Lead paste for starting lead-acid storage battery and starting lead-acid storage battery

Abstract

The application provides a starting lead-acid storage battery lead paste and a starting lead-acid storage battery, and the starting lead-acid storage battery lead paste comprises positive lead paste and negative lead paste, the positive lead paste comprises modified cerium oxide, and the negative lead paste comprises carbon-coated strontium titanate and In2O3. The starting lead-acid storage battery lead paste provided by the application can inhibit active material shedding, significantly improve the cycle endurance of the lead-acid storage battery, delay negative electrode passivation, and improve the high-rate discharge capacity of the lead-acid storage battery at ultra-low temperature.

Description

Technical Field

[0001] This invention relates to the field of lead-acid battery technology, and in particular to a starting lead-acid battery paste and a starting lead-acid battery. Background Technology

[0002] Lead-acid batteries, as a safe and reliable starting power source, have two major drawbacks for starting applications. First, their cycle durability is limited, resulting in insufficient cycle life and a short battery life. The failure mode is the softening and shedding of the positive electrode active material, caused by the repeated expansion and contraction of PbO2 particles during charge-discharge cycles. The second drawback is low-temperature, high-rate discharge, leading to a rapid voltage drop and insufficient starting capability. The failure mode here is the formation of a passivation layer on the negative electrode plate in low-temperature environments. This is because, during low-temperature, high-rate discharge, the solubility of PbSO4 drops sharply, and the formation rate of PbSO4 far exceeds the dissolution rate, instantly reaching supersaturation. PbSO4 rapidly crystallizes into a dense insulating layer (1-2 μm thick), blocking further high-rate discharge. The lower the ambient temperature and the higher the discharge rate, the more severe the passivation phenomenon on the negative electrode plate. Summary of the Invention

[0003] In view of this, the present invention proposes a starting lead-acid battery paste and a starting lead-acid battery.

[0004] The technical solution of this invention is implemented as follows:

[0005] In a first aspect, the present invention provides a starting lead-acid battery paste, comprising a positive electrode paste and a negative electrode paste, wherein the positive electrode paste comprises modified cerium oxide and the negative electrode paste comprises carbon-coated strontium titanate and In2O3.

[0006] Based on the above technical solution, the preparation method of the modified cerium oxide further includes: S1, dispersing cerium oxide in water to obtain a suspension;

[0007] S2. Dissolve melamine in water to prepare a solution;

[0008] S3. Under stirring, the solution is added dropwise to the suspension to obtain a mixture. The mixture is stirred continuously, the solid is collected by centrifugation, and after drying, the precursor powder is obtained.

[0009] S4. The precursor powder is placed in an inert gas atmosphere, heated, kept at that temperature, and cooled to room temperature to obtain modified cerium oxide.

[0010] The modified cerium oxide prepared in this invention is nitrogen-doped graphene-coated cerium oxide. Cerium oxide forms the core, and nitrogen-doped graphene forms the outer shell. The nitrogen-doped graphene reduces the internal resistance of the electrode, ensuring that electrons can be smoothly discharged during discharge and smoothly fed in during charging, thereby improving rate performance and charge acceptance.

[0011] A flexible yet high-strength nitrogen-doped graphene shell tightly encapsulates and connects cerium oxide and surrounding active material particles, forming a mechanically stable framework that limits the excessive growth of PbSO4 crystals. During discharge, PbSO4 forms fine, uniform crystals, rather than coarse, destructive crystals. During the volume changes caused by the interconversion of PbO2 and PbSO4, the outer graphene layer absorbs and disperses stress through its elastic deformation, preventing loss of electrical contact between active material particles and collapse of the microstructure. Furthermore, nitrogen doping stabilizes the carbon lattice of graphene, increases its electrochemical oxidation potential, slows down the oxidation to CO2 process, extends the lifespan of the conductive network, improves stability, suppresses hydrogen and oxygen evolution, and helps reduce water electrolysis and grid corrosion.

[0012] Ce of cerium oxide 3+ / Ce 4+ The variable valence state and oxygen vacancies cause the positive electrode potential to rise at the end of charging, leading to oxygen evolution. Cerium oxide can capture and temporarily neutralize lattice oxygen, mitigating the oxygen evolution process, reducing its overpotential, and alleviating corrosion of the grid.

[0013] Cerium oxide stabilizes the PbO2 lattice by mitigating oxygen evolution, thus protecting the structural integrity of the active material.

[0014] Based on the above technical solution, the mass ratio of cerium oxide to melamine is further 1:(2~5).

[0015] Based on the above technical solutions, the inert atmosphere is further defined as one or both of argon and nitrogen.

[0016] Based on the above technical solution, further, the temperature rise in step S4 is increased to 600~800℃ at a rate of 5℃ / min, and the heat preservation is maintained at 600~800℃ for 2~3 hours.

[0017] Based on the above technical solution, the method for preparing carbon-coated strontium titanate further includes: A1, dispersing strontium titanate in a sucrose solution to obtain a mixed solution;

[0018] A2. React the mixture in a high-pressure reactor, cool it, centrifuge, dry it, and collect the product.

[0019] A3. The product is placed in an inert atmosphere, heated, kept at that temperature, and cooled to room temperature to obtain the carbon-coated strontium titanate.

[0020] Negative electrode passivation is due to the formation of a dense, continuous, and insulating PbSO4 layer. Carbon-coated strontium titanate can prevent the formation of this PbSO4 layer. During low-temperature, high-rate discharge, carbon-coated strontium titanate undergoes rapid double-layer charging and discharging, instantly diverting some of the current. This directly reduces the instantaneous current density on the surface of the lead active material, thus preventing Pb from passing through. 2+ The dissolution rate of ions and the formation rate of PbSO4 are slowed down, thereby delaying the passivation of the negative electrode.

[0021] The uniformly dispersed carbon-coated strontium titanate particles provide numerous inert heterogeneous nucleation sites for PbSO4 precipitation. PbSO4 tends to nucleate at these sites, promoting the formation of fine, loose, and dispersed particle aggregates rather than a dense, continuous film. The loose structure allows for continued permeation of electrolyte and ions, sustaining the reaction.

[0022] The carbon coating itself is a conductor, and the dispersed carbon-coated strontium titanate particles can be connected into a network through carbon nanotubes. Electrons can be transported through the carbon network, which slows down the voltage drop.

[0023] The introduction of carbon-coated strontium titanate reduces the hydrogen evolution overpotential, exacerbating the hydrogen evolution reaction and leading to water loss and reduced charging efficiency. Adding In₂O₃ allows it to co-deposit on the lead surface, forming an alloy layer with a high hydrogen overpotential, effectively suppressing hydrogen production and ensuring that the lead-acid battery's water circulation and charging efficiency remain at a high level.

[0024] Based on the above technical solution, the mass ratio of strontium titanate to sucrose is further 1:(1~2).

[0025] Based on the above technical solution, the reaction is further carried out at 160~180℃ for 8~12 hours.

[0026] Based on the above technical solution, further, the temperature rise in step A3 is increased to 500~600℃ at a rate of 5℃ / min, and the heat preservation is maintained at 500~600℃ for 2~3 hours.

[0027] Based on the above technical solutions, the positive electrode lead paste further includes lead powder, red lead, dilute sulfuric acid, water, short fibers and polyvinylpyrrolidone.

[0028] Based on the above technical solution, further, by weight, the positive electrode lead paste includes 0.5-2 parts modified cerium oxide, 100-120 parts lead powder, 4.5-6 parts red lead, 10-12 parts dilute sulfuric acid, 12-15 parts water, 0.8-1 parts short fiber and 0.8-1 parts polyvinylpyrrolidone.

[0029] The role of polyvinylpyrrolidone is to improve the uniformity of lead paste and prevent the agglomeration of modified cerium oxide. It also acts as a binder, helping the active material adhere more firmly to the grid, increasing electrode strength, and promoting the formation of finer, more uniformly distributed PbSO4 crystals during discharge.

[0030] Short fibers are used in both positive and negative lead pastes. Their main function is to increase the mechanical strength of the active material, prevent the lead paste from falling off, and improve the cycle life of the battery.

[0031] Based on the above technical solutions, the negative electrode lead paste further includes lead powder, carbon nanotubes, dilute sulfuric acid, water, short fibers, sodium lignosulfonate, humic acid, and barium sulfate.

[0032] Based on the above technical solution, further, by weight, the negative electrode lead paste comprises 100-120 parts lead powder, 0.5-2.5 parts carbon-coated strontium titanate, 0.01-0.05 parts carbon nanotubes, 0.05-0.25 parts In2O3, 0.05-0.1 parts short fibers, 0.01-0.05 parts humic acid, 10-12 parts dilute sulfuric acid, 12-15 parts water, 0.01-0.05 parts sodium lignosulfonate, and 0.05-0.15 parts barium sulfate.

[0033] The role of carbon nanotubes in the negative electrode is to act as a conductor, reducing impedance during discharge and improving the utilization rate of active materials.

[0034] Sodium lignosulfonate adsorbs hydrophobic groups on the surface of lead particles in the negative electrode plate, generating a repulsive force towards the electrolyte, preventing lead deposition, avoiding the reduction of its surface area, and effectively improving the low-temperature high-rate discharge performance of the battery.

[0035] Humic acid, as an additive for the negative electrode active material, can be adsorbed onto the surface of lead crystals on the negative electrode plate. This allows lead to maintain its high dispersibility, and during discharge, the formed PbSO4 cannot directly surround the lead particles, preventing the negative electrode plate from shrinking. Therefore, humic acid has a significant effect on improving the discharge capacity of the battery, especially the low-temperature discharge capacity. Humic acid also increases the overpotential of hydrogen and reduces self-discharge. Among these effects, the carboxyl groups of humic acid play an important role in the depolarization of lead-acid batteries.

[0036] The role of barium sulfate is to provide nuclei for PbSO4 deposition during battery discharge. Adding inert barium sulfate provides a large surface area for PbSO4 deposition, preventing the formation of a water-impermeable passivation layer and thus preventing electrode passivation. BaSO4 also improves the high-rate performance of the battery at low temperatures.

[0037] Based on the above technical solutions, the short fiber is further defined as either polypropylene fiber or aramid fiber.

[0038] Based on the above technical solutions, the fineness of the short fibers is further improved to 0.35-0.5D.

[0039] Secondly, the present invention also provides a lead-acid battery for starting.

[0040] Compared with the prior art, the present invention has the following beneficial effects:

[0041] The lead paste for starting lead-acid batteries provided by this invention can inhibit the shedding of active materials, significantly improve the cycle durability of lead-acid batteries, delay negative electrode passivation, and improve the high-rate discharge capability of lead-acid batteries at ultra-low temperatures. Detailed Implementation

[0042] The technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative effort are within the scope of protection of the present invention.

[0043] In the following specific implementation, polyvinylpyrrolidone was purchased from Beyotime Biotechnology Co., Ltd., with product number Y175957-100g.

[0044] In the following specific embodiments, the density of dilute sulfuric acid is 1.4 g / cm³. 3 .

[0045] Example 1

[0046] This embodiment provides a starting lead-acid battery paste, including positive lead paste and negative lead paste.

[0047] The positive electrode lead paste comprises the following components in parts by weight: 1.5 parts modified cerium oxide, 110 parts lead powder, 5 parts red lead, 11 parts dilute sulfuric acid, 14 parts deionized water, 0.9 parts polypropylene fiber, and 0.9 parts polyvinylpyrrolidone, with 1 part by weight being 1 kg.

[0048] The preparation method of modified cerium oxide includes the following steps: S1, dispersing 10g of cerium oxide in 500mL of water to obtain a suspension;

[0049] S2. Dissolve 30g of melamine in 600mL of water to prepare a solution;

[0050] S3. Under stirring, the solution is slowly added dropwise to the suspension to obtain a mixture. The mixture is stirred continuously, centrifuged at 1000 rpm for 10 min to collect the solid, and dried to obtain the precursor powder.

[0051] S4. The precursor powder is placed in an Ar atmosphere and heated to 700°C at a rate of 5°C / min, held at that temperature for 3 hours, and then cooled to room temperature to obtain modified cerium oxide.

[0052] The preparation method of the positive electrode lead paste is as follows: A1. Add lead powder and red lead to a paste mixer and mix well;

[0053] A2. Add deionized water and mix well;

[0054] A3. Add dilute sulfuric acid to adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃;

[0055] A4. Add polypropylene fiber, polyvinylpyrrolidone, and modified cerium oxide, mix evenly, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0056] The negative electrode lead paste comprises the following components in parts by weight: 110 parts lead powder, 1 part carbon-coated strontium titanate, 0.02 parts carbon nanotubes, 0.1 parts In2O3, 0.08 parts short fibers, 0.03 parts humic acid, 11 parts dilute sulfuric acid, 14 parts deionized water, 0.04 parts sodium lignosulfonate, and 0.1 parts barium sulfate, where 1 part by weight is 1 kg.

[0057] The method for preparing carbon-coated strontium titanate includes the following steps: wherein the sucrose solution is obtained by dissolving 15g of sucrose in 100mL of water.

[0058] C1. Disperse 10g of strontium titanate in a sucrose solution to obtain a mixed solution;

[0059] C2. The mixed solution was reacted in a high-pressure reactor at 170°C for 10 h. After cooling to room temperature, it was centrifuged at 1000 rpm for 10 min, dried, and the product was collected.

[0060] C3. The product is placed in an Ar atmosphere and heated to 550°C at a rate of 5°C / min, held at that temperature for 3 hours, and then cooled to room temperature to obtain the carbon-coated strontium titanate.

[0061] The preparation method of the negative electrode lead paste is as follows: B1. Add lead powder to the paste mixer and mix well;

[0062] B2. Add deionized water and mix well.

[0063] B3. Add dilute sulfuric acid and adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃.

[0064] B4. Add aramid fiber, carbon-coated strontium titanate, carbon nanotubes, humic acid, sodium lignosulfonate, barium sulfate, and In2O3, mix well, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0065] Example 2

[0066] This embodiment provides a starting lead-acid battery paste, including positive lead paste and negative lead paste.

[0067] The positive electrode lead paste comprises the following components in parts by weight: 0.5 parts modified cerium oxide, 100 parts lead powder, 4.5 parts red lead, 10 parts dilute sulfuric acid, 12 parts deionized water, 0.8 parts polypropylene fiber, and 0.8 parts polyvinylpyrrolidone, with 1 part by weight being 1 kg.

[0068] The preparation method of modified cerium oxide includes the following steps: S1, dispersing 10g of cerium oxide in 500mL of water to obtain a suspension;

[0069] S2. Dissolve 20g of melamine in 600mL of water to prepare a solution;

[0070] S3. Under stirring, the solution is slowly added dropwise to the suspension to obtain a mixture. The mixture is stirred continuously, centrifuged at 1000 rpm for 10 min to collect the solid, and dried to obtain the precursor powder.

[0071] S4. The precursor powder is placed in an Ar atmosphere and heated to 600°C at a rate of 5°C / min, held at that temperature for 2 hours, and then cooled to room temperature to obtain modified cerium oxide.

[0072] The preparation method of the positive electrode lead paste includes the following steps: A1. Add lead powder and red lead to a paste mixer and mix well;

[0073] A2. Add deionized water and mix well;

[0074] A3. Add dilute sulfuric acid to adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃;

[0075] A4. Add polypropylene fiber, polyvinylpyrrolidone, and modified cerium oxide, mix evenly, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0076] The negative electrode lead paste comprises the following components in parts by weight: 100 parts lead powder, 0.5 parts carbon-coated strontium titanate, 0.01 parts carbon nanotubes, 0.05 parts In2O3, 0.05 parts short fibers, 0.01 parts humic acid, 10 parts dilute sulfuric acid, 12 parts deionized water, 0.01 parts sodium lignosulfonate, and 0.05 parts barium sulfate, with 1 part by weight being 10 kg.

[0077] The method for preparing carbon-coated strontium titanate includes the following steps: wherein the sucrose solution is obtained by dissolving 20g of sucrose in 100mL of water.

[0078] C1. Disperse 10g of strontium titanate in a sucrose solution to obtain a mixed solution;

[0079] C2. The mixed solution was reacted in a high-pressure reactor at 160°C for 8 hours. After cooling to room temperature, it was centrifuged at 1000 rpm for 10 minutes, dried, and the product was collected.

[0080] C3. The product is placed in an Ar atmosphere and heated to 500°C at a rate of 5°C / min, held at that temperature for 2 hours, and then cooled to room temperature to obtain the carbon-coated strontium titanate.

[0081] The preparation method of the negative electrode lead paste is as follows: B1. Add lead powder to the paste mixer and mix well;

[0082] B2. Add deionized water and mix well.

[0083] B3. Add dilute sulfuric acid and adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃.

[0084] B4. Add aramid fiber, carbon-coated strontium titanate, carbon nanotubes, humic acid, sodium lignosulfonate, barium sulfate, and In2O3, mix well, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0085] Example 3

[0086] This embodiment provides a starting lead-acid battery paste, including positive lead paste and negative lead paste.

[0087] The positive electrode lead paste comprises the following components in parts by weight: 2 parts modified cerium oxide, 120 parts lead powder, 6 parts red lead, 12 parts dilute sulfuric acid, 15 parts deionized water, 1 part polypropylene fiber, and 1 part polyvinylpyrrolidone, with 1 part by weight being 1 kg.

[0088] The preparation method of modified cerium oxide includes the following steps: S1, dispersing 10g of cerium oxide in 500mL of water to obtain a suspension;

[0089] S2. Dissolve 50g of melamine in 600mL of water to prepare a solution;

[0090] S3. Under stirring, the solution is slowly added dropwise to the suspension to obtain a mixture. The mixture is stirred continuously, centrifuged at 1000 rpm for 10 min to collect the solid, and dried to obtain the precursor powder.

[0091] S4. The precursor powder is placed in an Ar atmosphere and heated to 800°C at a rate of 5°C / min, held at that temperature for 2.5 hours, and then cooled to room temperature to obtain modified cerium oxide.

[0092] The preparation method of the positive electrode lead paste is as follows: A1. Add lead powder and red lead to a paste mixer and mix well;

[0093] A2. Add deionized water and mix well;

[0094] A3. Add dilute sulfuric acid to adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃;

[0095] A4. Add polypropylene fiber, polyvinylpyrrolidone, and modified cerium oxide, mix evenly, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0096] The negative electrode lead paste comprises the following components in parts by weight: 120 parts lead powder, 2.5 parts carbon-coated strontium titanate, 0.05 parts carbon nanotubes, 0.25 parts In2O3, 0.1 parts short fibers, 0.05 parts humic acid, 12 parts dilute sulfuric acid, 15 parts deionized water, 0.05 parts sodium lignosulfonate, and 0.15 parts barium sulfate, where 1 part by weight is 1 kg.

[0097] The method for preparing carbon-coated strontium titanate includes the following steps: wherein the sucrose solution is obtained by dissolving 10g of sucrose in 100mL of water.

[0098] C1. Disperse 10g of strontium titanate in a sucrose solution to obtain a mixed solution;

[0099] C2. The mixed solution was reacted in a high-pressure reactor at 180°C for 12 hours. After cooling to room temperature, it was centrifuged at 1000 rpm for 10 minutes, dried, and the product was collected.

[0100] C3. The product is placed in an Ar inert atmosphere and heated to 600°C at a rate of 5°C / min, held at that temperature for 2.5 hours, and then cooled to room temperature to obtain the carbon-coated strontium titanate.

[0101] The preparation method of the negative electrode lead paste is as follows: B1. Add lead powder to the paste mixer and mix well;

[0102] B2. Add deionized water and mix well;

[0103] B3. Add dilute sulfuric acid and adjust the negative pressure of the paste mixer to 180 mbar and the temperature to 60℃.

[0104] B4. Add aramid fiber, carbon-coated strontium titanate, carbon nanotubes, humic acid, sodium lignosulfonate, barium sulfate, and In2O3, mix well, cool to room temperature, and dispense the paste to obtain positive electrode lead paste.

[0105] Example 4

[0106] This embodiment provides a starting lead-acid battery, which includes uniformly coating the positive electrode lead paste and negative electrode lead paste prepared in Example 1 onto the grid as the positive electrode plate and negative electrode plate, respectively.

[0107] Comparative Example 1

[0108] The difference between this comparative example and Example 1 is that the positive electrode lead paste does not contain modified cerium oxide.

[0109] Comparative Example 2

[0110] The difference between this comparative example and Example 1 is that the negative electrode lead paste does not contain carbon-coated strontium titanate.

[0111] Comparative Example 3

[0112] The difference between this comparative example and Example 1 is that the negative electrode lead paste does not contain In2O3.

[0113] Comparative Example 4

[0114] The difference between this comparative example and Example 1 is that the modified cerium oxide is in the amount of 5 parts by weight.

[0115] Comparative Example 5

[0116] The difference between this comparative example and Example 1 is that the weight of carbon-coated strontium titanate is 5 parts.

[0117] Comparative Example 6

[0118] The difference between this comparative example and Example 1 is that the weight of In2O3 is 5 parts.

[0119] Performance testing

[0120] 1. The positive and negative lead pastes prepared in Examples 1-3 and Comparative Examples 1-6 were uniformly coated onto the lead-calcium alloy positive and negative electrode grids, respectively, using a coating density of 1.25 g / cm³. 3 Sulfuric acid was used as the electrolyte to prepare a starting lead-acid battery. A 40% DOD cycle durability test was conducted according to the test methods and standard requirements of GJB 1724A-2009. The test results are shown in Table 1.

[0121] Table 1. Cycle Durability Number of Examples and Comparative Examples

[0122]

[0123] 2. The positive and negative lead pastes prepared in Examples 1-3 and Comparative Examples 1-6 were uniformly coated onto the lead-calcium alloy positive and negative electrode grids, respectively, using a coating density of 1.25 g / cm³. 3 Using sulfuric acid as the electrolyte, a starting lead-acid battery with a rated voltage of 24V (12 cells in series) and a rated capacity of 130Ah was prepared. A high-rate discharge capability test at ultra-low temperature (-40℃) was conducted. The testing methods and standards are shown below, and the test results are shown in Table 2.

[0124] Test method: Place the fully charged battery in a -40℃ low temperature chamber for 24 hours, and then discharge it with a constant current of 390A for 75 seconds.

[0125] The standard requires that the voltage be no less than 14.4V after 30 seconds of discharge and no less than 12.0V after 75 seconds of discharge.

[0126] Table 2. Test results of ultra-low temperature high-rate discharge capability of the examples and comparative examples.

[0127]

[0128] As shown in Tables 1 and 2, the lead-acid batteries prepared using the positive and negative electrode pastes of this invention have a high cycle life and a large number of cycle cycles. They also exhibit excellent performance in high-rate discharge at ultra-low temperatures.

[0129] As can be seen from the comparison of Example 1 and the comparative example, when modified cerium oxide, carbon-coated strontium titanate, and In2O3 are not present, the cycle life and ultra-low temperature high-rate discharge performance of lead-acid batteries are significantly reduced.

[0130] When excessive amounts of modified cerium oxide, carbon-coated strontium titanate, and In₂O₃ are used, the cycle life and ultra-low temperature high-rate discharge performance of lead-acid batteries all decrease significantly. This is because excessive use of carbon-coated strontium titanate reduces the amount of active lead material per unit volume, leading to a decrease in the battery's initial capacity, potentially increased internal resistance, and altered pore structure of the lead paste. Excessive use of In₂O₃ increases side reactions, exacerbates self-discharge, and alters the structure of the active material. Excessive use of modified cerium oxide leads to a decrease in initial capacity and energy density, increased battery internal resistance, damage to electrode microstructure, and exacerbation of side reactions.

[0131] In summary, lead-acid batteries using the positive electrode paste of this invention as raw material are less prone to detachment and failure during cyclic charging and discharging, significantly improving their cycle life. Lead-acid batteries using the negative electrode paste of this invention as raw material are less prone to passivation of the negative electrode plate during ultra-low temperature, high-rate discharge, leading to starting failure. The battery discharge voltage platform is high, stable, and reliable, solving the problem of batteries struggling to release energy in low-temperature environments.

[0132] The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc., made within the spirit and principles of the present invention should be included within the protection scope of the present invention.

Claims

1. A starting lead-acid battery paste, characterized in that, It includes positive electrode lead paste and negative electrode lead paste, wherein the positive electrode lead paste includes modified cerium oxide, and the negative electrode lead paste includes carbon-coated strontium titanate and In2O3; The method for preparing the modified cerium oxide includes: S1, dispersing cerium oxide in water to obtain a suspension; S2. Dissolve melamine in water to prepare a solution; S3. Under stirring, the solution is added dropwise to the suspension to obtain a mixture. The mixture is stirred continuously, the solid is collected by centrifugation, and after drying, the precursor powder is obtained. S4. The precursor powder is placed in an inert gas atmosphere, heated, kept at the temperature, and cooled to room temperature to obtain modified cerium oxide. By weight, the positive electrode lead paste comprises 0.5-2 parts modified cerium oxide, 100-120 parts lead powder, 4.5-6 parts red lead, 10-12 parts dilute sulfuric acid, 12-15 parts water, 0.8-1 parts short fiber and 0.8-1 parts polyvinylpyrrolidone. By weight, the negative electrode lead paste comprises 100-120 parts lead powder, 0.5-2.5 parts carbon-coated strontium titanate, 0.01-0.05 parts carbon nanotubes, 0.05-0.25 parts In2O3, 0.05-0.1 parts short fibers, 0.01-0.05 parts humic acid, 10-12 parts dilute sulfuric acid, 12-15 parts water, 0.01-0.05 parts sodium lignosulfonate, and 0.05-0.15 parts barium sulfate.

2. The lead paste for starting lead-acid batteries as described in claim 1, characterized in that, The method for preparing carbon-coated strontium titanate includes: A1, dispersing strontium titanate in a sucrose solution to obtain a mixed solution; A2. React the mixture in a high-pressure reactor, cool it, centrifuge, dry it, and collect the product. A3. The product is placed in an inert atmosphere, heated, kept at that temperature, and cooled to room temperature to obtain the carbon-coated strontium titanate.

3. A starting lead-acid battery, characterized in that, The lead paste for the starting lead-acid battery is the lead paste for the starting lead-acid battery as described in any one of claims 1 to 2.

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