Positive electrode material, preparation method thereof, positive electrode sheet, sodium ion battery and electric device

By using a composite phase single-crystal layered oxide coating layer with the same composition as the core on the surface of the cathode material, the problems of high residual alkali content and low conductivity on the surface are solved, thereby improving the electrochemical performance and structural stability of sodium-ion batteries.

CN122417847APending Publication Date: 2026-07-17BEIJING EASPRING MATERIAL TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
BEIJING EASPRING MATERIAL TECH CO LTD
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The common problem in existing sodium-ion battery cathode materials is the high residual alkali content on the surface, which affects the electrochemical performance of the battery, and the low conductivity of the coating layer.

Method used

The coating layer uses the same composition as the cathode material. The core is an O3 phase single-crystal layered oxide, and the coating layer is a composite phase single-crystal layered oxide. By controlling the composition ratio and thickness, the crystal lattice matching of the core and the coating layer is achieved, the residual alkali on the surface is reduced, and the conductivity and structural stability are improved.

Benefits of technology

It significantly improves the electrochemical performance of cathode materials, including cycle performance and air stability, reduces the generation of gases such as CO2 and H2, inhibits the dissolution of transition metals and interfacial side reactions, and improves the structural stability of materials and the electrochemical performance of batteries.

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Abstract

本申请涉及电池技术领域,公开了正极材料及其制备方法、正极片、钠离子电池、用电装置。该正极材料包括正极材料颗粒,正极材料颗粒包括包覆层和内核;内核包括式1所示的化合物,且所述内核为O3相单晶层状氧化物;包覆层包括式2所示的化合物,且所述包覆层为复合相单晶层状氧化物;Naa1(Nix1Fey1Mnz1Md1)O2式1,Nab1(Nix2Fey2Mnz2Md2)O2式2;其中,0.90≤a1≤1.10,0<x1≤0.5,0<y1≤0.5,0<z1≤0.5,0<d1≤0.3,x1+y1+z1+d1=1,且y1>y2,z2>z1;M为掺杂元素,包括Sn、Ce、La、Co、Ca、Cu、Sr、Y、Ti、V、Mg、B、Cr、Sb、Al、Zn、Zr、Nb、W、Li中的至少一种。该正极材料表面的残碱低、电化学性能优异,使用该正极材料的钠离子电池具有优异的电化学性能。
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