Single-phase AB3 type superlattice hydrogen storage alloy and preparation method thereof

Abstract

The invention belongs to the field of hydrogen storage alloys, and particularly discloses a single-phase AB3 type superlattice hydrogen storage alloy and a preparation method thereof. The hydrogen storage alloy is of a single-phase AB3 type crystal phase structure and has higher hydrogen storage capacity and cycle stability compared with other multi-phase or single-phase A2B7 and A5B19 hydrogen storage alloys, the hydrogen absorption capacity reaches 1.8 wt.% or above, the effective hydrogen desorption capacity reaches 1.7 wt.% or above, and the 200-time cycle capacity retention rate reaches 95% or above.

Description

Technical Field

[0001] The invention belongs to the field of hydrogen storage alloys, and in particular relates to a single-phase AB3 type superlattice hydrogen storage alloy and a preparation method thereof. Background Art

[0002] According to domestic and foreign research reports, rare earth hydrogen storage materials are m B n The naming is in the form of, where A is an element with strong affinity for hydrogen and can react with hydrogen to produce hydrides, mainly rare earth elements, Ti, Mg, Zr, V, etc.; B is a control element for hydrogen transfer and release, mainly transition metals such as Ni, Co, Cr, etc.; element B generally does not react with hydrogen, but after forming an alloy with A, it can catalyze the absorption and release of hydrogen. Common rare earth hydrogen storage materials include AB5 type, superlattice type (such as AB3, A2B3, A5B 19 , AB4, etc.) and rare earth modified materials, etc.

[0003] AB5-type hydrogen storage alloy materials (such as LaNi5) have the advantages of easy activation and good cycle stability, but their weight hydrogen storage density is relatively low (about 1.4wt%), which restricts their application in gas-solid hydrogen storage (hydrogen energy and fuel cells, etc.). In order to improve the weight hydrogen storage density, new rare earth hydrogen storage materials with superlattice structure have become a research hotspot in recent years. The crystal structure of rare earth superlattice hydrogen storage materials is formed by stacking [A2B4] and [AB5] subunits along the c-axis, so this type of hydrogen storage material has the high capacity characteristics of AB2-type alloys and the advantages of easy activation of AB5-type alloys. The National Research Institute in Osaka, Japan, has developed a high-performance PuNi3-type superlattice hydrogen storage material (AB3-type) using powder metallurgy technology and light element substitution. The reversible hydrogen storage and desorption density at room temperature reaches more than 1.8wt%, which is significantly higher than the traditional AB5-type hydrogen storage material. Many researchers in my country have also conducted research on superlattice hydrogen storage materials for gas-solid hydrogen storage. The room-temperature hydrogen storage density of the obtained materials exceeds 1.7wt%, but the room-temperature hydrogen desorption density is only 1.4~1.6wt%. In addition to hydrogen storage capacity, the cycle life of rare earth hydrogen storage materials is also crucial. Ibaraki University in Japan found that Mg replaces Pr to form Pr1-xMgxNi3 alloy, which can anisotropically shrink the unit cell volume to reversibly adsorb and desorb hydrogen and prevent the alloy structure from changing. Yanshan University proposed that asynchronous expansion and contraction between [A2B4] and [AB5] sublattices will cause stress in the super stacking structure of the alloy, thereby destroying the cycle stability. Shanghai University found that a small amount of Mg replacing Y can significantly inhibit the hydrogen-induced amorphization of the La-Y-Ni system, while improving the electrochemical capacity, and the cycle capacity retention rate is increased by 1 times. Therefore, by adding Mg, the regulation of superlattice subunits and the replacement of lightweight elements, as well as the matching adjustment between unit cell size and subunits, it is expected to develop new rare earth hydrogen storage materials with high hydrogen storage density and long life.

[0004] However, due to the light weight and low melting point of Mg, in the preparation process of hydrogen storage alloys, the melting temperature or heat treatment temperature generally exceeds the melting point of Mg, which is easy to float, volatilize, and adhere to the equipment, resulting in uneven distribution of Mg in the hydrogen storage alloy, and uncontrollable Mg content. In addition, there are generally multiple types of alloy phase structures in the prepared hydrogen storage alloy, which reduces the weight hydrogen storage density and life of the hydrogen storage alloy. Therefore, at present, the process of using Mg to regulate the crystal phase structure and state of hydrogen storage alloys is still immature, and it is impossible to efficiently obtain a single-phase hydrogen storage alloy through a simple process to achieve the purpose of improving the weight hydrogen storage density and life of the hydrogen storage alloy. Summary of the invention

[0005] In view of the problem in the above-mentioned prior art that it is difficult to prepare a single-phase hydrogen storage alloy by using Mg to regulate the crystal structure and state of the hydrogen storage alloy, the present invention will provide a single-phase AB3 superlattice hydrogen storage alloy and a preparation method thereof.

[0006] To achieve the above purpose, the following technical solutions are specifically included: A hydrogen storage alloy having a general chemical formula of Y 1-x-y A x Mg y Ni 3-z B z , wherein x, y, and z are stoichiometric ratios, and the values ​​of x, y, and z satisfy the following formula: 0≤x≤0.2, 0.1<y≤0.2, 0≤z≤0.2, A includes at least one element of Sm, La, and Ca, and B includes at least one element of Co, Cr, Zn, and Mo; the hydrogen storage alloy is a single-phase AB3 type crystal phase structure.

[0007] The hydrogen storage alloy of the present invention has a single-phase AB3 type superlattice crystal phase structure, which is different from other multi-phase or single-phase A2B7, A5B 19 Hydrogen storage alloys have higher hydrogen storage capacity and cycle stability.

[0008] Preferably, the hydrogen storage alloy comprises at least one of the following chemical formulas: 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , Y 0.85 Mg 0.15 Ni3, Y 0.8 La 0.05 Mg 0.15 Ni3.

[0009] Preferably, the hydrogen storage alloy has a (Y,Mg)1Ni3 crystal phase.

[0010] A method for preparing the hydrogen storage alloy comprises the following steps: (1) According to the chemical formula Y 1-x-y A x Mg y Ni 3-z B z The stoichiometric ratio and the use of the simple substances of each element as raw materials for batching; (2) melting the single element raw materials of each element except the single element raw material of Mg; (3) adding Mg single substance raw material for smelting to obtain alloy melt; (4) performing belt-spinning smelting on the alloy melt to obtain an alloy belt; (5) The alloy is subjected to heat treatment to obtain the hydrogen storage alloy.

[0011] In the method of the present invention, the Mg single substance raw material and other metal element single substance raw materials are first smelted separately, and then the alloy melt is formed by a belt spinning method, and finally the alloy belt is heat treated. The various processes cooperate with each other, and the Mg element content can be accurately controlled, the alloy phase structure is optimized, and the purpose of improving the alloy performance is achieved.

[0012] The method of the present invention can overcome the defects of uneven distribution of Mg element, difficult control of Mg element content and the presence of multiple types of crystal phases in the alloy, and obtain a single-phase AB3 type hydrogen storage alloy with high hydrogen storage density and long hydrogen storage life.

[0013] Preferably, in step (1), when the ingredients are prepared, the chemical formula Y 1-x-y A x Mg y Ni 3-z B z Calculated based on the mass of Mg element in the raw material, the content of Mg element is in excess of 15-30wt.%.

[0014] The present invention increases the Mg content in the alloy by adding an excessive amount of Mg, further accurately controls the Mg content, improves lattice stability, and further improves the hydrogen storage performance of the hydrogen storage alloy.

[0015] Preferably, in step (2), the smelting is performed by induction smelting, the power of the induction smelting is 15-20 kW, and the time of the induction smelting is 20-30 min.

[0016] Preferably, in step (3), the smelting is performed by induction smelting, the power of the induction smelting is 10-15 kW, and the time of the induction smelting is 4-8 min.

[0017] Preferably, in step (4), the belt smelting rate is 0.5-1.5 m / s.

[0018] Preferably, in step (5), the heat treatment temperature is 900-950°C, the heat treatment time is 2-6h, and the heating rate when heating to the heat treatment temperature is 5-10°C / min.

[0019] Compared with the prior art, the present invention has the following beneficial effects: the hydrogen storage alloy of the present invention is a single-phase AB3 superlattice crystal phase structure, has a high hydrogen storage density and a long hydrogen storage life, wherein the hydrogen absorption amount reaches more than 1.8wt.%, the effective hydrogen release amount reaches more than 1.7wt.%, and the capacity retention rate after 200 cycles reaches more than 95%. BRIEF DESCRIPTION OF THE DRAWINGS

[0020] Figure 1 This is the SEM image of the hydrogen storage alloy of Example 1.

[0021] Figure 2 This is the SEM image of the hydrogen storage alloy of Comparative Example 1.

[0022] Figure 3 This is the SEM image of the hydrogen storage alloy of Comparative Example 2.

[0023] Figure 4 This is the SEM image of the hydrogen storage alloy of Comparative Example 3.

[0024] Figure 5 This is the SEM image of the hydrogen storage alloy of Comparative Example 4. DETAILED DESCRIPTION

[0025] In order to better illustrate the purpose, technical scheme and advantages of the present invention, the present invention will be further described below through specific examples. The test methods used in the examples and / or comparative examples are conventional methods unless otherwise specified; the materials, reagents, etc. used can be obtained from commercial channels unless otherwise specified.

[0026] Example 1 A method for preparing a hydrogen storage alloy comprises the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , take the single substance of each metal element as raw material and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, and based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the single element raw materials of Y, Sm, Ni, and Co, except for the single element raw material of Mg, are melted at a melting power of 18 kW and a melting time of 20 min; (3) Add Mg single substance raw material for smelting at a smelting power of 12 kW and a smelting time of 5 min to obtain a uniform alloy melt; (4) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 1.5 m / s to obtain the alloy belt-spinning; (5) The alloy is spun on a belt, and the temperature is increased from room temperature to 950° C. at a heating rate of 5° C. / min, and the temperature is kept at this temperature for 5 h. The alloy is then cooled to room temperature in a furnace to obtain the hydrogen storage alloy.

[0027] Example 2 A method for preparing a hydrogen storage alloy comprises the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.85 Mg 0.15 Ni3, take the single substance of each element as raw material, and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt induction melting furnace, the Y and Ni elemental raw materials except the Mg elemental raw material are melted at a melting power of 20 kW and a melting time of 30 min; (3) Add Mg single-element raw material for smelting at a smelting power of 15 kW and a smelting time of 5 min to obtain a uniform alloy melt; (4) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 0.8 m / s to obtain the alloy belt-spinning; (5) The alloy is spun on a belt, and the temperature is increased from room temperature to 950° C. at a heating rate of 5° C. / min, and the temperature is kept at this temperature for 4 h. The alloy is then cooled to room temperature in a furnace to obtain the hydrogen storage alloy.

[0028] Example 3 A method for preparing a hydrogen storage alloy comprises the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.8 La 0.05 Mg 0.15Ni3, take the single substance of each element as raw material, and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the Y, La, and Ni elemental raw materials except the Mg elemental raw material are melted at a melting power of 20 kW and a melting time of 20 min; (3) Add Mg single-element raw material for smelting at a smelting power of 15 kW and a smelting time of 3 min to obtain a uniform alloy melt; (4) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 1.5 m / s to obtain the alloy belt-spinning; (5) The alloy was spun on a belt, and the temperature was increased from room temperature to 925° C. at a heating rate of 5° C. / min, and the temperature was kept at that temperature for 3 h. The alloy was then cooled to room temperature in the furnace to obtain the hydrogen storage alloy.

[0029] Example 4 A method for preparing a hydrogen storage alloy comprises the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , take the single substance of each element as raw material and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, and based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the single element raw materials of Y, Sm, Ni, and Co, except for the single element raw material of Mg, are melted at a melting power of 19 kW and a melting time of 25 min; (3) Mg single substance raw material is added for smelting at a smelting power of 12 kW and a smelting time of 4 min to obtain a uniform alloy melt; (4) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 1 m / s to obtain the alloy belt-spinning; (5) The alloy is spun on a belt, and the temperature is increased from room temperature to 950° C. at a heating rate of 5° C. / min, and the temperature is kept at this temperature for 6 h. The alloy is then cooled to room temperature in a furnace to obtain the hydrogen storage alloy.

[0030] Comparative Example 1 The difference between this comparative example and Example 1 is that this comparative example does not adopt the belt-swinging method to form, but adopts the casting ingot method to form, and includes the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , take the single substance of each element as raw material and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, and based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the single element raw materials of Y, Sm, Ni, and Co, except for the single element raw material of Mg, are melted at a melting power of 18 kW and a melting time of 20 min; (3) Add Mg single-element raw material for smelting at a smelting power of 12 kW and a smelting time of 5 min to obtain a uniform alloy melt; (4) casting the alloy melt, and naturally cooling it after casting to obtain an ingot; (5) The ingot is heated from room temperature to 950° C. at a heating rate of 5° C. / min, kept at this temperature for 5 h, and then cooled to room temperature in the furnace to obtain a hydrogen storage alloy.

[0031] Comparative Example 2 The difference between this comparative example and Example 1 is that this comparative example does not perform heat treatment on the alloy strip, and comprises the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , take the single substance of each element as raw material and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, and based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the single element raw materials of Y, Sm, Ni, and Co, except for the single element raw material of Mg, are melted at a melting power of 18 kW and a melting time of 20 min; (3) Add Mg single-element raw material for smelting at a smelting power of 12 kW and a smelting time of 5 min to obtain a uniform alloy melt; (4) The alloy melt is subjected to belt melting at a belt melting speed of 1.5 m / s to obtain the hydrogen storage alloy.

[0032] Comparative Example 3 The difference between this comparative example and Example 1 is that this comparative example does not feed the Mg element single substance raw material and other element single substance raw materials separately, and includes the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , take the single substance of each element as raw material and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, and based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt induction melting furnace, the single element raw materials of Mg, Y, Sm, Ni and Co are melted at a melting power of 18 kW and a melting time of 20 min to obtain an alloy melt; (3) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 1.5 m / s to obtain the alloy belt-spinning; (4) The alloy is spun on a belt, and the temperature is increased from room temperature to 950° C. at a heating rate of 5° C. / min, and the temperature is kept at this temperature for 5 h. The alloy is then cooled to room temperature in a furnace to obtain the hydrogen storage alloy.

[0033] Comparative Example 4 The difference between this comparative example and Example 1 is that the alloy composition of this comparative example is Y 0.8 La 0.05 Mg 0.15 Ni2, comprising the following steps: (1) In terms of molar ratio, according to the chemical formula Y 0.8 La 0.05 Mg 0.15 Ni2, take the single substance of each element as raw material, and prepare the ingredients, wherein the total mass of the single substance raw materials of each element is 3kg, based on the mass of the Mg element converted in the above chemical formula, an excess of 20wt.% is added, that is, the mass of the Mg element converted in the above chemical formula is represented by m1, and the mass of the Mg single substance raw material is represented by m, then m=m1+m1*20%; (2) In a 5 kg-class belt-swinging induction melting furnace, the Y, La, and Ni elemental raw materials except the Mg elemental raw material are melted at a melting power of 18 kW and a melting time of 20 min; (3) Add Mg single substance raw material for smelting at a smelting power of 12 kW and a smelting time of 5 min to obtain a uniform alloy melt; (4) subjecting the alloy melt to belt-spinning smelting at a belt-spinning speed of 1.5 m / s to obtain the alloy belt-spinning; (5) The alloy is spun on a belt, and the temperature is increased from room temperature to 950° C. at a heating rate of 5° C. / min, and the temperature is kept at this temperature for 5 h. The alloy is then cooled to room temperature in a furnace to obtain the hydrogen storage alloy.

[0034] The alloys prepared in the above-mentioned embodiments and comparative examples were subjected to performance tests, and the specific test methods are as follows: (1) Phase structure and phase content (wt.%): XRD was used to characterize the phase of the alloy sample, and GSAS was used to refine the XRD data to obtain the lattice constant; (2) Hydrogen absorption and effective hydrogen desorption (wt.%): After the alloy sample is activated, the PCT curve test is carried out at 25°C and 8MPa hydrogen pressure to obtain the hydrogen absorption and effective hydrogen desorption above 0.1MPa; (3) 200-cycle capacity retention rate (%): Hydrogen absorption for 30 min at 25 °C and 8 MPa hydrogen pressure, followed by vacuuming at 25 °C for 30 min, as one cycle to test the hydrogen absorption capacity retention rate of the alloy; (3) Alloy micromorphology: scanning electron microscopy (SEM).

[0035] The test results are shown in Table 1 and Appendix Figure 1-4 shown.

[0036] Table 1

[0037] The above embodiments are combined with the attached Figure 1 As can be seen from Table 1, the hydrogen storage alloys of the present invention are all single-phase AB3 type, i.e., (Y,Mg)1Ni3 crystal phase, with a hydrogen absorption capacity of more than 1.8wt.%, an effective hydrogen release capacity of more than 1.7wt.%, a capacity retention rate of more than 95% after 200 cycles, and have high hydrogen storage density and long cycle life.

[0038] In the embodiment and comparative example 1, Figure 2 As can be seen from Table 1, after the hydrogen storage alloy in Comparative Example 1 is conventionally cast and cooled, Mg has a relatively low melting point, which is quite different from other components and is unevenly distributed in the alloy, resulting in the appearance of AB5 phase in the alloy, which reduces the amount of hydrogen absorption and desorption of the alloy. In addition, the presence of multiple phases in the alloy causes the alloy to be severely powdered during hydrogen absorption and desorption, the superlattice structure is easily collapsed, and the cycle performance is reduced.

[0039] In Example 1 and Comparative Example 2, Figure 3As shown in Table 1, heat treatment of the alloy strip can stabilize the phase structure of the alloy, improve the uniformity of the alloy, and reduce the lattice stress of the alloy; the alloy strip in Example 2 was not heat treated, resulting in a multiphase structure of the alloy, and the platform slope factor in the PCT curve was large, indicating that the amount of hydrogen absorption and desorption was reduced.

[0040] In Example 1 and Comparative Example 3, Figure 4 As can be seen from Table 1, the Mg raw material in Comparative Example 3 is directly fed together with other elements, resulting in severe Mg volatilization, insufficient Mg content in the alloy, poor repeatability, difficulty in forming a superlattice structure, and reduced hydrogen storage capacity.

[0041] In Example 1 and Comparative Example 4, Figure 5 As shown in Table 1, the alloy in Comparative Example 4 forms a multiphase structure, and the hydrogen storage and release capacity is reduced. Therefore, different alloy components will significantly affect the crystal phase composition of the alloy.

[0042] Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention rather than to limit the scope of protection of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solution of the present invention can be modified or replaced by equivalents without departing from the essence and scope of the technical solution of the present invention.

Claims

1. A hydrogen storage alloy, characterized in that Its chemical formula is Y 1-x-y A x Mg y Ni 3-z B z , wherein x, y, and z are stoichiometric ratios, and the values ​​of x, y, and z satisfy the following formula: 0≤x≤0.2, 0.1<y≤0.2, 0≤z≤0.2, A includes at least one element of Sm, La, and Ca, and B includes at least one element of Co, Cr, Zn, and Mo; the hydrogen storage alloy is a single-phase AB3 type crystal phase structure.

2. The hydrogen storage alloy according to claim 1, characterized in that The hydrogen storage alloy comprises at least one of the following chemical formulas: 0.7 Sm 0.15 Mg 0.15 Ni 2.9 Co 0.1 , Y 0.85 Mg 0.15 Ni3, Y 0.8 La 0.05 Mg 0.15 Ni3.

3. The hydrogen storage alloy according to claim 1, characterized in that The hydrogen absorption capacity of the hydrogen storage alloy reaches more than 1.8wt.%, and the effective hydrogen release capacity of the hydrogen storage alloy reaches more than 1.7wt.%.

4. The hydrogen storage alloy according to claim 1, characterized in that The hydrogen storage alloy has a (Y,Mg)1Ni3 crystal phase.

5. A method for preparing the hydrogen storage alloy according to any one of claims 1 to 4, characterized in that: The steps include: (1) According to the chemical formula Y 1-x-y A x Mg y Ni 3-z B z The stoichiometric ratio and the use of the simple substances of each element as raw materials for batching; (2) smelting the single element raw materials of each element except the single element raw material of Mg; (3) adding Mg single substance raw material for smelting to obtain alloy melt; (4) performing belt-spinning smelting on the alloy melt to obtain an alloy belt; (5) The alloy is subjected to heat treatment to obtain the hydrogen storage alloy.

6. The method for preparing a hydrogen storage alloy according to claim 5, characterized in that: In step (1), when the ingredients are prepared, the chemical formula Y 1-x-y A x Mg y Ni 3-z B z Calculated based on the mass of Mg element in the raw material, the content of Mg element is in excess of 15-30wt.%.

7. The method for preparing a hydrogen storage alloy according to claim 5, characterized in that: In step (2), the smelting is performed by induction smelting, the power of the induction smelting is 15-20 kW, and the time of the induction smelting is 20-30 min.

8. The method for preparing a hydrogen storage alloy according to claim 5, characterized in that: In step (3), the smelting is performed by induction smelting, the power of the induction smelting is 10-15 kW, and the time of the induction smelting is 4-8 min.

9. The method for preparing a hydrogen storage alloy according to claim 5, characterized in that: In step (4), the belt smelting rate is 0.5-1.5 m / s.

10. The method for preparing a hydrogen storage alloy according to claim 5, characterized in that: In step (5), the heat treatment temperature is 900-950°C, the heat treatment time is 2-6h, and the heating rate when heating to the heat treatment temperature is 5-10°C / min.

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