A positive electrode sheet, a battery and application

By designing a double-layer active material layer containing P2 and O3 phase layered oxides in the positive electrode of sodium-ion batteries, optimizing element distribution and pore structure, the problems of low-temperature start-up and high DCR of sodium-ion batteries were solved, and high plateau voltage, excellent rate performance and cycle stability were achieved.

CN122417784APending Publication Date: 2026-07-17ZHUHAI COSMX POWER BATTERY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHUHAI COSMX POWER BATTERY CO LTD
Filing Date
2025-01-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sodium-ion battery platforms have low voltage, making it difficult to start vehicles in low-temperature environments. They also have high DCR, low capacity recovery rate after cycling, and poor safety.

Method used

The positive electrode design includes a double-layer active material layer containing P2 phase and O3 phase layered oxides. The mass content of Fe, Ni, Na, Mn and Cu is unevenly distributed along the thickness direction of the electrode. The Fe, Ni and Na contents are low and the Mn and Cu contents are high on the side near the current collector surface. A porous structure is set to optimize ion conduction and improve the potential difference.

Benefits of technology

It improves the battery's platform voltage, enhances low-temperature discharge and cold-start performance, increases rate performance and cycle stability, reduces material costs, and strengthens battery safety.

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Abstract

本申请属于电池制备技术领域,具体涉及一种正极极片、电池及应用。本申请正极极片包括正极集流体和位于正极集流体至少一个表面的活性物质层;活性物质层包括含P2相层状氧化物的第一活性物质层和含O3相层状氧化物的第二活性物质层;第一活性物质层位于正极集流体的表面,第二活性物质层覆盖其上;沿正极极片厚度方向,活性物质层中各金属的质量含量不均匀分布,靠近正极集流体表面一侧的活性物质层中Fe、Ni和Na的质量含量低于另一侧的活性物质层,Mn和Cu的质量含量高于另一侧的活性物质层。本申请使平台电压更高的活性物质位于集流体表面,低的活性物质位于正极极片表面,有利于钠离子的嵌入,从而有利于低温放电和冷启动性能。
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