一种非均质梯度高硅负极极片及其制备方法与应用

By employing a gradient distribution design of silicon and graphite on the negative electrode sheet of a lithium-ion battery, the problems of low graphite capacity and easy destruction of silicon-based negative electrode structure are solved, realizing a lithium-ion battery with high energy density and long life, and simplifying the manufacturing process.

CN116960277BActive Publication Date: 2026-07-17HEFEI GUOXUAN HIGH TECH POWER ENERGY
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Patent Information

Application Number
CN202310869680.X
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-07-14
Publication Date
2026-07-17
Estimated Expiration
2043-07-14

AI Technical Summary

Technical Problem

The theoretical specific capacity of graphite, an existing lithium-ion battery anode material, is low. The structure of silicon-based anodes is easily damaged during lithium insertion/extraction cycling, leading to a decline in cycle performance. Furthermore, existing pre-lithiation technology is difficult to implement and has low production efficiency, failing to meet the demand for high energy density.

Method used

The silicon-carbon anode sheet with a heterogeneous gradient design forms a gradient electrode by coating silicon and graphite on the current collector. The silicon content decreases from the inside to the outside, while the graphite content increases from the inside to the outside. Combined with a special slurry formulation and processing technology, this optimizes the lithium-ion intercalation process.

Benefits of technology

It significantly improves the energy density and cycle performance of lithium-ion batteries, reduces electrode expansion rate, extends battery life, simplifies manufacturing process, and is suitable for mass production.

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Abstract

本发明公开了一种非均质梯度高硅负极极片及其制备方法与应用。本发明提供的硅碳负极极片,包括如下组成:集流体及覆于其上下表面的涂层;所述涂层中硅和石墨的含量分别呈梯度分布;其中所述硅的含量由内至外梯度降低,所述石墨的含量由内至外梯度增加。本发明能够提高石墨的嵌锂深度,有效抑制电极膨胀的同时提升电芯的循环性能,所得锂离子电池的电芯能量密度>380Wh / Kg。
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Citation Information

Patent Citations

  • Graphite / silicon gradient electrode material and preparation method and fast charging application thereof

    CN114156458A