Two-phase makeup removing cosmetic composition

Abstract

The present invention relates to a cosmetic composition consisting of a separated aqueous phase and an oily phase wherein the oily phase comprises: 48% to 82% by weight, relative to the total weight of the oily phase, of isododecane; 10% to 22% by weight of isopropyl palmitate relative to the total weight of the oily phase; and, relative to the total weight of the oily phase, from 8% to 18% by weight of isopropyl myristate, the composition not comprising C15 to C19 alkanes. The invention also relates to specific ternary mixtures, as well as to related methods and cosmetic uses.

Description

Technical Field

[0001] The present invention relates to a biphasic composition consisting of a separated aqueous phase and an oily phase, the oily phase comprising a specific oil. The present invention also relates to the use of such a composition, and a method for removing makeup using such a composition. Background Art

[0002] Compositions consisting of two separated phases, in particular an aqueous phase and an oily phase that are separated and not emulsified with each other at rest, are generally referred to by the term "biphasic composition". They differ from emulsions in that, at rest, the two phases are separated and not emulsified with each other. The use of these biphasic compositions requires pre-stirring to form an emulsion; the latter needs to have sufficient quality and stability to allow the two phases to be uniformly applied to the skin or keratin material to which it is applied. At rest, the phases must quickly separate from each other and return to their initial state, a phenomenon that is generally referred to by the term "phase separation" or "stratification".

[0003] One of the desired qualities of a biphasic composition is the relatively rapid stratification of the two phases after use. In fact, for various reasons, it is desirable to achieve rapid phase separation, especially because poor separation of the two phases is considered inelegant by the user and may cause the product to become "triphasic" over time.

[0004] In addition, commercially available biphasic compositions are particularly used for removing makeup from the face, especially from the eyes, and contain cyclopentasiloxane.

[0005] However, the cosmetics market tends to focus on increasingly natural, including more environmentally friendly compounds and / or compositions derived from biomass. In particular, there is a need for compositions that do not contain cyclopentasiloxane. Summary of the Invention

[0006] Therefore, there is still a need for new stable biphasic compositions that consist of two separated and immiscible phases, do not contain cyclopentasiloxane, and have good stratification quality while ensuring effective makeup removal. There is also a need for natural compositions. A "natural composition" means a cosmetic composition formulated mainly with natural ingredients and / or ingredients of natural origin. A "natural ingredient" means a compound obtained directly from the land or soil or from a plant or animal (where applicable) by one or more physical processes such as, for example, grinding, refining, distillation, purification or filtration. An "ingredient of natural origin" means a natural compound that has undergone one or more chemical treatments or related industrial treatments that produce modifications that are harmless to the basic qualities of the compound, and / or a compound that mainly comprises natural ingredients and that may or may not have undergone the transformations described above.

[0007] The inventors surprisingly found that a ternary combination of isododecane, isopropyl palmitate and isopropyl myristate in specific proportions, in combination with water, enables the obtaining of a biphasic composition that meets these requirements. The composition according to the invention is stable, free of cyclopentasiloxane, and particularly has good layering quality and is very effective for makeup removal.

[0008] More specifically, the present invention relates to a cosmetic composition consisting of a separated aqueous phase and an oily phase, wherein the oily phase comprises:

[0009] - 48% to 82% by weight of isododecane, relative to the total weight of the oily phase;

[0010] - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase; and

[0011] - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase,

[0012] The composition does not contain C15-C19 alkanes.

[0013] Such a composition according to the invention is a biphasic composition.

[0014] The present invention also relates to a composition consisting of:

[0015] - 48% to 82% by weight of isododecane, relative to the total weight of the composition;

[0016] - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the composition; and

[0017] - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the composition,

[0018] The composition does not contain C15-C19 alkanes.

[0019] The composition is also referred to as a "ternary mixture" in the present application. The ternary mixture corresponds to the preferred oily phase of the biphasic composition according to the invention.

[0020] The present invention also relates to a method for removing makeup and / or cleaning and / or caring for keratinous materials, comprising applying the biphasic composition or ternary mixture according to the invention to the keratinous materials, particularly keratinous materials of the eye area, preferably the eyelashes.

[0021] The present invention also relates to the use of the biphasic composition or ternary mixture according to the invention for removing makeup and / or cleaning and / or caring for keratinous materials, particularly keratinous materials of the eye area, preferably the eyelashes.

[0022] "Keratin material" refers to the skin, mucous membranes and / or skin appendages. Preferably, the keratin material is skin (especially facial skin), mucous membranes (such as the lips), and / or skin appendages (such as eyelashes). Detailed Description

[0023] Oil phase

[0024] The oily phase of the biphasic composition according to the invention comprises:

[0025] - 48% to 82% by weight of isododecane, relative to the total weight of the oily phase;

[0026] - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase; and

[0027] - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase,

[0028] The composition does not contain C15-C19 alkanes.

[0029] The ternary mixture composition according to the invention consists of:

[0030] - 48% to 82% by weight of isododecane, relative to the total weight of the composition;

[0031] - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the composition; and

[0032] - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the composition,

[0033] The mixture does not contain C15-C19 alkanes.

[0034] The feature "the composition does not contain C15-C19 alkanes" or "the mixture does not contain C15-C19 alkanes" should be understood to mean that the biphasic composition or the ternary mixture respectively does not contain C15-C19 alkanes at all. These excluded C15-C19 alkanes are especially C15-C19 branched alkanes, such as those sold by Seppic under the name EMOGREEN L19.

[0035] Preferably, the biphasic composition and the ternary mixture according to the invention do not contain alkanes other than isododecane.

[0036] The biphasic compositions and ternary mixtures according to the invention comprise: 48% to 82% by weight of isododecane, relative to the total weight of the oily phase. Preferably, the biphasic compositions and ternary mixtures according to the invention comprise 50% to 75% by weight, preferably 55% to 70% by weight, preferably 57% to 68% by weight of isododecane, relative to the total weight of the oily phase.

[0037] The biphasic compositions and ternary mixtures according to the invention comprise: 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase. Preferably, the biphasic compositions and ternary mixtures according to the invention comprise 15% to 22% by weight, preferably 17% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase.

[0038] The biphasic compositions and ternary mixtures according to the invention comprise: 8% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase. Preferably, the biphasic compositions and ternary mixtures according to the invention comprise 10% to 18% by weight, preferably 15% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase.

[0039] Preferably, the biphasic compositions and ternary mixtures according to the invention are substantially free of cyclopentasiloxane. "Substantially free of cyclopentasiloxane" means that the composition comprises less than 1% by weight, preferably less than 0.5% by weight, preferably less than 0.1% by weight of cyclopentasiloxane, relative to the total weight of the composition. Preferably, the biphasic compositions and ternary mixtures according to the invention are completely free of cyclopentasiloxane.

[0040] Aqueous phase

[0041] The aqueous phase of the biphasic composition comprises water.

[0042] Optionally, the aqueous phase contains at least one organic solvent that is soluble or miscible in water at 25 °C.

[0043] Water-soluble or water-miscible solvents suitable for the present invention include: short-chain straight-chain or branched-chain alkanols, such as C2-C4 alkanols, such as ethanol, isopropanol, propanol or butanol; diols or polyols, especially having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms, such as glycerol, ethylene glycol, 1,2-propanediol, 1,3-butanediol, hexanediol, diethylene glycol, 1,3-propanediol, 1,2-pentanediol, dipropylene glycol, 2-ethoxyethanol, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, sorbitol, polyethylene glycol having 2 to 200 ethylene oxide units; and mixtures thereof.

[0044] Preferably, the aqueous phase comprises: water in an amount of at least 60% by weight, preferably at least 70% by weight, more preferably in the range of 80% to 98% by weight, based on the total weight of the aqueous phase.

[0045] The aqueous phase may further comprise conventional cosmetic additives such as electrolytes, chelating agents, preservatives and / or surfactants.

[0046] The electrolyte may be selected from sodium chloride or sodium sulfate. Preferably, the electrolyte is sodium chloride.

[0047] Preferably, the active substance content of the electrolyte is from 0.2% to 5% by weight, preferably from 0.5% to 4% by weight, more preferably from 1% to 3% by weight, based on the total weight of the composition.

[0048] In particular, the aqueous phase may comprise at least one surfactant selected from anionic surfactants, amphoteric surfactants and nonionic surfactants. Preferably, the aqueous phase comprises at least one nonionic surfactant, preferably selected from alkyl polyglucosides, esters of fatty acids having 6 to 12 carbon atoms, and esters of polyglycerol having 5 to 8 glycerol units, and mixtures thereof.

[0049] Preferably, the aqueous phase comprises: surfactant in an amount of from 0.015% to 7% by weight, preferably from 0.01% to 5% by weight, more preferably from 0.02% to 1% by weight, based on the total weight of the aqueous phase.

[0050] Alkyl polyglycosides (APG) belong to the alkyl polyglycoside family and generally conform to the following structure: R(O)(G)x x

[0051] wherein the group R is a C 12 -C 22 linear or branched alkyl group, G is a glucose residue, and x is from 1 to 5, preferably from 1.05 to 2.5, more preferably from 1.1 to 2.

[0052] According to the present invention, the term alkyl polyglycoside (APG) also encompasses polyalkyl(poly)glucosides. As alkyl- and polyalkyl-glucosides or polyglucosides, those preferably used comprise an alkyl group having 6 to 30 carbon atoms, preferably 6 to 18, even 8 to 16 carbon atoms, and a glucoside group comprising preferably from 1 to 5, especially 1, 2 to 3 glucoside units. For example, alkyl polyglucosides may be selected from, for example: decyl glucoside (alkyl-C9 / C 11 -polyglucoside (1.4)), such as the product sold by Kao Chemicals under the trade name Mydol or the product sold by Henkel under the trade name Plantacare 2000 The products sold and SEPPIC under the trade name ORAMIX NS The products sold; octyl / decyl glucoside, such as those sold by Cognis under the trade name Plantacare KE or those sold by SEPPIC under the trade name ORAMIX CG The products sold; lauryl glucoside, such as those sold by Henkel under the trade name Plantacare 1200 or those sold by Henkel under the trade name Plantaren The products sold; cocoyl glucoside, such as those sold by Henkel under the trade name Plantacare 818 The products sold; octyl glucoside, such as those sold by Cognis under the trade name Plantacare The products sold; and mixtures thereof. Preferably, the APG is decyl glucoside.

[0053] The esters of fatty acids and polyglycerols are formed from at least one fatty acid comprising 6 to 12 carbon atoms and a polyglycerol comprising 5 to 8 glycerol units.

[0054] The fatty acid can be saturated or unsaturated. Preferably, the ester of the fatty acid and polyglycerol is a monoester or diester, preferably a monoester.

[0055] The term "polyglycerol" refers to a glycerol polymer having a linear chain of 5 to 8 glycerol units.

[0056] More specifically contemplated esters according to the present invention are esters obtained by esterifying polyglycerol with one or more C8 carboxylic acids (such as octanoic acid). The carboxylic acid can be straight-chain or branched-chain, saturated or unsaturated. Preferably, the carboxylic acid is a straight-chain monocarboxylic acid.

[0057] According to a specific embodiment, the esters suitable for the present invention can be derived from polyglycerol esterified with one or several identical or different carboxylic acids. The ester can be a hydroxylated monoester, hydroxylated diester, hydroxylated triester or a mixture thereof.

[0058] In a preferred embodiment of the present invention, the ester is selected from esters of fatty acids containing 8 carbon atoms and esters of polyglycerol containing 6 glycerol units.

[0059] The esters of fatty acids containing 8 carbon atoms and esters of polyglycerol containing 6 glycerol units are formed from (i) at least one fatty acid comprising an alkyl or alkenyl chain containing 8 carbon atoms (also referred to as C8 fatty acid) and (ii) 6 glycerol units.

[0060] Preferably, the C8 fatty acid is saturated and contains a straight-chain alkyl chain. Preferably, the C8 fatty acid is octanoic acid.

[0061] In a preferred embodiment of the present invention, the ester of a fatty acid containing 8 carbon atoms and a polyglycerol containing 6 glycerol units is polyglycerol monocaprylate containing 6 glycerol units, namely polyglycerol-6 monocaprylate (polyglycerol-6 caprylate).

[0062] Biphasic composition

[0063] The biphasic composition according to the present invention consists of a separated aqueous phase and an oily phase.

[0064] Preferably, the weight ratio between the aqueous phase and the oily phase is from 1 to 6, preferably from 1.03 to 5.8, more preferably from 1.04 to 5.7.

[0065] These ratios make it possible to obtain a biphasic composition with excellent makeup removal performance and a satisfactory visual appearance.

[0066] The present invention also relates to the use of the biphasic composition or the ternary mixture as defined above for makeup removal and / or cleaning of keratin materials, preferably the skin and / or mucous membranes (such as the lips) and / or keratin fibers (such as the eyelashes).

[0067] The present invention also relates to a method for makeup removal and / or cleaning of keratin materials, preferably the skin and / or mucous membranes (such as the lips) and / or keratin fibers (such as the eyelashes), comprising applying the biphasic composition according to the present invention or the ternary mixture according to the present invention to the keratin materials.

[0068] Unless otherwise specified, the expressions "between... and...", "ranging from... to..." and "varying from... to..." should be understood to include the limiting values.

[0069] Specific but non-limiting examples of the present invention will now be provided.

[0070] Unless otherwise specified, the pressure in the examples is atmospheric pressure.

[0071] Example

[0072] Example 1: Preparation of a comparative composition and a composition according to the invention

[0073] 1. Experimental plan for 4 variables (i.e., oil content):

[0074] % by weight relative to the weight of the oily phase:

[0075] Isododecane (QS) - Isopropyl palmitate (0 to 30%) - Isopropyl myristate (0 to 30%) - C15-C19 alkanes (0 to 35%)

[0076] - Oil phase preparation

[0077] In a beaker, add 4 kinds of oils (with different contents), and homogenize them cold for 20 minutes.

[0078] The composition of the oily phase is shown in Tables 2 to 5 below. In Tables 2 to 5, the percentages are by weight relative to the total weight of the oily phase.

[0079] - Aqueous phase preparation

[0080] Aqueous phase composition

[0081] [Table 1]

[0082]

[0083] The aqueous phase was prepared as follows:

[0084] In a beaker, add the raw materials of Phase A and heat to 65 °C. After dispersing for 20 minutes, add Raw Material B (the water must be cold), and disperse for 10 minutes.

[0085] - Integration in the biphasic composition

[0086] Measure the density of the two phases.

[0087] To obtain a biphasic composition with a weight ratio of 85% aqueous phase / 15% oily phase, the following calculations were carried out:

[0088] [Mathematical formula 1]

[0089]

[0090] [Mathematical formula 2]

[0091]

[0092] Calculate the m of each phase 相 And pour the corresponding substances into the selected packaging.

[0093] The following various compositions were obtained by mixing the aqueous phase in Table 1 with the oily phase (Tables 2 to 5) detailed below.

[0094] a. Height of the oil phase (clear) in cm after 45 seconds of stirring

[0095] Protocol: Stir the biphasic composition 10 times by rotation, then start the timer. After 45 seconds, measure the height of the separated oily phase with a ruler.

[0096] Target: 0.5 cm high

[0097] b. Height of the oil phase (clear) in cm after 1 minute of stirring

[0098] Procedure: Rotate and stir the biphasic composition 10 times, then start the timer. After 1 minute, measure the height of the separated oily phase with a ruler.

[0099] Target: 1.2 cm in height

[0100] c. Presence of droplets on the wall of the oil phase after 4 days of stirring

[0101] Procedure: For 5 consecutive days, rotate and stir the biphasic composition 10 times each day. Let the biphasic composition stand for 24 hours, then repeat the operation the next day. On the 5th day, do not stir and evaluate the biphasic composition.

[0102] The presence of droplets on the wall of the oily phase can be detected and annotated as follows:

[0103] 0 = No droplets; 1 = Very fine / sparse droplets; 2 = Fine / few droplets; 3 = Medium / more droplets; 4: Large / many droplets

[0104] Target: 2 or less

[0105] d. Clarity of the interface after 4 days of stirring

[0106] Procedure: For 5 consecutive days, rotate and stir the biphasic composition 10 times each day. Let the biphasic composition stand for 24 hours, then repeat the operation the next day. On the 5th day, do not stir and evaluate the biphasic composition. The interface corresponds to the dividing line between the aqueous phase and the oily phase.

[0107] The instability is annotated as follows:

[0108] 1 = Very turbid interface / large droplets; 2 = Turbid interface / medium droplets; 3 = Well-defined interface - sparse droplets; 4 = Well-defined interface - some micro-droplets; 5 = Well-defined interface

[0109] Target: 3 or more

[0110] Effect of C15 - C19 alkane content

[0111] [Table 2]

[0112]

[0113] The stratification rate of the two phases is evaluated by measuring the height of the oily phase after stirring for 45 seconds. The target is set at 0.5 cm. When C15 - C19 alkanes are added to the composition (Comparative Example 1) or completely replace isododecane (Comparative Example 2), the target is not achieved.

[0114] Thus, the biphasic composition and the ternary mixture according to the invention must not contain any alkanes other than isododecane.

[0115] Effect of isopropyl myristate content

[0116] [Table 3]

[0117]

[0118]

[0119] Evaluate the height of the oily phase after stirring for 1 minute and the presence of droplets on the wall after 4 days of stirring.

[0120] When the isopropyl myristate content is strictly less than 8% or strictly greater than 18%, the target is not achieved.

[0121] Thus, isopropyl myristate must be present at 8 wt% to 18 wt% relative to the total weight of the oil phase.

[0122] Effect of isopropyl palmitate content

[0123] [Table 4]

[0124]

[0125] Evaluate the clarity of the interface after 4 days of stirring and the presence of droplets on the wall after 4 days of stirring. When the isopropyl palmitate content is less than 10%, the target for the presence of droplets is not achieved. When the content is greater than 22%, these two targets are not achieved.

[0126] Thus, isopropyl palmitate must be present at 10 wt% to 22 wt% relative to the total weight of the oil phase.

[0127] Effect of isododecane content

[0128] [Table 5]

[0129]

[0130]

[0131] Evaluate the height of the oily phase after stirring for 45 seconds and the presence of droplets on the wall after 4 days of stirring. When the isododecane content is less than 48%, the 2 targets are not achieved. When the content is greater than 82%, the target for the presence of droplets is not achieved.

[0132] Thus, isododecane must be present at 48 wt% to 82 wt% relative to the total weight of the oil phase.

[0133] Isopropyl palmitate is essential, especially to obtain a small amount of droplets after 4 days of stirring.

[0134] Isopropyl myristate is essential, especially to obtain good stratification.

[0135] 2. Effect of ratio

[0136] Test other ratios with the following compositions (same oily phase composition, see below):

[0137] ·A 70% aqueous phase / 30% oil phase ratio; and

[0138] ·A 56% aqueous phase / 44% oil phase ratio.

[0139] Composition of the aqueous phase

[0140] The composition of the aqueous phase is shown in Table 1.

[0141] Composition of the oil phase

[0142] [Table 6]

[0143] Phase Raw material Percentage A Isododecane 65％ A Isopropyl palmitate 15％ A Isopropyl myristate 17.7％ A Additive QS100

[0144] Testing different ratios

[0145] [Table 7]

[0146]

[0147] At the same phase composition but different ratios, the tests were stable relative to the target.

[0148] Example 2: Evaluation of a composition according to the invention and a comparative composition

[0149] On foundation and mascara, evaluate the makeup removal effect of different biphasic compositions (reference, Invention 1 or 1', and Invention 2 or 2'):

[0150] Foundation (FDT) application: 0.1 mL of Maybelline Fit Me Matte + Poreless Shade 220 per half face.

[0151] Mascara application: Apply 30 coats of intense black mascara on the upper lashes.

[0152] Wait 30 minutes before makeup removal:

[0153] For FDT: For each half face, use 5 cotton pads soaked in 2 mL of the biphasic composition. Remove the makeup on each part of the face. Wait 5 minutes, then apply 2 mL of Lancôme Bifacil on the cotton pads, up to 6 cotton pads.

[0154] Calculate the number of cotton pads soaked in Bifacil required to remove the residue.

[0155] For mascara: For each eye, use 3 cotton pads soaked in 2 mL of the biphasic composition. Remove the makeup on the eyes. Wait 5 minutes, then apply 2 mL of Bifacil on the cotton pads, up to 6 cotton pads.

[0156] Calculate the number of cotton pads soaked in Bifacil required to remove the residue.

[0157] 1 / Formulation tested (ratio 85:15):

[0158] Total phase composition + phase ratio

[0159] [Table 8]

[0160]

[0161]

[0162] Results:

[0163] In the control, for FDT it is 1 cotton pad for makeup removal, and for mascara it is 1.5 cotton pads for makeup removal. For the two biphasic compositions according to the present invention, for FDT it is 0 cotton pads for makeup removal, and for mascara it is 1 cotton pad for makeup removal.

[0164] The two biphasic compositions according to the present invention have better makeup removal effect than the control.

[0165] 2 / Formulation tested (ratio 70:30):

[0166] Total phase composition + phase ratio

[0167] [Table 9]

[0168]

[0169] Results:

[0170] In the control, for FDT it is 0 cotton pads for makeup removal, and for mascara it is 0.5 cotton pads for makeup removal. For the two biphasic compositions according to the present invention, for FDT it is 0 cotton pads for makeup removal, and for mascara it is 0 cotton pads for makeup removal.

[0171] The two biphasic compositions according to the present invention have better makeup removal effect than the control.

Claims

1. A cosmetic composition comprising a separate aqueous phase and an oily phase, characterized in that, The oily phase comprises: - 48% to 82% by weight of isododecane, relative to the total weight of the oily phase; - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase; and - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase, The composition does not contain C15-C19 alkanes.

2. A composition, comprising: - 48% to 82% by weight of isododecane, relative to the total weight of the composition; - 10% to 22% by weight of isopropyl palmitate, relative to the total weight of the composition; and - 8% to 18% by weight of isopropyl myristate, relative to the total weight of the composition, The composition does not contain C15-C19 alkanes.

3. The composition according to any one of the preceding claims, comprising: 50% to 75% by weight, preferably 55% to 70% by weight, preferably 57% to 68% by weight of isododecane, relative to the total weight of the oily phase.

4. The composition according to any one of the preceding claims, comprising: 15% to 22% by weight, preferably 17% to 22% by weight of isopropyl palmitate, relative to the total weight of the oily phase.

5. The composition according to any one of the preceding claims, comprising: 10% to 18% by weight, preferably 15% to 18% by weight of isopropyl myristate, relative to the total weight of the oily phase.

6. The composition according to any one of the preceding claims, substantially free of cyclopentasiloxane, preferably completely free of cyclopentasiloxane.

7. The composition according to any one of claims 1 or 3 to 6, wherein, The aqueous phase comprises water and optionally at least one solvent which is aqueous or miscible at 25°C; preferably, the solvent is selected from: short-chain straight-chain or branched-chain alkanols, such as C2-C4 alkanols, such as ethanol, isopropanol, propanol or butanol; diols or polyols, especially having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms, such as glycerol, ethylene glycol, 1,2-propanediol, 1,3-butanediol, hexanediol, diethylene glycol, 1,3-propanediol, 1,2-pentanediol, dipropylene glycol, 2-ethoxyethanol, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, sorbitol, polyethylene glycol having 2 to 200 ethylene oxide units; and mixtures thereof.

8. The composition according to any one of claims 1 or 3 to 7, wherein The aqueous phase comprises: at least 60% by weight, preferably at least 70% by weight, preferably in an amount of 80% to 98% by weight of water, relative to the total weight of the aqueous phase.

9. The composition according to any one of claims 1 or 3 to 8, wherein, The aqueous phase comprises at least one surfactant selected from anionic surfactants, amphoteric surfactants and nonionic surfactants; preferably at least one nonionic surfactant, preferably selected from alkyl polyglucosides, esters of fatty acids having 6 to 12 carbon atoms, esters of polyglycerol having 5 to 8 glycerol units, and mixtures thereof.

10. The composition according to any one of claims 1 or 3 to 9, wherein, The weight ratio between the aqueous phase and the oily phase is from 1 to 6, preferably from 1.03 to 5.8, preferably from 1.04 to 5.

7.

11. A method of removing makeup and / or cleansing and / or caring for keratin materials, comprising applying the composition according to any one of claims 1 to 10 to the keratin materials, especially keratin materials of the eye area, preferably the eyelashes. Use of the composition according to any one of claims 1 to 10 for removing makeup and / or cleansing and / or caring for keratin materials, in particular keratin materials of the eye area, preferably the eyelashes.

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