Compositions comprising triglycerides

Abstract

The present invention relates to a composition comprising certain triglycerides having a low content of cyclopropene-based fatty acid (CPFA) acyl groups and tocopherols, as well as the use of such a composition, especially in cosmetic applications, and a method of treating baobab oil.

Description

Invention Field

[0001] This invention relates to a composition comprising a low content of certain triglycerides having cyclopropene fatty acid (CPFA) acyl groups while maintaining a high tocopherol content, and the use of such a composition, particularly in cosmetic applications, and a method for processing baobab oil. Existing technology

[0002] Baobab oil is used in the cosmetics industry due to its care, skin-soothing, moisturizing, and antioxidant properties.

[0003] It is extracted from the seeds of the baobab tree fruit. Baobab oil obtained by pressing the seeds typically contains 5-7% triglycerides with cyclopropene fatty acid (CPFA) acyl groups.

[0004] Due to its potential toxicity, it is rarely used in the food industry and only to a very limited extent in the cosmetics industry, as it releases toxic cyclopropene fatty acids through the hydrolysis of triglycerides.

[0005] In commercially available baobab oil products, the content of triglycerides with cyclopropene fatty acid acyl groups is generally unchanged compared to natural oils. Heat treatment (possibly in combination with steam) of baobab oil can destroy the CPFA acyl groups, but it also reduces the residual amounts of vitamins, other tocopherols, and phytosterols, which have value as active ingredients. Therefore, in refined and even deodorized variants of baobab oil, the content of triglycerides with cyclopropene fatty acid acyl groups is generally reduced, but still remains at a toxicologically critical level greater than 1%. Furthermore, drastic temperature treatments often result in the formation of polycyclic aromatic hydrocarbons (PAHs), which are known to be carcinogenic in some cases.

[0006] Typical procedures for the development and purification of triglycerides are described in the chapter “Fats and Fatty Oils” of Ullmann’s Encyclopedia of Industrial Chemistry, by Alfred Thomas, Bertrand Matthäus, and Hans-Jochen Fiebig, published on September 30, 2015.

[0007] Therefore, the object of the present invention is to provide a baobab oil, particularly for use in the cosmetics industry, which has a significantly lower content of triglycerides with cyclopropene fatty acid acyl groups, but still contains a large amount of tocopherol, which is beneficial for oxidative stability.

[0008] Invention Description Surprisingly, it was discovered that the shortcomings of the prior art can be overcome by subjecting the baobab oil to a certain temperature treatment while allowing water vapor to pass through it.

[0009] The present invention therefore provides a composition comprising a low content of triglycerides having certain cyclopropene fatty acid (CPFA) acyl groups and a high content of tocopherols, and uses of such a composition, particularly in cosmetic applications, and a method for processing baobab oil.

[0010] One advantage of the present invention is that the baobab oil according to the invention has reduced potential toxicity.

[0011] One advantage of the present invention is that the baobab oil according to the invention has high viscosity.

[0012] One advantage of this invention is that the baobab oil according to the invention has a more moisturizing feel on the skin.

[0013] One advantage of this invention is that the baobab oil according to the invention has a more pronounced velvety feel on the skin.

[0014] One advantage of the present invention is that the baobab oil according to the invention has higher oxidative stability.

[0015] One advantage of this invention is that the baobab oil according to the invention provides improved stability for cosmetic formulations.

[0016] One advantage of the present invention is that the baobab oil according to the invention has a more neutral odor.

[0017] This invention includes a composition comprising The triglyceride mixture has the following distribution of fatty acid acyl groups in its triglycerides: 18% to 34% by weight, preferably 20% to 30% by weight, more preferably 21% to 28% by weight of palmitoyl group. 0.5% to 10% by weight, preferably 1.0% to 9.0% by weight, more preferably 2.0% to 7.0% by weight of stearoyl group. 28% to 44% by weight, preferably 30% to 42% by weight, more preferably 31% to 41% by weight of oleoyl group. 18% to 34% by weight, preferably 21% to 31% by weight, more preferably 22% to 30% by weight of linoleyl group. The total amount is less than 1.0% by weight, preferably 0.01% to 0.7% by weight, more preferably 0.05% to 0.4% by weight of cyclopropylene fatty acid acyl groups. The weight percentages mentioned herein are calculated based on the total number of fatty acid acyl groups contained in all triglycerides included in the composition. The composition is characterized by comprising The tocopherol concentration is 100 ppm to 2000 ppm, preferably 200 ppm to 1500 ppm, more preferably 300 ppm to 1250 ppm, and most preferably 400 ppm to 1100 ppm, wherein the ppm is based on the total composition.

[0018] Unless otherwise stated, all percentages (%) given are mass percentages, which also apply to parts per million (ppm) and parts per billion (ppb).

[0019] In the compositions according to the invention, the most abundant cyclopropene fatty acid acyl groups are those of sterol [8-(2-octyl-1-cyclopropenyl)octanoic acid] and malvidic acid [7-(2-octyl-1-cyclopropenyl)heptanoic acid].

[0020] After complete saponification of triglycerides, the CPFA content was analyzed by GC. ISO 15884 is the preferred method. Another suitable method is described in "Upendo L. Msalilwa, Edna E. Makule, Linus K. Munishi, Patrick A. Ndakidemi, Physicochemical Properties, Fatty Acid Composition, and the Effect of Heating on the Reduction of Cyclopropenoid Fatty Acids on Baobab (Adansonia digitata L.) Crude Seed Oil. Journal of Lipids 2020, 1-13".

[0021] The term "tocopherol" in the context of this invention includes α-tocopherol, β-tocopherol, γ-tocopherol, and δ-tocopherol. Their respective molecular structures are based on "Kolter T, Tocopherole, RD-20-01995 (2011) in Böckler F.; Dill, RÖMPP [online], Stuttgart, Georg Thieme Verlag [September 2023]".

[0022] The amount of tocopherol in the composition was determined by HPLC. The appropriate method is described in "AM Lampi, Analysis of tocopherols and tocotrienols by HPLC, Selected Topics in the Analysis of Lipids, The AOCS lipid library, 2011".

[0023] Due to the structural similarity (same molecular weight and polarity) of β-tocopherol and γ-tocopherol, their amounts were determined as the sum of the two substances.

[0024] The main tocopherol content in the compositions according to the invention is preferably attributed to β-tocopherol and γ-tocopherol.

[0025] The preferred composition according to the invention comprises a total of less than 100 ppb, preferably 0.1 to 60 ppb, more preferably 0.5 to 25 ppb, and most preferably 1.0 to 10 ppb of polycyclic aromatic hydrocarbons (PAHs) selected from phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, and benzo(a)pyrene, wherein the ppb is based on the total composition.

[0026] A suitable method for analyzing PAHs in oils is described in “H. Ekner, K. Dreij, I. Sadiktsis, Determination of polycyclic aromatic hydrocarbons in commercial olive oils by HPLC / GC / MS – Occurrence, composition and sources. Food Control 2022, 132, 108528”.

[0027] The preferred composition according to the invention comprises The triglyceride mixture has the following distribution of fatty acid acyl groups in its triglycerides: 21% to 28% by weight palmitoyl group, 2.0% to 7.0% by weight of stearoyl group, 31% to 41% by weight of oleoyl group, 22% to 30% by weight of linoleyl group, 0.01% to 0.5% by weight, more preferably 0.05% to 0.4% by weight of cyclopropylene fatty acid acyl groups, The weight percentages mentioned herein are calculated based on the total number of fatty acid acyl groups contained in all triglycerides included in the composition. The composition is characterized by comprising Tocopherols in the range of 400 ppm to 1100 ppm, preferably distributed as at least 20 ppm of α-tocopherol, a total of at least 350 ppm of β-tocopherol and γ-tocopherol, and at least 30 ppm of δ-tocopherol, and Benzo(a)pyrene with a concentration less than 2 ppb, The ppm and ppb values ​​are used as a reference for the total composition.

[0028] The preferred composition according to the invention is characterized in that the composition has a triglyceride content of 90% to 99.95% by weight, preferably 95% to 99.92% by weight, wherein the weight percentage is based on the total composition.

[0029] The preferred composition according to the invention is characterized in that it has an iodine value of 70.0 g I / 100 g to 100 g I / 100 g, preferably 75.0 g I / 100 g to 95.0 g I / 100 g.

[0030] In the context of this invention, a suitable method for determining iodine value is EN 14111:2003.

[0031] The preferred composition according to the invention is characterized by having an acid value between 0.01 mg KOH / g and 8.0 mg KOH / g, preferably between 0.02 mg KOH / g and 2.0 mg KOH / g.

[0032] Suitable methods for determining acid value, especially those according to DGF CV 2, DIN EN ISO 2114, Ph. Eur. 2.5.1, ISO 3682 and ASTM D 974.

[0033] The preferred composition according to the invention is characterized by having a saponification value between 175 mg KOH / g and 210 mg KOH / g, preferably between 180 mg KOH / g and 205 mg KOH / g.

[0034] Suitable test methods for determining saponification value, especially those according to DGF CV 3, DIN EN ISO 3681 and Ph.Eur. 2.5.6.

[0035] According to the present invention, the composition of the present invention preferably has a viscosity of 71 mPas to 200 mPas, more preferably 72 mPas to 175 mPas, more preferably 73 mPas to 150 mPas, and most preferably 74 mPas to 140 mPas at 25°C.

[0036] A suitable method for determining viscosity is to use a rheometer (MCR 302, Anton Paar Germany) with a plate-to-plate measurement system covering a shear rate range of 0.1–100 s⁻¹. The upper plate has a diameter of 40 mm, a gap distance of 0.5 mm, and the measurement temperature is 25 °C.

[0037] The preferred compositions according to the invention are characterized in that they do not contain cosmetic preservatives, especially not any one selected from phenoxyethanol, parabens, isothiazolinones and benzyl alcohol.

[0038] The composition according to the invention is preferably obtained by the following method; the invention further provides a method for processing baobab oil, comprising the following steps: A) Provide baobab oil, B) The baobab oil is heated and maintained at a temperature within the range of 90°C to 270°C, preferably 190°C to 250°C, and more preferably 200°C to 230°C. C) Pass water vapor through the baobab oil, preferably continuously.

[0039] In the method of the present invention, any kind of baobab oil can be provided, and the baobab oil can be unrefined or refined.

[0040] In a preferred method according to the invention, the baobab oil is provided in step A) by separating the oil from the baobab seeds, preferably by cold pressing.

[0041] In the context of this invention, the term "cold pressing" refers to a temperature range of 1 to 80°C, preferably ambient temperature, where no additional heat is provided during the pressing process. More preferably, this temperature range is 10°C to 48°C, where the temperature is measured in a cool place.

[0042] In step A), it is preferable to refine and bleach the crude oil before starting step B).

[0043] The preferred method according to the invention is characterized in that, in step B), the temperature is maintained within the range for a period of 0.1 hours to 24 hours, preferably 0.3 hours to 15 hours, and more preferably 1 hour to 12 hours.

[0044] Preferably, in the method according to the invention, method step C) is performed in parallel with method step B).

[0045] The preferred method according to the invention is characterized in that the time period of method step C) corresponds to at least 80%, more preferably 90% to 100%, of the time period in which the temperature is maintained within the range of method step B).

[0046] A more preferred method according to the invention is characterized in that step C) is performed under reduced pressure, and therefore at less than 1 atm. The preferred pressure range is 0.1 to 200 mbar, more preferably 0.5 to 100 mbar, and most preferably 1 to 50 mbar.

[0047] The preferred method according to the invention is characterized in that, in step C), the water vapor is passed through the baobab oil at a rate of 0.05 to 2.5 wt% per hour, preferably 0.1 to 1.5 wt% per hour, more preferably 0.15 to 1.0 wt% per hour, and most preferably 0.2 to 0.6 wt% per hour, preferably in a batch process, wherein the weight percentage of water vapor is relative to the amount of oil processed.

[0048] When applied to skin and / or hair, the compositions according to the invention have many beneficial properties: It is quickly absorbed without burdening the skin and hair, and leaves no greasy shine. It softens and nourishes all types of skin and hair very well.

[0049] It helps restore the skin's lipid barrier, increases skin elasticity, and has anti-aging and antioxidant properties. It leaves skin velvety and improves plumpness. It also helps combat scars and stretch marks, and can prevent stretch marks from forming during pregnancy. It soothes sunburned skin and relieves irritation. It alleviates rosacea.

[0050] It can be used as part of a conditioning preparation for chemically treated, dry, and frizzy hair that requires extensive conditioning before straightening.

[0051] It improves the appearance of split ends and restores a healthy shine to hair and nails.

[0052] Therefore, it is ideal for caring for sensitive and irritated skin, for repairing and strengthening nails, for treating excessive dryness, brittleness and cracking of hair, and for healing skin cracks and preventing scarring.

[0053] Therefore, the present invention further provides the use of the compositions according to the invention in the preparation of cosmetic formulations, dermatological formulations, feed, food and / or pharmaceutical formulations, preferably for topical application, especially cosmetic formulations for topical application.

[0054] In a preferred embodiment according to the invention, at least one additional component, selected from [a specific ingredient], is used concurrently during the preparation of the formulation. Moisturizer Emulsifier, Thickener / viscosity modifier / stabilizer UV protection filter Antioxidants Water-soluble growth promoters Solids and fillers Film-forming agent, Pearlescent additives Deodorizing and antiperspirant active ingredients, Insect repellent, Tanning agent, Conditioner, essence, dye, Odor absorbent Superfatting agents. Other solvents.

[0055] Substances that can be used as exemplary representatives of the various categories are known to those skilled in the art and can be found, for example, in German application DE 102008001788.4. This patent application is incorporated herein by reference and thus constitutes a part of this disclosure.

[0056] For further optional components and the amounts of these components, please refer to relevant manuals known to those skilled in the art, such as K. Schrader, “Grundlagen und Rezepturen der Kosmetika [Cosmetics -fundamentals and formulations]”, 2nd edition, pp. 329-341, Hüthig Buch VerlagHeidelberg.

[0057] The amount of a particular additive depends on its intended use.

[0058] Typical boundary formulations used for their respective applications are known prior art and are contained in, for example, manufacturer's manuals for specific base materials and active ingredients. These existing formulations can generally be used unchanged. However, if necessary, modifications can be made without complexity for adjustment and optimization through simple trials.

[0059] The embodiments cited below illustrate the present invention, but are not intended to limit the invention to the implementations specified in the embodiments. The scope of the invention is apparent from the entire specification and claims.

[0060] Example: Example 1: A triglyceride-containing composition according to the present invention Cold-pressed and refined baobab oil was heated to 210°C, and water vapor was passed through it under reduced pressure at a rate of 0.5% / h relative to the oil volume. After 10 hours, the oil was cooled to 25°C. The product contained had a viscosity of 79.7 mPa·s, a tocopherol content of 956 ppm (72 ppm α-tocopherol, 765 ppm β-tocopherol + γ-tocopherol and 119 ppm δ-tocopherol), a total cyclopropene fatty acid content of 0.29% (0.22% malonic acid and 0.07% sterolic acid), and a total content of 1.5 ppb of phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthene, β, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, and benzo(a)pyrene.

[0061] Example 2: Compositions containing triglycerides not according to the present invention Cold-pressed crude baobab oil, having a viscosity of 67.5 mPa s at 25°C, a tocopherol content of 803 ppm (26 ppm α-tocopherol, 739 ppm β-tocopherol + γ-tocopherol and 38 ppm δ-tocopherol), a total cyclopropene fatty acid content of 6.1% (4.9% malonic acid and 1.2% malonic acid), and a total content of 8.4 ppb of phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthene, β, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene, serves as an example outside the scope of this invention.

[0062] Example 3: Compositions containing triglycerides not according to the present invention Commercially available cold-pressed and refined baobab oil, with a viscosity of 70.3 mPa·s at 25°C, a tocopherol content of 312 ppm (10 ppm α-tocopherol, 283 ppm β-tocopherol + γ-tocopherol and 19 ppm δ-tocopherol) and a total cyclopropene fatty acid content of 1.4% (1.1% malonic acid and 0.3% sterculic acid), serves as an example outside the scope of this invention.

[0063] Example 4: Compositions containing triglycerides not according to the present invention Cold-pressed and refined baobab oil was heated to 250°C, and water vapor was passed through it under reduced pressure at a rate of 5.0% / h relative to the oil volume. After 1.5 hours, the oil was cooled to 25°C. The products contained 59 ppm of tocopherols, 1.07% of total cyclopropene fatty acids (0.85% malonic acid and 0.22% sterolic acid), and 231 ppb of total phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthene, β, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, and benzo(a)pyrene.

[0064] Example 5: Oxidative Stability Test The oxidative stability of samples was measured at 120°C using the 892 Professional Rancimat according to its manual (version 8.892.8001EN / 2020-03-11). During the measurement, the oxidative decomposition of oils and fats can be monitored. Air is passed through the sample in the reaction vessel at 120°C. Fatty acids are oxidized. At the end of the test, volatile secondary reaction products are formed, which are conveyed to the measurement vessel by the air stream and absorbed into the test solution (deionized water). Due to the absorption of the reaction products, the conductivity of the continuously recorded test solution increases. This allows for the detection of their appearance. The time taken to detect the secondary reaction products is called the induction time. It characterizes the oxidative stability of oils and fats; the higher the induction time, the higher the oxidative stability. Induction time in h Example 1, according to the present invention 5.7 Example 2, not based on the present invention 4.3

[0065] The compositions according to the present invention have higher oxidative stability than compositions not according to the present invention.

[0066] Example 6: Storage stability of waterless soap bars, figures given are by weight percentage:

[0067] The above findings are quite surprising, as soap bars contain a large amount of other oils; however, the compositions of the present invention have beneficial storage effects.

[0068] Example 7: Viscosity of the cream, the figures given are by weight percentage: INCI Cream 1, according to the present invention, w-% Cream 2, not according to the present invention, w-% A Polyglycerol-4 diisostearate / polyhydroxystearate / sepiacetate 1.5 1.5 Wax paste* 0.7 0.7 Baobab (Adansonia digitata) seed oil, according to the present invention (Example 1) 20 Baobab (Adansonia digitata) seed oil, not according to the present invention (Example 2). 20 B water 73.8 73.8 glycerin 3 3 Magnesium sulfate 1 1 *wax paste Hydrogenated castor oil 7.50% Paraffin (and) microcrystalline wax 7.50% Ethylhexyl palmitate 85.00%

[0069] Processing Spread the wax paste evenly in the oil phase using MIG at 450 rpm for >2 minutes.

[0070] Add B to A and stir at 450 rpm for 2 minutes.

[0071] Homogenize at 1500 rpm for 3 minutes (using MIG, 2 blades).

[0072] Pour the emulsion into a 2,100 mL wide-mouth bottle.

[0073] Viscosity was measured using a Brookfield DV-I viscometer with rotor C that runs at 10 RPM after 10 seconds. Cream 1, according to the present invention Cream 2, not according to the present invention Viscosity 51 47

[0074] Example 8: Skin feel of the cream: The cream of Example 6 was evaluated by a trained sensory review panel. At least five people assessed the sensory characteristics of the formulation without knowing the composition of the sample being evaluated. The properties described by most panel members are reported in the table below: Cream 1, according to the present invention Cream 2, not according to the present invention plumpness on the skin During distribution: Easy to distribute; 5 minutes after absorption: Moderate absorption, leaving skin feeling rich and cared for. During distribution: Easy to distribute; 5 minutes after absorption: High absorption, moderately light skin feel.

[0075] Example formulation: The following examples demonstrate the suitability of baobab oil in various cosmetic formulations and its compatibility with a variety of other ingredients that are typically challenging to formulate, such as emulsifiers, stabilizers, preservatives, or active compounds such as UV filters or antimicrobial agents. The application of this invention is not limited to the formulations shown. The preparation of the examples was carried out according to commonly used standard methods.

[0076] Natural body spray Mutually Element w / w-% w / w-% w / w-% w / w-% A TEGO® Care LTP (Sorbitol Laurate; Polyglycerol-4 Laurate; Dilauryl Citrate) 2.50 3.00 TEGO® Care PBS 6 (Polyglycerol-6 stearate; Polyglycerol-6 betaine) 3.00 3.00 Example 1 12.50 14.00 12.00 9.50 B water Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 4.00 Gelcogel (CG-HA, CP Kelco) 0.10 0.10 0.10 0.15 C dermsosoft® OMP (Methylpropanediol; Octylethylene Glycol; Phenylacetyl Alcohol) 2.50 2.50 2.50 2.50

[0077] W / O Cream

[0078] Anti-aging day cream Mutually Element w / w-% w / w-% w / w-% w / w-% A ABIL® EM 90 (Cetyl PEG / PPG-10 / 1 Polydimethylsiloxane Triglyceride) 3.00 3.00 ABIL® EM 180 (Cetyl PEG / PPG-10 / 1 Polydimethylsiloxane Triglyceride) 2.00 ABIL® WE 09 (Polyglycerol-4 isostearate; cetyl PEG / PPG-10 / 1 polydimethylsiloxane; hexyl laurate) 4.00 TEGOSOFT® AC (Isoamyl Cocoate) 5.00 5.00 4.00 5.00 TEGOSOFT® DEC (Diethylhexyl carbonate) 6.00 6.00 5.00 5.00 Example 1 7.00 2.00 10.00 8.00 HyaCare® Filler CL (Water, Ethylhexyl Stearate, Sodium Hyaluronate Crosspolymer, Polyglycerol-4 Diisostearate / Polyhydroxystearate / Sebacate, Sodium Isostearate) 2.50 2.50 2.50 2.50 Tocopherol 0.50 0.50 0.50 0.50 Methyl methacrylate crosspolymer (Covabead LH 85, Sensient) 2.00 2.00 2.00 2.00 B water Add to 100 Add to 100 Add to 100 Add to 100 Sodium chloride 0.80 0.80 0.80 0.80 glycerin 4.00 4.00 4.00 4.00 Butylene glycol 4.00 4.00 4.00 4.00 TEGO® Pep 4-Even (Tetrapeptide-30; Glycerin) 2.50 2.50 2.50 2.50 Sodium ascorbate palmitate 1.50 1.50 1.50 1.50 Urea 2.50 2.50 2.50 2.50 Sodium bisulfite 0.10 0.10 0.10 0.10 Z Preservatives, fragrances qs qs qs qs

[0079] Light & Caring Cream

[0080] Serum Mutually Element w / w-% A TEGO® Care 165 (Glyceryl stearate; PEG-100 stearate) 3.00 TEGO® Alkanol 18 (Stearyl alcohol) 0.50 Isononyl isononanoate 4.00 Hydrogenated polyisobutylene 3.00 TEGOSOFT® APM (PPG-3 myristyl ether) 3.00 Example 1 0.50 Tocopherol 0.50 B water Add to 100 Butylene glycol 5.00 SKINMIMICS® (Cetearyl alcohol polyether-25; Glycerin; Cetyl alcohol; Betaine acid; Cholesterol; Ceramide NP; Ceramide NS; Ceramide EOS; Ceramide EOP; Ceramide AP; Hexanoyl phytosphingosine; Hexanoyl sphingosine) 2.50 C Polyacrylamide; C13-14 isoparaffins; Lauryl alcohol polyether-7 (Sepigel 305, Seppic) 0.75 Z Preservatives, fragrances qs

[0081] Body cream Mutually raw material w / w % A Dermofeel NC (Polyglycerol-3 distearate; Glyceryl stearate citrate) 4.00 <![CDATA[Tego ® Alkanol 18 (stearyl alcohol) 1.50 <![CDATA[Tegosoft ® CT (Caprylic / Capric Triglyceride) 4.50 Example 1 8.50 Tocopherol 0.50 Varisoft® TA 100 (Distearate Dimethyl Ammonium Chloride) 2.50 HyaCare 50 (Hydrolyzed Hyaluronic Acid) 0.20 B water Up to 100 glycerin 7.00 <![CDATA[Skinmimics ® (Cetearyl alcohol polyether-25; Glycerin; Cetyl alcohol; Succinic acid; Cholesterol; Ceramide NP; Ceramide NS; Ceramide EOS; Ceramide EOP; Ceramide AP; Hexanoyl phytosphingosine; Hexanoyl sphingosine) 1.50 C Xanthan Gum 0.50 Z Preservatives, fragrances qs

[0082] Rich natural cream Mutually Element w / w-% w / w-% w / w-% w / w-% A TEGO® Care PSC 3 (Polyglycerol-3 dicitrate / stearate) 3.00 Symbiomuls GC (Glyceryl stearate citrate; cetearyl alcohol; caprylic / caprylic glyceride) 3.50 Dermofeel NC (polyglycerol-3 distearate (and) glyceryl stearate citrate) 2.50 3.00 TEGIN® M Pellets (glyceryl stearate) 0.90 0.30 0.90 0.50 TEGO® Alkanol 1618 (Cetearyl Alcohol) 0.60 0.30 0.60 0.60 TEGOSOFT® P (Isopropyl Palmitate) 3.00 3.00 3.00 3.00 Sweet almond (Prunus Amygdalus Dulcis) oil 5.00 5.00 5.00 5.00 TEGOSOFT® CT (Caprylic / Capric Triglycerides) 4.50 4.50 4.50 4.50 Triisostearin 3.50 3.50 3.50 3.50 Example 1 6.00 6.00 6.00 6.00 B water Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 4.00 3.00 5.00 Xanthan gum (Keltrol CG-SFT, CP Kelco) 0.30 0.30 0.30 0.30 C Sodium hydroxide (10% in water) qs qs qs qs Z Preservatives, fragrances qs qs qs qs

[0083] Body butter Mutually raw material w / w % A <![CDATA[Dermofeel ® NC (polyglycerol-3 distearate; glycerol stearate citrate) 3.00 <![CDATA[Tego ® Alkanol 1618 (Cetearyl Alcohol) 4.00 <![CDATA[Tegin ® M Pellets (glyceryl stearate) 3.00 Example 1 6.00 Sunflower (Helianthus Annuus (Sunflower)) seed oil 5.50 Shea butter (Butyrospermum Parkii (Shea) oil) 6.00 Cocoa (Theobroma Cacao (Cocoa)) seed oil 6.00 <![CDATA[dermofeel ® Toco 70 non-GMO (Tocopherol; Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.50 B water Up to 100 glycerin 5.00 Xanthan gum (Keltrol CG-SFT, CP Kelco) 0.50 Z Preservatives, fragrances qs

[0084] Low whitening natural body butter Mutually raw material w / w % A <![CDATA[symbio ® muls GC MB (glyceryl stearate citrate; cetearyl alcohol; caprylic / caprylic glyceride) 7.00 Sunflower (Helianthus Annuus (Sunflower)) seed oil 35.00 Example 1 19.00 <![CDATA[dermofeel ® Toco 70 non-GMO (Tocopherol, Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.50 B water Up to 100 glycerin 3.00 <![CDATA[dermosoft ® anisate eco (sodium anisinate) 0.30 C <![CDATA[dermofeel ® PA-3 (sodium phytate; water; alcohol) 0.30 Z essence qs

[0085] Lip filler lipstick Mutually raw material w / w % A <![CDATA[Tegosoft ® G 20 (octyldodecanool) 15.00 <![CDATA[Tegosoft ® CT (Caprylic / Capric Triglyceride) 10.00 <![CDATA[Tegosoft ® OER (Oleyl Erucate) 2.00 <![CDATA[Tegosoft ® MM (Myristyl Myristate) 5.00 Castor (Ricinus Communis) seed oil (castor oil, Aldrich) 31.70 <![CDATA[Olus Oil (Cremerlin ® PURA,Cremer Care) ]]> 10.00 Stearic acid beeswax; beeswax (BW Ester BW67, Koster Keunen) 5.00 Ceramic wax (Kahlwax 1899, KahlWax) 5.00 White beeswax (Cera Alba) (Kahlwax 8104, KahlWax) 4.00 Candelilla wax (Euphorbia Cerifera Wax) (Kahlwax 2039L, KahlWax) 2.00 Example 1 5.00 B Tocopherol 0.10 essence 0.20 C <![CDATA[HyaCare ® Filler CL (water; ethylhexyl stearate; sodium hyaluronate crosspolymer; polyglycerol-4 diisostearate / polyhydroxystearate / sebacate; sodium isostearate) 5.00

[0086] Aftershave

[0087] O / W Cream Mutually raw material w / w % w / w % w / w % A Tego® Care PSC 3 (Polyglycerol-3 dicitrate / stearate) 3.00 C14-22 alcohol (and) C12-20 alkyl glucoside 4.00 Glyceryl stearate SE 4.50 <![CDATA[Tegin ® M Pellets (glyceryl stearate) 0.90 0.90 0.90 <![CDATA[Tego ® Alkanol 18 (stearyl alcohol) 0.60 0.60 0.60 <![CDATA[Tegosoft ® P (isopropyl palmitate) 3.00 3.00 3.00 Sweet almond (Prunus Amygdalus Dulcis (Sweet Almond) oil) 5.00 5.00 5.00 <![CDATA[Tegosoft ® CT (Caprylic / Capric Triglyceride) 4.50 4.50 4.50 Triisostearin 3.50 3.50 3.50 Example 1 6.00 6.00 6.00 B water Up to 100 Up to 100 Up to 100 glycerin 3.00 3.00 3.00 Xanthan gum (Keltrol CG-SFT, CP Kelco) 0.30 0.30 0.30 C Sodium hydroxide (10% in water) qs qs qs Z Preservatives, fragrances qs qs qs

[0088] Lightweight W / O Emulsion Mutually Element w / w-% A ISOLAN® GPS (Polyglycerol-4 diisostearate / Polyhydroxystearate / Sebacate) 3.00 Example 1 6.40 TEGOSOFT® DEC (Diethylhexyl carbonate) 6.40 Dioctyl carbonate, silachlorite, propylene carbonate (Cosmedia® Gel CC, Cognis) 3.00 B water Add to 100 glycerin 2.00 Magnesium sulfate heptahydrate 1.50 C Phenoxyethanol, ethylhexylglycerin (euxyl® PE 9010, Schülke & Mayr) 0.70

[0089] Anti-aging hydration cream Mutually Element w / w-% A TEGO® Care 450 (Polyglycerol-3-methylglucose distearate) 3.00 TEGIN® M Pellets (glyceryl stearate) 2.00 TEGO® Alkanol 18 (Stearyl alcohol) 1.00 TEGOSOFT® MM (Myristyl Myristate) 1.00 TEGOSOFT® DO (decyl oleate) 8.00 Example 1 11.50 Phytosphingosine SLC (Salicyloyl Phytosphingosine) 0.10 B glycerin 3.00 water Add to 100 C TEGO® Carbomer 134 0.20 TEGOSOFT® P (Isopropyl Palmitate) 0.80 D Sodium hydroxide (10% in water) qs Z Preservatives, fragrances qs

[0090] Lightweight O / W Sunscreen Lotion

[0091] Sunscreen spray SPF 30

[0092] cationic hand cream Mutually Element w / w-% A VARISOFT® TA 100 (Distearate Dimethyl Ammonium Chloride) 3.50 TEGIN® M Pellets (glyceryl stearate) 1.50 TEGO® Alkanol 18 (Stearyl alcohol) 1.00 Example 1 6.00 TEGOSOFT® DEC (Diethylhexyl carbonate) 13.00 TEGOSOFT® CR (Cetyl Ricinoleate) 1.00 Triisostearin 1.00 B TEGO® Cosmo C 100 (Crease) 0.50 glycerin 3.00 water Add to 100 Z Preservatives, fragrances qs

[0093] AP / Deo roll-on without PEG and ACH Mutually Element w / w-% A TEGO® Care APD 18 (Polyglycerol-6 stearate; Polyglycerol-6 betaine; C18-22 hydroxyalkyl hydroxypropyl guar gum) 5.00 TEGOSOFT® LO MB (Lauryl Oleate) 3.00 Example 1 2.00 B water Add to 100 glycerin 3.00 Potassium lum 5.00 C Preservatives, fragrances qs

[0094] Oil Release Lotion Mutually Element w / w-% w / w-% w / w-% A TEGO® Care PBS 6 (Polyglycerol-6 stearate, Polyglycerol-6 betaine) 3.00 3.00 3.00 TEGOSOFT® DEC (Diethylhexyl carbonate) 15.00 15.00 15.00 Example 1 5.00 10.00 10.00 TEGOSOFT® LO MB (Lauryl Oleate) 6.00 TEGOSOFT® OER (Oleyl Erucate) 18.00 12.00 16.00 TEGOSOFT® CT (Caprylic / Capric Triglycerides) 20.00 20.00 20.00 TEGOSOFT® AC (Isoamyl Cocoate) 13.00 14.00 10.00 TEGO® Feel C 10 (Cellulose) 1.00 1.00 1.00 B water Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 C Phenoxyethanol, ethylhexylglycerin (Euxyl PE9010, Schülke & Mayr GmbH) 0.70 0.70 0.70 D Citric acid (10% in water) qs qs qs

[0095] W / O foundation: According to INCI nomenclature w / w-% w / w-% w / w-% w / w-% w / w-% w / w-% A ISOLAN® 17 (polyglycerol-4 diisostearate / polyhydroxystearate / sepiacetate (and) caprylic / capric triglyceride (and) polyglycerol-3 oleate (and) diisostearoyl polyglycerol-3 dilinoleate) 4.00 3.00 2.00 3.00 2.00 ISOLAN® GPS (Polyglycerol-4 diisostearate / Polyhydroxystearate / Sebacic acid ester) 1.00 Dehymuls PGPH (Polyglycerol-2-dimeric hydroxystearate) 1.50 Cithrol PG3PR (Polyglycerol-3 polyricinoleate) 2.00 ABIL® EM 90 (Cetyl PEG / PPG-10 / 1 Polydimethylsiloxane) 1.50 3.00 Dermofeel sensolv (isoamyl laurate) 7.00 6.00 5.00 7.00 2.50 6.00 decyl cocoate 4.00 4.00 4.00 3.00 Isopropyl myristate 6.00 6.00 4.50 Caprylic / Capric Triglyceride 4.00 3.00 4.00 Diethylhexyl carbonate 4.00 5.00 polydimethylsiloxane 15.00 Example 1 3.00 2.00 6.00 4.00 TEGOSOFT® LO MB (Lauryl Oleate) 2.00 5.00 5.00 2.00 0.50 CI 77891 (and) hydrogenated lecithin 5.00 5.00 5.00 5.00 5.00 5.00 CI 77492 (and) hydrogenated lecithin 0.60 0.60 0.60 0.60 0.60 0.60 CI 77491 (and) hydrogenated lecithin 0.35 0.35 0.35 0.35 0.35 0.35 CI 77499 (and) hydrogenated lecithin 0.10 0.10 0.10 0.10 0.10 0.10 Distearate, lithium dimethylammonium montmorillonite, polydimethylsiloxane, propylene carbonate 2.00 2.00 2.00 2.00 2.00 2.00 B water Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Sodium chloride 1.00 1.00 1.50 Magnesium sulfate heptahydrate 1.50 2.00 2.00 glycerin 3.00 3.00 3.00 5.00 5.00 5.00 C Phenoxyethanol, Octylethylene glycol 1.00 1.00 1.00 1.00 1.00 1.00

[0096] Natural lipstick

[0097] Natural foundation Mutually raw material w / w % A Example 1 5.00 TEGOSOFT LO MB (Lauryl Oleate) 10.00 <![CDATA[Tegosoft ® DC (decyl cocoate) 3.00 <![CDATA[Tegosoft ® AC (isoamyl cocoate) 5.00 Safflower (Carthamus Tinctorius (Safflower)) Seed Oil 500 <![CDATA[ISOLAN ® GPS (Polyglycerol-4 diisostearate / polyhydroxystearate / sedicarboxylate) 4.00 Hydrogenated castor oil 7.00 <![CDATA[AEROSIL ® 200 (Silicon Dioxide) 0.30 <![CDATA[SPHINGONY ® (Sphingosine) 0.10 <![CDATA[dermofeel ® TocoBalance (Tocopherol, Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.10 B water Up to 100 glycerin 5.00 <![CDATA[TEGO ® Natural Betaine]]> 1.00 Zinc sulfate 1.50 C CI 77891, Hydrogenated Lecithin (Unipure White LC 981 HLC, Sensient) 5.00 CI 77492, Hydrogenated Lecithin (Unipure Yellow LC 182 HLC, Sensient) 1.20 CI 77491, Hydrogenated Lecithin (Unipure Red LC 381 HLC. Sensitive) 0.20 CI 77499, Hydrogenated Lecithin (Unipure Black LC 989 HLC, Sensient) 0.10 Titanium dioxide (Nano), aluminum oxide; stearic acid (Eusolex TS, Merck KgaA) 3.00 Zinc oxide (Zano M, EverZinc) 6.00 <![CDATA[dermosoft ® 250 eco (phenylpropanol)]]> 0.30 Z essence qs

[0098] Natural body oil raw material w / w % w / w % w / w % Example 1 35.00 15.00 15.00 TEGOSOFT LO MB (Lauryl Oleate) 20.00 Squalane (C13-15 alkane) 10.0 10.0 10.0 Sunflower (Helianthus Annuus (Sunflower)) seed oil 4.00 24.00 4.00 Coconut (Coconut Nucifera) oil 10.00 10.00 10.00 Meadowfoam (Limnanthes Alba) seed oil 15.00 15.00 15.00 <![CDATA[Tegosoft ® OER MB (Oleyl Erucate) 10.00 10.00 10.00 <![CDATA[dermofeel ® sensolv MB (isoamyl laurate) 15.00 15.00 15.00 <![CDATA[dermofeel ® Toco 70 non-GMO]]> 1.00 1.00 1.00

[0099] Transparent sunscreen Mutually raw material w / w % w / w % A <![CDATA[Tego ® SP 13 Sun Up (C10-30 alkyl polyacrylate) 2.50 2.50 <![CDATA[dermofeel ® Toco 70 non-GMO (Tocopherol, Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.50 0.50 Example 1 5.00 5.00 TEGOSOFT LO MB (Lauryl Oleate) 15.00 <![CDATA[Tegosoft ® AC (isoamyl cocoate) 15.00 <![CDATA[dermofeel ® sensolv]]> 15.00 15.00 <![CDATA[Tegosoft ® CT (Caprylic / Capric Triglyceride) to 20.00 Butylmethoxydibenzoylmethane 3.00 3.00 Ethylhexyl salicylate 5.00 5.00 Octylene 10.00 10.00 Humosalt 10.00 10.00 alcohol Up to 100 Up to 100 Z Preservatives, fragrances qs qs

[0100] cationic hand cream Mutually raw material w / w % A Varisoft® TA 100 (Distearate Dimethyl Ammonium Chloride) 3.50 <![CDATA[Tegin ® M Pellets (glyceryl stearate) 1.50 <![CDATA[Tego ® Alkanol 18 (stearyl alcohol) 1.00 Example 1 13.00 <![CDATA[Tegosoft ® DEC (diethylhexyl carbonate) 8.00 <![CDATA[Tegosoft ® CR (Cetyl ricinoleate) 1.00 Triisostearin 1.00 B <![CDATA[Tego ® Cosmo C 100 (creatine) 0.50 glycerin 3.00 water Up to 100 Z Preservatives, fragrances qs

[0101] Natural body cream with a smooth texture

[0102] Deep Comfort Silky Body Butter Mutually raw material w / w % w / w % w / w % w / w % w / w % w / w % A <![CDATA[Dermofeel ® NC (polyglycerol-3 distearate; glycerol stearate citrate) 3.00 3.00 3.00 3.00 <![CDATA[Sodium stearoyl glutamate (Emulgin ® SG, BASF)]]> 3.00 3.00 <![CDATA[Tego ® Alkanol 1618 (Cetearyl Alcohol) 4.00 4.00 4.00 4.00 4.00 4.00 <![CDATA[Tegin ® M Pellets (glyceryl stearate) 3.00 3.00 3.00 3.00 3.00 3.00 Example 1 1.00 7.00 7.00 7.00 1.00 0.1 <![CDATA[TEGOSOFT ® OER (Oleyl Erucate) 6.00 <![CDATA[TEGOSOFT ® LO MB (Lauryl Oleate) 6.00 6.00 Evening primrose (Oenothera biennis) seed extract (Life's GLA™ '10'n-6 Oil, DSM) 2.00 Squalane (Plantasens® squalane, Clariant) 2.00 Sunflower (Helianthus Annuus (Sunflower)) seed oil 5.50 5.50 5.50 5.50 5.50 5.50 Shea butter (Butyrospermum Parkii (Shea) oil) 6.00 6.00 6.00 4.00 6.00 6.00 Cocoa (Theobroma Cacao (Cocoa)) seed oil 6.00 6.00 4.00 6.00 6.00 6.00 <![CDATA[dermofeel ® Toco 70 non-GMO (Tocopherol; Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.50 0.50 0.50 0.50 0.50 0.50 B water Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 glycerin 5.00 5.00 5.00 5.00 5.00 5.00 Xanthan gum (Keltrol CG-SFT, CPKelco) 0.50 0.50 0.50 0.50 0.50 0.50 C Vecollage™ Fortify L (Water, Glycerin, sh-peptide-69 (proposed)) 3.00 3.00 Z Preservatives, fragrances qs qs qs qs qs qs

[0103] Super Comfortable Waterproof Sunscreen Spray SPF 30

[0104] Cationic foot cream Mutually raw material w / w-% w / w-% w / w-% A TEGO® Care Eco CAT MB (Distearyl Isopropyl Dimethyl Ammonium Methyl Sulfate) 4.00 4.00 4.00 TEGIN® M Pellets MB (Glyceryl Stearate) 3.00 3.00 3.00 Stearyl alcohol 5.30 5.30 5.30 TEGOSOFT® CT MB (Caprylic / Capric Triglyceride) 7.00 7.00 TEGOSOFT® AC MB (Isoamyl Cocoate) 5.00 5.00 5.00 Example 1 1.00 0.1 8.00 Shea butter (Butyrospermum Parkii (Shea) oil) 1.00 1.00 1.00 Grape (Vitis Vinifera (Grape)) seed oil 5.00 5.00 5.00 TEGO® Cosmo P 813 MB (Polyglycerol-3-octanoate) 0.10 0.10 0.10 dermofeel® Toco 70 non-GMO (Tocopherol; Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.20 0.20 0.20 B Water (Aqua) Add to 100 Add to 100 Add to 100 glycerin 5.00 5.00 5.00 Z Verstatil® BOB (Benzyl alcohol; Octyl glycol; Benzoic acid) 1.20 Verstatil® PC (phenoxyethanol; octylethylene glycol) 0.70 0.70

[0105] (PEG-free) AP / Deo roll-on Mutually raw material w / w-% w / w-% w / w-% w / w-% w / w-% A <![CDATA[TEGO ® Care APD 18 (Polyglycerol-6 stearate; Polyglycerol-6 betaine; C18-22 hydroxyalkyl hydroxypropyl guar gum) 5.00 3.50 3.30 3.30 Stearyl alcohol polyether-2 3.20 Stearyl alcohol polyether-20 0.80 Cetearyl alcohol 1.50 0.5 0.5 <![CDATA[TEGOSOFT ® CT MB (Caprylic / Capric Triglyceride) 5.7 2.00 Cetiol® OE (BASF) dioctyl ether 3.00 <![CDATA[TEGOSOFT ® LO MB (Lauryl Oleate) 2.50 5.00 0.5 Example 1 2.50 1.00 0.50 0.10 5.00 <![CDATA[TEGODEO ® PY 88 G (Zinc Ricinoleate) 1.00 1.00 <![CDATA[TEGO ® Cosmo P 813 MB (Polyglycerol-3-octanoate) 0.50 0.50 B water Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 Potassium lum 5.00 50% aqueous solution of aluminum chloride 20.00 20.00 Citric acid, 50% in water qs qs C Preservatives, fragrances qs qs qs qs qs

[0106] Milky Deo Roll-On for sensitive skin Mutually raw material w / w-% w / w-% w / w-% w / w-% A <![CDATA[dermofeel ® GSC SG (glyceryl stearate citrate) 0.40 0.40 0.40 0.40 <![CDATA[TEGOSOFT ® OER MB (Oleyl Erucate) 0.50 <![CDATA[dermosoft ® decalact deo MB (sodium hexanoyl / lauroyl lactyl lactylate; triethyl citrate; sage (Salvia officinalis (Sage) oil)) 0.30 0.30 0.30 0.30 <![CDATA[dermosoft ® G 3 CY MB (Polyglycerol-3-octanoate) 0.30 0.30 0.30 0.30 <![CDATA[dermofeel ® sensolv MB (isoamyl laurate) 0.50 0.50 0.50 0.50 <![CDATA[dermofeel ® TEC eco (triethyl citrate) 5.00 5.00 5.00 5.00 <![CDATA[TEGODEO ® PY 88 G (Zinc Ricinoleate) 1.00 1.00 1.00 1.00 Example 1 0.10 5.00 0.50 2.00 B water Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 3.00 Sodium citrate dihydrate (sodium citrate) 0.30 0.30 0.30 0.30 Xanthan Gum FNCSP-PC (Xanthan Gum) 0.90 0.90 0.90 0.90 Genuvisco Carrageenan CG-131 (Carrageenan) 0.10 0.10 0.10 0.10 <![CDATA[dermosoft ® 7GA MB (Water; Glycerin; Heptyleglycerin; Sodium anisinate) 2.60 2.60 2.60 2.60 Citric acid, 20% aqueous solution qs qs qs qs Z essence qs qs qs qs

[0107] Renewal Body Oil Release Lotion Mutually raw material w / w-% w / w-% w / w-% w / w-% w / w-% w / w-% A <![CDATA[TEGO ® Care PBS 6 (Polyglycerol-6 stearate, Polyglycerol-6 betaine) 3.00 1.50 3.00 3.00 <![CDATA[ECOHANCE ® PS 3 (polyglycerol-3 distearate) 1.50 3.00 3.00 <![CDATA[TEGOSOFT ® DEC (diethylhexyl carbonate) 10.00 10.00 10.00 10.00 10.00 10.00 <![CDATA[TEGOSOFT ® LO MB (Lauryl Oleate) 26.00 26.00 26.00 26.00 26.00 16.00 <![CDATA[TEGOSOFT ® OER (Oleyl Erucate) 10.00 10.00 10.00 10.00 10.00 10.00 <![CDATA[TEGOSOFT ® CT (Caprylic / Capric Triglyceride) 15.00 15.00 15.00 15.00 Example 1 0.50 0.50 0.10 15.00 15.00 10.00 <![CDATA[TEGOSOFT ® AC (isoamyl cocoate) 10.00 10.00 10.00 10.00 10.00 10.00 <![CDATA[TEGO ® Feel C 10 (cellulose) 1.00 1.00 1.00 1.00 1.00 1.00 B water Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 3.00 3.00 3.00 C Phenoxyethanol, ethylhexylglycerin (Euxyl PE9010, Schülke & Mayr GmbH) 0.70 0.70 0.70 0.70 0.70 0.70 D Citric acid (10% in water) qs qs qs qs qs qs

[0108] Long-lasting W / O foundation Mutually raw material w / w-% w / w-% w / w-% w / w-% w / w-% A <![CDATA[ISOLAN ® 17 (Polyglycerol-4 diisostearate / polyhydroxystearate / sepiacetate (and) caprylic / capric triglyceride (and) polyglycerol-3 oleate (and) diisostearoyl polyglycerol-3 dilinoleate)]]> 4.00 4.00 3.00 2.00 2.00 <![CDATA[TEGO ® FILMSTAR One MB (Polyglycerol-3-stearate / Sebacate Crosspolymer) 1.50 1.50 1.00 0.50 1.00 <![CDATA[ISOLAN ® GPS (Polyglycerol-4-diisostearate / Polyhydroxystearate / Sebacic Acid) 1.00 <![CDATA[ABIL ® EM 90 (Cetyl PEG / PPG-10 / 1 Polydimethylsiloxane) 1.50 1.50 Dermofeel sensolv (isoamyl laurate) 7.00 7.00 6.00 2.50 2.50 decyl cocoate 4.00 4.00 4.00 Isopropyl myristate 6.00 6.00 4.50 4.50 Caprylic / Capric Triglyceride 4.00 3.00 3.00 Diethylhexyl carbonate 5.00 5.00 TEGOSOFT® LO (Lauryl Oleate) 2.00 2.00 5.00 Example 1 2.00 2.00 5.00 8.00 0.50 CI 77891 (and) hydrogenated lecithin 5.00 5.00 5.00 5.00 5.00 CI 77492 (and) hydrogenated lecithin 0.60 0.60 0.60 0.60 0.60 CI 77491 (and) hydrogenated lecithin 0.35 0.35 0.35 0.35 0.35 CI 77499 (and) hydrogenated lecithin 0.10 0.10 0.10 0.10 0.10 Distearate, lithium dimethylammonium montmorillonite, polydimethylsiloxane, propylene carbonate 2.00 2.00 2.00 2.00 2.00 B water Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Sodium chloride 1.00 1.00 1.00 Magnesium sulfate heptahydrate 2.00 2.00 glycerin 3.00 3.00 3.00 5.00 5.00 C Phenoxyethanol, Octylethylene glycol 1.00 1.00 1.00 1.00 1.00 Vecollage™ Fortify L (Water, Glycerin, sh-peptide-69 (proposed)) 3.00 3.00

[0109] W / O sun care – Sunscreen, SPF 50+ Mutually Element w / w-% w / w-% w / w-% w / w-% w / w-% A ISOLAN® 17 MB (Polyglycerol-4 diisostearate / polyhydroxystearate / sepiacetate; caprylic / capric triglyceride; polyglycerol-3 oleate; diisostearoyl polyglycerol-3 dilinoleate) 4.30 4.30 4.30 4.30 4.30 Microcrystalline wax 0.30 0.30 0.30 0.30 0.30 Hydrogenated castor oil 0.30 0.30 0.30 0.30 0.30 TEGOSOFT® DEC (Diethylhexyl carbonate) 8.20 4.20 2.20 2.20 TEGOSOFT® XC (Phenoxyethyl Octanoate) 4.00 4.00 4.00 4.00 Dermofeel sensolv MB (Isoamyl Laurate) 2.00 2.00 2.00 Example 1 1.00 0.50 1.00 1.00 5.00 TEGO® FILMSTAR One MB (Polyglycerol-3-stearate / Sebacate Crosspolymer) 0.50 0.50 1.50 LexFilm™ Sun Natural MB 0.50 Uvinul A plus (diethylaminohydroxybenzoylhexyl benzoate) 6.00 6.00 6.00 6.00 6.00 Tinosorb S (bis-ethylhexyloxyphenol methoxyphenyl triazine) 7.00 7.00 7.00 7.00 7.00 Ethylhexyl salicylate 5.00 5.00 5.00 5.00 5.00 Ethylhexyl methoxycinnamate 8.00 8.00 8.00 8.00 8.00 Parsol TX (titanium dioxide (and) silica (and) polydimethylsiloxane) 6.00 6.00 6.00 6.00 6.00 Verstatil® BOB (Benzyl alcohol; Octyl glycol; Benzoic acid) 1.00 1.00 1.00 1.00 1.00 B Water (Aqua) Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 3.00 3.00 Zinc sulfate heptahydrate 1.00 1.00 1.00 1.00 1.00 Z essence qs qs qs qs qs

[0110] All Day Sun Protection Lotion SPF 30

[0111] High spreading sustainable lifting bodyspray Mutually Element w / w% w / w% w / w% w / w% w / w% w / w% A dermofeel® easymuls plus (glyceryl oleate citrate) 3.00 3.00 3.00 3.00 3.00 3.00 TEGOSOFT® LO MB (Lauryl Oleate) 12.00 6.00 12.00 6.00 12.00 5.00 Dermofeel sensolvMB 6.00 6.00 Example 1 1.00 6.00 0.50 1.00 0.1 0.5 B Water (Aqua) Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 dermosoft® Pentioleco (pentanediol) 3.00 3.00 3.00 3.00 3.00 3.00 Kelcogel CG-HA (Gellansé) 0.10 0.10 0.10 0.10 0.10 GenuviscoCarrageenan CG-131 (Carrageenan) 0.10 0.10 C dermosoft® OMP (Methylpropanediol, Octylethylene Glycol, Phenylpropanol) 2.50 2.50 2.50 2.50 2.50 2.50 Vecollage™ Fortify L (Water, Glycerin, sh-peptide-69 (tentative)) 3.00 D Sodium hydroxide, 10% aqueous solution qs qs qs qs qs qs

[0112] Hydration & Wrinkle Reduction O / W Sunscreen Mutually Element w / w-% w / w-% w / w-% w / w-% w / w-% w / w-% A TEGO® Care PBS 6 MB (Polyglycerol-6 stearate (and) polyglycerol-6 betaine) 4.00 4.00 4.00 4.00 4.00 4.00 ABIL® Care XL 80 MB (Bis-PEG / PPG-20 / 5PEG / PPG-20 / 5 polydimethylsiloxane; methoxy-PEG / PPG-25 / 4 polydimethylsiloxane; caprylic / capric triglyceride) 0.67 0.67 0.67 TEGO® SP 13 Sun Up MB (C10-30 Alkyl Polyacrylate) 1.50 1.50 1.50 1.50 1.50 1.50 TEGIN® M Pellets MB (Glyceryl Stearate) 0.20 0.20 0.20 0.20 0.20 0.20 TEGO® Alkanol 1618 MB (Cetearyl Alcohol) 0.20 0.20 0.20 0.20 0.20 0.20 TEGOSOFT® DEC (Diethylhexyl carbonate) 7.00 5.00 1.00 2.00 3.00 2.00 TEGOSOFT® XC (Phenoxyethyl Octanoate) 1.00 0.50 5.00 2.00 Dermofeel sensolv MB (Isoamyl Laurate) 2.00 0.70 2.00 Example 1 1.00 0.50 7.00 5.00 0.20 3.00 TEGO® FILMSTAR One MB (Polyglycerol-3-stearate / Sebacate Crosspolymer) 0.5 1.5 INQP70TMD (Titanium dioxide; Isononyl isononanoate; Polyhydroxystearic acid; Hydrogenated polydimethylsiloxane; Polydimethylsiloxane) 16.4 16.4 16.4 16.4 16.4 16.4 GCP55ZSG (Zinc oxide; Caprylic / Capric triglyceride; Polyhydroxystearic acid; Stearoyl glutamic acid) 24.3 24.3 24.3 24.3 24.3 24.3 B Water (Aqua) Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 glycerin 3.00 3.00 3.00 3.00 3.00 3.00 HyaCare® 50 (Hydrolyzed Hyaluronic Acid) 0.10 0.10 0.10 HyaCare® (Sodium Hyaluronate) 0.10 0.10 0.10 TEGO® Pep UP (Tetrapeptide-4, Glycerin, Water) 1.00 1.00 1.00 Xanthan Gum 0.50 0.50 0.50 0.2 0.50 Genuvisco Carrageenan CG-131 (Carrageenan) 0.5 0.2 C dermosoft® OMP (Methylpropanediol, Octylethylene Glycol, Phenylpropanol) 2.50 2.50 2.50 2.50 2.50 2.50

[0113] Daily wear cationic lotion with UV protection

[0114] Hydrating Foot Care Cream

[0115] Waterless sunscreen, SPF 50 Mutually Element w / w% w / w% w / w% w / w% A Diethylhexylbutyrylaminotriazinone 3.00 3.00 3.00 3.00 Ethylhexyl salicylate 3.00 3.00 3.00 3.00 Ethylhexyltriazine 3.50 3.50 3.50 3.50 Butylmethoxydibenzoylmethane 5.00 5.00 5.00 5.00 Diethylaminohydroxybenzoyl benzoate 8.00 8.00 8.00 8.00 bis-ethylhexyloxyphenol methoxyphenyl triphenyl ketone 8.00 8.00 8.00 8.00 TEGOSOFT® DC MB (decyl cocoate) Add to 100 Add to 100 Add to 100 Add to 100 TEGOSOFT® XC (Phenoxyethyl Octanoate) 30.00 30.00 30.00 30.00 Example 1 10.00 5.00 0.1 0.5 TEGOSOFT® DEC (Diethylhexyl carbonate) 10.00 4.50 14.00 15.00 TEGOSOFT® TN (C12-15 alkyl benzoate) 5.00 0.50 1.00 14.50 Tegosoft® CT (Caprylic / Capric Triglycerides) 10.00 ethanol 10.00 dermofeel® E 74 A non-GMO (Tocopheryl Acetate, Sunflower Seed Oil) 0.50 0.50 - - dermofeel® Toco 70 non-GMO (Tocopherol; Sunflower (Helianthus Annuus (Sunflower)) Seed Oil) 0.30 0.30 - -

[0116] Conditioning Balm Mutually Element w / w% w / w% A TEGO® Alkanol 1618 MB (Cetearyl Alcohol) 4.40 4.40 Example 1 1.00 0.1 VARISOFT® EQ 65 MB (Distearylethyldimethylammonium chloride; Cetearyl alcohol) 3.10 3.10 B Water (Aqua) Add to 100 Add to 100 glycerin 2.00 2.00 Z dermosoft® Pentiol eco (pentanediol) 4.00 4.00 essence qs qs

[0117] Cleansing balm for severely damaged hair. Mutually Element w / w% w / w% A Soybean (Glycine Soja) oil 45.00 45.00 Example 1 5.00 0.1 VARISOFT® EQ 100 (Bis-(isostearoyl / oleoyl isopropyl)dimethylammonium methyl sulfate) 1.00 1.00 TEGO® Sulfosuccinate DO 75 (Sodium diethylhexyl sulfosuccinate) 4.00 4.00 B Water (Aqua) Add to 100 Add to 100 Jaguar C-162 (Hydroxypropyl guar gum (and) Hydroxypropyl guar gum hydroxypropyltrimethylammonium chloride) 0.40 0.40 glycerin 2.00 2.00 TEGO® Betain F 50 (Cocamidopropyl Betaine) 7.90 7.90 REWOPOL® SB FA 30 B MB (Disodium lauryl ether sulfosuccinate) 7.50 7.50 Z Verstatil® BL non-GMO (water; sodium levulinate; sodium benzoate) 2.00 2.00 dermosoft® GMCY MB (Caprylic / Capric Glyceryl Acetate) 0.30 0.30

[0118] High Oil Cream Mutually Element w / w% w / w% w / w% A Soybean (Glycine Soja) oil 45.00 45.00 50.00 Example 1 5.00 5.00 0.10 VARISOFT® EQ 100 (Bis-(isostearoyl / oleoyl isopropyl)dimethylammonium methyl sulfate) 1.50 1.50 1.50 ECOHANCE® Remo XP (Sorbitol / Xylitol Nonanoate) 8.00 8.00 8.00 B SOPHANCE® LA-A (glycolipid) 6.00 RHEANCE® One (glycolipid) 6.00 6.00 TEGO® Betain F 50 (Cocamidopropyl Betaine) 18.00 18.00 18.00 Water (Aqua) Add to 100 Add to 100 Add to 100 glycerin 2.00 2.00 2.00 C Verstatil® TBO (Triethyl Citrate; Octyl Ethylene Glycol; Benzoic Acid) 0.60 0.60 0.60

[0119] Detangling Milk Mutually Element w / w% A VARISOFT® EQ 100 (Bis-(isostearoyl / oleoyl isopropyl)dimethylammonium methyl sulfate) 1.50 Example 1 0.10 TEGO® Solve 61 MB (Polyglycerol-6-octanoate; Polyglycerol-3-cocoate; Polyglycerol-4-decanoate; Polyglycerol-6-ricinoleate) 2.00 B Water (Aqua) Add to 100 glycerin 2.00 Verstatil® TBG MB (Triethyl citrate; Caprylic / Caprylic glyceride; Benzoic acid) 1.00

[0120] Clean Conditioning Shampoo Element w / w-% Example 1 0.5 TEXAPON® NSO, BASF, 28%-ig (INCI: Sodium lauryl ether sulfate) 32.00 REWODERM® LI S 80, Evonik Nutrition&Care GmbH (INCI: (PEG-200 hydrogenated palmitate glyceryl ester; PEG-7 glyceryl cocoate ester)) 2.00 essence 0.25 water Add to 100.00 TEGO® Cosmo C 100, Evonik Nutrition & Care GmbH, (INCI: Creatine) 1.50 Jaguar C-162, Solvay (INCI: Hydroxypropylguar hydroxypropyltrimethylammonium chloride) 0.20 TEGO® Betain F 50, Evonik Nutrition&Care GmbH, 38%-ig (INCI: cocamidopropyl betaine) 8.00 NaCl 2.50 Citric acid, 30%-ig qs (pH 5.0) preservative qs

[0121] Pearl Shampoo

[0122] Conditioning Shampoo

[0123] Anti-dandruff shampoo

[0124] Shampoo, PEG-free Element w / w-% TEXAPON® LS 35, BASF, 30% (INCI: Sodium Lauryl Sulfate) 28.00 water Add to 100.00 UCARE Polymer JR-400, Dow Chemicals, (INCI: Polyquaternium-10) 0.10 Jaguar C-162, Solvay (INCI: Hydroxypropylguar hydroxypropyltrimethylammonium chloride) 0.10 ANTIL® CM 90, Evonik Nutrition & Care GmbH, (INCI: Cocamide MEA) 0.50 ANTIL® SPA 80, Evonik Nutrition & Care GmbH, (INCI: Isostearamide MIPA; Glyceryl Laurate) 1.00 Xanthan Gum 0.50 Example 1 0.10 Dehyton AB 30, BASF, 31%, (INCI: cocobetaine) 8.00 Prifrac 2920, Croda, (INCI: Lauric Acid) 0.50 TEGOSOFT® PC 41, Evonik Nutrition & Care GmbH, (INCI: Polyglycerol-4-decanoate) 1.00 glycerin 1.00 Uvinul MS 40, BASF, (INCI: Benzophenone-4) 0.10 Versene 100, The Dow Chemical Company, (INCI: Tetrasodium EDTA) 0.10 Sodium chloride 1.00 Fragrances and preservatives qs Citric acid, 30%-ig qs (pH 5.0)

[0125] Sulfate-free shampoo

[0126] Sulfate-free shampoo

[0127] Rinse-Off Conditioner

[0128] Rinse-Off Conditioner

[0129] Wet wipes impregnation fluid I Element w / w-% Pentylene glycol 2.0 glycerin 1.0 TEGO® Solve 61 (Polyglycerol-6-octanoate; Polyglycerol-3-cocoate; Polyglycerol-4-decanoate; Polyglycerol-6-ricinoleate) 2.0 Example 1 0.5 Allantoin 0.2 maltodextrin 0.5 Chamomile extract 0.1 preservative qs essence qs water Add to 100.0 Citric acid, 30% Add to pH 5.5

[0130] Wet wipes impregnation fluid II Element w / w-% TEGO® Solve 61 (Polyglycerol-6-octanoate; Polyglycerol-3-cocoate; Polyglycerol-4-decanoate; Polyglycerol-6-ricinoleate) 1.5 TEGO® Solve 55 (Polyglycerol-6-octanoate; Polyglycerol-4-decanoate; Propylene glycol) 1.0 Example 1 0.2 preservative qs essence 0.1 Propylene glycol 3.0 water Add to 100.0

[0131] Cleansing Micellar Water Element w / w-% water Add to 100.0 TEGOSOFT® PC 41 (Polyglycerol-4-decanoate) 5.5 preservative qs Example 1 0.3 glycerin 1.0 Disodium EDTA 0.2 Citric acid, 30% Add to pH 5.5

[0132] Micellar Water Element w / w-% REWOTERIC® AM C (Sodium Cocoamphopropionate) 3.0 Example 1 0.6 TEGOSOFT® GMC 6 (PEG-6 Caprylic / Capric Glyceryl Acetate) 5.0 water Add to 100.0 glycerin 8.0 Citric acid Add to pH 5.5 preservative qs

Claims

1. A composition comprising The triglyceride mixture has the following distribution of fatty acid acyl groups in its triglycerides: 18% to 34% by weight, preferably 20% to 30% by weight, more preferably 21% to 28% by weight of palmitoyl group. 0.5% to 10% by weight, preferably 1.0% to 9.0% by weight, more preferably 2.0% to 7.0% by weight of stearoyl group. 28% to 44% by weight, preferably 30% to 42% by weight, more preferably 31% to 41% by weight of oleoyl group. 18% to 34% by weight, preferably 21% to 31% by weight, more preferably 22% to 30% by weight of linoleyl group. The total amount is less than 1.0% by weight, preferably 0.01% to 0.7% by weight, more preferably 0.05% to 0.4% by weight of cyclopropylene fatty acid acyl groups. The weight percentages mentioned herein are calculated based on the total number of fatty acid acyl groups contained in all triglycerides included in the composition. Its features The composition contains Tocopherol concentrations ranging from 50 ppm to 2000 ppm, preferably 150 ppm to 1500 ppm, more preferably 250 ppm to 1250 ppm, and most preferably 400 ppm to 1100 ppm. The ppm reference total composition is used.

2. The composition according to claim 1, characterized in that... It contains a total of less than 100 ppb, preferably 0.1 to 60 ppb, more preferably 0.5 to 25 ppb, and most preferably 1.0 to 10 ppb of polycyclic aromatic hydrocarbons (PAHs) selected from phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, and benzo(a)pyrene, wherein the ppb is based on the total composition.

3. The composition according to claim 1 or 2, characterized in that... The composition has a triglyceride content of 90% to 99.95% by weight, preferably 95% to 99.92% by weight, wherein the weight percentage is based on the total composition.

4. The composition according to at least one of the preceding claims, characterized in that... It has an iodine value of 70.0 g I / 100 g to 100 g I / 100 g, preferably 75.0 g I / 100 g to 95.0 g I / 100 g.

5. The composition according to at least one of the preceding claims, characterized in that... It has an acid value between 0.01 mg KOH / g and 8.0 mg KOH / g, preferably between 0.02 mg KOH / g and 2.0 mg KOH / g.

6. The composition according to at least one of the preceding claims, characterized in that... It has a saponification value between 175 mg KOH / g and 210 mg KOH / g, preferably between 180 mg KOH / g and 205 mg KOH / g.

7. The composition according to at least one of the preceding claims, characterized in that... It does not contain cosmetic preservatives.

8. A method for processing baobab oil, comprising the following steps: A) Provide baobab oil, B) Heat the baobab oil and maintain it at a temperature ranging from 90°C to 270°C. C) Pass water vapor through the baobab oil, preferably continuously.

9. The method according to claim 8, characterized in that... In step A), the baobab oil is provided by separating the oil from the baobab seeds, preferably by cold pressing.

10. The method according to claim 9, characterized in that... In step A), the baobab seeds are provided with or without peeling, preferably without peeling.

11. The method according to at least any one of claims 8 to 10, characterized in that... In step B), the temperature is maintained within the range for 0.1 hours to 24 hours, preferably 0.3 hours to 15 hours, and more preferably 1 hour to 12 hours.

12. The method according to at least one of claims 8 to 11, characterized in that... Method step C) is performed in parallel with method step B).

13. The method according to claim 12, characterized in that... The time period in step C) corresponds to at least 80%, more preferably 90% to 100%, of the time period in which the temperature is maintained within the range described in step B).

14. The method according to at least any one of claims 8 to 13, characterized in that In step C), the water vapor passes through the baobab oil at a rate of 0.05 to 2.5% by weight per hour, wherein the weight percentage of water vapor is relative to the amount of oil being processed.

15. Use of the composition according to at least one of claims 1 to 7 for the preparation of cosmetic formulations, dermatological formulations, feed, food and / or pharmaceutical formulations, preferably for topical application.

Images