Semi-coke wastewater treatment dephenolization equipment

By combining a steam-water mixer and a dissolved air pump, the semi-coke wastewater treatment equipment achieves efficient separation of phenol and tar, solving the problem of unstable phenol oxidation and separation effects in existing technologies, and ensuring the stable operation of the biochemical treatment system.

CN121269872APending Publication Date: 2026-01-06麦焘环境科技(上海)有限公司
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Patent Information

Application Number
CN202511687587.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-11-18
Publication Date
2026-01-06

AI Technical Summary

Technical Problem

Existing semi-coke wastewater treatment technologies are unable to efficiently separate ternary and higher-order phenols and tar, and phenolic compounds are easily oxidized to quinones during the treatment process, affecting the stable operation of subsequent biochemical treatment systems.

Method used

A phenol removal device for treating semi-coke wastewater is used. Wastewater, carbon dioxide gas, and nitrogen are mixed through a gas-water mixer and a dissolved air pump to form microbubbles. The device utilizes an automatic directional movement mechanism and an automatic switching mechanism to achieve efficient separation of phenol and tar, thus preventing the oxidation of phenol to quinone.

Benefits of technology

It achieves efficient separation of ternary and higher phenols and tar, avoids phenol oxidation, ensures stable operation of the biochemical treatment system, and reduces the frequency of equipment maintenance.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention discloses dephenolization equipment for semi-coke wastewater treatment, and relates to the technical field of semi-coke wastewater treatment.The dephenolization equipment comprises a flotation machine, an automatic directional moving mechanism and an automatic switching mechanism, a halfpace is arranged on one side of the flotation machine and communicated with a steam-water mixer through a pipeline, the bottom of the steam-water mixer is communicated with a dissolved air pump, and a pipeline mixer is installed on the dissolved air pump; the automatic directional moving mechanism comprises a track toothed plate, a sliding table, a main driving gear and the like, during use, wastewater, carbon dioxide and nitrogen are mixed in proportion through a gas dissolving pump and a pipeline mixer and react in a steam-water mixer under 0.45-0.55 MPa, a mixture with generated microbubbles enters a flotation machine, pollutants adsorbed by the microbubbles float upwards, and the pollutants are discharged from the flotation machine; the automatic directional moving mechanism and the automatic switching mechanism drive the floating scraper blade to scrape slag, and the density meter in the settling zone controls automatic slag discharge. The equipment prevents phenol from being oxidized into quinone, adapts to water quality fluctuation, improves the separation efficiency, and is high in automation degree, easy and convenient to maintain and suitable for efficient dephenolization treatment of semi-coke wastewater.
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Description

Technical Field

[0001] This invention relates to the field of semi-coke wastewater treatment technology, specifically to a semi-coke wastewater treatment and phenol removal device. Background Technology

[0002] Semi-coke wastewater is a high-concentration organic wastewater generated during the semi-coke production process. It contains a large amount of phenolic compounds (especially ternary and higher phenols), tar, suspended solids (SS), and water-insoluble oily substances. If not treated properly, it will cause serious pollution to the water environment. Therefore, efficient phenol removal and pollutant removal are the core requirements for semi-coke wastewater treatment and a key link to ensure the stable operation of subsequent biological treatment (such as A / O system).

[0003] Currently, the mainstream technology for treating semi-coke wastewater in China is air flotation, with dissolved air flotation (DAF) being the most widely used. This method involves dissolving air in water to form dissolved air water, which is then released under reduced pressure to generate bubbles. These bubbles adsorb suspended solids (SS) and oily substances in the wastewater, achieving separation. However, this technology has significant drawbacks: during the contact between air and wastewater, phenolic compounds in the wastewater are oxidized to quinones. Subsequent A / O systems cannot degrade quinones, leading to effluent that fails to meet standards. Furthermore, it affects the activity of microorganisms in the biological system, reducing overall treatment efficiency.

[0004] Another commonly used technology is nitrogen flotation, which separates pollutants using nitrogen bubbles. While this avoids the oxidation of phenols, it suffers from poor separation efficiency and weak adaptability to raw water quality. The quality of semi-coke wastewater fluctuates greatly. Influenced by raw materials and process parameters in semi-coke production, the concentration of suspended solids (SS), phenol content, and oil content in the wastewater often change drastically. Under these conditions, the separation capacity of nitrogen flotation decreases significantly, failing to stably remove ternary and higher-order phenols and tar, resulting in unstable treatment effects and difficulty meeting the needs of continuous industrial treatment. Based on the shortcomings of existing technologies, there is an urgent need to develop a semi-coke wastewater treatment and phenol removal device that can efficiently separate ternary and higher-order phenols from tar while preventing the oxidation of phenols to quinones.

[0005] Therefore, a phenol removal device for semi-coke wastewater treatment was proposed to solve the above problems. Summary of the Invention

[0006] In view of this, the technical problem to be solved by the present invention is to provide a phenol removal device for semi-coke wastewater treatment, so as to solve the problem of separating and removing ternary and higher-order phenols and tar in semi-coke wastewater treatment, and ensuring that phenols are not oxidized to quinones during the entire process.

[0007] To achieve the above objectives, the present invention provides the following technical solution: a semi-coke wastewater treatment and phenol removal device, comprising a flotation stage, a ladder platform provided on one side of the flotation stage, a steam-water mixer connected to the flotation stage via a pipeline, a dissolved air pump connected to the bottom of the steam-water mixer via a pipeline, a pipeline mixer installed on the dissolved air pump, and the semi-coke wastewater treatment and phenol removal device further comprising an automatic directional movement mechanism and an automatic switching mechanism; the automatic directional movement mechanism is located above the flotation stage, and the automatic switching mechanism is located in the middle of the flotation stage.

[0008] Preferably, the automatic orientation and movement mechanism includes a track toothed plate, with gear grooves symmetrically opened in the middle of the track toothed plate, both ends of the track toothed plate being fixedly installed on the inner wall of the flotation upper surface, and a slide table being slidably installed on the upper surface of the track toothed plate, with a main drive gear rotatably installed in the middle of the slide table.

[0009] Preferably, the tooth surface of the main drive gear meshes with a driven gear, the driven gear is symmetrically rotatably mounted in the slide, the tooth surface of the driven gear away from the main drive gear meshes with meshing teeth, a bearing is mounted in the middle of the lower surface of the meshing teeth, the bottom of the slide is symmetrically provided with guide grooves, and the middle of the outer surface of the bearing is slidably mounted in the guide groove of the slide.

[0010] Preferably, a pulley is fixedly installed on the middle of the upper surface of the meshing teeth, a transmission belt is driven on the pulley, a guide wheel is installed on the inner wall of one side of the slide, and the middle of the transmission belt is driven on the guide wheel.

[0011] Preferably, the automated switching mechanism includes a dynamic switching gear, the upper surface of the middle part of the dynamic switching gear is fixedly mounted on a meshing tooth, the tooth surface of the dynamic switching gear meshes in a gear groove opened in the track tooth plate, a directional adjustment plate is rotatably mounted on the lower surface of the middle part of the dynamic switching gear, a sliding plate is rotatably mounted on the middle part of the directional adjustment plate, the sliding plate is slidably mounted on the lower surface of the track tooth plate, and a pressure column is fixedly mounted on the lower surface of the directional adjustment plate near the dynamic switching gear.

[0012] Preferably, directional locking pins are symmetrically slidably mounted on the upper surface of the slide plate. A compression spring is sleeved on the outer surface of the directional locking pin. One end of the compression spring is fixedly mounted on the directional locking pin, and a pressure plate is fixedly mounted on the other end of the compression spring. A pressure groove is opened in the middle of the end of the directional locking pin near the directional adjustment plate, and the pressure pin is slidably mounted in the pressure groove.

[0013] Preferably, a semi-circular extrusion plate is fixedly installed in the middle of the skateboard, and semi-circular grooves are symmetrically opened on both sides of the semi-circular extrusion plate. A connecting hole is opened in the middle of the semi-circular groove of the semi-circular extrusion plate, and directional locking pins on both sides of the semi-circular extrusion plate are movably connected through the connecting hole by a connector; a telescopic plate is installed on the lower surface of the skateboard, and a floating scraper is fixedly installed on the end of the telescopic plate away from the skateboard.

[0014] Preferably, triangular extrusion blocks are symmetrically installed at both ends of the track tooth plate, and the inclined surfaces of the triangular extrusion blocks are in opposite directions. A conical backflow cylinder is symmetrically arranged at the bottom of the flotation, and the conical backflow cylinder is used to form a vortex in the mixture.

[0015] Compared with the prior art, the phenol removal equipment for semi-coke wastewater treatment provided by the present invention has the following beneficial effects: 1. In use, wastewater, carbon dioxide gas, and nitrogen gas are mixed, reacted, and separated in a certain proportion through a dissolved air pump and a gas-water separator. This process removes ternary and higher-order phenols and tar from semi-coke wastewater, and the phenols are not oxidized to quinones throughout the entire process.

[0016] 2. The gas-water separator of this invention, through its internal conical structure, achieves tangential entry and rotating flow, breaking large bubbles into microbubbles. This allows sufficient time for thorough mixing and reaction of the three components. The gas-water separator employs a wide channel measuring 50×50mm, preventing the deposition and clogging of suspended solids (SS) in the wastewater. A pressure gauge is installed at the top of the gas-water separator for continuous monitoring.

[0017] 3. This invention is equipped with a slag scraping trolley and a flip plate. During use, it is automatically controlled by a limit switch, so that slag scraping and maintenance can be carried out without opening the cover plate.

[0018] 4. This invention features a proprietary release head, designed with the principles of pressure-reducing release and the changing solubility of carbon dioxide and nitrogen with pressure in mind. During operation, the mixed gases released into the release head are microbubbles, carrying SS and fuel to the water surface.

[0019] 5. The present invention is equipped with an automatic slag discharge system. A density meter is installed at the bottom of the sedimentation tank. When the density reaches 1.07, the bottom slag discharge valve opens automatically. When the density is lower than 1.01, the bottom slag discharge valve closes automatically.

[0020] 6. This invention uses only two moving parts: a motor and a pump. This greatly reduces the frequency of inspection and maintenance. Attached Figure Description

[0021] Figure 1 This is a three-dimensional structural diagram of the present invention; Figure 2 This is an auxiliary schematic diagram of the three-dimensional structure of the present invention; Figure 3 This is a schematic diagram of the structural connection relationship of the automatic orientation and movement mechanism of the present invention; Figure 4 This is an auxiliary schematic diagram showing the structural connection relationship of the automatic orientation and movement mechanism of the present invention; Figure 5 For the present invention Figure 4 Enlarged view of point A in the middle; Figure 6 This is a schematic diagram showing the decomposed state of the structural connection relationship of the automatic orientation and movement mechanism of the present invention; Figure 7 For the present invention Figure 6 Enlarged view at point B in the middle; Figure 8 This is a schematic diagram showing the decomposed state of the structural connection relationship between the automatic orientation movement mechanism and the automatic switching mechanism of the present invention; Figure 9 For the present invention Figure 8 Enlarged view of point C.

[0022] In the picture: 1. Flotation machine; 11. Air-water mixer; 12. Dissolved air pump; 13. Pipeline mixer; 14. Platform; 2. Automatic orientation and movement mechanism; 21. Track toothed plate; 22. Slide table; 23. Main drive gear; 24. Pulley; 25. Meshing teeth; 26. Driven gear; 27. Transmission belt; 3. Automated switching mechanism; 31. Dynamic switching gear; 32. Slide plate; 33. Orientation adjustment plate; 34. Pressure column; 35. Orientation locking column head; 36. Compression spring; 37. Semi-arc extrusion plate; 38. Telescopic plate; 39. Floating scraper; 301. Triangular extrusion block. Detailed Implementation

[0023] The technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention.

[0024] The present invention will now be described in further detail with reference to the accompanying drawings and embodiments.

[0025] Example 1, please refer to Figures 1 to 9 As shown: To address the problems mentioned in the technical solutions, this application provides a phenol removal device for treating semi-coke wastewater, including a flotation 1. A ladder 14 is provided on one side of the flotation 1. A steam-water mixer 11 is connected to the flotation 1 via a pipeline. A dissolved air pump 12 is connected to the bottom of the steam-water mixer 11 via a pipeline. A pipeline mixer 13 is installed on the dissolved air pump 12. The phenol removal device for treating semi-coke wastewater also includes an automatic directional movement mechanism 2 and an automatic switching mechanism 3. The automatic directional movement mechanism 2 is located above the flotation 1, and the automatic switching mechanism 3 is located in the middle of the flotation 1. In this system, dissolved air pump 12 mixes wastewater, carbon dioxide gas, and nitrogen gas in a certain proportion within pipeline mixer 13, and then pumps the mixture into steam-water mixer 11. Under the pressure of 0.45 MPa-0.55 MPa within steam-water mixer 11, the solubility of carbon dioxide gas increases, allowing it to dissolve better in the wastewater and react with phenolic pollutants. Nitrogen gas also exhibits good solubility at this pressure, coupling with carbon dioxide and playing a crucial role in generating microbubbles after subsequent pressure release. The internal structure of steam-water mixer 11 is detailed in the CAD drawing. The steam-water mixture enters from the middle of steam-water mixer 11, flows tangentially through the internal conical guide tube, and exits from a 50mm × 50mm hole at the bottom of the cone. The steam-water mixture forms a swirling flow within the conical guide tube, increasing the reaction time while reducing the equipment volume. After the reaction is complete, the steam-water mixture flows out from the top of steam-water mixer 11 into flotation machine 1. A pressure gauge is installed on the top of steam-water mixer 11 for monitoring and adjustment.

[0026] The effluent from the gas-water mixer 11 flows by gravity into the gas release zone of the flotation machine 1, where it is released through a gas release device. Carbon dioxide and nitrogen gases are released through a dedicated release head, forming microbubbles that float suspended solids and water-insoluble light oily substances to the surface. These are then scraped to the collection trough by a scraper trolley. After passing through the release zone, the wastewater flows by gravity into the sedimentation zone. The purpose of the sedimentation zone is to settle the heavier, water-insoluble oily substances to the bottom. A density meter is installed at the bottom of the sedimentation tank. When the density reaches 1.07, the bottom sludge discharge valve automatically opens; when the density is below 1.01, the bottom sludge discharge valve automatically closes. After passing through the sedimentation zone, the wastewater flows by gravity into the drainage trough for discharge.

[0027] The bottom of the flotation machine 1 is symmetrically equipped with sedimentation zones. The purpose of the sedimentation zones is to settle heavy, water-insoluble oily substances at the bottom. A density meter is installed at the bottom of the sedimentation tank. When the density reaches 1.07, the bottom slag discharge valve automatically opens; when the density is lower than 1.01, the bottom slag discharge valve automatically closes. After passing through the sedimentation zone, the wastewater flows by gravity into the drainage trough for discharge.

[0028] Specifically, such as Figure 4 and Figure 5As shown, the track toothed plate 21 has symmetrical gear slots in the middle. The two ends of the track toothed plate 21 are fixedly installed on the inner wall of the upper surface of the flotation 1. A slide table 22 is slidably installed on the upper surface of the track toothed plate 21. A main drive gear 23 is rotatably installed in the middle of the slide table 22. A driven gear 26 meshes with the tooth surface of the main drive gear 23. The driven gear 26 is symmetrically rotatably installed in the slide table 22. A meshing tooth 25 meshes with the tooth surface of the driven gear 26 away from the main drive gear 23. A bearing is installed in the middle of the lower surface of the meshing tooth 25. Guide slots are symmetrically opened at the bottom of the slide table 22, and the bearing is slidably installed in the guide slot of the slide table 22 in the middle of the outer surface of the bearing. A pulley 24 is fixedly installed in the middle of the upper surface of the meshing tooth 25. A transmission belt 27 is driven on the pulley 24. A guide wheel is installed on the inner wall of one side of the slide table 22. The transmission belt 27 is driven on the guide wheel in the middle. A sealing plate is installed on the upper surface of the track tooth plate 21, and a drive motor is installed above the sealing plate. The drive shaft of the drive motor is fixedly installed in the middle of the main drive gear 23. The rotation of the drive motor can drive the main drive gear 23 to rotate, and at the same time drive the meshing driven gear 26 to drive the meshing teeth 25 to start rotating in the same direction as the main drive gear 23. The rotation of the meshing teeth 25 can drive the pulley 24 to rotate symmetrically and synchronously, which provides power support for driving the automatic switching mechanism 3 to automatically adjust the movement direction of the slide table 22.

[0029] Specifically, such as Figure 7 and Figure 9 As shown, the upper surface of the middle part of the dynamic switching gear 31 is fixedly mounted on the meshing gear 25. The tooth surface of the dynamic switching gear 31 meshes in the gear groove opened in the track tooth plate 21. The lower surface of the middle part of the dynamic switching gear 31 is rotatably mounted with a directional adjustment plate 33. The middle part of the directional adjustment plate 33 is rotatably mounted with a slide plate 32. The slide plate 32 is slidably mounted on the lower surface of the track tooth plate 21. A pressure column 34 is fixedly mounted on the lower surface of the directional adjustment plate 33 near the dynamic switching gear 31. A directional locking column head 35 is symmetrically slidably mounted on the upper surface of the slide plate 32. A compression spring 36 is sleeved on the outer surface of the directional locking column head 35. One end of the compression spring 36 is fixedly mounted on the directional locking column head 35. The other end of the compression spring 36 is fixedly mounted with a pressure plate. A pressure groove is opened in the middle part of the directional locking column head 35 near the directional adjustment plate 33. The pressure column 34 is slidably mounted in the pressure groove. The dynamic switching gear 31 and the compression spring 36 are symmetrically arranged at both ends of the slide plate 32, and the directional locking pins 35 are connected by a universal connecting rod slidably mounted on the directional locking pins 35.

[0030] A semi-circular extrusion plate 37 is fixedly installed in the middle of the slide plate 32. Semi-circular grooves are symmetrically opened on both sides of the semi-circular extrusion plate 37. A connecting hole is opened in the middle of the semi-circular groove of the semi-circular extrusion plate 37. The directional locking pins 35 set on both sides of the semi-circular extrusion plate 37 are movably connected through the connecting hole by a connector. A telescopic plate 38 is installed on the lower surface of the slide plate 32. A floating scraper 39 is fixedly installed at the end of the telescopic plate 38 away from the slide plate 32. When one end of the directional adjustment plate 33 moves to the end of the track tooth plate 21 and is pressed against the inclined surface of the triangular pressing block 301, as... Figure 6 As shown, when the directional adjustment plate 33 at one end is pressed against the inclined surface of the triangular extrusion block 301, it will cause the directional adjustment plate 33 to start swinging. Since the middle part of the directional adjustment plate 33 is installed as a lever, the swinging of one end of the directional adjustment plate 33 will cause the dynamic switching gear 31 at the other end of the directional adjustment plate 33 to start sliding in the guide groove of the slide table 22. At this time, as shown... Figure 7 As shown, the dynamic switching gear 31 will start to disengage from the upper tooth surface of the track tooth plate 21 due to the swing of the directional adjustment plate 33, and at the same time engage with the lower tooth surface of the track tooth plate 21. At this time, the pressure column 34 will squeeze the compression spring 36. At the same time, the mutual squeezing of the directional locking column head 35 and the semi-circular extrusion plate 37 will drive the directional locking column head 35 to slide to the upper end of the semi-circular extrusion plate 37. At the same time, the compression spring 36 will start to elastically extend again to achieve self-locking. Thus, the movement direction of the slide table 22 can be switched by squeezing through the directional adjustment plate 33. At the same time, by installing a rotatable and extendable floating scraper 39 under the slide plate 32, suspended objects can be cleaned and the height of the floating scraper 39 can be customized according to the liquid level.

[0031] The bottom of flotation unit 1 is symmetrically provided with conical backflow tubes, which are used to form swirls in the mixture; Example 2: This solution is applicable to the wastewater treatment workshop of semi-coke production enterprises. It is designed for semi-coke wastewater with high phenol content, high tar content, and large fluctuations in water quality. It achieves efficient separation of ternary and higher phenols and tar, and avoids the oxidation of phenols to quinones. The following is the implementation and setup process for a specific application scenario.

[0032] I. Equipment Installation and Layout Setup; Site selection and foundation construction: Select an area near the raw water storage tank and subsequent A / O treatment system for the wastewater treatment workshop, pour concrete foundation, ensure that the ground flatness error is ≤3mm, and reserve interfaces for drainage and slag discharge pipes.

[0033] Main equipment installation: Fix the flotation machine 1 on the foundation, leaving space for the ladder platform 14 on one side to ensure the access of operators for maintenance. The steam-water mixer 11 is connected to the upper part of the flotation machine 1 through a pipeline, and the bottom is connected to the dissolved air pump 12 through a pipeline. The pipeline mixer 13 is installed at the input end of the dissolved air pump 12, and interfaces for wastewater, carbon dioxide and nitrogen are reserved.

[0034] Auxiliary mechanism assembly: Fix both ends of the track tooth plate 21 to the inner wall of the upper surface of the flotation machine 1 to ensure that the gear grooves are symmetrically aligned; slide table 22 is slidably installed on track tooth plate 21, and automatically oriented moving mechanism 2 components such as main drive gear 23, driven gear 26, meshing gear 25 are assembled in sequence. Then connect the automatic switching mechanism 3 with meshing gear 25 and slide plate 32, and adjust the lifting flexibility of floating scraper 39.

[0035] Supporting system installation: Install a density meter in the sedimentation zone at the bottom of flotation machine 1 and connect it to an automatic slag discharge valve; install a pressure gauge on the top of steam-water mixer 11 with a range of 0.3-0.7MPa; align the slag scraper trolley with the slag collection trough to ensure an unobstructed slag scraping path.

[0036] II. Operating parameter settings; Mixing ratio adjustment: The mixing ratio of wastewater, carbon dioxide and nitrogen is set through the pipeline mixer 13, wherein the total proportion of gas is 5%-8% of the wastewater volume, and the volume ratio of carbon dioxide to nitrogen is 3:2.

[0037] Pressure parameter setting: Adjust the output pressure of dissolved air pump 12 to stabilize the working pressure inside the steam-water mixer 11 at 0.45-0.55MPa. The pressure is monitored in real time by a pressure gauge, and an automatic alarm is triggered when the deviation exceeds ±0.02MPa.

[0038] Sludge discharge parameter settings: Set the densitometer trigger threshold; when the sludge density in the sedimentation zone reaches 1.07 g / cm³. 3 When the density is below 1.01 g / cm³, the bottom slag discharge valve will automatically open. 3 When the slag discharge valve closes automatically, the slag discharge time is controlled to be 3-5 minutes each time.

[0039] Slag scraping mechanism parameters: Set the drive motor speed so that the slide table 22 moves at a speed of 0.5m / min. The automatic switching mechanism 3 is triggered by the triangular extrusion block 301 to realize the reciprocating movement of the slide table 22. The slag scraping frequency is once every 30 minutes.

[0040] III. Pretreatment and Feeding Preparation; Raw water pretreatment: The semi-coke wastewater is filtered through a screen to remove large particulate impurities and then enters an equalization tank for homogenization and flow equalization. The pH value of the raw water is controlled between 6.5 and 8.5, and the water temperature is maintained between 20 and 35℃.

[0041] Medium preparation: Carbon dioxide gas purity ≥99.5%, nitrogen gas purity ≥99.8%. Check cylinder pressure beforehand to ensure stable gas supply. Wastewater is pumped to pipeline mixer 13 via a booster pump. Flow rate is controlled within the equipment's rated capacity and adjusted according to the equipment model; a single unit capacity of 5-10 m³ / h is recommended. 3 / h.

[0042] IV. Startup and Operation Process Settings; No-load commissioning: Start the drive motor and test the smoothness of the reciprocating movement of the automatic directional moving mechanism 2 and the flexible lifting and lowering of the floating scraper 39; turn on the dissolved air pump 12 and run it under no-load for 30 minutes to check for any abnormal noises or leaks in the equipment.

[0043] Load start-up: First, introduce carbon dioxide and nitrogen. After the pressure inside the gas-water mixer 11 reaches the set value, introduce the pretreated semi-coke wastewater to ensure that the gas and liquid are fully mixed.

[0044] Operation monitoring: Observe the liquid level in the flotation machine 1 in real time and keep the liquid level 20-30cm from the top; monitor the scum scraping effect. If there is too much scum residue, the scum scraping frequency can be increased appropriately; take a sample through the outlet of the air-water mixer 11 to detect the microbubble particle size and ensure that the particle size is ≤50μm.

[0045] Subsequent treatment: The treated wastewater flows by gravity into the subsequent A / O treatment system, and the scum in the sludge collection tank is regularly transported to the hazardous waste treatment station for harmless disposal.

[0046] V. Maintenance and Emergency Setup; Routine maintenance: Check the accuracy of pressure gauge and densitometer readings daily; clean the pipe mixer 13 and release head weekly to prevent blockage; lubricate and maintain the gears and drive belt 27 of the automatic directional movement mechanism 2 monthly.

[0047] Emergency handling: If the pressure in the steam-water mixer 11 rises abnormally, immediately shut down the dissolved air pump 12 and check for pipe blockages; if the scum cannot float, check the gas ratio and the status of the release head, and adjust or replace them in time; in case of equipment failure, open the bypass pipe to ensure continuous wastewater treatment.

[0048] Please refer to the above work process. Figures 1 to 9 .

[0049] It should be noted that, in this document, relational terms such as "first" and "second" are used merely to distinguish one entity or operation from another, and do not necessarily require or imply any such actual relationship or order between these entities or operations. Furthermore, the terms "comprising," "including," or any other variations thereof are intended to cover non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements includes not only those elements but also other elements not expressly listed, or elements inherent to such a process, method, article, or apparatus. Without further limitations, an element defined by the phrase "comprising one..." does not exclude the presence of other identical elements in the process, method, article, or apparatus that includes said element.

[0050] Although embodiments of the invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and variations can be made to these embodiments without departing from the principles and spirit of the invention, the scope of which is defined by the appended claims and their equivalents.

Claims

1. A phenol removal device for treating semicoke wastewater, comprising a flotation (1), one side of the flotation (1) is provided with a ladder (14), the flotation (1) is communicated with a steam-water mixer (11) through a pipeline, the bottom of the steam-water mixer (11) is communicated with a dissolved air pump (12) through a pipeline, and the dissolved air pump (12) is installed with a pipeline mixer (13), characterized in that, The waste water treatment and phenol removal equipment for semi coke further comprises an automatic directional moving mechanism (2) and an automatic switching mechanism (3); the automatic directional moving mechanism (2) is arranged above the floatation (1), and the automatic switching mechanism (3) is arranged at the middle part of the floatation (1).

2. The equipment for treating phenol in semicoke wastewater according to claim 1, characterized in that: The automatic directional moving mechanism (2) comprises a track toothed plate (21), a gear groove is symmetrically formed in the middle part of the track toothed plate (21), the track toothed plate (21) is fixedly installed at both ends on the inner wall of the upper surface of the floatation (1), a sliding table (22) is slidably installed on the upper surface of the track toothed plate (21), and a main drive gear (23) is rotatably installed at the middle part of the sliding table (22).

3. The equipment for treating phenol in semicoke wastewater according to claim 2, characterized in that: The main drive gear (23) is meshed with a driven gear (26), the driven gear (26) is symmetrically rotatably installed in the sliding table (22), the driven gear (26) is meshed with a meshing tooth (25) on the side away from the main drive gear (23), a bearing is installed on the lower surface of the meshing tooth (25), and a guide groove is symmetrically formed in the bottom of the sliding table (22), and the outer surface of the bearing is slidably installed in the guide groove of the sliding table (22).

4. The equipment for treating phenol in semicoke wastewater according to claim 3, characterized in that: A belt pulley (24) is fixedly installed at the middle part of the upper surface of the meshing tooth (25), a transmission belt (27) is drivingly installed on the belt pulley (24), a guide wheel is installed on the inner wall of one side of the sliding table (22), and the middle part of the transmission belt (27) is drivingly installed on the guide wheel.

5. The apparatus for treating phenol in semicoke wastewater according to claim 2, characterized in that: The automatic switching mechanism (3) comprises a dynamic switching gear (31), the dynamic switching gear (31) is fixedly installed on the upper surface of the middle part of the meshing tooth (25), the dynamic switching gear (31) is meshed in the gear groove formed in the track toothed plate (21), a directional adjusting plate (33) is rotatably installed on the lower surface of the middle part of the dynamic switching gear (31), a sliding plate (32) is rotatably installed on the middle part of the directional adjusting plate (33), the sliding plate (32) is slidably installed on the lower surface of the track toothed plate (21), and a pressing column (34) is fixedly installed on the lower surface of one end of the directional adjusting plate (33) close to the dynamic switching gear (31).

6. The apparatus for treating phenol in semicoke wastewater according to claim 5, characterized in that: A directional locking stud (35) is symmetrically slidably installed on the upper surface of the sliding plate (32), a compression spring (36) is sleeved on the outer surface of the directional locking stud (35), one end of the compression spring (36) is fixedly installed on the directional locking stud (35), the other end of the compression spring (36) is fixedly installed with a pressing disc, a pressing groove is formed in the middle part of one end of the directional locking stud (35) close to the directional adjusting plate (33), and the pressing column (34) is slidably installed in the pressing groove.

7. The apparatus according to claim 6, characterized in that: A semicircular surface extrusion plate (37) is fixedly installed on the middle part of the sliding plate (32), semicircular surface grooves are symmetrically formed in the two sides of the semicircular surface extrusion plate (37), a connecting hole is formed in the middle part of the semicircular surface groove of the semicircular surface extrusion plate (37), and the directional locking studs (35) arranged on the two sides of the semicircular surface extrusion plate (37) are movably connected through the connecting hole; a telescopic plate (38) is installed on the lower surface of the sliding plate (32), and a floating scraper (39) is fixedly installed on the end of the telescopic plate (38) away from the sliding plate (32).

8. The apparatus according to claim 7, characterized in that: The track toothed plate (21) is symmetrically provided with triangular extrusion blocks (301) at both ends, and the inclined surfaces of the triangular extrusion blocks (301) are opposite, and the flotation (1) is symmetrically provided with a conical backflow cylinder at the bottom, and the conical backflow cylinder is used for forming a cyclone for the mixture.