Oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrate and preparation method and application thereof

Abstract

The application discloses an oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 and a preparation method and application thereof. The oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 is composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate. The oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 is a dispersant composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate. The dispersant has low surface energy. After being added into ore slurry, the dispersant can disperse the mineral processing reagent on the surface of minerals. The mineral processing reagent migrates to the surface of the dispersant, changes the stable state of the mineral processing reagent, reduces the adhesion of the mineral processing reagent, and further makes the mineral processing reagent more easily dispersed from the surface of the minerals.

Description

TECHNICAL FIELD

[0001] The application belongs to the technical field of metallurgical chemical industry, and particularly relates to a kind of oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000 and its preparation method and application. BACKGROUND

[0002] Lanping lead-zinc mine has the single largest in the domestic first, the world's fifth largest lead-zinc mine resources, after years of 'rich and poor', the mine area of 4000 tons of low-grade oxygen sulfur mixed lead-zinc ore (grade Zn6.5%, Pb1.58%, zinc metal amount 213.56 million tons, lead metal amount 49.20 million tons), accounting for one-third of the current geological reserves, potential economic value of more than 30 billion yuan. The mine is difficult to handle, low grade, has not been effectively developed.

[0003] On the basis of years of research, the low-grade oxygen sulfur mixed stockpiled ore has good economic efficiency and process stability by mixed flotation to obtain oxygen sulfur mixed concentrate. The smelting application of the mixed concentrate has two key technical difficulties: (1) it is difficult to enter the existing smelting process due to oxygen sulfur mixing; (2) after mixed flotation, the oxidized ore is wrapped with sulfur by reagent, and the existing beneficiation technology is difficult to separate oxygen and sulfur. Therefore, it is necessary to develop a product that can solve the above technical problems. SUMMARY

[0004] The first purpose of the present application is to provide a kind of oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000;Second purpose is to provide the preparation method of the oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000;The third purpose is to provide the application of the oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000.

[0005] The first purpose of the present application is achieved, and the oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000 is composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate.

[0006] The second purpose of the present application is achieved, which comprises the following steps:

[0007] 1) uniformly mix the glycerol trioleate and glycerol monostearate of formula ratio to obtain solution a;

[0008] 2) uniformly mix the trimethylolpropane trioleate and sorbitan monostearate of formula ratio to obtain solution b;

[0009] 3) add solution a to solution b to obtain the target oxygen sulfur mixed zinc concentrate oxygen sulfur separation agent JH-3000.

[0010] The mixed concentrate surface will generate a large amount of foam during acid leaching due to a large amount of beneficiation reagents, and in severe cases, the tank will be overflowed. In order to solve this problem, JH-3000 is added to the mixed concentrate slurry, which is a dispersant that can disperse the beneficiation reagents on the surface of the mixed concentrate, so that the hydrophilic oxidized ore and the hydrophobic sulfide ore can be separated.

[0011] The oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrate provided by the present application is a dispersant composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate. DETAILED DESCRIPTION

[0012] The present application will be further described below in conjunction with examples, but in no way limits the present application, any transformation or replacement based on the teaching of the present application belongs to the protection scope of the present application.

[0013] The oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrate provided by the present application is composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate.

[0014] The mass ratio of the glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate is (3-6):(1-4):(2-5):(1-3).

[0015] The preparation method of the oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrate provided by the present application comprises the following steps:

[0016] 1) uniformly mix the formula-proportioned glycerol trioleate and glycerol monostearate to obtain solution a;

[0017] 2) uniformly mix the formula-proportioned trimethylolpropane trioleate and sorbitan monostearate to obtain solution b;

[0018] 3) add solution a to solution b to obtain the target oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrate.

[0019] 1) the step is to sequentially add the formula-proportioned glycerol trioleate and glycerol monostearate to a container, and uniformly mix them under the condition of water bath temperature 70-90 DEG C and stirring, control the water bath temperature to be 70-90 DEG C for 20-40 min to obtain solution a.

[0020] 2) The step is to add the formula-proportioned trimethylolpropane trioleate into a container, and formula-proportioned sorbitan monostearate is added under the condition of stirring at a water bath temperature of 60-80℃, and after uniform stirring, the water bath temperature is controlled at 60-80℃ for 50-70min to obtain solution b.

[0021] 3) The step is to add solution a into solution b, and then hot water at a temperature of 60-80℃ is added, and a homogenizer is used to homogenize under high pressure to form a uniform solution to obtain the target object oxygen-sulfur separation agent JH-3000 of oxygen-sulfur mixed zinc concentrate.

[0022] The hot water is added in an equal volume to the total volume of solution a and solution b.

[0023] The high pressure is 60-70MPa.

[0024] The application of the oxygen-sulfur separation agent JH-3000 of oxygen-sulfur mixed zinc concentrate is the application of the oxygen-sulfur separation agent JH-3000 of oxygen-sulfur mixed zinc concentrate in the oxygen-sulfur separation process of oxygen-sulfur mixed zinc concentrate.

[0025] The application of the oxygen-sulfur separation agent JH-3000 of oxygen-sulfur mixed zinc concentrate is the application of the oxygen-sulfur separation agent JH-3000 of oxygen-sulfur mixed zinc concentrate in the oxygen-sulfur separation process of oxygen-sulfur mixed zinc concentrate.

[0026] Example 1

[0027] (1) 40g of glyceryl trioleate and 30g of glyceryl monostearate are sequentially added to a beaker, and the water bath temperature is raised to 70-90℃, first slowly stirred to mix uniformly, then the speed is increased to form a uniform solution, and after 30min of heat preservation, it is cooled to room temperature to obtain solution a;

[0028] (2) 35g of trimethylolpropane trioleate is added to a beaker, slowly stirred at 60-80℃ in a water bath, and then 20g of sorbitan monostearate is added, uniformly stirred at high speed, and after 60min of heat preservation, it is cooled to room temperature to obtain solution b;

[0029] (3) Solution a is slowly added to solution b, then hot water is added, and a high-pressure homogenizer is used to homogenize at 60-70MPa to form a uniform solution JH-3000.

[0030] Example 2

[0031] (1) 45g of glyceryl trioleate and 25g of glyceryl monostearate are sequentially added to a beaker, and the water bath temperature is raised to 70-90℃, first slowly stirred to mix uniformly, then the speed is increased to form a uniform solution, and after 30min of heat preservation, it is cooled to room temperature to obtain solution a;

[0032] (2) 30 g of trimethylolpropane trioleate was added into a beaker, slowly stirred at 60-80 °C in a water bath, then 22 g of sorbitan monostearate was added, stirred at high speed until uniform, and then cooled to room temperature after 60 min to obtain solution b;

[0033] (3) Solution a was slowly added to solution b, then hot water was added, and a high-pressure homogenizer was used to homogenize at 60-70 MPa to form a uniform solution JH-3000.

[0034] Example 3

[0035] (1) 30 g of glyceryl trioleate and 10 g of glyceryl monostearate were sequentially added into a beaker, the temperature was raised to 70-90 °C in a water bath, slowly stirred first until uniform, then the stirring speed was increased to form a uniform solution, and then cooled to room temperature after 30 min to obtain solution a;

[0036] (2) 20 g of trimethylolpropane trioleate was added into a beaker, slowly stirred at 60-80 °C in a water bath, then 10 g of sorbitan monostearate was added, stirred at high speed until uniform, and then cooled to room temperature after 60 min to obtain solution b;

[0037] (3) Solution a was slowly added to solution b, then hot water was added, and a high-pressure homogenizer was used to homogenize at 60-70 MPa to form a uniform solution JH-3000.

[0038] Example 4

[0039] (1) 60 g of glyceryl trioleate and 40 g of glyceryl monostearate were sequentially added into a beaker, the temperature was raised to 70-90 °C in a water bath, slowly stirred first until uniform, then the stirring speed was increased to form a uniform solution, and then cooled to room temperature after 30 min to obtain solution a;

[0040] (2) 50 g of trimethylolpropane trioleate was added into a beaker, slowly stirred at 60-80 °C in a water bath, then 30 g of sorbitan monostearate was added, stirred at high speed until uniform, and then cooled to room temperature after 60 min to obtain solution b;

[0041] (3) Solution a was slowly added to solution b, then hot water was added, and a high-pressure homogenizer was used to homogenize at 60-70 MPa to form a uniform solution JH-3000.

[0042] Example 5

[0043] (1) 40 g of glycerol trioleate, 20 g of glycerol monostearate were added into a beaker in turn, and the temperature of the water bath was raised to 70-90 °C. First, the solution was slowly stirred until it was mixed uniformly, and then the stirring speed was increased to form a uniform solution. After 30 min of incubation, the solution was cooled to room temperature to obtain solution a;

[0044] (2) 30 g of trimethylolpropane trioleate was added into a beaker, and slowly stirred at 60-80 °C in a water bath. Then, 20 g of sorbitan monostearate was added, and stirred uniformly at high speed. After 60 min of incubation, the solution was cooled to room temperature to obtain solution b;

[0045] (3) Solution a was slowly added to solution b, and then hot water was added. A high-pressure homogenizer was used to homogenize the solution to form a uniform solution JH-3000 at 60-70 MPa.

[0046] Example 6

[0047] (1) 50 g of glycerol trioleate, 30 g of glycerol monostearate were added into a beaker in turn, and the temperature of the water bath was raised to 70-90 °C. First, the solution was slowly stirred until it was mixed uniformly, and then the stirring speed was increased to form a uniform solution. After 30 min of incubation, the solution was cooled to room temperature to obtain solution a;

[0048] (2) 40 g of trimethylolpropane trioleate was added into a beaker, and slowly stirred at 60-80 °C in a water bath. Then, 25 g of sorbitan monostearate was added, and stirred uniformly at high speed. After 60 min of incubation, the solution was cooled to room temperature to obtain solution b;

[0049] (3) Solution a was slowly added to solution b, and then hot water was added. A high-pressure homogenizer was used to homogenize the solution to form a uniform solution JH-3000 at 60-70 MPa.

[0050] Example 7

[0051] (1) 45 g of glycerol trioleate, 25 g of glycerol monostearate were added into a beaker in turn, and the temperature of the water bath was raised to 70-90 °C. First, the solution was slowly stirred until it was mixed uniformly, and then the stirring speed was increased to form a uniform solution. After 30 min of incubation, the solution was cooled to room temperature to obtain solution a;

[0052] (2) 35 g of trimethylolpropane trioleate was added into a beaker, and slowly stirred at 60-80 °C in a water bath. Then, 23 g of sorbitan monostearate was added, and stirred uniformly at high speed. After 60 min of incubation, the solution was cooled to room temperature to obtain solution b;

[0053] (3) Solution a was slowly added to solution b, and then hot water was added. A high-pressure homogenizer was used to homogenize the solution to form a uniform solution JH-3000 at 60-70 MPa.

[0054] Example 8

[0055] The application test was carried out by using the oxygen-sulfur separation agent JH-3000 prepared in Example 3, and the specific operation was as follows:

[0056] (1) 1000g of the oxygen-sulfur mixed concentrate was taken, mixed uniformly with 2000g of water, and then ultrasonic dispersion was carried out, and air was introduced during the dispersion process, and the air flow was 50L / min; 5g of the oxygen-sulfur separation agent JH-3000 prepared in Example 3 was added, the reaction time was 20min, the reaction temperature was 25℃, the stirring speed was 500r / min, and the foam on the surface of the slurry was scraped out gradually during the reaction until no foam was generated;

[0057] (2) The scraped foam and the remaining slurry were respectively subjected to solid-liquid separation, and then zinc oxide product and zinc sulfide product were obtained; the above two products were sent for analysis, and the grade of the obtained zinc oxide product was 24.19% and the content of zinc sulfide was 0.63%, and the grade of the obtained zinc sulfide was 32.84% and the content of zinc oxide was 1.69%;

[0058] The above results show that the separation effect of the oxygen-sulfur separation agent JH-3000 prepared in Example 3 is good, and the technical difficulties existing in the smelting of the mixed concentrate in the prior art can be solved.

[0059] Example 9

[0060] The application test was carried out by using the oxygen-sulfur separation agent JH-3000 prepared in Example 1, Example 2, Example 4, Example 5, Example 6, and Example 7, and the method was the same as that in Example 8, and the results all showed that the separation effect of the oxygen-sulfur separation agent JH-3000 prepared in the application was good, and the technical difficulties existing in the smelting of the mixed concentrate in the prior art could be solved.

Claims

1. An oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrates, characterized by, The oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 is composed of glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate; The mass ratio of the glycerol trioleate, glycerol monostearate, trimethylolpropane trioleate and sorbitan monostearate in the oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 is (3-6):(1-4):(2-5):(1-3).

2. A method for preparing the oxygen-sulfur separation agent JH-3000 for oxygen-sulfur mixed zinc concentrates according to claim 1, characterized in that, The method comprises the following steps: 1) uniformly mixing the formula-proportioned glycerol trioleate and glycerol monostearate to obtain solution a; 2) uniformly mixing the formula-proportioned trimethylolpropane trioleate and sorbitan monostearate to obtain solution b; 3) homogenizing solution a into solution b to obtain the target object oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000.

3. The production method according to claim 2, characterized by, 1) The step is to sequentially add the formula-proportioned glycerol trioleate and glycerol monostearate into a container, and uniformly mix them under stirring at a water bath temperature of 70-90 DEG C, and then control the water bath temperature at 70-90 DEG C for 20-40 min to obtain solution a.

4. The preparation method according to claim 2, characterized in that, 2) The step is to add the formula-proportioned trimethylolpropane trioleate into a container, and then add the formula-proportioned sorbitan monostearate under stirring at a water bath temperature of 60-80 DEG C, and then uniformly mix them, and then control the water bath temperature at 60-80 DEG C for 50-70 min to obtain solution b.

5. The preparation method according to claim 2, characterized in that, 3) The step is to add solution a into solution b, and then add hot water at a temperature of 60-80 DEG C, and then use a homogenizer to homogenize the mixture under high pressure to form a uniform solution to obtain the target object oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000.

6. The production method according to claim 5, wherein The hot water is added in an amount equal to the total volume of solution a and solution b.

7. The preparation method according to claim 5, characterized in that, The high pressure is 60-70 MPa.

8. The use of the oxygen-sulfur separation agent JH-3000 for zinc concentrate of claim 1, characterized in that, The oxygen-sulfur mixed zinc concentrate oxygen-sulfur separation agent JH-3000 is used in the oxygen-sulfur separation process of oxygen-sulfur mixed zinc concentrate.