Heating device and mobile phone shell

By designing a heating device for electronic products, the problem of degradation of electronic products' battery performance in low-temperature environments is solved, and the battery temperature is effectively maintained under low-temperature conditions, extend the service life of the equipment and improve the user experience.

CN223053129UActive Publication Date: 2025-07-01GUANGDONG HUATENG SHENGLI TECH CO LTD
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Patent Information

Application Number
CN202422258304.X
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-09-14
Publication Date
2025-07-01
Estimated Expiration
2034-09-14

AI Technical Summary

Technical Problem

In low-temperature environments, the power consumption of lithium-ion batteries of electronic products increases, resulting in rapid power loss of equipment, limiting the availability of electronic products under low-temperature conditions.

Method used

A heating device is designed, including a main body and an automatic temperature heating component. The automatic temperature heating component includes an automatic temperature heating plate and a power circuit. The position of the heating plate corresponds to the driving power position of the electronic product. The power circuit supplies power to heat the heating plate to a preset temperature.

Benefits of technology

In a low temperature environment, the heating device can quickly increase the temperature around the driving power supply to between 40°C and 50°C, improve the working state of the driving power supply, reduce the occurrence of power failure, and ensure the safety and stability of the battery during heating.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model discloses a heating device and a mobile phone shell, and the heating device comprises a main body which is used for being connected with an electronic product; the automatic temperature control heating assembly is connected to the main body, the automatic temperature control heating assembly comprises an automatic temperature control heating sheet and an electrifying loop, the position of the automatic temperature control heating sheet corresponds to the position of a driving power supply of the electronic product, and the electrifying loop is electrically connected with the automatic temperature control heating sheet; wherein the power-on loop is used for being connected with a power supply, supplying power to the self-temperature-control heating sheet, driving the self-temperature-control heating sheet to heat to a preset temperature and keeping the temperature at the preset temperature so as to heat the driving power supply. The peripheral temperature of the driving power supply can be quickly increased to a preset range, such as 40-50 DEG C, in a low-temperature environment, so that the working state of the driving power supply is effectively improved, the performance of the driving power supply under the low-temperature condition is improved, the power failure phenomenon is reduced, the safety and stability of a battery in the heating process are ensured, and the service life of the battery is prolonged. And the device is suitable for various types of electronic products.
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Description

Technical Field

[0001] The utility model relates to the technical field of electronic accessories, in particular to a heating device and a mobile phone case with a heating device. Background Art

[0002] With the rapid development of mobile communication technology and consumer electronic products, smart phones and other portable electronic products have become an indispensable part of people's daily lives. However, the normal operation of these devices depends on the good working condition of their built-in batteries. Especially in cold climate conditions, such as during winter outdoor activities, low temperature will have a significant negative impact on common portable device batteries such as lithium-ion batteries. Research shows that in an environment of minus 5 degrees Celsius, the power consumption of the same mobile phone will increase to 1.7 times that at standard room temperature (about 20 degrees Celsius); and when the ambient temperature further drops to minus 30 degrees Celsius, most of the tested mobile phones will experience automatic shutdown, that is, the so-called "power-off" problem. This phenomenon greatly limits the usability of electronic products under low temperature conditions and brings great inconvenience to the user experience.

[0003] Traditional solutions often focus on improving the battery material itself or optimizing the battery management system, but these methods usually are difficult to achieve significant effects in a short time and may be accompanied by an increase in cost. In addition, some auxiliary devices on the market, such as external battery packs or heating pads, although they can alleviate the problems brought by low temperature to a certain extent, most of them rely on chemical reaction heat release, have problems such as unstable temperature control, inconvenient use, and may have certain safety hazards.

[0004] In view of this, there is an urgent need for a new solution to address the problem of the decline in battery performance of electronic products in low temperature environments. An ideal solution should be able to effectively maintain the temperature of the battery surrounding environment, ensure that the battery can still maintain a good working state under low temperature conditions, and at the same time, this solution should also have the characteristics of convenient use, safety and reliability. Summary of the Utility Model

[0005] The utility model aims to solve at least one of the technical problems existing in the prior art. For this reason, the utility model provides a heating device, which effectively solves the problem of rapid power-off of the driving power supply of electronic products in low temperature environments. When applied, it has uniform heating and constant temperature, uses a safe voltage and PTC material, avoids the risk of overheating, ensures the safety and reliability of the device, and improves the user experience under cold conditions.

[0006] The utility model also provides a mobile phone case with the above-mentioned heating device.

[0007] According to the heating device of the utility model, it includes:

[0008] A main body for connecting to an electronic product;

[0009] A self - controlled temperature heating component connected to the main body. The self - controlled temperature heating component includes a self - controlled temperature heating sheet and an energizing circuit. The position of the self - controlled temperature heating sheet corresponds to the position of the driving power supply of the electronic product, and the energizing circuit is electrically connected to the self - controlled temperature heating sheet;

[0010] Wherein, the energizing circuit is used to connect to a power supply and supply power to the self - controlled temperature heating sheet, driving the self - controlled temperature heating sheet to heat up to a preset temperature and maintain at the preset temperature to heat the driving power supply.

[0011] The heating device according to the present utility model has at least the following beneficial effects: By designing the self - controlled temperature heating component corresponding to the position of the driving power supply of the electronic product, the temperature around the driving power supply can be rapidly increased to the preset range, such as between 40°C and 50°C, in a low - temperature environment, thereby effectively improving the working state of the driving power supply. It can not only improve the performance of the driving power supply under low - temperature conditions and reduce the occurrence of power - off phenomena, but also ensure the safety and stability of the battery during the heating process due to the characteristics of uniform heating surface and constant temperature; In addition, the design of this device is convenient for installation and disassembly, has strong adaptability, and is suitable for use with various types of electronic products.

[0012] According to some embodiments of the present utility model, for the heating device, the main body includes an annular part, the annular part is arranged around the peripheral wall of the electronic product, and the annular part is detachably sleeved on the electronic product.

[0013] According to some embodiments of the present utility model, for the heating device, the annular part is provided with an avoidance groove, and the avoidance groove is used for the electrical interface of the power supply to pass through to energize the energizing circuit.

[0014] According to some embodiments of the present utility model, for the heating device, the main body includes a supporting part, the self - controlled temperature heating sheet is installed on the inner side or the outer side of the supporting part, and the supporting part is adapted to abut against the outer wall of the electronic product for heat conduction.

[0015] According to some embodiments of the present utility model, for the heating device, the self - controlled temperature heating sheet includes a first PI film layer, a conductive layer, an electroplated layer, a PTC paste layer, and a second PI film layer which are sequentially laminated.

[0016] According to some embodiments of the present utility model, for the heating device, the preset temperature is A, satisfying: 40°≤A≤50°.

[0017] The heating device according to some embodiments of the present utility model, the power supply is installed inside the main body, a control button is provided on the outer wall of the main body, the control button is electrically connected to the power supply, and is used to control the turning on and off of the power supply.

[0018] The heating device according to some embodiments of the present utility model, the power supply is a receiving coil, and the receiving coil is charged by wireless charging.

[0019] The heating device according to some embodiments of the present utility model, the power supply is a storage battery, the main body is provided with an installation groove, the storage battery is installed in the installation groove, the main body is further installed with a heat conducting plate, one end face of the heat conducting plate is used to cover the self-controlled temperature heating sheet, and the other end face is used to abut against the driving power supply of the electronic product.

[0020] The mobile phone case according to the present utility model includes the heating device according to the present utility model.

[0021] The mobile phone case according to the present utility model has at least the following beneficial effects: by correspondingly designing the self-controlled temperature heating component with the position of the driving power supply of the electronic product, the temperature around the driving power supply can be rapidly increased to a preset range in a low-temperature environment. Such a mobile phone case can not only protect the mobile phone from external impacts, but more importantly, it can effectively improve the working efficiency of the mobile phone battery in a low-temperature environment, ensure the normal use of the mobile phone in cold conditions, and greatly facilitate the user's outdoor activities.

[0022] The additional aspects and advantages of the present utility model will be partly given in the following description, partly will become obvious from the following description, or will be understood through the practice of the present utility model. BRIEF DESCRIPTION OF THE DRAWINGS

[0023] The above and / or additional aspects and advantages of the present utility model will become obvious and easy to understand from the description of the embodiments in conjunction with the following drawings, wherein:

[0024] Figure 1 is an exploded view of the heating device according to an embodiment of the present utility model;

[0025] Figure 2 is a schematic structural diagram of the heating device according to an embodiment of the present utility model;

[0026] Figure 3 is a schematic structural diagram of the heating device according to another embodiment of the present utility model;

[0027] Figure 4 is Figure 3 the exploded view of the shown heating device;

[0028] Figure 5Structural schematic diagram of a heating device according to another embodiment of the present utility model;

[0029] Figure 6 is Figure 5 exploded view of the heating device shown;

[0030] Figure 7 Structural schematic diagram of a self - controlled temperature heating sheet of a heating device according to an embodiment of the present utility model;

[0031] Figure 8 Application schematic diagram of a mobile phone case according to an embodiment of the present utility model.

[0032] Explanation of reference numerals in the drawings:

[0033] Main body 100; mounting groove 101; control button 102; fixing protrusion 103; annular part 110; clearance groove 1101; supporting part 120;

[0034] Self - controlled temperature heating component 200; self - controlled temperature heating sheet 210; first PI film layer 211; conductive layer 212; electroplated layer 213; PTC paste layer 214; second PI film layer 215; energizing circuit 220; electrical interface 230;

[0035] Receiving coil 310; magnetic attracting ring 311; storage battery 320;

[0036] Heat conducting plate 400;

[0037] Artificial leather 500; partition 510;

[0038] Rear cover 600; positioning post 610; fixing block 620;

[0039] Circuit board 700;

[0040] Mobile phone 800. Detailed implementation manners

[0041] The embodiments of the present utility model will be described in detail below. Examples of the embodiments are shown in the drawings, where the same or similar reference numerals represent the same or similar elements or elements with the same or similar functions from beginning to end. The embodiments described below by referring to the drawings are exemplary and are only used to explain the present utility model and should not be construed as a limitation of the present utility model.

[0042] In the description of the present utility model, it should be understood that the orientation or positional relationship indicated by terms such as up, down, front, back, left, right, etc. is based on the orientation or positional relationship shown in the drawings. It is only for the convenience of describing the present utility model and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus should not be construed as a limitation of the present utility model.

[0043] In the description of the present utility model, the meaning of "several" is one or more, the meaning of "multiple" is more than two, and understandings such as "greater than", "less than", "exceeding", etc. do not include the base number, and understandings such as "above", "below", "within", etc. include the base number. If there is a description of "first" and "second", it is only for the purpose of distinguishing technical features and cannot be understood as indicating or implying relative importance or implicitly indicating the quantity of the indicated technical features or implicitly indicating the sequence relationship of the indicated technical features.

[0044] In the description of the present utility model, unless otherwise clearly defined, words such as "set", "installed", "connected", etc. should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above words in the present utility model in combination with the specific content of the technical solution.

[0045] In the description of the present utility model, the description with reference to terms such as "one embodiment", "some embodiments", "schematic embodiments", "examples", "specific examples", or "some examples", etc. means that the specific features, structures, materials, or characteristics described in connection with the embodiment or example are included in at least one embodiment or example of the present utility model. In this specification, the schematic expressions of the above terms do not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials, or characteristics described can be combined in a suitable manner in any one or more embodiments or examples.

[0046] With the rapid development of mobile communication technology and consumer electronic products, smart phones and other portable electronic products have become an indispensable part of people's daily lives. However, the normal operation of these devices depends on the good working condition of their built-in batteries. Especially in cold climatic conditions, such as during winter outdoor activities, low temperature will have a significant negative impact on common portable device batteries such as lithium-ion batteries. Research shows that in an environment of minus 5 degrees Celsius, the power consumption of the same mobile phone will increase to 1.7 times that at standard room temperature (about 20 degrees Celsius); and when the ambient temperature further drops to minus 30 degrees Celsius, most of the tested mobile phones will experience automatic shutdown, that is, the so-called "power loss" problem. This phenomenon greatly limits the usability of electronic products under low temperature conditions and brings great inconvenience to the user experience.

[0047] Traditional solutions often focus on improving the battery material itself or optimizing the battery management system, but these methods usually are difficult to achieve significant effects in a short time and may be accompanied by an increase in cost. In addition, some auxiliary devices on the market, such as external battery packs or heating pads, although they can alleviate the problems brought by low temperature to a certain extent, most of them rely on chemical reaction heat release, have problems such as unstable temperature control, inconvenient use, etc., and may have certain safety hazards.

[0048] In view of this, there is an urgent need for a new solution to address the problem of the decline in battery performance of electronic products in low-temperature environments. An ideal solution should be able to effectively maintain the temperature of the environment around the battery, ensure that the battery can still maintain a good working state under low-temperature conditions, and at the same time, the solution should also have the characteristics of being easy to use, safe and reliable, etc.

[0049] For this purpose, as Figures 1 to 8 shown, the heating device proposed by the present utility model includes a main body 100 and a self-controlled temperature heating component 200 connected to the main body 100. Among them, the main body 100 is used to be connected to an electronic product, and the self-controlled temperature heating component 200 includes a self-controlled temperature heating sheet 210 and an energization circuit 220. The position of the self-controlled temperature heating sheet 210 corresponds to the position of the driving power supply of the electronic product. The energization circuit 220 is electrically connected to the self-controlled temperature heating sheet 210. In application, the energization circuit 220 is used to be connected to a power supply and supply power to the self-controlled temperature heating sheet 210, driving the self-controlled temperature heating sheet 210 to heat up to a preset temperature and maintain at the preset temperature to heat the driving power supply. It should be noted that by designing the self-controlled temperature heating component 200 corresponding to the position of the driving power supply of the electronic product, the temperature around the driving power supply can be quickly increased to a preset range, such as between 40°C and 50°C, in a low-temperature environment, thereby effectively improving the working state of the driving power supply. It can not only improve the performance of the driving power supply under low-temperature conditions and reduce the occurrence of power-off phenomena, but also ensure the safety and stability of the battery during the heating process due to the characteristics of its uniform heating surface and constant temperature; in addition, the design of this device is convenient for installation and disassembly, has strong adaptability, and is suitable for use with various types of electronic products.

[0050] Refer to Figure 1, in some embodiments of the present utility model, the main body 100 includes an annular portion 110. The annular portion 110 is arranged around the peripheral wall of the electronic product. The annular portion 110 is detachably sleeved with the electronic product, which not only simplifies the installation and disassembly steps of the user, improves the convenience of use, but also allows the user to replace or adjust the heating device at any time according to actual needs, enhancing the flexibility and practicality of the device. Moreover, the annular portion 110 can protect the electronic product, acting as a protective cover to protect the electronic product from being scratched, dropped, etc. In some embodiments, the main body 100 includes a supporting portion 120. The self-controlled temperature heating sheet 210 is installed on the inner or outer side of the supporting portion 120, and the supporting portion 120 is adapted to abut against the outer wall of the electronic product for heat conduction. Such a structural design is conducive to the effective conduction of heat, ensuring that the heat generated by the self-controlled temperature heating sheet 210 can be quickly transferred to the driving power supply of the electronic product, thereby improving the heating efficiency and better protecting the driving power supply of the electronic product from the influence of low temperature. It is easy to understand that the supporting portion 120 can not only support the self-controlled temperature heating sheet 210, but also play the role of supporting the electronic product. Optionally, the supporting portion 120 is a flat structure, which can better support the planar self-controlled temperature heating sheet 210. In some embodiments, the annular portion 110 surrounds the outer peripheral edge of the supporting portion 120 and is integrally formed with the supporting portion 120. Specifically, as Figure 1 shown, artificial leather 500 is provided on the outer side wall of the supporting portion 120, and the self-controlled temperature heating sheet 210 is directly installed on the artificial leather 500. For example, the self-controlled temperature heating sheet 210 is sewn on the artificial leather 500. Referring again to Figure 3 and Figure 4 , the self-controlled temperature heating sheet 210 is pressed between two partition plates 510, and the artificial leather 500 is laminated on the outermost partition plate 510 and fixedly connected thereto.

[0051] As Figure 1 shown, the power supply is arranged outside the main body 100, and the self-controlled temperature heating sheet 210 is powered by an external power supply (not shown in the figure) for heating. In application, an external power supply needs to be directly plugged in for power supply. Further, in some embodiments of the present utility model, the annular portion 110 is provided with a clearance groove 1101. The clearance groove 1101 is used for the electrical interface 230 of the power supply to pass through, so as to energize the power-on circuit 220, ensuring the availability of the power supply and guaranteeing the normal operation of the device. At the same time, the design of the clearance groove 1101 also takes into account not affecting the normal use of the electronic product, improving the rationality of the overall design. In some embodiments, the clearance groove 1101 is provided on the bottom wall of the annular portion 110; in some embodiments, the clearance groove is provided on the side wall of the annular portion (not shown in the figure); in some embodiments, the clearance groove is provided on the top wall of the annular portion (not shown in the figure).

[0052] In some embodiments of the present utility model, the power supply is installed inside the main body 100, and, referring toFigure 5 , a control button 102 is provided on the outer wall of the main body 100. The control button 102 is electrically connected to the power supply and is used to control the on and off of the power supply. Furthermore, the user can easily operate the on and off of the power supply through the control button 102, enhancing the user's operation experience and the controllability of the power supply. In this regard, a circuit board 700 is provided inside the main body 100. The circuit board 700 integrally controls the power supply through the control button 102. And, an electrical interface 230 is provided on the circuit board 700 and extends out from the installation groove 101. The electrical interface 230 is used to connect to an external power source to charge the power supply. Optionally, the electrical interface 230 can be various common interfaces such as Microsoft USB, Type-C, etc. Referring again to Figure 2 , in some embodiments of the present invention, the power supply is a receiving coil 310, and the receiving coil 310 is charged by wireless charging. The wireless charging method not only eliminates the restraint of traditional charging cables, making the heating device more portable and easy to use, but also reduces the risk of damage that may be caused by frequent plugging and unplugging of the charging interface 230, and extends the service life of the product. In addition, a magnetic induction ring 311 is also provided inside the main body 100, which can assist in magnetic absorption charging. Referring again to Figure 5 and Figure 6 , in some embodiments of the present invention, the power supply is a storage battery. Optionally, the storage battery is a lithium battery. Correspondingly, the main body 100 is provided with an installation groove 101, and the storage battery is installed in the installation groove 101. And, the main body 100 is equipped with a heat conducting plate 400. One end face of the heat conducting plate 400 is used to cover the self-controlled temperature heating sheet 210, and the other end face is used to abut against the driving power source of the electronic product. The design of the storage battery enables the heating device to work independently of the power system of the electronic product itself, increasing the autonomy and flexibility of the heating device. In addition, the design of the heat conducting plate 400 further enhances the efficiency of heat conduction, ensuring that the driving power source can be fully heated and protected. In some embodiments, a detachable rear cover 600 is provided on the back side of the main body 100, which can conveniently perform maintenance and repair on the self-controlled temperature heating component 200 and the power supply. Specifically, the rear cover 600 is provided with positioning posts 610, and the back side of the main body 100 is provided with positioning grooves (not shown in the figure). The positioning posts 610 are conical structures and are adapted to be inserted and matched with the positioning grooves. And, the rear cover 600 is provided with fixing blocks 620, and the main body 100 is provided with fixing protrusions 103. A fixing groove with a closed setting is provided in the middle of the fixing block 620. During the insertion process of the rear cover 600 and the main body 100, the fixing block 620 deforms towards the center of the rear cover 600 and resets after being inserted in place. At this time, the fixing protrusion 103 is inserted into the fixing groove to fix the main body 100 and the rear cover 600.

[0053] In some embodiments of the present invention, such as Figure 7As shown in the figure, the self-controlled temperature heating sheet 210 includes a first PI film layer 211, a conductive layer 212, a plating layer 213, a PTC paste layer 214, and a second PI film layer 215 that are sequentially laminated. Such a structure not only provides excellent mechanical strength and electrical insulation performance, but also the plating layer 213 can prevent the conductive layer 212 from being oxidized. Moreover, the use of the PTC paste layer 214 ensures that the heating sheet has good self-controlled temperature characteristics, can automatically adjust the heat generation amount according to the ambient temperature change, avoid overheating phenomena, and ensure the safety and stability of the heating sheet during operation. Among them, the preset temperature is A, satisfying: 40° ≤ A ≤ 50°. This temperature range can not only effectively increase the working temperature around the drive power supply, but also will not cause damage to the drive power supply. By precisely controlling the temperature of the heating sheet, it is possible to ensure that the performance of the battery in a low-temperature environment is improved, extend the service life of the drive power supply of the electronic product, and provide a comfortable hand feeling temperature for the user. Specifically, the preset temperature is 45°. Reference can be made to the patent with the publication number of CN 109907878 A and the patent name of a rapid heating constant temperature hot compress element and its preparation method, as well as the patent with the publication number of CN 108503940 A and the patent name of a PTC organic composite material with a low Curie temperature point and its preparation method.

[0054] Referring again to Figure 8 , the mobile phone case according to an embodiment of the present invention includes a heating device according to an embodiment of the present invention. Among them, the main body 100 is sleeved and installed on the back of the mobile phone 800. By adopting the heating device of the embodiment of the present invention, the self-controlled temperature heating component 200 is designed corresponding to the position of the drive power supply of the mobile phone 800, and the temperature around the drive power supply can be rapidly increased to the preset range in a low-temperature environment. Such a mobile phone case can not only protect the mobile phone 800 from external impacts, but more importantly, it can effectively improve the working efficiency of the battery of the mobile phone 800 in a low-temperature environment, ensure the normal use of the mobile phone 800 under cold conditions, and greatly facilitate the outdoor activities of users.

[0055] Other components and operations of the mobile phone case according to an embodiment of the present invention are known to those of ordinary skill in the art and will not be described in detail here.

[0056] The embodiments of the present invention have been described in detail above in conjunction with the accompanying drawings. However, the present invention is not limited to the above embodiments, and various changes can be made without departing from the gist of the present invention within the knowledge scope of those of ordinary skill in the art.

Claims

1. A heating device, characterized in that: include: A main body, used for connecting with electronic products; A self-controlling temperature heating component is connected to the main body, the self-controlling temperature heating component comprises a self-controlling temperature heating sheet and a power supply circuit, the position of the self-controlling temperature heating sheet corresponds to the position of the driving power supply of the electronic product, and the power supply circuit is electrically connected to the self-controlling temperature heating sheet; The power-on circuit is used to connect to the power supply and supply power to the self-controlling temperature heating plate, driving the self-controlling temperature heating plate to generate heat to a preset temperature and maintain it at the preset temperature, so as to heat the driving power supply.

2. The heating device according to claim 1, characterized in that: The main body comprises an annular portion, which is arranged around the peripheral wall of the electronic product and is detachably sleeved with the electronic product.

3. The heating device according to claim 2, characterized in that: The annular portion is provided with a clearance groove, and the clearance groove is used for allowing the electrical interface of the power supply to pass through so as to energize the power circuit.

4. The heating device according to claim 1, characterized in that: The main body comprises a supporting portion, the self-temperature-controlling heating sheet is installed on the inner side or the outer side of the supporting portion, and the supporting portion is suitable for abutting against the outer wall of the electronic product for heat conduction.

5. The heating device according to claim 1, characterized in that: The self-temperature-controlling heating sheet comprises a first PI film layer, a conductive layer, an electroplating layer, a PTC slurry layer and a second PI film layer which are laminated in sequence.

6. The heating device according to claim 1, characterized in that: The preset temperature is A, which satisfies: 40°≤A≤50°.

7. The heating device according to any one of claims 1 to 6, characterized in that: The power supply is installed in the main body, and a control button is arranged on the outer wall of the main body. The control button is electrically connected to the power supply and is used to control the opening and closing of the power supply.

8. The heating device according to claim 7, characterized in that: The power supply is a receiving coil, and the receiving coil is charged by wireless charging.

9. The heating device according to claim 7, characterized in that: The power supply is a storage battery, the main body is provided with a mounting groove, the storage battery is installed in the mounting groove, the main body is also equipped with a heat conducting plate, one end surface of the heat conducting plate is used to cover the self-controlling temperature heating plate, and the other end surface is used to abut against the driving power supply of the electronic product.

10. A mobile phone case, characterized in that: The invention comprises a heating device as claimed in any one of claims 1 to 9.

Citation Information

Patent Citations

  • Low-Curie-temperature-point positive temperature coefficient (PTC) organic composite material and preparation method thereof

    CN108503940A

  • Rapid-heating constant-temperature hot compress patch and preparation method thereof

    CN109907878A