A photoelectric coupled reactor for methane dry reforming with efficient utilization of solar energy
By designing a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy, the temperature unevenness caused by uneven solar energy distribution is solved, uniform control of temperature in the reactor and diversified utilization of solar energy are achieved, and the efficiency and stability of synthesis gas reaction are improved.
Patent Information
- Application Number
- CN202510259787.1
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2025-03-06
- Publication Date
- 2025-05-16
- Estimated Expiration
- 2045-03-06
AI Technical Summary
In solar thermochemical reactors, due to the intermittentity and uneven distribution of solar energy, the temperature gradient in the reforming chamber is large and the temperature distribution is uneven, which affects the efficiency and stability of the synthesis gas.
A methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy is designed, using a full-dimensional energy storage solar concentrator and power storage original storage body, combining the double-layer structure of intelligent fixed-point heating resistor ring and concentrated solar panels, achieving uniform control of the temperature in the reforming chamber and diversified utilization of solar energy.
Through precise point heating and diversified utilization of solar energy, the uniformity of temperature in the reforming chamber and the controllability of reactions are achieved, the efficiency and stability of methane dry reforming syngas reactions are improved, and carbon emissions and side reactions are reduced.
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Figure CN119746763B_ABST
Abstract
Description
Technical Field
[0001] The invention belongs to the technical field of preparing synthesis gas by utilizing solar energy, and in particular relates to a methane dry reforming photoelectric coupling reactor which efficiently utilizes solar energy. Background Art
[0002] In order to deal with energy problems and global warming, it is necessary to increase the proportion of clean energy - solar energy in the energy system and recycle and process greenhouse gases that have been emitted into the atmosphere to meet sustainable development. The methane dry reforming reaction generates a fuel with high calorific value - synthesis gas while recycling methane and carbon dioxide from the atmosphere. The reaction uses solar-driven heating instead of traditional combustion heating, which greatly reduces carbon emissions.
[0003] As a clean and renewable resource, solar energy has broad application prospects. However, in solar thermochemical reactors, due to uncontrollable conditions such as intermittent and uneven distribution of solar energy, it is easy to cause problems such as uneven heating of the reforming chamber or insufficient heat source to support the reaction requirements, which greatly shortens the service life of the reactor and increases carbon deposition and side reactions, seriously affecting the efficiency and stability of synthesis gas production. Summary of the invention
[0004] The present invention overcomes the shortcomings of the prior art and proposes a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy; in order to solve the problem that uneven and uncontrollable sunlight causes a large temperature gradient and uneven temperature distribution in the reforming chamber when driving the reforming reaction; the present invention is achieved through the following technical solutions:
[0005] A methane dry reforming photoelectric coupling reactor for efficient use of solar energy, comprising a reforming reactor body, an omnidirectional energy storage type solar concentrator and an electric storage element storage body; the omnidirectional energy storage type solar concentrator is a pot body structure with an arc-shaped inner wall; the reforming reactor body is located on the inner side of the omnidirectional energy storage type solar concentrator;
[0006] The inner side wall of the omnidirectional energy storage type solar concentrator is provided with a plurality of concentrating solar panels; the inner bottom of the omnidirectional energy storage type solar concentrator is provided with a concentrating heat collecting reflector; the inner part of the storage element storage body is provided with a storage element;
[0007] The reforming reactor body is provided with a reforming chamber; a conical chamber is provided at the center of the reforming chamber; a second quartz window is provided at the bottom of the conical chamber; a methane dry reforming reaction area is provided between the outer wall of the conical chamber and the inner wall of the reforming chamber, and a catalyst is filled in the methane dry reforming reaction area; a focusing and heat collecting reflector reflects light energy and injects it into the conical chamber through the second quartz window, and heats the methane dry reforming reaction area through the heat generated by the conical chamber;
[0008] The outer wall of the reforming chamber is wrapped with a preheating outer layer, the side wall of the preheating outer layer is a first quartz window, a plurality of concentrating solar panels are located in the same plane as the preheating outer layer, and light energy is injected into the preheating outer layer through the concentrating solar panels to preheat the raw gas inside the preheating outer layer; a temperature sensor is arranged inside the preheating outer layer; the preheating outer layer is connected to the reforming chamber;
[0009] The concentrating solar panel is a double-layer structure, the upper layer is a plurality of rows of concentrating reflectors arranged in sequence, and the lower layer is a solar panel; each row of concentrating reflectors is composed of a plurality of concentrating reflectors connected in sequence, and the rows are connected by nickel-based high-temperature synthetic wires; two adjacent rows of concentrating reflectors are connected by springs, and an electric cut-type telescopic rod is arranged at the bottom of the plurality of rows of concentrating reflectors, the base of the electric cut-type telescopic rod is fixed at one end of the plurality of rows of concentrating reflectors, and the extended end of the electric cut-type telescopic rod is connected to the spring away from the base of the electric cut-type telescopic rod; the electric cut-type telescopic rod and the temperature sensor are both connected to the PLC system; when the temperature sensor sends a signal that the preheating temperature of the raw gas reaches a preset temperature threshold, the electric cut-type telescopic rod is controlled to retract through the PLC system, so that the plurality of rows of concentrating reflectors are folded to expose the solar panel on the lower layer; the solar panel is connected to the power storage element to convert the solar energy absorbed by the solar panel into electrical energy for storage.
[0010] Furthermore, the spring is made of nickel-based high temperature synthetic wire.
[0011] Furthermore, curved pipelines are distributed inside the preheating outer layer, and the temperature sensor is arranged in the curved pipeline; openings are symmetrically arranged on the top of the preheating outer layer; an air inlet is arranged at the bottom of the reforming chamber; a product air outlet is arranged at the top of the reforming chamber; and the end of the curved pipeline is connected to the air inlet at the bottom of the reforming chamber.
[0012] Furthermore, the upper part of the reforming reactor body is a heat recovery chamber, and the reforming chamber is arranged at the lower part of the reforming reactor body; a raw material air inlet and a product outlet are arranged at the top of the heat recovery chamber; a serpentine sleeve is arranged inside the heat recovery chamber; the top of the inner tube of the serpentine sleeve is connected to the raw material air inlet, and the top of the outer tube of the serpentine sleeve is connected to the product outlet; the bottom of the inner tube of the serpentine sleeve is connected to the opening, and the bottom of the outer tube of the serpentine sleeve is connected to the product outlet.
[0013] Furthermore, the outside of the conical cavity is surrounded by an intelligent fixed-point heating resistance ring; the intelligent fixed-point heating resistance ring is composed of a number of resistance heating units connected by pure nickel high-temperature wires, each resistance heating unit is composed of a resistor with a hollow cylindrical structure and an intelligent heating controller located inside the resistor, and the intelligent heating controller is provided with a temperature sensor and a control switch; the resistance heating unit is connected to the PLC system.
[0014] Furthermore, the focusing and heat collecting reflector is parabolic in shape as a whole, and is composed of a plurality of focusing reflectors in the shape of fan rings.
[0015] Furthermore, the storage body for the electricity storage element is a hollow cone structure, and the electricity storage element is placed in the hollow cone structure.
[0016] Furthermore, every four adjacent concentrated solar panels are connected to a dual-axis rotation solar tracking system to form an angle adjustment unit.
[0017] Furthermore, the cavity wall of the conical cavity is a dense ceramic layer of SiC material with a thickness of 1 mm.
[0018] Furthermore, the methane dry reforming reaction area is filled with solid porous ceramic SiC, and the solid porous ceramic SiC is coated with a Co / carbon-based material catalyst.
[0019] The beneficial effects of the present invention compared with the prior art are as follows:
[0020] 1. The present invention provides a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy, which solves the problems of uneven sunlight distribution and uncontrollable problems when using sunlight as the main heat source for the reforming reaction. An intelligent fixed-point heating resistor ring is set outside the conical cavity for adjusting the distribution of sunlight, and electric heating is used as an auxiliary heat source. Through the coordination and cooperation of the intelligent controller in the heating resistor unit and the PLC system, the purpose of independent or coordinated operation of a single or multiple heating resistor units is achieved. Therefore, regardless of whether sunlight exists or is uniform, the reactor can ensure the uniformity of temperature at each point in the reforming cavity through precise fixed-point heating, thereby achieving full utilization of clean energy while increasing the controllability and efficiency of the reaction, so that the methane dry reforming gasification reaction can be carried out efficiently and stably.
[0021] 2. The present invention provides a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy. The concentrating solar panel has a special double-layer structure, which has the functions of concentrating and collecting heat and photoelectric conversion. When the raw gas in the outer inner pipeline is heated and preheated to a set suitable temperature, the outer concentrating reflector is folded and pulled to the top of the concentrating solar panel with the contraction of the electric telescopic rod and the extension of the spring, thereby exposing the inner solar panel for absorbing excess sunlight, and storing the converted electrical energy in the storage element to provide energy for other electrical equipment. This structure not only realizes the diversified utilization of solar energy, reduces the cost caused by the use of traditional energy, and improves the economy of the entire reactor, but also fully utilizes solar energy, a clean energy, without the generation of pollutants, making the entire reaction more green and sustainable.
[0022] 3. The present invention provides a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy. A plurality of concentrated solar panels are arranged on an omnidirectional energy storage type solar concentrator. Four panels are used as units to refract sunlight onto the preheating outer layer, and the curved pipeline in the preheating outer layer is heated through a quartz window to heat the raw gas. The side heating is used so that the raw gas reaches the optimal main reaction temperature when entering the reforming chamber to participate in the reaction, which greatly reduces the probability of side reactions, makes more reasonable use of raw materials, significantly improves the utilization rate of raw materials, effectively avoids the carbon deposition and deactivation of the catalyst, and prolongs the service life of the reactor, which is in line with the core principles of green chemistry.
[0023] 4. The present invention provides a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy. The upper part of the reforming reactor body is a heat recovery zone. A serpentine sleeve is arranged inside the heat recovery zone. The high-temperature gas generated by the reforming reaction is fully heat-exchanged with the raw material gas in the outer layer of the sleeve and the inner layer, so that the raw material at room temperature is preheated for the first time, making full use of the sensible heat of the high-temperature synthesis gas, recovering heat energy to the greatest extent, and improving the energy utilization efficiency of the entire reactor. BRIEF DESCRIPTION OF THE DRAWINGS
[0024] Figure 1 It is a schematic diagram of the three-dimensional structure of the present invention;
[0025] Figure 2 It is a schematic diagram of the three-dimensional structure of the omnidirectional energy storage type solar concentrator of the present invention;
[0026] Figure 3 It is a schematic diagram of the three-dimensional structure of the concentrating solar panel of the present invention;
[0027] Figure 4 A side view of the folded concentrated solar panel of the present invention;
[0028] Figure 5 A top view of an unfolded concentrated solar panel of the present invention;
[0029] Figure 6 It is a schematic diagram of the three-dimensional structure of the storage body of the electric storage element of the present invention;
[0030] Figure 7 It is a schematic diagram of the three-dimensional structure of the reforming reactor body of the present invention;
[0031] Figure 8 It is a structural schematic diagram of the intelligent fixed-point heating resistance coil of the present invention;
[0032] Fig. 9 It is a structural schematic diagram of the resistance heating unit of the present invention;
[0033] Fig.10It is a schematic diagram of the structure of the curved pipeline inside the preheating outer layer of the present invention;
[0034] Fig.11 It is a schematic diagram of the structure of the serpentine sleeve inside the heat recovery chamber of the present invention.
[0035] Numbers in the figure:
[0036] 1. Reforming reactor body; 2. All-round energy storage solar concentrator; 3. Heat recovery chamber; 4. Preheating outer layer; 5. Reforming chamber; 7. Concentrating and heat collecting reflector; 8. Storage body for power storage components;
[0037] 31. Snake-shaped casing; 32. Raw material air inlet; 33. Product outlet;
[0038] 41. first quartz window; 42. curved pipeline; 43. opening;
[0039] 51. Intelligent fixed-point heating resistance coil; 52. Conical cavity; 53. Second quartz window; 54. Product gas outlet; 55. Gas inlet; 511. Resistance heating unit; 5111. Resistance; 5112. Intelligent heating controller;
[0040] 61. Concentrating solar panel; 611. Concentrating reflector; 612. Spring; 613. Electric telescopic rod; 614. Solar panel; 81. Electricity storage element. DETAILED DESCRIPTION
[0041] In order to make the technical problems, technical solutions and beneficial effects to be solved by the present invention clearer, the present invention is further described in detail in conjunction with the embodiments and the accompanying drawings. It should be understood that the specific embodiments described herein are only used to explain the present invention and are not intended to limit the present invention. The technical solutions of the present invention are described in detail below in conjunction with the embodiments and the accompanying drawings, but the scope of protection is not limited thereto.
[0042] See also Figures 1 to 11The present embodiment proposes a methane dry reforming photoelectric coupling reactor for efficiently utilizing solar energy, comprising a reforming reactor body 1, an omnidirectional energy storage type solar concentrator 2 and an electric storage element storage body 8; the omnidirectional energy storage type solar concentrator 2 is a pot body structure with an arc-shaped inner wall; the reforming reactor body 1 is located at the inner center of the omnidirectional energy storage type solar concentrator 2 and is connected and fixed by three brackets; a plurality of concentrating solar panels 61 are arranged on the inner side wall of the omnidirectional energy storage type solar concentrator 2; wherein every four adjacent concentrating solar panels 61 are connected to a dual-axis rotating solar tracking system to form an angle adjustment unit; a concentrating and heat collecting reflector 7 is arranged on the inner bottom of the omnidirectional energy storage type solar concentrator 2; the concentrating and heat collecting reflector 7 is parabolic in shape as a whole, and is composed of a plurality of concentrating reflectors in the shape of fan rings. The bottom of the omni-directional energy storage type solar concentrator 2 is connected to the top of the storage element storage body 8 through a dual-axis rotation solar tracking system; the storage element storage body 8 is a hollow cone structure, and a storage element 81 is placed inside the storage element storage body 8. It should be noted that the dual-axis rotation solar tracking system is an existing device, and the product model used in this embodiment is the PLS-STAS-I small solar dual-axis tracking application system.
[0043] The upper part of the reforming reactor body 1 is a heat recovery chamber 3, and the lower part is a reforming chamber 5; the top of the heat recovery chamber 3 is provided with a raw material air inlet 32 and a product outlet 33; and a serpentine sleeve 31 is provided inside the heat recovery chamber 3; the top of the inner tube of the serpentine sleeve 31 is connected to the raw material air inlet 32, and the top of the outer tube of the serpentine sleeve 31 is connected to the product outlet 33; a conical chamber 52 is provided at the center of the reforming chamber 5; a second quartz window 53 is provided at the bottom of the conical chamber 52; an intelligent fixed-point heating resistor ring 51 is provided around the outside of the conical chamber 52; wherein, the conical chamber 5 The cavity wall of 2 is a dense ceramic layer of SiC material with a thickness of 1mm; the space between the outer wall of the conical cavity 52 and the inner wall of the reforming cavity 5 is filled with solid porous ceramic SiC, and the solid porous ceramic SiC is coated with a catalyst of Co / carbon-based material; the space is the main area of methane dry reforming reaction; during the reaction process, the focusing and heat collecting reflector 7 reflects the light energy and injects it into the interior of the conical cavity 52 through the second quartz window 53, and the methane dry reforming reaction area is heated by the heat generated by the conical cavity 52, and the catalyst is heated from the inside to make the ambient temperature of the catalyst more uniform. Two front-to-back symmetrical air inlets 55 are arranged at the bottom of the reforming cavity 5, and the gas flows into it for reaction; the top of the reforming cavity 5 is provided with a product outlet 54.
[0044] The intelligent fixed-point heating resistance coil 51 is composed of a plurality of resistance heating units 511 connected by pure nickel high-temperature wires. Each resistance heating unit 511 is composed of a resistor 5111 with a hollow cylindrical structure and an intelligent heating controller 5112 located inside the resistor 5111. The intelligent heating controller 5112 is provided with a temperature sensor and a control switch. The resistance heating unit 511 is connected to the PLC system.
[0045] The outer wall of the reforming chamber 5 is wrapped with a preheating outer layer 4; the side wall of the preheating outer layer 4 is a first quartz window 41, which is made of quartz with strong light transmittance; two openings 43 are symmetrically arranged on the top of the preheating outer layer 4, and two sets of left-right symmetrical curved pipelines 42 are distributed inside the preheating outer layer 4, and temperature sensors are arranged in the curved pipelines 42; the top of the curved pipeline 42 is connected to the corresponding opening 43, and the end of the curved pipeline 42 is connected to the air inlet 55 at the bottom of the reforming chamber 5. The bottom of the inner tube of the serpentine sleeve 31 is connected to the opening 43, and the bottom of the outer tube of the serpentine sleeve 31 is connected to the product outlet 54; the high-temperature synthesis gas produced by the methane dry reforming reaction flows into the outer tube of the serpentine sleeve 31 from the product outlet 54.
[0046] A plurality of concentrated solar panels 61 are located in the same plane as the preheating outer layer 4 , and light energy is emitted into the preheating outer layer 4 through the concentrated solar panels 61 to preheat the raw gas inside the preheating outer layer 4 .
[0047] The concentrating solar panel 61 is a double-layer structure, the upper layer is a plurality of rows of concentrating reflectors 611 arranged in sequence, and the lower layer is a solar panel 614; each row of concentrating reflectors 611 is composed of a plurality of concentrating reflectors 611 connected in sequence, and the rows are connected by nickel-based high-temperature synthetic wires; two adjacent rows of concentrating reflectors 611 are connected by springs 612, and the springs 612 are made of nickel-based high-temperature synthetic wires; an electric cut-off telescopic rod 613 is provided at the bottom of the plurality of rows of concentrating reflectors 611, the base of the electric cut-off telescopic rod 613 is fixed to one end of the plurality of rows of concentrating reflectors 611, and the extended end of the electric cut-off telescopic rod 613 is connected to the electric cut-off telescopic rod 613 away from the electric cut-off telescopic rod 613. The telescopic rod 613 is connected to the spring 612 at the base; the telescopic length of each section of the electric cut telescopic rod 613 is the width of two rows of condensing reflectors 611, and the electric cut telescopic rod 613 and the temperature sensor in the curved pipeline 42 are connected to the PLC system; when the temperature sensor in the curved pipeline 42 sends a signal that the preheating temperature of the raw gas reaches the preset temperature threshold, the electric cut telescopic rod 613 is controlled by the PLC system to retract, so that the multiple rows of condensing reflectors 611 are folded to expose the solar panel 614 at the lower layer; the solar panel 614 is connected to the power storage element 81, which is used to convert the solar energy absorbed by the solar panel 614 into electrical energy for storage. The power storage element 81 is connected to all electrical equipment in the device through lines to provide electrical energy for these electrical equipment.
[0048] On the contrary, when the preheating temperature of the raw gas does not reach the preset temperature threshold, the electric telescopic rod 613 is in an extended state, and the multiple rows of focusing reflectors 611 are in an unfolded state. It should be noted that the nickel-based high-temperature synthetic wire connected between the rows is lower than its own yield level during the folding process, and the spring 612 made of the nickel-based high-temperature synthetic wire undergoes elastic deformation.
[0049] This embodiment proposes a methane dry reforming photoelectric coupling reactor that efficiently utilizes solar energy. The working principle is:
[0050] Methane and carbon dioxide are introduced from the raw material inlet 32 in a volume ratio of 1:1, enter the inner tube of the serpentine sleeve 31, and then enter the curved pipeline 42 of the preheating outer layer 4 through two symmetrical openings 43 on the preheating outer layer 4. Multiple rows of focusing reflectors 611 inject light energy into the curved pipeline 42 through the first quartz window 41, which is used to preheat and heat the raw gas inside the curved pipeline 42; the heated raw gas enters the reforming chamber 5 through the air inlet 55 for methane dry reforming reaction, and the high-temperature synthesis gas produced by the reaction flows into the outer tube of the serpentine sleeve 31 through the product outlet 54, thereby preliminarily preheating the raw gas in the inner tube of the serpentine sleeve 31; the high-temperature synthesis gas after heat exchange is discharged through the product outlet 33. While preheating the raw gas in the curved pipeline 42, the temperature of the reforming chamber 5 is gradually increased under the focusing effect of the focusing heat collecting reflector 7 and the second quartz window 53, and the temperature of the catalyst environment in the reforming chamber 5 is more uniform.
[0051] Due to the shortcomings of uneven sunlight and uncontrollable sunlight, an intelligent fixed-point heating resistor coil 51 is also provided in the reforming chamber 5. Each resistance heating unit 511 is provided with an intelligent heating controller 5112. The intelligent heating controller 5112 has a temperature sensor inside and is connected to the PLC system. The resistance heating unit 511 at each part of the reforming chamber 5 is set with a reaction temperature. When the actual temperature of a point in the reforming chamber 5 is lower than the set reaction temperature, the resistance heating unit 511 at that point is powered on to generate heat until the temperature at that point reaches the set value and stops heating. Since each individual resistance heating unit 511 has an independent control structure, each resistance heating unit 511 can carry out heating work alone or work in coordination with each other; the entire heating system has temperature control flexibility, realizes refined control of the temperature in the reforming chamber 5, meets diverse heating requirements, and enables the methane dry reforming reaction to proceed efficiently and stably.
[0052] When the temperature sensor in the curved pipeline 42 sends a signal that the raw gas preheating temperature reaches the preset temperature threshold, the PLC system controls the electric telescopic rod 613 to retract, so that the multiple rows of focusing reflectors 611 are folded to expose the lower solar panels 614; the solar panels 614 are connected to the power storage element 81 to convert the solar energy absorbed by the solar panels 614 into electrical energy for storage. The power storage element 81 is connected to all electrical devices in the device through lines to provide electrical energy for these electrical devices.
[0053] The above content is a further detailed description of the present invention in combination with a specific preferred embodiment. It cannot be determined that the specific embodiments of the present invention are limited to this. For ordinary technicians in the technical field to which the present invention belongs, several simple deductions or substitutions can be made without departing from the present invention, which should be regarded as belonging to the present invention and the scope of patent protection determined by the submitted claims.
Claims
1. A methane dry reforming photoelectric coupled reactor that efficiently utilizes solar energy, characterized in that: It comprises a reforming reactor body (1), an omnidirectional energy storage type solar concentrator (2) and an electric storage element storage body (8); the omnidirectional energy storage type solar concentrator (2) is a pot body structure with an arc-shaped inner wall; the reforming reactor body (1) is located on the inner side of the omnidirectional energy storage type solar concentrator (2); The internal side wall of the omnidirectional energy storage type solar concentrator (2) is provided with a plurality of concentrated solar panels (61); the internal bottom of the omnidirectional energy storage type solar concentrator (2) is provided with a concentrated heat collecting reflector (7); and the internal part storage body (8) is provided with an electric storage element (81); The reforming reactor body (1) is provided with a reforming chamber (5); a conical chamber (52) is provided at the center of the reforming chamber (5); a second quartz window (53) is provided at the bottom of the conical chamber (52); a methane dry reforming reaction region is provided between the outer wall of the conical chamber (52) and the inner wall of the reforming chamber (5), and a catalyst is filled in the methane dry reforming reaction region; a focusing and heat collecting reflector (7) reflects light energy and injects it into the interior of the conical chamber (52) through the second quartz window (53), and heats the methane dry reforming reaction region through the heat generated by the conical chamber (52); The outer wall of the reforming chamber (5) is wrapped with a preheating outer layer (4), the side wall of the preheating outer layer (4) is a first quartz window (41), a plurality of concentrating solar panels (61) are located on the same plane as the preheating outer layer (4), and light energy is emitted into the preheating outer layer (4) through the concentrating solar panels (61) to preheat the raw gas inside the preheating outer layer (4); a temperature sensor is arranged inside the preheating outer layer (4); and the preheating outer layer (4) is connected to the reforming chamber (5); The concentrating solar panel (61) is a double-layer structure, the upper layer is a plurality of rows of concentrating reflectors (611) arranged in sequence, and the lower layer is a solar panel (614); each row of concentrating reflectors (611) is composed of a plurality of concentrating reflectors (611) connected in sequence, and the rows are connected by nickel-based high-temperature synthetic wires; two adjacent rows of concentrating reflectors (611) are connected by springs (612), and an electric cut-type telescopic rod (613) is provided at the bottom of the plurality of rows of concentrating reflectors (611), and the base of the electric cut-type telescopic rod (613) is fixed to one end of the plurality of rows of concentrating reflectors (611). The extended end of the rod (613) is connected to a spring (612) away from the base of the electric telescopic rod (613); the electric telescopic rod (613) and the temperature sensor are both connected to a PLC system; when the temperature sensor sends a signal that the raw gas preheating temperature reaches a preset temperature threshold, the electric telescopic rod (613) is controlled to retract through the PLC system, so that the multiple rows of focusing reflectors (611) are folded to expose the solar panel (614) at the lower layer; the solar panel (614) is connected to the power storage element (81) to convert the solar energy absorbed by the solar panel (614) into electrical energy for storage.
2. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 1, characterized in that: The spring (612) is made of nickel-based high temperature synthetic wire.
3. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 1, characterized in that: A curved pipeline (42) is distributed inside the preheating outer layer (4), and the temperature sensor is arranged in the curved pipeline (42); openings (43) are symmetrically arranged at the top of the preheating outer layer (4); an air inlet (55) is arranged at the bottom of the reforming chamber (5); a product air outlet (54) is arranged at the top of the reforming chamber (5); and the end of the curved pipeline (42) is connected to the air inlet (55) at the bottom of the reforming chamber (5).
4. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 3, characterized in that: The upper part of the reforming reactor body (1) is a heat recovery chamber (3), and the reforming chamber (5) is arranged at the lower part of the reforming reactor body (1); the top of the heat recovery chamber (3) is provided with a raw material air inlet (32) and a product outlet (33); a serpentine sleeve (31) is arranged inside the heat recovery chamber (3); the top of the inner tube of the serpentine sleeve (31) is connected to the raw material air inlet (32), and the top of the outer tube of the serpentine sleeve (31) is connected to the product outlet (33); the bottom of the inner tube of the serpentine sleeve (31) is connected to the opening (43), and the bottom of the outer tube of the serpentine sleeve (31) is connected to the product outlet (54).
5. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 1, characterized in that: An intelligent fixed-point heating resistance ring (51) surrounds the outside of the conical cavity (52); the intelligent fixed-point heating resistance ring (51) is composed of a plurality of resistance heating units (511) connected by pure nickel high-temperature wires, each resistance heating unit (511) is composed of a resistor (5111) with a hollow cylindrical structure and an intelligent heating controller (5112) located inside the resistor (5111), and a temperature sensor and a control switch are provided in the intelligent heating controller (5112); the resistance heating unit (511) is connected to a PLC system.
6. The photoelectric coupled reactor for dry reforming of methane with high efficiency of utilizing solar energy according to claim 1, characterized in that: The light-collecting and heat-collecting reflector (7) is parabolic in shape as a whole, and is composed of a plurality of light-collecting reflectors in the shape of fan rings.
7. The photoelectric coupled reactor for dry reforming of methane with high efficiency of utilizing solar energy according to claim 1, characterized in that: The electricity storage element storage body (8) is a hollow cone structure, and the electricity storage element (81) is placed in the hollow cone structure.
8. The photoelectric coupled reactor for dry reforming of methane with high efficiency of utilizing solar energy according to claim 1, characterized in that: Every four adjacent concentrated solar panels (61) are connected to a dual-axis rotation solar tracking system to form an angle adjustment unit.
9. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 1, characterized in that: The cavity wall of the conical cavity (52) is a dense ceramic layer made of SiC material with a thickness of 1 mm.
10. The methane dry reforming photoelectric coupled reactor for efficient utilization of solar energy according to claim 1, characterized in that: The methane dry reforming reaction area is filled with solid porous ceramic SiC, and the solid porous ceramic SiC is coated with a Co / carbon-based material catalyst.
Citation Information
Patent Citations
Solar energy methane reforming reactor based on photo-thermal cooperative utilization
CN103738918A
High-temperature solar air heating device
CN103940120A
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