一种除氟萃取剂以及从酸性硫酸盐溶液中深度除氟的方法

By using a defluorination extractant containing cation exchange groups and neutral molecular complexing groups, combined with a modifier and a diluent, deep defluorination in acidic sulfate solutions was achieved, solving the problems of incomplete defluorination and impurity contamination in existing technologies, and achieving a low-cost and high-efficiency defluorination effect.

CN117867277BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2022-10-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for achieving deep defluorination of acidic sulfate solutions in non-ferrous metal hydrometallurgy, and existing methods suffer from problems such as impurity contamination, high cost, and incomplete defluorination.

Method used

A defluorinating extractant containing cation exchange groups and neutral molecular complexing groups is used in combination with a modifier and a diluent to deeply remove fluoride from acidic sulfate solutions through single-stage or multi-stage countercurrent extraction and back-extraction.

Benefits of technology

This method reduces the fluoride content in the solution to 1-15 ppm, reduces wastewater generation, and allows the extractant to be regenerated, thus avoiding problems such as impurity pollution and excessive costs.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开一种除氟萃取剂以及从酸性硫酸盐溶液中深度除氟的方法,其向除氟萃取剂中添加改质剂和稀释剂组成有机相;用有机相与酸性含氟硫酸盐溶液进行单级或多级逆流萃取,得到负载氟的有机相和除氟后的萃余液;其中,所述除氟萃取剂包含阳离子交换基团,以及中性分子络合基团。本发明提出的方法可以达到深度除氟的目的。
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