Catalyst regeneration energy recovery heat pump system
By designing a catalyst regeneration energy recovery heat pump system, the problems of temperature difference loss and low flue gas energy utilization efficiency during catalyst regeneration are solved, efficient energy recovery and utilization are achieved, and the overall energy consumption efficiency of refining production is improved.
Patent Information
- Application Number
- CN202510251472.2
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2024-03-16
- Filing Date
- 2025-02-26
- Publication Date
- 2025-06-20
AI Technical Summary
There are problems such as irreversible temperature difference loss, low flue gas energy utilization efficiency, and poor integration of energy recovery and oil refining production processes during the existing catalyst regeneration process.
A catalyst regeneration energy recovery heat pump system is designed, which consists of a scorch-regeneration system, a heat source heat regeneration device, an absorber, a generator, a condenser, an evaporator, etc. The recycling and utilization of flue gas energy is optimized through components such as high-temperature heat exchangers, throttle valves and solution heat exchangers.
It effectively reduces the temperature difference loss in the catalyst regeneration process, improves the utilization efficiency of flue gas energy, and integrates energy recovery with oil refining production process, improving the efficient utilization and economical energy.
Smart Images

Figure CN120176322A_ABST
Abstract
Description
Technical Field:
[0001] The present invention belongs to the technical fields of thermodynamics and heat pump technology. Background Art:
[0002] Catalytic cracking is a process in which heavy petroleum hydrocarbons produce light oil products such as liquefied gas, gasoline, and diesel under the action of a catalyst. When the feedstock oil undergoes catalytic cracking on the catalyst, on the one hand, products such as gas, gasoline, and diesel are generated through cracking and other reactions, and on the other hand, a condensation reaction occurs simultaneously to form coke deposited on the surface of the catalyst - this reduces the activity of the catalyst.
[0003] People burn the coke deposited on the catalyst with air to restore the activity of the catalyst - catalyst regeneration. This process releases a large amount of thermal energy at a relatively high temperature, which should be fully utilized. Currently, the main means of recovering the energy of the regenerated flue gas is to set up a waste heat boiler to generate steam or further generate power. However, after careful analysis, the following problems are found:
[0004] (1) There is a large irreversible loss of temperature difference during the coke burning process; (2) In the utilization link, the temperature and quantity of the flue gas are not considered simultaneously; (3) The technology for utilizing the energy of the flue gas needs to be improved, and there is still a large room for improvement in both power utilization and heat supply utilization; (4) The energy recovery of the flue gas is not combined with the overall energy consumption of the oil refining production process to enhance its application value.
[0005] Based on the basic principles of simple, active, safe, and efficient energy utilization, the present invention provides a catalyst regeneration energy recovery heat pump system with a reasonable process, simple structure, and capable of realizing efficient / high-value recovery and utilization of the energy for catalyst regeneration. Summary of the Invention:
[0006] The main object of the present invention is to provide a catalyst regeneration energy recovery heat pump system, and the specific content of the invention is elaborated item by item as follows:
[0007] 1. A catalyst regeneration energy recovery heat pump system mainly consists of a burning-regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a recuperator; there is an air passage outside that is connected to the burning-regeneration system through the heat source recuperator, and the burning-regeneration system also has a flue gas passage that is connected to the outside through the high-temperature heat exchanger, the generator and the heat source recuperator; the absorber has a dilute solution pipeline that is connected to the generator through the solution pump and the solution heat exchanger, the generator also has a concentrated solution pipeline that is connected to the absorber through the solution heat exchanger, the generator also has a refrigerant vapor passage that is connected to the condenser, the condenser also has a refrigerant liquid pipeline that is connected to the evaporator through the throttle valve, the evaporator also has a refrigerant vapor passage that is connected to the compressor, the compressor also has a refrigerant vapor passage that is connected to the expander through the recuperator and the high-temperature heat exchanger, the expander also has a refrigerant vapor passage that is connected to itself through the recuperator, and the expander also has a refrigerant vapor passage that is connected to the absorber; the absorber and the condenser also respectively have heated medium passages that are connected to the outside, the evaporator also has a low-temperature heat medium passage that is connected to the outside, and the expander is connected to the compressor and transmits power to form a catalyst regeneration energy recovery heat pump system; wherein, a turbine may be added and the throttle valve may be replaced.
[0008] 2. A catalyst regeneration energy recovery heat pump system mainly consists of a burning-regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a recuperator; there is an air passage outside that is connected to the burning-regeneration system through the heat source recuperator, and the burning-regeneration system also has a flue gas passage that is connected to the outside through the high-temperature heat exchanger, the generator and the heat source recuperator; the absorber has a dilute solution pipeline that is connected to the generator through the solution pump and the solution heat exchanger, the generator also has a concentrated solution pipeline that is connected to the absorber through the solution heat exchanger, the generator also has a refrigerant vapor passage that is connected to the condenser, the condenser also has a refrigerant liquid pipeline that is connected to the evaporator through the throttle valve, the evaporator also has a refrigerant vapor passage that is connected to the compressor, the compressor also has a refrigerant vapor passage that is connected to itself through the recuperator, the compressor also has a refrigerant vapor passage that is connected to the expander through the high-temperature heat exchanger, the expander also has a refrigerant vapor passage that is connected to the absorber through the recuperator; the absorber and the condenser also respectively have heated medium passages that are connected to the outside, the evaporator also has a low-temperature heat medium passage that is connected to the outside, and the expander is connected to the compressor and transmits power to form a catalyst regeneration energy recovery heat pump system; wherein, a turbine may be added and the throttle valve may be replaced.
[0009] 3. The catalyst regeneration energy recovery heat pump system mainly consists of a burning - regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high - temperature heat exchanger, a compressor, an expander, a recuperator, a second compressor and a second recuperator; externally, there is an air passage that is connected to the burning - regeneration system through the heat source recuperator, and the burning - regeneration system also has a flue gas passage that is connected to the outside through the high - temperature heat exchanger, the generator and the heat source recuperator; the absorber has a dilute solution pipeline that is connected to the generator through the solution pump and the solution heat exchanger, the generator also has a concentrated solution pipeline that is connected to the absorber through the solution heat exchanger, the generator also has a refrigerant vapor passage that is connected to the condenser, the condenser also has a refrigerant liquid pipeline that is connected to the evaporator through the throttle valve, the evaporator also has a refrigerant vapor passage that is connected to the compressor, the compressor also has a refrigerant vapor passage that is connected to itself through the recuperator, the compressor also has a refrigerant vapor passage that is connected to the high - temperature heat exchanger through the second recuperator, the second compressor has a refrigerant vapor passage that is connected to the high - temperature heat exchanger, the high - temperature heat exchanger also has a refrigerant vapor passage that is connected to the expander, the expander also has a steam extraction passage that is connected to the second compressor through the second recuperator, and the expander also has a refrigerant vapor passage that is connected to the absorber through the recuperator; the absorber and the condenser also respectively have a heated medium passage that is connected to the outside, the evaporator also has a low - temperature heat medium passage that is connected to the outside, and the expander is connected to the compressor and the second compressor and transmits power, forming a catalyst regeneration energy recovery heat pump system; among them, a turbine can be added and the throttle valve can be replaced.
[0010] 4. The catalyst regeneration energy recovery heat pump system is a system in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 3, with a second generator, a second throttle valve, a second solution pump and a second solution heat exchanger added. The absorber is provided with a dilute solution pipeline that is connected to the second generator through the second solution pump and the second solution heat exchanger, and the second generator also has a concentrated solution pipeline that is connected to the absorber through the second solution heat exchanger. The connection that the generator has a refrigerant vapor passage connected to the condenser is adjusted to that the generator has a refrigerant vapor passage connected to the second generator, and then the second generator has a refrigerant liquid pipeline that is connected to the condenser or the evaporator through the second throttle valve. The second generator also has a refrigerant vapor passage connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0011] 5. The catalyst regeneration energy recovery heat pump system is a system that, in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 3, adds a second generator, a second throttle valve, and a second solution heat exchanger. The connection where the dilute solution pipeline of the absorber is connected to the generator through a solution pump and a solution heat exchanger is adjusted to the dilute solution pipeline of the absorber being connected to the generator through a solution pump, a solution heat exchanger, and a second solution heat exchanger. The connection where the concentrated solution pipeline of the generator is connected to the absorber through a solution heat exchanger is adjusted to the concentrated solution pipeline of the generator being connected to the second generator through a second solution heat exchanger, and then the concentrated solution pipeline of the second generator is connected to the absorber through a solution heat exchanger. The connection where the refrigerant vapor channel of the generator is connected to the condenser is adjusted to the refrigerant vapor channel of the generator being connected to the second generator first, and then the second generator has a refrigerant liquid pipeline that is connected to the condenser or the evaporator through a second throttle valve, and the second generator also has a refrigerant vapor channel connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0012] 6. The catalyst regeneration energy recovery heat pump system is a system that, in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 3, adds a second generator, a second throttle valve, a second solution pump, and a second solution heat exchanger. The connection where the dilute solution pipeline of the absorber is connected to the generator through a solution pump and a solution heat exchanger is adjusted to the dilute solution pipeline of the absorber being connected to the second generator through a solution pump and a solution heat exchanger, and then the second generator has a concentrated solution pipeline that is connected to the generator through a second solution pump and a second solution heat exchanger. The connection where the concentrated solution pipeline of the generator is connected to the absorber through a solution heat exchanger is adjusted to the concentrated solution pipeline of the generator being connected to the absorber through a second solution heat exchanger and a solution heat exchanger. The connection where the refrigerant vapor channel of the generator is connected to the condenser is adjusted to the refrigerant vapor channel of the generator being connected to the second generator first, and then the second generator has a refrigerant liquid pipeline that is connected to the condenser or the evaporator through a second throttle valve, and the second generator also has a refrigerant vapor channel connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0013] 7. The catalyst regeneration energy recovery heat pump system is a system in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1-3, with the addition of a second generator, a second solution pump, a second solution heat exchanger, and a second absorber. The flue gas passage of the coking-regeneration system, which is connected to the outside through a high-temperature heat exchanger, a generator, and a heat source regenerator, is adjusted to be connected to the outside through a high-temperature heat exchanger, a generator, a second generator, and a heat source regenerator. The absorber's dilute solution pipeline, which is connected to the generator through a solution pump and a solution heat exchanger, is adjusted to be connected to the second absorber through a solution pump and a solution heat exchanger, and the second absorber then has a dilute solution pipeline connected to the generator through a second solution pump and a second solution heat exchanger. The generator's concentrated solution pipeline, which is connected to the absorber through a solution heat exchanger, is adjusted to be connected to the second generator through a second solution heat exchanger, and the second generator then has a concentrated solution pipeline connected to the absorber through a solution heat exchanger. The second generator also has a refrigerant vapor passage connected to the second absorber, and the second absorber also has a heated medium passage connected to the outside, thus forming a catalyst regeneration energy recovery heat pump system.
[0014] 8. The catalyst regeneration energy recovery heat pump system is a system in any one of the catalyst regeneration energy recovery heat pump systems described in Item 7, with the addition of a third generator, a second throttle valve, a third solution pump, and a third solution heat exchanger. The second absorber is provided with a dilute solution pipeline connected to the third generator through a third solution pump and a third solution heat exchanger, and the third generator also has a concentrated solution pipeline connected to the second generator through a third solution heat exchanger. The generator's refrigerant vapor passage, which is connected to the condenser, is adjusted to be connected to the third generator first, and then the third generator has a refrigerant liquid pipeline connected to the condenser or the evaporator through the second throttle valve. The third generator also has a refrigerant vapor passage connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0015] 9. The catalyst regeneration energy recovery heat pump system is a system that, in any one of the catalyst regeneration energy recovery heat pump systems described in Item 7, adds a third generator, a second throttle valve, and a third solution heat exchanger. The adjustment is made such that the dilute solution pipeline of the second absorber is connected to the generator via the second solution pump and the second solution heat exchanger, which is adjusted to the dilute solution pipeline of the second absorber being connected to the generator via the second solution pump, the second solution heat exchanger, and the third solution heat exchanger. The concentrated solution pipeline of the generator is connected to the second generator via the second solution heat exchanger, which is adjusted to the concentrated solution pipeline of the generator being connected to the third generator via the third solution heat exchanger. The concentrated solution pipeline of the third generator is then connected to the second generator via the second solution heat exchanger. The refrigerant vapor channel of the generator is connected to the condenser, which is adjusted to the refrigerant vapor channel of the generator being connected to the third generator, and then the third generator has a refrigerant liquid pipeline that is connected to the condenser or the evaporator via the second throttle valve. The third generator also has a refrigerant vapor channel connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0016] 10. The catalyst regeneration energy recovery heat pump system is a system that, in any one of the catalyst regeneration energy recovery heat pump systems described in Item 7, adds a third generator, a second throttle valve, a third solution pump, and a third solution heat exchanger. The adjustment is made such that the dilute solution pipeline of the second absorber is connected to the generator via the second solution pump and the second solution heat exchanger, which is adjusted to the dilute solution pipeline of the second absorber being connected to the third generator via the second solution pump and the second solution heat exchanger. The third generator then has a concentrated solution pipeline that is connected to the generator via the third solution pump and the third solution heat exchanger. The concentrated solution pipeline of the generator is connected to the second generator via the second solution heat exchanger, which is adjusted to the concentrated solution pipeline of the generator being connected to the second generator via the third solution heat exchanger and the second solution heat exchanger. The refrigerant vapor channel of the generator is connected to the condenser, which is adjusted to the refrigerant vapor channel of the generator being connected to the third generator, and then the third generator has a refrigerant liquid pipeline that is connected to the condenser or the evaporator via the second throttle valve. The third generator also has a refrigerant vapor channel connected to the condenser, thus forming a catalyst regeneration energy recovery heat pump system.
[0017] 11. The catalyst regeneration energy recovery heat pump system is to add a second generator, a second solution pump, a second solution heat exchanger, and a second absorber to any one of the catalyst regeneration energy recovery heat pump systems described in Items 1-3. The flue gas passage of the coking-regeneration system is adjusted to be externally connected through a high-temperature heat exchanger, the second generator, the generator, and the heat source regenerator instead of being externally connected through a high-temperature heat exchanger, the generator, and the heat source regenerator. The refrigerant vapor passage of the generator is adjusted to be connected to the second absorber instead of being connected to the condenser. The second absorber also has a dilute solution pipeline connected to the second generator through the second solution pump and the second solution heat exchanger. The second generator also has a concentrated solution pipeline connected to the second absorber through the second solution heat exchanger. The second generator also has a refrigerant vapor passage connected to the condenser. The second absorber also has a heated medium passage externally connected, thus forming a catalyst regeneration energy recovery heat pump system.
[0018] 12. The catalyst regeneration energy recovery power device is to add an air compressor to any one of the catalyst regeneration energy recovery power devices described in Items 1-11. The external air passage is adjusted to be connected to the coking-regeneration system through the air compressor and the heat source regenerator instead of being connected to the coking-regeneration system through the heat source regenerator. A gas turbine is added, and the flue gas passage of the coking-regeneration system is adjusted to be externally connected to the high-temperature heat exchanger through the gas turbine instead of being externally connected to the high-temperature heat exchanger directly. The gas turbine is connected to the air compressor to transmit power, thus forming a catalyst regeneration energy recovery power device.
[0019] 13. The catalyst regeneration energy recovery power device is to add an auxiliary combustion chamber to any one of the catalyst regeneration energy recovery power devices described in Items 1-11. The external fuel passage is connected to the auxiliary combustion chamber. The flue gas passage of the coking-regeneration system is adjusted to be connected to the auxiliary combustion chamber instead of being externally connected to the high-temperature heat exchanger directly. The auxiliary combustion chamber then has a flue gas passage externally connected to the high-temperature heat exchanger, thus forming a catalyst regeneration energy recovery power device.
[0020] 14. The catalyst regeneration energy recovery power device is to add an air compressor to any one of the catalyst regeneration energy recovery power devices described in Item 13. The external air passage is adjusted to be connected to the coking-regeneration system through the air compressor and the heat source regenerator instead of being connected to the coking-regeneration system through the heat source regenerator. A gas turbine is added, and the flue gas passage of the auxiliary combustion chamber is adjusted to be connected to the high-temperature heat exchanger through the gas turbine instead of being externally connected to the high-temperature heat exchanger directly. The gas turbine is connected to the air compressor to transmit power, thus forming a catalyst regeneration energy recovery power device.
[0021] 15. The catalyst regeneration energy recovery heat pump system is to add a nozzle and replace the throttle valve, and add a dual-energy compressor and replace the compressor in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 3, 7, and 11 to form a catalyst regeneration energy recovery power device.
[0022] 16. The catalyst regeneration energy recovery heat pump system is to add a working machine in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 14. The expander is connected to the working machine and provides power to the working machine to form a catalyst regeneration energy recovery heat pump system with an additional externally provided power load.
[0023] 17. The catalyst regeneration energy recovery heat pump system is to add a power machine in any one of the catalyst regeneration energy recovery heat pump systems described in Items 1 - 14. The power machine is connected to the compressor and provides power to the compressor to form a catalyst regeneration energy recovery heat pump system driven by an additional external power. Description of the Drawings:
[0024] Figure 1 It is the first principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0025] Figure 2 It is the second principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0026] Figure 3 It is the third principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0027] Figure 4 It is the fourth principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0028] Figure 5 It is the fifth principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0029] Figure 6 It is the sixth principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0030] Figure 7 It is the seventh principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0031] Figure 8 It is the eighth principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0032] Figure 9It is the 9th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0033] Figure 10 It is the 10th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0034] Figure 11 It is the 11th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0035] Figure 12 It is the 12th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0036] Figure 13 It is the 13th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0037] Figure 14 It is the 14th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0038] Figure 15 It is the 15th principle thermodynamic system diagram of the catalyst regeneration energy recovery heat pump system provided by the present invention.
[0039] In the figure, 1 - coke burning - regeneration system, 2 - heat source recuperator, 3 - absorber, 4 - generator, 5 - condenser, 6 - evaporator, 7 - throttle valve, 8 - solution pump, 9 - heat source heat exchanger, 10 - high - temperature heat exchanger, 11 - compressor, 12 - expander, 13 - recuperator, 14 - second compressor, 15 - second recuperator, 16 - second generator, 17 - second throttle valve, 18 - second solution pump, 19 - second heat source heat exchanger, 20 - second absorber, 21 - third generator, 22 - third solution pump, 23 - third heat source heat exchanger, 24 - air compressor, 25 - expander for flue gas, 26 - auxiliary combustion chamber; A - nozzle, B - diffuser. Specific implementation manners:
[0040] First of all, it should be noted that in the description of the structure and process, without necessity, it will not be repeated, and the obvious processes will not be described. The present invention will be described in detail below with reference to the drawings and examples.
[0041] Figure 1 The shown catalyst regeneration energy recovery heat pump system is realized as follows:
[0042] (1) Structurally, it mainly consists of a charring-regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a recuperator; externally, there is an air passage communicating with the charring-regeneration system 1 through the heat source recuperator 2, and the charring-regeneration system 1 also has a flue gas passage communicating with the outside through the high-temperature heat exchanger 10, the generator 4 and the heat source recuperator 2; the absorber 3 has a dilute solution pipeline communicating with the generator 4 through the solution pump 8 and the solution heat exchanger 9, the generator 4 also has a concentrated solution pipeline communicating with the absorber 3 through the solution heat exchanger 9, the generator 4 also has a refrigerant vapor passage communicating with the condenser 5, the condenser 5 also has a refrigerant liquid pipeline communicating with the evaporator 6 through the throttle valve 7, the evaporator 6 also has a refrigerant vapor passage communicating with the compressor 11, the compressor 11 also has a refrigerant vapor passage communicating with the expander 12 through the recuperator 13 and the high-temperature heat exchanger 10, the expander 12 also has a refrigerant vapor passage communicating with itself through the recuperator 13, and the expander 12 also has a refrigerant vapor passage communicating with the absorber 3; the absorber 3 and the condenser 5 also respectively have a heated medium passage communicating with the outside, the evaporator 6 also has a low-temperature heat medium passage communicating with the outside, and the expander 12 is connected to the compressor 11 and transmits power.
[0043] (2) In terms of the process, the external air flows through the heat source regenerator 2 to absorb heat and increase in temperature, and then enters the coke burning-regeneration system 1 to participate in combustion; the air and the coke on the catalyst surface undergo a series of processes including combustion to realize catalyst regeneration and generate flue gas; the flue gas generated by the coke burning-regeneration system 1 and after separation and purification is supplied to the high-temperature heat exchanger 10, and the flue gas flows through the high-temperature heat exchanger 10, the generator 4 and the heat source regenerator 2 to gradually release heat and decrease in temperature, and then is discharged externally; the dilute solution in the absorber 3 enters the generator 4 through the solution pump 8 and the solution heat exchanger 9, the flue gas flows through the generator 4, heats the solution entering it to release refrigerant vapor and supplies it to the condenser 5, the concentrated solution in the generator 4 enters the absorber 3 through the solution heat exchanger 9, absorbs the refrigerant vapor and releases heat to the heated medium; the refrigerant vapor released by the generator 4 enters the condenser 5 to release heat and condense, the refrigerant liquid in the condenser 5 flows through the throttle valve 7 to throttle and enters the evaporator 6, absorbs heat to become refrigerant vapor and supplies it to the compressor 11; the refrigerant vapor flows through the compressor 11 to increase in pressure and temperature, flows through the regenerator 13 and the high-temperature heat exchanger 10 to gradually absorb heat and increase in temperature, and then is supplied to the expander 12; the refrigerant vapor enters the expander 12 to decrease in pressure and do work, after reaching a certain level, it flows through the regenerator 13 to release heat and decrease in temperature, enters the expander 12 to continue to decrease in pressure and do work, and then is supplied to the absorber 3; the flue gas discharged from the coke burning-regeneration system 1 provides the driving heat load, the air and the flue gas take away the low-temperature discharge heat load through the inlet and outlet processes, the low-temperature heat medium provides the low-temperature heat load through the evaporator 6, and the heated medium obtains the medium-temperature heat load through the absorber 3 and the condenser 5; the work output by the expander 12 is supplied to the compressor 11 as power, or the work output by the expander 12 is supplied to the compressor 11 and the external as power, forming a catalyst regeneration energy recovery heat pump system.
[0044] Figure 2 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0045] (1) Structurally, it mainly consists of a charring-regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a recuperator; externally, there is an air passage connected to the charring-regeneration system 1 through the heat source recuperator 2, and the charring-regeneration system 1 also has a flue gas passage connected to the outside through the high-temperature heat exchanger 10, the generator 4 and the heat source recuperator 2; the absorber 3 has a dilute solution pipeline connected to the generator 4 through the solution pump 8 and the solution heat exchanger 9, the generator 4 also has a concentrated solution pipeline connected to the absorber 3 through the solution heat exchanger 9, the generator 4 also has a refrigerant vapor passage connected to the condenser 5, the condenser 5 also has a refrigerant liquid pipeline connected to the evaporator 6 through the throttle valve 7, the evaporator 6 also has a refrigerant vapor passage connected to the compressor 11, the compressor 11 also has a refrigerant vapor passage connected to itself through the recuperator 13, the compressor 11 also has a refrigerant vapor passage connected to the expander 12 through the high-temperature heat exchanger 10, and the expander 12 also has a refrigerant vapor passage connected to the absorber 3 through the recuperator 13; the absorber 3 and the condenser 5 also respectively have a heated medium passage connected to the outside, the evaporator 6 also has a low-temperature heat medium passage connected to the outside, and the expander 12 is connected to the compressor 11 to transmit power.
[0046] (2) In terms of the process, compared with the Figure 1 catalyst regeneration energy recovery heat pump system shown, the difference lies in that the refrigerant vapor enters the compressor 11 to increase in pressure and temperature. After reaching a certain level, it flows through the recuperator 13 to absorb heat and increase in temperature, enters the compressor 11 to continue increasing in pressure and temperature, flows through the high-temperature heat exchanger 10 to absorb heat and increase in temperature, flows through the expander 12 to reduce pressure and do work, flows through the recuperator 13 to release heat and reduce in temperature, and then is supplied to the absorber 3, forming a catalyst regeneration energy recovery heat pump system.
[0047] Figure 3 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0048] (1) Structurally, it mainly consists of a charring-regeneration system, a heat source recuperator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander, a recuperator, a second compressor, and a second recuperator; externally, there is an air passage connected to the charring-regeneration system 1 through the heat source recuperator 2, and the charring-regeneration system 1 also has a flue gas passage connected to the outside through the high-temperature heat exchanger 10, the generator 4, and the heat source recuperator 2; the absorber 3 has a dilute solution pipeline connected to the generator 4 through the solution pump 8 and the solution heat exchanger 9, the generator 4 also has a concentrated solution pipeline connected to the absorber 3 through the solution heat exchanger 9, the generator 4 also has a refrigerant vapor passage connected to the condenser 5, the condenser 5 also has a refrigerant liquid pipeline connected to the evaporator 6 through the throttle valve 7, the evaporator 6 also has a refrigerant vapor passage connected to the compressor 11, the compressor 11 also has a refrigerant vapor passage connected to itself through the recuperator 13, the compressor 11 also has a refrigerant vapor passage connected to the high-temperature heat exchanger 10 through the second recuperator 15, the second compressor 14 has a refrigerant vapor passage connected to the high-temperature heat exchanger 10, the high-temperature heat exchanger 10 also has a refrigerant vapor passage connected to the expander 12, the expander 12 also has a steam extraction passage connected to the second compressor 14 through the second recuperator 15, and the expander 12 also has a refrigerant vapor passage connected to the absorber 3 through the recuperator 13; the absorber 3 and the condenser 5 also respectively have heated medium passages connected to the outside, the evaporator 6 also has a low-temperature heat medium passage connected to the outside, and the expander 12 is connected to the compressor 11 and the second compressor 14 to transmit power.
[0049] (2) In terms of the process, compared with the Figure 1 catalyst regeneration energy recovery heat pump system shown, the difference lies in that the refrigerant vapor enters the compressor 11 to increase in pressure and temperature. After reaching a certain level, it flows through the recuperator 13 to absorb heat and increase in temperature, enters the compressor 11 to continue increasing in pressure and temperature, flows through the second recuperator 15 to absorb heat and increase in temperature, and then enters the high-temperature heat exchanger 10 to absorb heat and increase in temperature. The refrigerant vapor discharged from the second compressor 14 enters the high-temperature heat exchanger 10 to absorb heat and increase in temperature; the refrigerant vapor discharged from the high-temperature heat exchanger 10 enters the expander 12 to reduce in pressure and do work. After reaching a certain level, it is divided into two paths - the first path flows through the second recuperator 15 to release heat and reduce in temperature and then enters the second compressor 14 to increase in pressure and temperature, and the second path continues to reduce in pressure and do work, flows through the recuperator 13 to release heat and reduce in temperature, and then is supplied to the absorber 3; the work output by the expander 12 is provided as power for the compressor 11 and the second compressor 14, forming a catalyst regeneration energy recovery heat pump system.
[0050] Figure 4 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0051] (1) Structurally, in Figure 1In the catalyst regeneration energy recovery heat pump system shown, a second generator, a second throttle valve, a second solution pump, and a second solution heat exchanger are added. A dilute solution pipeline is added to the absorber 3 and is connected to the second generator 16 through the second solution pump 18 and the second solution heat exchanger 19. The second generator 16 also has a concentrated solution pipeline connected to the absorber 3 through the second solution heat exchanger 19. The refrigerant vapor channel of the generator 4 being connected to the condenser 5 is adjusted to the refrigerant vapor channel of the generator 4 being connected to the second generator 16 first, and then the second generator 16 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The second generator 16 also has a refrigerant vapor channel connected to the condenser 5.
[0052] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The refrigerant vapor generated by the generator 4 is provided to the second generator 16 as the driving heat medium. Part of the dilute solution in the absorber 3 enters the second generator 16 through the second solution pump 18 and the second solution heat exchanger 19. The refrigerant vapor flows through the second generator 16, heats the solution entering it, releases refrigerant vapor, and supplies it to the condenser 5. The concentrated solution of the second generator 16 enters the absorber 3 through the second solution heat exchanger 19. After the refrigerant vapor flowing through the second generator 16 releases heat and becomes refrigerant liquid, it is throttled through the second throttle valve 17 and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0053] Figure 5 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0054] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, a second generator, a second throttle valve, and a second solution heat exchanger are added. The dilute solution pipeline of the absorber 3 being connected to the generator 4 through the solution pump 8 and the solution heat exchanger 9 is adjusted to the dilute solution pipeline of the absorber 3 being connected to the generator 4 through the solution pump 8, the solution heat exchanger 9, and the second solution heat exchanger 19. The concentrated solution pipeline of the generator 4 being connected to the absorber 3 through the solution heat exchanger 9 is adjusted to the concentrated solution pipeline of the generator 4 being connected to the second generator 16 through the second solution heat exchanger 19, and then the second generator 16 has a concentrated solution pipeline connected to the absorber 3 through the solution heat exchanger 9. The refrigerant vapor channel of the generator 4 being connected to the condenser 5 is adjusted to the refrigerant vapor channel of the generator 4 being connected to the second generator 16 first, and then the second generator 16 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The second generator 16 also has a refrigerant vapor channel connected to the condenser 5.
[0055] (2) In terms of the process, compared with Figure 1Compared with the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The refrigerant vapor generated by the generator 4 is provided to the second generator 16 as the driving heat medium. The weak solution in the absorber 3 enters the generator 4 through the solution pump 8, the solution heat exchanger 9, and the second solution heat exchanger 19. The concentrated solution in the generator 4 enters the second generator 16 through the second solution heat exchanger 19. The refrigerant vapor flows through the second generator 16, heats the solution entering it, releases refrigerant vapor, and supplies it to the condenser 5. The concentrated solution in the second generator 16 enters the absorber 3 through the solution heat exchanger 9. The refrigerant vapor flowing through the second generator 16 releases heat to become refrigerant liquid and then throttles through the second throttle valve 17 and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0056] Figure 6 The catalyst regeneration energy recovery heat pump system shown is achieved as follows:
[0057] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, a second generator, a second throttle valve, a second solution pump, and a second solution heat exchanger are added. The connection of the weak solution pipeline in the absorber 3 to the generator 4 through the solution pump 8 and the solution heat exchanger 9 is adjusted to the connection of the weak solution pipeline in the absorber 3 to the second generator 16 through the solution pump 8 and the solution heat exchanger 9. Then, the second generator 16 has a concentrated solution pipeline connected to the generator 4 through the second solution pump 18 and the second solution heat exchanger 19. The connection of the concentrated solution pipeline in the generator 4 to the absorber 3 through the solution heat exchanger 9 is adjusted to the connection of the concentrated solution pipeline in the generator 4 to the absorber 3 through the second solution heat exchanger 19 and the solution heat exchanger 9. The connection of the refrigerant vapor channel in the generator 4 to the condenser 5 is adjusted to the connection of the refrigerant vapor channel in the generator 4 to the second generator 16, and then the second generator 16 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The second generator 16 also has a refrigerant vapor channel connected to the condenser 5.
[0058] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The refrigerant vapor generated by the generator 4 is provided to the second generator 16 as the driving heat medium. The weak solution in the absorber 3 enters the second generator 16 through the solution pump 8 and the solution heat exchanger 9. The refrigerant vapor flows through the second generator 16, heats the solution entering it, releases refrigerant vapor, and supplies it to the condenser 5. The concentrated solution in the second generator 16 enters the generator 4 through the second solution pump 18 and the second solution heat exchanger 19. The concentrated solution in the generator 4 enters the absorber 3 through the second solution heat exchanger 19 and the solution heat exchanger 9. The refrigerant vapor flowing through the second generator 16 releases heat to become refrigerant liquid and then throttles through the second throttle valve 17 to reduce pressure and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0059] Figure 7 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0060] (1) In terms of structure, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, a second generator, a second solution pump, a second solution heat exchanger and a second absorber are added. The flue gas passage of the coke burning-regeneration system 1 is adjusted to be connected to the outside through the high-temperature heat exchanger 10, the generator 4, the second generator 16 and the heat source regenerator 2 instead of being connected to the outside through the high-temperature heat exchanger 10, the generator 4 and the heat source regenerator 2. The dilute solution pipeline of the absorber 3 is adjusted to be connected to the second absorber 20 through the solution pump 8 and the solution heat exchanger 9 instead of being connected to the generator 4. The dilute solution pipeline of the second absorber 20 is then connected to the generator 4 through the second solution pump 18 and the second solution heat exchanger 19. The concentrated solution pipeline of the generator 4 is adjusted to be connected to the second generator 16 through the second solution heat exchanger 19 instead of being connected to the absorber 3. The concentrated solution pipeline of the second generator 16 is then connected to the absorber 3 through the solution heat exchanger 9. The second generator 16 also has a refrigerant vapor passage connected to the second absorber 20, and the second absorber 20 also has a heated medium passage connected to the outside.
[0061] (2) In terms of process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The flue gas discharged from the coke burning-regeneration system flows through the high-temperature heat exchanger 10, the generator 4, the second generator 16 and the heat source regenerator 2, gradually releasing heat and cooling down, and then being discharged to the outside. The dilute solution of the absorber 3 enters the second absorber 20 through the solution pump 8 and the solution heat exchanger 9, absorbs the refrigerant vapor and releases heat to the heated medium. The dilute solution of the second absorber 20 enters the generator 4 through the second solution pump 18 and the second solution heat exchanger 19. The concentrated solution of the generator 4 enters the second generator 16 through the second solution heat exchanger 19. The flue gas flows through the second generator 16, heats the solution entering it to release refrigerant vapor and supplies it to the second absorber 20. The concentrated solution of the second generator 16 enters the absorber 3 through the solution heat exchanger 9, forming a catalyst regeneration energy recovery heat pump system.
[0062] Figure 8 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0063] (1) In terms of structure, in Figure 7In the catalyst regeneration energy recovery heat pump system shown, a third generator, a second throttle valve, a third solution pump, and a third solution heat exchanger are added. A dilute solution pipeline is added to the second absorber 20 and is connected to the third generator 21 through the third solution pump 22 and the third solution heat exchanger 23. The third generator 21 also has a concentrated solution pipeline connected to the second generator 16 through the third solution heat exchanger 23. The refrigerant vapor channel of the generator 4 is connected to the condenser 5 is adjusted to that the refrigerant vapor channel of the generator 4 is connected to the third generator 21 first, and then the third generator 21 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The third generator 21 also has a refrigerant vapor channel connected to the condenser 5.
[0064] (2) In terms of the process, compared with Figure 7 the catalyst regeneration energy recovery heat pump system shown, the difference is that the refrigerant vapor generated by the generator 4 is provided to the second generator 21 as the driving heat medium. Part of the dilute solution of the second absorber 20 enters the second generator 21 through the second solution pump 22 and the third solution heat exchanger 23. The refrigerant vapor flows through the second generator 21, heats the solution entering it, releases refrigerant vapor, and provides it to the condenser 5. The concentrated solution of the second generator 21 enters the second generator 16 through the second solution heat exchanger 22. After the refrigerant vapor flowing through the second generator 21 releases heat and becomes refrigerant liquid, it is throttled through the second throttle valve 17 and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0065] Figure 9 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0066] (1) In terms of the structure, in Figure 7 the catalyst regeneration energy recovery heat pump system shown, a third generator, a second throttle valve, and a third solution heat exchanger are added. The connection that the second absorber 20 has a dilute solution pipeline connected to the generator 4 through the second solution pump 18 and the second solution heat exchanger 19 is adjusted to that the second absorber 20 has a dilute solution pipeline connected to the generator 4 through the second solution pump 18, the second solution heat exchanger 19, and the third solution heat exchanger 23. The connection that the generator 4 has a concentrated solution pipeline connected to the second generator 16 through the second solution heat exchanger 19 is adjusted to that the generator 4 has a concentrated solution pipeline connected to the third generator 21 through the third solution heat exchanger 23. The third generator 21 then has a concentrated solution pipeline connected to the second generator 16 through the second solution heat exchanger 19. The connection that the generator 4 has a refrigerant vapor channel connected to the condenser 5 is adjusted to that the refrigerant vapor channel of the generator 4 is connected to the third generator 21 first, and then the third generator 21 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The third generator 21 also has a refrigerant vapor channel connected to the condenser 5.
[0067] (2) In terms of the process, compared with Figure 7Compared with the shown catalyst regeneration energy recovery heat pump system, the differences are as follows: The refrigerant vapor generated by the generator 4 is provided to the second generator 21 as the driving heat medium. The dilute solution of the second absorber 20 enters the generator 4 through the second solution pump 18, the second solution heat exchanger 19 and the third solution heat exchanger 23. The concentrated solution of the generator 4 enters the second generator 21 through the second solution heat exchanger 22. The refrigerant vapor flow passes through the second generator 21, heats the solution entering it to release refrigerant vapor and supplies it to the condenser 5. The concentrated solution of the second generator 21 enters the second generator 16 through the second solution heat exchanger 19. After the refrigerant vapor flowing through the second generator 21 releases heat to become refrigerant liquid, it is throttled by the second throttle valve 17 and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0068] Figure 10 The shown catalyst regeneration energy recovery heat pump system is realized as follows:
[0069] (1) Structurally, in Figure 7 the shown catalyst regeneration energy recovery heat pump system, a third generator, a second throttle valve, a third solution pump and a third solution heat exchanger are added. The dilute solution pipeline of the second absorber 20 is adjusted to be connected to the generator 4 through the second solution pump 18 and the second solution heat exchanger 19, and is adjusted to be connected to the third generator 21 through the second solution pump 18 and the second solution heat exchanger 19. The concentrated solution pipeline of the third generator 21 is then connected to the generator 4 through the third solution pump 22 and the third solution heat exchanger 23. The concentrated solution pipeline of the generator 4 is adjusted to be connected to the second generator 16 through the third solution heat exchanger 23 and the second solution heat exchanger 19. The refrigerant vapor channel of the generator 4 is adjusted to be connected to the third generator 21, and then the third generator 21 has a refrigerant liquid pipeline connected to the condenser 5 through the second throttle valve 17. The third generator 21 also has a refrigerant vapor channel connected to the condenser 5.
[0070] (2) In terms of the process, compared with Figure 7Compared with the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The refrigerant vapor generated by the generator 4 is supplied to the second generator 21 as the driving heat medium. The dilute solution of the second absorber 20 enters the second generator 21 through the second solution pump 18 and the second solution heat exchanger 19. The refrigerant vapor flows through the second generator 21, heats the solution entering it, releases refrigerant vapor and supplies it to the condenser 5. The concentrated solution of the second generator 21 enters the generator 4 through the second solution pump 22 and the third solution heat exchanger 23. The concentrated solution of the generator 4 enters the second generator 16 through the third solution heat exchanger 23 and the second solution heat exchanger 19. The refrigerant vapor flowing through the second generator 21 releases heat to become refrigerant liquid and then throttles through the second throttle valve 17 and enters the condenser 5, forming a catalyst regeneration energy recovery heat pump system.
[0071] Figure 11 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0072] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, a second generator, a second solution pump, a second solution heat exchanger and a second absorber are added. The flue gas passage of the coking-regeneration system 1 is adjusted to be connected to the outside through the high-temperature heat exchanger 10, the second generator 16, the generator 4 and the heat source regenerator 2 instead of being connected to the outside through the high-temperature heat exchanger 10, the generator 4 and the heat source regenerator 2. The connection of the refrigerant vapor passage of the generator 4 to the condenser 5 is adjusted to the connection of the refrigerant vapor passage of the generator 4 to the second absorber 20. The second absorber 20 also has a dilute solution pipeline connected to the second generator 16 through the second solution pump 18 and the second solution heat exchanger 19. The second generator 16 also has a concentrated solution pipeline connected to the second absorber 20 through the second solution heat exchanger 19. The second generator 16 also has a refrigerant vapor passage connected to the condenser 5. The second absorber 20 also has a heated medium passage connected to the outside.
[0073] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the differences are as follows: The flue gas discharged from the coking-regeneration system flows through the high-temperature heat exchanger 10, the second generator 16, the generator 4 and the heat source regenerator 2, gradually releases heat and cools down, and then is discharged to the outside. The refrigerant vapor generated by the generator 4 enters the second absorber 20. The dilute solution of the second absorber 20 enters the second generator 16 through the second solution pump 18 and the second solution heat exchanger 19. The flue gas flows through the second generator 16, heats the solution entering it, releases refrigerant vapor and supplies it to the condenser 5. The concentrated solution of the second generator 16 enters the second absorber 20 through the second solution heat exchanger 19, absorbs the refrigerant vapor and releases heat to the heated medium, forming a catalyst regeneration energy recovery heat pump system.
[0074] Figure 12 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0075] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, an air compressor 24 is added, and the external air passage is adjusted to be connected to the charring-regeneration system 1 through the air compressor 24 and the heat source recuperator 2 instead of being directly connected through the heat source recuperator 2. A gas turbine 25 is added, and the flue gas passage of the charring-regeneration system 1 is adjusted to be connected to the outside of the high-temperature heat exchanger 10 through the gas turbine 25 instead of being directly connected to the outside of the high-temperature heat exchanger 10. The gas turbine 25 is connected to the air compressor 24 and transmits power.
[0076] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the difference is that the external air flows through the air compressor 24 to increase the pressure and temperature, then flows through the heat source recuperator 2 to absorb heat and increase the temperature, and then is supplied to the charring-regeneration system 1; the flue gas discharged from the charring-regeneration system flows through the gas turbine 25 to reduce the pressure and do work, and then is supplied to the high-temperature heat exchanger 10; the gas turbine 25 provides power to the air compressor 24, forming a catalyst regeneration energy recovery heat pump system.
[0077] Figure 13 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0078] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, an auxiliary combustion chamber 26 is added, and an external fuel passage is connected to the auxiliary combustion chamber 26. The flue gas passage of the charring-regeneration system 1 is adjusted to be connected to the auxiliary combustion chamber 26 instead of being directly connected to the outside of the high-temperature heat exchanger 10, and the auxiliary combustion chamber 26 has a flue gas passage connected to the outside of the high-temperature heat exchanger 10.
[0079] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the difference is that the external fuel enters the auxiliary combustion chamber 26, the flue gas discharged from the charring-regeneration system 1 enters the auxiliary combustion chamber 26, and the fuel and the flue gas burn in the auxiliary combustion chamber 26 to form flue gas at a higher temperature, and then it is supplied to the high-temperature heat exchanger 10, forming a catalyst regeneration energy recovery heat pump system.
[0080] Figure 14 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0081] (1) Structurally, in Figure 13In the catalyst regeneration energy recovery heat pump system shown, an air compressor 24 is added, and the connection that the external air passage communicates with the charring and regeneration system 1 through the heat source regenerator 2 is adjusted to that the external air passage communicates with the charring and regeneration system 1 through the air compressor 24 and the heat source regenerator 2. A gas turbine 25 is added, and the connection that the flue gas passage of the auxiliary combustion chamber 26 communicates with the outside of the high-temperature heat exchanger 10 is adjusted to that the flue gas passage of the auxiliary combustion chamber 26 communicates with the high-temperature heat exchanger 10 through the gas turbine 25; the gas turbine 25 is connected to the air compressor 24 and transmits power.
[0082] (2) In terms of the process, compared with Figure 13 the catalyst regeneration energy recovery heat pump system shown, the difference is that: the external air flows through the air compressor 24 to increase the pressure and temperature, flows through the heat source regenerator 2 to absorb heat and increase the temperature, and then is supplied to the charring and regeneration system 1; the flue gas discharged from the auxiliary combustion chamber 26 flows through the gas turbine 25 to reduce the pressure and do work, and then is supplied to the high-temperature heat exchanger 10; the gas turbine 25 provides power to the air compressor 24, forming a catalyst regeneration energy recovery heat pump system.
[0083] Figure 15 The catalyst regeneration energy recovery heat pump system shown is realized as follows:
[0084] (1) Structurally, in Figure 1 the catalyst regeneration energy recovery heat pump system shown, a nozzle A is added and replaces the throttle valve 7, and a dual-energy compressor B is added and replaces the compressor 11.
[0085] (2) In terms of the process, compared with Figure 1 the catalyst regeneration energy recovery heat pump system shown, the difference is that: the condensate discharged from the condenser 5 flows through the nozzle A to reduce the pressure and increase the speed, flows through the evaporator 6 to absorb heat and evaporate, flows through the dual-energy compressor B to reduce the speed, increase the pressure and increase the temperature, and then is supplied to the high-temperature heat exchanger 10, forming a catalyst regeneration energy recovery heat pump system.
[0086] The effects that can be achieved by the technology of the present invention - the catalyst regeneration energy recovery heat pump system proposed by the present invention has the following effects and advantages:
[0087] (1) Reduce the irreversible loss of temperature difference in the catalyst regeneration process and increase the temperature of the initial driving heat source.
[0088] (2) Increase the average temperature of the driving heat load of the heat pump system, thereby increasing the heat supply parameter / performance index of the heat pump system by increasing the heat absorption temperature.
[0089] (3) Adopt simple technical measures to achieve efficient / high-value utilization of flue gas energy, reduce costs and improve economic efficiency.
[0090] (4) The heat regeneration measure raises the average temperature of the heat absorption process of the heat pump system, with small systematic temperature difference loss, and improves the heating parameter / performance index of the heat pump system.
[0091] (5) There is good adaptability between the boosting range of the refrigerant vapor and the flue gas parameters.
[0092] (6) Providing multiple technical solutions is beneficial to expanding the application scope and value of the catalyst regeneration energy recovery heat pump system for refrigeration / heating.
Claims
1. A catalyst regeneration energy recovery heat pump system, mainly composed of a char-regeneration system, a heat source regenerator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a regenerator; an air channel is connected to the char-regeneration system (1) through the heat source regenerator (2); the char-regeneration system (1) also has a flue gas channel connected to the outside through the high-temperature heat exchanger (10), the generator (4) and the heat source regenerator (2); the absorber (3) has a dilute solution pipeline connected to the generator (4) through the solution pump (8) and the solution heat exchanger (9); the generator (4) also has a concentrated solution pipeline connected to the absorber (3) through the solution heat exchanger (9); the generator (4) also has a refrigerant steam channel connected to the refrigerant The condenser (5) is connected to the evaporator (6), the condenser (5) also has a refrigerant liquid pipeline connected to the evaporator (6) through a throttle valve (7), the evaporator (6) also has a refrigerant vapor channel connected to the compressor (11), the compressor (11) also has a refrigerant vapor channel connected to the expander (12) through the regenerator (13) and the high-temperature heat exchanger (10), the expander (12) also has a refrigerant vapor channel connected to itself through the regenerator (13), and the expander (12) also has a refrigerant vapor channel connected to the absorber (3); the absorber (3) and the condenser (5) also have heated medium channels connected to the outside, the evaporator (6) also has a low-temperature heat medium channel connected to the outside, the expander (12) is connected to the compressor (11) and transmits power, forming a catalyst regeneration energy recovery heat pump system; wherein, Or add a turbine and replace the throttle valve.
2. A catalyst regeneration energy recovery heat pump system, mainly composed of a char-regeneration system, a heat source regenerator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander and a regenerator; an air channel is connected to the char-regeneration system (1) through the heat source regenerator (2); the char-regeneration system (1) also has a flue gas channel connected to the outside through the high-temperature heat exchanger (10), the generator (4) and the heat source regenerator (2); the absorber (3) has a dilute solution pipeline connected to the generator (4) through the solution pump (8) and the solution heat exchanger (9); the generator (4) also has a concentrated solution pipeline connected to the absorber (3) through the solution heat exchanger (9); the generator (4) also has a refrigerant steam channel connected to the refrigerant The condenser (5) is connected to the evaporator (6), the condenser (5) also has a refrigerant liquid pipeline connected to the evaporator (6) through a throttle valve (7), the evaporator (6) also has a refrigerant steam channel connected to the compressor (11), the compressor (11) also has a refrigerant steam channel connected to itself through a regenerator (13), the compressor (11) also has a refrigerant steam channel connected to the expander (12) through a high-temperature heat exchanger (10), and the expander (12) also has a refrigerant steam channel connected to the absorber (3) through the regenerator (13); the absorber (3) and the condenser (5) also have heated medium channels connected to the outside, the evaporator (6) also has a low-temperature heat medium channel connected to the outside, the expander (12) is connected to the compressor (11) and transmits power, forming a catalyst regeneration energy recovery heat pump system; wherein, Or add a turbine and replace the throttle valve.
3. A catalyst regeneration energy recovery heat pump system, mainly composed of a char-regeneration system, a heat source regenerator, an absorber, a generator, a condenser, an evaporator, a throttle valve, a solution pump, a solution heat exchanger, a high-temperature heat exchanger, a compressor, an expander, a regenerator, a second compressor and a second regenerator; an air channel is connected to the char-regeneration system (1) via the heat source regenerator (2), and the char-regeneration system (1) also has a flue gas channel connected to the outside via the high-temperature heat exchanger (10), the generator (4) and the heat source regenerator (2); the absorber (3) has a dilute solution pipeline connected to the generator (4) via the solution pump (8) and the solution heat exchanger (9), the generator (4) also has a concentrated solution pipeline connected to the absorber (3) via the solution heat exchanger (9), the generator (4) also has a refrigerant steam channel connected to the condenser (5), the condenser (5) also has a refrigerant liquid pipeline connected to the evaporator (6) via the throttle valve (7), and the evaporator (6) also has a refrigerant liquid pipeline connected to the condenser (5). The steam channel is connected to the compressor (11), and the compressor (11) also has a refrigerant steam channel connected to itself through the regenerator (13). The compressor (11) also has a refrigerant steam channel connected to the high-temperature heat exchanger (10) through the second regenerator (15). The second compressor (14) has a refrigerant steam channel connected to the high-temperature heat exchanger (10). The high-temperature heat exchanger (10) also has a refrigerant steam channel connected to the expander (12). The expander (12) also has a steam extraction channel connected to the second compressor (14) through the second regenerator (15). The expander (12) also has a refrigerant steam channel connected to the absorber (3) through the regenerator (13); the absorber (3) and the condenser (5) also have heated medium channels connected to the outside, and the evaporator (6) also has a low-temperature heat medium channel connected to the outside. The expander (12) is connected to the compressor (11) and the second compressor (14) and transmits power to form a catalyst regeneration energy recovery heat pump system; wherein, Or add a turbine and replace the throttle valve.
4. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claims 1-3, wherein a second generator, a second throttle valve, a second solution pump and a second solution heat exchanger are added, the absorber (3) is provided with a dilute solution pipeline connected to the second generator (16) via the second solution pump (18) and the second solution heat exchanger (19), the second generator (16) also has a concentrated solution pipeline connected to the absorber (3) via the second solution heat exchanger (19), the generator (4) having a refrigerant vapor channel connected to the condenser (5) is adjusted to the generator (4) having a refrigerant vapor channel connected to the second generator (16), and then the second generator (16) has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) via the second throttle valve (17), and the second generator (16) also has a refrigerant vapor channel connected to the condenser (5), to form a catalyst regeneration energy recovery heat pump system.
5. A catalyst regeneration energy recovery heat pump system, comprising: a catalyst regeneration energy recovery heat pump system according to any one of claims 1 to 3, wherein a second generator, a second throttle valve and a second solution heat exchanger are added, and the absorber (3) has a dilute solution pipeline connected to the generator (4) via a solution pump (8) and a solution heat exchanger (9) so that the absorber (3) has a dilute solution pipeline connected to the generator (4) via a solution pump (8), a solution heat exchanger (9) and a second solution heat exchanger (19), and the generator (4) has a concentrated solution pipeline connected to the absorber (3) via a solution heat exchanger (9) so that the generator (4) has a concentrated solution pipeline connected to the absorber (3) via a solution heat exchanger (9). The concentrated solution pipeline is connected to the second generator (16) via the second solution heat exchanger (19), and the second generator (16) further has a concentrated solution pipeline connected to the absorber (3) via the solution heat exchanger (9). The generator (4) has a refrigerant steam channel connected to the condenser (5), and the generator (4) has a refrigerant steam channel connected to the second generator (16). After that, the second generator (16) further has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) via the second throttle valve (17), and the second generator (16) also has a refrigerant steam channel connected to the condenser (5), forming a catalyst regeneration energy recovery heat pump system.
6. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claims 1 to 3, wherein a second generator, a second throttle valve, a second solution pump and a second solution heat exchanger are added, and the absorber (3) is adjusted from having a dilute solution pipeline connected to the generator (4) via the solution pump (8) and the solution heat exchanger (9) to having a dilute solution pipeline connected to the second generator (16) via the solution pump (8) and the solution heat exchanger (9), and the second generator (16) is further connected to the generator (4) via a concentrated solution pipeline connected to the generator (4) via the second solution pump (18) and the second solution heat exchanger (19), and the generator ( 4) The concentrated solution pipeline is connected to the absorber (3) through the solution heat exchanger (9), and the concentrated solution pipeline of the generator (4) is connected to the absorber (3) through the second solution heat exchanger (19) and the solution heat exchanger (9). The refrigerant vapor channel of the generator (4) is connected to the condenser (5), and the refrigerant vapor channel of the generator (4) is connected to the second generator (16). After that, the second generator (16) has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) through the second throttle valve (17). The second generator (16) also has a refrigerant vapor channel connected to the condenser (5), forming a catalyst regeneration energy recovery heat pump system.
7. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claims 1 to 3, wherein a second generator, a second solution pump, a second solution heat exchanger and a second absorber are added, and the flue gas channel of the charring-regeneration system (1) is connected to the outside through the high-temperature heat exchanger (10), the generator (4) and the heat source heat regenerator (2), and is adjusted to the flue gas channel of the charring-regeneration system (1) being connected to the outside through the high-temperature heat exchanger (10), the generator (4), the second generator (16) and the heat source heat regenerator (2); the dilute solution pipeline of the absorber (3) is connected to the generator (4) through the solution pump (8) and the solution heat exchanger (9), and is adjusted to the dilute solution pipeline of the absorber (3) being connected to the generator (4) through the solution pump (8) and the solution heat exchanger (9). The liquid heat exchanger (9) is connected to the second absorber (20), and the second absorber (20) is further connected to the generator (4) through a second solution pump (18) and a second solution heat exchanger (19). The generator (4) is connected to the absorber (3) through a concentrated solution pipeline through the solution heat exchanger (9), and the generator (4) is adjusted to be connected to the second generator (16) through a concentrated solution pipeline through the second solution heat exchanger (19). The second generator (16) is further connected to the absorber (3) through a concentrated solution pipeline through the solution heat exchanger (9). The second generator (16) is further connected to the absorber (3) through a refrigerant steam channel. The second absorber (20) is also connected to the outside through a heated medium channel, thereby forming a catalyst regeneration energy recovery heat pump system.
8. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claim 7, wherein a third generator, a second throttle valve, a third solution pump and a third solution heat exchanger are added, the second absorber (20) is provided with a dilute solution pipeline connected to the third generator (21) via the third solution pump (22) and the third solution heat exchanger (23), the third generator (21) also has a concentrated solution pipeline connected to the second generator (16) via the third solution heat exchanger (23), the generator (4) having a refrigerant steam channel connected to the condenser (5) is adjusted to the generator (4) having a refrigerant steam channel connected to the third generator (21), and then the third generator (21) has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) via the second throttle valve (17), and the third generator (21) also has a refrigerant steam channel connected to the condenser (5), to form a catalyst regeneration energy recovery heat pump system.
9. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claim 7, wherein a third generator, a second throttle valve and a third solution heat exchanger are added, and the second absorber (20) has a dilute solution pipeline connected to the generator (4) through the second solution pump (18) and the second solution heat exchanger (19) and is adjusted to the second absorber (20) having a dilute solution pipeline connected to the generator (4) through the second solution pump (18), the second solution heat exchanger (19) and the third solution heat exchanger (23), and the generator (4) having a concentrated solution pipeline connected to the second generator (16) through the second solution heat exchanger (19). The generator (4) has a concentrated solution pipeline connected to the third generator (21) via a third solution heat exchanger (23), and the third generator (21) further has a concentrated solution pipeline connected to the second generator (16) via a second solution heat exchanger (19). The generator (4) has a refrigerant steam channel connected to the condenser (5), which is adjusted so that the generator (4) has a refrigerant steam channel connected to the third generator (21), and then the third generator (21) has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) via a second throttle valve (17), and the third generator (21) also has a refrigerant steam channel connected to the condenser (5), thereby forming a catalyst regeneration energy recovery heat pump system.
10. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claim 7, wherein a third generator, a second throttle valve, a third solution pump and a third solution heat exchanger are added, and the second absorber (20) is connected with the generator (4) through the dilute solution pipeline via the second solution pump (18) and the second solution heat exchanger (19) so that the second absorber (20) is connected with the third generator (21) through the dilute solution pipeline via the second solution pump (18) and the second solution heat exchanger (19), and the third generator (21) is connected with the generator (4) through the concentrated solution pipeline via the third solution pump (22) and the third solution heat exchanger (23). The concentrated solution pipeline of the generator (4) is connected to the second generator (16) via the second solution heat exchanger (19), and is adjusted so that the concentrated solution pipeline of the generator (4) is connected to the second generator (16) via the third solution heat exchanger (23) and the second solution heat exchanger (19). The refrigerant steam channel of the generator (4) is connected to the condenser (5), and is adjusted so that the refrigerant steam channel of the generator (4) is connected to the third generator (21). After that, the third generator (21) further has a refrigerant liquid pipeline connected to the condenser (5) or the evaporator (6) via the second throttle valve (17). The third generator (21) also has a refrigerant steam channel connected to the condenser (5), thereby forming a catalyst regeneration energy recovery heat pump system.
11. A catalyst regeneration energy recovery heat pump system, which is any one of the catalyst regeneration energy recovery heat pump systems described in claims 1 to 3, by adding a second generator, a second solution pump, a second solution heat exchanger and a second absorber, and adjusting the charring-regeneration system (1) to have a flue gas channel connected to the outside through a high-temperature heat exchanger (10), a generator (4) and a heat source heat regenerator (2), so that the charring-regeneration system (1) has a flue gas channel connected to the outside through a high-temperature heat exchanger (10), a second generator (16), a generator (4) and a heat source heat regenerator (2); and adjusting the generator (4) to have a refrigerant steam channel connected to the outside through a high-temperature heat exchanger (10), a second generator (16), a generator (4) and a heat source heat regenerator (2); The generator (4) is connected to the second absorber (20) through a refrigerant steam channel, the second absorber (20) is connected to the second generator (16) through a second solution pump (18) and a second solution heat exchanger (19), the second generator (16) is connected to the second absorber (20) through a concentrated solution pipeline through a second solution heat exchanger (19), the second generator (16) is connected to the second absorber (20) through a refrigerant steam channel, the second generator (16) is connected to the condenser (5), and the second absorber (20) is connected to the outside through a heated medium channel, thereby forming a catalyst regeneration energy recovery heat pump system.
12. A catalyst regeneration energy recovery power device, which is any one of the catalyst regeneration energy recovery power devices described in claims 1-11, wherein an air compressor (24) is added, and the external air passage is adjusted to be connected with the charring-regeneration system (1) via the heat source heat regenerator (2) as the external air passage is connected with the charring-regeneration system (1) via the air compressor (24) and the heat source heat regenerator (2), and a smoke exhaust fan (25) is added, and the smoke exhaust fan (25) is adjusted to be connected with the high-temperature heat exchanger (10) via the smoke exhaust fan (25) as the smoke exhaust fan (25) is connected with the high-temperature heat exchanger (10) as the smoke exhaust fan (25) is connected to the air compressor (24) and transmits power to form a catalyst regeneration energy recovery power device.
13. A catalyst regeneration energy recovery power device is a catalyst regeneration energy recovery power device according to any one of claims 1 to 11, wherein an auxiliary combustion chamber (26) is added, and a fuel channel is externally connected to the auxiliary combustion chamber (26), and the burn-regeneration system (1) having a flue gas channel externally connected to the high-temperature heat exchanger (10) is adjusted to a burn-regeneration system (1) having a flue gas channel externally connected to the auxiliary combustion chamber (26), and the auxiliary combustion chamber (26) further having a flue gas channel externally connected to the high-temperature heat exchanger (10), thereby forming a catalyst regeneration energy recovery power device.
14. A catalyst regeneration energy recovery power device, which is any one of the catalyst regeneration energy recovery power devices described in claim 13, wherein an air compressor (24) is added, and the external air passage is adjusted to be connected with the charring-regeneration system (1) via the heat source heat regenerator (2) as the external air passage is connected with the charring-regeneration system (1) via the air compressor (24) and the heat source heat regenerator (2), and a smoke exhaust fan (25) is added, and the auxiliary combustion chamber (26) has a smoke passage connected to the outside of the high-temperature heat exchanger (10) as the auxiliary combustion chamber (26) has a smoke passage connected to the high-temperature heat exchanger (10) via the smoke exhaust fan (25); the smoke exhaust fan (25) is connected to the air compressor (24) and transmits power to form a catalyst regeneration energy recovery power device.
15. A catalyst regeneration energy recovery heat pump system is a catalyst regeneration energy recovery heat pump system according to any one of claims 1 to 3, 7, and 11, wherein a nozzle (A) is added to replace the throttle valve (7), and a dual-energy compressor (B) is added to replace the compressor (11), so as to form a catalyst regeneration energy recovery power device.
16. A catalyst regeneration energy recovery heat pump system is a catalyst regeneration energy recovery heat pump system according to any one of claims 1 to 14, wherein a working machine is added, and an expander (12) is connected to the working machine and provides power to the working machine, thereby forming a catalyst regeneration energy recovery heat pump system that additionally provides power load to the outside.
17. A catalyst regeneration energy recovery heat pump system is a catalyst regeneration energy recovery heat pump system according to any one of claims 1 to 14, wherein a power machine is added, the power machine is connected to a compressor (11) and provides power to the compressor (11), thereby forming a catalyst regeneration energy recovery heat pump system driven by an additional external power.