Organic liquid hydrogen storage intelligent control system

By designing an intelligent control system for organic liquid hydrogen storage, real-time detection and monitoring of the status of organic liquid hydrogen storage equipment, the problem of lack of overall control in the existing technology of hydrogen refueling, transportation and dehydrogenation processes is solved, and the efficiency and safety of hydrogen storage are improved.

CN119620811APending Publication Date: 2025-03-14SUZHOU QINGDA NEW ENERGY AUTOMOBILE TECH CO LTD
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Patent Information

Application Number
CN202411751755.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-02
Publication Date
2025-03-14

AI Technical Summary

Technical Problem

The existing organic liquid hydrogen storage technology lacks overall control and coordination during hydrogenation, transportation and dehydrogenation, resulting in low hydrogen storage efficiency, large losses and increased manpower investment.

Method used

An intelligent control system for hydrogen storage of organic liquid is designed, including a hydrogen delivery control module, a pressure detection control module, a temperature detection control module, a safety detection module and an organic liquid saturation detection module. By real-time detection and monitoring of the status of organic liquid hydrogen storage equipment, intelligent control of hydrogen refueling, transportation and dehydrogenation processes are achieved.

Benefits of technology

It improves the efficiency and safety of the organic liquid hydrogen storage process, reduces hydrogen storage losses and manpower investment, and achieves coordinated control of the overall process.

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Abstract

The invention relates to the technical field of organic liquid hydrogen storage, in particular to an intelligent control system for organic liquid hydrogen storage, which is characterized in that a hydrogen conveying control module is used for controlling hydrogen conveying and hydrogenation processes of organic liquid hydrogen storage equipment; in the hydrogenation process, the pressure intensity detection control module and the temperature detection control module are used for detecting and monitoring the pressure intensity and temperature conditions of the organic liquid hydrogen storage equipment in real time, in the hydrogenation process, the safety detection module is used for detecting and monitoring the operation environment of the organic liquid hydrogen storage equipment and controlling the gas inlet and outlet valve, and in the hydrogenation process, the safety detection module is used for controlling the gas inlet and outlet valve. And the organic liquid saturation detection module judges the saturation of the hydrogenated organic liquid according to the quality and color of the organic liquid and controls the hydrogenation progress. The system has the advantages that the hydrogen sensing device and the liquid level sensor are arranged on the conveying pipeline and the organic liquid hydrogenation equipment respectively, the organic liquid adding condition and the hydrogen conveying condition are monitored, and the hydrogen conveying control module can conveniently detect and control the hydrogenation process of the organic liquid hydrogenation equipment.
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Description

Technical Field

[0001] The invention relates to the technical field of organic liquid hydrogen storage, in particular to an intelligent control system for organic liquid hydrogen storage. Background Art

[0002] Organic liquid hydrogen storage technology refers to the storage of hydrogen through the reversible reaction and hydrogenation reaction of unsaturated liquid organic matter such as certain olefins, alkynes or aromatic hydrocarbons and hydrogen, and the release of hydrogen through the dehydrogenation reaction. The mass hydrogen storage density is 5%-10%, and the hydrogen storage capacity is large. The hydrogen storage material is liquid organic matter, which can be transported at room temperature and pressure, which is convenient and safe. In the process of organic liquid hydrogen storage, multiple control modules such as hydrogenation, transportation, and dehydrogenation need to work in coordination. Therefore, the organic liquid hydrogen storage intelligent control system is required to carry out comprehensive control and coordination to improve efficiency.

[0003] An organic liquid in-station hydrogenation station and its control method disclosed in Chinese patent CN116697272A stores hydrogen in a first hydrogen storage tank group and a second hydrogen storage tank group, so that when a car is refueled with hydrogen, the vehicle can be refueled in stages and in sequence, thereby avoiding excessive hydrogen refueling at one time and improving safety during refueling. However, the organic liquid in-station hydrogenation station and its control method mainly control the hydrogenation process, and cannot perform overall control and coordination for the organic liquid hydrogen storage process of hydrogenation, transportation and dehydrogenation, which is likely to affect the hydrogen storage efficiency and cause losses and increased manpower investment. Summary of the invention

[0004] The purpose of the present invention is to overcome the shortcomings of the prior art and provide an intelligent control system for organic liquid hydrogen storage, which effectively solves the deficiencies of the prior art.

[0005] The purpose of the present invention is achieved through the following technical solutions: an intelligent control system for organic liquid hydrogen storage, comprising the following modules and steps:

[0006] 1) The hydrogen delivery control module controls the hydrogen delivery and hydrogenation process of the organic liquid hydrogen storage equipment;

[0007] 2) During the hydrogenation process, the pressure detection control module and the temperature detection control module perform real-time detection and monitoring of the pressure and temperature of the organic liquid hydrogen storage equipment;

[0008] 3) During the hydrogenation process, the safety detection module detects and monitors the operating environment of the organic liquid hydrogen storage equipment and controls the inlet and outlet valves;

[0009] 4) During the hydrogenation process, the organic liquid saturation detection module determines the saturation of the hydrogenated organic liquid based on the quality and color of the organic liquid, and controls the progress of hydrogenation;

[0010] 5) When the hydrogen storage organic liquid is transported and dehydrogenated, the temperature and pressure are controlled, and the dehydrogenation catalyst is automatically replaced and regenerated and recycled.

[0011] Optionally, the hydrogen delivery control module in step 1) controls the internal temperature and pressure of the organic liquid hydrogen storage equipment to reach rated values, and a hydrogen sensing device is set in the delivery pipeline, and a liquid level sensor is set in the organic liquid hydrogenation equipment.

[0012] The above technical solution is adopted: by respectively arranging a hydrogen sensing device and a liquid level sensor on the transmission pipeline and the organic liquid hydrogenation equipment, the organic liquid addition situation and the hydrogen transmission situation are monitored, so that the hydrogen transmission control module can detect and control the hydrogenation process of the organic liquid hydrogenation equipment.

[0013] Optionally, the hydrogen delivery control module in step 1) controls the filling of unsaturated organic liquid into the organic liquid hydrogenation equipment, and the liquid level height is sensed and controlled by a liquid level sensor.

[0014] The above technical solution is adopted: by setting a liquid level sensor in the organic liquid hydrogenation equipment, it is convenient to add an appropriate amount of unsaturated organic liquid in the equipment to carry out hydrogenation storage operations.

[0015] Optionally, the hydrogen sensing device in step 1) starts the mixing device of the organic liquid and hydrogen when the hydrogen gas enters the delivery pipeline, and after the hydrogenation of the organic liquid is completed, the saturated organic liquid is injected into the hydrogen storage organic liquid transportation equipment.

[0016] The above technical solution is adopted: by arranging a hydrogen sensing device in the conveying pipeline, timely feedback can be given on the hydrogen delivery situation, so as to control the mixing and stirring device of the organic liquid and hydrogen to perform gentle stirring only when hydrogen is added, thereby reducing the energy consumed by idling of the mixing and stirring device, and accelerating the mixing efficiency of hydrogen and unsaturated organic liquid through mixing and stirring, thereby improving the hydrogenation efficiency.

[0017] Optionally, the pressure detection control module and the temperature detection control module in the step 2) set the pressure safety threshold and the temperature safety threshold. When the pressure parameter reaches or exceeds the safety threshold, information is sent to the safety detection module. When the temperature parameter reaches or exceeds the safety threshold, information is sent to the safety detection module. After receiving the signal, the safety detection module automatically closes the inlet and outlet valves.

[0018] The above technical solution is adopted: by setting up a pressure and temperature detection control module, the pressure and temperature data of the organic liquid hydrogenation equipment are monitored in real time, reducing the experience input of operators, and being able to respond in time according to the pressure and temperature fluctuations before safety hazards. After the safety detection module processes the information, the extractor valve is closed to interrupt the hydrogenation process, thereby reducing the safety hazards in the hydrogenation process.

[0019] Optionally, the safety detection module in the step 3) is provided with a hydrogen detection device on the outside of the organic liquid hydrogen storage equipment. After the hydrogen detection device detects hydrogen leakage in the organic liquid hydrogen storage equipment, it sends an alarm signal to the control terminal. The safety detection module controls the equipment to automatically close the extractor valve. After receiving the signal that the pressure and temperature exceed the threshold value, the safety detection module automatically closes the extractor valve.

[0020] The above technical solution is adopted: by setting up a safety detection module, the internal temperature and pressure of the organic liquid hydrogenation equipment, as well as the hydrogen leakage in the external environment, are detected in real time, and the hydrogenation operation is terminated in time when there is a safety hazard. The safety detection module reduces the operational risk in the hydrogenation process, reduces the experience investment of the operating personnel, and improves the safety factor.

[0021] Optionally, the organic liquid saturation detection module in step 4) is provided with a weighing device in the organic liquid hydrogenation equipment to measure the mass of the organic liquid, and the density of the hydrogenated organic liquid is calculated according to the mass of the organic liquid, thereby determining the amount of hydrogenation.

[0022] Optionally, the organic liquid saturation detection module in step 4) uses a camera to identify the color of the hydrogenated organic liquid, and determines its saturation based on the color change of the hydrogenated organic liquid. The organic liquid saturation detection module sends a prompt signal to the control terminal when the hydrogenation amount is close to saturation and closes the air intake valve after saturation.

[0023] The above technical solution is adopted: the density of the hydrogenated organic liquid is calculated by the organic liquid saturation detection module, and its saturation is judged according to the color change, so that the hydrogenation is terminated in time after the organic liquid is saturated with hydrogen, the accuracy of hydrogenation control is improved, and the situation that insufficient hydrogenation or excessive hydrogenation may be caused by reasons such as the purity of the organic liquid in quantitative hydrogenation is avoided.

[0024] Optionally, the hydrogen storage organic liquid dehydrogenation module in step 5) performs activity detection on the dehydrogenation catalyst in the organic liquid dehydrogenation reaction tank, stops dehydrogenation in time and replaces the catalyst after the activity of the dehydrogenation catalyst decreases, and regenerates the deactivated catalyst for reuse.

[0025] Optionally, the hydrogen storage organic liquid dehydrogenation module in step 5) controls the temperature and pressure in the organic liquid dehydrogenation tank within a rated range to generate hydrogen by dehydrogenation, and the hydrogen storage organic liquid dehydrogenation module transports the hydrogen generated by dehydrogenation to a storage device or a hydrogen fuel cell.

[0026] The present invention has the following advantages:

[0027] 1. The intelligent control system for organic liquid hydrogen storage monitors the organic liquid addition and hydrogen delivery conditions by respectively arranging hydrogen sensing devices and liquid level sensors on the delivery pipeline and the organic liquid hydrogenation equipment, so as to facilitate the hydrogen delivery control module to detect and control the hydrogenation process of the organic liquid hydrogenation equipment. By arranging a liquid level sensor in the organic liquid hydrogenation equipment, it is convenient to add an appropriate amount of unsaturated organic liquid in the equipment for hydrogenation storage operations.

[0028] 2. The intelligent control system for hydrogen storage in organic liquid can provide timely feedback on the hydrogen delivery situation by setting a hydrogen sensing device in the delivery pipeline, thereby controlling the mixing and stirring device of organic liquid and hydrogen to perform mild stirring only when hydrogen is added, reducing the energy consumed by idling of the mixing and stirring device, and accelerating the mixing efficiency of hydrogen and unsaturated organic liquid through mixing and stirring, thereby improving the hydrogenation efficiency. By setting a pressure and temperature detection control module, the pressure and temperature data of the organic liquid hydrogenation equipment can be monitored in real time, reducing the experience input of operators, and being able to respond in time according to the pressure and temperature fluctuations before safety hazards. After the safety detection module processes the information, the extractor valve is closed to interrupt the hydrogenation process, thereby reducing the safety hazards in the hydrogenation process.

[0029] 3. The intelligent control system for organic liquid hydrogen storage, by setting up a safety detection module, conducts real-time detection of the internal temperature and pressure of the organic liquid hydrogenation equipment, as well as hydrogen leakage in the external environment, and promptly terminates the hydrogenation operation when there is a safety hazard. The safety detection module reduces the operational risk in the hydrogenation process, reduces the operator's experience and input, and improves the safety factor. The density of the hydrogenated organic liquid is calculated by the organic liquid saturation detection module, and its saturation is determined based on the color change, so that the hydrogenation is terminated in time after the organic liquid is saturated with hydrogen, thereby improving the accuracy of hydrogenation control and avoiding the situation where quantitative hydrogenation may cause insufficient or excessive hydrogenation due to reasons such as the purity of the organic liquid. BRIEF DESCRIPTION OF THE DRAWINGS

[0030] Figure 1 It is a structural schematic diagram of the present invention;

[0031] Figure 2 It is a structural schematic diagram of the hydrogen delivery control module of the present invention;

[0032] Figure 3 It is a structural schematic diagram of the pressure and temperature detection module of the present invention;

[0033] Figure 4 It is a structural schematic diagram of the safety detection module of the present invention;

[0034] Figure 5 It is a structural schematic diagram of the organic liquid saturation detection module of the present invention;

[0035] Figure 6 It is a schematic structural diagram of the hydrogen storage organic liquid dehydrogenation module of the present invention. DETAILED DESCRIPTION

[0036] Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are intended to be used to explain the present invention, and should not be construed as limiting the present invention.

[0037] like Figures 1 to 6 As shown, an intelligent control system for organic liquid hydrogen storage includes the following modules and steps:

[0038] 1) The hydrogen delivery control module controls the hydrogen delivery and hydrogenation process of the organic liquid hydrogen storage equipment;

[0039] 2) During the hydrogenation process, the pressure detection control module and the temperature detection control module perform real-time detection and monitoring of the pressure and temperature of the organic liquid hydrogen storage equipment;

[0040] 3) During the hydrogenation process, the safety detection module detects and monitors the operating environment of the organic liquid hydrogen storage equipment and controls the inlet and outlet valves;

[0041] 4) During the hydrogenation process, the organic liquid saturation detection module determines the saturation of the hydrogenated organic liquid based on the quality and color of the organic liquid, and controls the progress of hydrogenation;

[0042] 5) When the hydrogen storage organic liquid is transported and dehydrogenated, the temperature and pressure are controlled, and the dehydrogenation catalyst is automatically replaced and regenerated and recycled.

[0043] Embodiment 1: The hydrogen delivery control module in step 1) is used to control the internal temperature and pressure of the organic liquid hydrogen storage equipment to reach the rated value, and a hydrogen sensing device is set in the delivery pipeline, and a liquid level sensor is set in the organic liquid hydrogenation equipment. By respectively setting the hydrogen sensing device and the liquid level sensor on the delivery pipeline and the organic liquid hydrogenation equipment, the organic liquid addition situation and the hydrogen delivery situation are monitored, which facilitates the hydrogen delivery control module to detect and control the hydrogenation process of the organic liquid hydrogenation equipment.

[0044] Example 2: The hydrogen delivery control module in step 1) controls the filling of unsaturated organic liquid into the organic liquid hydrogenation equipment, and the liquid level height is sensed and controlled by the liquid level sensor. By setting the liquid level sensor in the organic liquid hydrogenation equipment, it is convenient to add an appropriate amount of unsaturated organic liquid in the equipment to perform hydrogenation storage operations.

[0045] Example 3: The hydrogen sensing device in step 1) starts the mixing device of the organic liquid and hydrogen when the hydrogen gas enters the delivery pipeline. After the hydrogenation of the organic liquid is completed, the saturated organic liquid is poured into the hydrogen storage organic liquid transportation equipment. By arranging the hydrogen sensing device in the delivery pipeline, timely feedback on the hydrogen delivery situation can be obtained, thereby controlling the mixing and stirring device of the organic liquid and hydrogen to perform mild stirring only when hydrogen is added, reducing the energy consumed by the idling of the mixing and stirring device, and accelerating the mixing efficiency of hydrogen and unsaturated organic liquid through mixing and stirring, thereby improving the hydrogenation efficiency.

[0046] Embodiment 4: The pressure detection control module and the temperature detection control module in step 2) set the pressure safety threshold and the temperature safety threshold. When the pressure parameter reaches or exceeds the safety threshold, the information is sent to the safety detection module. When the temperature parameter reaches or exceeds the safety threshold, the information is sent to the safety detection module. After receiving the signal, the safety detection module automatically closes the inlet and outlet valves. By setting the pressure and temperature detection control modules, the pressure and temperature data of the organic liquid hydrogenation equipment are monitored in real time, reducing the operator's experience input, and being able to respond in time according to the pressure and temperature fluctuations before the safety hazards. After the safety detection module processes the information, the extractor valve is closed to interrupt the hydrogenation process, thereby reducing the safety hazards in the hydrogenation process.

[0047] Embodiment 5: The safety detection module in step 3) sets a hydrogen detection device on the outside of the organic liquid hydrogen storage equipment. After the hydrogen detection device detects hydrogen leakage in the organic liquid hydrogen storage equipment, it sends an alarm signal to the control terminal. The safety detection module controls the equipment to automatically close the extractor valve. After receiving the signal that the pressure and temperature exceed the threshold value, the safety detection module automatically closes the extractor valve. By setting up the safety detection module, the internal temperature and pressure of the organic liquid hydrogenation equipment, as well as hydrogen leakage in the external environment, are detected in real time. When there is a safety hazard, the hydrogenation operation is terminated in time. The safety detection module reduces the operational risk in the hydrogenation process, reduces the experience investment of the operating personnel, and improves the safety factor.

[0048] Embodiment 6: The organic liquid saturation detection module in step 4) sets a weighing device in the organic liquid hydrogenation equipment to measure the mass of the organic liquid, and calculates the density of the hydrogenated organic liquid according to the mass of the organic liquid, thereby determining the amount of hydrogenation.

[0049] Embodiment 7: The organic liquid saturation detection module in step 4) uses a camera to perform color recognition on the hydrogenated organic liquid, and determines its saturation according to the color change of the hydrogenated organic liquid. The organic liquid saturation detection module sends a prompt signal to the control terminal when the hydrogenation amount is close to saturation and closes the air intake valve after saturation. The density of the hydrogenated organic liquid is calculated by the organic liquid saturation detection module, and its saturation is determined according to the color change, so that the hydrogenation is terminated in time after the organic liquid is saturated with hydrogen, thereby improving the accuracy of hydrogenation control and avoiding the situation where quantitative hydrogenation may cause insufficient hydrogenation or excessive hydrogenation due to reasons such as the purity of the organic liquid.

[0050] Example 8: The hydrogen storage organic liquid dehydrogenation module in step 5) performs activity detection on the dehydrogenation catalyst in the organic liquid dehydrogenation reaction tank, stops dehydrogenation in time and replaces the catalyst when the activity of the dehydrogenation catalyst decreases, and regenerates the deactivated catalyst for reuse.

[0051] Embodiment 9: The hydrogen storage organic liquid dehydrogenation module in step 5) controls the temperature and pressure in the organic liquid dehydrogenation tank within the rated range, dehydrogenates to produce hydrogen, and the hydrogen storage organic liquid dehydrogenation module transports the hydrogen produced by dehydrogenation to a storage device or a hydrogen fuel cell.

[0052] The working principle of the present invention is as follows:

[0053] S1, the hydrogen delivery control module controls the hydrogen delivery and hydrogenation process of the organic liquid hydrogen storage equipment;

[0054] S2. During the hydrogenation process, the pressure detection control module and the temperature detection control module perform real-time detection and monitoring of the pressure and temperature of the organic liquid hydrogen storage equipment;

[0055] S3. During the hydrogenation process, the safety detection module detects and monitors the operating environment of the organic liquid hydrogen storage equipment and controls the inlet and outlet valves;

[0056] S4. During the hydrogenation process, the organic liquid saturation detection module determines the saturation of the hydrogenated organic liquid according to the quality and color of the organic liquid, and controls the progress of hydrogenation;

[0057] S5. When the hydrogen storage organic liquid is transported and dehydrogenated, the temperature and pressure are controlled, and the dehydrogenation catalyst is automatically replaced and regenerated and cycled.

[0058] Compared with the prior art, the present invention has the following beneficial effects:

[0059] 1. The intelligent control system for organic liquid hydrogen storage monitors the organic liquid addition and hydrogen delivery conditions by respectively arranging hydrogen sensing devices and liquid level sensors on the delivery pipeline and the organic liquid hydrogenation equipment, so as to facilitate the hydrogen delivery control module to detect and control the hydrogenation process of the organic liquid hydrogenation equipment. By arranging a liquid level sensor in the organic liquid hydrogenation equipment, it is convenient to add an appropriate amount of unsaturated organic liquid in the equipment for hydrogenation storage operations.

[0060] 2. The intelligent control system for hydrogen storage in organic liquid can provide timely feedback on the hydrogen delivery situation by setting a hydrogen sensing device in the delivery pipeline, thereby controlling the mixing and stirring device of organic liquid and hydrogen to perform mild stirring only when hydrogen is added, reducing the energy consumed by idling of the mixing and stirring device, and accelerating the mixing efficiency of hydrogen and unsaturated organic liquid through mixing and stirring, thereby improving the hydrogenation efficiency. By setting a pressure and temperature detection control module, the pressure and temperature data of the organic liquid hydrogenation equipment can be monitored in real time, reducing the experience input of operators, and being able to respond in time according to the pressure and temperature fluctuations before safety hazards. After the safety detection module processes the information, the extractor valve is closed to interrupt the hydrogenation process, thereby reducing the safety hazards in the hydrogenation process.

[0061] 3. The intelligent control system for organic liquid hydrogen storage, by setting up a safety detection module, conducts real-time detection of the internal temperature and pressure of the organic liquid hydrogenation equipment, as well as hydrogen leakage in the external environment, and promptly terminates the hydrogenation operation when there is a safety hazard. The safety detection module reduces the operational risk in the hydrogenation process, reduces the operator's experience and input, and improves the safety factor. The density of the hydrogenated organic liquid is calculated by the organic liquid saturation detection module, and its saturation is determined based on the color change, so that the hydrogenation is terminated in time after the organic liquid is saturated with hydrogen, thereby improving the accuracy of hydrogenation control and avoiding the situation where quantitative hydrogenation may cause insufficient or excessive hydrogenation due to reasons such as the purity of the organic liquid.

Claims

1. An intelligent control system for organic liquid hydrogen storage, characterized in that: It includes the following modules and steps: 1) The hydrogen delivery control module controls the hydrogen delivery and hydrogenation process of the organic liquid hydrogen storage equipment; 2) During the hydrogenation process, the pressure detection control module and the temperature detection control module perform real-time detection and monitoring of the pressure and temperature of the organic liquid hydrogen storage equipment; 3) During the hydrogenation process, the safety detection module detects and monitors the operating environment of the organic liquid hydrogen storage equipment and controls the inlet and outlet valves; 4) During the hydrogenation process, the organic liquid saturation detection module determines the saturation of the hydrogenated organic liquid based on the quality and color of the organic liquid, and controls the progress of hydrogenation; 5) When the hydrogen storage organic liquid is transported and dehydrogenated, the temperature and pressure are controlled, and the dehydrogenation catalyst is automatically replaced and regenerated and recycled.

2. An intelligent control system for organic liquid hydrogen storage according to claim 1, characterized in that: The hydrogen delivery control module in step 1) controls the internal temperature and pressure of the organic liquid hydrogen storage device to reach the rated value, and a hydrogen sensing device is set in the delivery pipeline, and a liquid level sensor is set in the organic liquid hydrogenation equipment.

3. An intelligent control system for organic liquid hydrogen storage according to claim 2, characterized in that: The hydrogen delivery control module in step 1) controls the filling of unsaturated organic liquid into the organic liquid hydrogenation equipment, and the liquid level height is sensed and controlled by the liquid level sensor.

4. An intelligent control system for organic liquid hydrogen storage according to claim 3, characterized in that: The hydrogen sensing device in step 1) starts the mixing device of organic liquid and hydrogen when the hydrogen entering the delivery pipeline is detected, and after the hydrogenation of the organic liquid is completed, the saturated organic liquid is poured into the hydrogen storage organic liquid transportation equipment.

5. An intelligent control system for organic liquid hydrogen storage according to claim 4, characterized in that: The pressure detection control module and the temperature detection control module in the step 2) set the pressure safety threshold and the temperature safety threshold. When the pressure parameter reaches or exceeds the safety threshold, information is sent to the safety detection module. When the temperature parameter reaches or exceeds the safety threshold, information is sent to the safety detection module. After receiving the signal, the safety detection module automatically closes the inlet and outlet valves.

6. An intelligent control system for organic liquid hydrogen storage according to claim 5, characterized in that: The safety detection module in the step 3) sets a hydrogen detection device on the outside of the organic liquid hydrogen storage equipment. After the hydrogen detection device detects hydrogen leakage from the organic liquid hydrogen storage equipment, it sends an alarm signal to the control terminal. The safety detection module controls the equipment to automatically close the extractor valve. After receiving the signal that the pressure and temperature exceed the threshold value, the safety detection module automatically closes the extractor valve.

7. An intelligent control system for organic liquid hydrogen storage according to claim 6, characterized in that: The organic liquid saturation detection module in step 4) is provided with a weighing device in the organic liquid hydrogenation equipment to measure the mass of the organic liquid, and the density of the hydrogenated organic liquid is calculated according to the mass of the organic liquid, thereby determining the amount of hydrogenation.

8. An intelligent control system for organic liquid hydrogen storage according to claim 7, characterized in that: The organic liquid saturation detection module in step 4) uses a camera to identify the color of the hydrogenated organic liquid and determines its saturation according to the color change of the hydrogenated organic liquid. The organic liquid saturation detection module sends a prompt signal to the control terminal when the hydrogenation amount is close to saturation and closes the intake valve after saturation.

9. An intelligent control system for organic liquid hydrogen storage according to claim 8, characterized in that: The hydrogen storage organic liquid dehydrogenation module in step 5) detects the activity of the dehydrogenation catalyst in the organic liquid dehydrogenation reaction tank, stops dehydrogenation in time and replaces the catalyst when the activity of the dehydrogenation catalyst decreases, and regenerates the deactivated catalyst for reuse.

10. An intelligent control system for organic liquid hydrogen storage according to claim 9, characterized in that: The hydrogen storage organic liquid dehydrogenation module in step 5) controls the temperature and pressure in the organic liquid dehydrogenation tank within the rated range, dehydrogenates to generate hydrogen, and the hydrogen storage organic liquid dehydrogenation module transports the hydrogen generated by dehydrogenation to the storage device or hydrogen fuel cell.

Citation Information

Patent Citations

  • Hydrogen production and refueling station in organic liquid station and control method of hydrogen production and refueling station

    CN116697272A