A flue gas carbon dioxide recovery and resource utilization device

Abstract

The invention relates to the technical field of flue gas treatment, and discloses a flue gas carbon dioxide recovery and resource utilization device, comprising two adsorption devices and a filtering device, wherein a solid amine particle module for adsorbing carbon dioxide in flue gas is placed in the adsorption device, the two adsorption devices are symmetrically arranged and fixedly connected to each other, and the two adsorption devices are communicated; heat exchange tubes are fixedly installed at both ends of the adsorption device, the heat exchange tubes are attached to the bottom of the adsorption device, the heat exchange tubes are in contact with the adsorption device and heat exchange occurs; by arranging the adsorption device, the heat exchange tubes and the filtering device, after the high-temperature flue gas is heated and filtered by the filtering device, the flue gas is transported to the adsorption device through the heat exchange tube, and the high-temperature flue gas in the heat exchange tube is heat-exchanged with the solid amine particle module inside the adsorption device, thereby achieving preheating treatment of the solid amine particle module, thereby achieving the effect of quickly using the solid amine particle module to adsorb carbon dioxide.

Description

Technical Field

[0001] The invention relates to the technical field of flue gas treatment, and in particular to a flue gas carbon dioxide recovery and resource utilization device. Background Art

[0002] Carbon dioxide is an important industrial gas. In addition to nitrogen, which has the highest content, the flue gas produced by combustion in industrial production also contains a relatively high concentration of carbon dioxide. Recycling carbon dioxide for reuse can further reduce carbon emissions and turn carbon dioxide into treasure, which has extremely high economic value.

[0003] Among the existing carbon dioxide adsorption methods, the most mature and low-cost method is the adsorption method. The main principle of the adsorption method is to use solid adsorbents to adsorb carbon dioxide in the mixed gas. This principle is to select adsorbents that have stronger adsorption force on the carbon dioxide component in the mixed gas than other components based on the spatial structure and molecular polarity of carbon dioxide molecules. Due to the difference in the attractive force between the molecules of each component in the mixed gas and the active points on the surface of the adsorbent, when the mixed gas passes through the adsorbent carried by the adsorption bed under a certain pressure, the adsorbent selectively absorbs carbon dioxide, thereby achieving the separation and recovery of carbon dioxide gas.

[0004] In the prior art, solid amine particles are often used to adsorb carbon dioxide in flue gas. However, the solid amine particles need to be preheated before adsorption, and the flue gas needs to be filtered before adsorption can be performed. Flue gas itself is a high-temperature gas, and there is no device in the prior art that directly utilizes the heat of high-temperature flue gas, which leads to energy waste. At the same time, in the prior art, the preheating and adsorption of solid amine particles cannot be adjusted each time, and need to be treated separately, resulting in low efficiency. Summary of the invention

[0005] 1. Technical issues to be resolved

[0006] In view of the deficiencies of the prior art, the present invention provides a flue gas carbon dioxide recovery and resource utilization device.

[0007] (II) Technical solution

[0008] To achieve the above-mentioned purpose, the present invention provides the following technical solutions: a flue gas carbon dioxide recovery and resource utilization device, comprising two adsorption devices and a filtering device, wherein a solid amine particle module for adsorbing carbon dioxide in flue gas is placed in the adsorption device, and the two adsorption devices are symmetrically arranged and fixedly connected to each other, and the two adsorption devices are communicated;

[0009] Wherein, heat exchange tubes are fixedly installed at both ends of the adsorption device, and the heat exchange tubes are attached to the bottom of the adsorption device, and the heat exchange tubes are in contact with the adsorption device to exchange heat;

[0010] The filtering device comprises a shell, and three through holes are opened on the circumference of the shell, one of the through holes is fixedly mounted with an air inlet pipe, and high-temperature flue gas is introduced through the air inlet pipe, and the other two through holes are fixedly connected with air delivery pipes;

[0011] Wherein, a driving mechanism is arranged between the adsorption device and the filtering device, and the driving mechanism drives the internal components of the adsorption device and the filtering device to operate;

[0012] Wherein, an exhaust pipe is fixedly connected to the gas delivery pipe, and the exhaust pipe is used to discharge the treated residual gas.

[0013] Preferably, the through holes are respectively located above and at the bottom of the shell, and the two through holes above are symmetrically arranged. A fourth rotating shaft is rotatably installed at the center of the filtering device, and a partition and two filter plates are fixedly installed on the fourth rotating shaft. The partition and the filter plate form an isosceles triangle at one end away from the fourth rotating shaft. The partition moves on both sides of the two through holes, the fourth rotating shaft extends out of the shell, and a connecting column is fixedly installed at the edge of the fourth rotating shaft.

[0014] Preferably, the driving mechanism comprises an action frame and a fixed plate, the second rotating shaft and the first rotating shaft are rotatably connected on the fixed plate, a disc is fixedly mounted on the first rotating shaft, the action frame is fixedly mounted on the second rotating shaft, a first action rod is fixedly mounted on the edge of the disc, the first rotating shaft and the first action rod are within the frame of the action frame, and the first action rod drives the action frame to rotate around the second rotating shaft;

[0015] Wherein, the upper and lower sections of the action frame are fixedly installed with connecting pieces, and the two connecting pieces are respectively connected to the connecting column and the heat exchange tube;

[0016] Wherein, the connecting piece is composed of a telescopic rod and a rotating shaft, and the rotating shaft is rotatably connected to the two ends of the connecting piece.

[0017] Preferably, the exhaust pipe is installed on the side of the gas supply pipe, a hinge is fixedly installed at the connection between the exhaust pipe and the gas supply pipe, a blocking plate is fixed on the hinge, and the blocking plate is rotated at the connection between the gas supply pipe and the exhaust pipe through the hinge;

[0018] The blocking plate is tiltedly installed in the air delivery pipe by the elastic force of the hinge, and the shape of the blocking plate is adapted to the exhaust pipe.

[0019] Preferably, the adsorption device comprises a pipe shell, two ends of the two pipe shells away from each other are each provided with two movable grooves, a movable groove is provided on the inner wall of the pipe shell between the two movable grooves, and an adsorption mechanism is movably engaged in the movable groove and the movable groove;

[0020] The adsorption mechanism moves between the two movable grooves and the movable groove, and the adsorption mechanism is preheated by heat conduction between the adsorption device and the heat exchange tube.

[0021] Preferably, a movable plate is slidably mounted on one end of the two pipe shells close to each other, a slide groove is provided at the bottom of the pipe shell, a clamping strip is slidably mounted in the two slide grooves, the clamping strip is connected to the connecting piece at the upper end of the action frame, and the clamping strip is movably connected to the action frame through the connecting piece;

[0022] The clamping strip is fixedly connected to the movable plate, and the rotation of the action frame drives the connecting piece to swing, thereby driving the clamping strip to slide in the locking block, and then causing the movable plate to reciprocate in the pipeline housing.

[0023] Preferably, the movable plate is movably connected with a second action rod, a spirally arranged engaging groove is provided on the circumferential surface of the second action rod, a engaging rod is fixedly installed on the side of the movable plate, the engaging rod is interactively engaged in the engaging groove, and through the engaging effect of the engaging rod and the engaging groove, as the movable plate reciprocates left and right, the second action rod operates in a rotation-movement-rotation manner with the movable plate;

[0024] Wherein, the second action rod is fixedly connected to the adsorption mechanism, and the second action rod drives the adsorption mechanism to operate in the pipeline shell.

[0025] Preferably, the adsorption mechanism includes a placement frame, and two engaging blocks are symmetrically installed on the outside of the placement frame, and the two engaging blocks are engaged in the movable groove or the movable groove, and move in the movable groove and rotate in the movable groove;

[0026] Wherein, a partition plate is fixedly installed at the center of the inner circle of the placement frame, and the partition plate is arranged corresponding to the locking block. The partition plate divides the inner circle of the placement frame into two parts, and a solid amine particle module is placed in each part.

[0027] Preferably, the dividing plate is rotatably connected to a third rotating shaft, and the third rotating shaft is rotatably connected to a baffle, and the baffle is a semicircular plate, and the baffle moves inside the pipeline shell as the placement frame moves, and shields the solid amine particle module located below the dividing plate.

[0028] (III) Beneficial effects

[0029] Compared with the prior art, the present invention provides a flue gas carbon dioxide recovery and resource utilization device, which has the following beneficial effects:

[0030] 1. The flue gas carbon dioxide recovery and resource utilization device is provided with an adsorption device, a heat exchange tube and a filter device. After the high-temperature flue gas passes through the filter device for heat filtration treatment, dust and particles in the flue gas are filtered out, and then the flue gas is transported to the adsorption device through the heat exchange tube. Since the heat exchange tube fits the bottom of the adsorption device, the high-temperature flue gas in the heat exchange tube exchanges heat with the solid amine particle module inside the adsorption device, thereby preheating the solid amine particle module, thereby achieving the effect of quickly using the solid amine particle module to adsorb carbon dioxide. At the same time, the preheating treatment of the high-temperature flue gas is utilized to achieve the effect of efficient utilization of resources.

[0031] 2. In the flue gas carbon dioxide recovery and resource utilization device, when the through hole at the bottom is connected with the through hole on the left, the high-temperature flue gas is transported upward from the gas pipe on the left, and is transported to the inside of the adsorption device from the heat exchange pipe on the left, and is adsorbed by the solid amine particle modules inside the two adsorption devices to achieve a better adsorption effect, and the high-temperature flue gas is transported from the air inlet pipe to the filter device, and is filtered by two partitions to achieve a better effect of filtering dust and particles in the flue gas. By setting the filtering device, the flue gas guiding and filtering effects are achieved.

[0032] 3. In the flue gas carbon dioxide recovery and resource utilization device, when the high-temperature flue gas is transported from the gas pipe on one side to the adsorption device, the airflow is from bottom to top, and the gas pipe on the other side is used to discharge the flue gas after adsorption, that is, to discharge the residual gas, and the airflow is from top to bottom. When the gas pipe transports the high-temperature flue gas, the airflow formed by the high-temperature flue gas acts on the baffle plate, pushing the baffle plate to seal the exhaust pipe, thereby completing the transportation of the high-temperature flue gas. When the gas pipe discharges the residual gas, the residual gas pushes the baffle plate to seal the gas pipe, and the residual gas is discharged from the exhaust pipe to achieve the effect of discharging the residual gas.

[0033] 4. The flue gas carbon dioxide recovery and resource utilization device ensures that the airflow can push the blocking plate to seal the exhaust pipe or the gas pipe through the design of the fourth rotating shaft, thereby achieving the effect of airflow guidance and better completing the effects of flue gas transportation and residual gas discharge.

[0034] 5. The flue gas carbon dioxide recovery and resource utilization device, the placement frame and the locking block drive the adsorption device to rotate, that is, the two solid amine particle modules are adjusted in the upper and lower positions. With the reciprocating movement of the movable plate, the placement frame operates in a rotating disk°-moving-rotating disk°-moving mode between the two movable grooves and the movable groove. When the placement frame of the solid amine particle module rotates, the solid amine particles located at the bottom exchange heat with the corresponding heat exchange tubes to achieve the preheating effect, and the solid amine particle module rotated to the top is directly passed by the flue gas to achieve the effect of adsorbing carbon dioxide.

[0035] 6. The flue gas carbon dioxide recovery and resource utilization device, when the high-temperature flue gas moves between the two adsorption devices, after two adsorptions and two heat exchanges, achieves the effect of absorbing the heat of the flue gas, reducing the heat in the flue gas, and achieving a better effect of exhausting the residual gas.

[0036] 7. In the flue gas carbon dioxide recovery and resource utilization device, the high-temperature flue gas enters the solid amine particle module in the second adsorption device for adsorption, and is also discharged through the heat exchange tube. The heat exchange tube exchanges heat with the solid amine particle module. When the filtering device is in operation, the conveying direction of the flue gas is reversed. At this time, the solid amine particle module in the second adsorption device achieves the effect of preheating before preheating due to the previous heat exchange, that is, the solid amine particle module undergoes two preheating treatments when it is in effect, achieving a better preheating treatment effect. BRIEF DESCRIPTION OF THE DRAWINGS

[0037] Figure 1 It is a schematic diagram of the overall structure of the present invention;

[0038] Figure 2 It is a schematic diagram of the structure of the driving mechanism of the present invention;

[0039] Figure 3 It is a schematic diagram of the structure of the adsorption device of the present invention;

[0040] Figure 4 This is a schematic diagram of the structure of the filter device of the present invention when transmitting gas on the left side;

[0041] Figure 5 This is a schematic diagram of the structure of the right side of the filter device of the present invention when transmitting gas;

[0042] Figure 6 This is a schematic diagram of the structure of the movable plate of the present invention;

[0043] Figure 7 It is a schematic diagram of the exhaust pipe structure of the present invention.

[0044] In the figure: 10, adsorption device; 11, heat exchange tube; 12, driving mechanism; 13, air delivery pipe; 14, exhaust pipe; 15, filter device; 16, air inlet pipe; 17, fixed plate; 18, disc; 19, first rotating shaft; 20, first action rod; 21, second rotating shaft; 22, action frame; 23, connecting piece; 24, pipeline shell; 25, engaging rod; 26, clamping strip; 27, movable plate; 28, second action rod; 29, engaging groove; 30, movable groove; 31, movable groove; 32, engaging block; 33, placement frame; 34, dividing plate; 35, third rotating shaft; 36, baffle; 37, shell; 38, filter plate; 39, through hole; 40, partition; 41, connecting column; 42, slide groove; 43, hinge; 44, blocking plate; 45, fourth rotating shaft. DETAILED DESCRIPTION

[0045] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0046] See also Figure 1-Figure 7 A flue gas carbon dioxide recovery and resource utilization device includes two adsorption devices 10 and a filtering device 15. A solid amine particle module for adsorbing carbon dioxide in flue gas is placed in the adsorption device 10. The two adsorption devices 10 are symmetrically arranged and fixedly connected to each other, and the two adsorption devices 10 are connected;

[0047] Wherein, heat exchange tubes 11 are fixedly installed at both ends of the adsorption device 10, and the heat exchange tubes 11 are attached to the bottom of the adsorption device 10, and the heat exchange tubes 11 are in contact with the adsorption device 10 and heat exchange occurs;

[0048] The filter device 15 includes a housing 37, and three through holes 39 are opened on the circumference of the housing 37. An air inlet pipe 16 is fixedly installed on one of the through holes 39, and high-temperature flue gas is introduced through the air inlet pipe 16. The other two through holes 39 are fixedly connected to the gas delivery pipe 13.

[0049] A driving mechanism 12 is provided between the adsorption device 10 and the filtering device 15, and the driving mechanism 12 drives the internal components of the adsorption device 10 and the filtering device 15 to operate;

[0050] The gas delivery pipe 13 is fixedly connected with an exhaust pipe 14, and the exhaust pipe 14 is used to discharge the treated residual gas.

[0051] By setting up the adsorption device 10, the heat exchange tube 11 and the filter device 15, the high-temperature flue gas is heated and filtered by the filter device 15 to filter out dust and particles in the flue gas, and then the flue gas is transported to the adsorption device 10 through the heat exchange tube 11. Since the heat exchange tube 11 is in contact with the bottom of the adsorption device 10, the high-temperature flue gas in the heat exchange tube 11 exchanges heat with the solid amine particle module inside the adsorption device 10, thereby preheating the solid amine particle module, thereby achieving the effect of quickly using the solid amine particle module to adsorb carbon dioxide, and at the same time utilizing the preheating treatment of the high-temperature flue gas to achieve the effect of efficient utilization of resources.

[0052] The through holes 39 are respectively located above the shell 37 and at the bottom of the shell 37, and the two through holes 39 above are symmetrically arranged. A fourth rotating shaft 45 is rotatably installed at the center of the filtering device 15, and a partition 40 and two filter plates 38 are fixedly installed on the fourth rotating shaft 45. The partition 40 and the end of the filter plate 38 away from the fourth rotating shaft 45 form an isosceles triangle. The partition 40 moves on both sides of the two through holes 39, the fourth rotating shaft 45 extends out of the shell 37, and a connecting column 41 is fixedly installed at the edge of the fourth rotating shaft 45.

[0053] As the action frame 22 swings, the action frame 22 drives the connecting column 41 to swing back and forth through the connecting member 23, so that the fourth rotating shaft 45 rotates back and forth in the housing 37, so that the filter plate 38 moves between the two sides of the through hole 39, so that the through hole 39 at the bottom is connected with the through hole 39 at the top in sequence, and the high-temperature flue gas is sequentially introduced into the two gas pipes 13. Figure 4 and Figure 5 As shown, when the through hole 39 at the bottom is connected with the through hole 39 on the left, the high-temperature flue gas is transported upward from the gas supply pipe 13 on the left, and is transported from the heat exchange pipe 11 on the left to the inside of the adsorption device 10, and is adsorbed by the solid amine particle modules inside the two adsorption devices 10 to achieve a better adsorption effect, and the high-temperature flue gas is transported from the air inlet pipe 16 to the filter device 15, and is filtered by two partitions 40 to achieve a better effect of filtering dust and particles in the flue gas. By setting the filter device 15, the effect of flue gas guiding and filtering is achieved.

[0054] The driving mechanism 12 includes an action frame 22 and a fixed plate 17, the fixed plate 17 is rotatably connected with a second rotating shaft 21 and a first rotating shaft 19, the first rotating shaft 19 is fixedly mounted with a disc 18, the second rotating shaft 21 is fixedly mounted with an action frame 22, a first action rod 20 is fixedly mounted at the edge of the disc 18, the first rotating shaft 19 and the first action rod 20 are within the frame of the action frame 22, and the first action rod 20 drives the action frame 22 to rotate around the second rotating shaft 21;

[0055] The upper and lower sections of the action frame 22 are fixedly mounted with connecting pieces 23, and the two connecting pieces 23 are respectively connected to the connecting column 41 and the heat exchange tube 11;

[0056] The connecting member 23 is composed of a telescopic rod and a rotating shaft, and the rotating shaft is rotatably connected to both ends of the connecting member 23 .

[0057] The first rotating shaft 19 is connected to the output shaft of an external rotating motor, and the external motor drives the first rotating shaft 19 to rotate, so that the first action rod 20 rotates around the first rotating shaft 19, and the first action rod 20 drives the action frame 22 to swing back and forth. By utilizing the connection method of the connecting piece 23, the action frame 22 drives the fourth rotating shaft 45 to swing back and forth, and drives the card bar 26 to move back and forth.

[0058] The exhaust pipe 14 is installed on the side of the gas pipe 13, and a hinge 43 is fixedly installed at the connection between the exhaust pipe 14 and the gas pipe 13. A blocking plate 44 is fixed on the hinge 43, and the blocking plate 44 rotates at the connection between the gas pipe 13 and the exhaust pipe 14 through the hinge 43;

[0059] The blocking plate 44 is installed in an inclined manner in the air delivery pipe 13 by the elastic force of the hinge 43 , and the shape of the blocking plate 44 is adapted to the exhaust pipe 14 .

[0060] When the high-temperature flue gas is transported from the air pipe 13 on one side to the adsorption device 10, the airflow is from bottom to top, and the air pipe 13 on the other side is used to discharge the flue gas after adsorption, that is, to discharge the residual gas, and the airflow is from top to bottom. When the air pipe 13 transports the high-temperature flue gas, the airflow formed by the high-temperature flue gas acts on the blocking plate 44, pushing the blocking plate 44 to seal the exhaust pipe 14, thereby completing the transportation of the high-temperature flue gas. When the air pipe 13 discharges the residual gas, the residual gas pushes the blocking plate 44 to seal the air pipe 13, and the residual gas is discharged from the exhaust pipe 14 to achieve the effect of discharging the residual gas. The design of the fourth rotating shaft 45 ensures that the airflow can push the blocking plate 44 to seal the exhaust pipe 14 or the air pipe 13, thereby achieving the effect of airflow guidance and better completing the effects of flue gas transportation and residual gas discharge.

[0061] The adsorption device 10 includes a pipe shell 24, and two ends of the two pipe shells 24 that are away from each other are each provided with two movable grooves 30, and a movable groove 31 is provided on the inner wall of the pipe shell 24 between the two movable grooves 30, and an adsorption mechanism is movably engaged in the movable groove 31 and the movable groove 30;

[0062] The adsorption mechanism moves between the two movable grooves 30 and the movable groove 31 , and the adsorption mechanism is preheated by heat conduction between the adsorption device 10 and the heat exchange tube 11 .

[0063] A moving plate 27 is slidably mounted on one end of the two pipe housings 24 that are close to each other. A slide groove 42 is provided at the bottom of the pipe housing 24. A clamping strip 26 is slidably mounted in the two slide grooves 42. The clamping strip 26 is connected to the connecting piece 23 at the upper end of the action frame 22, and the clamping strip 26 is movably connected to the action frame 22 through the connecting piece 23.

[0064] The clamping strip 26 is fixedly connected to the moving plate 27 , and the rotation of the action frame 22 drives the connecting member 23 to swing, thereby driving the clamping strip 26 to slide in the locking block 32 , and then the moving plate 27 reciprocates in the pipe housing 24 .

[0065] The movable plate 27 is movably connected with a second action rod 28, and a spirally arranged engaging groove 29 is provided on the circumferential surface of the second action rod 28. A engaging rod 25 is fixedly installed on the side of the movable plate 27, and the engaging rod 25 is interactively engaged in the engaging groove 29. Through the engaging effect of the engaging rod 25 and the engaging groove 29, as the movable plate 27 reciprocates left and right, the second action rod 28 operates in a rotation-movement-rotation mode with the movable plate 27;

[0066] The second action rod 28 is fixedly connected to the adsorption mechanism, and the second action rod 28 drives the adsorption mechanism to operate in the pipeline housing 24 .

[0067] The adsorption mechanism includes a placement frame 33, and two snap-fit ​​blocks 32 are symmetrically installed on the outside of the placement frame 33. The two snap-fit ​​blocks 32 are snap-fitted into the movable groove 31 or the movable groove 30, and move in the movable groove 31 and rotate in the movable groove 30;

[0068] A partition plate 34 is fixedly installed at the center of the inner circle of the placement frame 33. The partition plate 34 is arranged corresponding to the locking block 32. The partition plate 34 divides the inner circle of the placement frame 33 into two parts, and a solid amine particle module is placed in each part.

[0069] The partition plate 34 is rotatably connected to a third rotating shaft 35 , and the third rotating shaft 35 is rotatably connected to a baffle 36 , and the baffle 36 is a semicircular plate. The baffle 36 moves inside the pipeline housing 24 as the placement frame 33 moves, and shields the solid amine particle module located below the partition plate 34 .

[0070] The movable plate 27 moves left and right in the pipe housing 24 along with the card strip 26. When the card strip 26 moves from left to right, at the beginning, the placement frame 33 and the engaging block 32 are movably engaged in the movable groove 30. As the movable plate 27 moves, the second action rod 28 moves along with the movement of the movable plate 27, so that the engaging block 32 slides on the engaging block 32. When the engaging block 32 is movably engaged in another movable groove 30, the engaging block 32 is blocked by the side of the movable groove 30. As the movable plate 27 continues to move, the movable plate 27 drives the engaging rod 25 to slide in the engaging groove 29, so that the second action rod 28 rotates along with the movement of the movable plate 27. The position of the engaging rod 25 in the engaging groove 29 is adjusted, so that the driven adsorption device of the placement frame 33 and the engaging block 32 is 108° rotation, that is, the two solid amine particle modules are adjusted in the upper and lower positions. With the reciprocating movement of the movable plate 27, the placement frame 33 operates between the two movable grooves 30 and the movable groove 31 in the manner of rotating the disk 180°-moving-rotating the disk 180°-moving. When the placement frame 33 of the solid amine particle module rotates, the solid amine particles located at the bottom exchange heat with the corresponding heat exchange tubes 11 to achieve the preheating effect, and the solid amine particle module rotated to the top is directly passed by the flue gas to achieve the effect of adsorbing carbon dioxide. When the high-temperature flue gas moves between the two adsorption devices 10, after two adsorptions and two heat exchanges, the effect of absorbing the heat of the flue gas is achieved, thereby reducing the heat in the flue gas and achieving a better effect of discharging the residual gas.

[0071] The high-temperature flue gas is adsorbed by the solid amine particle module in the second adsorption device 10, and is discharged through the heat exchange tube 11. The heat exchange tube 11 exchanges heat with the solid amine particle module. When the filtering device 15 is in operation, the conveying direction of the flue gas is reversed. At this time, the solid amine particle module in the second adsorption device 10 achieves the effect of preheating before preheating due to the last heat exchange, that is, the solid amine particle module undergoes two preheating treatments when it is in effect, achieving a better preheating treatment effect.

[0072] When using,

[0073] Step 1: The first rotating shaft 19 is connected to the output shaft of the external rotating motor, and the external motor drives the first rotating shaft 19 to rotate, so that the first action rod 20 rotates around the first rotating shaft 19, and the first action rod 20 drives the action frame 22 to swing back and forth. By using the connection method of the connecting member 23, the action frame 22 drives the fourth rotating shaft 45 to swing back and forth, and drives the card bar 26 to move back and forth;

[0074] Step 2: As the action frame 22 swings, the action frame 22 drives the connecting column 41 to swing back and forth through the connecting piece 23, so that the fourth rotating shaft 45 rotates back and forth in the housing 37, so that the filter plate 38 moves on both sides and between the through holes 39, so that the through holes 39 at the bottom are connected with the through holes 39 at the top in sequence, and the high-temperature flue gas is passed into the two gas pipes 13 in sequence;

[0075] Step 3: The moving plate 27 moves left and right in the pipe housing 24 along with the card strip 26. When the card strip 26 moves from left to right, at the beginning, the placement frame 33 and the snap block 32 are movably snapped in the movable groove 30. As the moving plate 27 moves, the second action rod 28 moves along with the movement of the moving plate 27, so that the snap block 32 slides on the snap block 32. When the snap block 32 is movably snapped in another movable groove 30, the snap block 32 is blocked by the side of the movable groove 30. As the moving plate 27 continues to move, the moving plate 27 drives the snap rod 25 to slide in the snap groove 29, so that the second action rod 28 rotates along with the movement of the moving plate 27. The position of the snap rod 25 in the snap groove 29 is adjusted so that the placement frame 33 and the snap block 32 are snapped. The adsorption device rotates 108°, that is, the two solid amine particle modules are adjusted in the up and down positions. With the reciprocating movement of the movable plate 27, the placement frame 33 operates between the two movable grooves 30 and the movable groove 31 in the manner of rotating the disk 180°-moving-rotating the disk 180°-moving. When the placement frame 33 of the solid amine particle module rotates, the solid amine particles located at the bottom exchange heat with the corresponding heat exchange tubes 11, while the solid amine particle module rotated to the top is directly passed by the flue gas, thereby achieving the effect of adsorbing carbon dioxide. Moreover, when the high-temperature flue gas moves between the two adsorption devices 10, after two adsorptions and two heat exchanges, the heat of the flue gas is absorbed, the heat in the flue gas is reduced, and the effect of better exhausting the residual gas is achieved.

[0076] Step 4: When the high-temperature flue gas is transported from the gas pipe 13 on one side to the adsorption device 10, the airflow is from bottom to top, and the gas pipe 13 on the other side is used to discharge the adsorbed flue gas, that is, to discharge the residual gas, and the airflow is from top to bottom. When the gas pipe 13 transports the high-temperature flue gas, the airflow formed by the high-temperature flue gas acts on the blocking plate 44, pushing the blocking plate 44 to seal the exhaust pipe 14, thereby completing the transportation of the high-temperature flue gas. When the gas pipe 13 discharges the residual gas, the residual gas pushes the blocking plate 44 to seal the gas pipe 13, and the residual gas is discharged from the exhaust pipe 14, achieving the effect of discharging the residual gas.

[0077] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. A flue gas carbon dioxide recovery and resource utilization device, comprising two adsorption devices (10) and a filtering device (15), wherein a solid amine particle module for adsorbing carbon dioxide in flue gas is placed in the adsorption device (10), characterized in that: The two adsorption devices (10) are symmetrically arranged and fixedly connected to each other, and the two adsorption devices (10) are in communication with each other; Wherein, heat exchange tubes (11) are fixedly mounted at both ends of the adsorption device (10), the heat exchange tubes (11) are attached to the bottom of the adsorption device (10), and the heat exchange tubes (11) are in contact with the adsorption device (10) to exchange heat; The filtering device (15) comprises a housing (37), and three through holes (39) are formed on the circumference of the housing (37), wherein an air intake pipe (16) is fixedly mounted on one of the through holes (39), and high-temperature flue gas is introduced through the air intake pipe (16), and the other two through holes (39) are fixedly connected to air delivery pipes (13); Wherein, a driving mechanism (12) is provided between the adsorption device (10) and the filtering device (15), and the driving mechanism (12) drives the internal components of the adsorption device (10) and the filtering device (15) to operate; Wherein, the gas delivery pipe (13) is fixedly connected to an exhaust pipe (14), and the exhaust pipe (14) is used to discharge the treated residual gas; The through holes (39) are respectively located above the housing (37) and at the bottom of the housing (37), and the two through holes (39) at the top are symmetrically arranged. A fourth rotating shaft (45) is rotatably mounted at the center of the filtering device (15), and a partition (40) and two filter plates (38) are fixedly mounted on the fourth rotating shaft (45). The partition (40) and the filter plates (38) at one end away from the fourth rotating shaft (45) form an isosceles triangle. The partition (40) moves on both sides of the two through holes (39). The fourth rotating shaft (45) extends out of the housing (37), and a connecting column (41) is fixedly mounted on the edge of the fourth rotating shaft (45); The exhaust pipe (14) is installed on the side of the gas supply pipe (13); a hinge (43) is fixedly installed at the connection between the exhaust pipe (14) and the gas supply pipe (13); a blocking plate (44) is fixed on the hinge (43); the blocking plate (44) is rotated at the connection between the gas supply pipe (13) and the exhaust pipe (14) through the hinge (43); The blocking plate (44) is installed in an inclined manner in the gas delivery pipe (13) by means of the elastic force of the hinge (43), and the shape of the blocking plate (44) is adapted to the exhaust pipe (14); The adsorption device (10) comprises a pipe shell (24), two ends of the two pipe shells (24) being provided with two movable grooves (30), an inner wall of the pipe shell (24) between the two movable grooves (30) being provided with a movable groove (31), and an adsorption mechanism being movably engaged in the movable groove (31) and the movable groove (30); The adsorption mechanism moves between the two movable grooves (30) and the movable groove (31), and the adsorption mechanism is preheated by heat conduction between the adsorption device (10) and the heat exchange tube (11); A movable plate (27) is slidably mounted on one end of the two pipe shells (24) close to each other, a slide groove (42) is provided at the bottom of the pipe shell (24), a clamping strip (26) is slidably mounted in the two slide grooves (42), the clamping strip (26) is connected to a connecting piece (23) at the upper end of the action frame (22), and the clamping strip (26) is movably connected to the action frame (22) via the connecting piece (23); The clamping strip (26) is fixedly connected to the movable plate (27), and the rotation of the action frame (22) drives the connecting member (23) to swing, thereby driving the clamping strip (26) to slide in the locking block (32), thereby causing the movable plate (27) to reciprocate in the pipeline housing (24); The movable plate (27) is movably connected with a second action rod (28), a spirally arranged engaging groove (29) is provided on the circumferential surface of the second action rod (28), a engaging rod (25) is fixedly mounted on the side of the movable plate (27), the engaging rod (25) is interactively engaged in the engaging groove (29), and through the engaging effect of the engaging rod (25) and the engaging groove (29), as the movable plate (27) reciprocates left and right, the second action rod (28) operates in a rotation-movement-rotation manner along with the movable plate (27); The second action rod (28) is fixedly connected to the adsorption mechanism, and the second action rod (28) drives the adsorption mechanism to operate in the pipeline housing (24); The adsorption mechanism comprises a placement frame (33), and two engaging blocks (32) are symmetrically mounted on the outside of the placement frame (33); the two engaging blocks (32) are engaged in the movable groove (31) or the movable groove (30), and move in the movable groove (31) and rotate in the movable groove (30); A partition plate (34) is fixedly installed at the center of the inner circle of the placement frame (33), and the partition plate (34) is arranged corresponding to the locking block (32). The partition plate (34) divides the inner circle of the placement frame (33) into two parts, and a solid amine particle module is placed in each part; The partition plate (34) is rotatably connected to a third rotating shaft (35), and the third rotating shaft (35) is rotatably connected to a baffle (36), wherein the baffle (36) is a semicircular plate, and the baffle (36) moves inside the pipeline housing (24) along with the movement of the placement frame (33), and shields the solid amine particle module located below the partition plate (34).

2. The device for recovering and recycling flue gas carbon dioxide according to claim 1, characterized in that: The driving mechanism (12) comprises an action frame (22) and a fixed plate (17); a second rotating shaft (21) and a first rotating shaft (19) are rotatably connected to the fixed plate (17); a disk (18) is fixedly mounted on the first rotating shaft (19); the action frame (22) is fixedly mounted on the second rotating shaft (21); a first action rod (20) is fixedly mounted on the edge of the disk (18); the first rotating shaft (19) and the first action rod (20) are within the frame of the action frame (22); and the first action rod (20) drives the action frame (22) to rotate around the second rotating shaft (21); Wherein, the upper and lower sections of the action frame (22) are both fixedly mounted with connecting pieces (23), and the two connecting pieces (23) are respectively connected to the connecting column (41) and the heat exchange tube (11); The connecting member (23) is composed of a telescopic rod and a rotating shaft, and the rotating shaft is rotatably connected to both ends of the connecting member (23).

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