Active agent composition and cosmetic

Abstract

Provided are: an active agent composition having low viscosity and excellent handling properties, which contains (A) a nonionic surfactant having two or more hydroxyl groups per hydrophilic group, and (B) an oily component that is liquid at 25 DEG C and has only one hydroxyl group; the viscosity of the active agent composition at 25 DEG C is less than 50% of the viscosity of the component (A).

Description

Technical Field

[0001] The present invention relates to an active agent composition and a cosmetic comprising the same. Background Art

[0002] Generally, nonionic surfactants used in cosmetics are surfactants having a hydrophilic group that does not dissociate into ions in the molecule. As the hydrophilic group, a polyoxyethylene chain or a polyol chain is generally used.

[0003] Nonionic surfactants having polyol chains, represented by glycerol, have been widely used as emulsifiers, solubilizers, etc. due to their excellent safety and functions. For example, Patent Document 1 discloses a low-viscosity emulsion-like W / O type emulsified cosmetic material having excellent feel in use and good stability over time. The emulsified cosmetic material is characterized by containing one or more polyglycerol fatty acid esters, glycerol, an oil base, and water.

[0004] In addition, it is known that silicone surfactants modified with glycerol or polyglycerol have excellent moisturizing properties (Patent Document 2). In addition, a technique for improving the stability of a formulation by improving the dispersibility of a powder by hydrophobic treatment is also known (Patent Document 3). A technique for improving the stability of a formulation by using a glycerol-modified silicone surfactant and trimethylsiloxysilicic acid in combination is also known (Patent Document 4).

[0005] However, nonionic surfactants such as glycerol, which use a polyol chain having two or more hydroxyl groups as a hydrophilic group, are difficult to handle due to increased viscosity, and there are limitations in the development of high molecular weight products.

[0006] Prior art literature

[0007] Patent Literature

[0008] Patent Document 1: Japanese Patent Application Laid-Open No. 6-128135

[0009] Patent Document 2: Japanese Patent Application Publication No. 2002-3334

[0010] Patent Document 3: Japanese Patent Application Publication No. 2013-035872

[0011] Patent Document 4: Japanese Patent Application Publication No. 2007-182402 Summary of the invention

[0012] Problems to be solved by the invention

[0013] The present invention has been made in view of the above-mentioned actual situation, and an object of the present invention is to provide an activator composition having a low viscosity and excellent handling properties, and a cosmetic containing the activator composition having a good feel during use.

[0014] Means for solving problems

[0015] The present inventors have conducted intensive studies to solve the above-mentioned problems and have found that the above-mentioned problems can be solved by adjusting the viscosity of an surfactant composition containing (A) a nonionic surfactant having two or more hydroxyl groups per one hydrophilic group and (B) an oil having one hydroxyl group at 25° C. to less than 50% of the viscosity of the component (A), thereby completing the present invention.

[0016] That is, the present invention provides the following active agent composition and cosmetic.

[0017] 1. An surfactant composition comprising: (A) a nonionic surfactant having two or more hydroxyl groups per hydrophilic group, and (B) an oily component having only one hydroxyl group and being liquid at 25°C, wherein the viscosity of the surfactant composition at 25°C is less than 50% of the viscosity of the component (A).

[0018] 2. The active agent composition according to 1, wherein the composition ratio of the component (A) to the component (B) is 70:30 to 95:5, expressed as a mass ratio, and the viscosity of the active agent composition at 25° C. is 100 to 50,000 mPa·s.

[0019] 3. The active agent composition according to 1 or 2, wherein the component (A) is polyglycerol-modified silicone.

[0020] 4. The active agent composition according to 3, wherein the component (A) is a linear or branched polyglycerol-modified silicone.

[0021] 5. The activator composition according to any one of 1 to 4, wherein the component (B) is at least one selected from aliphatic alcohols and ester oils.

[0022] 6. The active agent composition according to 5, wherein the component (B) is a branched aliphatic alcohol having 16 to 24 carbon atoms.

[0023] 7. The activating agent composition according to any one of 1 to 6, wherein the solubility of the component (B) in 100 g of purified water at 25°C is less than 1 g.

[0024] 8. A cosmetic comprising 0.1 to 40% by mass of the active agent composition according to any one of 1 to 7 based on the entire cosmetic.

[0025] 9. The cosmetic according to 8, which is a water-in-oil emulsified cosmetic.

[0026] Effects of the Invention

[0027] According to the present invention, it is possible to provide a surfactant composition having a reduced viscosity of a nonionic surfactant having two or more hydroxyl groups per one hydrophilic group and excellent in handling properties, and a cosmetic containing the same and having a good feel during use. DETAILED DESCRIPTION

[0028] The present invention is described in detail below. In the present invention, the ingredient name may be described as a cosmetic name or International Nomenclature of Cosmetic Ingredient (INCI). When the cosmetic name corresponds to INCI, the English description may be omitted.

[0029] [(A) ingredient]

[0030] The (A) component of the present invention is a nonionic surfactant having two or more hydroxyls relative to each hydrophilic group, and one kind can be used alone or two or more kinds can be used in combination. As the hydrophilic group of the (A) component, as long as it is a hydrophilic group generally used in nonionic surfactants, it is not limited. For example, hydrophilic groups of the structure of polyols including glycerol, trimethylolpropane, pentaerythritol, sorbitan, sorbitol, sucrose, polyglycerol, and cottonseed sugar can be listed. In addition, it can be a group formed by modifying a part of the hydroxyl groups possessed by these hydrophilic groups, or it can be a structure formed by combining one or more of these hydrophilic groups. Among these, in terms of emulsification, dispersibility, and moisture retention, it is preferred to have a hydrophilic group with a structure of glycerol or polyglycerol.

[0031] The number of hydroxyl groups in component (A) is two or more per hydrophilic group. The more hydroxyl groups there are, the more remarkable the effect of the present invention becomes. From the viewpoint of balance with the hydrophobic groups, the number is preferably 3 to 20, more preferably 3 to 15, and even more preferably 4 to 10.

[0032] As the component (A), for example, there can be mentioned fatty acid ester-based surfactants of polyhydric alcohols such as sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbitol fatty acid esters, glycerol fatty acid esters, polyoxyethylene glycerol fatty acid esters, and polyglycerol fatty acid esters, and silicone-based surfactants such as polyglycerol-modified silicone (organopolysiloxane). Among these, silicone-based surfactants are preferred, and polyglycerol-modified silicone is more preferred, because the effect of high viscosity due to the hydrophobic group is small and the effect of the present invention is significantly manifested.

[0033] Specific examples of the ester surfactant include polyglyceryl-2 isostearate, polyglyceryl-10 laurate, polyhydroxystearate, sorbitan stearate, and sorbitan sesquiisostearate.

[0034] As for the organosilicon surfactant, it can be straight-chain or branched. Specifically, partially cross-linked polyglycerol-modified organosilicon, straight-chain or branched polyglycerol-modified organopolysiloxane, and straight-chain or branched polyglycerol-alkyl co-modified organopolysiloxane can be listed. Among them, products with straight-chain or branched organopolysiloxane as the main skeleton and polyglycerol chains in the side chains, or products with straight-chain or branched organopolysiloxane as the main skeleton and polyglycerol chains and alkyl chains in the side chains can be used most preferably in terms of feel in use and emulsification performance.

[0035] Examples of partially cross-linked polyglyceryl-modified silicone include (dimethicone / polyglyceryl-3) crosspolymer (INCI), (lauryl dimethicone / polyglyceryl-3) crosspolymer (INCI), and (polyglyceryl-3 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI). The partially cross-linked polyglyceryl-modified silicone may be a composition comprising the partially cross-linked polyglyceryl-modified silicone and an oil that is liquid at room temperature. Examples of the liquid oil include cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), triethylhexanoin (INCI), and squalane (INCI).

[0036] Examples of commercially available partially cross-linked polyglycerol-modified silicones swollen with a liquid oil include KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, and KSG-850Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0037] As the linear or branched polyglyceryl-modified organopolysiloxane, the linear or branched polyglyceryl-alkyl co-modified organopolysiloxane, specifically, polyglyceryl-3 disiloxane dimethyl polysiloxane (INCI), polyglyceryl-3 polydimethylsiloxyethyl dimethyl polysiloxane (INCI), lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethyl polysiloxane (INCI), bisbutyl dimethicone polyglyceryl-3 (INCI), etc. can be cited. As examples of commercially available products, Shin-Etsu Chemical Co., Ltd.: KF-6100, KF-6104, KF-6105, KF-6106, KF-6115, etc. can be cited. The partially cross-linked polyglyceryl-modified silicone has a viscosity-increasing effect due to the cross-linked part in its structure, so the viscosity-reducing effect of the component (B) of the present invention is not significant. As the polyglyceryl-modified silicone, a linear or branched one is preferred.

[0038] The viscosity of the component (A) at 25°C is preferably selected from the range of 100 to 500,000 mPa·s, more preferably 1,000 to 400,000 mPa·s, and further preferably 3,000 to 50,000 mPa·s. According to the present invention, even a component (A) having such a viscosity can have a lower viscosity. It should be noted that in the present invention, the viscosity is a value at 25°C measured by the method using a B-type rotational viscometer described in JIS K7117-1:1999 (the same below).

[0039] [(B) ingredient]

[0040] The component (B) of the present invention is an oily component having one hydroxyl group and being liquid at 25°C. Among them, components having a solubility of less than 1 g in 100 g of purified water at 25°C are preferred. Regardless of the number of hydroxyl groups in the component (A), the component (B) does not contain an oily agent having no hydroxyl group or an oily agent having two or more hydroxyl groups. In addition, the component (B) does not contain a low alcohol having 1 to 5 carbon atoms which has high hydrophilicity and may have poor affinity with the oil layer.

[0041] As the component (B), for example, higher alcohols, higher fatty acids and ester oils that are liquid at 25° C. are listed. Among these, higher alcohols such as aliphatic alcohols and ester oils are preferred, and branched aliphatic alcohols having 16 to 24 carbon atoms are most preferred in terms of feel during use and low viscosity. These can be used alone or in combination of two or more.

[0042] Examples of the higher alcohol include alcohols having 6 or more carbon atoms, preferably 16 to 24 carbon atoms, more preferably 16 to 20 carbon atoms, and particularly preferably 16 to 18 carbon atoms in terms of compatibility with the component (A) and feel during use. Specific examples of the higher alcohol include lauryl alcohol (INCI), hexyldecanol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), decyltetradecyl alcohol (INCI), and the like.

[0043] Examples of higher fatty acids include fatty acids having 6 or more carbon atoms, preferably 16 to 24 carbon atoms, and more preferably 16 to 20 carbon atoms. Examples thereof include oleic acid (INCI: Oleic Acid), linoleic acid (INCI: Linoleic Acid), linolenic acid (INCI: Linolenic Acid), arachidonic acid (INCI: Arachidonic Acid), eicosapentaenoic acid (INCI: Eicosapentaenoic Acid), docosahexaenoic acid (INCI: Docosahexaenoic Acid), and isostearic acid (INCI: Isostearic Acid).

[0044] Examples of the ester oil include diisostearyl malate (INCI: Diisostearyl Malate), triethyl citrate (INCI: Triethyl Citrate), cetyl lactate (INCI: Cetyl Lactate), myristyl lactate (INCI: Myristyl Lactate), cholesteryl hydroxystearate (INCI: Cholesteryl Hydroxystearate), coconut fatty acid BG (INCI: Butylene Glycol Cocoate), polyglyceryl-2 triisostearate (INCI: Polyglyceryl-2 Triisostearate), homosalate (INCI), and ethylhexyl salicylate (INCI: Ethylhexyl Salicylate).

[0045] In the present invention, the viscosity of component (A) is further reduced by combining component (A) with component (B), and the viscosity of component (B) at 25° C. itself is not limited as long as it is liquid at 25° C. For example, it is preferably selected from the range of 1 to 3000 mPa·s, more preferably 5 to 400 mPa·s, and even more preferably 30 to 60 mPa·s.

[0046] The composition ratio of component (A) to component (B) is expressed as a mass ratio, preferably in the range of 70:30 to 95:5, more preferably 80:20 to 98:2, and further preferably 85:15 to 95:5. When the total is set to 100, when the mass ratio of (A) exceeds 95, the viscosity is sometimes not sufficiently low, and when the mass ratio of (B) exceeds 30, the function of the sufficient activator is sometimes not obtained. In the activator composition, the total amount of component (A) and component (B) can also be 15% by mass or more, but is preferably 90% by mass or more, more preferably 95% by mass or more, further preferably 99% by mass or more, and particularly preferably 100% by mass. By making the total amount of component (A) and component (B) 90% by mass or more, the miscibility (easy weighing) in the oil phase during the preparation of the cosmetic is further improved. Furthermore, the active agent composition of the present invention is prepared by mixing the components (A) and (B) in advance and compounding them according to the cosmetic formulation, and by making the active agent with low viscosity and excellent handling properties, it is easy to weigh and put in. Therefore, it is not unintentionally mixed in the formulation.

[0047] The components other than the components (A) and (B) in the active agent composition are components generally blended in cosmetics, and are not particularly limited as long as they are components and their amounts that can achieve a predetermined viscosity range. Examples thereof include surfactants other than the component (A), such as polyether-modified silicones, pyrrolidonecarboxylic acid-modified silicones, and ionic surfactants, and oils other than the component (B), such as silicone oils, hydrocarbon oils, and ester oils, aqueous components, powders, and the like.

[0048] The viscosity of the mixture and the activator composition obtained by mixing the components (A) and (B) at 25°C is less than 50% of the viscosity of the component (A), preferably less than 40%, more preferably less than 30%, and further preferably less than 25%. In the present invention, since the viscosity of the component (A) can be further reduced, the viscosity of the mixture and the activator composition at 25°C is preferably 100 to 50,000 mPa·s, more preferably 500 to 15,000 mPa·s, and further preferably 500 to 5,000 mPa·s. If it is such a viscosity, it is easy to handle, and it is easy to weigh and mix. Furthermore, as mentioned above, the viscosity is a value at 25°C measured by the method using a B-type rotational viscometer described in JIS K7117-1:1999.

[0049] Furthermore, the active agent composition of the present invention is preferably a composition that can be mixed uniformly. Specifically, it is a composition that does not separate at 25°C after mixing, and a turbid composition is not preferred. A semi-transparent dissolving composition is preferred, and a transparent dissolving composition is further preferred from the perspective of quality management. Furthermore, with regard to transparency, when the total light transmittance measured by the method described in JIS K7361-1:1997 when filled in a cell with a thickness of 1 cm is 50% or more, it is judged as semi-transparent, and when it is 80% or more, it is judged as transparent. Furthermore, from the viewpoint of transparency, a combination of polyglyceryl-3 polydimethylsiloxyethyl dimethyl polysiloxane as the component (A) and a higher alcohol having 16 to 18 carbon atoms as the component (B), a combination of lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethyl polysiloxane as the component (A) and a higher alcohol having 16 to 24 carbon atoms as the component (B), a combination of polyglyceryl-3 disiloxane dimethyl polysiloxane as the component (A) and a higher alcohol having 16 to 18 carbon atoms as the component (B), and a combination of polyglyceryl-10 laurate as the component (A) and a higher alcohol having 16 to 18 carbon atoms as the component (B).

[0050] The active agent composition of the present invention can be obtained by mixing the above-mentioned components (A) and (B), and optional components. As optional components, the components exemplified in the following cosmetics can be mentioned, and they can be blended in appropriate amounts.

[0051] [Cosmetics]

[0052] The activator composition of the present invention can be used in various applications, and can be particularly used as a raw material for all cosmetics for external use on skin and hair. The cosmetics mixed with the activator composition have a good feel for use. The cosmetics of the present invention can be obtained by mixing the pre-prepared activator composition in the cosmetics. In this case, the amount of the activator composition is preferably in the range of 0.1 to 40% by mass of the total cosmetics, and in particular, as an emulsifier when making an emulsion, it is preferably 0.1 to 8% by mass of the total cosmetics, and more preferably 0.1 to 5% by mass. When converted to the total amount of component (A) and component (B), it is preferably 0.1 to 8% by mass of the total cosmetics, and more preferably 0.1 to 5% by mass.

[0053] The cosmetic containing the active agent composition of the present invention may be in the form of any of powder, oily liquid, water-in-oil emulsified cosmetic (W / O), oil-in-water emulsified cosmetic (O / W), non-aqueous cosmetic, W / O / W type, O / W / O type multiple emulsions, etc. In particular, when used as an active agent for a water-in-oil emulsified cosmetic, the viscosity is reduced, the emulsification efficiency is improved, and a stable cosmetic is obtained.

[0054] The cosmetic of the present invention may contain various optional components that are usually used in cosmetics.

[0055] <Other optional ingredients>

[0056] Other optional components include, for example, (1) oils other than component (B), (2) aqueous components, (3) surfactants other than component (A), (4) powders, (5) a composition of a crosslinked organopolysiloxane and an oil that is liquid at room temperature, (6) a film-forming agent, (7) an ultraviolet light absorbing and scattering agent, and (8) other additives. These can be used alone or in combination of two or more, and each can be blended in an appropriate amount.

[0057] (1) Oils other than component (B)

[0058] The cosmetic of the present invention may contain an oily agent other than the component (B). The oily agent may be volatile or non-volatile, and may be solid, semi-solid, or liquid at room temperature (25° C.), and examples thereof include silicone oil, silicone wax, natural animal and plant oils and semi-synthetic oils, hydrocarbon oils, higher alcohols, fatty acids, ester oils, fluorine-based oils, and ultraviolet absorbers.

[0059] Silicone oil

[0060] Examples of the silicone oil include alkyl-modified silicones such as dimethylpolysiloxane (INCI), trisiloxane (INCI), methyltrimethicone (INCI), ethyltrisiloxane (INCI), ethylmethylpolysiloxane (INCI), and hexyldimethicone (INCI), long-chain alkyl-modified silicones such as octylmethylpolysiloxane (INCI), phenyltrimethicone (INCI), diphenyldimethicone (INCI), diphenylsiloxyphenyltrimethicone (INCI), tetraphenyldimethyldisiloxane (INCI), and methylhydrogenpolysiloxane, and linear or branched organopolysiloxanes of low to high viscosity such as cyclotetrasiloxane (INCI). , cyclic organopolysiloxanes such as cyclopentasiloxane (INCI) and cyclohexasiloxane (INCI), amino-modified organopolysiloxanes such as amodimethylpolysiloxane (INCI) and aminopropyl dimethylpolysiloxane (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethylpolysiloxane (INCI), pyrrolidone carboxylic acid-modified organopolysiloxane, high-polymerization gum-like dimethylpolysiloxane, gum-like amino-modified organopolysiloxane or silicone rubber such as dimethylsiloxane-methylphenylsiloxane copolymer, and low-viscosity organopolysiloxane solutions of silicone gum or silicone rubber, amino acid-modified silicone, fluorine-modified silicone, silicone resin and silicone resin dissolution, etc.

[0061] Examples of commercially available silicone oils include KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-96A-6cs, KF-4422, KF-54, KF-54HV, KF-56A, and KF-995 manufactured by Shin-Etsu Chemical Co., Ltd.

[0062] Solid oily ingredients

[0063] In the present invention, when it is desired to solidify the cosmetic, it is preferred to mix an oily component that is solid at 25° C. Examples of the oily component that is solid at 25° C. include waxes, hydrocarbons, esters, higher alcohols, and higher fatty acids having a melting point of preferably 40° C. or higher, more preferably 60 to 110° C., and are not particularly limited as long as they are raw materials that can be generally mixed in cosmetics. Specific examples include carnauba wax (indicative name (INCI: Copernicia Cerifera (Carnauba) Wax), sugar cane wax, candelilla wax (INCI: Euphorbia Cerifera (Candelilla) Wax), purified candelilla wax, rice wax, wood wax, jojoba wax, kapok wax, rice bran wax, bayberry wax, shea butter, cocoa butter, sumac wax (INCI: Rhus Succedanea Fruit Wax), montan wax (INCI: Montan Wax), vegetable waxes such as hydrogenated castor oil isostearate, beeswax, beef tallow, beef bone fat, pig fat (INCI: Lard), horse fat (INCI: Horse fat), and the like. Fat), lanolin, wool fat (INCI: Lanolin), animal wax such as wormwood wax, shellac wax, spermaceti, semi-synthetic wax such as lanolin ester, lanolin fatty acid ester, beeswax acid ester, hardened oil such as hardened castor oil and hardened coconut oil, paraffin wax, polyethylene, ceresin, ceresin, microcrystalline wax and other hydrocarbon waxes, wax esters such as synthetic beeswax, amino acid stearyl alcohol such as dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, fatty acids such as stearic acid and behenic acid, and silicone wax such as acrylic silicone resin of acrylic acid-silicone graft or block copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.: acrylic acid-silicone graft copolymer: KP-561P, 562P, etc.), or derivatives thereof, preferably one or more selected from these.

[0064] Natural animal and plant oils and semi-synthetic oils

[0065] Examples of the natural plant and animal oils and semi-synthetic oils include avocado oil (INCI: Persea Gratissima (Avocado) Oil), linseed oil (INCI: Linum Usitatissimum (Linseed) Seed Oil), almond oil (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil), perilla oil (INCI), olive oil (INCI: Olea Europaea (Olive) Fruit Oil), torreya californica oil (INCI: Torreya Californica (California Nutmeg) Oil), citronella oil (INCI: Cymbopogon Nardus (Citronella) Oil), torreya seed oil (INCI: Torreya Nucifera Seed Oil), almond oil (INCI: Kyounin Yu)), wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), sesame oil (INCI: Sesamum Indicum (Sesame) Seed Oil), wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), rice germ oil (INCI: Oryza Sativa (Rice) Germ Oil), rice bran oil (INCI: Oryza Sativa (Rice) Bran Oil), camellia oil (INCI: Camellia Kissi Seed Oil), safflower oil (INCI: Carthamus Tinctorius (Safflower) Seed Oil), soybean oil (INCI: Glycine Soja (Soybean) Oil), tea seed oil (INCI: Camellia Sinensis Seed Oil), camellia oil (INCI: Camellia Japonica Seed Oil)), Evening Primrose Oil (INCI: Oenothera Biennis (Evening Primrose) Oil)), Rapeseed Oil (INCI: Corn Germ Oil)Mays (Corn) Germ Oil)), wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil)), peach kernel oil (INCI: Elaeis Guineensis (Palm) Oil), palm kernel oil (INCI: Elaeis Guineensis (Palm) Kernel Oil)), castor oil (INCI: Ricinus Communis (Castor) Seed Oil)), sunflower seed oil (INCI: Helianthus Annuus (Sunflower) Seed Oil)), grape seed oil (INCI: Vitis Vinifera (Grape) Seed Oil)), jojoba seed oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil)), macadamia seed oil (INCI: Macadamia Ternifolia Including natural plant oils such as Limnanthes Alba (Meadowfoam) Seed Oil, Cottonseed Oil (INCI: Gossypium Herbaceum (Cotton) Seed Oil), Coconut Oil (INCI: Cocos Nucifera (Coconut) Oil), Peanut Oil (INCI: Arachis Hypogaea (Peanut) Oil), shark liver oil (INCI: Shark Liver Oil), cod liver oil (INCI: Cod Liver Oil), cod liver oil (INCI: Fish Liver Oil), turtle oil (INCI: Turtle Oil), mink oil (INCI: Mink Oil), egg yolk oil (INCI: Egg Oil), hydrogenated coconut oil (INCI: Hydrogenated Coconut Oil)), liquid lanolin (indicative name (INCI: Lanolin Oil)) and other semi-synthetic oils and fats.

[0066] Hydrocarbon oil

[0067] Examples of the hydrocarbon oil include linear or branched hydrocarbon oils, and may be volatile or nonvolatile.

[0068] Specific examples include olefin oligomers (INCI), isoparaffins such as (C13, 14) isoparaffin (INCI), isododecane (INCI), undecane (INCI), dodecane (INCI), isohexadecane (INCI), hydrogenated polyisobutene (INCI: Hydrogenated Polyisobutene), squalane (INCI), mineral oil (INCI), coconut alkane (INCI), (C13-15) alkane (INCI), and petrolatum (INCI: Petrolatum).

[0069] Higher fatty acids

[0070] Examples of higher fatty acids include hydroxystearic acid (indicative name (INCI: Hydroxystearic Acid)).

[0071] ·Higher alcohols

[0072] Examples of higher alcohols include straight-chain saturated alcohols having 6 or more carbon atoms such as myristyl alcohol (INCI), cetyl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), and batyl alcohol (INCI). In addition, examples include sterols such as cholesterol (INCI), sitosterol (INCI: Beta-Sitosterol), phytosterol (INCI), and lanosterol (INCI).

[0073] ·Ester oil

[0074] Examples of the ester oil include diisobutyl adipate (indicative name (INCI: Diisobutyl Adipate)), dihexyldecyl adipate (indicative name (INCI: Diheptylundecyl Adipate)), isostearyl isostearate (indicative name (INCI: Isostearyl Isostearate)), isocetyl isostearate (indicative name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (indicative name (INCI: Trimethylolpropane Triisostearate)), glycol diethylhexanoate (indicative name (INCI: Glycol Diethylhexanoate), Cetyl Ethylhexanoate (INCI: CetylEthylhexanoate), Trimethylolpropane Triethylhexanoate (INCI: TrimethylolpropaneTriethylhexanoate), PentaerythritylTetraethylhexanoate (INCI: PentaerythritylTetraethylhexanoate), Cetyl Caprylate (INCI: Cetyl Ethylhexanoate), Octyldodecyl Stearoyl Stearate (INCI: Octyldodecyl Stearoyl Stearate), Oleyl Oleate (INCI: Oleyl Oleate), Octyldodecyl Oleate (INCI: Octyldodecyl Oleate), Decyl Oleate (INCI: Decyl Oleate), Neopentyl Glycol Dioctanoate (INCI: Neopentyl Glycol Diethylhexanoate), Neopentyl Glycol Dicaprate (INCI: Neopentyl Glycol Dicaprate), Diethylhexyl Succinate (INCI: Diethylhexyl Succinate), Amyl Acetate (INCI: Amyl Acetate), Ethyl Acetate (INCI: Etyl Acetate), Butyl Acetate (INCI: Butyl Aceetate), Isocetyl Stearate (INCI: IsocetylStearate), butyl stearate (INCI: ButylStearate), diisopropyl sebacate (INCI: Diisopropyl Sebacate), diethylhexyl sebacate (INCI: Diethylhexyl Sebacate), isononyl isononanoate (INCI: IsononylIsononanoate), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), isopropyl palmitate (INCI: Isopropyl Palmitate), ethylhexyl palmitate (INCI: Ethylhexyl Isopalmitate), hexyldecyl palmitate (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate), palmitate, isopropyl myristate (INCI: IsopropylMyristate), octyldodecyl myristate (INCI: Octyldodecyl Myristate), myristyl myristate (INCI: Myristyl Myristate), ethylhexyl laurate (INCI: Ethylhexyl Laurate), hexyl laurate (INCI: Hexyl Laurate), dioctyldodecyl lauroyl glutamate (INCI: Dioctyldodecyl LauroylGlutamate), isopropyl lauroyl sarcosinate (INCI: Isopropyl LauroylSarcosinate), (caprylic / capric) coconut oil alkyl esters (INCI: Coco-Caprylate·Caprate).

[0075] Among the ester oils, examples of the glyceride oil include triisooctanoin (INCI), tri(caprylic / capric)glyceride (INCI: Caprylic / Capric Triglyceride), and tri(caprylic / capric / succinic)glyceride (INCI: Caprylic / Capric / Succinic Triglyceride).

[0076] Fluorine oil

[0077] Examples of the fluorine-based oil include perfluorodecahydronaphthalene (INCI), perfluorononyldimethylpolysiloxane (INCI), and perfluoromethylcyclopentane (INCI).

[0078] UV absorber

[0079] Examples of the ultraviolet absorber include octocrylene (INCI), t-butyl methoxydibenzoylmethane (INCI: Butyl Methoxydibenzoylmethane), diethylamino hydroxybenzoyl hexyl benzoate (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate), oxybenzone-6 (INCI: Benzophenone-6), oxybenzone-9 (INCI: Benzophenone-9), oxybenzone-1 (INCI: Benzophenone-1), polysilicone-15 (INCI), octyl dimethoxybenzylidene dioxoimidazolidine propionate (INCI: Ethylhexyl Dimethoxybenzylidene =DioxoimidazolidinePropionate), Oxybenzone-2 (Indicative Name (INCI: Benzophenone-2)), Terephthalylidene Dicamphor Sulfonic Acid (Indicative Name (INCI: Terephthalylidene Dicamphor Sulfonic Acid)), Ethylhexyl Triazone (INCI), Isopentyl Trimethoxycinnamate Trisiloxane (Indicative Name (INCI: Isopentyl Trimethoxycinnamate Trisiloxane)), Drometrizole Trisiloxane (INCI), Ethylhexyl Dimethyl PABA (Indicative Name (INCI: Ethylhexyl Dimethyl PABA)), Isopropyl Methoxycinnamate (Indicative Name (INCI: Isopropyl Methoxycinnamate)), Ethylhexyl Methoxycinnamate (Indicative Name (INCI: Ethylhexyl Methoxycinnamate)), Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (Indicative Name (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine), Oxybenzophenone-3 (Indicative name (INCI: Benzophenone-3)), Oxybenzophenone-4 (Indicative name (INCI: Benzophenone-4)), Oxybenzophenone-5 (Indicative name (INCI: Benzophenone-5)), Phenylbenzimidazole Sulfonic Acid (Indicative name (INCI: PhenylbenzimidazoleSulfonic Acid)), Methylene Bisbenzotriazolyl Tetramethylbutylphenol (Indicative name (INCI: MethyleneBis-Benzotriazolyl Tetramethylbutylphenol), Glyceryl Ethylhexanoate Dimethoxycinnamate (INCI: Glyceryl Ethylhexanoate Dimethoxycinnamate), Glyceryl PABA (INCI: Glyceryl PABA), Methyl Diisopropyl Cinnamate (INCI: Diisopropyl MethylCinnamate), Cinoxate (INCI), Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), etc. In addition, a UVA absorber (for example, diethylaminohydroxybenzoyl hexyl benzoate (INCI: DiethylaminoHydroxybenzoyl Hexyl Benzoate)) and a UVB absorber (for example, ethylhexyl methoxycinnamate (INCI: Ethylhexyl Methoxycinnamate)) may be used together, or they may be arbitrarily combined.

[0080] (2) Water-based ingredients

[0081] The aqueous component is not particularly limited as long as it is an aqueous component that can be generally mixed in cosmetics. Specifically, water, lower alcohols preferably having 2 to 5 carbon atoms such as ethanol (INCI: Alcohol) and isopropyl alcohol (INCI: Isopropyl Alcohol), and sugar alcohols such as sorbitol (INCI), maltose (INCI), and xylitol (INCI) are listed. In addition, polyols such as BG (INCI: Butylene Glycol), PG (INCI: Propylene Glycol), DPG (INCI: Dipropylene Glycol), pentylene glycol (INCI), 1,10-decanediol (INCI), caprylyl glycol (INCI), 1,2-hexanediol (INCI), erythritol (INCI), glycerin (INCI), diglycerin (INCI), and polyethylene glycol; glucose (INCI), glyceryl glucoside (INCI), betaine (INCI), chondroitin sulfate sodium (INCI: Sodium Chondroitin Sulfate), PCA-Na (INCI: Sodium PCA)), Methyl Gluceth-10 (INCI), Methyl Gluceth-20 (INCI), Hyaluronic Acid, Egg Yolk Lecithin, Soy Lecithin, Phosphatidylcholine, Phosphatidylethanolamine, Phosphatidylserine, Phosphatidylglycerol, Phosphatidylinositol, Sphingolipids and other moisturizers.

[0082] (3) Surfactants other than component (A)

[0083] As surfactants, there are nonionic, anionic, cationic and amphoteric active agents. As long as they are surfactants other than the above-mentioned (A) component, there is no particular limitation, and any surfactant used in common cosmetics can be used. Among these surfactants, preferably partially cross-linked polyether-modified silicone, linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxane, linear or branched polyoxyethylene-alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene-polyoxypropylene-alkyl co-modified organopolysiloxane. Among these surfactants, preferably the content of hydrophilic polyoxyethylene and polyoxyethylene-polyoxypropylene groups accounts for 10 to 70% by mass in the molecule.

[0084] Examples of the partially cross-linked polyether-modified silicone include (dimethicone / (PEG-10 / 15)) crosspolymer (INCI), (PEG-15 / lauryl dimethicone) crosspolymer (INCI), (PEG-10 / lauryl dimethicone) crosspolymer (INCI), and (PEG-15 / lauryl dimethylsiloxyethyl dimethicone) crosspolymer (INCI). In addition, when a partially cross-linked polyether-modified silicone is used, preferably, in a composition composed of the cross-linked organopolysiloxane and an oil agent that is liquid at room temperature, the cross-linked organopolysiloxane swells with respect to the liquid oil including at least its own weight of the liquid oil agent.

[0085] As the liquid oil, liquid silicone oils, hydrocarbon oils, ester oils, natural plant and animal oils, semi-synthetic oils, and fluorine-based oils listed in the above-mentioned component (B) or the oils other than the above-mentioned component (1) (B) can be used, and examples thereof include cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: isotridecyl isononanoate), squalane (INCI), and the like. Examples of commercially available crosslinked organopolysiloxanes that swell by containing a liquid oil include KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, and KSG-350Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0086] Examples of surfactants other than crosslinked organopolysiloxanes include PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxyethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxyethyl dimethicone (INCI), and cetyl PEG / PPG-10 / 1 dimethicone (INCI). Examples of commercially available products include KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, and KF-6048 manufactured by Shin-Etsu Chemical Co., Ltd.

[0087] In all cases, the amount of surfactant blended is preferably 0.1 to 20% by mass of the total cosmetic material together with component (A). If it is 0.1% by mass or more, the dispersion and emulsification functions can be fully exerted, and if it is 20% by mass or less, there is no need to worry about the cosmetic material becoming sticky, so it is preferred. There is no limitation on the HLB of the surfactant, but from the purpose of maintaining the water resistance of the cosmetic material, it is preferably 2 to 14.5.

[0088] (4) Powder

[0089] Examples of the powder include coloring pigments, inorganic powders, metal powders, organic powders, inorganic-organic composite powders, etc. The specific examples are as follows.

[0090] Coloring Pigments

[0091] The coloring pigment is not particularly limited as long as it is a pigment used for coloring cosmetics, and includes red iron oxide (indicative name (INCI: Iron Oxides)), yellow iron oxide (indicative name (INCI: Iron Oxides)), white titanium oxide (indicative name (INCI: Titanium Dioxide)), black iron oxide (indicative name (INCI: Iron Oxides)), ultramarine (indicative name (INCI: Ultramarines)), cyan (indicative name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (indicative name (INCI: Manganese Violet)), cobalt titanate (indicative name (INCI: Cobalt Titanium Oxide)), chromium hydroxide (indicative name (INCI: Chromium HydroxideGreen)), chromium oxide (indicative name (INCI: Chromium OxideGreens)), (aluminum / cobalt) oxide (indicative name (INCI: Cobalt Aluminum Inorganic brown pigments such as titanium nitride (INCI: Titanium Nitride), ferrous hydroxide (INCI: Iron Hydroxide), γ-iron oxide, and the like, inorganic yellow pigments such as loess, and colored pigments such as products obtained by laking tar pigments and products obtained by laking natural pigments can be used.

[0092] The shape of the pigment may be any shape, such as spherical, substantially spherical, rod-shaped, spindle-shaped, petal-shaped, elongated, or irregular, and the geometrical form is not particularly limited as long as it can impart color to the cosmetic.

[0093] Inorganic powder

[0094] Examples of the inorganic powder include zirconium oxide (INCI: Zirconium Dioxide), zinc oxide (INCI: Zinc Oxide), cerium oxide (INCI: Cerium Oxide), magnesium oxide (INCI: Magnesium Oxide), Ba sulfate (INCI: Barium Sulfate), calcium sulfate (INCI: Calcium Carbonate), Mg sulfate (INCI: Magnesium Sulfate), Ca carbonate (INCI: Calcium Carbonate), Mg carbonate (INCI: Magnesium Carbonate), talc (INCI), mica (INCI), kaolin (INCI), synthetic fluorphlogopite (INCI: Synthetic Fluorphlogopite), synthetic phlogopite iron (INCI), biotite (INCI: Biotite), potassium silicate (INCI: Potassium Silicate), Silica (INCI), Aluminum Silicate (Indicative Name (INCI: Aluminum Silicate)), Magnesium Silicate (Indicative Name (INCI: Magnesium Silicate)), Silicic Acid (Aluminum / Magnesium) (Indicative Name (INCI: Magnesium Aluminum Silicate)), Calcium Silicate (Indicative Name (INCI: Calcium Silicate)), Silicic Acid (Aluminum / Calcium / Sodium) (Indicative Name (INCI: Aluminum Calcium Sodium Silicate)), Silicic Acid (Lithium / Magnesium / Sodium) (Indicative Name (INCI: Lithium Magnesium Sodium Silicate)), Silicic Acid (Sodium / Magnesium) (Indicative Name (INCI: Sodium Magnesium Silicate)), Borosilicate (Calcium / Aluminum) (Indicative Name (INCI: Calcium Aluminum Borosilicate)), Borosilicate (Calcium / Sodium) (Indicative Name (INCI: CalciumSodium Borosilicate), hydroxyapatite (INCI), bentonite (INCI), montmorillonite (INCI), hectorite (INCI), zeolite (INCI), alumina (INCI), aluminum hydroxide (INCI: Aluminum Hydroxide), boron nitride (INCI: BoronNitride)), glass (indicative name (INCI: Glass)), etc.

[0095] Inorganic colored pearl pigments include pearlescent agents such as mica (INCI) coated with titanium oxide (INCI: Titanium Dioxide), synthetic fluorphlogopite (INCI: Synthetic Fluorphlogopite) coated with titanium oxide (INCI: Titanium Dioxide), bismuth oxychloride (INCI: Bismuth Oxychloride), bismuth oxychloride (INCI: Bismuth Oxychloride) coated with titanium oxide (INCI: Titanium Dioxide), talc (INCI) coated with titanium oxide (INCI: Titanium Dioxide), fish scale foil (INCI), and colored mica coated with titanium oxide (INCI: Titanium Dioxide). The pigment may be untreated or may be subjected to a known surface treatment generally used in cosmetics, and is not particularly limited.

[0096] Metal powder

[0097] Examples of the metal powder include metal fine particles made of aluminum (INCI: Aluminum, Aluminum Powder), copper (INCI: Copper Powder), silver (INCI: Silver Powder), and gold (INCI: Gold).

[0098] Organic powder

[0099] Examples of the organic powder include powders composed of silicone, polyamide, polyacrylic acid-acrylate, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene-acrylic acid copolymer, divinylbenzene-styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate, cellulose (INCI), silk (INCI), nylon (indicative name), phenolic resin, epoxy resin, polycarbonate, and the like.

[0100] In particular, examples of silicone include silicone resin particles; polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder; (vinyl dimethicone / methylpolysiloxane silsesquioxane) crosspolymer (indicative name (INCI: vinyl dimethicone / methicone silsesquioxane crosspolymer)), (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (indicative name (INCI: diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer)), polysilicone-1 crosspolymer (INCI), polysilicone-22 (INCI), and the like. Examples of commercially available powders made of silicone include KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-300, KSP-411, KSP-441, KM-9729, and KM-440 manufactured by Shin-Etsu Chemical Co., Ltd.

[0101] In addition, metal soaps and the like can also be mentioned. Specific examples include powders consisting of zinc stearate (indicative name (INCI: Zinc Stearate)), aluminum stearate (indicative name (INCI: Aluminum Stearate)), calcium stearate (indicative name (INCI: Calcium Stearate)), magnesium stearate (indicative name (INCI: Magnesium Stearate)), zinc myristate (indicative name (INCI: Zinc Myristate)), magnesium myristate (indicative name (INCI: Magnesium Myristate)), cetyl phosphate (zinc / sodium) (indicative name (INCI: Sodium Zinc Cetyl Phosphate)), and potassium cetyl phosphate (indicative name (INCI: Potassium Cetyl Phosphate)).

[0102] Furthermore, organic pigments can also be mentioned. Specific examples include Red 3, Red 104 (1) (indicative name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (indicative name (INCI: Red 6)), Red 202 (indicative name (INCI: Red 7)), Red 204, Red 205, Red 220 (indicative name (INCI: Red 34)), Red 226 (indicative name (INCI: Red 30)), Red 227 (indicative name (INCI: Red 33, RED 33 Lake)), Red 228 (indicative name (INCI: Red 36)), Red 230 (1) (indicative name (INCI: Red 22, Red 22 Lake)), Red 230 (2) (indicative name), Red 401 (indicative name), Red 505 (indicative name), Yellow 4 (indicative name (INCI: Yellow 5 5)), Yellow 5 (Indication Name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202 (1) (Indication Name (INCI: Yellow 8)), Yellow 203 (Indication Name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (Indication Name (INCI: Yellow 11)), Yellow 401, Blue 1 (Indication Name (INCI: Blue 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (Indication Name (INCI: Blue 4)), Blue 404 (Indication Name), Green 3 (Indication Name (INCI: Green 3, Green 3 Lake)), Green 201 (Indication Name (INCI: Green 5)), Green 202 (Indication Name (INCI: Green 6)), Green 204 (Indication Name (INCI: Green 8)), Green 205 (Indication Name), Orange 201 (Indication Name (INCI: Orange 5)), Orange 203 (Indicative name (INCI: PigmentOrange 5)), Orange 204 (Indicative name), Orange 205 (Indicative name (INCI: Orange 4, Orange 4Lake)), Orange 206 (Indicative name (INCI: Orange 10)), Orange 207 (Indicative name (INCI: Orange 11)), etc., tar pigments, cochineal (INCI), lac acid (Indicative name (INCI: Laccaic Acid)), safflower (Indicative name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), ginkgo root extract (Indicative name (INCI: Lithospermum OfficinaleRoot Extract)), Gardenia Yellow (indicated name), Gardenia Blue (indicated name (INCI: Hydrolyzed Gardenia Florida Extract)) and other natural pigments.

[0103] Inorganic-organic composite powder

[0104] Examples of the inorganic-organic composite powder include composite powders obtained by coating the surface of an inorganic powder with an organic powder by a known and commonly used method.

[0105] Furthermore, the above-mentioned powder can also be used as a product in which the particle surface is treated. In addition, the surface treatment agent is preferably capable of imparting hydrophobicity from the viewpoint of water resistance of the cosmetic material, and the treatment agent imparting hydrophobicity is not particularly limited, and examples thereof include silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyl and phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate and magnesium myristate.

[0106] More preferred are silicone treatment agents, and examples thereof include silanes or silanizing agents such as triethoxycaprylylsilane (INCI), dimethylpolysiloxane (INCI), methylpolysiloxane (INCI), hydrogendimethylpolysiloxane (INCI), triethoxysilylethyl polydimethylsiloxyethyl dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (INCI), and (Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / DimethiconeMethacrylate) Copolymer (Indicative name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / DimethiconeMethacrylate Copolymer).

[0107] Specific examples of these silicone treatment agents include AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574, and KP-541 manufactured by Shin-Etsu Chemical Co., Ltd.

[0108] Furthermore, the above-mentioned surface hydrophobizing agent can be used alone or in combination of two or more. As a specific example of the coloring pigment implemented with surface treatment, Shin-Etsu Chemical Industry (Strain) system: KTP-09 series, especially KTP-09W, KTP-09R, KTP-09Y, KTP-09B, etc. can be listed.

[0109] (5) Composition consisting of a cross-linked organopolysiloxane and an oil agent that is liquid at room temperature

[0110] In the composition composed of the crosslinked organopolysiloxane and the oil agent that is liquid at room temperature, the crosslinked organopolysiloxane preferably swells with respect to the liquid oil by containing the liquid oil agent in an amount greater than its own weight. The liquid oil agent may be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal and plant oil, semi-synthetic oil, or fluorine-based oil in the component (B) or the optional component (1) oil agent, for example, cyclopentasiloxane (INCI), dimethyl polysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), squalane (INCI), and the like.

[0111] The component (5) is different from the component (A) and the component (3) described above, and is a compound that does not have a polyether or polyglycerol structure in its molecular structure. Specific examples thereof include (dimethicone / vinyl dimethicone) crosspolymer (INCI), (dimethicone / phenyl vinyl dimethicone) crosspolymer (INCI), (vinyl dimethicone / lauryl dimethicone) crosspolymer (INCI), and (lauryl dimethylsiloxyethyl dimethicone / bisvinyl dimethicone) crosspolymer (INCI). Examples of commercially available compositions consisting of a cross-linked organopolysiloxane and an oil that is liquid at room temperature include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-042Z, KSG-045Z, and KSG-048Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0112] (6) Film-forming agent

[0113] The film-forming agent is mainly added to further maintain the effect of the cosmetic material. Although not particularly limited, from the viewpoint of imparting water repellency, a silicone composition is preferably used. Specifically, trimethylsiloxysilicic acid, acrylic-silicone film-forming agent, silicone-modified norbornene, silicone-modified pullulan, silicone-modified polyvinyl alcohol, etc. can be used.

[0114] Examples of the film-forming agent of the silicone composition include trimethylsiloxysilicate (INCI: Trimethylsiloxysilicate), (acrylate / dimethylpolysiloxane) copolymer (INCI), (norbornene / tris(trimethylsiloxy)silylnorbornene) copolymer (INCI), and tris(trimethylsiloxy)silylpropylcarbamate pullulan (INCI: Trimethylsiloxysilylcarbamoylpullulan).

[0115] The film-forming agent may be dissolved in an oily agent that is liquid at room temperature and then mixed into the cosmetic. The liquid oily agent may be component (B), or liquid silicone oil, hydrocarbon oil, ester oil, natural animal or plant oil, semi-synthetic oil, or fluorine-based oil in the oily agent (1) of the optional component may be used, for example, cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), squalane (INCI), butyl acetate (INCI: Butyl Acetate), and the like.

[0116] Specific examples of commercially available silicone film-forming agents include KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, and TSPL-30-D5 manufactured by Shin-Etsu Chemical Co., Ltd.

[0117] (7) Ultraviolet light absorbing and scattering agent

[0118] As the ultraviolet absorption and scattering agent, particles that absorb and scatter ultraviolet rays, such as micro-particle titanium oxide, micro-particle iron-containing titanium oxide, micro-particle zinc oxide, micro-particle cerium oxide, and a composite thereof, can be listed. A dispersion in which these ultraviolet absorption and scattering particles are dispersed in oil in advance can also be used. As the oil, liquid silicone oil, hydrocarbon oil, ester oil, natural animal and plant oil, semi-synthetic oil, etc., and fluorine-based oil listed in the above-mentioned component (B) or the oil other than the above-mentioned component (1) (B) can be used. For example, cyclopentasiloxane (INCI), dimethyl polysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (indicative name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. can be listed. Specific examples of dispersions in which particles that absorb and scatter ultraviolet rays are dispersed in an oil in advance include SPD series (trade name), especially SPD-T5, SPD-Z5, SPD-T6, SPD-Z6, SPD-T7, etc., manufactured by Shin-Etsu Chemical Co., Ltd.

[0119] (8) Other additives

[0120] Other additives include oil-soluble gelling agents, preservatives / bactericides, antiperspirants, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin beautifying ingredients (whitening agents, cell activators, rough skin improvers, blood circulation promoters, skin astringents, anti-seborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc.

[0121] Oil-soluble gelling agent

[0122] Examples of the oil-soluble gelling agent include metal soaps selected from aluminum stearate, magnesium stearate, zinc myristate, and the like; amino acid derivatives such as lauroyl glutamic acid (indicative name (INCI: Lauroyl Glutamic Acid)) and α,γ-di-n-butylamine; dextrin palmitate (indicative name (INCI: Dextrin Palmitate)), dextrin isostearate (indicative name (INCI: Dextrin Isostearate)), dextrin myristate (indicative name (INCI: Dextrin Myristate)), stearoyl inulin (indicative name (INCI: Stearoyl Inulin)), dextrin (palmitic acid / ethylhexanoate) (indicative name (INCI: Dextrin Palmitate / Ethylhexanoate) and other dextrin fatty acid esters; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzyl derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; distearyldimethylammonium hectorite (INCI), stearalkonium hectorite (INCI), organically modified clay minerals of hectorite; stearalkonium bentonite (INCI), etc.

[0123] Preservatives / fungicides

[0124] Examples of the preservative / bactericide include alkyl parabens, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolinyl urea, salicylic acid, isopropyl methylphenol, carbolic acid, para-chloro-meta-cresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, triclocarbam, iodopropynyl butylcarbamate, polylysine, photosensitizer, silver, and plant extracts.

[0125] Antiperspirant

[0126] Examples of antiperspirants include aluminum hydroxyhalides such as aluminum chlorohydroxyaluminum, aluminum halides such as aluminum chloride, aluminum allantoin, tannic acid, oyster tannin, aluminum potassium sulfate, zinc oxide, zinc p-phenolsulfonate, pyroalum, tetrachloro(aluminum / zirconium)hydrate, trichlorohydrate glycine (aluminum / zirconium), etc. In particular, preferred components that exhibit high effects include aluminum hydroxyhalides, aluminum halides, and complexes or mixtures of these with zirconium oxyhalides and zirconium oxyhalides (e.g., tetrachloro(aluminum / zirconium)hydrate, trichlorohydrate glycine (aluminum / zirconium)), etc.

[0127] ·spices

[0128] As fragrances, there are natural fragrances and synthetic fragrances. As natural fragrances, there are plant fragrances separated from flowers, leaves, wood, peels, etc.; animal fragrances such as musk and civet. As synthetic fragrances, there are hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols; aldehydes such as terpene aldehydes and aromatic aldehydes; ketones such as alicyclic ketones; esters such as terpene esters; lactones; phenols; oxides; nitrogen-containing compounds; acetals, etc.

[0129] Salts

[0130] As salts, inorganic salts, organic acid salts, amine salts and amino acid salts can be listed. As inorganic salts, for example, sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, etc. of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid can be listed; as organic acid salts, for example, salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, and stearic acid can be listed; as amine salts and amino acid salts, for example, salts of amines such as triethanolamine, and salts of amino acids such as glutamic acid can be listed. In addition, salts of hyaluronic acid, chondroitin sulfate, aluminum zirconium glycine complexes, etc., and acid-base neutralization salts used in cosmetic formulations can also be used.

[0131] Antioxidants

[0132] The antioxidant is not particularly limited, and examples thereof include carotenoids, ascorbic acid and salts thereof, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, p-tert-butylphenol, butylhydroxyanisole, butylated hydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, sorbic acid and salts thereof, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, kaempferol, myricetin, quercetin, etc. The antioxidant may be used alone or in combination of two or more.

[0133] pH adjuster

[0134] Examples of the pH adjuster include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate, and ammonium bicarbonate.

[0135] Chelating agents

[0136] Examples of the chelating agent include alanine, edetic acid sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0137] · Cooling agent

[0138] Examples of the cooling agent include L-menthol, camphor, and menthyl lactate.

[0139] Anti-inflammatory agents

[0140] Examples of the anti-inflammatory agent include allantoin, glycyrrhizic acid and its salts, glycyrrhetinic acid and glycyrrhetinic acid stearyl, tranexamic acid, and azulene.

[0141] Skin-beautifying ingredients

[0142] Examples of skin beautifying ingredients include whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract; cell activators such as royal jelly, photosensitizer, cholesterol derivatives, and calf blood extract; skin roughness improving agents; nonanoic acid vanillamide, benzyl nicotinate, β-butoxyethyl nicotinate, capsaicin, ginger ketone, chelidonium tincture, ichthyol, caffeine, tannic acid, α-camphenol, tocopherol nicotinate, inositol hexanicotinate, cycloamycin, cinnarizine, triazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, and other blood circulation promoters; skin astringents such as zinc oxide and tannic acid; and anti-seborrheic acid agents such as sulfur and dimethylthiothrene.

[0143] Vitamins

[0144] Examples of the vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate and other vitamin A compounds, riboflavin, riboflavin butyrate, flavin adenine nucleotide and other vitamin B2 compounds, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate and other vitamin B6 compounds, vitamin B 12 Its derivatives, vitamin B 15 Vitamin B and its derivatives, L-ascorbic acid, L-ascorbyl dipalmitate, sodium L-ascorbic acid-2-sulfate, dipotassium L-ascorbyl phosphate, etc. Vitamin C, calciferol, cholecalciferol, etc. Vitamin D, α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, etc. Vitamin E; niacin, benzyl nicotinate, niacinamide, etc. Nicotinic acid, vitamin H, vitamin P, pantothenic acid, calcium pantothenate, D-panthenol, panthenyl ethyl ether, acetyl panthenyl ethyl ether, etc. Pantothenic acid, biotin, etc.

[0145] Amino Acids

[0146] Examples of the amino acid include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0147] Nucleic Acids

[0148] Examples of nucleic acids include deoxyribonucleic acid and the like.

[0149] ·hormone

[0150] Examples of the hormone include estradiol and vinyl estradiol.

[0151] Inclusion complex

[0152] Examples of the inclusion compound include cyclodextrin and the like.

[0153] Examples of the form of the cosmetic material of the present invention include powder, liquid, solid, etc. The main formulation forms include liquid, paste, aerosol, ointment, emulsified solid, stick, and emulsified stick.

[0154] Example

[0155] The following examples and comparative examples are shown to more specifically illustrate the present invention, but the present invention is not limited to the following examples. In the following examples and comparative examples, "%" of the composition represents mass %, and "part" represents mass part. In addition, the blending amount recorded by the product name is the blending amount of the blended product. In addition, the solubility of all the (B) components used in 100g of purified water at 25°C is less than 1g.

[0156] [Example, Comparative Example (Active Agent Composition-1)]

[0157] Active agent compositions having the compositions shown in Tables 1 and 2 were prepared.

[0158] (Manufacturing method)

[0159] Each component was weighed in a beaker and mixed.

[0160] The following evaluations were performed on the obtained active agent compositions, and the results are collectively shown in the table.

[0161] [Viscosity]

[0162] The viscosity was measured at 25°C in a 30 mL vial according to the method described in JIS K 7117-1:1999 using a B-type viscometer (TVB-10, manufactured by Toki Sangyo).

[0163] [Transparency]

[0164] Visual observation was performed using a 30 mL vial at 25°C, with transparent dissolution being marked as "○", semi-transparent dissolution being marked as "△", and separation being marked as "×". "△" or above ("△" or "○") was considered acceptable.

[0165] [Table 1]

[0166]

[0167] (Note 1) KF-6104: Made by Shin-Etsu Chemical Co., Ltd.

[0168] (Note 2) KF-6105: Made by Shin-Etsu Chemical Co., Ltd.

[0169] (Note 3) KF-6100: Made by Shin-Etsu Chemical Co., Ltd.

[0170] [Table 2]

[0171]

[0172] (Note 1) KF-6104: Made by Shin-Etsu Chemical Co., Ltd.

[0173] (Note 2) KF-6105: Made by Shin-Etsu Chemical Co., Ltd.

[0174] (Note 3) KF-6100: Made by Shin-Etsu Chemical Co., Ltd.

[0175] (Note 4) KF-6017: Made by Shin-Etsu Chemical Co., Ltd.

[0176] Table 3 shows the viscosity reduction rates of the obtained active agent compositions in Examples and Comparative Examples.

[0177] [Viscosity reduction rate]

[0178] Determine how much the viscosity of the activator composition accounts for the viscosity of the component (A).

[0179] [Table 3]

[0180]

[0181] As can be seen from Table 3, it is confirmed that the viscosity reduction rate of the active agent of the active agent composition of Examples 1 to 12 is good. In particular, it can be seen from the results of Examples 6 to 8 that it is not simply the effect produced by the viscosity of the (B) component. As can be seen from Examples 1 to 5, when the (A) component is a polyglycerol-modified silicone and the (B) component is a branched saturated alcohol, the viscosity reduction rate is more significant. In addition, as can be seen from Comparative Examples 1 to 9, if the silicone oil or hydrocarbon oil usually used in combination with the (A) component, or the ester oil having a viscosity similar to that of the (B) component, is mixed with a different (A) component, the viscosity reduction rate is insufficient. Although Comparative Example 10, in which the number of hydroxyl groups of the active agent is 1 for each hydrophilic group, is a combination with the (B) component, sufficient viscosity reduction is not found. From these results, it can be seen that the combination of the (A) component and the (B) component is important for viscosity reduction.

[0182] [Examples, Comparative Examples (Cosmetics)]

[0183] Water-in-oil (W / O) formulations shown in Table 4 were prepared.

[0184] (Manufacturing method)

[0185] A: Mix ingredients (1).

[0186] B: Mix ingredients (2).

[0187] C: The mixture obtained in B was added to the mixture obtained in A and emulsified to obtain a water-in-oil (W / O) cream.

[0188] [Characteristics evaluation]

[0189] Using the following evaluation criteria, a 10-person special evaluation panel evaluated the compatibility (ease of weighing) in the oil phase when the cosmetic is made and the feel of use (good spreading) of the cosmetic. The results were based on the average of the 10 people and judged according to the following judgment criteria. The results are recorded in the table.

[0190] [Evaluation criteria]

[0191] 5 points: Very good

[0192] 4 points: Good

[0193] 3 points: Average

[0194] 2 points: Slightly poor

[0195] 1 point: Poor

[0196] The obtained average scores were judged with ○× according to the following criteria.

[0197] [Judgment criteria]

[0198] ◎: Average score is 4.5 or above

[0199] ○: Average score is 3.5 or more and less than 4.5

[0200] △: Average score is 2.5 or more and less than 3.5

[0201] ×: The average score is 1.5 or more and less than 2.5

[0202] ××: The average score is less than 1.5 points

[0203] Those with a score of “△” or above were considered as passing.

[0204] [Table 4]

[0205]

[0206] (Note 1) KF-6104: Made by Shin-Etsu Chemical Co., Ltd.

[0207] (Note 2) KF-6105: Made by Shin-Etsu Chemical Co., Ltd.

[0208] As can be seen from Table 4, the cosmetics of Examples 13 to 16 have good feel during use, and in particular, Examples 13 and 14 have good mixing properties and are easy to prepare. The viscosity of the mixture of (1) of Examples 15 and 16 at 25°C is less than 50% of the viscosity of component (A) (3392 mPa·s).

[0209] [Example, Comparative Example (Active Agent Composition-2)]

[0210] Using the formulation shown in Table 6, an active agent composition was prepared.

[0211] (Manufacturing method)

[0212] After weighing each ingredient in a beaker, mix them.

[0213] The viscosity, transparency and viscosity reduction rate were evaluated by the same method as above. The results are also shown in the table.

[0214] [Table 5]

[0215]

[0216] (Note 1) KF-6105: Made by Shin-Etsu Chemical Co., Ltd.

[0217] (Note 2) KF-6100: Made by Shin-Etsu Chemical Co., Ltd.

[0218] As can be seen from Table 6, the activator compositions of Examples 17 to 22 demonstrated that the viscosity reduction rate of the activator was good even when the mass ratio of the component (A) to the component (B) was adjusted.

[0219] [Example 23] Water-in-oil sunscreen

[0220]

[0221]

[0222] (Manufacturing method)

[0223] A: Mix ingredients 1 to 8 evenly.

[0224] B: Components 9 to 12 are uniformly dissolved in component 13.

[0225] C: The dissolved substance obtained in B was slowly added to the mixture obtained in A under stirring to emulsify and obtain a water-in-oil type sunscreen.

[0226] The water-in-oil type sunscreen obtained as described above has a very good feel during use, does not change due to temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0227] [Example 24] Water-in-oil paste lipstick

[0228]

[0229] (Note 1) Made by Chiba Flour Milling Co., Ltd.: Leopal TT

[0230] (Note 2) Shin-Etsu Chemical Co., Ltd.: Dissolved product of 70% cyclopentasiloxane + 30% (acrylate / dimethicone) copolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Mixture of 65-75% triethylhexanoin + 25-35% (vinyl dimethicone / lauryl dimethicone) crosspolymer

[0231] (Manufacturing method)

[0232] A: Component 8 is mixed with a portion of component 2, and dispersed using a roll mill. The resulting dispersion is then heated and mixed with component 1, the remainder of component 2, and components 3 to 5.

[0233] B: Heat ingredients 6 and 7, add to the mixture obtained in A, emulsify and then cool.

[0234] C: Component 9 was added to the emulsion obtained in B to obtain a cream lipstick.

[0235] The resulting cream lipstick is easy to spread, has no stickiness or greasiness, and forms a film with good durability on the lips. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0236] [Example 25] Rinse-off facial mask cosmetic

[0237]

[0238] (Manufacturing method)

[0239] A: Mix components 1 to 3 and 8.

[0240] B: After uniformly mixing components 5 to 7 and 10, components 4 and 9 are mixed and stirred.

[0241] C: The mixture obtained in A was added to the mixture obtained in B while stirring, and the mixture was emulsified to obtain a paste-like rinse-off facial mask cosmetic.

[0242] The facial mask cosmetic material of the flushing type obtained as mentioned above is easily spread during coating, and has excellent cleaning effect. After flushing, it is moist, non-sticky, and the skin feels smooth, has very excellent use sense, and is also excellent in stability. In addition, by using the activating agent composition of the present invention, the making of the cosmetic material is easy.

[0243] [Example 26] Water-in-oil sunscreen lotion

[0244]

[0245] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethicone and 20-30% (dimethicone / (PEG-10 / 15)) cross-linked polymer

[0246] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0247] (Note 3) Shin-Etsu Chemical Co., Ltd.: PEG-9 Polydimethylsiloxyethyl Dimethicone

[0248] (Manufacturing method)

[0249] A: Components 7 to 9 were mixed with part of component 5 and part of component 16, and uniformly dispersed using a bead mill.

[0250] B: Components 1 to 4, the remainder of 5, and components 6 and 10 are uniformly mixed.

[0251] C: Mix ingredients 11 to 14 and the remainder of ingredient 16.

[0252] D: C was added to B under stirring, emulsified, and A and ingredient 15 were added to obtain a water-in-oil type sunscreen emulsion.

[0253] It is known that the sunscreen lotion obtained as described above has a very good feel during use, does not change due to temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0254] [Example 27] Water-in-oil sunscreen

[0255]

[0256] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% squalane and 25-35% (lauryl dimethicone / polyglyceryl-3) cross-linked polymer

[0257] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% triethylhexanoin and 25-35% (vinyl dimethicone / lauryl dimethicone) crosspolymer

[0258] (Note 3) Made by Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0259] (Note 4) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethyl polysiloxane

[0260] (Note 5) Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethyl polysiloxane / methyl polysiloxane silsesquioxane) cross-linked polymer

[0261] (Manufacturing method)

[0262] A: Mix ingredients 3 and 7 uniformly, and then mix with ingredient 1 uniformly.

[0263] B: A, components 2, and 4 to 6 are uniformly mixed.

[0264] C: Components 8 to 14 are uniformly mixed.

[0265] D: Add C to B, emulsify, and you get sunscreen.

[0266] It is known that the sunscreen lotion obtained as described above has a very good feel during use, does not change due to temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0267] [Example 28] Water-in-oil foundation

[0268]

[0269]

[0270] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethicone and 20-30% (dimethicone / (PEG-10 / 15)) cross-linked polymer

[0271] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0272] (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0273] (Note 4) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Ethylhexyl Acrylate / Methacrylate Dimethylpolysiloxane) Copolymer

[0274] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated coloring inorganic pigment, W: white, R: red, Y: yellow, B: black

[0275] (Manufacturing method)

[0276] A: Components 10 to 14 and part of component 9 were uniformly dispersed using a roll mill.

[0277] B: Mix ingredients 3, 5 and 6 evenly.

[0278] C: Mix B and components 1, 2, 4, and 7 to 9 uniformly.

[0279] D: Components 15 to 18 are uniformly mixed.

[0280] E: D was added to C, emulsified, and A was added and mixed to obtain a water-in-oil foundation.

[0281] It is known that the water-in-oil foundation obtained as described above has a very good feel during use, does not change due to temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0282] [Example 29] Water-in-oil stick foundation

[0283]

[0284] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / polyglycerol-3) cross-linked polymer

[0285] (Note 2) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone

[0286] (Note 3) Made by Chiba Flour Milling Co., Ltd.: Leopal ISK2

[0287] (Note 4) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethyl polysiloxane

[0288] (Note 5) Shin-Etsu Chemical Co., Ltd.: Polymethylsilsesquioxane

[0289] (Note 6) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0290] (Note 7) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated coloring inorganic pigment, W: white, R: red, Y: yellow, B: black

[0291] (Manufacturing method)

[0292] A: Mix ingredients 9 and 10 evenly.

[0293] B: A, components 8, and 11 to 14 are dispersed using a roll mill.

[0294] C: Heat B and components 1 to 7 to 95°C and mix them evenly.

[0295] D: Components 15 to 19 are uniformly mixed and heated to 85°C.

[0296] E: D was added to C, emulsified, filled into a stick container, and then slowly cooled to obtain a stick foundation.

[0297] The water-in-oil stick foundation obtained as described above is excellent in feel during use, spreadability, makeup retention and formulation stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0298] [Example 30] Polyol-in-Oil Emulsified Cream

[0299]

[0300]

[0301] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / polyglycerol-3) cross-linked polymer

[0302] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0303] (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0304] (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0305] (Note 5) Shin-Etsu Chemical Co., Ltd.: 50% trimethylsiloxysilicate dissolved in cyclopentasiloxane

[0306] (Note 6) Shin-Etsu Chemical Co., Ltd.: (Diphenyldimethylpolysiloxane / Vinyldiphenyldimethylpolysiloxane / Silsesquioxane) cross-linked polymer

[0307] (Manufacturing method)

[0308] A: Mix ingredients 4 and 6 evenly, and then mix evenly with ingredient 1.

[0309] B: Add A, ingredients 2, 3, 5, 7, 8 and 10 and mix well.

[0310] C: Mix ingredients 9, 11 and 12.

[0311] D: C was added to B and uniformly emulsified to obtain a cream.

[0312] The polyol-in-oil emulsified cream obtained as described above is easy to spread, has no stickiness or greasiness, and has a moist feel. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0313] [Example 31] Water-in-oil cream

[0314]

[0315]

[0316] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / polyglycerol-3) cross-linked polymer

[0317] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 80-90% dimethyl polysiloxane and 10-20% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0318] (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0319] (Note 4) Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethyl polysiloxane / methyl polysiloxane silsesquioxane) cross-linked polymer

[0320] (Manufacturing method)

[0321] A: Mix components 3 and 4 evenly, and then mix with component 1 evenly.

[0322] B: Mix A, components 2, 5 and 6 evenly.

[0323] C: Components 7 to 12 are uniformly mixed.

[0324] D: C was added to B and emulsified to obtain a water-in-oil cream.

[0325] It is known that the water-in-oil type cream obtained as described above has a very good feel during use, does not change with temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0326] [Example 32] Oil-in-water cream

[0327]

[0328]

[0329] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0330] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0331] (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Disiloxane Dimethyl Polysiloxane

[0332] (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0333] (Note 5) Clariant: Aristoflex AVC

[0334] (Note 6) Seppic: Simulgel 600

[0335] (Manufacturing method)

[0336] A: Mix ingredients 5 to 7 evenly.

[0337] B: Mix A, components 4, and 8 to 11 uniformly.

[0338] C: Mix components 1 to 3 evenly.

[0339] D: The mixture obtained in C was added to the mixture obtained in B and emulsified to obtain an oil-in-water cream.

[0340] It is known that the water-in-oil type cream obtained as described above has a very good feel during use, does not change with temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0341] [Example 33] Deodorant spray

[0342]

[0343] (Note 1) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethylpolysiloxane

[0344] (Note 2) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0345] (Manufacturing method)

[0346] A: Mix ingredients 10 and 11 evenly.

[0347] B: Mix components 2 to 4, 6 to 9, and the mixture obtained in A uniformly.

[0348] C: Component 1 is uniformly mixed with the mixture obtained in B, and the mixture is uniformly dispersed and mixed using a mixer.

[0349] D: Add ingredient 5 to the mixture obtained in C and mix evenly.

[0350] E: 10 parts by mass of the stock solution component D and 90 parts by mass of liquefied propane gas (LPG) were charged into a spray container.

[0351] The deodorant spray obtained as described above has no excessive dryness or stickiness and is excellent in the durability of the deodorant effect. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0352] [Example 34] Lipstick

[0353]

[0354] (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Stearyl Acrylate / Dimethyl Polysiloxane Methacrylate) Copolymer

[0355] (Note 2) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0356] (Manufacturing method)

[0357] A: Mix components 6 and 8 evenly.

[0358] B: Heat the mixture obtained from components 1 to 5, 7, 9, 10, and A to 90° C. and mix uniformly.

[0359] C: Components 11 and 12 were uniformly mixed in the mixture obtained in B at 80°C, filled into a stick-shaped container, and then slowly cooled to obtain a lipstick.

[0360] The lipstick obtained as described above is easy to spread, has no stickiness or greasiness, and forms a film with good durability on the lips. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0361] [Example 35] Water-in-oil cream

[0362]

[0363]

[0364] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethyl polysiloxane and 20-30% (dimethyl polysiloxane / polyglycerol-3) cross-linked polymer

[0365] (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethyl polysiloxane / vinyl dimethyl polysiloxane) cross-linked polymer

[0366] (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 polydimethylsiloxyethyl dimethyl polysiloxane (manufacturing method)

[0367] A: Mix components 3 and 4 evenly, and then mix with component 1 evenly.

[0368] B: The mixture obtained in A and components 2 and 5 are uniformly mixed.

[0369] C: Components 6 to 10 are uniformly mixed.

[0370] D: The mixture obtained in C was added to the mixture obtained in B and emulsified to obtain a water-in-oil cream.

[0371] The water-in-oil type cream obtained as described above has a very good feel during use, does not change with temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

[0372] [Example 36] Pressed foundation

[0373]

[0374]

[0375] (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethyl polysiloxane

[0376] (Note 2) Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethyl polysiloxane / methyl polysiloxane silsesquioxane) crosslinked polymer

[0377] (Note 3) Shin-Etsu Chemical Co., Ltd.: (Diphenyldimethylpolysiloxane / Vinyldiphenyldimethylpolysiloxane / Silsesquioxane) cross-linked polymer

[0378] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated coloring inorganic pigment, W: white, R: red, Y: yellow, B: black

[0379] (Note 5) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethylpolysiloxane

[0380] (Manufacturing method)

[0381] A: Mix components 3 and 4 evenly.

[0382] B: The mixture obtained in A and components 1 and 2 are uniformly mixed.

[0383] C: Components 4 to 13 were uniformly mixed using an open mill.

[0384] D: The mixture obtained in B was added to the mixture obtained in C, mixed uniformly, filled into a mold, and molded to obtain a press foundation.

[0385] The pressurized foundation obtained as described above has a very good feel during use, does not change due to temperature or time, and is also excellent in stability. In addition, by using the active agent composition of the present invention, the preparation of cosmetics is easy.

Claims

1. An surfactant composition comprising: (A) a nonionic surfactant having two or more hydroxyl groups per hydrophilic group, and (B) an oily component having only one hydroxyl group and being liquid at 25°C, wherein the viscosity of the surfactant composition at 25°C is less than 50% of the viscosity of the component (A).

2. The active agent composition according to claim 1, in, The composition ratio of the component (A) to the component (B) is 70:30 to 95:5, expressed as a mass ratio, and the viscosity of the active agent composition at 25° C. is 100 to 50,000 mPa·s.

3. The active agent composition according to claim 1, in, The component (A) is polyglycerol-modified silicone.

4. The active agent composition according to claim 3, in, The component (A) is a linear or branched polyglycerol-modified silicone.

5. The active agent composition according to claim 1, in, The component (B) is at least one selected from aliphatic alcohols and ester oils.

6. The active agent composition according to claim 5, in, The component (B) is a branched aliphatic alcohol having 16 to 24 carbon atoms.

7. The active agent composition according to claim 1, in, The solubility of the component (B) in 100 g of purified water at 25°C is less than 1 g.

8. A cosmetic comprising 0.1 to 40% by mass of the active agent composition according to any one of claims 1 to 7 based on the total amount of the cosmetic. 9 . The cosmetic according to claim 8 , which is a water-in-oil emulsified cosmetic.

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