Composite silicon-carbon negative electrode material and preparation method thereof

By constructing a multi-level conductive network and enhancing interfacial compatibility in lithium-ion battery anode materials, the problems of low initial coulombic efficiency, insufficient cycle stability, and large electrode expansion rate of silicon-carbon anode materials have been solved, realizing a composite silicon-carbon anode material with high capacity, long cycle stability, and low expansion rate.

CN122417832APending Publication Date: 2026-07-17HUIZHOU SAILIDA IND CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUIZHOU SAILIDA IND CO LTD
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-carbon anode materials in lithium-ion batteries suffer from problems such as low initial coulombic efficiency, insufficient cycle stability, large electrode expansion rate, and poor capacity recovery, making it difficult to simultaneously achieve volume expansion buffering, interfacial bonding, and electrolyte adsorption and wetting functions.

Method used

The structure adopts a core of CVD silicon carbon, with an outer layer of composite conductive layer and graphite coating layer. A multi-level conductive network is constructed using modified conductive precursors, hydroxylated single-walled carbon nanotubes and modified graphite. Elastic polymers and highly absorbent polymer emulsions are introduced to enhance interfacial compatibility and electrolyte holding capacity.

Benefits of technology

It improves electron transport efficiency and active material utilization, enhances electrode structure stability, increases initial discharge specific capacity, coulombic efficiency and cycle capacity retention, reduces electrode expansion risk, and has good long-cycle stability and industrialization value.

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Abstract

本发明涉及锂离子电池技术领域,具体公开了一种复合硅碳负极材料及其制备方法。所述复合硅碳负极材料由内而外依次包括:内核、复合导电层以及石墨包覆层;所述内核为CVD硅碳;所述复合导电层由前驱体浆料包覆于所述内核表面并经固化制成;所述石墨包覆层由石墨包覆浆料包覆于所述复合导电层表面并经固化制成;本发明通过构建多级导电网络、柔性缓冲网络和储液润湿网络的协同复合结构,有利于提高复合硅碳负极材料的首次库仑效率、负极克容量和循环容量保持率,并降低极片膨胀率、提高容量恢复率,从而显著提升复合硅碳负极材料的综合电化学性能和应用稳定性。
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