Preparation method for producing titanium dioxide from titanium liquid with poor clarity and titanium dioxide

By adding an appropriate amount of seed crystals and dilute sulfuric acid to titanium liquid with poor clarity to control the hydrolysis rate, uniform metatitanic acid particles were prepared, solving the problem of irregular particles during the hydrolysis of titanium liquid and improving the quality and performance of titanium dioxide.

CN121361828APending Publication Date: 2026-01-20JIANGSU TOP FINE NEW RAW MATERIAL CO LTD
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Patent Information

Application Number
CN202511847561.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-12-09
Publication Date
2026-01-20

AI Technical Summary

Technical Problem

In existing technologies, the irregular metatitanic acid particles generated during the hydrolysis process of poorly clarified titanium liquid affect the filtration, washing, and calcination quality of titanium dioxide, leading to a downgrade in product quality.

Method used

By adding an appropriate amount of seed crystals and dilute sulfuric acid to the titanium solution to control the hydrolysis rate, uniformly sized metatitanic acid particles are prepared, avoiding the side effects of irregular seed crystals. An appropriate amount of acid is added during the hydrolysis process to control the hydrolysis rate.

Benefits of technology

It improves the whiteness and bleaching power of titanium dioxide, shortens the washing time, improves filtration performance, and ensures the quality of titanium dioxide.

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Abstract

The invention discloses a preparation method for producing titanium dioxide from a titanium solution with poor clarity and titanium dioxide. The preparation method comprises the following steps: S1, adding a seed crystal into the titanium solution to be hydrolyzed, stirring, heating to boil, and adding dilute acid when the titanium solution is light gray; s2, continuing to preserve heat, adding hot water to preserve heat when the titanium liquid is whitened, and hydrolyzing to prepare titanium dioxide; in the step S1, when the solid content of the titaniferous solution to be hydrolyzed is greater than 20 mg / L and less than or equal to 40 mg / L, the adding amount of the seed crystal is 0.8-1.0%; when the solid content of the titaniferous solution to be hydrolyzed is greater than 40 mg / L and less than or equal to 50 mg / L, the addition amount of the seed crystal is 1.1-1.3%; when the solid content of the titaniferous solution to be hydrolyzed is greater than 50mg / L, the adding amount of the seed crystal is greater than or equal to 1.4%. The hydrolysis material prepared by the method is uniform in particle size, good in metatitanic acid hydrolysis quality of the titaniferous solution and short in washing time; the titanium dioxide is good in quality whiteness and brightness and high in fading power. And the sanding effect of the calcined crude product is good.
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Citation Information

Patent Citations

  • Production method of titanium dioxide

    CN104098136B