Surface-enhanced raman scattering substrate structure based on double catenarian structure and preparation method thereof

By constructing a hollow nanocavity with a double catenary structure and introducing a two-dimensional material layer, plasma-exciton coupling was achieved, which solved the problems of limited enhancement capability and limited control range of existing SERS substrate structures, and improved the sensitivity and repeatability of Raman signal detection.

CN122409618APending Publication Date: 2026-07-17XIAMEN UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XIAMEN UNIV
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing SERS substrate structures suffer from problems such as strong structural randomness, poor repeatability, limited local electric field enhancement capability, and limited control range in improving Raman signal intensity, making it difficult to achieve the synergistic effect of multiple enhancement mechanisms.

Method used

A surface-enhanced Raman scattering substrate structure based on a double catenary structure is adopted. By constructing a hollow double catenary nanocavity and introducing a two-dimensional material layer, the parameters are adjusted to achieve the matching of the plasmonic resonance peak and the exciton resonance peak, thereby exciting plasmonic-exciton coupling and forming a plasmonic-exciton hybrid state to enhance the local electromagnetic field.

Benefits of technology

It significantly improves the optical field localization capability of the nanocavity, realizes the excitation of various high-order plasmon modes, improves the detection sensitivity and electric field intensity of Raman signals, and provides a wider optical control range and higher repeatability.

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Abstract

本发明公开了一种基于双悬链线结构的表面增强拉曼散射基底结构及其制备方法,包括衬底及其上方的双悬链线结构和二维材料层,双悬链线结构包括由金属层构成的第一悬链线结构和第二悬链线结构,并且均包含相对的第一侧边和第二侧边,第一侧边和第二侧边在衬底上的正交投影形状为两条开口方向相同的悬链线曲线线段;第一悬链线结构和第二悬链线结构之间间隔设置并形成纳米间隙,二维材料层覆盖在金属层的表面以及纳米间隙上方并形成中空双悬链线纳米腔;在中空双悬链线纳米腔的局域内,通过调整双悬链线结构的参数使金属层的等离子体共振峰与二维材料层的激子共振峰匹配,从而激发了等离子体‑激子耦合,能够显著提升拉曼散射强度。
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