Rubber-metal composite plate coiled material production system and rubber-metal composite plate

By designing a rubber metal composite board coil production system and using an extruder and vulcanized drying channel for solvent-free production, the problems of complex production processes and environmental pollution are solved, and the effects of process simplification, efficiency improvement and cost reduction are achieved.

CN222521847UActive Publication Date: 2025-02-25GUILIN JINGU NEW MATERIAL CO LTD
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Patent Information

Application Number
CN202421336042.8
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-06-12
Publication Date
2025-02-25
Estimated Expiration
2034-06-12

AI Technical Summary

Technical Problem

The production process of traditional rubber metal composite panels is complex and requires a large amount of organic solvents, which leads to environmental pollution and waste of materials. At the same time, the investment cost of calendering method is high, technical difficulty and low production efficiency.

Method used

A rubber metal composite board coil production system is designed, including retracting and unwinding equipment, extrusion glue attachment equipment and vulcanized drying channels. The mixing glue is plasticized and evenly coated on both sides of the metal substrate through an extruder. After that, high-temperature vulcanization is carried out in the vulcanized drying channel. The entire process does not require organic solvents, which simplifies the process and improves production efficiency.

Benefits of technology

It has achieved simplification and efficiency improvement in the production process, no need to use organic solvents, which reduces environmental pollution and material waste and reduces production costs.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model discloses a rubber metal composite plate coiled material production system and a rubber metal composite plate, the production system comprises a reeling and unreeling device, an extrusion glue attaching device and a vulcanization drying tunnel, the reeling and unreeling device supports a metal base material to be produced and reels the produced rubber metal composite plate; the extrusion adhesive-attaching equipment comprises an extruder and an adhesive-attaching mouth-shaped die, the adhesive-attaching mouth-shaped die comprises an upper mouth-shaped part and a lower mouth-shaped part, a gap is formed between the upper mouth-shaped part and the lower mouth-shaped part, rubber runners are arranged on the upper mouth-shaped part and the lower mouth-shaped part, and the vulcanization drying tunnel is used for supporting the extruded rubber-metal composite plate for vulcanization. According to the utility model, the rubber material is extruded into the rubber runner through the extruder, when the metal base material passes through the gap, the extruded rubber material is coated to two surfaces from the rubber runner, and then the metal base material is fed into the vulcanization drying tunnel for vulcanization, so that the whole production process is simple in process, high in production efficiency, free of organic solvents and calendaring facilities, small in environmental pollution and low in production cost. And the production cost is effectively reduced.
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Description

Technical Field

[0001] The utility model relates to the technical field of rubber sealing materials, in particular to a rubber-metal composite plate coil production system and a rubber-metal composite plate. Background Art

[0002] Rubber metal composite sheet is an indispensable material for seals and is widely used in seals of oil pumps, motorcycles, automobile cylinders, etc. Traditional rubber metal composite sheets generally dissolve and filter the rubber material to obtain the rubber coating, then attach the rubber coating to the metal plate by spraying, pouring, rolling, or scraping, and then send it to the drying oven for vulcanization after drying. The production process is not only complicated but also requires a large amount of organic solvents. A large amount of volatile organic compounds will be generated during production, which will cause great pollution to the environment and waste of production materials. There are also some that use four-roll calendering for solvent-free production of rubber metal composite sheets, and the rubber layer is attached to the metal sheet by a calender, but the calendering method has high investment costs, high technical difficulty, and low production efficiency. Utility Model Content

[0003] The main purpose of the utility model is to overcome the defects of the above-mentioned background technology and provide a rubber-metal composite plate coil production system and a rubber-metal composite plate.

[0004] To achieve the above-mentioned purpose, the rubber-metal composite plate coil production system proposed in the utility model includes: a winding and unwinding device, an extrusion and adhesive device and a vulcanization oven, wherein the winding and unwinding device includes an unwinding device and a winding device, wherein the unwinding device is used to support and install the rolled metal substrate for production, and the winding device is used to collect the high-temperature vulcanized rubber-metal composite plate into a roll; the extrusion and adhesive device includes an extruder and an adhesive die, wherein the adhesive die is installed on the extruder, and the adhesive die includes an upper die portion and a lower die portion, wherein a gap is provided between the upper die portion and the lower die portion for the metal substrate unrolled from the unwinding device to pass through, and the upper die portion and the lower die portion are respectively provided with a rubber flow channel connected to the gap, and one end of the rubber flow channel is connected to the extrusion port on the extruder; the vulcanization oven includes an oven box and a conveyor belt, wherein the conveyor belt is arranged in the oven box and is used to lift the rubber-metal composite plate passing through the oven box for vulcanization. The extruder plasticizes the rubber compound and extrude it into the rubber flow channels of the upper and lower die parts respectively. The metal substrate is simultaneously pulled through the gap between the upper and lower die parts. The extruded rubber compound is evenly coated on the upper and lower surfaces of the metal substrate from the upper and lower independent rubber flow channels to ensure that the thickness of the rubber film on the upper and lower surfaces of the metal substrate is consistent. The rubber-metal composite plate with adhesive is put into the vulcanization oven for high-temperature vulcanization and then wound onto the winding device to complete the production.

[0005] The technical solution is further optimized, and further includes a first auxiliary roller, which is arranged between the extrusion adhesive device and the vulcanization oven. After the extrusion adhesive device completes the adhesive bonding, the metal substrate passes through the first auxiliary roller and enters the oven box of the vulcanization oven for vulcanization. The rubber-metal composite plate that has just been adhesive-bonded is restricted by the first auxiliary roller to ensure its transmission stability.

[0006] The technical solution is further optimized, and further includes a second auxiliary roller, which is arranged between the winding device and the vulcanization drying tunnel. After the rubber-metal composite plate comes out of the vulcanization drying tunnel, it passes through the second auxiliary roller and enters the winding device for winding. The newly vulcanized rubber-metal composite plate is restricted by the second auxiliary roller to ensure its stability in transmission in the drying tunnel box.

[0007] To further optimize the technical solution, wear-resistant blocks are provided at both ends of the gap to limit the metal substrate in the gap, thereby preventing the metal substrate from shaking left and right when the adhesive is attached, thereby affecting the adhesive effect.

[0008] To further optimize the technical solution, a rubber discharge port is provided between the wear-resistant block far from one end of the extruder and the upper die portion and the lower die portion, so as to discharge the rubber material that has been staying in the rubber flow channel for a long time and has generated scorched particles through the rubber discharge port.

[0009] To further optimize the technical solution, the upper die portion and the lower die portion are respectively provided with flow regulating ports on the side close to the extruder, the flow regulating ports penetrate into the corresponding rubber flow channel, and a flow regulating bolt is provided in the flow regulating port. The flow of the rubber material in the rubber flow channel is adjusted by rotating the flow regulating bolt.

[0010] To further optimize the technical solution, temperature control water channels are respectively provided on the upper mouth portion and the lower mouth portion, and the temperature control water channels are used to cool the rubber in the rubber flow channels entering the upper mouth portion and the lower mouth portion, and the temperature of the rubber is indirectly controlled by controlling the water inlet flow rate of the temperature control water channels.

[0011] To further optimize the technical solution, the rubber flow channel includes a main flow channel and a side flow channel, the main flow channel and the side flow channel are connected, and the cross-sections of the main flow channel and the side flow channel are in a "comma" structure, the head of the "comma" is the main flow channel, and the inner diameter is larger, which is conducive to the flow of rubber and ensures smooth flow of rubber, and the tail of the "comma" is the side flow channel, and the inner diameter is smaller, which is conducive to uniformly dispersing the rubber pressure and making the rubber fluid evenly attached to the metal substrate.

[0012] The utility model also provides a rubber-metal composite plate, which is produced by the rubber-metal composite plate coil production system. The rubber-metal composite plate comprises a metal substrate and a rubber layer, and the rubber layer is coated on both the upper and lower surfaces of the metal substrate.

[0013] To further optimize the technical solution, the material of the metal substrate is any one of stainless steel plate, cold-rolled plate, and copper plate, and the material of the rubber layer is any one of nitrile rubber, fluororubber, and EPDM rubber.

[0014] The beneficial effects of the utility model include: plasticizing the mixed rubber through an extruder, and then extruding it into the rubber flow channels of the upper die portion and the lower die portion, while the unwinding device unwinds the metal substrate to be coated with glue, and the winding device performs winding and traction, and when the metal substrate passes through the gap between the upper die portion and the lower die portion, the extruded mixed rubber material is uniformly coated on the upper and lower surfaces of the metal substrate from the upper and lower independent rubber flow channels at the same time, ensuring that the thickness of the glue film on the upper and lower surfaces of the metal substrate is consistent, and the rubber-metal composite plate after the glue is attached enters the vulcanization oven for high-temperature vulcanization and is then wound onto the winding device to complete the production. The entire production process is simple in technology and high in production efficiency, does not require the use of organic solvents, and does not require calendering facilities, has little pollution to the environment, requires little facility investment, and effectively reduces production costs. BRIEF DESCRIPTION OF THE DRAWINGS

[0015] Figure 1 It is an overall schematic diagram of a rubber metal composite sheet coil production system in an embodiment of the utility model.

[0016] Figure 2 It is a cross-sectional schematic diagram of an adhesive extrusion device in an embodiment of the utility model.

[0017] Figure 3 It is a cross-sectional schematic diagram of a die with a glue port in an embodiment of the present invention.

[0018] Figure 4 yes Figure 3 Schematic diagram of the cross section of AA.

[0019] Figure 5 It is a schematic diagram of the extrusion production of the adhesive extrusion equipment in the embodiment of the utility model.

[0020] Figure numerals: 1 unwinding device; 2 winding device; 3 metal substrate; 4 extrusion adhesive device; 401 extruder; 402 adhesive die; 403 upper die; 404 lower die; 405 gap; 406 rubber flow channel; 4061 main flow channel; 4062 side flow channel; 407 extrusion outlet; 408 wear-resistant block; 409 glue discharge outlet; 4010 flow regulating outlet; 4011 flow regulating bolt; 4012 temperature control water channel; 5 vulcanization drying tunnel; 501 drying tunnel box; 502 conveyor belt; 6 first auxiliary roller; 7 second auxiliary roller; 8 rubber metal composite plate; 9 rubber layer. DETAILED DESCRIPTION

[0021] In order to make the technical problems, technical solutions and beneficial effects to be solved by the embodiments of the present invention more clearly understood, the present invention is further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention and are not intended to limit the present invention.

[0022] It should be noted that when a component is referred to as being "fixed to" or "disposed on" another component, it can be directly on the other component or indirectly on the other component. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or indirectly connected to the other element. In addition, connection can be used for both fixing and circuit connection.

[0023] It should be understood that the terms "length", "width", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", etc., indicating the orientation or position relationship, are based on the orientation or position relationship shown in the accompanying drawings, and are only for the convenience of describing the embodiments of the utility model and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the utility model.

[0024] In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Therefore, a feature defined as "first" or "second" may explicitly or implicitly include one or more of the features. In the description of the embodiments of the present utility model, the meaning of "multiple" is two or more, unless otherwise clearly and specifically defined.

[0025] See also Figures 1 to 5In one embodiment, a rubber-metal composite plate coil production system disclosed herein comprises a winding and unwinding device, an adhesive extrusion device 4 and a vulcanization drying tunnel 5. The winding and unwinding device comprises a winding device 1 and a winding device 2. The winding device 1 is arranged at the starting end of the production system, and is used to support and install a rolled metal substrate 3 for production, and to control the winding speed of the metal substrate 3 coil during production. The winding device 2 is arranged at the end of the production system, and is used to roll the finished rubber-metal composite plate 8 that has been vulcanized at high temperature for storage and transportation. The winding device 2 provides traction power during production through a rotating device (not shown) that drives a power. Both the winding device 1 and the winding device 2 are prior art equipment, and they have The structure of the body is not repeated; the extrusion adhesive device 4 includes an extruder 401 and an adhesive die 402, the adhesive die 402 is installed on the extruder 401, the adhesive die 402 includes an upper die portion 403 and a lower die portion 404, a gap 405 is provided between the upper die portion 403 and the lower die portion 404 for the metal substrate 3 unwound from the unwinding device 1 to pass through, and a rubber flow channel 406 connected to the gap 405 is provided on the upper die portion 403 and the lower die portion 404, respectively, and one end of the rubber flow channel 406 is connected to the extrusion port 407 on the extruder 401, and the vulcanization drying tunnel 5 includes a drying tunnel box 501 and a conveyor belt 502, and the conveyor belt 502 is arranged on the drying tunnel The box 501 is used to lift the rubber-metal composite plate 8 passing through the oven box 501 for vulcanization, so as to prevent the rubber-metal composite plate from shaking and scratching the rubber layer during the vulcanization transmission in the vulcanization oven 5. Specifically, the conveying speed of the conveyor belt 502 is consistent with the traction movement speed of the rubber-metal composite plate 8, so as to avoid the friction and scratches caused by the relative movement between the rubber-metal composite plate 8 and the conveyor belt 502 due to the speed difference. Of course, the conveyor belt 502 can also be replaced by a conveying roller. In this embodiment, the extruder 401 plasticizes the mixed rubber, and then extrude it through the extrusion port 407 into the rubber flow channel 406 corresponding to the upper die portion 403 and the lower die portion 404 respectively. At the same time, the unwinding device 1 unwinds the metal substrate 3 to be coated with glue, and the winding device 2 performs winding and traction. When the metal substrate 3 passes through the gap 405 between the upper die portion 403 and the lower die portion 404, the extruded mixed rubber material is uniformly coated on the upper and lower surfaces of the metal substrate 3 from the upper and lower independent rubber flow channels 406 to attach glue, ensuring that the thickness of the glue film on the upper and lower surfaces of the metal substrate 3 is consistent. The rubber-metal composite plate 8 after adhesive attachment enters the vulcanization drying tunnel 5 for high-temperature vulcanization and is then wound onto the winding device 2 to complete the production. The entire production process has a simple process route and high production efficiency, does not require the use of organic solvents, and does not require calendering facilities, has little pollution to the environment, requires little facility investment, and effectively reduces production costs.

[0026] In a preferred embodiment, the disclosed rubber-metal composite sheet coil production system further includes a first auxiliary roller 6, which is disposed between the extrusion adhesive device 4 and the vulcanization drying tunnel 5. After the metal substrate 3 is glued by the extrusion adhesive device 4, it passes through the first auxiliary roller 6 and enters the drying tunnel box 501 of the vulcanization drying tunnel 5 for vulcanization. The first auxiliary roller 6 limits the rubber-metal composite sheet 8 that has just been glued, ensuring its transmission stability and preventing the rubber-metal composite sheet 8 from shaking during the traction process, which affects the effect of the extrusion adhesive.

[0027] In a preferred embodiment, the disclosed rubber-metal composite sheet coil production system further includes a second auxiliary roller 7, which is disposed between the winding device 2 and the vulcanization drying tunnel 5. After the rubber-metal composite sheet 8 comes out of the vulcanization drying tunnel 5, it passes through the second auxiliary roller 7 and enters the winding device 2 for winding. The second auxiliary roller 7 limits the newly vulcanized rubber-metal composite sheet 8 to ensure its stability in transmission in the drying tunnel box 501, and prevents the rubber-metal composite sheet 8 from shaking during the traction process, scratching the rubber layer 9, and affecting the vulcanization effect.

[0028] In a specific example, wear-resistant blocks 408 are provided at both ends of the gap 405. The distance between the two wear-resistant blocks 408 corresponds to the width of the metal substrate 3. The wear-resistant blocks 408 limit the metal substrate 3 from shaking left and right when the adhesive is attached in the gap 405, thus affecting the adhesive attachment effect.

[0029] In a specific example, a rubber leakage port 409 is provided between the wear-resistant stopper 408 at one end away from the extruder 401 and the upper die portion 403 and the lower die portion 404. When the rubber material accumulates and stays in the rubber flow channel 406 for too long, the rubber material can flow out from the rubber leakage port 409, thereby preventing the rubber material from staying in the rubber flow channel 406 for a long time to generate scorched particles, which may cause quality problems in the extruded rubber-metal composite plate 8.

[0030] In a specific example, flow regulating ports 4010 are respectively provided on one side of the upper die portion 403 and the lower die portion 404 close to the extruder 401, and the flow regulating ports 4010 penetrate into the corresponding rubber flow channel 406, and a flow regulating bolt 4011 is provided in the flow regulating port 4010. By turning the flow regulating bolt 4011, the bottom end of the flow regulating bolt 4011 extends into the rubber flow channel 406, thereby adjusting the channel opening size of the rubber flow channel 406 to adjust the flow, so that the flow of the rubber in the rubber flow channel 406 of the upper die portion 403 and the lower die portion 404 can be controlled to be consistent, so as to control the thickness of the adhesive on the upper and lower sides of the metal substrate 3 to be the same.

[0031] In a specific example, a temperature control water channel 4012 is provided on the upper mouth portion 403 and the lower mouth portion 404 respectively. The temperature control water channel 4012 is connected to an external cooling water source. The cooling water flow entering the temperature control water channel 4012 is controlled to adjust the temperature of the rubber entering the rubber flow channel 406 of the upper mouth portion 403 and the lower mouth portion 404, thereby ensuring that the rubber can be effectively attached to the metal substrate 3.

[0032] In a preferred embodiment, the rubber flow channel 406 includes a main flow channel 4061 and a side flow channel 4062, the main flow channel 4061 and the side flow channel 4062 are connected, and the vertical sections of the main flow channel 4061 and the side flow channel 4062 are in a "comma" structure. When the metal substrate 3 is wider, the rubber flow channel 406 is relatively long. The conventional flow channel design will cause difficulty in the flow of the rubber, and the pressure difference between the front and the back is too large, resulting in uneven thickness of the rubber film; and by setting the vertical section of the rubber flow channel 406 to a "comma" structure, the head of the "comma", that is, the main flow channel 4061, has a larger inner diameter, which is conducive to the flow of the rubber and ensures smooth flow of the rubber. The tail of the "comma", that is, the side flow channel 4062, has a smaller inner diameter, which is conducive to uniformly dispersing the pressure of the rubber, so that the rubber fluid is evenly attached to the metal substrate 3.

[0033] An embodiment of the utility model further discloses a rubber-metal composite plate 8, which is produced by the above-mentioned rubber-metal composite plate coil production system. The rubber-metal composite plate 8 includes a metal substrate 3 and a rubber layer 9, and the upper and lower surfaces of the metal substrate 3 are coated with the rubber layer 9.

[0034] In a preferred embodiment, the material of the metal substrate 3 is any one of stainless steel plate, cold-rolled plate, and copper plate, preferably stainless steel plate, and the material of the rubber layer 9 is any one of nitrile rubber, fluororubber, and EPDM rubber, preferably nitrile rubber.

[0035] When the rubber-metal composite plate coil production system of the utility model is used to produce the rubber-metal composite plate 8, the mixed rubber used for production and the metal substrate 3 coil for the adhesive are first prepared, the metal substrate 3 and the traction plate are spliced ​​and passed through the gap 405 between the upper die portion 403 and the lower die portion 404, the extrusion temperature of the extruder 401 is set, the temperature of the adhesive die 402 is set, the vulcanization drying tunnel 5 is turned on and the drying tunnel temperature is set, and after the temperatures of the extruder 401, the adhesive die 402 and the vulcanization drying tunnel 5 meet the process requirements, the prepared rubber strip is fed into the extruder 401, the adhesive die 402 and the vulcanization drying tunnel 5. The rubber material flows out of the rubber discharge port 409 on 402, and the metal substrate 3 is unwound by the traction plate into the gap 405 to start extruding the attached rubber. The attached rubber is extruded for about 1 meter, and the appearance and thickness of the attached rubber layer 9 are inspected. If it is within the qualified range, continuous extrusion production can be started. If it is not within the qualified range, the flow rate (extrusion speed) of the rubber flow channel 406 and the traction speed of the metal substrate 3 are adjusted until it is qualified. When the extruded rubber-metal composite plate 8 passes through the vulcanization drying tunnel 5 for high-temperature vulcanization, it is inspected online. If the product is qualified, production continues, and the rubber-metal composite plate 8 is rolled up to the winding device 2 for storage.

[0036] The above content is a further detailed description of the utility model in combination with specific / preferred embodiments, and it cannot be determined that the specific implementation of the utility model is limited to these descriptions. For ordinary technicians in the technical field to which the utility model belongs, without departing from the concept of the utility model, it can also make several substitutions or modifications to these described embodiments, and these substitutions or modifications should be regarded as belonging to the scope of protection of the utility model. In the description of this specification, the description of the reference terms "an embodiment", "some embodiments", "preferred embodiments", "examples", "specific examples" or "some examples" means that the specific features, structures, materials or characteristics described in combination with the embodiment or example are included in at least one embodiment or example of the utility model. In this specification, the schematic representation of the above terms does not necessarily target the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described can be combined in any one or more embodiments or examples in a suitable manner. In the absence of mutual contradiction, those skilled in the art can combine and combine the different embodiments or examples described in this specification and the features of different embodiments or examples. Although the embodiments of the present invention and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations may be made herein without departing from the scope of protection of the patent application.

Claims

1. A rubber metal composite sheet coil production system, characterized in that: include: The unwinding and winding equipment includes an unwinding device and a winding device, wherein the unwinding device is used to support and install the rolled metal substrate for production, and the winding device is used to roll the high-temperature vulcanized rubber-metal composite plate; An adhesive extrusion device, the adhesive extrusion device comprising an extruder and an adhesive die, the adhesive die being mounted on the extruder, the adhesive die comprising an upper die portion and a lower die portion, a gap being provided between the upper die portion and the lower die portion for the metal substrate unwound from the unwinding device to pass through, a rubber flow channel being provided on the upper die portion and the lower die portion respectively and being connected to the gap, one end of the rubber flow channel being connected to an extrusion port on the extruder; The vulcanization oven comprises an oven box and a conveyor belt. The conveyor belt is arranged in the oven box and is used to lift the rubber-metal composite plate passing through the oven box for vulcanization.

2. The rubber-metal composite sheet coil production system according to claim 1, characterized in that: It also includes a first auxiliary roller, which is arranged between the extrusion adhesive device and the vulcanization oven. After the extrusion adhesive device completes the adhesive attachment, the metal substrate passes through the first auxiliary roller and enters the oven box of the vulcanization oven for vulcanization.

3. The rubber-metal composite sheet coil production system according to claim 2, characterized in that: It also includes a second auxiliary roller, which is arranged between the winding device and the vulcanization drying tunnel. After the rubber-metal composite plate comes out of the vulcanization drying tunnel, it passes through the second auxiliary roller and enters the winding device for winding.

4. The rubber-metal composite sheet coil production system according to claim 3, characterized in that: Wear-resistant blocks are arranged at both ends of the gap.

5. The rubber-metal composite sheet coil production system according to claim 4, characterized in that: A glue discharge port is provided between the wear-resistant stopper away from one end of the extruder and the upper die portion and the lower die portion.

6. The rubber-metal composite sheet coil production system according to claim 5, characterized in that: The upper die portion and the lower die portion are respectively provided with flow regulating ports on one side close to the extruder, and the flow regulating ports penetrate into the corresponding rubber flow channels, and flow regulating bolts are provided in the flow regulating ports.

7. The rubber-metal composite sheet coil production system according to claim 6, characterized in that: The upper die portion and the lower die portion are respectively provided with temperature control water channels.

8. The rubber-metal composite sheet coil production system according to claim 7, characterized in that: The rubber flow channel includes a main flow channel and a side flow channel, the main flow channel and the side flow channel are connected, and the cross-sections of the main flow channel and the side flow channel are in a "comma" structure.

9. A rubber metal composite plate, characterized in that: The rubber-metal composite plate coil production system is used as claimed in any one of claims 1 to 8, wherein the rubber-metal composite plate comprises a metal substrate and a rubber layer, and the rubber layer is coated on both the upper and lower surfaces of the metal substrate.

10. The rubber-metal composite plate according to claim 9, characterized in that: The material of the metal substrate is any one of a stainless steel plate, a cold-rolled plate, and a copper plate; the material of the rubber layer is any one of a nitrile rubber, a fluororubber, and an EPDM rubber.