A kind of wastewater treatment device and method of propiconazole
Through the combined technology of distillation heat treatment and flocculation electrolysis of the air floater, the problems of long treatment time and high pressure in the prior art are solved, and the effect of efficient removal of organic matter and heavy metals is achieved.
Patent Information
- Application Number
- CN202411729834.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-29
- Publication Date
- 2025-03-18
- Estimated Expiration
- 2044-11-29
AI Technical Summary
The existing propionazole wastewater treatment technology requires a long time and high pressure, making it difficult to effectively remove a variety of organic matter and heavy metal ions in the wastewater.
The wastewater is heated and treated by distillation kettle, and the low-boiling organic matter is treated by condensation and reuse or harmless treatment, and combined with the flocculation and electrolytic treatment of the air floater, the organic matter and heavy metals are further removed.
It significantly reduces the sewage treatment time and pressure, improves treatment efficiency, effectively removes organic matter and heavy metals in the sewage, and meets emission standards.
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Figure CN119219278B_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of sewage treatment, and in particular to a propiconazole wastewater treatment device and method. Background Art
[0002] Propiconazole is a broad-spectrum triazole fungicide that has a good control effect on a variety of plant fungal diseases and is widely used in disease control of field crops, cash crops and horticultural plants. During its production process, it produces a large amount of wastewater, which contains heavy metal ions, organic matter and intermediates, etc., and needs to be strictly treated before it can be discharged according to regulations.
[0003] Most of the existing propiconazole wastewater treatment methods follow the conventional sewage treatment method, that is, after pH adjustment, preliminary flocculation is performed, and then it is discharged into anaerobic tanks, aerobic tanks, sedimentation tanks, etc. for treatment, and then discharged. However, propiconazole wastewater contains many types of organic matter and some heavy metal ions. This treatment method requires a long treatment time and a high treatment pressure. Summary of the invention
[0004] In order to solve the defects in the prior art, the present invention provides a wastewater treatment device and method of propiconazole, which is specifically achieved by the following technical solutions:
[0005] A wastewater treatment device for propiconazole comprises a still, wherein the still is fixedly connected to a first pipeline, a twelfth pipeline and an eleventh pipeline respectively, the twelfth pipeline is used to introduce sewage to be treated into the still, the end of the first pipeline away from the still is fixedly connected to a condenser, the condenser is connected to a liquid storage tank through a second pipeline, the end of the eleventh pipeline away from the still is connected to a buffer tank, the buffer tank is also connected to an air flotation machine through a tenth pipeline, the air flotation machine is sequentially connected to a regulating tank, an anaerobic tank, an aerobic tank and a sedimentation tank through pipelines; a first interlayer for heating is provided on the outer wall of the still, a funnel-shaped heating tank is fixedly installed inside the still, and the heating tank is provided with a second The interlayer is provided with a coil for heating in the second interlayer, the bottom of the heating tank is fixedly connected to the first end of the transition pipe, the second end of the transition pipe is fixedly connected to the first water distribution tank fixedly installed on the bottom wall of the distillation kettle, a plurality of branch pipes are fixedly installed at the end of the first water distribution tank away from the heating tank, the plurality of branch pipes are all sleeved in the drainage pipe, the ends of the plurality of branch pipes away from the first water distribution tank are fixedly connected to the second water distribution tank fixedly installed at the bottom of the drainage pipe, the second water distribution tank is fixedly connected to the water inlet pipe, the water inlet pipe is fixedly connected to the twelfth pipeline, a drainage outlet fixedly connected to the eleventh pipeline is installed on the side wall of the drainage pipe, and a second air outlet fixedly connected to the first pipeline is installed on the top of the distillation kettle.
[0006] The branch pipe is C-shaped.
[0007] There is a gap between adjacent branch pipes, and there is also a gap between the branch pipe and the inner wall of the drain pipe.
[0008] A second motor is fixedly installed on the top of the distillation kettle, an output end of the second motor is fixedly connected to a second stirring shaft, and a second fan blade is installed on a portion of the second stirring shaft located in the heating tank.
[0009] The second stirring shaft sleeve is provided with a plurality of sleeves, a gap is left between two adjacent sleeves, a plurality of second blades are fixedly mounted on each sleeve, and the sleeves are fixed to the second stirring shaft by means of a top screw.
[0010] The flotation machine is provided with a flocculation chamber, a flotation chamber, a slag discharge chamber, and a clean water chamber which are connected to each other in sequence from the first end to the second end; a clean water outlet is fixedly installed on one side of the clean water chamber, and the clean water outlet is connected to the regulating tank through a pipeline, and the flocculation chamber is respectively connected to the additive tank, the flocculant tank, and the buffer tank through pipelines, and the flocculation chamber is also fixedly installed with a first electrode plate and a second electrode plate, and the first electrode plate and the second electrode plate are respectively electrically connected to the positive electrode and the negative electrode of the power supply.
[0011] A first stirring shaft driven by a first motor is also installed in the flocculation chamber, and a plurality of first fan blades are installed on the first stirring shaft.
[0012] A weir plate matching the clean water outlet is installed in the clean water chamber.
[0013] Several groups of flotation tubes are installed in the flotation chamber, each group of the flotation tubes includes two vertical second air tubes, the tops of the second air tubes are connected to the first air tubes, the first air tubes are connected to the dissolved air tank through a thirteenth pipeline, and the dissolved air tank is also connected to the clean water outlet through a pipeline.
[0014] A wastewater treatment method using the wastewater treatment device of propiconazole comprises the following steps:
[0015] Step 1: The sewage enters the second water distribution tank through the twelfth pipeline, then passes through the branch pipe, and finally enters the heating tank for heating. The evaporated low-boiling point components are condensed through the condenser and enter the liquid storage tank. The remaining sewage enters the buffer tank through the drain pipe;
[0016] Step 2: The sewage in the buffer tank enters the flocculation chamber of the air flotation machine and is mixed with the flocculant and sodium carbonate solution that enter the flocculation chamber at the same time;
[0017] Step 3: Turn on the power supply to generate current in the flocculation chamber;
[0018] Step 4: The sewage in the flocculation chamber is discharged to the regulating tank through the flotation chamber, the slag discharge chamber and the clean water chamber of the flotation machine in sequence;
[0019] Step 5: The pH of the sewage in the regulating tank is adjusted to neutral;
[0020] Step 6: The sewage adjusted to neutrality enters the anaerobic tank and the aerobic tank for treatment in turn;
[0021] Step 7: The sewage treated in the aerobic tank enters the sedimentation tank to remove the silt and then is discharged.
[0022] The technical solution of the present invention has the following advantages:
[0023] In the present invention, a distillation kettle is first used to evaporate the low-boiling point organic matter in the wastewater, which is then reused or subjected to other harmless treatment after condensation; at this time, the organic matter content in the wastewater will be greatly reduced. The distilled wastewater enters the flotation machine to remove part of the organic matter, heavy metals and insoluble matter again, which greatly reduces the burden of subsequent treatment and improves the efficiency of wastewater treatment.
[0024] In the present invention, after the sewage is heated in the heating tank, it overflows from the top of the heating tank and falls in the shape of a water curtain. During the falling process, it is heated again, which can fully improve the efficiency of distillation. BRIEF DESCRIPTION OF THE DRAWINGS
[0025] In order to more clearly illustrate the specific implementation methods of the present invention or the technical solutions in the prior art, the drawings required for use in the specific implementation methods or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are some implementation methods of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.
[0026] Figure 1 It is a structural schematic diagram of the present invention;
[0027] Figure 2 It is a structural schematic diagram of the air flotation machine;
[0028] Figure 3 It is a structural schematic diagram of a distillation kettle;
[0029] Figure 4 for Figure 3 Schematic diagram of the structure at B in the middle;
[0030] Figure 5 for Figure 3 Schematic diagram of the structure at A in the middle.
[0031] In the figure, 1-stillation kettle, 2-first pipeline, 3-condenser, 4-second pipeline, 5-third pipeline, 6-vacuum pump, 7-liquid storage tank, 8-additive tank, 9-first pump, 10-fourth pipeline, 11-second pump, 12-fifth pipeline, 13-flotation machine, 14-sixth pipeline, 15-third pump, 16-regulating tank, 17-seventh pipeline, 18-fourth pump, 19-anaerobic tank, 20-eighth pipeline, 21-fifth pump, 22-aerobic tank, 23-ninth pipeline, 24-sixth pump, 25-tenth pipeline, 26-seventh pump, 27-sedimentation tank, 28-buffer tank, 29-eleventh pipeline, 30-tenth pump, 31-twelfth pipeline, 32-eighth pump, 33-first air pipe, 34-second air pipe, 35-sludge scraper chain, 36-slag discharge chamber, 37-first air outlet, 38-weir plate, 39-clean water outlet , 40-return pipe, 41-box, 42-clean water chamber, 43-first partition, 44-slag discharge chamber, 45-ninth pump, 46-second partition, 47-aeration head, 48-floatation chamber, 49-third partition, 50-first electrode plate, 51-power supply, 52-second electrode plate, 53-dissolving tank, 54-thirteenth pipeline, 55-first motor, 56-top cover, 57-second stirring shaft, 58-second outlet Mouth, 59-convex edge, 60-first heat medium outlet, 61-heating tank, 62-coil, 63-transition pipe, 64-second heat medium inlet, 65-first water distribution tank, 66-drain pipe, 67-branch pipe, 68-second water distribution tank, 69-water inlet pipe, 70-drain port, 71-first heat medium inlet, 72-first water confluence port, 73-second water confluence port, 74-sleeve, 75-second fan blade, 76-top screw. DETAILED DESCRIPTION
[0032] The technical solution of the present invention will be described clearly and completely below in conjunction with the accompanying drawings. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0033] In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicating the orientation or positional relationship, are based on the orientation or positional relationship shown in the drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the modules or elements referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as limiting the present invention. In addition, the terms "first", "second", and "third" are used for descriptive purposes only and cannot be understood as indicating or implying relative importance.
[0034] In the description of the present invention, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
[0035] In addition, the technical features involved in the different embodiments of the present invention described below can be combined with each other as long as they do not conflict with each other.
[0036] As attached Figure 1 As shown, the present invention provides a wastewater treatment device for propiconazole, including a distillation kettle 1, which is fixedly connected to the first pipeline 2, the twelfth pipeline 31 and the eleventh pipeline 29 respectively; wherein the twelfth pipeline 31 is installed with an eighth pump 32, which is used to pass the sewage to be treated into the distillation kettle 1, and the distillation kettle 1 distills the sewage, and the low-boiling point components are evaporated from the first pipeline 2, and the remaining liquid is discharged from the eleventh pipeline 29.
[0037] The end of the first pipeline 2 away from the still 1 is fixedly connected to the condenser 3, and the condenser 3 is connected to the liquid storage tank 7 through the second pipeline 4. The steam generated by the still 1 enters the condenser 3 from the first pipeline 2, is condensed to form liquid, and finally enters the liquid storage tank 7 for storage. In order to improve the efficiency of distillation, the top of the liquid storage tank 7 is connected to the vacuum pump 6 through the third pipeline 5. The vacuum pump 6 puts the liquid storage tank 7 and the still 1 in a negative pressure state, which can improve the distillation efficiency.
[0038] One end of the eleventh pipeline 29 away from the distillation kettle 1 is fixedly connected to the buffer tank 28, and a tenth pump 30 is installed on the eleventh pipeline 29, and the tenth pump 30 is preferably a variable frequency pump.
[0039] The buffer tank 28 is also connected to the air flotation machine 13 via the tenth pipeline 25 equipped with the seventh pump 26. The liquid discharged from the still 1 enters the buffer tank 28 for natural cooling, and then enters the air flotation machine 13 for treatment.
[0040] The air flotation machine 13 is connected to the regulating tank 16 through the sixth pipeline 14 equipped with the third pump 15. The organic and inorganic contents of the water treated by the air flotation machine 13 are greatly reduced, which can reduce the burden of the subsequent treatment process and speed up the treatment. The regulating tank 16 adjusts the pH of the sewage treated by the air flotation machine 13.
[0041] The regulating tank 16 is connected to the anaerobic tank 19 through the seventh pipeline 17 equipped with the fourth pump 18; the anaerobic tank 19 is connected to the aerobic tank 22 through the eighth pipeline 20 equipped with the fifth pump 21, and the aerobic tank 22 is connected to the sedimentation tank 27 through the ninth pipeline 23 equipped with the sixth pump 24. Finally, the clean water in the sedimentation tank 27 is discharged into the specified pipe network.
[0042] The structure of the aforementioned still 1 is as shown in the attached Figure 3 and attached Figure 4 As shown, it includes a kettle body, and a first interlayer is provided on the outer wall of the kettle body. A second heat medium inlet 64 is fixedly installed at the lower part of the first interlayer, and a second heat medium outlet is fixedly installed at the upper part.
[0043] A funnel-shaped heating tank 61 is fixedly installed inside the still 1, and the axis of the heating tank 61 coincides with the axis of the still 1. The heating tank 61 is connected to the still 1 using existing technology, for example, by being fixed to the inner wall of the still 1 through a connecting column, or by being connected to the still 1 through a supporting frame, or by other methods in the existing technology.
[0044] The maximum outer diameter of the heating tank 61 is smaller than the inner diameter of the distillation pot 1 .
[0045] The heating tank 61 is provided with a second interlayer, in which a spiral coil 62 is provided, the top of the coil 62 is fixedly connected to the first heat medium outlet 60, and the bottom of the coil 62 is fixedly connected to the first heat medium inlet 71. This structure can prevent the coil 62 from being corroded.
[0046] The bottom of the heating tank 61 is fixedly connected to the first end of the transition pipe 63, and the second end of the transition pipe 63 is fixedly connected to the top of the first water distribution tank 65. The first water distribution tank 65 can be as shown in the attached Figure 3 and attached Figure 4 It is shown as a part of the bottom wall of the still 1, and can also be welded and fixed to the top of the bottom wall of the still 1.
[0047] The structure of the first water distribution tank 65 is shown in the attached Figure 4 As shown, the interior is hollow, with a first water confluence port 72 connected to the transition pipe 63 at the top and a plurality of first water distribution holes at the bottom, each of which is fixedly connected to the top of a corresponding branch pipe 67. The plurality of branch pipes 67 are distributed in a circular array around the axis of the still 1.
[0048] All the branch pipes 67 are sleeved in the drain pipe 66, the bottom of the drain pipe 66 is closed, and a second water distribution box 68 is fixedly installed on the bottom wall of the drain pipe 66. The second water distribution box 68 is also hollow, and a plurality of second water distribution holes are provided on the top, and each second water distribution hole is fixedly connected to the corresponding branch pipe 67. A second water confluence port 73 is provided at the bottom of the second water distribution box 68, and the second water confluence port 73 matches the water inlet pipe 69. The water inlet pipe 69 is fixedly connected to the twelfth pipeline 31.
[0049] A drain port 70 is fixedly mounted on the side wall of the drain pipe 66 , and the drain port 70 is fixedly connected to the eleventh pipeline 29 .
[0050] The branch pipes 67 are C-shaped, with gaps between them, and also between the branch pipes 67 and the inner wall of the drain pipe 66. The C-shaped branch pipes 67 can extend the water flow path.
[0051] A plurality of through holes are provided on the bottom wall of the distillation kettle 1 around the first water distribution tank 65 , and the through holes are connected to the drain pipe 66 .
[0052] A flange 59 is fixedly mounted on the top outer edge of the heating tank 61. The outer diameter of the flange 59 is smaller than the inner diameter of the distillation kettle 1.
[0053] A second gas outlet 58 is fixedly installed on the top of the distillation kettle 1 , and the second gas outlet 58 is fixedly connected to the first pipeline 2 .
[0054] The sewage to be treated is pumped into the water inlet pipe 69 by the eighth pump 32, and then distributed to the branch pipe 67 by the second water distribution tank 68, and then collected in the first water distribution tank 65 and enters the heating tank 61; since the heating tank 61 is funnel-shaped, the water flow rate is slower as it goes up, so it can be fully heated by the heat medium in the coil 62; the heated sewage begins to evaporate at the top of the heating tank 61, and at this time the sewage will overflow the top of the heating tank 61 and flow down from the edge of the convex edge 59, forming a waterfall-like water curtain. The water curtain will be heated from both sides by the coil 62 and the heat medium in the first interlayer, thereby improving the efficiency of evaporation.
[0055] The waste water after distillation falls to the bottom of the distillation kettle 1, enters the drain pipe 66, and exchanges heat with the sewage in the branch pipe 67, thereby realizing heat recovery and utilization, which is beneficial to energy saving.
[0056] In order to fully heat the sewage in the heating tank 61 , a second motor is fixedly installed on the top of the distillation kettle 1 , and the output end of the second motor is fixedly connected to the second stirring shaft 57 .
[0057] A rotating shaft bracket is fixedly installed inside the heating tank 61 , and the rotating shaft bracket and the second stirring shaft 57 are rotatably matched through bearings to ensure the stability of the second stirring shaft 57 .
[0058] As attached Figure 4 and attached Figure 5 As shown, the portion of the second stirring shaft 57 located in the heating tank 61 is sleeved with a plurality of sleeves 74, and a gap is left between two adjacent sleeves 74. A plurality of second blades 75 are fixedly mounted on each sleeve 74.
[0059] The width direction of the second blade 75 forms an angle of 45 degrees with the axial direction of the second stirring shaft 57 .
[0060] The sleeve 74 is fixed to the second stirring shaft 57 via a jackscrew 76 .
[0061] The distillation kettle 1 is equipped with a temperature sensor.
[0062] The structure of the air floatation machine 13 is shown in the attached Figure 1 and attached Figure 2 As shown, the box body 41 includes a box body 41 , a dissolved gas tank 53 is fixedly mounted on a first end of the box body 41 , and a clean water outlet 39 is fixedly mounted on a second end of the box body 41 . The clean water outlet 39 is fixedly connected to the sixth pipeline 14 .
[0063] A third partition plate 49 , a second partition plate 46 and a first partition plate 43 are fixedly installed in sequence from the first end to the second end inside the box body 41 .
[0064] A gap is left between the bottom of the first partition 43 and the bottom of the box 41, and a clean water chamber 42 is formed between the first partition 43 and the side wall of the second end of the box 41. An L-shaped weir plate 38 is fixedly installed in the clean water chamber 42, and the clean water outlet 39 matches the weir plate 38.
[0065] A slag discharge chamber 44 is formed between the first partition plate 43 and the second partition plate 46 . A scraper chain 35 for driving a scraper blade is installed above the slag discharge chamber 44 . A slag discharge chamber 36 matching the scraper blade is fixedly installed on the first partition plate 43 .
[0066] The top height of the second partition plate 46 is smaller than the top height of the box body 41 .
[0067] An air flotation chamber 48 is formed between the second partition plate 46 and the third partition plate 49, and a plurality of groups of air flotation tubes are installed inside the air flotation chamber 48. A gap is left between the bottom of the third partition plate 49 and the bottom of the box body 41.
[0068] A flocculation chamber is formed between the third partition plate 49 and the side wall of the first end of the box body 41 .
[0069] The tenth pipeline 25 is connected to the flocculation chamber.
[0070] The flocculation chamber is connected to the additive tank 8 and the flocculant tank respectively through the fourth pipeline 10 and the fifth pipeline 12. The additive tank 8 contains a sodium carbonate solution, and the flocculant tank contains a flocculant.
[0071] A first stirring shaft driven by a first motor 55 is also installed in the flocculation chamber, and a plurality of first blades are fixedly installed on the first stirring shaft.
[0072] A first pump 9 is installed on the fourth pipeline 10, and a second pump 11 is installed on the fifth pipeline 12. The second pump 11 and the first pump 9 are metering pumps.
[0073] The aforementioned air flotation tube is connected to the dissolved air tank 53 through the thirteenth pipeline 54 , and the dissolved air tank 53 is also connected to the clean water outlet 39 through the return water pipe 40 , and the ninth pump 45 is installed on the return water pipe 40 .
[0074] A first electrode plate 50 is fixedly mounted on one side of the third partition 49 close to the first end of the box body 41, and a second electrode plate 52 matching the first electrode plate 50 is fixedly mounted on the side wall of the first end of the box body 41. The first electrode plate 50 and the second electrode plate 52 are electrically connected to the positive and negative poles of the power supply 51, respectively.
[0075] Of course, the first electrode plate 50 and the second electrode plate 52 may also be installed at other positions of the flocculation chamber, such as the middle of the flocculation chamber, or the first electrode plate 50 and the second electrode plate 52 may be installed vertically and parallelly.
[0076] Each group of the aforementioned air flotation tubes includes two vertical second air tubes 34, the top of the second air tube 34 is connected to the first air tube 33, and the first air tube 33 is connected to the thirteenth pipeline 54. An aeration head 47 is fixedly installed at the bottom of the second air tube 34.
[0077] The sewage, flocculant and sodium carbonate solution enter the flocculation chamber together and are mixed evenly under the action of the first motor 55. The sodium carbonate solution can improve the conductivity of the wastewater.
[0078] The first electrode plate 50 and the second electrode plate 52 form a weak current in the flocculation chamber, which can accelerate flocculation and decompose organic matter to a certain extent. The current will also electrolyze the water, so that some heavy metal ions will form insoluble hydroxides; the added carbonate ions will also cause some heavy metal ions to form insoluble carbonates. After these insoluble substances enter the flotation chamber 48, the dissolved water in the dissolved gas tank 53 is released from the aeration head 47 to form a large number of bubbles, which bring the insoluble substances and flocculants in the sewage to the water surface to form scum, and are sent to the slag discharge chamber 36 in the slag discharge chamber 44.
[0079] The clean water enters the clean water chamber 42 through the bottom of the first partition plate 43 , then overflows the top of the weir plate 38 , and finally is discharged from the clean water outlet 39 .
[0080] The first electrode plate 50 and the second electrode plate 52 will electrolyze a portion of water to form hydrogen and oxygen, so a top cover 56 is fixedly installed on the top of the box body 41, and a first gas outlet 37 is fixedly installed on the top cover 56. The first gas outlet 37 is connected to the exhaust gas treatment system.
[0081] The first motor 55 is fixedly mounted on the top of the top cover 56 .
[0082] In this embodiment, all pumps, sensors, motors, etc. are electrically connected to the controller.
[0083] The sewage treatment method of this embodiment comprises the following steps:
[0084] Step 1: The sewage enters the second water distribution tank 68 through the twelfth pipeline 31, then passes through the branch pipe 67, and finally enters the heating tank 61 for heating. The evaporated low-boiling point components are condensed through the condenser 3 and enter the liquid storage tank 7. The remaining sewage enters the buffer tank 28 through the drain pipe 66;
[0085] Step 2: The sewage in the buffer tank 28 enters the flocculation chamber of the air flotation machine 13 and is mixed with the flocculant and sodium carbonate solution that simultaneously enter the flocculation chamber;
[0086] Step 3: Turn on the power supply 51 to generate current in the flocculation chamber;
[0087] Step 4: The sewage in the flocculation chamber is discharged to the regulating tank 16 through the flotation chamber 48, the slag discharge chamber 44 and the clean water chamber 42 of the flotation machine 13 in sequence;
[0088] Step 5: The pH of the sewage in the regulating tank 16 is adjusted to neutral;
[0089] Step 6: The sewage adjusted to neutrality enters the anaerobic tank 19 and the aerobic tank 22 for treatment in turn;
[0090] Step 7: The sewage treated in the aerobic tank 22 enters the sedimentation tank 27 to be discharged after the sediment is removed.
[0091] Obviously, the above embodiments are merely examples for the purpose of clear explanation, and are not intended to limit the implementation methods. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. The obvious changes or modifications derived therefrom are still within the scope of protection of the invention.
Claims
1. A wastewater treatment device for propiconazole, characterized in that: The invention comprises a distillation kettle (1), wherein the distillation kettle (1) is fixedly connected to a first pipeline (2), a twelfth pipeline (31) and an eleventh pipeline (29), respectively; the twelfth pipeline (31) is used to introduce sewage to be treated into the distillation kettle (1); an end of the first pipeline (2) away from the distillation kettle (1) is fixedly connected to a condenser (3); the condenser (3) is connected to a liquid storage tank (7) via a second pipeline (4); an end of the eleventh pipeline (29) away from the distillation kettle (1) is fixedly connected to a buffer tank (7); The buffer tank (28) is connected to the flotation tank (13) through a tenth pipeline (25), and the flotation tank (13) is connected to the regulating tank (16), the anaerobic tank (19), the aerobic tank (22), and the sedimentation tank (27) in sequence through pipelines; a first interlayer for heating is provided on the outer wall of the distillation kettle (1), a funnel-shaped heating tank (61) is fixedly installed inside the distillation kettle (1), and the heating tank (61) is provided with a second interlayer, and a A coil (62) for heating, the bottom of the heating tank (61) is fixedly connected to the first end of the transition pipe (63), the second end of the transition pipe (63) is fixedly connected to a first water distribution tank (65) fixedly mounted on the bottom wall of the distillation kettle (1), a plurality of branch pipes (67) are fixedly mounted on one end of the first water distribution tank (65) away from the heating tank (61), the plurality of branch pipes (67) are all sleeved in the drainage pipe (66), and the plurality of branch pipes (67) are located at one end of the first water distribution tank (65) away from the first water distribution tank (65). The end of the drain pipe (66) is fixedly connected to a second water distribution tank (68) fixedly mounted on the bottom of the drain pipe (66); the second water distribution tank (68) is fixedly connected to a water inlet pipe (69); the water inlet pipe (69) is fixedly connected to a twelfth pipeline (31); a drain outlet (70) fixedly connected to an eleventh pipeline (29) is mounted on a side wall of the drain pipe (66); a second air outlet (58) fixedly connected to the first pipeline (2) is mounted on the top of the distillation kettle (1); the branch pipe (67) is C-shaped; A gap is left between adjacent branch pipes (67), and a gap is also left between the branch pipe (67) and the inner wall of the drainage pipe (66); A convex edge (59) is fixedly mounted on the top outer edge of the heating groove (61).
2. The wastewater treatment device of propiconazole according to claim 1, characterized in that: A second motor is fixedly mounted on the top of the distillation kettle (1); an output end of the second motor is fixedly connected to a second stirring shaft (57); a second fan blade (75) is mounted on the portion of the second stirring shaft (57) located in the heating tank (61).
3. The wastewater treatment device of propiconazole according to claim 2, characterized in that: The second stirring shaft (57) is sleeved with a plurality of sleeves (74), a gap is left between two adjacent sleeves (74), a plurality of second blades (75) are fixedly mounted on each sleeve (74), and the sleeves (74) and the second stirring shaft (57) are fixed by means of a top screw (76).
4. The wastewater treatment device of propiconazole according to claim 1, characterized in that: The flotation machine (13) is provided with a flocculation chamber, an air flotation chamber (48), a slag discharge chamber (44), and a clean water chamber (42) which are connected to each other in sequence from the first end to the second end; a clean water outlet (39) is fixedly installed on one side of the clean water chamber (42), and the clean water outlet (39) is connected to the regulating tank (16) through a pipeline; the flocculation chamber is respectively connected to the additive tank (8), the flocculant tank, and the buffer tank (28) through pipelines; the flocculation chamber is also fixedly installed with a first electrode plate (50) and a second electrode plate (52), and the first electrode plate (50) and the second electrode plate (52) are respectively electrically connected to the positive electrode and the negative electrode of a power source (51).
5. The wastewater treatment device of propiconazole according to claim 4, characterized in that: A first stirring shaft driven by a first motor (55) is also installed in the flocculation chamber, and a plurality of first fan blades are installed on the first stirring shaft.
6. The wastewater treatment device of propiconazole according to claim 4, characterized in that: A weir plate (38) matching the clean water outlet (39) is installed in the clean water chamber (42).
7. The wastewater treatment device of propiconazole according to claim 4, characterized in that: A plurality of groups of flotation tubes are installed in the flotation chamber (48), each group of the flotation tubes comprising two vertical second air tubes (34), the tops of the second air tubes (34) being connected to the first air tube (33), the first air tube (33) being connected to the air dissolving tank (53) via a thirteenth pipeline (54), and the air dissolving tank (53) being further connected to the clean water outlet (39) via a pipeline.
8. A method for treating wastewater of a wastewater treatment device of propiconazole according to claim 4, characterized in that: The following steps are involved: Step 1: The sewage enters the second water distribution tank (68) through the twelfth pipeline (31), then passes through the branch pipe (67), and finally enters the heating tank (61) for heating. The evaporated low-boiling point components are condensed through the condenser (3) and enter the liquid storage tank (7). The remaining sewage enters the buffer tank (28) through the drain pipe (66); Step 2: The sewage in the buffer tank (28) enters the flocculation chamber of the air flotation machine (13) and is mixed with the flocculant and sodium carbonate solution that simultaneously enter the flocculation chamber; Step 3: Turn on the power supply (51) to generate current in the flocculation chamber; Step 4: The sewage in the flocculation chamber is discharged into the regulating tank (16) through the flotation chamber (48), the slag discharge chamber (44), and the clean water chamber (42) of the flotation machine (13) in sequence; Step 5: The pH of the sewage in the regulating tank (16) is adjusted to neutral; Step 6: The sewage adjusted to neutrality enters the anaerobic tank (19) and the aerobic tank (22) for treatment in sequence; Step 7: The sewage treated in the aerobic tank (22) enters the sedimentation tank (27) to remove the sediment and then is discharged.
Citation Information
Patent Citations
Medicine intermediate production wastewater treatment process
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