Easy-to-clean radix asparagi polyurea anticorrosive paint and preparation method thereof

By using silicone modified hydroxyacrylic resin and polyaspartic resin in asparagus polyurea coatings, combined with wear-resistant additives, the problem of stains not easy to clean after wear and impact of the paint and the paint film is easily broken, achieving excellent cleaning, impact resistance and corrosion resistance of the coating.

CN119752295APending Publication Date: 2025-04-04SICHUAN SANKESHU PAINT CO LTD
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Patent Information

Application Number
CN202411989442.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-31
Publication Date
2025-04-04

AI Technical Summary

Technical Problem

The existing asparagus polyurea coatings are not easy to clean after high-strength wear, and the paint film is prone to breaking after strong impact, affecting the overall appearance and corrosion resistance of the coating film.

Method used

The combination of silicone modified hydroxyacrylic resin and polyaspartic resin is used to improve the stain resistance and impact resistance of the paint film, and add wear-resistant additives to improve the corrosion resistance and easy cleaning of the paint film.

Benefits of technology

It achieves excellent cleaning, impact resistance and corrosion resistance of the coating, avoids the problems of stain residue and paint film fragmentation, and improves the overall performance of the coating.

✦ Generated by Eureka AI based on patent content.

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Patent Text Reader

Abstract

The invention relates to an easy-to-clean radix asparagi polyurea anticorrosive paint and a preparation method thereof, the easy-to-clean radix asparagi polyurea anticorrosive paint comprises a main agent and a curing agent, the main agent is mainly prepared from the following components: polyaspartic acid resin, organosilicon modified hydroxy acrylic resin, a wear-resistant additive, a filler, titanium dioxide, a rheological additive, a dispersant, a defoaming agent, a leveling agent, an anti-aging additive and xylene; the curing agent is mainly prepared from the following components: a hexamethylene diisocyanate isocyanurate tripolymer and butyl acetate. The polyaspartic acid ester polyurea paint overcomes the defects that when an existing polyaspartic acid ester polyurea material is applied to the fields of engineering machinery, maritime work equipment and the like, stains are not easy to clean after a paint film is subjected to high-strength abrasion, and even the paint film is broken after being strongly impacted, so that the corrosion resistance of the paint film is influenced; the organic silicon modified hydroxy acrylic resin and the polyaspartic acid resin are matched to improve the stain resistance and impact resistance of a paint film, so that a coating is easier to clean, and the wear-resistant additive is matched, so that the paint has the advantages of being easy to clean and excellent in impact resistance and corrosion resistance.
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Description

Technical Field

[0001] The invention relates to an easy-to-clean aspartame polyurea anticorrosive coating and a preparation method thereof, and is applied in the field of anticorrosive coating production. Background Art

[0002] Polyaspartic acid ester polyurea material, referred to as aspartic polyurea, is a new type of aliphatic polyurea that has appeared in the polyurea industry in recent years, and is also known as the third generation of polyurea. Aspartic polyurea coatings are widely used in petrochemicals, wind turbine blades, special containers, engineering machinery, marine heavy-duty anti-corrosion, automobiles, high-end industrial and commercial flooring, waterproofing and other fields due to their excellent comprehensive performance. However, it is currently found in the applications of some engineering machinery, marine equipment, etc. that the stains on the paint film are difficult to clean after high-intensity wear, and even break after strong impact, which affects the overall appearance of the coating and the comprehensive anti-corrosion performance of the matching coating.

[0003] Therefore, it has become an urgent task to provide an easy-to-clean asparagus polyurea anti-corrosion coating with excellent impact resistance and corrosion resistance and a preparation method thereof. Summary of the invention

[0004] In order to overcome the shortcomings of existing polyaspartic acid ester polyurea materials used in engineering machinery, marine equipment and other fields, such as the paint film is difficult to clean after high-intensity wear and even breaks after a strong impact, affecting the overall appearance of the coating film and the comprehensive anti-corrosion performance of the matching coating. The present invention provides an easy-to-clean aspartic acid polyurea anti-corrosion coating and a preparation method thereof. Silicone-modified hydroxy acrylic resin and polyaspartic acid resin are used to improve the anti-fouling and impact resistance of the paint film, making the coating easier to clean, and wear-resistant additives are used to improve the corrosion resistance of the paint film. It has the advantages of easy cleaning, excellent impact resistance and corrosion resistance.

[0005] The technical solution of the present invention is as follows:

[0006] An easy-to-clean aspartame polyurea anticorrosive coating, comprising a main agent and a curing agent.

[0007] The main agent is mainly prepared from the following components in the following weight proportions:

[0008]

[0009]

[0010] The curing agent is mainly prepared from the following components in the following weight proportions:

[0011] 80-90 parts of hexamethylene diisocyanate isocyanurate trimer

[0012] 10-20 parts of butyl acetate.

[0013] The easy-to-clean asparagus polyurea anticorrosive coating of the present application adopts organosilicon-modified hydroxy acrylic resin and polyaspartic acid resin to improve the anti-fouling and impact resistance of the paint film, making the coating easier to clean, matching wear-resistant additives, improving the anti-corrosion of the paint film, and having the advantages of easy cleaning, impact resistance and excellent anti-corrosion. It embeds hydrophobic and oleophobic organosilicon segments in the asparagus polyurea resin structure through the chemical reaction of hydroxyl and isocyanate, so as to achieve the effect of anti-fouling and easy cleaning; the introduction of hydrophobic and oleophobic organosilicon segments also greatly improves the water resistance, chemical resistance and salt spray resistance of the paint film, so that the anti-corrosion performance of the paint film is greatly improved; in addition, the flexibility of the organosilicon segments improves the impact resistance of the asparagus polyurea coating, and reduces the anti-corrosion performance caused by impact cracks. At the same time, by adding wear-resistant additives, the surface energy of the paint film is greatly reduced, the smoothness and wear resistance of the paint film surface are improved, and the anti-corrosion performance of the supporting coating is finally made more excellent, further improving the anti-fouling and easy-to-clean effect of the paint film.

[0014] The secondary amino group content in the polyaspartic acid resin is 250-300 g / mol.

[0015] The filler is one or any combination of two or more of talc, barium sulfate, silica powder or molecular sieve.

[0016] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0017] The rheological additive is one of fumed silica, bentonite, and polyamide wax powder, or any combination of two or more thereof.

[0018] The other additives are dispersants, defoamers, leveling agents or anti-aging additives.

[0019] The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 from Wanhua Chemical or DESMODUR N3300 from Covestro.

[0020] The easy-to-clean aspartame polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 2.5-4:1.

[0021] The method for preparing the easy-to-clean aspartame polyurea anticorrosive coating comprises the following steps in sequence:

[0022] (1) starting a stirrer, adjusting the speed to 1200-1600 r / min, adding polyaspartic acid resin, silicone-modified hydroxy acrylic resin, dispersant, defoamer, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after uniform dispersion, heating to 60-80° C. and keeping the temperature for at least 30 minutes to obtain a mixture;

[0023] (2) Grind the mixture obtained in step (1) to a fineness of <30 μm (please confirm), then put the mixture into a mixer, start the mixer, adjust the mixer speed to 400-800 r / min, add wear-resistant additives, leveling agents and anti-aging additives while dispersing, and continue to disperse until uniform, thereby obtaining the main agent;

[0024] The preparation method of the curing agent comprises the following steps performed in sequence:

[0025] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0026] The preparation method of the easy-to-clean aspartame polyurea anti-corrosion coating of the present application has simple steps and is easy to operate.

[0027] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 2.5-4:1 to obtain the easy-to-clean aspartame polyurea anti-corrosion coating.

[0028] The easy-to-clean asparagus polyurea anti-corrosion coating of the present application is easy to use and only requires a simple mixing of the main agent and the curing agent.

[0029] Compared with the prior art, the present invention has the following advantages:

[0030] 1) The easy-to-clean aspartic polyurea anticorrosive coating of the present application uses silicone-modified hydroxy acrylic resin and polyaspartic acid resin to improve the anti-fouling and impact resistance of the paint film, making the coating easier to clean, and is matched with wear-resistant additives to improve the corrosion resistance of the paint film. It has the advantages of easy cleaning, excellent impact resistance and corrosion resistance;

[0031] 2) The preparation method of the easy-to-clean aspartame polyurea anticorrosive coating has simple steps and is easy to operate;

[0032] 3) The easy-to-clean polyurea anti-corrosion coating of the present application is easy to use and only requires a simple mixing of the main agent and the curing agent. DETAILED DESCRIPTION

[0033] The technical solution of the present invention is described in detail below in conjunction with the embodiments of the specification.

[0034] Example 1

[0035] The easy-to-clean aspartame polyurea anticorrosive coating of the present invention comprises a main agent and a curing agent.

[0036] The main agent is mainly prepared from the following components in the following weight proportions:

[0037]

[0038] The curing agent is mainly prepared from the following components in the following weight proportions:

[0039] 90 parts of hexamethylene diisocyanate isocyanurate trimer

[0040] 10 parts of butyl acetate.

[0041] The secondary amino group content in the polyaspartic acid resin is 280 g / mol.

[0042] The filler is barium sulfate.

[0043] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0044] The rheological additive is bentonite.

[0045] The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 produced by Wanhua Chemical.

[0046] The easy-to-clean aspartame polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 3:1 when in use.

[0047] The method for preparing the easy-to-clean aspartame polyurea anticorrosive coating comprises the following steps in sequence:

[0048] (1) starting a stirrer, adjusting the speed to 1200 r / min, adding polyaspartic acid resin, silicone-modified hydroxy acrylic resin, dispersant, defoamer, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after uniform dispersion, heating to 60° C. and keeping the temperature for 30 minutes to obtain a mixture;

[0049] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 400 r / min, adding a wear-resistant additive, a leveling agent and an anti-aging additive while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0050] The preparation method of the curing agent comprises the following steps performed in sequence:

[0051] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0052] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 3:1 to obtain the easy-to-clean asparagine polyurea anti-corrosion coating.

[0053] Example 2

[0054] The easy-to-clean aspartame polyurea anticorrosive coating of the present invention comprises a main agent and a curing agent.

[0055] The main agent is mainly prepared from the following components in the following weight proportions:

[0056]

[0057] The curing agent is mainly prepared from the following components in the following weight proportions:

[0058] 85 parts of hexamethylene diisocyanate isocyanurate trimer

[0059] 15 parts of butyl acetate.

[0060] The secondary amino group content in the polyaspartic acid resin is 250 g / mol.

[0061] The filler is a mixture of barium sulfate and silicon powder in a weight ratio of 10:9.

[0062] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0063] The rheological additive is polyamide wax powder.

[0064] The hexamethylene diisocyanate isocyanurate trimer is DESMODUR N3300 from Covestro.

[0065] The easy-to-clean aspartame polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 2.5:1 when in use.

[0066] The method for preparing the easy-to-clean aspartame polyurea anticorrosive coating comprises the following steps in sequence:

[0067] (1) starting a stirrer, adjusting the speed to 1600 r / min, adding polyaspartic acid resin, silicone-modified hydroxy acrylic resin, dispersant, defoamer, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after uniform dispersion, heating to 80° C. and keeping the temperature for 40 minutes to obtain a mixture;

[0068] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 800 r / min, adding a wear-resistant additive, a leveling agent and an anti-aging additive while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0069] The preparation method of the curing agent comprises the following steps performed in sequence:

[0070] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0071] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 2.5:1 to obtain the easy-to-clean aspartame polyurea anti-corrosion coating.

[0072] Example 3

[0073] The easy-to-clean aspartame polyurea anticorrosive coating of the present invention comprises a main agent and a curing agent.

[0074] The main agent is mainly prepared from the following components in the following weight proportions:

[0075]

[0076] The curing agent is mainly prepared from the following components in the following weight proportions:

[0077] 80 parts of hexamethylene diisocyanate isocyanurate trimer

[0078] 20 parts of butyl acetate.

[0079] The secondary amino group content in the polyaspartic acid resin is 300 g / mol.

[0080] The filler is a mixture of barium sulfate, silicon micropowder and molecular sieve in a weight ratio of 11:11:4.

[0081] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0082] The rheological additive is a mixture of fumed silica and bentonite in a weight ratio of 2:1.

[0083] The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 produced by Wanhua Chemical.

[0084] The easy-to-clean aspartame polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 4:1 when in use.

[0085] The method for preparing the easy-to-clean aspartame polyurea anticorrosive coating comprises the following steps in sequence:

[0086] (1) starting a stirrer, adjusting the speed to 1400 r / min, adding polyaspartic acid resin, silicone-modified hydroxy acrylic resin, dispersant, defoamer, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after uniform dispersion, heating to 70° C. and keeping the temperature for 50 minutes to obtain a mixture;

[0087] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 600 r / min, adding a wear-resistant additive, a leveling agent and an anti-aging additive while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0088] The preparation method of the curing agent comprises the following steps performed in sequence:

[0089] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0090] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 4:1 to obtain the easy-to-clean aspartame polyurea anti-corrosion coating.

[0091] Raw material information involved in each embodiment:

[0092] Polyaspartic acid resin: Feiyang Chemical F520, Feiyang Chemical F420, Bayer NH1520, Bayer NH1420

[0093] Silicone modified hydroxy acrylic resin: Jiazhi JZ-9522

[0094] Wear-resistant additive: Polytetrafluoroethylene-modified polyethylene wax powder, Lubrizol Laco TF 1780

[0095] Filler: Molecular sieve: Grace A3 Hexamethylene diisocyanate Isocyanurate trimer: Wanhua Chemical WANNATE HT-100, Covestro DESMODUR N3300

[0096] Rheological additives: fumed silica: Degussa R972, bentonite: Clayminton 72, polyamide wax powder: CRAYVALLACULTRA

[0097] Other additives: dispersants: BYK-163, BYK-110, Efcona 4063, leveling agents: BYK-306, BYK358, BYK333, anti-aging additives: BASF TINUVIN 292, BASF TINUVIN 1130, defoamers: BYK-052, BYK-141, Efka 2020AN.

[0098] Experimental data:

[0099] Comparative Example 1:

[0100] The difference from Example 1 is that no silicone-modified hydroxy acrylic resin and wear-resistant additive are used, and the amounts of each component are slightly different.

[0101] An asparagine polyurea anticorrosive coating comprises a main agent and a curing agent.

[0102] The main agent is mainly prepared from the following components in the following weight proportions:

[0103]

[0104] The curing agent is mainly prepared from the following components in the following weight proportions:

[0105] 80 parts of hexamethylene diisocyanate isocyanurate trimer

[0106] 20 parts of butyl acetate.

[0107] The secondary amino group content in the polyaspartic acid resin is 280 g / mol.

[0108] The filler is one or any combination of two or more of talc, barium sulfate, silica powder or molecular sieve.

[0109] The rheological additive is one of fumed silica, bentonite, and polyamide wax powder, or any combination of two or more thereof.

[0110] The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 produced by Wanhua Chemical.

[0111] The asparagus polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 3:1 when in use.

[0112] The preparation method of the asparagine polyurea anticorrosive coating, the preparation method of the main agent comprises the following steps performed in sequence:

[0113] (1) starting a stirrer, adjusting the speed to 1200 r / min, adding polyaspartic acid resin, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after being evenly dispersed, heating to 60° C. and maintaining the temperature for 30 minutes to obtain a mixture;

[0114] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 400 r / min, adding other additives while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0115] The preparation method of the curing agent comprises the following steps performed in sequence:

[0116] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0117] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 3:1 to obtain the asparagine polyurea anti-corrosion coating.

[0118] Comparative Example 2:

[0119] The difference from Example 2 is that no silicone-modified hydroxy acrylic resin is used and the amounts of each component are slightly different.

[0120] An asparagine polyurea anticorrosive coating comprises a main agent and a curing agent.

[0121] The main agent is mainly prepared from the following components in the following weight proportions:

[0122]

[0123]

[0124] The curing agent is mainly prepared from the following components in the following weight proportions:

[0125] 80 parts of hexamethylene diisocyanate isocyanurate trimer

[0126] 20 parts of butyl acetate.

[0127] The secondary amino group content in the polyaspartic acid resin is 250 g / mol.

[0128] The filler is a mixture of barium sulfate and silicon powder in a weight ratio of 10:9.

[0129] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0130] The rheological additive is polyamide wax powder.

[0131] The hexamethylene diisocyanate isocyanurate trimer is DESMODUR N3300 from Covestro.

[0132] The asparagus polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 2.5:1 when in use.

[0133] The preparation method of the asparagine polyurea anticorrosive coating, the preparation method of the main agent comprises the following steps performed in sequence:

[0134] (1) starting a stirrer, adjusting the speed to 1600 r / min, adding polyaspartic acid resin, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after being evenly dispersed, heating to 80° C. and keeping the temperature for 40 minutes to obtain a mixture;

[0135] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 800 r / min, adding wear-resistant additives and other additives while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0136] The preparation method of the curing agent comprises the following steps performed in sequence:

[0137] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0138] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 2.5:1 to obtain the asparagine polyurea anti-corrosion coating.

[0139] Comparative Example 3:

[0140] The difference from Example 3 is that instead of using the organosilicon-modified hydroxy acrylic resin, an amino-terminated organosilicon coupling agent is used, and no wear-resistant additive is used. The amounts of the components used are slightly different.

[0141] An easy-to-clean aspartame polyurea anticorrosive coating, comprising a main agent and a curing agent.

[0142] The main agent is mainly prepared from the following components in the following weight proportions:

[0143]

[0144] The curing agent is mainly prepared from the following components in the following weight proportions:

[0145] 80 parts of hexamethylene diisocyanate isocyanurate trimer

[0146] 20 parts of butyl acetate.

[0147] The secondary amino group content in the polyaspartic acid resin is 300 g / mol.

[0148] The filler is a mixture of barium sulfate, silicon micropowder and molecular sieve in a weight ratio of 11:11:4.

[0149] The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

[0150] The rheological additive is a mixture of fumed silica and bentonite in a weight ratio of 2:1.

[0151] The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 produced by Wanhua Chemical.

[0152] The asparagus polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 4:1 when in use.

[0153] The preparation method of the asparagine polyurea anticorrosive coating, the preparation method of the main agent comprises the following steps performed in sequence:

[0154] (1) starting a stirrer, adjusting the speed to 1400 r / min, adding polyaspartic acid resin, amino-terminated silicone coupling agent, filler, titanium dioxide, rheological additive and xylene into the stirrer, and after uniform dispersion, heating to 70° C. and keeping the temperature for 50 minutes to obtain a mixture;

[0155] (2) grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 600 r / min, adding other additives while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent;

[0156] The preparation method of the curing agent comprises the following steps performed in sequence:

[0157] Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

[0158] When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 4:1 to obtain the asparagine polyurea anti-corrosion coating.

[0159] The above-mentioned comparative examples 1-3 and embodiments 1-3 were painted and made into boards by mixing the main agent and the curing agent according to the ratio, and then the performance test was carried out according to HG / T 5368-2018. The results are shown in Table 1 below:

[0160] Table 1 Performance test results

[0161]

[0162]

[0163] From Table 1, the products of the embodiments of the present case to which silicone-modified hydroxy acrylic resin is added have greatly improved stain resistance of the paint film after being worn, and they are easy to clean after wiping the pollution source. The test results in Comparative Examples 1-3 show that stains are not easy to clean after being attached. It is also found that the embodiments to which silicone-modified hydroxy acrylic resin is added have good alkali resistance and salt spray resistance, but excessive addition will reduce hardness and wear resistance; comparison also shows that after adding wear-resistant additives, the hardness and wear resistance of the paint film are significantly improved; the test results of Comparative Example 3 show that the use of amino-terminated silicone coupling agent instead of silicone-modified hydroxy acrylic resin has an anti-fouling and easy-to-clean effect that is significantly inferior to that achieved by the present invention, and there is also a significant gap in wear resistance.

[0164] The easy-to-clean asparagine polyurea anti-corrosion coating and preparation method thereof described in the present invention are not limited to the above-mentioned embodiments. Any improvement or replacement based on the principle of the present invention should be within the protection scope of the present invention.

Claims

1. An easy-to-clean aspartame polyurea anticorrosive coating, characterized in that: Including main agent and curing agent, The main agent is mainly prepared from the following components in the following weight proportions: 30-40 parts of polyaspartic acid resin 6-15 parts of silicone modified hydroxy acrylic resin Wear-resistant additive 0.5-3 parts Filler 18-26 parts Titanium dioxide 20-28 parts Rheological additive 0.9-1.8 parts Dispersant 0.4-0.8 parts Defoamer 0.3-0.6 parts Leveling agent 0.3-0.6 parts Anti-aging additive 0.4-1.0 parts Xylene 2.7-5.1 parts; The curing agent is mainly prepared from the following components in the following weight proportions: 80-90 parts of hexamethylene diisocyanate isocyanurate trimer 10-20 parts of butyl acetate.

2. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The secondary amino group content in the polyaspartic acid resin is 250-300 g / mol.

3. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The filler is one or any combination of two or more of talc, barium sulfate, silica powder or molecular sieve.

4. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The wear-resistant additive is polyethylene wax powder modified by polytetrafluoroethylene.

5. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The rheological additive is one of fumed silica, bentonite, and polyamide wax powder, or any combination of two or more thereof.

6. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The hexamethylene diisocyanate isocyanurate trimer is WANNATE HT-100 from Wanhua Chemical or DESMODUR N3300 from Covestro.

7. The easy-to-clean aspartame polyurea anticorrosive coating according to claim 1, characterized in that: The easy-to-clean aspartame polyurea anti-corrosion coating is prepared by mixing a main agent and a curing agent in a weight ratio of 2.5-4:

1.

8. The method for preparing the easy-to-clean asparagine polyurea anticorrosive coating according to any one of claims 1 to 7, characterized in that: The preparation method of the main agent comprises the following steps performed in sequence: (1) Start the mixer and adjust the speed to 1200-1600r / min. Add polyaspartic acid resin, silicone-modified hydroxy acrylic resin, dispersant, defoamer, filler, titanium dioxide, rheological additive and xylene into the mixer. After uniform dispersion, heat to 60-80℃ and keep warm. At least 30 minutes to obtain a mixture; (2) Grinding the mixture obtained in step (1) to a fineness of less than 30 μm, then putting the mixture into a mixer, starting the mixer, adjusting the mixer speed to 400-800 r / min, adding a wear-resistant additive, a leveling agent and an anti-aging additive while dispersing, and continuing to disperse until uniform, thereby obtaining a main agent; The preparation method of the curing agent comprises the following steps performed in sequence: Under nitrogen protection conditions, hexamethylene diisocyanate isocyanurate trimer and butyl acetate are uniformly mixed to obtain a curing agent.

9. The method for preparing the easy-to-clean aspartame polyurea anticorrosive coating according to claim 8, characterized in that: When in use, the main agent and the curing agent are evenly mixed in a weight ratio of 2.5-4:1 to obtain the easy-to-clean aspartame polyurea anti-corrosion coating.

Citation Information

Patent Citations

  • Low temperature curing type acrylic polyurethane coating and manufacturing method thereof

    CN105778742A

  • High-wear-resistance synthetic leather and preparation method thereof

    CN118360806A