsequent exploration experiments. Among them, the structural formula of dodecyltrimethylammonium chloride is shown in Formula II.

[0047]

[0048] Example 2

[0049] The preparation process of the light-controlled dissipative self-assembly system is the same as that in Example 1, wherein the concentration of the fixed sulfonic acid merocyanine is 0.14 mmol / L, and the concentrations of dodecyltrimethylammonium chloride are 0 mmol / L, 0.25 mmol / L, 0.5 mmol / L, 0.75 mmol / L, 1.0 mmol / L, 1.25 mmol / L, 1.5 mmol / L, 2.0 mmol / L, 2.5 mmol / L, and 3.0 mmol / L, respectively, to obtain ten groups of light-controlled dissipative self-assembly systems.

[0050] The optical transmittance of the ten light-controlled dissipative self-assembly systems was also measured at 650 nm after irradiation with 420 nm light for 150 s. Figure 2 shown. Figure 2 The UV transmission titration diagram of the fixed concentration of sulfonic acid merocyanine at 0.14mmol / L and the concentration of dodecyltrimethylammonium chloride gradually increasing from 0 to 3mmol / L is shown in the figure. Figure 2 It can be seen that the lowest point of optical transmittance appeared when the concentration of dodecyltrimethylammonium chloride was 1 mmol / L, indicating that the optimal assembly concentration was dodecyltrimethylammonium chloride 1 mmol / L / merocyanine sulfonate 0.14 mmol / L.

[0051] The spherical nanoparticles formed by irradiating the sulfonic acid merocyanine and dodecyltrimethylammonium chloride obtained by the optimal assembly concentration of dodecyltrimethylammonium chloride 1mmol / L / sulfonic acid merocyanine 0.14mmol / L in this example were analyzed by scanning electron microscopy and transmission electron microscopy. The results are as follows: Figure 7-8 As shown. Figure 7 This is a scanning electron micrograph of spherical nanoparticles formed by sulfonic acid merocyanine and dodecyltrimethylammonium chloride after irradiation; Figure 7 It can be seen that sulfonic acid cyanine and dodecyltrimethylammonium chloride form 80nm spherical nanoparticles after illumination. In the dark, sulfonic acid cyanine and dodecyltrimethylammonium chloride do not assemble, but after illumination, sulfonic acid cyanine isomerizes and dodecyltrimethylammonium chloride forms 80nm spherical nanoparticles.

[0052] Figure 8 This is a transmission electron microscopy image of spherical nanoparticles formed by sulfonic acid merocyanine and dodecyltrimethylammonium chloride after light exposure; Figure 8 It can be seen that dodecyltrimethylammonium chloride and sulfonic acid merocyanine successfully constructed a light-controlled dissipative self-assembly system before and after illumination.

[0053] Example 3

[0054] The preparation process of the light-controlled dissipative self-assembly system is the same as that in Example 1, wherein tetradecyltrimethylammonium chloride is used as the surfactant, the concentration of tetradecyltrimethylammonium chloride is fixed at 0.2 mmol / L, and the concentration of sulfonic acid merocyanine is gradually increased from 0 to 0.1 mmol / L, that is, 0 mmol / L, 0.01 mmol / L, 0.02 mmol / L, 0.03 mmol / L, 0.04 mmol / L, 0.05 mmol / L, 0.06 mmol / L, 0.07 mmol / L, 0.08 mmol / L, 0.09 mmol / L and 0.10 mmol / L, respectively, to obtain eleven groups of light-controlled dissipative self-assembly systems.

[0055] The above eleven groups of light-controlled dissipative self-assembly systems were also irradiated with 420nm light for 150s and the optical transmittance at 650nm was measured. The results are as follows: Figure 3 shown. Figure 3 The UV transmittance titration diagram of the sulfonic acid merocyanine concentration gradually increasing from 0 to 0.1 mmol / L when the concentration of tetradecyl trimethyl ammonium chloride is fixed at 0.2 mmol / L is obtained by Figure 3It can be seen that the optical transmittance gradually decreases with the increase of the sulfonic acid merocyanine concentration, but changes occur when the sulfonic acid merocyanine concentration is around 0.01mmol / L. When the optical transmittance increases from 0 to 0.01mmol / L, there is basically no change in the optical transmittance, while the rate of decrease of the optical transmittance at 650nm increases significantly from 0.01 to 0.1mmol / L. Therefore, the sulfonic acid merocyanine concentration is selected to be 0.1mmol / L. Among them, the structural formula of epitetradecyltrimethylammonium chloride is shown in Formula III,

[0056]

[0057] Example 4

[0058] The preparation process of the light-controlled dissipative self-assembly system is the same as that in Example 1, wherein the concentration of sulfonic acid merocyanine is fixed at 0.1 mmol / L, and the concentration of tetradecyltrimethylammonium chloride is increased from 0 to 0.5 mmol / L, i.e., 0 mmol / L, 0.05 mmol / L, 0.1 mmol / L, 0.15 mmol / L, 0.2 mmol / L, 0.25 mmol / L, 0.3 mmol / L, 0.35 mmol / L, 0.4 mmol / L, 0.45 mmol / L and 0.5 mmol / L, respectively, to obtain eleven groups of light-controlled dissipative self-assembly systems.

[0059] The above eleven groups of light-controlled dissipative self-assembly systems were also irradiated with 420nm light for 150s and the optical transmittance at 650nm was measured. The results are as follows: Figure 4 shown. Figure 4 The UV transmission titration diagram of the fixed concentration of sulfonic acid merocyanine at 0.1mmol / L and the concentration of tetradecyltrimethylammonium chloride gradually increasing from 0 to 0.5mmol / L is shown in the figure. Figure 4 It can be seen that the optical transmittance at 650 nm is lowest at a concentration of 0.2 mmol / L of tetradecyltrimethylammonium chloride, ranging from 86–88%, which is consistent with the previous experimental results with an error of no more than 2%, indicating that the optimal assembly concentration is 0.2 mmol / L of tetradecyltrimethylammonium chloride / 0.1 mmol / L of sulfonic acid merocyanine.

[0060] Example 5

[0061] The preparation process of the light-controlled dissipative self-assembly system is the same as that in Example 1, wherein cetyltrimethylammonium chloride is used as the surfactant, the concentration of cetyltrimethylammonium chloride is fixed at 0.04 mmol / L, and the concentration of sulfonic acid merocyanine is gradually increased from 0 to 0.1 mmol / L, that is, 0 mmol / L, 0.01 mmol / L, 0.02 mmol / L, 0.03 mmol / L, 0.04 mmol / L, 0.05 mmol / L, 0.06 mmol / L, 0.07 mmol / L, 0.08 mmol / L, 0.09 mmol / L and 0.1 mmol / L, respectively, to obtain eleven groups of light-controlled dissipative self-assembly systems.

[0062] The above eleven groups of light-controlled dissipative self-assembly systems were also irradiated with 420nm light for 150s and the optical transmittance at 650nm was measured. The results are as follows: Figure 5 shown. Figure 5 The UV transmittance titration diagram of the sulfonic acid merocyanine concentration gradually increasing from 0 to 0.1 mmol / L when the concentration of hexadecyltrimethylammonium chloride is fixed at 0.04 mmol / L is obtained by Figure 5 It can be seen that the optical transmittance at 650nm gradually decreases with the increase of the concentration of sulfonic acid merocyanine, but changes when the concentration of sulfonic acid merocyanine is about 0.04mmol / L. Therefore, the optimal concentration of sulfonic acid merocyanine is selected as 0.09mmol / L. Among them, the structural formula of hexadecyltrimethylammonium chloride is shown in Formula IV.

[0063]

[0064] Example 6

[0065] The preparation process of the light-controlled dissipative self-assembly system was the same as that in Example 1, wherein the concentration of sulfonic acid merocyanine was fixed at 0.09 mmol / L, and the concentration of hexadecyltrimethylammonium chloride was gradually increased from 0 to 0.08 mmol / L, i.e., 0 mmol / L, 0.01 mmol / L, 0.02 mmol / L, 0.03 mmol / L, 0.04 mmol / L, 0.05 mmol / L, 0.06 mmol / L, 0.07 mmol / L and 0.08 mmol / L, respectively, to obtain nine groups of light-controlled dissipative self-assembly systems.

[0066] The optical transmittance of the nine groups of light-controlled dissipative self-assembly systems was also measured at 650nm after irradiation with 420nm light for 150s. Figure 6 shown. Figure 6 The UV transmittance titration diagram of the fixed concentration of sulfonic acid merocyanine at 0.09mmol / L and the concentration of hexadecyltrimethylammonium chloride gradually increasing from 0 to 0.08mmol / L is shown in the figure. Figure 6It can be seen that the lowest point of the optical transmittance at 650 nm appeared at 0.04 mmol / L of hexadecyltrimethylammonium chloride, indicating that the optimal assembly concentration is 0.04 mmol / L of hexadecyltrimethylammonium chloride and 0.09 mmol / L of sulfonic acid merocyanine.

[0067] Example 7

[0068] Prepare a 1 mmol / L solution of the fluorescent dye disodium distyryldiphenyl disulfonate in dimethyl sulfoxide (DMSO).

[0069] The preparation process of the light-controlled dissipative self-assembly system is the same as that of Example 1, and the light-controlled dissipative self-assembly system is prepared according to the optimal assembly concentration of 1 mmol / L dodecyltrimethylammonium chloride and 0.14 mmol / L merocyanine sulfonate;

[0070] The above-configured fluorescent dye disodium distyryl diphenyl disulfonate solution was added to the above-mentioned light-controlled dissipative self-assembly system with a concentration of 1 mmol / L dodecyltrimethylammonium chloride and 0.14 mmol / L merocyanine sulfonate to obtain a light-controlled dissipative self-assembly dynamic luminescence system, so that the concentration of disodium distyryl diphenyl disulfonate in the dynamic luminescence system was 0.01 mmol / L.

[0071] The above-mentioned dynamic luminescence system of light-controlled dissipative self-assembly is used to prepare a reversible logic gate, wherein the input A is darkness 0 or 420±10nm light irradiation 1, the input B is darkness 0 or 350±20nm light irradiation 1, and the output C is 440±10nm fluorescence intensity weak 0 and fluorescence intensity strong 1, respectively. Figure 9 As shown, a logic signal gate AND gate among the reversible logic signal gates of light-controlled dissipative self-assembly loaded fluorescent molecules is obtained.

[0072] Figure 9 It is an AND gate design, which includes 0.01mmol / L disodium distyryl diphenyl disulfonate, 420nm light irradiation, 444nm fluorescence dynamic change diagram and fluorescence photograph under 350nm excitation; A is an input and output schematic, including input 350±20nm light irradiation or darkness and input 420±10nm light irradiation or darkness, and the output is 440±10nm fluorescence intensity, B is a truth table, that is, when input A is 1 and input B is 1, output C is 1, and in other input states, output C is 0, C is a schematic diagram of the dissipative self-assembly process of two input stimulus responses and output fluorescence intensity changes, under 420±10nm light irradiation and 350±20nm light irradiation, the fluorescence intensity of 440±10nm gradually becomes stronger and stabilizes after 33s, while under dark conditions, the fluorescence intensity is weak and the output is 0. Five cycles were performed. By Figure 9It can be seen that the logic gate AND gate can be reciprocated and successfully implemented.

[0073] Example 8

[0074] Prepare a 1 mmol / L fluorescent dye Eosin Y solution in dimethyl sulfoxide (DMSO).

[0075] The preparation process of the light-controlled dissipative self-assembly system is the same as that of Example 1, and the light-controlled dissipative self-assembly system is prepared according to the optimal assembly concentration of 1 mmol / L of dodecyltrimethylammonium chloride and 0.14 mmol / L of merocyanine sulfonate; or the light-controlled dissipative self-assembly system is prepared according to the optimal assembly concentration of 0.09 mmol / L of hexadecyltrimethylammonium chloride and 0.04 mmol / L of merocyanine sulfonate;

[0076] The fluorescent dye Eosin Y is added to the above-mentioned light-controlled dissipative self-assembly system with a concentration of 1 mmol / L dodecyltrimethylammonium chloride and 0.14 mmol / L merocyanine sulfonate to obtain a light-controlled dissipative self-assembly dynamic luminescence system, so that the concentration of Eosin Y in the system is 0.01 mmol / L, or the fluorescent dye Eosin Y is added to the above-mentioned light-controlled dissipative self-assembly system with a concentration of 0.09 mmol / L hexadecyltrimethylammonium chloride and 0.04 mmol / L merocyanine sulfonate to obtain a light-controlled dissipative self-assembly dynamic luminescence system, so that the concentration of Eosin Y in the system is 0.005 mmol / L;

[0077] The above-mentioned dynamic luminescence system of light-controlled dissipative self-assembly is used to prepare a reversible logic gate, wherein the input A is darkness 0 or 420±10nm light irradiation 1, the input B is surfactant hexadecyltrimethylammonium chloride 0 or surfactant dodecyltrimethylammonium chloride 1, and the output C is 550±10nm fluorescence intensity weak 0 and fluorescence intensity strong 1, respectively. Figure 10 As shown, a logic signal gate XNOR is obtained among the reversible logic signal gates of light-controlled dissipative self-assembly loaded with fluorescent molecules.

[0078] Figure 10This is an XNOR logic gate design, which includes 0.01mmol / L and 0.005mmol / L of the fluorescent dye Eosin Y, respectively, before and after 420nm light irradiation, and under 520nm excitation, the 550nm fluorescence dynamic change diagram; where A is the input and output schematic, including input A surfactant hexadecyltrimethylammonium chloride or surfactant dodecyltrimethylammonium chloride and input B 420±10nm light irradiation or darkness, the output is a fluorescence intensity of 550±10nm, B is a summary diagram, C is a truth table and a schematic diagram of the dissipative self-assembly process of two input stimulus responses and output fluorescence intensity changes, that is, when input A is 1 and input B is 1, output C is 1; when input A is 0 and input B is 0, output C is 1; when input A is 0 and input B is 1, output C is 0; when input A is 1 and input B is 0, output C is 0. Under 420±10nm light irradiation and surfactant hexadecyltrimethylammonium chloride, under 520±20nm light irradiation, it stabilizes after 90s, and the fluorescence intensity of 550±10nm is stable. The fluorescence intensity is strong and output is 1; in the absence of 420±10nm light irradiation and surfactant hexadecyltrimethylammonium chloride, the fluorescence intensity of 550±10nm becomes weak under 520±20nm light irradiation and the output is 0; while under 420±10nm light irradiation and surfactant dodecyltrimethylammonium chloride, the fluorescence intensity of 550±10nm becomes weak under 520±20nm light irradiation and the output is 0; while in the absence of 420±10nm light irradiation and surfactant dodecyltrimethylammonium chloride, the fluorescence intensity of 550±10nm becomes strong under 520±20nm light irradiation and the output is 1. Five cycles were performed respectively. Figure 10 It can be seen that the reversible reciprocation of the logic gate XNOR is successfully implemented.

[0079] Example 9

[0080] Prepare a 1 mmol / L solution of the fluorescent dye sulforhodamine B in dimethyl sulfoxide (DMSO).

[0081] The preparation process of the light-controlled dissipative self-assembly system is the same as that of Example 1, and the light-controlled dissipative self-assembly system is prepared according to the optimal assembly concentration of tetradecyltrimethylammonium chloride 0.2 mmol / L and merocyanine sulfonate 0.1 mmol / L;

[0082] The fluorescent dye sulfonylrhodamine B solution configured above was added to the above-mentioned light-controlled dissipative self-assembly system with a concentration of 0.2 mmol / L dodecyltrimethylammonium chloride and 0.1 mmol / L sulfonic acid merocyanine to obtain a light-controlled dissipative self-assembly dynamic luminescence system, so that the concentration of sulfonylrhodamine B in the dynamic luminescence system was 0.01 mmol / L.

[0083] The above-mentioned dynamic luminescence system of light-controlled dissipative self-assembly is used to prepare a reversible logic gate, wherein the input A is darkness 0 or 420±10nm light irradiation 1, the input B is 365±10nm light irradiation 0 and 570±10nm light irradiation 1, and the output C is 590±10nm fluorescence intensity weak 0 and fluorescence intensity strong 1, respectively. Figure 11 As shown, a reversible logic signal gate XOR gate among the logic signal gates of light-controlled dissipative self-assembly loaded fluorescent molecules is obtained.

[0084] Figure 11 Design of an XOR logic gate, which includes 0.02mmol / L of the fluorescent dye sulfonylrhodamine B, and the dynamic change diagram of 590nm fluorescence under 365nm and 570nm excitation before and after 420nm light irradiation. Among them, A is an input-output schematic, which includes input A 420±10nm light irradiation or darkness and input A 365±10nm light irradiation or 570±10nm light irradiation, and the output is the fluorescence intensity of 590±10nm. B is a summary diagram, and C is a truth table and a schematic diagram of the dissipative self-assembly process of two input stimulus responses and output fluorescence intensity changes, that is, when input A is 1 and input B is 1, output C is 0; when input A is 0 and input B is 0, output C is 0; when input A is 0 and input B is 1, output C is 1; when input A is 1 and input B is 0, output C is 1, and when input A is 1 and input B is 0, output C is 1. Under irradiation, it stabilizes after 50s, the fluorescence intensity of 590±10nm is weak, and the output is 0; without irradiation of 420±10nm light and 570±10nm light, the fluorescence intensity of 590±10nm becomes stronger, and the output is 1; under irradiation of 420±10nm light and 365±10nm light, the fluorescence intensity of 590±10nm becomes stronger, and the output is 1; without irradiation of 420±10nm light and 365±10nm light, the fluorescence intensity of 590±10nm becomes weak, and the output is 0. Five cycles were performed, respectively. Figure 11 It can be seen that the reversible reciprocation of the logic gate XOR is successfully implemented.

Claims

1. A dynamic luminescent system of light-controlled dissipative self-assembly, characterized in that: The system comprises the following steps: a sulfonic acid merocyanine is self-assembled with a surfactant in acidic water to form a light-controlled dissipative self-assembly system, and then a fluorescent dye is added thereto; the surfactant is dodecyltrimethylammonium chloride, tetradecyltrimethylammonium chloride or hexadecyltrimethylammonium chloride; the fluorescent dye is disodium distyryldiphenyl disulfonate, eosin Y or sulforhodamine B; the acidic water is prepared by adjusting the pH value of the water to 4-6 using hydrochloric acid; and the structure of the sulfonic acid merocyanine is shown in Formula I: Formula I.

2. The dynamic luminescence system of light-controlled dissipative self-assembly according to claim 1, characterized in that: When the surfactant is dodecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.75-1.25 mmol / L, and the concentration of sulfonic acid merocyanine is 0.12-0.16 mmol / L. When the surfactant is tetradecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.1-0.4 mmol / L, and the concentration of sulfonic acid merocyanine is 0.08-0.12 mmol / L. When the surfactant is hexadecyltrimethylammonium chloride, the concentration of the surfactant in the light-controlled dissipative self-assembly system is 0.02-0.06 mmol / L, and the concentration of sulfonic acid merocyanine is 0.7-0.11 mmol / L.

3. The method for preparing the light-controlled dissipative self-assembly dynamic luminescence system according to claim 1 or 2, characterized in that: The method comprises the following steps: dissolving sulfonic acid merocyanine solid dispersion in acidic water, adding a surfactant after ultrasonic dissolution and fully mixing to obtain a light-controlled dissipative self-assembly system, adding a fluorescent dye to the light-controlled dissipative self-assembly system and stirring evenly to obtain a light-controlled dissipative self-assembly dynamic luminescence system.

4. A reversible logic gate of light-controlled dissipative self-assembly loaded with fluorescent molecules, characterized in that: The reversible logic gate includes the light-controlled dissipative self-assembled dynamic luminescence system described in claim 1 or 2 as a light-controlled dissipative system, the reversible logic gate is an AND gate, an XNOR gate or an XOR gate, and the reversible logic gate is a dual-input single-output mechanism, the input A is 420±10 nm light irradiation or dark conditions, the input B is various excitation lights or surfactants, and the output C is the intensity of the fluorescence change.

5. The light-controlled dissipative self-assembled reversible logic gate loaded with fluorescent molecules according to claim 4, characterized in that: When the AND gate is set as AND, the fluorescent dye disodium distyryl diphenyl disulfonate is added to the light-controlled dissipative self-assembly system of the surfactant dodecyltrimethylammonium chloride and sulfonic acid merocyanine as the light-controlled dissipative system. The input A is dark conditions or 420±10 nm light irradiation, the input B is dark conditions or 350±20 nm light irradiation, and the output C is the strength of the fluorescence intensity at 440±10 nm.

6. The light-controlled dissipative self-assembled reversible logic gate loaded with fluorescent molecules according to claim 4, characterized in that: When it is an exclusive-NOR gate XNOR, the light-controlled dissipative self-assembly system of surfactant hexadecyltrimethylammonium chloride and sulfonic acid merocyanine or the light-controlled dissipative self-assembly system of surfactant dodecyltrimethylammonium chloride and sulfonic acid merocyanine is added to the system obtained by adding fluorescent dye Eosin Y as the light-controlled dissipative system, the input A is darkness or 420±10 nm light irradiation, the input B is surfactant dodecyltrimethylammonium chloride or surfactant hexadecyltrimethylammonium chloride, and the output C is the strength of the fluorescence intensity at 550±10 nm.

7. The light-controlled dissipative self-assembled reversible logic gate loaded with fluorescent molecules according to claim 4, characterized in that: When the XOR gate is used, the fluorescent dye sulfonylrhodamine B is added to the light-controlled dissipative self-assembly system of the surfactant tetradecyltrimethylammonium chloride and sulfonic acid merocyanine as the light-controlled dissipative system. The input A is darkness or 420±10 nm light irradiation, the input B is 365±10 nm or 570±10 nm light irradiation, and the output C is the strength of the fluorescence intensity at 590±10 nm.

8. Application of the dynamic luminescent system of light-controlled dissipative self-assembly according to claim 1 or 2 or the reversible logic gate according to any one of claims 4 to 7 in information transmission and storage.

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