Method of forming a semiconductor structure
By removing part of the dielectric layer and the cover layer in the semiconductor structure formation method, the use of masks is reduced, the thickness of the dielectric layer is controlled, the mask alignment and leakage problems are solved, the cost is reduced and the manufacturing efficiency and yield are improved.
Patent Information
- Application Number
- CN202310809966.9
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-06-30
- Publication Date
- 2025-10-21
- Estimated Expiration
- 2043-06-30
AI Technical Summary
In the existing technology, there are mask alignment problems in the manufacturing process of semiconductor structures, which leads to poor morphology and performance of structural components such as word lines. The use of multi-layer masks increases costs, and leakage problems at the edge of the array area are serious, affecting manufacturing efficiency and yield.
By removing part of the dielectric layer in the array area and the covering layer in the peripheral area in the semiconductor structure formation method, the use of masks is reduced. After depositing the conductive material layer, part of the conductive material layer is removed, and the thickness of the dielectric layer is controlled within the range of 40nm to 100nm, ensuring that the conductive layer is located lower than the isolation layer, thereby improving the electrical isolation effect.
The manufacturing cost of the semiconductor structure is reduced, the manufacturing yield is improved, the leakage problem is reduced, the electrical isolation effect is improved, the residual conductive material in the peripheral area is avoided, and the structural performance is ensured.
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Figure CN119277766B_ABST
Abstract
Description
Technical Field
[0001] The present disclosure relates to the field of semiconductor manufacturing technology, and in particular to a method for forming a semiconductor structure. Background Art
[0002] Dynamic Random Access Memory (DRAM) is a semiconductor device commonly used in electronic devices such as computers. It includes an array area and a peripheral area located outside the array area. The array area is composed of multiple memory cells, and multiple word lines and bit lines electrically connected to the multiple memory cells. Each memory cell typically includes a switching element and a storage element electrically connected to the switching element. The word line voltage on the word line can control the opening and closing of the switching element, thereby allowing data stored in the storage element to be read or written to the storage element through the bit line.
[0003] In the manufacturing process of semiconductor structures such as DRAM, for example, in the process of forming word lines, multiple layers of masks are usually required, and the alignment of the masks can affect the morphology and performance of structural components such as word lines. The use of too many masks can also increase the manufacturing cost of semiconductor structures and reduce the manufacturing efficiency of semiconductor structures. In addition, during the process of applying processing to the array area, due to the limitations of the processing process, the film layer stacking in the middle and edge positions of the array area will be unbalanced, which can easily affect the device structure at the edge of the array area. For example, leakage problems are likely to occur between the word lines at the edge and the storage elements at the edge, resulting in reduced performance of the semiconductor structure, and in severe cases, it can even cause the semiconductor structure to be scrapped.
[0004] Therefore, how to improve the performance of semiconductor structures while reducing the manufacturing costs of semiconductor structures and improving the manufacturing yield of semiconductor structures is a technical problem that needs to be solved urgently. Summary of the Invention
[0005] Some embodiments of the present disclosure provide methods for forming a semiconductor structure, which are used to improve the performance of the semiconductor structure, reduce the manufacturing cost of the semiconductor structure, and increase the manufacturing yield of the semiconductor structure.
[0006] According to some embodiments, the present disclosure provides a method for forming a semiconductor structure, comprising the following steps:
[0007] Providing a substrate, the substrate comprising an array region and a peripheral region located outside the array region along a first direction, the array region comprising a plurality of active pillars arranged at intervals, the first direction being parallel to a top surface of the substrate;
[0008] forming a dielectric layer covering the array region and the peripheral region, an isolation layer covering the sidewalls and top surface of the dielectric layer in the peripheral region, and a cover layer covering the isolation layer, wherein the width of the dielectric layer along the first direction is 40 nm to 100 nm;
[0009] removing a portion of the dielectric layer in the array area and removing the cover layer in the peripheral area to expose the active pillars;
[0010] forming a conductive material layer covering the array area and the peripheral area;
[0011] A portion of the conductive material layer in the array area and the entire conductive material layer in the peripheral area are removed to form a conductive layer electrically connected to the active pillar.
[0012] In some embodiments, the specific steps of forming a dielectric layer covering the array region and the peripheral region, an isolation layer covering the sidewalls and top surface of the dielectric layer in the peripheral region, and a cover layer covering the isolation layer include:
[0013] forming the active pillars covering the array region and the dielectric layer covering the peripheral region, wherein a top surface of the dielectric layer in the array region is located below a top surface of the dielectric layer in the peripheral region;
[0014] forming the isolation layer continuously distributed in the array region and the peripheral region and covering the surface of the dielectric layer;
[0015] forming a covering layer continuously distributed in the array region and the peripheral region and covering the surface of the isolation layer;
[0016] The covering layer and the isolation layer in the array area are removed, and a portion of the covering layer in the peripheral area is removed.
[0017] In some embodiments, the specific steps of forming the active pillars covering the array area and the dielectric layer covering the peripheral area include:
[0018] forming a first dielectric layer covering surfaces of the active pillars in the array region and a surface of the substrate in the peripheral region;
[0019] forming a second dielectric layer covering the first dielectric layer;
[0020] A third dielectric layer covering the second dielectric layer is formed to form the dielectric layer including the first dielectric layer, the second dielectric layer and the third dielectric layer.
[0021] In some embodiments, the specific steps of removing the covering layer and the isolation layer in the array area and removing a portion of the covering layer in the peripheral area include:
[0022] Using a planarization process to remove all of the covering layer in the array area and partially remove the covering layer in the peripheral area, exposing the isolation layer in the array area;
[0023] The isolation layer in the array area is removed to expose the dielectric layer in the array area.
[0024] In some embodiments, the specific steps of removing a portion of the dielectric layer in the array area and removing the cover layer in the peripheral area include:
[0025] A wet etching process is adopted to remove a portion of the dielectric layer in the array area and the cover layer in the peripheral area, thereby exposing the active pillars in the array area and the isolation layer in the peripheral area.
[0026] In some embodiments, the specific steps of removing a portion of the dielectric layer in the array area and removing the cover layer in the peripheral area include:
[0027] Part of the dielectric layer in the array area is removed, and the covering layer in the peripheral area is removed to expose the active pillars in the array area and the isolation layer in the peripheral area, and the top surface of the remaining dielectric layer in the array area is located below the top surface of the dielectric layer in the peripheral area.
[0028] In some embodiments, the peripheral region includes a first peripheral region adjacent to the array region and a second peripheral region outside the first peripheral region; and the specific steps of removing a portion of the dielectric layer in the array region and removing the cover layer in the peripheral region include:
[0029] forming a photoresist layer on the substrate, wherein the photoresist layer includes an etching window exposing the array region and the first peripheral region;
[0030] A portion of the dielectric layer in the array area is removed along the etching window, and the cover layer in the first peripheral area is removed.
[0031] In some embodiments, before depositing the conductive material on the array region and the peripheral region, the method further includes the following steps:
[0032] A functional layer is formed to cover the sidewalls of the active pillar.
[0033] In some embodiments, the specific steps of forming the conductive material layer covering the array area and the peripheral area include:
[0034] Conductive material is deposited in the array area and the peripheral area to form the conductive material layer, which covers the remaining surface of the dielectric layer in the array area, fills the gaps between adjacent active pillars, covers the functional layer, and covers the isolation layer in the peripheral area.
[0035] In some embodiments, the specific steps of forming a conductive layer electrically connected to the active pillar include:
[0036] Part of the conductive material layer in the array area and the entire conductive material layer in the peripheral area are etched back to expose the isolation layer in the peripheral area, and the remaining conductive material layer in the array area is used as the conductive layer, and the top surface of the conductive layer is located below the top surface of the active column.
[0037] In some embodiments, before etching back a portion of the conductive material layer in the array area and the entire conductive material layer in the peripheral area, the method further includes the following steps:
[0038] The conductive material layer is planarized so that a top surface of the conductive material layer in the array region is flush with a top surface of the conductive material layer in the peripheral region.
[0039] In some embodiments, the peripheral region is located outside the array region along a first direction, the isolation layer in the peripheral region includes a first portion extending along a second direction, and a second portion connected to the first portion and extending along the first direction, the first direction is parallel to the top surface of the substrate, and the second direction is perpendicular to the top surface of the substrate;
[0040] The top surface of the conductive layer is flush with the top surface of the second portion; or, the top surface of the conductive layer is located below the top surface of the second portion.
[0041] In some embodiments, after removing part of the conductive material layer in the array area and all of the conductive material layer in the peripheral area, the method further includes the following steps:
[0042] A spacer layer is formed covering the conductive layer, the active pillar and the isolation layer.
[0043] In some embodiments, the active pillar includes a channel region, and a source region and a drain region distributed on opposite sides of the channel region along a second direction, wherein the second direction is perpendicular to the top surface of the substrate;
[0044] The conductive layer is a word line covering the channel region.
[0045] Some embodiments of the present disclosure provide methods for forming semiconductor structures. In the process of exposing active pillars, a mask covering the outer layer of the peripheral region is not required. Instead, a portion of the dielectric layer in the array region and the outer layer of the peripheral region are removed. This reduces the number of masks required in the semiconductor structure manufacturing process, thereby reducing the manufacturing cost of the semiconductor structure. Furthermore, in some embodiments of the present disclosure, the outer layer of the peripheral region is removed during the process of removing the portion of the dielectric layer in the array region. A conductive material layer is deposited simultaneously in both the array region and the outer layer. Subsequently, when forming the conductive layer, the portion of the conductive material layer in the array region and the entire conductive material layer in the outer layer are removed. This prevents the conductive material layer from remaining in the outer layer, improves the electrical isolation between the conductive layer and the outer layer, and thus improves the performance of the semiconductor structure. Furthermore, in some embodiments of the present disclosure, the thickness of the dielectric layer is limited to 40 nm to 100 nm. This allows the conductive layer formed after etching back to be positioned lower than the isolation layer, further improving the electrical isolation between the conductive layer and the outer layer without significantly increasing the size of the semiconductor structure. BRIEF DESCRIPTION OF THE DRAWINGS
[0046] Attachment Figure 1 is a flow chart of a method for forming a semiconductor structure in a specific embodiment of the present disclosure;
[0047] Attachment Figure 2 -Attached Figure 15 It is a schematic diagram of the main process structure in the process of forming a semiconductor structure according to a specific embodiment of the present disclosure. DETAILED DESCRIPTION
[0048] The specific implementation of the method for forming a semiconductor structure provided by the present disclosure is described in detail below with reference to the accompanying drawings.
[0049] This embodiment provides a method for forming a semiconductor structure. Figure 1 is a flow chart of a method for forming a semiconductor structure in a specific embodiment of the present disclosure, Figure 2 -Attached Figure 15 This is a schematic diagram of the main process structure in the process of forming a semiconductor structure in the specific embodiment of the present disclosure. Figures 1-15 As shown, the method for forming the semiconductor structure includes the following steps:
[0050] Step S11, providing a substrate 15, wherein the substrate 15 includes an array region 13 and a peripheral region 14 located outside the array region 13 along a first direction, wherein the array region 13 includes a plurality of active pillars 30 arranged at intervals, and the first direction is parallel to the top surface of the substrate 15;
[0051] Step S12, forming a dielectric layer 40 covering the array region 13 and the peripheral region 14, an isolation layer 41 covering the sidewalls and top surface of the dielectric layer 40 in the peripheral region 14, and a cover layer 42 covering the isolation layer 41, wherein a width D of the dielectric layer along the first direction is 40 nm to 100 nm;
[0052] Step S13 , removing a portion of the dielectric layer 40 in the array region 13 and removing the cover layer 42 in the peripheral region 14 to expose the active pillars 30 ;
[0053] Step S14, forming a conductive material layer 130 covering the array region 13 and the peripheral region 14;
[0054] In step S15 , a portion of the conductive material layer 130 in the array region 13 and the entire conductive material layer 130 in the peripheral region 14 are removed to form a conductive layer 140 electrically connected to the active pillars 30 .
[0055] In some embodiments, the specific steps of forming the dielectric layer 40 covering the array region 13 and the peripheral region 14 , the isolation layer 41 covering the sidewalls and top surface of the dielectric layer 40 in the peripheral region 14 , and the cover layer 42 covering the isolation layer 41 include:
[0056] forming the active pillars 30 covering the array region 13 and the dielectric layer 40 covering the peripheral region 14 , wherein a top surface of the dielectric layer 40 in the array region 13 is located below a top surface of the dielectric layer 40 in the peripheral region 14 ;
[0057] forming the isolation layer 41 continuously distributed in the array region 13 and the peripheral region 14 and covering the surface of the dielectric layer 40;
[0058] forming a covering layer 42 that is continuously distributed in the array region 13 and the peripheral region 14 and covers the surface of the isolation layer 41;
[0059] Remove the cover layer 42 and the isolation layer 41 in the array area 13, and remove part of the cover layer 42 in the peripheral area 14. Figure 4 shown. Figure 2 is a schematic top view of the semiconductor structure formed in this specific embodiment, Figure 4 yes Figure 2 A schematic cross-sectional view of position aa after the covering layer 42 is formed.
[0060] In some embodiments, the specific steps of forming the active pillars 30 covering the array region 13 and the dielectric layer 40 covering the peripheral region 14 include:
[0061] forming a first dielectric layer covering the surface of the active pillars 30 in the array region 13 and the surface of the substrate 15 in the peripheral region 14;
[0062] forming a second dielectric layer covering the first dielectric layer;
[0063] A third dielectric layer covering the second dielectric layer is formed to form the dielectric layer 40 including the first dielectric layer, the second dielectric layer, and the third dielectric layer.
[0064] The semiconductor structure described in this specific embodiment may be, but is not limited to, a DRAM. This specific embodiment is described by taking the semiconductor structure being a DRAM as an example. The substrate 15 may be, but is not limited to, a silicon substrate. This specific embodiment is described by taking the substrate 15 being a silicon substrate as an example. In other embodiments, the substrate 20 may also be a semiconductor substrate such as gallium nitride, gallium arsenide, gallium carbide, silicon carbide or SOI. The substrate 15 and the active pillars 30 on the substrate 15 may be formed by the following method: first, an initial substrate is formed; then, a first mask layer 32 is formed on the initial substrate, wherein the first mask layer 32 has an opening exposing the initial substrate; then, the initial substrate is etched along the opening to form a plurality of first trenches 31 extending along the first direction D1 and the third direction D3, wherein the plurality of first trenches 31 separate the initial substrate into a plurality of active pillars 30 arranged in a two-dimensional array along the first direction D1 and the third direction D3, and the remaining initial substrate below the active pillars 30 serves as the substrate 15, as shown in FIG. Figure 2 and Figure 3 As shown. Among them, Figure 3 yes Figure 2 A schematic cross-sectional view of the position aa in FIG. 3 after forming the active pillar 30. In one example, the depth of the first trench 31 along the second direction D2 may be In one example, the first direction D1 and the third direction D3 are both parallel to the top surface of the substrate 15, and the first direction D1 intersects the third direction D3 (e.g., perpendicularly or obliquely), and the second direction D2 is perpendicular to the top surface of the substrate 15. The top surface of the substrate 15 refers to the surface of the substrate 15 facing the active pillar 30.
[0065] After forming the active pillars 30, a first dielectric layer can be formed covering the surfaces of the active pillars 30 in the array region 13 and the exposed surface of the substrate 15 in the peripheral region 14 by in-situ water vapor growth (ISSG) or other methods. In one example, the thickness of the first dielectric layer (e.g., the width of the first dielectric layer along the first direction D1) is 1 nm to 5 nm (e.g., 4 nm). Next, a dielectric material such as silicon dioxide can be deposited in the array region 13 and the peripheral region 14 by chemical vapor deposition, physical vapor deposition, or atomic layer deposition to form a second dielectric layer that at least fills the first trenches 31 between adjacent active pillars 30 and covers the first dielectric layer. In one example, the thickness of the second dielectric layer (e.g., the width of the second dielectric layer along the first direction D1) is 1 nm to 5 nm (e.g., 3.5 nm). Thereafter, a third dielectric layer covering the second dielectric layer can be formed again by chemical vapor deposition, physical vapor deposition, or atomic layer deposition. In one example, the thickness of the third dielectric layer (e.g., the width of the third dielectric layer along the first direction D1) is 35 nm to 95 nm (e.g., 35 nm, 50 nm, 65 nm, 80 nm, 85 nm, or 90 nm). The first dielectric layer, the second dielectric layer, and the third dielectric layer together constitute the dielectric layer 40. In one example, the material of the first dielectric layer, the material of the second dielectric layer, and the material of the third dielectric layer are all the same (e.g., silicon dioxide), thereby simplifying subsequent processes and further reducing the manufacturing cost of the semiconductor structure.
[0066] Because the array region 13 includes a plurality of active pillars 30, along the second direction D2, the top surfaces of the active pillars 30 in the array region 13 are located above the top surface of the substrate 15 in the peripheral region 14, thereby causing the dielectric layer 40 to have a stepped shape. The height of the dielectric layer 40 in the array region 13 along the second direction D2 is higher than the height of the dielectric layer 40 in the peripheral region 14 along the second direction D2. That is, the top surface of the dielectric layer 40 in the array region 13 is higher than the top surface of the dielectric layer 40 in the peripheral region 14. Subsequently, after the isolation layer 41 is deposited on the surface of the dielectric layer 40 using a chemical vapor deposition process, a physical vapor deposition process, or an atomic layer deposition process, the isolation layer 41 also has a stepped shape. In one example, the material of the isolation layer 41 can be a nitride material, such as silicon nitride. Next, the cover layer 42 is formed to cover the isolation layer 41, and a planarization process such as chemical mechanical polishing (CMP) is performed to make the top surface of the cover layer 42 flat. Figure 4In one example, the material of the cover layer 42 may be an oxide material, such as silicon dioxide. In one example, the thickness of the isolation layer 41 may be (For example ). The thickness of the covering layer can be (For example ).
[0067] In this specific embodiment, the thickness of the third dielectric layer can be adjusted to ensure that the overall width of the dielectric layer 40 along the first direction D1 is within a range of 40 nm to 100 nm. This ensures that when the conductive material layer is subsequently etched back to form the conductive layer, the conductive layer portion closest to the isolation layer 41 is lower than the isolation layer 41 along the second direction D2. This structure, on the one hand, increases the distance between the active pillars 30 located at the edge of the array region 13 and the conductive structures (e.g., lead structures, CMOS circuit structures) located in the peripheral region 14, reducing leakage between the array region 13 and the peripheral region 14, thereby improving the performance of the semiconductor structure. On the other hand, it also increases the distance between the subsequently formed conductive layer and the conductive structures located in the peripheral region 14, thereby reducing leakage within the semiconductor structure.
[0068] In some embodiments, the specific steps of removing the cover layer 42 and the isolation layer 41 in the array area 13 and removing a portion of the cover layer 42 in the peripheral area 14 include:
[0069] Using a planarization process, the entire cover layer 42 in the array region 13 is removed, and a portion of the cover layer 42 in the peripheral region 14 is removed, exposing the isolation layer 41 in the array region 13 ;
[0070] The isolation layer 41 in the array region 13 is removed to expose the dielectric layer 40 in the array region 13 .
[0071] In some embodiments, the specific steps of removing a portion of the dielectric layer 40 in the array area 13 and removing the cover layer 42 in the peripheral area 14 include:
[0072] A wet etching process is used to remove a portion of the dielectric layer 40 in the array region 13 and the cover layer 42 in the peripheral region 14 , thereby exposing the active pillars 30 in the array region 13 and the isolation layer 41 in the peripheral region 14 .
[0073] In some embodiments, the specific steps of removing a portion of the dielectric layer 40 in the array area 13 and removing the cover layer 42 in the peripheral area 14 include:
[0074] Part of the dielectric layer 40 in the array area 13 is removed, and the covering layer 42 in the peripheral area 14 is removed, exposing the active pillars 30 in the array area 13 and the isolation layer 41 in the peripheral area 14, and the top surface of the remaining dielectric layer 40 in the array area 13 is located below the top surface of the dielectric layer 40 in the peripheral area 14.
[0075] In some embodiments, the peripheral region 14 includes a first peripheral region 141 adjacent to the array region 13 and a second peripheral region 142 located outside the first peripheral region 141 . The specific steps of removing a portion of the dielectric layer 40 in the array region 13 and removing the cover layer 42 in the peripheral region 14 include:
[0076] forming a photoresist layer 72 on the substrate 15 , wherein the photoresist layer 72 includes etching windows exposing the array region 13 and the first peripheral region 141 ;
[0077] A portion of the dielectric layer 40 in the array region 13 is removed along the etching window, and the cover layer 42 in the first peripheral region 141 is removed.
[0078] Specifically, the peripheral region 14 includes a first peripheral region 141 adjacent to the array region 13, and a second peripheral region 142 away from the array region 13 and adjacent to the first peripheral region 141. Figure 2As shown. In one example, the semiconductor structure further includes a plurality of bit lines 11 extending along the first direction D1 and spaced apart along the third direction D3, and a plurality of word lines 12 extending along the third direction D3 and spaced apart along the first direction D1. The bit lines 11 are electrically connected to the plurality of active pillars 30 spaced apart along the first direction D1, and the word lines 12 are electrically connected to the plurality of active pillars 30 spaced apart along the third direction D3. The word lines 12 and the bit lines 11 extend from the array region 13 to the first peripheral region 141, i.e., the ends of the word lines 12 and the bit lines 11 are located in the first peripheral region 141. The first peripheral region 141 further includes word line leads for leading out or leading in signals of the word lines 12, and bit line leads for leading out or leading in signals of the bit lines 11. The second peripheral region 142 is used to form a control circuit (e.g., a CMOS circuit), which transmits a control signal to the bit line lead and the word line lead via a bridge circuit located in the peripheral region 14. In one example, the second peripheral region 142 includes a peripheral active pillar 73 located on the substrate 15 and a peripheral isolation layer 80 covering the surface of the peripheral active pillar 73. Figure 7 As shown. Among them, Figure 7 yes Figure 2 The cross-sectional view of the position ee in the middle is before the dielectric layer 40 is formed. Subsequently, the dielectric layer 40, the isolation layer 41 and the cover layer 42 are formed simultaneously in the array region 13, the first peripheral region 141 and the second peripheral region 142. Figure 8 As shown. Among them, Figure 8 yes Figure 2 A schematic cross-sectional view of the center ee position after the cover layer 42 is formed.
[0079] Afterwards, the isolation layer 41 can be used as a grinding stop layer, and a planarization process such as chemical mechanical polishing can be used to remove part of the cover layer 42, exposing the isolation layer 41 in the array region 13 and the isolation layer 41 in the second peripheral region 142, and making the top surface of the isolation layer 41 remaining in the array region 13 after the planarization process flush with the top surface of the cover layer 42 remaining in the peripheral region 14 (including the first peripheral region 141 and the second peripheral region 142), as shown in FIG. Figure 5 and 9 As shown. Among them, Figure 5 yes Figure 2 The cross-sectional view of the cover layer 42 at position aa in the figure is shown after the cover layer 42 is planarized. Figure 9 yes Figure 2A schematic cross-sectional view of the ee position in the middle after the cover layer 42 is planarized. Next, a stripping process may be used to remove the isolation layer 41 exposed in the array region 13 and the isolation layer 41 exposed in the second peripheral region 142 to expose the dielectric layer 40 in the array region 13. Figure 6 and Figure 10 As shown. Among them, Figure 6 yes Figure 2 The cross-sectional view of the position aa in FIG. 4 after the isolation layer 41 is peeled off and exposed, Figure 10 yes Figure 2 A schematic cross-sectional view of the middle ee position after the isolation layer 41 is peeled off and exposed.
[0080] In order to protect the isolation structure such as the peripheral isolation layer 80 in the second peripheral region 142 and avoid damaging the second peripheral region 142, before etching back the dielectric layer 40, a second mask layer 70, a third mask layer 71 located above the second mask layer 70, and the photoresist layer 72 located above the third mask layer 71 can be formed above the array region 13 and the peripheral region 14. The photoresist layer 72 is patterned by a mask to form the etching window exposing the array region 13 and the first peripheral region 141, as shown in FIG. Figure 11 shown. Figure 11 Shown respectively Figure 2 Schematic cross-sectional view of the positions aa and ee in FIG. 7 after the patterned photoresist layer 72 is formed. The third mask layer 71 and the second mask layer 70 are etched downward along the etching window to expose the dielectric layer 40 in the array region 13 and the cover layer 42 in the first peripheral region 141. Afterwards, a wet etching process can be used to back-etch away a portion of the dielectric layer in the array region 13 and all of the cover layer 42 in the first peripheral region 141 along the etching window. After removing the photoresist layer 72, the second mask layer 70 and the third mask layer 71, the following is obtained: Figure 12 The structure shown. Figure 12 Shown respectively Figure 2 Schematic cross-sectional view at positions aa and ee after removing the photoresist layer 72, the second mask layer 70, and the third mask layer 71. In one example, by adjusting the etching parameters (e.g., etching time, etchant dosage, etc.) of the wet etching process, the top surface of the dielectric layer 40 remaining in the array region 13 can be lower than the top surface of the dielectric layer 40 in the first peripheral region 141, thereby facilitating control of the depth of the subsequently formed conductive layer 140.
[0081] In some embodiments, before depositing the conductive material on the array region 13 and the peripheral region 14, the following steps are further included:
[0082] A functional layer 131 is formed to cover the sidewalls of the active pillar 30. In one example, the functional layer 131 may be an oxide layer (eg, a silicon dioxide layer) formed by a deposition process or an in-situ water vapor growth process, and may subsequently serve as a gate dielectric layer.
[0083] In some embodiments, the specific steps of forming the conductive material layer 130 covering the array region 13 and the peripheral region 14 include:
[0084] Conductive material is deposited on the array region 13 and the peripheral region 14 to form the conductive material layer 130. The conductive material layer 130 covers the remaining surface of the dielectric layer 40 in the array region 13, fills the gaps between adjacent active pillars 30, covers the functional layer 131, and covers the isolation layer 41 in the peripheral region 14. Figure 13 shown.
[0085] In some embodiments, the specific steps of forming the conductive layer 140 electrically connected to the active pillar 30 include:
[0086] Part of the conductive material layer 130 in the array area 13 and the entire conductive material layer 130 in the peripheral area 14 are etched back to expose the isolation layer 41 in the peripheral area 14, and the remaining conductive material layer 130 in the array area 13 is used as the conductive layer 140, and the top surface of the conductive layer 140 is located below the top surface of the active pillar 30.
[0087] In some embodiments, before etching back a portion of the conductive material layer 130 in the array region 13 and the entire conductive material layer 130 in the peripheral region 14 , the following steps are further included:
[0088] The conductive material layer 130 is planarized so that a top surface of the conductive material layer 130 in the array region 13 is flush with a top surface of the conductive material layer 130 in the peripheral region 14 .
[0089] For example, during the deposition of the conductive material, the same photomask as used for etching back the dielectric layer 40 in the array region 13 can be used to further reduce the manufacturing cost of the semiconductor structure. A conductive material such as TiN or metallic tungsten can be deposited in the array region 13 and the first peripheral region 141 using a chemical vapor deposition process, a physical vapor deposition process, or an atomic layer deposition process to form the conductive material layer 130. Subsequently, a planarization process such as chemical mechanical polishing can be used to treat the conductive material layer 130 so that the top surface of the conductive material layer 130 remaining in the array region 13 is flush with the top surface of the conductive material layer 130 remaining in the first peripheral region 141. Afterwards, the same photomask as that used in back-etching the dielectric layer 40 in the array region 13 can be used to back-etch the entire conductive material layer 130 in the first peripheral region 141 and a portion of the conductive material layer 130 in the array region 13. For example, the entire conductive material layer 130 covering the surface of the isolation layer 41 is removed, thereby exposing the entire surface of the isolation layer 41 in the first peripheral region 141. That is, the remaining conductive material layer 130 in the array region 13 can cover the channel region in the active pillar to form the conductive layer 140. In addition, in the second direction D2, the entire isolation layer 41 is positioned higher than the conductive layer 140. Figure 14 shown.
[0090] Because this embodiment does not shield the first peripheral region 141 during the process of etching back the dielectric layer 40, there is no need to use a photoresist layer or mask layer to cover the first peripheral region 141 during the process of etching back the dielectric layer 40. This helps reduce the manufacturing cost of the semiconductor structure and improves the manufacturing efficiency of the semiconductor structure. At the same time, this embodiment simultaneously removes the conductive material layer 130 in the first peripheral region 141 during the process of etching back the conductive material layer 130 in the array region 13, thereby reducing or even eliminating the residual conductive material layer 130 in the first peripheral region 141, further improving the performance of the semiconductor structure. In addition, before back-etching the conductive material layer 130, this specific embodiment performs a planarization treatment on the conductive material layer 130, so that the top surface of the conductive material layer 130 remaining in the array area 13 is flush with the top surface of the conductive material layer 130 remaining in the first peripheral area 141, thereby helping to control the etching amount of the conductive material layer 130 during the back-etching process. While ensuring that the conductive material layer 130 in the first peripheral area 141 is fully removed, the height of the conductive material layer 130 remaining in the array area 13 can be accurately controlled, thereby improving the controllability of the semiconductor structure process technology.
[0091] In some embodiments, the peripheral region 14 is located outside the array region 13 along a first direction D1. The isolation layer 41 of the peripheral region 14 includes a first portion 411 extending along a second direction D2, and a second portion 412 connected to the first portion 411 and extending along the first direction D1. The first direction D1 is parallel to the top surface of the substrate 15, and the second direction D2 is perpendicular to the top surface of the substrate.
[0092] The top surface of the conductive layer 140 is flush with the top surface of the second part 412, thereby ensuring the electrical performance stability of the conductive layer 140 closest to the isolation layer 41; or, the top surface of the conductive layer 140 is located below the top surface of the second part 412, thereby further ensuring that the conductive material layer 130 in the first peripheral area 141 can be fully removed, thereby further avoiding the conductive material layer 130 from remaining in the first peripheral area 141.
[0093] For example, during the deposition of the conductive material layer 130, the width of the conductive material layer 130 along the first direction D1 can be made equal to the width of the dielectric layer 40 formed in step S12 along the first direction D1, so that when the conductive material layer 130 is subsequently etched back, the conductive material layer 130 on the surface of the isolation layer 41 is completely removed, and the top surface of the formed conductive layer 140 is flush with the top surface of the second part 412 of the isolation layer 41.
[0094] In some embodiments, after removing part of the conductive material layer 130 in the array region 13 and all of the conductive material layer 130 in the peripheral region 14 , the following steps are further included:
[0095] A spacer layer 150 is formed covering the conductive layer 140, the active pillar 30 and the isolation layer 41. Figure 15 As shown, Figure 15 Implementation Figure 2 Schematic cross-sectional view of the position aa in FIG. 1 after forming the spacer layer 150. In one example, the spacer layer 150 is made of an oxide material, such as silicon dioxide.
[0096] In some embodiments, the active pillar 30 includes a channel region, and a source region and a drain region distributed on opposite sides of the channel region along a second direction D2, wherein the second direction D2 is perpendicular to the top surface of the substrate 15;
[0097] The conductive layer 140 is a word line covering the channel region.
[0098] In some embodiments of this embodiment, a method for forming a semiconductor structure provides a method for exposing an active pillar without using a mask covering the outer region. Instead, the method removes a portion of the dielectric layer in the array region and the outer region's outer layer, thereby reducing the number of masks required in the semiconductor structure's manufacturing process and lowering the manufacturing cost of the semiconductor structure. Furthermore, in some embodiments of this embodiment, the outer region's outer layer is removed during the removal of the portion of the dielectric layer in the array region. A conductive material layer is deposited simultaneously in both the array region and the outer region. Subsequently, when forming the conductive layer, the portion of the conductive material layer in the array region and the entire conductive material layer in the outer region are removed. This prevents the conductive material layer from remaining in the outer region, improves the electrical isolation between the conductive layer and the outer region, and thus improves the performance of the semiconductor structure. Furthermore, in some embodiments of this embodiment, the thickness of the dielectric layer is limited to 40 nm to 100 nm, which allows the conductive layer formed after etching back to be positioned lower than the isolation layer, further improving the electrical isolation between the conductive layer and the outer region without significantly increasing the size of the semiconductor structure.
[0099] The above is only a preferred embodiment of the present disclosure. It should be pointed out that ordinary technicians in this technical field can make several improvements and modifications without departing from the principles of the present disclosure. These improvements and modifications should also be regarded as within the scope of protection of the present disclosure.
Claims
1. A method for forming a semiconductor structure, characterized in that: The steps include: Providing a substrate, the substrate comprising an array region and a peripheral region located outside the array region along a first direction, the array region comprising a plurality of active pillars arranged at intervals, the first direction being parallel to a top surface of the substrate; forming a dielectric layer covering the array region and the peripheral region, an isolation layer covering the sidewalls and top surface of the dielectric layer in the peripheral region, and a cover layer covering the isolation layer, wherein the dielectric layer located at the junction of the array region and the peripheral region and covering the sidewalls of the active pillars has a width along the first direction of 40 nm to 100 nm; removing a portion of the dielectric layer in the array area and removing the cover layer in the peripheral area to expose the active pillars; forming a conductive material layer covering the array area and the peripheral area; A portion of the conductive material layer in the array area and the entire conductive material layer in the peripheral area are removed to form a conductive layer electrically connected to the active pillar.
2. The method for forming a semiconductor structure according to claim 1, wherein: The specific steps of forming a dielectric layer covering the array region and the peripheral region, an isolation layer covering the sidewalls and top surface of the dielectric layer in the peripheral region, and a cover layer covering the isolation layer include: forming the active pillars covering the array region and the dielectric layer covering the peripheral region, wherein a top surface of the dielectric layer in the array region is located below a top surface of the dielectric layer in the peripheral region; forming the isolation layer continuously distributed in the array region and the peripheral region and covering the surface of the dielectric layer; forming a covering layer continuously distributed in the array region and the peripheral region and covering the surface of the isolation layer; The covering layer and the isolation layer in the array area are removed, and a portion of the covering layer in the peripheral area is removed.
3. The method for forming a semiconductor structure according to claim 2, wherein: The specific steps of forming the active pillars covering the array area and the dielectric layer covering the peripheral area include: forming a first dielectric layer covering surfaces of the active pillars in the array region and a surface of the substrate in the peripheral region; forming a second dielectric layer covering the first dielectric layer; A third dielectric layer covering the second dielectric layer is formed to form the dielectric layer including the first dielectric layer, the second dielectric layer and the third dielectric layer.
4. The method for forming a semiconductor structure according to claim 2, wherein: The specific steps of removing the covering layer and the isolation layer in the array area and removing part of the covering layer in the peripheral area include: Using a planarization process to remove all of the covering layer in the array area and partially remove the covering layer in the peripheral area, exposing the isolation layer in the array area; The isolation layer in the array area is removed to expose the dielectric layer in the array area.
5. The method for forming a semiconductor structure according to claim 1, wherein: The specific steps of removing part of the dielectric layer in the array area and removing the cover layer in the peripheral area include: A wet etching process is adopted to remove a portion of the dielectric layer in the array area and the cover layer in the peripheral area, thereby exposing the active pillars in the array area and the isolation layer in the peripheral area.
6. The method for forming a semiconductor structure according to claim 1, wherein: The specific steps of removing part of the dielectric layer in the array area and removing the cover layer in the peripheral area include: Part of the dielectric layer in the array area is removed, and the covering layer in the peripheral area is removed to expose the active pillars in the array area and the isolation layer in the peripheral area, and the top surface of the remaining dielectric layer in the array area is located below the top surface of the dielectric layer in the peripheral area.
7. The method for forming a semiconductor structure according to claim 1, wherein: The peripheral region includes a first peripheral region adjacent to the array region and a second peripheral region outside the first peripheral region; The specific steps of removing part of the dielectric layer in the array area and removing the cover layer in the peripheral area include: forming a photoresist layer on the substrate, wherein the photoresist layer includes an etching window exposing the array region and the first peripheral region; A portion of the dielectric layer in the array area is removed along the etching window, and the cover layer in the first peripheral area is removed.
8. The method for forming a semiconductor structure according to claim 1, wherein: Before depositing the conductive material on the array area and the peripheral area, the method further includes the following steps: A functional layer is formed to cover the sidewalls of the active pillar.
9. The method for forming a semiconductor structure according to claim 8, wherein: The specific steps of forming a conductive material layer covering the array area and the peripheral area include: Conductive material is deposited in the array area and the peripheral area to form the conductive material layer, which covers the remaining surface of the dielectric layer in the array area, fills the gaps between adjacent active pillars, covers the functional layer, and covers the isolation layer in the peripheral area.
10. The method for forming a semiconductor structure according to claim 1, wherein: The specific steps of forming a conductive layer electrically connected to the active pillar include: Part of the conductive material layer in the array area and the entire conductive material layer in the peripheral area are etched back to expose the isolation layer in the peripheral area, and the remaining conductive material layer in the array area is used as the conductive layer, and the top surface of the conductive layer is located below the top surface of the active column.
11. The method for forming a semiconductor structure according to claim 1, wherein: Before etching back part of the conductive material layer in the array area and the entire conductive material layer in the peripheral area, the following steps are also included: The conductive material layer is planarized so that a top surface of the conductive material layer in the array region is flush with a top surface of the conductive material layer in the peripheral region.
12. The method for forming a semiconductor structure according to claim 1, wherein: The peripheral region is located outside the array region along a first direction, the isolation layer in the peripheral region includes a first portion extending along a second direction, and a second portion connected to the first portion and extending along the first direction, the first direction is parallel to the top surface of the substrate, and the second direction is perpendicular to the top surface of the substrate; The top surface of the conductive layer is flush with the top surface of the second portion; Alternatively, the top surface of the conductive layer is located below the top surface of the second portion.
13. The method for forming a semiconductor structure according to claim 1, wherein: After removing part of the conductive material layer in the array area and all of the conductive material layer in the peripheral area, the method further includes the following steps: A spacer layer is formed covering the conductive layer, the active pillar and the isolation layer.
14. The method for forming a semiconductor structure according to claim 1, wherein: The active pillar includes a channel region, and a source region and a drain region distributed on opposite sides of the channel region along a second direction, wherein the second direction is perpendicular to the top surface of the substrate; The conductive layer is a word line covering the channel region.
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