Preparation method of frosted embossed stained paper for ceramics

Abstract

The invention provides a preparation method of frosted embossed stained paper for ceramics, and relates to the technical field of ceramic decal paper. The preparation method of the frosted embossed stained paper for ceramics specifically comprises the following steps: S1, preparing ground color stained paper; s2, preparing embossed stained paper; and S3, preparing the frosted embossed stained paper. According to the preparation method of the frosted embossment stained paper for the ceramics, the frosted embossment stained paper prepared through the preparation method of the frosted embossment stained paper for the ceramics is high in adhesion degree with a ceramic vessel, good in fitness and not prone to deformation, has the artistic effect of frosted porcelain, also has the concave-convex feeling of the embossment stained paper, can achieve the effect similar to the frosted embossment, and can be used for preparing the frosted embossment stained paper for the ceramics. The appearance is more attractive.

Description

Technical Field

[0001] The invention relates to the technical field of ceramic decals, in particular to a method for preparing frosted embossed decals for ceramics. Background Art

[0002] Ceramic decal paper is a tool for adding decorative patterns or text to ceramic products. It is also often called ceramic transfer paper or decals. This paper is printed with special ink that can transfer the pattern from the paper to the ceramic surface through heat transfer.

[0003] Ceramic decals are special printed products used to decorate ceramics. The drawings designed according to the shape of ceramic vessels are separated into colors and plated. The ink prepared with ceramic pigments is printed on special printing paper or plastic film, and then attached to the surface of the ceramic. After high-temperature baking, a bright, colorful, and firmly attached fine picture is formed, achieving a decorative effect that adds icing on the cake to the ceramic. At present, the frosted relief ceramics on the market are all achieved through screen printing. However, under this vast market demand, there is no product that can achieve a similar frosted relief effect with ordinary ceramic decals. The artistic effect is relatively simple, which is difficult to meet the needs of some customers and lacks in aesthetics. Summary of the invention

[0004] 1. Technical issues to be resolved

[0005] In view of the deficiencies in the prior art, the present invention provides a method for preparing frosted embossed decal paper for ceramics, which solves the problem that the existing common ceramic decal paper is difficult to achieve a similar frosted embossed effect.

[0006] (II) Technical solution

[0007] To achieve the above objectives, the present invention is implemented by the following technical scheme: a method for preparing frosted embossed paper for ceramics, specifically comprising the following steps:

[0008] S1. Preparation of base color flower paper

[0009] Mix the base color pigment with the ink, print it on the base paper with a 230 mesh screen, and dry it for 4-8 hours to obtain the base color flower paper;

[0010] S2. Preparation of embossed paper

[0011] Mix the frosted relief pigment and the cooling curing agent with the ink, and print them on the base color paper with a 140 mesh screen. After drying for 3-4 hours, print them repeatedly for 4 times and dry them for 12-16 hours to obtain the relief paper.

[0012] S3. Made into frosted embossed paper

[0013] Print the cover glue onto the flower paper with 80 mesh screen and dry it for 2-5 hours to get the frosted embossed flower paper for ceramics.

[0014] Preferably, the base color pigment in step S1 includes the following components in parts by mass: 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 20-30 parts of boron oxide, and 30-40 parts of feldspar.

[0015] Preferably, the preparation method of the base color pigment is: silicon dioxide, lead-free frit, boron oxide and feldspar are mixed, calcined at 1200-1300°C, ball milled after cooling, dried, and passed through a 300-mesh sieve to obtain the base color pigment.

[0016] Preferably, in step S1, the mixing mass ratio of the base color pigment to the ink is 10:6-8.

[0017] Preferably, the frosted relief pigment and the cooling curing agent in step S2 include the following components in parts by mass: 5-10 parts of cooling curing agent, 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 20-30 parts of zinc oxide, and 30-40 parts of feldspar.

[0018] Preferably, the preparation method of the frosted relief pigment is: silicon dioxide, lead-free frit, zinc oxide and feldspar are mixed, calcined at 1200-1300° C., after cooling, phosphor is added for ball milling, drying, and passing through a 300-mesh sieve to obtain the frosted relief pigment.

[0019] Preferably, in step S2, the mixing mass ratio of the frosted relief pigment to the ink is 10:6-8.

[0020] A method for using frosted embossed paper for ceramics, comprising the following steps:

[0021] a. Soaking frosted embossed paper

[0022] Soak the frosted embossed paper in a mixture of acetic acid and water for 30-40 seconds;

[0023] b. Frosted embossed paper lamination

[0024] Remove the backing paper from the frosted embossed paper, stick it on the surface of the ceramic ware, and squeeze to remove bubbles;

[0025] c. Decorative paper baking

[0026] The ceramic ware with the flower paper is left to stand for 24 hours to dry before being put into the baking production line for baking.

[0027] Preferably, in step a, the mass ratio of the mixed solution of acetic acid and water is 1:4-5, and the temperature of the mixed solution is 25-40° C., and in step c, the baking temperature is 680-780° C., and the baking time is 6-8 hours.

[0028] (III) Beneficial effects

[0029] The present invention provides a method for preparing frosted embossed paper for ceramics, which has the following beneficial effects:

[0030] The invention provides a method for preparing frosted embossed flower paper for ceramics. The frosted flower paper is made of feldspar, borax, kaolin and low-temperature lead-free frit. After the frosted flower paper is applied to ceramic products, the products not only have the artistic effect of frosted porcelain, but also have the concave-convex feeling of embossed flower paper, and can achieve a similar frosted embossed effect to meet people's personalized needs. The invention also provides a decaling method thereof. The flower paper has high adhesion to the ceramic vessel, good lamination, and is not easy to deform. DETAILED DESCRIPTION

[0031] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative work are within the scope of protection of the present invention.

[0032] Embodiment 1:

[0033] The embodiment of the present invention provides a method for preparing frosted embossed paper for ceramics, which specifically comprises the following steps:

[0034] S1. Preparation of base color flower paper

[0035] Mix the base color pigment with the ink, print it on the base paper with a 230 mesh screen, and dry it for 4 hours to obtain the base color flower paper;

[0036] S2. Preparation of embossed paper

[0037] Mix the frosted relief pigment and the cooling curing agent with the ink, and print them on the base color paper with a 140 mesh screen. After drying for 3 hours, print them repeatedly for 4 times and dry them for 12 hours to obtain the relief paper.

[0038] S3. Made into frosted embossed paper

[0039] Print the cover glue onto the flower paper with 80 mesh screen and dry it for 2 hours to obtain the frosted embossed flower paper for ceramics.

[0040] The base color pigment in step S1 includes the following components in parts by mass: 20 parts of silicon dioxide, 10 parts of lead-free frit, 20 parts of boron oxide, and 30 parts of feldspar. The preparation method of the base color pigment is: mixing silicon dioxide, lead-free frit, boron oxide, and feldspar, calcining at 1200°C, ball milling after cooling, drying, and passing through a 300-mesh sieve to obtain the base color pigment. The mixing mass ratio of the base color pigment to the ink in step S1 is 10:6.

[0041] The frosted relief pigment and the cooling curing agent in step S2 include the following components in parts by mass: 5 parts of cooling curing agent, 20 parts of silicon dioxide, 10 parts of lead-free frit, 20 parts of zinc oxide, and 30 parts of feldspar. The preparation method of the frosted relief pigment is: mixing silicon dioxide, lead-free frit, zinc oxide, and feldspar, calcining at 1200° C., adding fluorescent powder after cooling, ball milling, drying, and passing through a 300-mesh sieve to obtain the frosted relief pigment. The mixing mass ratio of the frosted relief pigment to the ink in step S2 is 10:6.

[0042] A method for using frosted embossed paper for ceramics, specifically comprising the following steps:

[0043] a. Soaking frosted embossed paper

[0044] Soak the frosted embossed paper in a mixture of acetic acid and water for 30 seconds;

[0045] b. Frosted embossed paper lamination

[0046] Remove the backing paper from the frosted embossed paper, stick it on the surface of the ceramic ware, and squeeze to remove bubbles;

[0047] c. Decorative paper baking

[0048] The ceramic ware with the flower paper is left to stand for 24 hours to dry before being put into the baking production line for baking.

[0049] The mass ratio of the mixed liquid of acetic acid and clean water in step a is 1:4. Adding acetic acid to water can soften the embossed paper to a certain extent, and the embossed paper can better fit the ceramic vessel when the frosted embossed paper is pasted, and the temperature of the mixed liquid is 25° C. The baking temperature in step c is 680° C. and the baking time is 6 hours. After pasting, the ceramic vessel is embossed, which can stabilize the fit between the frosted embossed paper and the ceramic vessel and prevent bubbles from appearing between the frosted embossed paper and the ceramic vessel.

[0050] Embodiment 2:

[0051] The embodiment of the present invention provides a method for preparing frosted embossed paper for ceramics, which specifically comprises the following steps:

[0052] S1. Preparation of base color flower paper

[0053] Mix the base color pigment with the ink, print it on the base paper with a 230 mesh screen, and dry it for 6 hours to obtain the base color flower paper;

[0054] S2. Preparation of embossed paper

[0055] Mix the frosted relief pigment and the cooling curing agent with the ink, and print them on the base color paper with a 140 mesh screen. After drying for 3.5 hours, print them repeatedly for 4 times and dry them for 14 hours to obtain the relief paper.

[0056] S3. Made into frosted embossed paper

[0057] Print the cover glue onto the flower paper with 80 mesh screen and dry it for 3.5 hours to obtain the frosted embossed flower paper for ceramics.

[0058] The base color pigment in step S1 includes the following components in parts by mass: 25 parts of silicon dioxide, 13 parts of lead-free frit, 25 parts of boron oxide, and 35 parts of feldspar. The preparation method of the base color pigment is: mixing silicon dioxide, lead-free frit, boron oxide, and feldspar, calcining at 1250°C, ball milling after cooling, drying, and passing through a 300-mesh sieve to obtain the base color pigment. The mixing mass ratio of the base color pigment to the ink in step S1 is 10:7.

[0059] The frosted relief pigment and the cooling curing agent in step S2 include the following components in parts by mass: 8 parts of cooling curing agent, 25 parts of silicon dioxide, 13 parts of lead-free frit, 25 parts of zinc oxide, and 35 parts of feldspar. The preparation method of the frosted relief pigment is: mixing silicon dioxide, lead-free frit, zinc oxide, and feldspar, calcining at 1250°C, adding fluorescent powder after cooling, ball milling, drying, and passing through a 300-mesh sieve to obtain the frosted relief pigment. The mixing mass ratio of the frosted relief pigment to the ink in step S2 is 10:7.

[0060] A method for using frosted embossed paper for ceramics, specifically comprising the following steps:

[0061] a. Soaking frosted embossed paper

[0062] Soak the frosted embossed paper in a mixture of acetic acid and water for 35 seconds;

[0063] b. Frosted embossed paper lamination

[0064] Remove the backing paper from the frosted embossed paper, stick it on the surface of the ceramic ware, and squeeze to remove bubbles;

[0065] c. Decorative paper baking

[0066] The ceramic ware with the flower paper is left to stand for 24 hours to dry before being put into the baking production line for baking.

[0067] A method for using frosted embossed paper for ceramics: in step a, the mass ratio of the mixed liquid of acetic acid and clean water is 1:4.5. Acetic acid is added to water to soften the embossed paper to a certain extent, and the embossed paper has a better fit with the ceramic vessel when the frosted embossed paper is pasted, and the temperature of the mixed liquid is 32° C. In step c, the baking temperature is 730° C. and the baking time is 7 hours. After pasting, the ceramic vessel is embossed, which can stabilize the fit between the frosted embossed paper and the ceramic vessel and prevent bubbles from appearing between the frosted embossed paper and the ceramic vessel.

[0068] Embodiment 3:

[0069] The embodiment of the present invention provides a method for preparing frosted embossed paper for ceramics, which specifically comprises the following steps:

[0070] S1. Preparation of base color flower paper

[0071] Mix the base color pigment with the ink, print it on the base paper with a 230 mesh screen, and dry it for 8 hours to obtain the base color flower paper;

[0072] S2. Preparation of embossed paper

[0073] Mix the frosted relief pigment and the cooling curing agent with the ink, and print them on the base color paper with a 140 mesh screen. After drying for 4 hours, print them repeatedly for 4 times and dry them for 16 hours to obtain the relief paper.

[0074] S3. Made into frosted embossed paper

[0075] Print the cover glue onto the flower paper with 80 mesh screen and dry it for 5 hours to obtain the frosted embossed flower paper for ceramics.

[0076] The base color pigment in step S1 includes the following components in parts by mass: 30 parts of silicon dioxide, 15 parts of lead-free frit, 30 parts of boron oxide, and 40 parts of feldspar. The preparation method of the base color pigment is: mixing silicon dioxide, lead-free frit, boron oxide, and feldspar, calcining at 1300° C., ball milling after cooling, drying, and passing through a 300-mesh sieve to obtain the base color pigment.

[0077] The mixing mass ratio of the base color pigment to the ink in step S1 is 10:8. The frosted relief pigment and the cooling curing agent in step S2 include the following components in mass fractions: 10 parts of cooling curing agent, 30 parts of silicon dioxide, 15 parts of lead-free frit, 30 parts of zinc oxide, and 40 parts of feldspar. The preparation method of the frosted relief pigment is: mixing silicon dioxide, lead-free frit, zinc oxide, and feldspar, calcining at 1300°C, adding fluorescent powder after cooling, ball milling, drying, and passing through a 300-mesh sieve to obtain the frosted relief pigment. The mixing mass ratio of the frosted relief pigment to the ink in step S2 is 10:8.

[0078] A method for using frosted embossed paper for ceramics, specifically comprising the following steps:

[0079] a. Soaking frosted embossed paper

[0080] Soak the frosted embossed paper in a mixture of acetic acid and water for 40 seconds;

[0081] b. Frosted embossed paper lamination

[0082] Remove the backing paper from the frosted embossed paper, stick it on the surface of the ceramic ware, and squeeze to remove bubbles;

[0083] c. Decorative paper baking

[0084] The ceramic ware with the flower paper is left to stand for 24 hours to dry before being put into the baking production line for baking.

[0085] The mass ratio of the mixed liquid of acetic acid and clean water in step a is 1:5. Adding acetic acid to water can soften the embossed paper to a certain extent, and the embossed paper can better fit the ceramic vessel when the frosted embossed paper is pasted, and the temperature of the mixed liquid is 40°C. The baking temperature in step c is 780°C, and the baking time is 8 hours. After pasting, the ceramic vessel is embossed, which can stabilize the fit between the frosted embossed paper and the ceramic vessel and prevent bubbles from appearing between the frosted embossed paper and the ceramic vessel.

[0086] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. A method for preparing frosted embossed paper for ceramics, characterized in that: The specific steps include: S1. Preparation of base color flower paper Mix the base color pigment with the ink, print it on the base paper with a 230 mesh screen, and dry it for 4-8 hours to obtain the base color flower paper; S2. Preparation of embossed paper Mix the frosted relief pigment and the cooling curing agent with the ink, and print them on the base color paper with a 140 mesh screen. After drying for 3-4 hours, print them repeatedly for 4 times and dry them for 12-16 hours to obtain the relief paper. S3. Make frosted embossed paper Print the cover glue onto the flower paper with 80 mesh screen and dry it for 2-5 hours to get the frosted embossed flower paper for ceramics.

2. The method for preparing frosted embossed paper for ceramics according to claim 1, characterized in that: The base color pigment in step S1 includes the following components in parts by mass: 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 20-30 parts of boron oxide, and 30-40 parts of feldspar.

3. The method for preparing frosted embossed paper for ceramics according to claim 2, characterized in that: The preparation method of the base color pigment is as follows: silicon dioxide, lead-free frit, boron oxide and feldspar are mixed, calcined at 1200-1300° C., ball-milled after cooling, dried and sieved through a 300-mesh sieve to obtain the base color pigment.

4. The method for preparing frosted embossed paper for ceramics according to claim 1, characterized in that: In step S1, the mixing mass ratio of the base color pigment to the ink is 10:6-8.

5. The method for preparing frosted embossed paper for ceramics according to claim 1, characterized in that: The frosted relief pigment and the cooling curing agent in step S2 include the following components in parts by mass: 5-10 parts of cooling curing agent, 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 20-30 parts of zinc oxide, and 30-40 parts of feldspar.

6. The method for preparing frosted embossed paper for ceramics according to claim 5, characterized in that: The preparation method of the frosted relief pigment is as follows: silicon dioxide, lead-free frit, zinc oxide and feldspar are mixed, calcined at 1200-1300° C., after cooling, phosphor powder is added for ball milling, drying and passing through a 300-mesh sieve to obtain the frosted relief pigment.

7. The method for preparing frosted embossed paper for ceramics according to claim 1, characterized in that: The mixing mass ratio of the frosted relief pigment to the ink in step S2 is 10:6-8.

8. The method for using the frosted embossed paper for ceramics according to any one of claims 1 to 7, characterized in that: The specific steps include: a. Soaking frosted embossed paper Soak the frosted embossed paper in a mixture of acetic acid and water for 30-40 seconds; b. Frosted embossed paper lamination Remove the backing paper from the frosted embossed paper, stick it on the surface of the ceramic ware, and squeeze to remove bubbles; c. Decorative paper baking The ceramic ware with the flower paper is left to stand for 24 hours to dry before being put into the baking production line for baking.

9. The method for using the frosted embossed paper for ceramics according to claim 8, characterized in that: In the step a, the mass ratio of the mixed liquid of acetic acid and water is 1:4-5, and the temperature of the mixed liquid is 25-40° C., and the baking temperature in the step c is 680-780° C., and the baking time is 6-8 hours.