Mechanochemical catalytic depolymerisation

EP4590433A1Pending Publication Date: 2025-07-30UNIVERSITEIT UTRECHT HOLDING BV
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Patent Information

Application Number
EP2023790752
Authority / Receiving Office
EP · EP
Patent Type
Applications
Current Assignee / Owner
Priority Date
2022-10-17
Filing Date
2023-10-17
Publication Date
2025-07-30

AI Technical Summary

Technical Problem

Current chemical recycling methods for plastic waste, such as pyrolysis, are unselective and require high temperatures, making them inefficient for converting plastic materials into desired compounds, particularly for polyolefins like polypropylene and polyethylene.

Method used

The method involves using catalytically functionalized grinding media, such as sulfated or tungstated metal oxide balls, to mechanically agitate plastic materials, facilitating depolymerization at lower temperatures through mechanochemical cleavage and heterogeneous catalysis, allowing for the selective production of monomers and short-chain hydrocarbons without the need for solvents or additional reactants.

Benefits of technology

This approach enhances the selectivity and efficiency of plastic depolymerization, achieving a fourfold increase in propene formation rate and significant production of C1–C10 products at room temperature, while maintaining the structural integrity of the catalyst and allowing for easy recovery.

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Abstract

The disclosure pertains to method of depolymerizing plastic material using certain grinding media, to the grinding media, and to methods of manufacturing the grinding media. The grinding media are catalytically functionalized. In an example embodiment, milling balls (1) can be used for the depolymerization of polymers (2), such as polyolefins. The zirconia milling balls are sulfated (3) to enhance solid acid catalytic functionality. The vigorous motion (4) during milling and the catalytic functionality synergistically contribute to depolymerisation.
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