An amorphous / nanocrystalline material heat treatment method based on mponba effect and an amorphous / nanocrystalline material prepared by the method

By employing a multi-step gradient cooling annealing method based on the Mpemba effect, the problems of insufficient atomic relaxation and incomplete release of residual stress in the heat treatment of amorphous/nanocrystalline alloys have been solved, achieving efficient and stable preparation of nanocrystalline materials. This method is applicable to various amorphous systems such as amorphous alloys, polymer glasses, and small molecule glasses.

CN122405941APending Publication Date: 2026-07-17NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI
Filing Date
2026-03-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing heat treatment processes for amorphous/nanocrystalline alloys suffer from problems such as insufficient atomic relaxation, incomplete release of residual stress, difficulty in refining nanocrystals, sensitivity to temperature windows, and low process efficiency, which affect the consistency of material properties and industrial applications.

Method used

A multi-step gradient cooling annealing method based on the Mpemba effect is adopted, including first isothermal annealing and gradient cooling annealing. By activating fast and slow relaxation modes at different temperatures, the energy of the system is reduced rapidly in a stepwise manner. Combined with relaxation process control parameters, it is ensured that atomic relaxation is sufficient and residual stress is completely released, thereby refining the grains.

Benefits of technology

This significantly improves the efficiency and stability of the heat treatment process, resulting in amorphous/nanocrystalline materials with full atomic relaxation, complete release of residual stress, and fine and uniform grains, meeting the performance requirements of high-end electronic devices.

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Abstract

本发明提供一种基于姆潘巴效应的非晶 / 纳米晶材料热处理方法及其制得的非晶 / 纳米晶材料,涉及非晶材料热处理技术领域。该热处理方法包括:将坯料升温至低于玻璃转变温度或第一个晶化起始温度的第一设定温度进行等温退火,退火时间下限为从β弛豫向α弛豫转变的时间;然后进行梯度降温退火,每步等温退火时间下限为对应温度下从β弛豫向α弛豫转变的时间;直至温度降至目标退火温度,保温至亚稳平衡态。本发明,通过多步降温退火实现不同弛豫模式的协同加速,显著提升工艺效率与稳定性,实现残余应力完全释放和纳米晶粒细化。本发明适用于金属非晶合金、高分子玻璃及小分子玻璃,可满足高频电子器件对软磁材料的严苛要求。
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