Thermal insulation coating for temperature change coating
By adding thermal insulation coating and temperature-changing coating to the temperature-changing coating and using hollow glass microspheres and toughening agents to form a porous structure, the problem of low temperature sensing sensitivity of temperature-changing coatings in clothing and luggage applications is solved, and better thermal insulation effects are achieved.
Patent Information
- Application Number
- CN202510889097.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-06-30
- Publication Date
- 2025-09-09
AI Technical Summary
Existing temperature-sensitive coatings have low temperature sensing sensitivity in clothing and luggage applications, making it difficult to effectively isolate the effects of body temperature and external temperature changes.
A coating formula containing a thermal insulation coating and a temperature-variable coating is used. By adding components such as hollow glass microspheres and toughening agents, a porous, soft and fluffy structure is formed. By utilizing the principle of poor thermal conductivity of air, it can quickly respond to temperature changes and provide thermal insulation.
It improves the temperature sensing sensitivity of the coating, reduces unnecessary heat conduction, and enhances the thermal insulation effect of clothing in different temperature environments. It is suitable for use as a base layer for clothing, isolating it from the interference of body temperature and external temperature.
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Figure BDA0005474475760000071
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of temperature-changing coating preparation, and in particular to a heat-insulating coating for temperature-changing coating. Background Art
[0002] Temperature-sensitive coatings are commonly used in clothing and luggage, primarily through coating or spraying fabric or leather coils, as well as custom printing. However, in actual applications, they often suffer from low temperature sensitivity.
[0003] Currently, no effective solutions have been proposed for the problems in related technologies. Summary of the Invention
[0004] In response to the problems in the related art, the present invention proposes a thermal insulation coating for temperature-changing coatings to overcome the above-mentioned technical problems existing in the existing related art.
[0005] To this end, the specific technical solutions adopted in the present invention are as follows:
[0006] A thermal insulation coating for temperature-variable coating, comprising a thermal insulation coating and a temperature-variable coating, wherein:
[0007] The heat-insulating coating comprises the following components and their contents in parts by weight: 20-80 parts of resin, 0-1 part of pigment, 10-40 parts of solvent cyclohexanone, 10-40 parts of ethyl acetate, 1-20 parts of reinforcing agent, 0.2-0.8 parts of antioxidant, and 0.07-0.5 parts of ultraviolet absorber.
[0008] Preferably, the reinforcing agent is a hard reinforcing agent, which is a composition of hollow glass microspheres and a toughening agent in a mass ratio of 1-1.5:2-2.5. Preferably, the reinforcing agent is a flexible reinforcing agent, which is a foaming agent.
[0009] Preferably, the resin is any one of epoxy resin, PVB resin, TPU resin and PU resin.
[0010] Preferably, the antioxidant is any one of BASF1076, BASF245, BASF168, BASF136, and BASF1010.
[0011] Preferably, the specific model of the ultraviolet absorber is any one of UV-328, UV-5411, UV-531, UV-329, and UV-312.
[0012] As a preferred method, the preparation method is:
[0013] S1 Take a beaker, add ethyl acetate, turn on the precision power-boosting electric stirrer, set the speed to 70 rpm, and add cyclohexanone dropwise;
[0014] S2 is heated using a heating jacket, the temperature is set at 60°C, and antioxidant is added;
[0015] S3 After the antioxidant is fully dissolved, add the ultraviolet absorber;
[0016] After S4 is completely dissolved, add toughening agent;
[0017] Adjust the temperature of S5 to 120℃, add resin, and adjust the speed to 140 rpm;
[0018] S6: After the resin is fully dissolved, add the hollow glass microspheres in small amounts and multiple times. After all the microspheres are added, adjust the speed to 100 rpm and the temperature to 140°C until they are fully dispersed.
[0019] S7: Slowly cool the material temperature to room temperature and stop stirring;
[0020] S8 pours the material into the prepared tank and the preparation is completed.
[0021] The beneficial effects of the present invention are: by adding a layer of thermal insulation coating, the heat conduction on one side of the temperature-variable coating is blocked, so that it can respond quickly to the temperature change of the sensing surface, avoiding unnecessary heat transfer and generating buffering. After the coating is cured, the coating hardness is relatively large. By utilizing the principle of poor thermal conductivity of air, the coating formula is adjusted to make the coating rich in air to achieve the purpose of thermal insulation. The flexible coating formed by heating and foaming the coating to solidify it into a porous, soft and fluffy structure is more suitable for clothing and used as a base on clothing to isolate the interference of body temperature on the temperature-variable layer. Because the human body temperature is basically constant, the temperature-variable layer is difficult to change, and it will also weaken the impact of changes in the external environment temperature on the temperature-variable layer. BRIEF DESCRIPTION OF THE DRAWINGS
[0022] In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following briefly introduces the drawings required for use in the embodiments. Obviously, the drawings described below are only some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative work.
[0023] Figure 1 This is a schematic diagram of the preparation steps of a thermal insulation coating for temperature-changing coatings according to an embodiment of the present invention. DETAILED DESCRIPTION
[0024] To further illustrate each embodiment, the present invention provides drawings, which are part of the disclosure of the present invention. They are mainly used to illustrate the embodiments and can be used in conjunction with the relevant descriptions in the specification to explain the operating principles of the embodiments. By referring to these contents, ordinary technicians in this field should be able to understand other possible implementation methods and advantages of the present invention. The components in the figures are not drawn to scale, and similar component symbols are generally used to represent similar components.
[0025] According to an embodiment of the present invention, a thermal insulation coating for temperature-changing coating is provided.
[0026] First, materials are obtained and prepared according to the following embodiments to prefabricate the thermal insulation coating.
[0027] Example 1
[0028] like Figure 1 As shown, 100 grams of ethyl acetate, 45 grams of cyclohexanone, 2 grams of antioxidant BASF1076, 1.5 grams of BASF245, 1 gram of BASF168, 10 grams of toughening agent, 60 grams of resin, 25 grams of hollow glass microspheres, 0.12 grams of ultraviolet absorber uv-328, and 0.06 grams of uv-5411;
[0029] It is prepared by the following method:
[0030] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0031] s1. Take a 500ml beaker, add 100 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 45 g of cyclohexanone dropwise;
[0032] s2 using a heating mantle for heating, the temperature was set at 60 ° C, into the antioxidant BASF1076 2 g, BASF245 1.5 g, BASF168 1 g;
[0033] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber uv-328 and 0.06 g of uv-5411;
[0034] s4. After complete dissolution, add 10 g of toughening agent MX217;
[0035] s5. The temperature was adjusted to 120°C, 60 g of resin was added, and the speed was adjusted to 140 rpm;
[0036] s6. After the resin is fully dissolved, add 25 g of hollow glass microspheres in small amounts and multiple times. After the resin is fully dissolved, adjust the speed to 100 rpm and the temperature to 140 ° C until it is completely dispersed.
[0037] s7. Slowly lower the material temperature to room temperature and then stop stirring;
[0038] Pour the material into the prepared tank and the preparation is complete.
[0039] In this embodiment, by adding a layer of thermal insulation coating, the heat conduction on one side of the temperature-variable coating is blocked, so that it can respond quickly to the temperature change of the sensing surface, avoiding unnecessary heat transfer and generating buffering. After the coating is cured, the coating hardness is relatively high.
[0040] Example 2
[0041] like Figure 1 As shown, 80 grams of ethyl acetate, 35 grams of cyclohexanone, 1.5 grams of antioxidant BASF245, 1 gram of BASF168, 0.5 grams of BASF136, 5 grams of toughening agent, 40 grams of resin, 10 grams of hollow glass microspheres, 0.12 grams of ultraviolet absorber uv-531, and 0.06 grams of uv-329;
[0042] It is prepared by the following method:
[0043] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0044] s1. Take a 500ml beaker, add 80 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 35 g of cyclohexanone dropwise;
[0045] s2 was heated using a heating mantle, the temperature was set at 60 ° C, and the antioxidant BASF245 was put into 1.5 g, BASF168 was 1 g, and BASF136 was 0.5 g;
[0046] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber uv-531 and 0.06 g of uv-329;
[0047] s4. After complete dissolution, add 5 g of toughening agent MX217;
[0048] s5. The temperature was adjusted to 120°C, 60 g of resin was added, and the speed was adjusted to 140 rpm;
[0049] s6. After the resin is fully dissolved, add 10 g of hollow glass microspheres in small amounts and multiple times. After the resin is fully dissolved, adjust the speed to 100 rpm and the temperature to 140°C until it is completely dispersed.
[0050] s7. Slowly lower the material temperature to room temperature and then stop stirring;
[0051] Pour the material into the prepared tank and the preparation is complete.
[0052] Example 3
[0053] like Figure 1 As shown, ethyl acetate 70 grams, cyclohexanone 30 grams, antioxidant BASF168 is 1 gram, BASF136 is 0.5 grams, BASF1010 is 0.3 grams, toughening agent 2.5 grams, resin 30 grams, hollow glass microspheres 20 grams, ultraviolet absorber UV-329 is 0.12 grams, UV-312 is 0.06 grams;
[0054] It is prepared by the following method:
[0055] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0056] s1. Take a 500ml beaker, add 70 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 30 g of cyclohexanone dropwise;
[0057] s2 was heated using a heating mantle, the temperature was set at 60 ° C, and the antioxidant BASF168 was 1 g, BASF136 was 0.5 g, and BASF1010 was 0.3 g;
[0058] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber UV-329 and 0.06 g of UV-312;
[0059] s4. After complete dissolution, add 10 g of toughening agent MX217;
[0060] s5. The temperature was adjusted to 120°C, 30 g of resin was added, and the speed was adjusted to 140 rpm;
[0061] s6. After the resin is fully dissolved, add 20 grams of hollow glass microspheres in small amounts and multiple times. After the resin is fully dissolved, adjust the speed to 100 rpm and the temperature to 140°C until it is completely dispersed.
[0062] s7. Slowly lower the material temperature to room temperature and then stop stirring;
[0063] Pour the material into the prepared tank and the preparation is complete
[0064] Example 4
[0065] like Figure 1 As shown, ethyl acetate 100 grams, cyclohexanone 45 grams, antioxidant BASF136 2 grams, BASF1010 1.5 grams, BASF168 1 gram, foaming agent 10 grams, resin 60 grams, ultraviolet absorber uv-329 0.12 grams, uv-5411 0.06 grams;
[0066] It is prepared by the following method:
[0067] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0068] s1. Take a 500ml beaker, add 100 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 45 g of cyclohexanone dropwise;
[0069] s2 was heated using a heating mantle, the temperature was set at 60 ° C, and the antioxidant BASF136 was added 2 g, BASF1010 was 1.5 g, and BASF168 was 1 g;
[0070] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber uv-329 and 0.06 g of uv-5411;
[0071] s4. After complete dissolution, add 10 g of foaming agent;
[0072] s5. The temperature was adjusted to 120°C, 60 g of resin was added, and the speed was adjusted to 140 rpm;
[0073] s6. Slowly lower the material temperature to room temperature and stop stirring;
[0074] s7. Pour the material into the prepared tank and the preparation is complete.
[0075] Example 5
[0076] like Figure 1 As shown, 80 grams of ethyl acetate, 35 grams of cyclohexanone, 1.5 grams of antioxidant BASF136, 1 gram of BASF1010, 0.5 grams of BASF168, 15 grams of foaming agent, 40 grams of resin, 0.12 grams of ultraviolet absorber uv-531, and 0.06 grams of uv-329;
[0077] It is prepared by the following method:
[0078] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0079] s1. Take a 500ml beaker, add 80 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 35 g of cyclohexanone dropwise;
[0080] s2 was heated using a heating mantle at 60 ° C, the antioxidant BASF136 was 1.5 g, BASF1010 was 1 g, and BASF168 was 0.5 g;
[0081] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber uv-531 and 0.06 g of uv-329;
[0082] s4. After complete dissolution, add 15 g of foaming agent;
[0083] s5. The temperature was adjusted to 120°C, 40 g of resin was added, and the speed was adjusted to 140 rpm;
[0084] s6. Slowly lower the material temperature to room temperature and stop stirring;
[0085] s7. Pour the material into the prepared tank and the preparation is complete.
[0086] Example 6
[0087] like Figure 1 As shown, ethyl acetate 70 grams, cyclohexanone 30 grams, antioxidant BASF245 is 1 gram, BASF1076 is 0.6 grams, BASF1010 is 0.8 grams, foaming agent 20 grams, resin 30 grams, ultraviolet absorber UV-329 is 0.12 grams, UV-312 is 0.06 grams;
[0088] It is prepared by the following method:
[0089] Use a fine power-boosting electric stirrer to mix the materials, and the ambient humidity should be controlled at 30-50%;
[0090] s1. Take a 500ml beaker, add 70 g of ethyl acetate, turn on the precision power-enhancing electric stirrer, set the speed to 70 rpm, and add 30 g of cyclohexanone dropwise;
[0091] s2 was heated using a heating mantle, the temperature was set at 60 ° C, the input antioxidant BASF245 was 1 g, BASF1076 was 0.6 g, BASF1010 was 0.8 g;
[0092] s3. After the antioxidant is fully dissolved, add 0.12 g of UV absorber uv-329 and 0.06 g of uv-5411;
[0093] s4. After complete dissolution, add 20 g of foaming agent;
[0094] s5. The temperature was adjusted to 120°C, 30 g of resin was added, and the speed was adjusted to 140 rpm;
[0095] s6. Slowly lower the material temperature to room temperature and stop stirring;
[0096] s7. Pour the material into the prepared tank and the preparation is complete.
[0097] Comparative Example
[0098] Hard coating
[0099] Resin 20-80 parts, pigment 0-1 part, solvent 20-80 parts, hollow glass microspheres 1-20 parts;
[0100] Flexible coatings
[0101] Resin 20-80 parts, pigment 0-1 part, solvent 20-80 parts, foaming agent 1-20 parts.
[0102] In this embodiment, the principle of poor thermal conductivity of air is utilized and the coating formula is adjusted to make the coating rich in air, thereby achieving the purpose of thermal insulation. The coating is heated, foamed and solidified to form a porous, soft and fluffy structure. The flexible coating formed is more suitable for clothing and can be used as a base layer on clothing to isolate the interference of body temperature on the temperature change layer. Because human body temperature is basically constant, it is difficult for the temperature change layer to change. At the same time, it will also weaken the impact of changes in external environmental temperature on the temperature change layer.
[0103]
[0104]
[0105] Through testing, it is found that compared with the comparative example, Examples 1, 2, 3, 4, 5 and 6 have higher thermal resistance, lower heat transfer coefficient and lower thermal conductivity, and have better heat insulation effect.
[0106] The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the scope of protection of the present invention.
Claims
1. A thermal insulation coating for temperature-changing coating, characterized in that: Including thermal insulation coating and temperature-changing coating, including: The heat-insulating coating comprises the following components and their contents in parts by weight: 20-80 parts of resin, 0-1 part of pigment, 10-40 parts of solvent cyclohexanone, 10-40 parts of ethyl acetate, 1-20 parts of reinforcing agent, 0.2-0.8 parts of antioxidant, and 0.07-0.5 parts of ultraviolet absorber.
2. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The reinforcing agent is a hard reinforcing agent, which is a composition formed by hollow glass microspheres and a toughening agent in a mass ratio of 1-1.5:2-2.
5.
3. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The reinforcing agent is a flexibility reinforcing agent, and the flexibility reinforcing agent is a foaming agent.
4. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The foaming agent is 1-20 parts.
5. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The foaming agent is any one of ADC foaming agent, DPT foaming agent and sodium bicarbonate.
6. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The resin is any one of epoxy resin, PVB resin, TPU resin and PU resin.
7. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The antioxidant is specifically any one of BASF1076, BASF245, BASF168, BASF136, and BASF1010.
8. The thermal insulation coating for temperature-changing coating according to claim 1, characterized in that: The specific model of the ultraviolet absorber is any one of UV-328, UV-5411, UV-531, UV-329, and UV-312.
9. A thermal insulation coating for temperature-changing coating according to any one of claims 1 to 8, characterized in that: The steps include: S1 Take a beaker, add ethyl acetate, turn on the precision power-boosting electric stirrer, set the speed to 70 rpm, and add cyclohexanone dropwise; S2 is heated using a heating jacket, the temperature is set at 60°C, and antioxidant is added; S3 After the antioxidant is fully dissolved, add the ultraviolet absorber; After S4 is completely dissolved, add toughening agent; Adjust the temperature of S5 to 120℃, add resin, and adjust the speed to 140 rpm; S6: After the resin is fully dissolved, add the hollow glass microspheres in small amounts and multiple times. After all the microspheres are added, adjust the speed to 100 rpm and the temperature to 140°C until they are fully dispersed. S7: Slowly cool the material temperature to room temperature and stop stirring; S8 pours the material into the prepared tank and the preparation is completed.