Corrosion-resistant steel with grade of 10.9 or above, pipe piece bolt and preparation method of corrosion-resistant steel

Abstract

The invention belongs to the technical field of fastening connection, and particularly relates to corrosion-resistant steel with the grade of 10.9 or above, a duct piece bolt and a preparation method of the duct piece bolt. By compounding Cu and Ni, a compact and stable rust layer is promoted to be formed on the surface of the material, further corrosion is prevented, and the corrosion resistance of the material is improved; through trace Sn, a compound of SnO2 and graphite can be formed on the surface of the material to serve as an anti-corrosion layer, and the corrosion resistance of the material is greatly enhanced; by optimizing the content of C and adding a trace amount of B, the hardenability of the steel is improved so as to meet the performance requirements of the large-specification duct piece bolt of the tunnel. According to the corrosion-resistant steel with the grade of 10.9 or above, specific elements with specific contents are adopted, the excellent corrosion resistance is achieved, the mechanical performance is good, and the comprehensive performance is excellent.

Description

Technical Field

[0001] The present invention belongs to the technical field of fastening connection, and in particular relates to a corrosion-resistant steel material of grade 10.9 or above, a segment bolt and a preparation method thereof. Background Art

[0002] With the vigorous development of China's transportation construction, the number of cross-river tunnels, undersea tunnels and mountain tunnels has increased year by year. Concrete segments and steel segments are often connected by segment bolts, which are used in large quantities and have high corrosion resistance requirements. Existing segment bolts are usually made of low-alloy steel (such as 20Cr, 40Cr) combined with surface treatment. However, due to the complex service environment of traffic tunnels, when the surface coating of low-alloy steel peels off, the exposed part of the segment bolt is easily exposed to corrosive ions in the environment (such as Cl - 、SO4 2- ) or gas undergoes chemical or electrochemical reactions, causing bolt corrosion. The corrosion of segment bolts has many effects on the shield lining structure. It not only reduces the cross-sectional area of ​​the bolts themselves, but also causes concrete to rust, expand, crack, and damage. In addition, it also causes the bonding performance between the bolts and concrete to decrease, seriously affecting the safety of the tunnel structure.

[0003] At present, there is no clear standard in China requiring the corrosion resistance of segment bolts, but anti-corrosion technology for large-size bolt materials or similar materials has emerged. However, its corrosion resistance is insufficient and cannot meet the segment connection requirements in complex tunnel structure environments. Summary of the invention

[0004] The object of the present invention is to provide a corrosion-resistant steel material of grade 10.9 or above, a segment bolt and a preparation method thereof. The corrosion-resistant steel material provided by the present invention has a grade of grade 10.9 or above and has excellent corrosion resistance.

[0005] In order to achieve the above object, the present invention provides the following technical solutions:

[0006] The invention provides a corrosion-resistant steel material of grade 10.9 or above, comprising the following chemical components in percentage by mass: C 0.30-0.35%, Si 0.31-0.35%, Mn 0.85-1.10%, Ni 0.10-0.36%, Cu 0.22-0.38%, Al 0.018-0.030%, Ti 0.01-0.05%, B 0.0008-0.0040%, Sn 0.02-0.10% and Fe balance.

[0007] Preferably, the corrosion-resistant steel material of grade 10.9 or above further comprises a multi-element alloy co-penetration layer; the multi-element alloy co-penetration layer covers the surface of the corrosion-resistant steel material of grade 10.9 or above; the thickness of the multi-element alloy co-penetration layer is not less than 80 μm, and the mass is not less than 11.2 g / m 2The multi-element alloy co-diffusion layer includes the following chemical components in percentage by mass: 75-80wt% zinc, 13-18wt% aluminum and the remainder chromium.

[0008] The present invention also provides a method for preparing the corrosion-resistant steel of grade 10.9 or above described in the above scheme, comprising the following steps:

[0009] The raw steel is subjected to a tempering heat treatment after hot upsetting, wherein the tempering heat treatment comprises quenching, water cooling, tempering and cooling in sequence, so as to obtain the corrosion-resistant steel material above grade 10.9; the raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%; Si 0.31-0.35%; Mn 0.85-1.10%; Ni 0.10-0.36%; Cu 0.22-0.38%; Al 0.018-0.030%; Ti 0.01-0.05%; B 0.0008-0.0040%; Sn 0.02-0.10% and Fe balance.

[0010] Preferably, the hot upsetting temperature is 900-1050° C., the pressure is 400-520 KN, and the hot upsetting time is 2-3 s.

[0011] Preferably, the quenching temperature is 870-900° C., and the holding time is 45-60 min.

[0012] Preferably, the tempering temperature is 500-580° C., and the holding time is 60-90 min.

[0013] Preferably, the tempering heat treatment also includes surface treatment of the obtained product; the surface treatment is powder multi-component alloy co-infiltration surface treatment; the infiltration temperature of the powder multi-component alloy co-infiltration surface treatment is 300-350°C, and the infiltration layer thickness is not less than 80μm; the infiltration layer elements of the powder multi-component alloy co-infiltration surface treatment include 75-80wt% zinc, 13-18wt% aluminum and a remainder of chromium.

[0014] The present invention also provides the use of the corrosion-resistant steel of grade 10.9 or above described in the above scheme or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method of the above scheme in the field of fastening connection.

[0015] The present invention also provides a segment bolt, which is prepared using the corrosion-resistant steel of grade 10.9 or above described in the above scheme or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method described in the above scheme.

[0016] The present invention also provides a method for preparing the segment bolts described in the above scheme, comprising the following steps:

[0017] The raw steel is subjected to hot upsetting and then to hot thread rolling and tempering heat treatment in sequence, wherein the tempering heat treatment includes quenching, water cooling, tempering and cooling in sequence to obtain the segment bolts; the raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%; Si 0.31-0.35%; Mn 0.85-1.10%; Ni 0.10-0.36%; Cu 0.22-0.38%; Al 0.018-0.030%; Ti 0.01-0.05%; B 0.0008-0.0040%; Sn 0.02-0.10% and Fe remainder.

[0018] The present invention provides a corrosion-resistant steel material of grade 10.9 or above. The present invention promotes the formation of a dense and stable rust layer on the surface of the material through the composite of Cu and Ni, hinders further corrosion, and improves the corrosion resistance of the material; the present invention can form a composite of SnO2 and graphite on the surface of the material as an anti-corrosion layer through trace Sn, greatly enhancing the corrosion resistance of the material; the present invention improves the hardenability of steel by optimizing the C content and adding a trace amount of B to meet the performance requirements of large-scale tunnel segment bolts. The corrosion-resistant steel material of grade 10.9 or above provided by the present invention adopts specific elements with specific contents, achieves excellent corrosion resistance, good mechanical properties, and excellent comprehensive performance. The results of the embodiment show that in a 72h accelerated corrosion test in a NaCl solution with a constant temperature of 30°C, a pH value of 0.85, and a concentration of 10wt%, the annual average corrosion rate (CR) is ≤0.27mm / a.

[0019] The present invention also provides a method for preparing the corrosion-resistant steel material of grade 10.9 or above as described in the above scheme. The preparation method provided by the present invention has simple steps, convenient operation, high feasibility and low cost.

[0020] The present invention also provides the application of the corrosion-resistant steel of grade 10.9 or above described in the above scheme or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method of the above scheme in the field of fastening connection. The corrosion-resistant steel of grade 10.9 or above provided by the present invention has excellent corrosion resistance and is suitable for fastening connection, such as preparing M30-M36 segment bolts, and can especially meet the performance requirements of complex environments such as mountainous areas, river crossings or submarine tunnels.

[0021] The present invention also provides a segment bolt. Compared with the prior art, the segment bolt provided by the present invention can significantly improve the corrosion resistance under the same bolt performance grade condition, the average annual corrosion rate in the accelerated corrosion test is lower than 0.27 mm / a, no red rust is found on the surface of the specimen after 1500 hours of neutral salt spray test, and no red rust is found on the surface of the specimen after 870 hours of wet heat test.

[0022] The present invention also provides a method for preparing the segment bolts of the above solution. The preparation method provided by the present invention has low labor cost, good safety, and is suitable for industrial-scale production. DETAILED DESCRIPTION

[0023] The invention provides a corrosion-resistant steel material of grade 10.9 or above, comprising the following chemical components in percentage by mass: C 0.30-0.35%, Si 0.31-0.35%, Mn 0.85-1.10%, Ni 0.10-0.36%, Cu 0.22-0.38%, Al 0.018-0.030%, Ti 0.01-0.05%, B 0.0008-0.0040%, Sn 0.02-0.10% and Fe balance.

[0024] The corrosion-resistant steel material with a grade of 10.9 or above provided by the present invention comprises 0.30-0.35% C, specifically 0.30%, 0.31%, 0.32%, 0.33%, 0.34% or 0.35%. The present invention improves the strength and hardness of the material by adding the above-mentioned C as the main strengthening element in the material, while ensuring the toughness and plasticity of the material.

[0025] The corrosion-resistant steel material above grade 10.9 provided by the present invention comprises 0.31-0.35% Si, specifically 0.31%, 0.32%, 0.33%, 0.34% or 0.35%. The present invention adds Si as a reducing agent and a deoxidizing agent, and Si can also play a role of solid solution strengthening.

[0026] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention comprises 0.85-1.10% Mn, specifically 0.85%, 0.90%, 0.95%, 1.00%, 1.05% or 1.10%. The present invention mainly uses Mn as a desulfurizing agent by adding Mn; the present invention controls the content of Mn within the above range, and can also avoid the tendency of Mn segregation to grain boundaries during tempering.

[0027] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention comprises 0.10-0.36% Ni, specifically 0.10%, 0.12%, 0.14%, 0.16%, 0.18%, 0.20%, 0.22%, 0.24%, 0.26%, 0.28%, 0.30%, 0.32%, 0.34% or 0.36%. The present invention significantly increases the compactness of the inner rust layer of the material by adding Ni, shifts the corrosion potential of the material positively, and improves the acid resistance, alkali resistance and atmospheric corrosion resistance of the material; in addition, Ni can improve the toughness of the material, especially the low-temperature toughness.

[0028] The corrosion-resistant steel material with a grade of 10.9 or above provided by the present invention comprises 0.22-0.38% Cu, and specifically can be 0.22%, 0.24%, 0.26%, 0.28%, 0.30%, 0.32%, 0.34%, 0.36% or 0.38%. The present invention adds Cu, which plays a role of activating the cathode in the corrosion process, and promotes the passivation of the material anode, thereby slowing down the corrosion; at the same time, it promotes the compactness and stability of the inner rust layer, and hinders the further occurrence of corrosion.

[0029] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention comprises 0.018% to 0.030% Al, specifically 0.018%, 0.020%, 0.022%, 0.024%, 0.026%, 0.028% or 0.030%. The present invention refines the grains, improves the anti-oxidation property of the material, and reduces the brittle transition temperature of the material by adding Al as a deoxidizing and nitrogen fixing agent.

[0030] The corrosion-resistant steel material above grade 10.9 provided by the present invention comprises 0.01-0.05% Ti, specifically 0.01%, 0.02%, 0.03%, 0.04% or 0.05%. The present invention adds Ti as a carbide-forming element, which has a strong solid solution strengthening effect and can significantly refine the grains.

[0031] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention comprises 0.0008% to 0.0040% B, specifically 0.0008%, 0.0010%, 0.0015%, 0.0020%, 0.0025%, 0.0030%, 0.0035% or 0.0040%. By adding a trace amount of B, the hardenability of the material can be significantly improved.

[0032] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention comprises 0.02-0.10% Sn, specifically 0.02%, 0.03%, 0.04%, 0.05%, 0.06%, 0.07%, 0.08%, 0.09% or 0.10%. Sn has always been considered as a harmful impurity element in steel materials, which affects the quality of steel materials, especially the quality of continuous casting billets, causes hot brittleness and temper brittleness of steel, produces cracks and fractures, and affects the welding performance of steel. However, the present invention has found that by adding a trace amount of Sn, a dense SnO2 and graphite protective layer can be formed on the surface of the material, which hinders the further occurrence of corrosion reaction and significantly improves the corrosion resistance of the material.

[0033] The corrosion-resistant steel of grade 10.9 or above provided by the present invention includes Fe surplus. Corrosion-resistant steel inevitably contains impurities, and the present invention reduces the content of impurity elements P and S as much as possible, reduces their segregation on grain boundaries, and improves grain boundary strength.

[0034] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention preferably further comprises a multi-element alloy co-infiltration layer; the multi-element alloy co-infiltration layer is covered on the surface of the corrosion-resistant steel material of grade 10.9 or above; the thickness of the multi-element alloy co-infiltration layer is preferably not less than 80 μm, and the mass is preferably not less than 11.2 g / m 2 The multi-element alloy co-diffusion layer preferably comprises the following chemical components in percentage by mass: 75-80wt% zinc, 13-18wt% aluminum and the remainder chromium.

[0035] In the present invention, the content of zinc is preferably 75-80wt%, specifically 75wt%, 76wt%, 77wt%, 78wt%, 79wt% or 80wt%.

[0036] In the present invention, the aluminum content is preferably 13-18wt%, specifically 13wt%, 14wt%, 15wt%, 16wt%, 17wt% or 18wt%.

[0037] The present invention also provides a method for preparing the corrosion-resistant steel of grade 10.9 or above described in the above scheme, comprising the following steps:

[0038] The raw steel is subjected to a tempering heat treatment after hot upsetting, wherein the tempering heat treatment comprises quenching, water cooling, tempering and cooling in sequence, so as to obtain the corrosion-resistant steel material above grade 10.9; the raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%; Si 0.31-0.35%; Mn 0.85-1.10%; Ni 0.10-0.36%; Cu 0.22-0.38%; Al 0.018-0.030%; Ti 0.01-0.05%; B 0.0008-0.0040%; Sn 0.02-0.10% and Fe balance.

[0039] The present invention performs hot upsetting on the raw steel. In the present invention, the raw steel is preferably round steel; the raw steel is preferably obtained by hot rolling of a steel billet; the starting rolling temperature of the hot rolling is preferably not less than 1100°C, specifically 1100°C, 1200°C, 1300°C or 1500°C, and the final rolling temperature is not less than 1050°C, specifically 1050°C, 1150°C, 1250°C or 1350°C.

[0040] In the present invention, the temperature of the hot upsetting is preferably 900-1050°C, specifically 900°C, 950°C, 1000°C or 1050°C; the pressure is preferably 400-520KN, specifically 400KN, 420KN, 450KN, 480KN, 500KN or 520KN; the hot upsetting time is preferably 2-3s, specifically 2.5s.

[0041] After hot upsetting, the present invention performs a tempering heat treatment on the obtained hot upsetting piece, and the tempering heat treatment includes quenching, water cooling, tempering and cooling in sequence to obtain the corrosion-resistant steel material of grade 10.9 or above. In the present invention, the quenching temperature is preferably 870-900°C, specifically 870°C, 875°C, 880°C, 885°C, 890°C, 895°C, or 900°C, and the holding time is preferably 45-60min, specifically 45min, 50min, 55min or 60min.

[0042] In the present invention, the water cooling is preferably direct water cooling; the water temperature of the water cooling is preferably 40°C.

[0043] In the present invention, the tempering temperature is preferably 500-580°C, specifically 500°C, 510°C, 520°C, 530°C, 540°C, 550°C, 560°C, 570°C or 580°C, and the holding time is preferably 60-90 min, specifically 60 min, 70 min, 80 min or 90 min.

[0044] In the present invention, the cooling is preferably air cooling; the air cooling is preferably direct air cooling; and the final temperature of the cooling is preferably room temperature.

[0045] In the present invention, the tempering heat treatment preferably also includes surface treatment of the obtained product; the surface treatment is preferably powder multi-component alloy co-diffusion surface treatment; the infiltration temperature of the powder multi-component alloy co-diffusion surface treatment is preferably 300-350°C, specifically 300°C, 310°C, 330°C or 350°C, and the infiltration layer thickness is preferably not less than 80μm, specifically 80μm, 90μm, 100μm, 120μm, 150μm, 180μm or 200μm.

[0046] In the present invention, the diffusion layer elements of the powder multi-element alloy co-diffusion surface treatment preferably include 75-80wt% zinc, 13-18wt% aluminum and a remainder of chromium; the zinc content is preferably 75-80wt%, specifically 75wt%, 76wt%, 77wt%, 78wt%, 79wt% or 80wt%.

[0047] In the present invention, the aluminum content is preferably 13-18wt%, specifically 13wt%, 14wt%, 15wt%, 16wt%, 17wt% or 18wt%.

[0048] The present invention also provides the use of the corrosion-resistant steel of grade 10.9 or above described in the above scheme or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method of the above scheme in the field of fastening connection.

[0049] The corrosion-resistant steel material of grade 10.9 or above provided by the present invention has excellent corrosion resistance and is suitable for fastening connections, such as preparing M30-M36 segment bolts, and can especially meet the performance requirements of complex tunnel environments such as mountains, rivers or seabeds.

[0050] The present invention also provides a segment bolt, which is prepared using the corrosion-resistant steel of grade 10.9 or above described in the above scheme or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method described in the above scheme.

[0051] In the present invention, the length of the segment bolts is preferably 120 to 900 mm, and specifically can be 120 mm, 200 mm, 400 mm, 650 mm, 750 mm or 900 mm.

[0052] The segment bolts provided by the present invention can significantly improve the corrosion resistance under the condition of the same bolt performance grade. The average annual corrosion rate in the accelerated corrosion test is lower than 0.27 mm / a. No red rust is observed on the surface of the specimen after 1500 h of the neutral salt spray test and 870 h of the wet heat test.

[0053] The present invention also provides a method for preparing the segment bolts described in the above scheme, comprising the following steps:

[0054] The raw steel is subjected to hot upsetting and then to hot thread rolling and tempering heat treatment in sequence, wherein the tempering heat treatment includes quenching, water cooling, tempering and cooling in sequence to obtain the segment bolts; the raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%; Si 0.31-0.35%; Mn 0.85-1.10%; Ni 0.10-0.36%; Cu 0.22-0.38%; Al 0.018-0.030%; Ti 0.01-0.05%; B 0.0008-0.0040%; Sn 0.02-0.10% and Fe remainder.

[0055] In the present invention, the preparation parameters of the segment bolts are the same as the preparation parameters of the corrosion-resistant steel of grade 10.9 or above described in the above scheme, except that the temperature of the hot thread rolling is preferably 850-1000°C, specifically 850°C, 875°C, 900°C, 925°C, 950°C, 975°C or 1000°C.

[0056] In order to further illustrate the present invention, the scheme of the present invention is described in detail below in conjunction with embodiments, but they should not be understood as limiting the scope of protection of the present invention.

[0057] Example

[0058] A 100kg vacuum induction furnace was used to smelt 3 furnaces of corrosion-resistant steel materials of grade 10.9 or above of the present invention (Examples 1 to 3) and 4 furnaces of comparative steel materials (Comparative Examples 1 to 4). At the same time, 3 furnaces of typical bolt steels 35VB, 40Cr and weathering bolt steel NHB10 were selected as comparative steel materials, and the specific components were shown in Table 1. The molten steel was cast into ingots and then rolled into Φ36 round steel. The round steel was hot-forged (temperature of 980°C, pressure of 470KN, and hot-forging time of 2.5s) and was subjected to tempering heat treatment (wherein the water temperature of water cooling was 40°C and the final temperature of air cooling was room temperature) and then surface treated ( The penetration temperatures of Examples 1 to 3 and Comparative Examples 1 to 2 are 300°C, 310°C, 320°C, 340°C and 350°C, respectively, and the alloy components are 80wt%, 15wt% zinc, aluminum and the balance chromium). They are processed into standard room temperature tensile specimens, standard V-neck Charpy impact specimens and hanging specimens (60mm×25mm×5mm). The specimens are subjected to tensile tests at room temperature, impact performance tests at -20°C, and accelerated corrosion tests for 72h. The accelerated corrosion test conditions are shown in Table 2. The corrosion weight loss and annual average corrosion rate of each specimen are evaluated. The specific conditions and test results are shown in Table 3.

[0059] Segment bolts were prepared using the round steel of Examples 1 to 3 and Comparative Examples 1 to 4, and hot thread rolling was performed before surface treatment. Other conditions were the same as above. The existing surface treatment process was used as a comparison. After different surface treatments, neutral salt spray tests (refer to GB / T 10125 "Artificial atmosphere corrosion test salt spray test") and wet heat tests (60±2°C, 95±3%RH, refer to GB / T2423.3 "Environmental testing Part 2: Test method Test Cab: Constant wet heat test") were performed. The corrosion resistance of the segment bolts was determined by the time when red rust appeared. The test results are shown in Table 4.

[0060] Table 1 Composition (wt%) of Examples 1 to 3, Comparative Examples 1 to 4 and Comparative Steel Materials

[0061]

[0062]

[0063] Table 2 Accelerated corrosion test conditions

[0064] Test solution NaCl (10 wt%) and HCl mixed solution, pH = 0.85 Test temperature 30℃ constant temperature Test time 72h Remark Replace the solution every 24 hours to keep the pH value stable

[0065] Table 3 Test results of Examples 1 to 3, Comparative Examples 1 to 4 and comparative steel materials

[0066]

[0067] It can be seen from Table 3 that the corrosion-resistant steel of grade 10.9 or above provided by the present invention has better strength and toughness as a whole, a tensile strength of more than 925 MPa, a yield strength ratio of more than 0.85, a low-temperature impact energy of -20°C KV2 of not less than 130 J, better corrosion resistance, and a comprehensive performance significantly better than the comparative example.

[0068] Table 4 Segment bolt test results of Examples 1 to 3 and Comparative Examples 1 to 4

[0069]

[0070]

[0071] It can be seen from Table 4 that the segment bolts made of corrosion-resistant steel of grade 10.9 or above of the present invention have excellent corrosion resistance, and no red rust is observed on the surface of the specimen after a 1500h neutral salt spray test or a 870h wet heat test.

[0072] It can be seen from the above embodiments that the corrosion-resistant steel of grade 10.9 or above provided by the present invention has excellent corrosion resistance, good mechanical properties and excellent comprehensive performance.

[0073] Although the above embodiment describes the present invention in detail, it is only a part of the embodiments of the present invention, not all of the embodiments. Other embodiments can be obtained based on this embodiment without creativity, and these embodiments all fall within the protection scope of the present invention.

Claims

1. A corrosion-resistant steel material of grade 10.9 or above, characterized in that: The invention comprises the following chemical components in percentage by mass: C 0.30-0.35%, Si 0.31-0.35%, Mn 0.85-1.10%, Ni 0.10-0.36%, Cu 0.22-0.38%, Al 0.018-0.030%, Ti 0.01-0.05%, B 0.0008-0.0040%, Sn 0.02-0.10% and Fe balance.

2. The corrosion-resistant steel material of grade 10.9 or above according to claim 1, characterized in that: The corrosion-resistant steel material of grade 10.9 or above further comprises a multi-element alloy co-penetration layer; the multi-element alloy co-penetration layer covers the surface of the corrosion-resistant steel material of grade 10.9 or above; the thickness of the multi-element alloy co-penetration layer is not less than 80 μm, and the mass is not less than 11.2 g / m 2 The multi-element alloy co-diffusion layer includes the following chemical components in percentage by mass: 75-80wt% zinc, 13-18wt% aluminum and the remainder chromium.

3. The method for preparing the corrosion-resistant steel material of grade 10.9 or above according to any one of claims 1 to 2, characterized in that: The following steps are involved: The raw steel is subjected to a tempering heat treatment after hot upsetting, wherein the tempering heat treatment includes quenching, water cooling, tempering and cooling in sequence to obtain the corrosion-resistant steel material of grade 10.9 or above; The raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%, Si 0.31-0.35%, Mn 0.85-1.10%, Ni 0.10-0.36%, Cu 0.22-0.38%, Al 0.018-0.030%, Ti 0.01-0.05%, B 0.0008-0.0040%, Sn 0.02-0.10% and Fe balance.

4. The preparation method according to claim 3, characterized in that: The temperature of the hot upsetting is 900-1050°C, the pressure is 400-520KN, and the hot upsetting time is 2-3s.

5. The preparation method according to claim 3 or 4, characterized in that: The quenching temperature is 870-900° C., and the holding time is 45-60 minutes.

6. The preparation method according to claim 3 or 4, characterized in that: The tempering temperature is 500-580° C., and the heat preservation time is 60-90 minutes.

7. The preparation method according to claim 3, characterized in that: The tempering heat treatment also includes surface treatment of the obtained product; The surface treatment is powder multi-element alloy co-penetration surface treatment; The infiltration temperature of the powder multi-element alloy co-infiltration surface treatment is 300-350°C, and the infiltration layer thickness is not less than 80 μm; The elements of the infiltration layer of the powder multi-element alloy co-infiltration surface treatment include 75-80wt% zinc, 13-18wt% aluminum and the balance of chromium.

8. Use of the corrosion-resistant steel material with a grade of 10.9 or above as claimed in any one of claims 1 to 2 or the corrosion-resistant steel material with a grade of 10.9 or above obtained by the preparation method according to any one of claims 3 to 7 in the field of fastening connections.

9. A segment bolt, prepared by using the corrosion-resistant steel of grade 10.9 or above as described in any one of claims 1 to 2 or the corrosion-resistant steel of grade 10.9 or above obtained by the preparation method described in any one of claims 3 to 7.

10. The method for preparing the segment bolts according to claim 9, characterized in that: The following steps are involved: The raw steel is subjected to hot upsetting and then hot thread rolling and quenching and tempering heat treatment in sequence, wherein the quenching and tempering heat treatment includes quenching, water cooling, tempering and cooling in sequence to obtain the segment bolts; The raw steel comprises the following chemical components in percentage by mass: C 0.30-0.35%, Si 0.31-0.35%, Mn 0.85-1.10%, Ni 0.10-0.36%, Cu 0.22-0.38%, Al 0.018-0.030%, Ti 0.01-0.05%, B 0.0008-0.0040%, Sn 0.02-0.10% and Fe balance.

Images