Mosquito-repelling carpet surface for mosquito-repelling automobile carpet, and preparation method and application thereof
By using a combination of plant particles and mosquito repellent masterbatch in automotive carpets, the problems of complex and costly preparation of existing mosquito repellent carpet surfaces are solved, achieving a simple, low-cost, and highly effective mosquito repellent effect, while also improving the mechanical properties and mosquito repellent durability of automotive carpets.
Patent Information
- Application Number
- CN202311383899.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-10-24
- Publication Date
- 2025-12-26
- Estimated Expiration
- 2043-10-24
AI Technical Summary
Existing mosquito repellent blankets have complex manufacturing processes, high costs, and are not suitable for use in cars; further improvements are needed to enhance their mosquito-repellent effect.
The mosquito repellent blanket is made by combining silk thread material with plant particles and mosquito repellent masterbatch. The plant particles are a mixture of rue, bitter yam, patchouli, camphor, mint and mosquito repellent grass. The mosquito repellent masterbatch is composed of ethyl butyl acetaminophen, polycyclic aromatic esters, lubricants and dispersants. The blanket is made by melt conveying, spinning, cooling, stretching and winding, and then bonded to SBR layer, PU sponge layer, XPE foam layer and silicone anti-slip bottom.
It achieves a simple and low-cost manufacturing process, is suitable for use in automobiles, and has a highly efficient and long-lasting mosquito-repellent effect, while also possessing good mechanical and anti-slip properties.
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Figure CN117364282B_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The present application relates to the field of automotive interior, in particular to a mosquito-repelling carpet surface for mosquito-repelling automotive carpet, and a preparation method and application thereof. BACKGROUND
[0002] With the continuous rise of global temperature, the population and quantity of mosquitoes are greatly improved, which increasingly threatens human health. In addition to direct biting and blood-sucking, mosquitoes also spread a variety of diseases. In China, there are four types of mosquito-borne diseases, including malaria, lymphatic filariasis, epidemic encephalitis B and dengue fever (or dengue hemorrhagic fever). In addition, mosquito-borne viral diseases also include yellow fever and various equine encephalitis, which are extremely harmful. As one of the four major pests, mosquitoes not only affect people's daily life, but also are the carriers of various diseases. For the car which has basically integrated into people's life as a means of transportation, mosquitoes entering the car pose a certain degree of threat to the health of the driver and passengers.
[0003] At present, the main methods for preventing and controlling mosquitoes are chemical control, biological control, environmental management, and comprehensive management combining these methods. Environmental management mainly plays a preventive role, and chemical control and biological control are the main means for controlling mosquitoes. Chemical control mainly has two forms, insecticides and repellents. Chemical mosquito repellents, such as mosquito incense and mosquito-killing aerosol, have irritability, and improper use can cause nervous system diseases, skin diseases, and even cancer with poor quality products, and also cause serious environmental pollution. Chemical repellent method is a technology that uses mosquito response to chemical signal substances to avoid them. Due to its high sensitivity and high selectivity, it has been widely used in chemical ecology.
[0004] Chinese patent CN103815761B discloses a preparation process of mosquito-repelling carpet, including color fixing, washing, vacuum water absorption, soaking, drying, inspection, packaging, and finished product. The composition of the mosquito repellent in the soaking solution includes 50% butyl diglycol, 10% chlorpyrifos, 20% aryl benzene polyoxydioxolane, and 20% water by volume fraction. By adding a mosquito repellent with a certain pH and a reinforcing agent Nano PU in the preparation process of the carpet, the mosquito repellent rate of the carpet is improved. However, the preparation process is complex, the cost is high, it is not suitable for use in cars, and the mosquito-repelling effect still needs to be further improved.
[0005] Therefore, it is of great significance to develop a mosquito-repelling carpet surface for mosquito-repelling automotive carpet with simple preparation process, low cost, and excellent mosquito-repelling effect, which is suitable for use in cars. SUMMARY
[0006] In view of the problems that the existing mosquito-repelling carpet surface has a relatively complex preparation process, high cost, is not suitable for use in a car, and the mosquito-repelling effect still needs to be further improved, the application provides a mosquito-repelling carpet surface for mosquito-repelling car carpets, which has a simple preparation process, low cost, is suitable for use in a car, and excellent mosquito-repelling effect.
[0007] To achieve the above object, the technical scheme adopted by the application is:
[0008] A mosquito-repelling carpet surface for mosquito-repelling car carpets comprises the following components in mass parts:
[0009] 900-1000 parts of silk material, 55-113 parts of mosquito-repelling master batch, and 29-53 parts of plant particles.
[0010] The plant particles are prepared by mixing the following raw materials in parts by weight: 10-20 parts of mint, 10-20 parts of tripartite bitter, 5-6 parts of agastache, 2-3 parts of camphor, 1-2 parts of mint, and 1-2 parts of mosquito-repelling grass.
[0011] Mint, a perennial herb of the order Magnoliophyta, the mint family, has a strong smell all over the plant, and is the most commonly used insect-repelling herb for books in ancient China. The earliest origin of "book fragrance" is mint. Tripartite bitter, a tree plant of the genus Melicope in the Rutaceae family, has roots, stems, branches, and leaves that can be used as medicine, has a bitter taste, and has a mosquito-repelling effect, and is a mosquito-repelling plant often used by ethnic minorities in Xishuangbanna. Agastache is the aboveground parts of the herbaceous plant Agastache rugosa or Agastache foeniculum, has a fragrant aroma, can help the central state clear gas, and has the effects of driving insects, eliminating dampness and waking up the spleen, dispelling impurities, and harmonizing the center. Camphor is a granular material prepared by distillation and refining of the roots, stems, branches, and leaves of the Cinnamomum camphora plant, has the effects of unblocking the nasal passages, promoting stagnation, dispelling impurities, killing insects, relieving itching, reducing swelling, and relieving pain. Mint, a member of the Lamiaceae family, has a special fragrant aroma, and mosquitoes will be dizzy when they smell it, has the effects of cooling, anti-inflammatory, and relieving itching. Mosquito-repelling grass generally refers to the fragrant leaf geranium, has volatile fragrance, and can extract geranium oil, the main components of which are geraniol, rose alcohol, citronellol, and linalool, and has a mosquito-repelling effect.
[0012] By compounding a plurality of plants with potential high mosquito-repelling effects in a certain proportion, a natural plant source repellent with no harm to human health, no pollution to the environment, and high mosquito-repelling activity can be obtained.
[0013] Further, the silk material is polyester and / or nylon.
[0014] Further, the mosquito-repelling master batch comprises the following components in mass parts:
[0015] 15-18 parts of butyl acetyl amino propionic acid ethyl ester, 30-75 parts of polycyclic aromatic ester, 5-10 parts of lubricant, and 5-10 parts of dispersant.
[0016] Ethyl butylacetylaminopropionate (also known as DEET, N, N-diethyl-m-toluamide), chemical formula is C 11 H 21 NO3, is a derivative of beta-alanine, can be used to drive mosquitoes, biodegradation is more thorough, the harm to the human body and the environment is small, safe and harmless, in the WHO and CDC recommended mosquito repellent, DEET is the only one that can be used for infants, pregnant women and lactating women. Polycyclic aromatic ester has the effects of sterilization and oxidation resistance, can interfere with the sensory system of mosquitoes through the odor volatilized, and auxiliary enhance the mosquito repellent effect of the product. The lubricant can well improve the dispersibility of other components in the system, improve the extrusion fluidity, appropriately increase the yield, and the particle surface made has good gloss, uniform color, good dispersibility, no crystal point, no broken silk, and no net blockage. The dispersant makes the mosquito repellent powder stably and uniformly distributed, improves the quality and stability of the master batch.
[0017] The above several components coordinate to better play the mosquito repellent effect of the application, so that the mosquito repellent master batch can provide better mosquito repellent effect.
[0018] Further, the plant particles are prepared by the following method:
[0019] D1. Each component is weighed according to mass parts;
[0020] D2. The patchouli, tripartite bitter, agastache, camphor, mint and mosquito repellent grass are respectively crushed, passed through a 100-200 mesh sieve, and uniformly mixed to obtain the particles.
[0021] Another object of the application is to provide a preparation method of the mosquito repellent carpet surface for mosquito repellent automobile carpet.
[0022] A preparation method of the mosquito repellent carpet surface for mosquito repellent automobile carpet according to any one of the preceding description, characterized in that it comprises the following steps:
[0023] S1. Each component is weighed according to mass parts;
[0024] S2. The silk material, mosquito repellent master batch and plant particles are mixed, melt conveying, spinning, air cooling, oiling, stretching, and winding to form, to obtain the mosquito repellent carpet surface for mosquito repellent automobile carpet.
[0025] Further, the melt conveying temperature is 265-275℃.
[0026] Further, the air cooling side blowing temperature is 23℃, the wind speed is 1.2m / min, and the humidity is 60-70%.
[0027] Further, the stretching speed of the draw texturing machine is controlled at 1900m / min, and the stretching temperature is 80-90℃.
[0028] Further, the winding forming winding machine speed control is 1800-2000 m / min.
[0029] Another object of the present application is to provide the use of the mosquito-repelling carpet surface for the mosquito-repelling automobile carpet.
[0030] A mosquito-repelling automobile carpet using the mosquito-repelling carpet surface according to any one of the above, comprising a carpet body comprising, from top to bottom, (1) a mosquito-repelling carpet surface for the mosquito-repelling automobile carpet, (2) an SBR layer, (3) a PU sponge layer, (4) an XPE foaming layer, and (5) a silica gel anti-skid bottom.
[0031] Compared with the prior art, the present application has the following advantages and beneficial effects:
[0032] (1) The plant particles in the mosquito-repelling carpet surface component of the present application are natural repellents from plants. Through the synergistic effect of various plant sources such as patchouli, tripartite bitter, agastache, camphor, mint, and mosquito-repelling grass in a certain proportion, the repellent effect of the plant particles is enhanced, achieving a natural, environmentally friendly, and efficient mosquito-repelling effect without affecting human health or causing environmental pollution. The silk material and mosquito-repelling master batch in the component of the present application are mixed, the mosquito-repelling master batch with complete biodegradation and little toxicity to the human body and the environment further enhances the mosquito-repelling effect, and the silk material improves the stability of the system. In addition to improving the mechanical properties such as toughness and impact resistance of the mosquito-repelling carpet surface for the mosquito-repelling automobile carpet, the present application achieves a comprehensive, long-lasting, and efficient mosquito-repelling effect.
[0033] (2) The mosquito-repelling carpet surface of the present application is obtained by sequentially bonding the mosquito-repelling carpet surface, the SBR layer, the PU sponge layer, the XPE foaming layer, and the silica gel anti-skid bottom to obtain the mosquito-repelling automobile carpet. Not only does it have excellent mosquito-repelling and insect-repelling effects, but the SBR layer and the PU sponge layer also ensure that the mosquito-repelling automobile carpet has good physical strength and elasticity. The XPE foaming layer with a high foaming rate of up to 15 times has good water resistance, which can prevent water from falling into the original car carpet from the carpet surface. The silica gel anti-skid bottom layer at the bottom can provide good anti-skid performance and prevent the carpet from shifting after installation. The mosquito-repelling automobile carpet obtained by the present application has good mechanical properties and excellent mosquito-repelling effects, and is suitable for use as an automobile interior carpet.
[0034] (3) The mosquito-repelling carpet surface for the mosquito-repelling automobile carpet of the present application has a short preparation process, high efficiency, low investment, simple equipment, and simple process, and can be used for large-scale production. BRIEF DESCRIPTION OF DRAWINGS
[0035] The application is further described with reference to the drawings, but the embodiments in the drawings do not constitute any limitation to the application, and other embodiments can be obtained by those skilled in the art without creative effort on the basis of the following drawings.
[0036] Figure 1 is a sectional view of the mosquito-repelling automobile carpet in the application, which includes (1) a mosquito-repelling carpet surface for the mosquito-repelling automobile carpet, (2) an SBR layer, (3) a PU sponge layer, (4) an XPE foaming layer, and (5) a silica gel anti-skid bottom. DETAILED DESCRIPTION
[0037] For better illustrating the purpose, technical scheme and advantages of the application, the application is further illustrated by the following examples. Obviously, the following examples are only a part of the examples of the application, but not all the examples; it should be understood that the examples of the application are only used for illustrating the technical effects of the application, but not used for limiting the protection scope of the application.
[0038] The raw materials in the examples can be obtained by market purchase; unless specifically stated, the reagents, methods and equipment used in the application are the conventional reagents, methods and equipment in the technical field.
[0039] Example 1
[0040] A preparation method of a mosquito-repelling carpet surface for a mosquito-repelling automobile carpet, comprising the following steps:
[0041] Preparation of plant particles, comprising the following steps:
[0042] D1. Each component is weighed according to the mass fraction;
[0043] D2. The patchouli 15 parts, the triplinervis 15 parts, the agastache 5 parts, the camphor 2 parts, the mint 2 parts and the mosquito-repelling grass 2 parts are respectively crushed and passed through a 200-mesh sieve, and then uniformly mixed to obtain the particles.
[0044] S1. Each component is weighed according to the mass fraction;
[0045] S2. The polyester 1000 parts, the mosquito-repelling master batch 60 parts (butyl acetyl amino propionate ethyl ester 15 parts, polycyclic aromatic ester 35 parts, lubricant 5 parts, dispersant 5 parts) and the plant particles 39 parts are mixed, melt conveying at 270℃, spinning, blowing cooling, side blowing temperature is 23℃, wind speed is 1.2m / min, humidity is 63%, oiling on the cluster, stretching at 1900m / min and 80℃, and winding at 2000m / min to form, to obtain the mosquito-repelling carpet surface for the mosquito-repelling automobile carpet.
[0046] The mosquito-repelling carpet surface for the mosquito-repelling automobile carpet is sequentially bonded with the SBR layer, the PU sponge layer, the XPE foaming layer and the silica gel anti-skid bottom to obtain the mosquito-repelling automobile carpet.
[0047] Embodiment 2
[0048] A preparation method of the mosquito-repelling carpet surface for mosquito-repelling automobile carpet, comprising the following steps:
[0049] Preparation of plant granules, comprising the following steps:
[0050] D1. Each component is weighed according to mass parts;
[0051] D2. The patchouli 10 parts, the tripartite bitter 11 parts, the agastache 5 parts, the camphor 2 parts, the mint 1 part, and the mosquito-repelling grass 1 part are respectively crushed and passed through a 100-mesh sieve, and then uniformly mixed to obtain the granules.
[0052] S1. Each component is weighed according to mass parts;
[0053] S2. The nylon 963 parts, the mosquito-repelling master granules 98 parts (butyl acetyl amino propionic acid ethyl ester 18 parts, polycyclic aromatic ester 65 parts, lubricant 8 parts, dispersant 7 parts), and the plant granules 30 parts are mixed, melt conveying at 270°C, spinning, blowing cooling, side blowing temperature is 23°C, wind speed is 1.2 m / min, humidity is 70%, oiling on the bundle, stretching at 1900 m / min and 85°C, and winding at 2000 m / min to form, to obtain the mosquito-repelling carpet surface for mosquito-repelling automobile carpet.
[0054] The mosquito-repelling carpet surface for mosquito-repelling automobile carpet is sequentially bonded with an SBR layer, a PU sponge layer, an XPE foaming layer, and a silica gel anti-skid bottom to obtain the mosquito-repelling automobile carpet.
[0055] Embodiment 3
[0056] A preparation method of the mosquito-repelling carpet surface for mosquito-repelling automobile carpet, comprising the following steps:
[0057] Preparation of plant granules, comprising the following steps:
[0058] D1. Each component is weighed according to mass parts;
[0059] D2. The patchouli 19 parts, the tripartite bitter 18 parts, the agastache 6 parts, the camphor 3 parts, the mint 2 parts, and the mosquito-repelling grass 2 parts are respectively crushed and passed through a 100-mesh sieve, and then uniformly mixed to obtain the granules.
[0060] S1. Each component is weighed according to mass parts;
[0061] S2. 1000 parts of polyester, 70 parts of mosquito repellent master batch (15 parts of butyl acetyl amino propionic acid ethyl ester, 50 parts of polycyclic aromatic ester, 5 parts of lubricant, 5 parts of dispersant), 50 parts of plant particles are mixed, melt conveying at 270°C, spinning, air cooling, side blowing temperature is 23°C, wind speed is 1.2 m / min, humidity is 60%, oiling on the bundle, stretching at 1900 m / min and 85°C, winding at 1900 m / min to form, thus the mosquito repellent carpet surface for mosquito repellent automobile carpet is obtained.
[0062] The mosquito repellent carpet surface is sequentially bonded with an SBR layer, a PU sponge layer, an XPE foaming layer and a silica gel anti-skid bottom to obtain the mosquito repellent automobile carpet.
[0063] Comparative Example 1
[0064] A preparation method of a mosquito repellent carpet surface comprises the following steps:
[0065] S1. Each component is weighed according to mass parts;
[0066] S2. 1000 parts of polyester, 60 parts of mosquito repellent master batch (15 parts of butyl acetyl amino propionic acid ethyl ester, 35 parts of polycyclic aromatic ester, 5 parts of lubricant, 5 parts of dispersant) are mixed, melt conveying at 270°C, spinning, air cooling, side blowing temperature is 23°C, wind speed is 1.2 m / min, humidity is 63%, oiling on the bundle, stretching at 1900 m / min and 80°C, winding at 2000 m / min to form, thus the mosquito repellent carpet surface is obtained.
[0067] The mosquito repellent carpet surface is sequentially bonded with an SBR layer, a PU sponge layer, an XPE foaming layer and a silica gel anti-skid bottom to obtain the mosquito repellent automobile carpet.
[0068] Compared with Example 1, the plant particles are not added in the comparative example.
[0069] Comparative Example 2
[0070] A preparation method of a mosquito repellent carpet surface comprises the following steps:
[0071] Preparation of plant particles comprises the following steps:
[0072] D1. Each component is weighed according to mass parts;
[0073] D2. 15 parts of Coleus amboinicus, 15 parts of Triadica cochinchinensis, 5 parts of Agastache rugosa, 2 parts of camphor, 2 parts of mint and 2 parts of mosquito repellent grass are respectively crushed and passed through a 200-mesh sieve, and then mixed uniformly, thus the particles are obtained.
[0074] S1. Each component is weighed according to mass parts;
[0075] S2. Take 1000 parts of polyester, 39 parts of plant particles, mix, melt delivery at 270°C, spinning, air cooling, side blowing temperature is 23°C, wind speed is 1.2 m / min, humidity is 63%, oiling, 1900 m / min, 80°C stretching, 2000 m / min winding forming, the mosquito-repellent carpet surface is obtained.
[0076] The mosquito-repellent carpet surface is sequentially bonded with the SBR layer, the PU sponge layer, the XPE foaming layer, and the silica gel anti-skid bottom to obtain the mosquito-repellent automobile carpet.
[0077] Compared with Example 1, the comparative example does not add the mosquito-repellent master batch.
[0078] Comparative Example 3
[0079] A preparation method of a mosquito-repellent carpet surface, comprising the following steps:
[0080] Preparation of plant particles, comprising the following steps:
[0081] D1. According to the mass parts, the components are weighed;
[0082] D2. Take 30 parts of mint, 5 parts of agastache, 2 parts of camphor, 2 parts of peppermint, and 2 parts of mosquito-repellent grass, respectively, crush, pass through a 200-mesh sieve, and mix evenly to obtain the particles.
[0083] S1. According to the mass parts, the components are weighed;
[0084] S2. Take 1000 parts of polyester, 60 parts of mosquito-repellent master batch (15 parts of butyl acetyl amino propionate, 35 parts of polycyclic aromatic ester, 5 parts of lubricant, and 5 parts of dispersant), and 39 parts of plant particles, mix, melt delivery at 270°C, spinning, air cooling, side blowing temperature is 23°C, wind speed is 1.2 m / min, humidity is 63%, oiling, 1900 m / min, 80°C stretching, 2000 m / min winding forming, the mosquito-repellent carpet surface is obtained.
[0085] The mosquito-repellent carpet surface is sequentially bonded with the SBR layer, the PU sponge layer, the XPE foaming layer, and the silica gel anti-skid bottom to obtain the mosquito-repellent automobile carpet.
[0086] Compared with Example 1, the comparative example does not add the three components of picrotoxin, and the missing part is supplemented by mint.
[0087] Comparative Example 4
[0088] A preparation method of a mosquito-repellent carpet surface, comprising the following steps:
[0089] Preparation of plant particles, comprising the following steps:
[0090] D1. According to the mass parts, the components are weighed;
[0091] D2. Crushed mint 15 parts, tripetide 15 parts, agastache 5 parts, camphor 2 parts, mint 2 parts, and mosquito repellent grass 2 parts are mixed evenly through a 200-mesh sieve to obtain the granules.
[0092] S1. Each component is weighed according to the quality parts;
[0093] S2. The polyester 1000 parts, mosquito repellent master batch 60 parts (butyl acetyl amino propionic acid ethyl ester 15 parts, polycyclic aromatic ester 35 parts, lubricant 5 parts, dispersant 5 parts), and plant granules 39 parts are mixed, melt conveyed at 270°C, spun, air-cooled, side air temperature is 23°C, air speed is 1.2 m / min, humidity is 63%, bundled and oiled, stretched at 1900 m / min and 80°C, and wound at 2000 m / min to form the mosquito repellent carpet surface.
[0094] The mosquito repellent carpet surface is sequentially bonded with the SBR layer, PU sponge layer, XPE foaming layer, and silica gel anti-skid bottom to obtain the mosquito repellent automobile carpet.
[0095] Compared with Example 1, the plant granules of the present comparative example do not add the mint component, and the missing part is supplemented by tripetide.
[0096] Comparative Example 5
[0097] A preparation method of a mosquito repellent carpet surface, comprising the following steps:
[0098] Preparation of plant granules, comprising the following steps:
[0099] D1. Each component is weighed according to the quality parts;
[0100] D2. Crushed mint 15 parts, tripetide 15 parts, agastache 5 parts, camphor 2 parts, mint 2 parts, and mosquito repellent grass 2 parts are mixed evenly through a 200-mesh sieve to obtain the granules.
[0101] S1. Each component is weighed according to the quality parts;
[0102] S2. The polyester 1000 parts, mosquito repellent master batch 60 parts (butyl acetyl amino propionic acid ethyl ester 15 parts, polycyclic aromatic ester 35 parts, lubricant 5 parts, dispersant 5 parts), and plant granules 39 parts are mixed, melt conveyed at 270°C, spun, air-cooled, side air temperature is 23°C, air speed is 1.2 m / min, humidity is 63%, bundled and oiled, stretched at 1900 m / min and 80°C, and wound at 2000 m / min to form the mosquito repellent carpet surface.
[0103] The mosquito repellent carpet surface is sequentially bonded with the SBR layer, PU sponge layer, XPE foaming layer, and silica gel anti-skid bottom to obtain the mosquito repellent automobile carpet.
[0104] Compared with Example 1, the mosquito repellent master batch component of the present comparative example is insufficient.
[0105] Comparative Example 6
[0106] A commercially available mosquito-repelling car mat for repelling mosquitoes.
[0107] The weight parts of the partial components of Examples 1-3 and Comparative Examples 1-5 are shown in Table 1 below.
[0108] Table 1 Weight parts of components of Examples 1-3 and Comparative Examples 1-5
[0109] Silk material Mosquito repellent master batch Peppermint Quassia Agastache Camphor Mint Mosquito repellent grass Example 1 1000 60 15 15 5 2 2 2 Example 2 963 98 10 11 5 2 1 1 Example 3 1000 70 19 18 6 3 2 2 Comparative Example 1 1000 60 — — — — — — Comparative Example 2 1000 — 15 15 5 2 2 2 Comparative Example 3 1000 60 30 — 5 2 2 2 Comparative Example 4 1000 60 — 30 5 2 2 2 Comparative Example 5 1000 50 15 15 5 2 2 2
[0110] The above samples were subjected to performance testing, and the specific testing process was as follows:
[0111] In 9 two-square-meter experimental spaces, the mosquito-repelling car carpets prepared from Examples 1-3 and Comparative Examples 1-6 were laid, and a blank control was set, and they were respectively placed in a laboratory without external mosquito interference. A temperature controller was used to control the temperature to 25℃ and the relative humidity to 45%, and 100 mosquitoes were respectively released for classification testing, and counting was performed once at 1h, 4h, 12h, 24h and 48h.
[0112] Repelling rate = (number of mosquitoes released - number of mosquitoes remaining) / number of mosquitoes released x 100%
[0113] The specific test results of Examples 1-3 and Comparative Examples 1-6 are shown in Table 2 below.
[0114] Table 2 Test results of Examples 1-3 and Comparative Examples 1-6
[0115]
[0116]
[0117] As can be seen from Table 2, the mosquito-repelling car carpet with a mosquito-repelling carpet surface prepared from the silk thread material, the mosquito-repelling master batch and the plant particles, wherein the plant particles include a specific ratio of lemon balm, triadica cochinchinensis, agastache, camphor, mint and mosquito-repelling grass, has excellent mosquito-repelling performance. The mosquito-repelling car carpet of Example 1-3 has a repelling rate of more than 80% at 1h, a repelling rate of 100% at 12h, and a repelling rate of 100% at 24h, and still maintains excellent mosquito-repelling effect after 48h.
[0118] The mosquito-repelling automobile carpet of the comparative example 1 has no plant particle component added to the carpet surface, and the mosquito-repelling effect is poor, and the avoidance rate is still less than 75% after 48 hours; the mosquito-repelling automobile carpet of the comparative example 2 has no mosquito-repelling master particle component added to the carpet surface, so that the persistence of the mosquito-repelling effect is greatly reduced, and the avoidance rate rises again after 48 hours; the comparative examples 3 and 4 change the proportion of the plant particle component, and the mosquito-repelling effect is better than that of the comparative examples 1 and 2, but the avoidance rate is still less than 90% within 48 hours compared with the examples, and the mosquito-repelling effect is not satisfactory; the mosquito-repelling master particle component of the comparative example 5 is lower than the specific range, although the initial 1h avoidance rate is higher in the comparative examples, the mosquito-repelling effect lasts for a short time, and the avoidance rate rises again as in the comparative example 2. The commercially available comparative example 6 has poor mosquito-repelling effect, and the avoidance rate is still less than 85% at 24h, and the avoidance rate rises again at 48h, and the rising amplitude is large, which indicates that the mosquito-repelling effect is unstable, and the mosquito-repelling duration is short.
[0119] In summary, the mosquito-repelling automobile carpet of the comparative example 1 has no plant particle component added to the carpet surface, and the mosquito-repelling effect is poor, and the avoidance rate is still less than 75% after 48 hours; the mosquito-repelling automobile carpet of the comparative example 2 has no mosquito-repelling master particle component added to the carpet surface, so that the persistence of the mosquito-repelling effect is greatly reduced, and the avoidance rate rises again after 48 hours; the comparative examples 3 and 4 change the proportion of the plant particle component, and the mosquito-repelling effect is better than that of the comparative examples 1 and 2, but the avoidance rate is still less than 90% within 48 hours compared with the examples, and the mosquito-repelling effect is not satisfactory; the mosquito-repelling master particle component of the comparative example 5 is lower than the specific range, although the initial 1h avoidance rate is higher in the comparative examples, the mosquito-repelling effect lasts for a short time, and the avoidance rate rises again as in the comparative example 2. The commercially available comparative example 6 has poor mosquito-repelling effect, and the avoidance rate is still less than 85% at 24h, and the avoidance rate rises again at 48h, and the rising amplitude is large, which indicates that the mosquito-repelling effect is unstable, and the mosquito-repelling duration is short.
[0120] The mosquito-repelling automobile carpet of the comparative example 1 has no plant particle component added to the carpet surface, and the mosquito-repelling effect is poor, and the avoidance rate is still less than 75% after 48 hours; the mosquito-repelling automobile carpet of the comparative example 2 has no mosquito-repelling master particle component added to the carpet surface, so that the persistence of the mosquito-repelling effect is greatly reduced, and the avoidance rate rises again after 48 hours; the comparative examples 3 and 4 change the proportion of the plant particle component, and the mosquito-repelling effect is better than that of the comparative examples 1 and 2, but the avoidance rate is still less than 90% within 48 hours compared with the examples, and the mosquito-repelling effect is not satisfactory; the mosquito-repelling master particle component of the comparative example 5 is lower than the specific range, although the initial 1h avoidance rate is higher in the comparative examples, the mosquito-repelling effect lasts for a short time, and the avoidance rate rises again as in the comparative example 2. The commercially available comparative example 6 has poor mosquito-repelling effect, and the avoidance rate is still less than 85% at 24h, and the avoidance rate rises again at 48h, and the rising amplitude is large, which indicates that the mosquito-repelling effect is unstable, and the mosquito-repelling duration is short.
[0121] It should be pointed out finally that the above embodiments are only used to illustrate the technical solutions of the present application, and are not intended to limit the protection scope of the present application. Although the present application has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solutions of the present application can be modified or equivalently replaced without departing from the essence and scope of the technical solutions of the present application.
Claims
1. A mosquito repellent carpet face for mosquito repellent automotive carpets, characterized in that, The mosquito-repelling carpet surface for mosquito-repelling automobile carpet comprises the following components by mass fraction: 900-1000 parts of silk material, 55-113 parts of mosquito-repelling master batch, and 29-53 parts of plant granules; The plant granules are prepared by mixing the following raw materials by weight fraction: 10-20 parts of mint, 10-20 parts of tripartite bitter, 5-6 parts of agastache, 2-3 parts of camphor, 1-2 parts of peppermint, and 1-2 parts of mosquito-repelling grass. The mosquito-repelling master batch comprises the following components by mass fraction: 15-18 parts of ethyl butylacetylaminopropionate, 30-75 parts of polycyclic aromatic ester, 5-10 parts of lubricant, and 5-10 parts of dispersant.
2. The insect repellent carpet face for insect repellent automotive carpet of claim 1, wherein: The silk material is polyester and / or nylon.
3. The insect repellent carpet face for insect repellent automotive carpet of claim 1 wherein: The plant granules are prepared by the following method: D1. Each component is weighed according to mass fraction; D2. The mint, tripartite bitter, agastache, camphor, peppermint, and mosquito-repelling grass are respectively crushed, passed through a 100-200 mesh sieve, and mixed evenly to obtain the granules.
4. A process for the production of a mosquito repellent carpet face for mosquito repellent automotive carpets according to any one of claims 1 to 3, characterized in that The method comprises the following steps: S1. Each component is weighed according to mass fraction; S2. The silk material, mosquito-repelling master batch, and plant granules are mixed, melt conveyed, spun, air-cooled, bundled, oiled, stretched, and wound to form the mosquito-repelling carpet surface for mosquito-repelling automobile carpet.
5. The method for preparing the mosquito-repellent carpet surface for car carpets as described in claim 4, characterized in that: The melt conveying temperature is 265-275℃.
6. The method for preparing the mosquito-repellent carpet surface for car carpets as described in claim 4, characterized in that: The air-cooling side air-blowing temperature is 23℃, the air speed is 1.2 m / min, and the humidity is 60-70%.
7. The method for preparing the mosquito-repellent carpet surface for car carpets as described in claim 4, characterized in that: The stretching speed of the stretching deformation machine is controlled at 1900 m / min, and the stretching temperature is 80-90℃.
8. The process for preparing the mosquito repellent carpet face for mosquito repellent automobile carpet according to claim 4, characterized by: The winding speed of the winding machine is controlled at 1800-2000 m / min.
9. An anti-mosquito automobile carpet using the anti-mosquito carpet surface of claim any one of claims 1 to 3, characterized by, The mosquito-repelling carpet surface for mosquito-repelling automobile carpet comprises a carpet body, wherein the carpet body comprises, from top to bottom, (1) the mosquito-repelling carpet surface for mosquito-repelling automobile carpet, (2) an SBR layer, (3) a PU sponge layer, (4) an XPE foaming layer, and (5) a silica gel anti-skid bottom.
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