HAIR CARE COMPOSITIONS

Abstract

HAIR CARE COMPOSITIONS Hair care compositions and processes for providing conditioning benefits to hair are disclosed. Hair care compositions may include one or more nonionic surfactants comprising one or more alkyl polyglucosides; one or more fatty alcohols; one or more fatty esters comprising a caprylic / capric triglyceride; about 0.5 to about 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester; one or more silicones comprising polysilicone-11; one or more thickening agents; and water, in which the hair care composition is an emulsion, and all weight percentages are based on the total weight of the hair care composition. Figure for the abstract: NONE

Description

Title of the invention: HAIR CARE COMPOSITIONS disclosure domain

[0001] This disclosure relates to hair care compositions and processes for providing conditioning benefits to hair, context of disclosure

[0002] Consumers desire new and improved formulations for treating, caring for, and / or conditioning keratinous substances, such as hair. In general, hair is exposed to intrinsic and extrinsic influences, such as environmental, mechanical, and chemical factors, as well as heat and aging, which damage it. For example, environmental factors, such as sunlight and heat, and mechanical or chemical treatments, such as brushing, combing, dyeing, bleaching, perming and / or straightening, blow-drying, flat ironing, or even repeated washing, can damage and weaken hair fibers. Over time, hair can become dry, coarse, brittle, or dull, particularly in fragile areas, and especially at the ends, leading to split ends.

[0003] To overcome these drawbacks, it is common practice to use hair care products with compositions designed to condition the hair, giving it satisfactory cosmetic properties, particularly in terms of softness, shine, suppleness, lightness, natural feel, and good detangling properties. For example, hair care compositions, such as conditioners and / or treatment compositions, can be used before or after the hair has been washed with shampoo and / or chemically treated in order to enhance or restore the hair's natural shine, luster, and softness, or to improve the feel, appearance, and manageability of the hair.

[0004] It is understood that different forms of hair care compositions can provide different benefits. However, there is always a need for products that provide superior conditioning properties, while not weighing down the hair, leaving it greasy, and / or providing undesirable cosmetic properties. summary of disclosure

[0005] Certain aspects of the disclosure relate to hair care compositions that provide significant hair conditioning benefits. For example, certain embodiments of the compositions provide deep conditioning of the hair while simultaneously repairing damaged areas. damaged hair fibers. Furthermore, hair care compositions can be formulated as emulsions containing large amounts of oils. The inventors discovered that unique combinations of ingredients in certain ratios surprisingly produce emulsions that stably contain large amounts of oil. For example, the inventors unexpectedly discovered that hair care compositions combining alkyl polyglucosides, including a C12.20 alkyl glucoside, fatty alcohols, including C14.22 alcohols, and an acrylic thickening agent, including a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer, in certain weight ratios produced emulsions with significantly improved stability.It was further discovered that hair care compositions obtained unexpected benefits when certain ingredients, such as caprylic / capric triglyceride and polysilicone-11, were combined with the rest of the hair care compositions.

[0006] The composition of hair care products according to one aspect of disclosure typically includes:

[0007] (a) one or more non-ionic surfactants comprising one or more poly alkyl glucosides;

[0008] (b) one or more fatty alcohols;

[0009] (c) one or more fatty esters comprising a caprylic / capric triglyceride;

[0010] (d) approximately 0.5 to approximately 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester;

[0011] (e) one or more silicones comprising polysilicone-11;

[0012] (f) one or more thickening agents; and

[0013] (g) of water,

[0014] wherein the hair care composition is an emulsion, and all percentages by weight are based on the total weight of the hair care composition.

[0015] In some embodiments, the hair care compositions comprise:

[0016] (a) approximately 2 to approximately 15% by weight of one or more non-ionic surfactants comprising one or more alkyl polyglucosides selected from among the C12-20 alkyl glucosides;

[0017] (b) approximately 0.5 to approximately 5% by weight of one or more fatty alcohols, in which one or more fatty alcohols include C14.22 alcohols;

[0018] (c) approximately 1 to approximately 15% by weight of one or more fatty esters comprising a caprylic / capric triglyceride;

[0019] (d) approximately 0.5 to approximately 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester;

[0020] (e) approximately 0.5 to approximately 10% by weight of one or more silicones comprising poly silicone-11;

[0021] (f) approximately 0.1 to approximately 10% by weight of one or more thickening agents, in of which one or more thickening agents include a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer; and

[0022] (g) about 40% by weight or more of water.

[0023] The fatty alcohols in the hair care composition may include octyldodecanol in addition to the CM.22 alcohols. The hair care compositions may have a weight ratio of the total amount of alkyl glucoside in the Ci2_20 and alcohols in the Ci4 22 to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer of about 0.1:1 to about 1:0.1. In some cases, the weight ratio of the total amount of CM.22 alcohols and alkyl glucoside in the Ci2 20 to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer is about 0.5:1 to about 1:0.5.

[0024] In addition, or alternatively, the hair care compositions may be formulated to contain a total amount of oil of approximately 1 to 20% by weight, based on the weight of the hair care composition. The fatty compound, other than fatty alcohol and fatty ester, may include approximately 0.1 to approximately 10% by weight of a wax. For example, the hair care composition may include a wax selected from illipe butter, beeswax, butyrospermum parkii (shea) butter, euphorbia cerifera wax, camauba, lanolin, lanolin derivatives, candelilla wax, cocoa butter, sugar cane wax, lignite wax, whale wax, berry wax, acacia flower wax, vegetable waxes, and a mixture thereof.

[0025] Non-limiting examples of suitable fatty esters include cetyl ester, purcellin oil, isopropyl myristate, isopropyl palmitate, glyceryl stearate, caprylic / capric triglyceride, sorbitan isostearate, Ci2-Ci5 alkyl benzoate, 2-ethylphenyl benzoate, isopropyl lanolate, hexyl laurate, dii-sopropyl adipate, isononyl isononanoate, oleyl erucate, 2-ethylhexyl palmitate, isostearyl isostearate, diisopropyl sebacate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, hydroxylated esters, dicaprylyl carbonate, pentaerythritol esters, or a mixture thereof. In at least one case, the one or more fatty esters include isopropyl myristate and caprylic / capric triglyceride.

[0026] The hair care composition may include one or more silicones comprising dimethicone, dimethiconol, decamethylcyclopentasiloxane, cyclomethicone or a mixture thereof, in addition to polysilicone-11.

[0027] In addition or alternatively, the hair care composition may further include approximately 3 to approximately 20% by weight of a polyol. The polyol may be selected from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1,3 propanediol, glycerin, polyethylene glycols, and a mixture thereof.

[0028] In some cases, the hair care composition further includes about 0.01 to about 10% by weight of a cationic polymer.Des exemples de polymères cationiques incluent, sans s’y limiter, les polyquatemium-4, polyquatemium-6, poly-quatemium-7, polyquaternium-10, polyquaternium-11, polyquaternium-16, poly-quatemium-22, polyquaternium-28, polyquaternium-32, polyquaternium-46, poly-quatemium-51, polyquaternium-52, polyquaternium-53, polyquaternium-54, poly-quatemium-55, polyquaternium-56, polyquaternium-57, polyquaternium-58, poly-quatemium-59, polyquaternium-60, polyquaternium-63, polyquaternium-64, poly-quatemium-65, polyquaternium-66, polyquaternium-67, polyquaternium-70, poly-quatemium-73, polyquaternium-74, polyquaternium-75, polyquaternium-76, poly-quatemium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, poly-quatemium-81, polyquaternium-82, polyquaternium-84, polyquaternium-85, poly-quatemium-86, polyquaternium-87, polyquaternium-90, polyquaternium-91, poly-quatemium-92, polyquaternium-94, chlorure de guar hydroxypropyltrimonium, ou un mélange de ceux-ci. .

[0029] According to another aspect of the disclosure, a method is provided for improving hair. The method typically includes:

[0030] (I) the application of a hair care composition to the hair, the com Hair care package including:

[0031] (a) one or more non-ionic surfactants comprising one or more poly- alkyl glucosides;

[0032] (b) one or more fatty alcohols;

[0033] (c) one or more fatty esters comprising a caprylic / capric triglyceride;

[0034] (d) approximately 0.5 to approximately 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester;

[0035] (e) one or more silicones comprising polysilicone-11;

[0036] (f) one or more thickening agents; and

[0037] (g) of water,

[0038] in which all percentages by weight are based on the total weight of the hair care composition,

[0039] (II) optionally, rinsing hair care compositions from hair.

[0040] The hair care composition of the process may have a weight ratio of the total amount of alkyl glucoside in Ci2_20 and alcohols in Ci4 22 to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer from approximately 0.1:1 to approximately 1:0.1. In some cases, the hair care composition may include a silicone selected from dimethicone, dimethiconol, decamethylcyclopentasiloxane, cyclomethicone, and a mixture thereof, in addition to polysilicone-11. Detailed disclosure description

[0041] This disclosure generally relates to hair care compositions and processes that provide significant conditioning benefits to the hair. Desirably, certain embodiments of the compositions provide deep conditioning to the hair while simultaneously repairing damaged sites on the hair fiber.

[0042] Furthermore, the inventors discovered that unique combinations of ingredients in certain ratios promote emulsions that stably contain large amounts of oil. Thus, some embodiments of hair care compositions unexpectedly contain large amounts of oil in a stable oil-in-water emulsion. For example, the inventors unexpectedly discovered that hair care compositions having the combination of alkyl glucoside in the C12-20 group, alcohols in the C14-22 group, and sodium hydroxyethyl acrylate / acryloyldimethyl taurate copolymer in certain weight ratios produced emulsions with improved stability.It has also been discovered that hair care compositions have yielded unexpected benefits when certain ingredients, such as caprylic / capric triglyceride and polysilicone-11, have been combined with the rest of the hair care compositions.

[0043] Hair care compositions according to one aspect of disclosure typically include:

[0044] (a) one or more non-ionic surfactants comprising one or more poly- alkyl glucosides;

[0045] (b) one or more fatty alcohols;

[0046] (c) one or more fatty esters comprising a caprylic / capric triglyceride;

[0047] (d) about 0.5 to about 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester;

[0048] (e) one or more silicones comprising polysilicone-11;

[0049] (f) one or more thickening agents; and

[0050] (g) of water,

[0051] wherein the hair care composition is an emulsion, and all percentages by weight are based on the total weight of the hair care composition.

[0052] As used here, an oil refers to compounds having a melting point below 35°C and having a hydrophobic portion. For example, hair care compositions may include oils selected from fatty compounds, such as fatty alcohols (e.g., octyldodecanol), fatty esters (e.g., per for example, triglycerides), etc., as well as silicones, such as silicone polymers (e.g., dimethicone). In at least one case, the oils present in the hair care composition are chosen from the group consisting of fatty compounds, silicones, and a mixture thereof.

[0053] The total amount of oil (such as oils selected from fatty compounds and silicones) may be from about 1 to about 20% by weight, relative to the total weight of the hair care composition. In some cases, the total amount of oil may be from about 1 to about 20% by weight, about 2 to about 20% by weight, about 3 to about 20% by weight, about 4 to about 20% by weight, about 5 to about 20% by weight, about 6 to about 20% by weight, about 8 to about 20% by weight, about 10 to about 20% by weight, about 12.5 to about 20% by weight, about 15 to about 20% by weight; about 1 to about 18% by weight, about 2 to about 18% by weight, about 3 to about 18% by weight, about 4 to about 18% by weight, about 5 to about 18% by weight, about 6 to about 18% by weight, about 8 to about 18% by weight, about 10 to about 18% by weight, about 12.5 to about 18% by weight, about 15 to about 18% by weight;approximately 1 to approximately 16% by weight, approximately 2 to approximately 16% by weight, approximately 3 to approximately 16% by weight, approximately 4 to approximately 16% by weight, approximately 5 to approximately 16% by weight, approximately 6 to approximately 16% by weight, approximately 8 to approximately 16% by weight, approximately 10 to approximately 16% by weight, approximately 12.5 to approximately 16% by weight, approximately 15 to approximately 16% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0054] In addition or alternatively, the hair care compositions form an emulsion. For example, the hair care compositions may be in the form of an oil-in-water emulsion.

[0055] Suitable components, such as those listed below, may be included or excluded from formulations for hair care compositions depending on the specific combination of other components, the form of the hair care compositions and / or the use of the formulation.

[0056] Non-ionic surfactant(s)

[0057] Hair care compositions include one or more nonionic surfactants comprising alkyl polyglucosides. In one embodiment, the hair care compositions include one or more nonionic surfactants comprising a Ci2-20 alkyl glucoside that is commercially available as a mixture with Ci4-22 alcohols under the brand name MONTANOV L of the Seppic company.

[0058] Typically, hair care compositions include a total amount of nonionic surfactant(s) of approximately 1 to approximately 15% by weight, based on weighttotal composition of hair care products. For example, the composition of hair care products may include non-ionic surfactants in an amount of approximately 1 to approximately 15% by weight, approximately 1 to approximately 13% by weight, approximately 1 to approximately 11% by weight, approximately 1 to approximately 9% by weight, approximately 1 to approximately 7% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight; approximately 2 to approximately 15% by weight, approximately 2 to approximately 13% by weight, approximately 2 to approximately 11% by weight, approximately 2 to approximately 9% by weight, approximately 2 to approximately 7% by weight, approximately 2 to approximately 5% by weight; approximately 3 to approximately 15% by weight, approximately 3 to approximately 13% by weight, approximately 3 to approximately 11% by weight, approximately 3 to approximately 9% by weight, approximately 3 to approximately 7% by weight; about 4 to about 15% by weight, about 4 to about 13% by weight, about 4 to about 11% by weight, about 4 to about 9% by weight, about 4 to about 7% by weight;approximately 5 to approximately 15% by weight, approximately 5 to approximately 13% by weight, approximately 5 to approximately 11% by weight, approximately 5 to approximately 9% by weight, approximately 5 to approximately 7% by weight, approximately 6 to approximately 7% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0059] The amount of alkyl glycoside in Ci2_20 present in the hair care composition can be from about 0.05 to about 10% by weight, based on the total weight of the hair care composition. In some cases, the amount of alkyl glycoside in Ci2_20 in the hair care composition can be from about 0.05 to about 8% by weight, about 0.05 to about 6% by weight, about 0.05 to about 4% by weight, about 0.05 to about 3% by weight, about 0.05 to about 2% by weight, about 0.05 to about 1% by weight; approximately 0.1 to approximately 10% by weight, approximately 0.1 to approximately 8% by weight, approximately 0.1 to approximately 6% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.1 to approximately 1% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0060] In addition to the alkyl glucoside in Ci2 20, the hair care compositions may include other nonionic surfactants. In at least one embodiment, the other nonionic surfactants include PEG-40 hydrogenated castor oil and, optionally, polysorbate 60 in addition to the alkyl polyglucosides.

[0061] One or more nonionic surfactants in the hair care composition may include alkanolamides, alkyl polyglucosides, polyoxyalkylated nonionic surfactants, polyglycerolated nonionic surfactants, ethoxylated fatty esters, and / or ethoxylated oils of vegetable origin. Non-limiting examples of nonionic surfactants other than alkyl polyglucosides include: alkanolamides; alkyl polyglucosides; polyoxyalkylated nonionic surfactants; polyglycerolated nonionic surfactants; ethoxylated fatty esters; alcohols, alpha-diols, alkylphenols, and esters of fatty acids, ethoxylated, propoxylated or glycerolated; copolymers of ethylene oxide and / or propylene oxide; condensates of ethylene oxide and / or propylene oxide with fatty alcohols; polyethoxylated fatty amides; ethoxylated fatty acid esters of sorbitan comprising 2 to 30 moles of ethylene oxide; ethoxylated oils of vegetable origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; mono- or diesters of polyethoxylated fatty acids of glycerol; C6-C24 alkyl polyglycosides; C6-C24 N-alkylglucamine derivatives, amine oxides such as C10-C14 alkylamine oxides or C10-C14 N-(acyl)aminopropylmorpholine oxides; and mixtures thereof. In some cases, a plurality of non-ionic surfactants may be useful.

[0062] A more detailed discussion of nonionic surfactants other than alkyl polyglucosides that may be suitable in hair care compositions is provided below: i. Alkanolamides

[0063] Non-limiting examples of alkanolamides include fatty acid alkanolamides. Fatty acid alkanolamides may be fatty acid monoalkanolamides, fatty acid dialkanolamides, or fatty acid isoalkanolamides, and may have a hydroxyalkyl group at C2-8 (the C2-8 chain may be substituted by one or more -OH groups). Non-limiting examples include fatty acid diethanolamides (DEA) or fatty acid monoethanolamides (MEA), fatty acid monoisopropanolamides (MIPA), fatty acid diisopropanolamides (DIPA), and fatty acid glucamides (acylglucamides).

[0064] Suitable fatty acid alkanolamides include those formed by the reaction of an alkanolamine and a C6-C36 fatty acid. Examples include, but are not limited to: oleic acid diethanolamide, myristic acid monoethanolamide, soybean fatty acid diethanolamide, stearic acid ethanolamide, oleic acid monoisopropanolamide, linoleic acid diethanolamide, stearic acid monoethanolamide (stearamide MEA), behenic acid monoethanolamide, isostearic acid monoisopropanolamide (isostearamide MIPA), erucic acid diethanolamide, ricinoleic acid monoethanolamide, coconut fatty acid monoisopropanolamide (cocoamide MIPA), coconut acid monoethanolamide (cocamide MEA), palm kernel acid diethanolamide, coconut fatty acid diethanolamide, lauric diethanolamide, polyoxyethylene coconut fatty acid monoethanolamide, monoethanolamide of coconut oil, lauric monoethanolamide,lauric acid monoisopropanolamide (lauramide MIPA), myristic acid monoisopropanolamide (myristamide MIPA), coconut fatty acid diisopropanolamide (cocamide DIPA), and mixtures thereof.

[0065] In some cases, fatty acid alkanolamides preferably include cocamide MIPA, cocamide DEA, cocamide MEA, cocamide DIPA, and mixtures thereof. In particular, the fatty acid alkanolamide may be cocamide MIPA, which is commercially available under the brand name EMPILAN from Innospec Active Chemicals.

[0066] Fatty acid alkanolamides include those of the following structure: O r4cnr5r6

[0067] in which,

[0068] - R4 is an alkyl chain of 4 to 20 carbon atoms (R4 can be, for example, chosen from lauric acid, coconut acid, palmitic acid, myristic acid, behenic acid, babassu fatty acid, isostearic acid, stearic acid, maize fatty acid, soybean fatty acid, shea butter fatty acids, caprylic acid, capric acid, and mixtures thereof);

[0069] - R6 is chosen from -CH2OH, -CH2CH2OH, -CH2CH2CH2OH, -CH2(CHOH)4CH2 OH, -benzyl, and mixtures thereof; and

[0070] - R6 is chosen from -H, -CH3, -CH2OH, -CH2CH3, -CH2CH2OH, -CH2CH2CH2OH, - -CH2(CHOH)4CH2OH, -benzyl, and mixtures thereof.

[0071] In some cases, one or more of the fatty acid alkanolamides include one or more acyl glucamides, for example, acyl glucamides having a carbon chain length of 8 to 20. Non-limiting examples include lauroyl / myristoyl methyl glucamide, capryloyl / capryl methyl glucamide, lauroyl methyl glucamide, myristoyl methyl glucamide, capryloyl methyl glucamide, capryl methyl glucamide, cocoyl methyl glucamide, capryloyl / caproyl methyl glucamide, cocoyl methyl glucamide, lauryl methyl glucamide, oleoyl methyl glucamide oleate, stearoyl methyl glucamide stearate, sunflower methyl glucamide, and tocopheryl succinate methyl glucamide.

[0072] (ii) Alkyl polyglucosides

[0073] For the purposes of the present invention, the term "alkyl polyglycoside" means an alkyl monosaccharide (degree of polymerization 1) or an alkyl polyglycoside (degree of polymerization greater than 1).

[0074] Alkyl polyglycosides can be used alone or as mixtures of several alkyl polyglycosides. Examples of alkyl polyglycosides include those having the following formula: Rl-O-(R2O)nZ(x)

[0075] in which,

[0076] - R1 is an alkyl group having from 8 to 22 carbon atoms;

[0077] - R2 is an ethylene or propylene group;

[0078] - Z is a saccharide group having 5 to 6 carbon atoms;

[0079] - n is an integer from 0 to 10; and

[0080] - x is an integer from 1 to 5, preferably from 1.05 to 2.5 and more preferably tiellement from 1.1 to 2.

[0081] Non-limiting examples of alkyl polyglucosides that may be useful in hair care compositions include lauryl glucoside, octyl glucoside, decyl glucoside, coco glucoside, caprylyl / capryl glucoside, and sodium lauryl glucose carboxylate. Typically, at least one alkyl polyglucoside compound is selected from the group consisting of lauryl glucoside, decyl glucoside, and coco glucoside. In some cases, the nonionic surfactant is decyl glucoside.

[0082] The saccharide residue can be selected from glucose, dextrose, sucrose, fructose, galactose, maltose, maltotriose, lactose, cellobiose, mannose, ribose, dextran, talose, allose, xylose, levoglucan, cellulose and starch.

[0083] More preferably, the saccharidic residue refers to glucose.

[0084] It should also be noted that each motif of the polysaccharide portion of the alkyl polyglycoside can be in alpha or beta isomer form, in L or D form, and the configuration of the saccharidic residue can be of the furanoside or pyranoside type.

[0085] It is of course possible to use mixtures of alkyl polysaccharides, which may differ from one another by the nature of the alkyl carrier motif and / or the nature of the carrier polysaccharide chain.

[0086] Alkyl polyglucosides may also be selected from the group consisting of myristyl alcohol / myristyl glucoside (MONTANOV 14); isostearyl alcohol / isostearyl glucoside; cetyl alcohol / cetylstearyl glucoside (MONTANOV 68); cetylstearyl alcohol / coco glucoside (MONTANOV 82); arachidyl alcohol and behenyl alcohol / arachidyl glucoside (MONTANOV 202); Ci422 alcohols / Ci2_20 alkyl glucoside (MONTANOV L); co-coyl alcohol / cocoyl glucoside (MONTANOV S); hydroxystearyl alcohol and hydroxystearyl glucoside (SIMULGREEN 18-2), or any mixture thereof.

[0087] In one embodiment, said alkyl polyglucosides are chosen from the group consisting of alkyl polyglucosides with an alkyl having 12 to 22 carbon atoms.

[0088] In one embodiment, said alkyl polyglucosides are chosen from the group consisting of alkyl polyglucosides with an alkyl having 14 to 18 carbon atoms.

[0089] In one embodiment, said alkyl polyglucosides are present in the form of a mixture of alkyl polysaccharides with an alkyl portion having from 12 to 22 carbon atoms and even more preferably from 12 to 20 carbon atoms.

[0090] In one embodiment, said alkyl polyglucosides are chosen from the group consisting of caprylyl / capryl glucoside, palm kernel / coconut glucoside, cetearyl glucoside, decyl glucoside, lauryl glucoside, coco glucoside, arachidyl glucoside, C12.20 alkyl glucoside, C10-16 alkyl glucoside, myristyle glucoside, myristoyl ethyl glucoside, methyl coco glucoside, ethyl tallow glucoside, undecyl glucoside, octyldodecyl glucoside, isostearyl glucoside, lauroyl ethyl glucoside, cocoyl ethyl glucoside, caproyl ethyl glucoside, butyl glucoside, or mixtures thereof.

[0091] (iii) Various non-ionic surfactants

[0092] Non-ionic surfactants also include, for example, alcohols, alpha-diols, alkylphenols and fatty acid esters, ethoxylated, propoxylated or glycerolated and comprising at least one fatty chain comprising, for example, 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups ranging from 2 to 50, and the number of glycerol groups from 1 to 30. Maltose derivatives may also be mentioned.Other examples include, but are not limited to, copolymers of ethylene oxide and / or propylene oxide; condensates of ethylene oxide and / or propylene oxide with fatty alcohols; poly-ethoxylated fatty amides comprising, for example, 2 to 30 moles of ethylene oxide; polyglycerol fatty amides comprising, for example, 1.5 to 5 glycerol groups, such as 1.5 to 4; ethoxylated fatty acid esters of sorbitan comprising 2 to 30 moles of ethylene oxide; ethoxylated oils of vegetable origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; mono- or diesters of poly-ethoxylated fatty acids of glycerol; alkyl polyglycosides (C6-C24); derivatives of N-(C6-C24 alkyl) glucamine, amine oxides such as (C10-C14 alkyl) amine oxides or N-(C10-C14 acyl) aminopropylmorpholine oxides; and mixtures thereof.In some cases, the nonionic surfactant is chosen from among polyoxyalkylated or polyglycerolated nonionic surfactants. The oxyalkylene motifs are more particularly oxyethylene or oxypropylene motifs, or a combination thereof, and are preferably oxyethylene motifs.

[0093] In addition or alternatively, the nonionic surfactant may be selected from polyol esters with fatty acids having a saturated or unsaturated chain containing, for example, 8 to 24 carbon atoms, preferably 12 to 22 carbon atoms, and alkoxylated derivatives thereof, preferably with 10 to 200 alkylene oxides, and more preferably 10 to 100, such as glyceryl esters of one or more C8-C24 fatty acids, preferably C12-C22, and alkoxylated derivatives thereof, preferably with 10 to 200 alkylene oxides, and more preferably 10 to 100; polyethylene glycol esters of one or more C8-C24 fatty acids, preferably Ci2-C22, and alkoxylated derivatives thereof, preferably with an alkylene oxide number of 10 to 200, and more preferably from 10 to 100; sorbitol esters of one or more C8-C24 fatty acids, preferably Ci2-C22, and alkoxylated derivatives thereof, preferably with an alkylene oxide number of 10 to 200, and more preferably from 10 to 100; sugar esters (sucrose, glucose, alkyl glycoses) of one or more C8-C24 fatty acids, preferably C12-C22, and alkoxylated derivatives thereof, preferably with 10 to 200 alkylene oxides, and more preferably 10 to 100; fatty alcohol ethers; sugar ethers and one or more C8-C24 fatty alcohols, preferably C12-C22; and mixtures thereof.

[0094] Examples of ethoxylated fatty esters that may be mentioned include the addition products of ethylene oxide with esters of lauric acid, palmitic acid, stearic acid or behenic acid, and mixtures thereof, in particular those containing 9 to 100 oxyethylene groups, such as PEG-9 to PEG-50 laurate (under the CTFA names: PEG-9 laurate to PEG-50 laurate); PEG-9 to PEG-50 palmitate (under the CTFA names: PEG-9 palmitate to PEG-50 palmitate); PEG-9 to PEG-50 stearate (under the CTFA names: PEG-9 stearate to PEG-50 stearate); PEG-9 to PEG-50 palmitostearate; PEG-9 to PEG-50 behenate (under the CTFA names: PEG-9 behenate to PEG-50 behenate); polyethylene glycol 100 EO monostearate (under the CTFA name: PEG-100 stearate); and mixtures thereof.

[0095] The nonionic surfactant may be selected from fatty acid glyceryl esters, such as glyceryl stearate (glyceryl mono-, di- and / or tristearate) (CTFA name: glyceryl stearate), glyceryl ricinoleate, and mixtures thereof. The fatty acid glyceryl esters may be C8-C24 alkoxylated fatty acid glyceryl esters and / or polyethoxylated glyceryl stearate (glyceryl mono-, di- and / or tristearate), such as PEG-20 glyceryl stearate.

[0096]

[0097] Fatty alcohol(s)

[0098] Hair care compositions include one or more fatty alcohols. Preferably, the total amount of fatty alcohols present in the hair care composition is approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight; approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, approximately 1 to approximately 3% by weight; approximately 2 to approximately 10% by weight, approximately 2 to approximately 8% by weight, approximately 2 to approximately 6% by weight, approximately 2 to about 5% by weight, about 2 to about 4% by weight; about 3 to about 10% by weight, about 3 to about 8% by weight, about 3 to about 6% by weight or about 3 to about 5% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0099] Hair care compositions may be formulated to have C14.22 alcohols in an amount of about 0.05 to about 8% by weight, about 0.05 to about 6% by weight, about 0.05 to about 4% by weight, about 0.05 to about 3% by weight, about 0.05 to about 2% by weight, about 0.05 to about 1% by weight; about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight; approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0100] The composition of hair care products may include one or more fatty alcohols in addition to alcohols in Ciw. For example, the composition of hair care products may include one or more fatty alcohols having a fatty alcohol group with a carbon chain of more than 8 carbon atoms, 8 to 50 carbon atoms, 8 to 40 carbon atoms, 8 to 30 carbon atoms, 8 to 22 carbon atoms, 12 to 22 carbon atoms, or 12 to 18 carbon atoms, including all intermediate ranges and subranges. In some cases, the fatty alcohol group has a carbon chain of 10 to 20 carbon atoms or 10 to 18 carbon atoms. Fatty alcohols may be selected from polyethylene glycol ethers, such as those having a fatty alcohol group with a carbon chain of 12 to 16 or 12 to 14 carbon atoms. In at least one embodiment, the hair care product composition includes octyldodecanol in addition to alcohols in C]4-22*

[0101] The fatty alcohol portion is preferably hydrogenated (e.g., stearyl, lauryl, cetyl, cetearyl); however, the fatty alcohol may contain one or more double bonds (e.g., oleyl). Non-limiting examples of fatty alcohols include decyl alcohol, undecyl alcohol, dodecyl alcohol, myristyl alcohol, lauryl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol (cetyl alcohol and stearyl alcohol), isostearyl alcohol, isocetyl alcohol, behenyl alcohol, linalool, oleyl alcohol, cis-4-t-butylcyclohexanol, isotridecyl alcohol, myricyl alcohol, and mixtures thereof. In some cases, fatty alcohols include at least one of the following or may be chosen from myristyl alcohol, lauryl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, oleyl alcohol, isotridecyl alcohol and a mixture of these.

[0102] Fatty alcohols can be saturated or unsaturated. Examples of saturated liquid fatty alcohols may be branched and optionally contain at least one aromatic or non-aromatic ring in their structure. In some cases, however, fatty alcohols are acyclic. Non-limiting examples of saturated liquid fatty alcohols include octyldodecanol, isostearyl alcohol, and 2-hexyldecanol.

[0103] Examples of liquid unsaturated fatty alcohols may include at least one double or triple bond in their structure. For example, fatty alcohols may include several double bonds (such as 2 or 3 double bonds), which may be conjugated or nonconjugated. Unsaturated fatty alcohols may be linear or branched and may be acyclic or include at least one aromatic or non-aromatic ring in their structure. Liquid unsaturated fatty alcohols may include, or be selected from, oleyl alcohol, linoleyl alcohol, linolenic alcohol, and undecylenic alcohol.

[0104] Fatty alcohols may be alkoxylated fatty alcohols, for example, having about 1 to about 100 moles of an alkylene oxide per mole of alkoxylated fatty alcohol. For example, alkoxylated fatty alcohols may be alkoxylated with about 1 to about 80 moles, about 2 to about 50 moles, about 5 to about 45 moles, about 10 to about 40 moles, or 15 to about 35 moles, including all intermediate ranges and sub-ranges, of an alkylene oxide per mole of alkoxylated fatty alcohol.

[0105] Examples of alkoxylated fatty alcohols include steareth (e.g., steareth-2, steareth-20, and steareth-21), laureth (e.g., laureth-4 and laureth-12), ceteth (e.g., ceteth-10 and ceteth-20), and ceteareth (e.g., ceteareth-2, ceteareth-10, and ceteareth-20). In at least one case, one or more of the alkoxylated fatty alcohols include steareth-20. In some cases, one or more of the alkoxylated fatty alcohols may consist exclusively of steareth-20.

[0106] Additional fatty alcohol derivatives that may optionally be suitable include methyl stearyl ether; 2-ethylhexyl dodecyl ether; stearyl acetate; cetyl propionate; the ceteth series of compounds, such as ceteth-1 to ceteth-45, which are ethylene glycol ethers of cetyl alcohol, in which the numerical designation indicates the number of ethylene glycol fractions present; the steareth series of compounds, such as steareth-1 to 10, which are ethylene glycol ethers of steareth alcohol, in which the numerical designation indicates the number of ethylene glycol fractions present; ceteareth-1 to ceteareth-10, which are the ethylene glycol ethers of ceteareth alcohol, i.e. a mixture of fatty alcohols containing mainly cetyl alcohol and stearyl alcohol, in which the numerical designation indicates the number of ethylene glycol fractions present;Ci-C30 alkyl ethers of the ceteth, steareth and ceteareth compounds described above; polyoxyethylenic ethers of branched alcohols such as octyldodecyl alcohol, alcohol; dodecylpentadecyl, hexyldecyl alcohol and isostearyl alcohol; polyoxyethylenic ethers of behenyl alcohol; PPG ethers such as PPG-9-steareth, PPG-11 stearyl ether, PPG-8-cetheth-1, and PPG-10 cetyl ether; and mixtures thereof.

[0107] Fatty ester(s)

[0108] The hair care composition includes one or more fatty esters comprising caprylic / capric triglyceride. The total amount of fatty esters present in the hair care composition may be from about 1 to about 20% by weight, based on the total weight of the hair care composition. For example, the amount of fatty esters in the hair care composition may be from about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 11% by weight, about 1 to about 10% by weight, about 1 to about 9% by weight; about 3 to about 20% by weight, about 3 to about 18% by weight, about 3 to about 16% by weight, about 3 to about 14% by weight, about 3 to about 12% by weight, about 3 to about 11% by weight, about 3 to about 10% by weight, about 3 to about 9% by weight;approximately 5 to approximately 20% by weight, approximately 5 to approximately 18% by weight, approximately 5 to approximately 16% by weight, approximately 5 to approximately 14% by weight, approximately 5 to approximately 12% by weight, approximately 5 to approximately 11% by weight, approximately 5 to approximately 10% by weight or approximately 5 to approximately 9% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0109] Hair care compositions may include caprylic / capric triglyceride in an amount of about 0.01 to about 8% by weight, about 0.01 to about 6% by weight, about 0.01 to about 4% by weight, about 0.01 to about 3% by weight, about 0.01 to about 2% by weight, about 0.01 to about 1% by weight; about 0.05 to about 8% by weight, about 0.05 to about 6% by weight, about 0.05 to about 4% by weight, about 0.05 to about 3% by weight, about 0.05 to about 2% by weight, about 0.05 to about 1% by weight; about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight;approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0110] The hair care composition preferably includes one or more fatty esters in addition to caprylic / capric triglyceride. For example, the fatty ester(s) may be selected from dialkyl carbonates of formula: RiO(C=O)R2, in which Ri and R2 are independent linear or branched, saturated or unsaturated alkyl chains having 1 to 30 carbon atoms, or having 2 to 28 carbon atoms, or having 4 to 25 carbon atoms, or having 6 to 22 carbon atoms, preferably one or more fatty carbonates selected from dialkyl carbonates in C14-I5, dicaprylyl carbonate, diethyl carbonate, dihexyl carbonate, diethylhexyl carbonate, dimethoxyphenyl and phenyloxoethyl ethyl carbonate, dimethyl carbonate, dipropyl carbonate, dipropylheptyl carbonate, dioctyl carbonate, and a mixture thereof. In at least one case, the hair care composition includes isopropyl myristate and glyceryl stearate in addition to caprylic / capric triglyceride.

[0111] In addition or alternatively, the fatty ester may be selected from cetyl ester, purcellin oil (cetearyl octanoate), isopropyl myristate, isopropyl palmitate, glyceryl stearate, C12-C15 alkyl benzoate, 2-ethylphenyl benzoate, isopropyl lanolate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, oleyl erucate, 2-ethylhexyl palmitate, isostearyl isostearate, diisopropyl sebacate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, hydroxylated esters, dicaprylyl carbonate, pentaerythritol esters, and a mixture thereof. Other fatty esters worth mentioning include polyglyceryl-10 oleate, polyglyceryl-10 dioleate, polyglyceryl-6 stearate, polyglyceryl-6 distearate, polyglyceryl-10 stearate, polyglyceryl-10 distearate, polyglyceryl-8 dipalmitate, polyglyceryl-10 dipalmitate, polyglyceryl-10 behenate, and polyglyceryl-12 trilaurate.

[0112] Fatty compound(s) other than a fatty alcohol and a fatty ester

[0113] Hair care compositions include one or more fatty compounds other than a fatty alcohol and a fatty ester in an amount typically ranging from about 0.5 to about 30% by weight, based on the total weight of the hair care compositions. In some cases, the total amount of fatty compounds other than a fatty alcohol and a fatty ester present in the hair care composition is about 0.5 to about 30% by weight, about 0.5 to about 25% by weight, about 0.5 to about 20% by weight, about 0.5 to about 15% by weight, about 0.5 to about 12.5% ​​by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight; about 2 to about 30% by weight, about 2 to about 25% by weight, about 2 to about 20% by weight, about 2 to about 15% by weight, about 2 to about 12.5% ​​by weight, about 2 to about 10% by weight, about 2 to about 8% by weight;about 5 to about 30% by weight, about 5 to about 25% by weight, about 5 to about 20% by weight, about 5 to about 15% by weight, about 5 to about 12.5% ​​by weight, about 5 to about 10% by weight, about 5 to about 8% by weight; about 7 to about 30% by weight, about 7 to about 25% by weight, about 7 to about 20%; by weight, approximately 7 to approximately 15% by weight, approximately 7 to approximately 12.5% ​​by weight, or approximately 7 to approximately 10% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0114] Fatty ether(s)

[0115] Hair care compositions may optionally include one or more fatty ethers. The total amount of fatty ethers, if present in the hair care composition, may be from about 0.05 to about 8% by weight, about 0.05 to about 6% by weight, about 0.05 to about 4% by weight, about 0.05 to about 3% by weight, about 0.05 to about 2% by weight, about 0.05 to about 1% by weight; about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight; about 0.5 to about 8% by weight, about 0.5 to about 6% by weight, about 0.5 to about 4% by weight, about 0.5 to about 3% by weight, about 0.5 to about 2% by weight;approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, approximately 1 to approximately 3% by weight; approximately 2 to approximately 8% by weight, approximately 2 to approximately 6% by weight, approximately 2 to approximately 5% by weight, approximately 2 to approximately 4% by weight; approximately 3 to approximately 8% by weight, approximately 3 to approximately 6% by weight, approximately 3 to approximately 5% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0116] Fatty ethers may be selected from polyoxyethylene cetyl / stearyl ether, polyoxyethylene cholesterol ether, polyoxyethylene laurate or dilaurate, polyoxyethylene stearate or distearate, polyoxyethylene lauryl or stearyl ether, dicaprylyl ether, dicetyl ether, distearyl ether and a mixture of these. Non-limiting examples of suitable polyoxyethylene fatty ethers include, but are not limited to, polyoxyethylene cetyl / stearyl ether, polyoxyethylene cholesterol ether, polyoxyethylene laurate or dilaurate, polyoxyethylene stearate or distearate, polyoxyethylene lauryl or stearyl ether, and mixtures thereof, wherein the polyoxyethylene head group is in a range of about 2 to about 100 groups.In some embodiments, polyoxyethylene fatty ethers include polyoxyethylene stearyl ether, polyoxyethylene myristyl ether, polyoxyethylene lauryl ether having from about 3 to about 10 oxyethylene units and mixtures thereof.

[0117] Fatty acid(s)

[0118] In some cases, hair care compositions may include one or more fatty acids. The total amount of fatty acids, if present in the composition hair care position, can be from about 0.05 to about 8% by weight, about 0.05 to about 6% by weight, about 0.05 to about 4% by weight, about 0.05 to about 3% by weight, about 0.05 to about 2% by weight, about 0.05 to about 1% by weight; about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight; about 0.5 to about 8% by weight, about 0.5 to about 6% by weight, about 0.5 to about 4% by weight, about 0.5 to about 3% by weight, about 0.5 to about 2% by weight; about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight, about 1 to about 4% by weight, about 1 to about 3% by weight; about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight, about 2 to about 4% by weight;approximately 3 to approximately 8% by weight, approximately 3 to approximately 6% by weight, approximately 3 to approximately 5% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0119] Hair care compositions may include one or more fatty acids, fatty acid derivatives, fatty acid esters, hydroxyl-substituted fatty acids, and alkoxylated fatty acids. The fatty acids may be straight-chain or branched-chain and / or saturated or unsaturated. Non-limiting examples of fatty acids include diacids, triacids, and other multiple acids, as well as salts of these fatty acids. For example, the fatty acid may optionally include or be selected from lauric acid, palmitic acid, stearic acid, behenic acid, arachidonic acid, oleic acid, isostearic acid, sebacic acid, and a mixture thereof. In some cases, the fatty acids are selected from the group consisting of palmitic acid, stearic acid, and a mixture thereof.

[0120] Non-limiting examples of polyglycerol esters of fatty acids include those of the following formula: OR2 R^OCH2-CH-CH2O)n-R3

[0121] wherein the average value of n is approximately 3 and R1, R2, and R3 can each independently be a fatty acid fraction or a hydrogen atom, provided that at least one of R1, R2, and R3 is a fatty acid fraction. For example, R1, R2, and R3 can be saturated or unsaturated, linear or branched, and have a length of C1-C40, CrC30, CrC25, or CrC20, CrC16, or CrC10.

[0122] Fatty acid derivatives are defined herein to include fatty acid esters of fatty alcohols as defined above, fatty acid esters of fatty alcohol derivatives as defined above when these fatty alcohol derivatives have a group esterifiable hydroxyl, fatty acid esters of alcohols other than fatty alcohols and fatty alcohol derivatives described above, hydroxy-substituted fatty acids, and a mixture thereof.Non-limiting examples of fatty acid derivatives include ricinoleic acid, glyceryl monostearate, 12-hydroxystearic acid, ethyl stearate, cetyl stearate, cetyl palmitate, polyoxyethylene cetyl ether stearate, polyoxyethylene stearyl ether stearate, polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, polyoxyethylene distearate, propylene glycol monostearate, propylene glycol distearate, trimethylolpropane distearate, sorbitan stearate, polyglyceryl stearate, dimethyl sebacate, PEG-15 cocoate, PPG-15 stearate, monostearate of Glyceryl, glyceryl distearate, glyceryl tristearate, PEG-8 laurate, PPG-2 isostearate, PPG-9 laurate, and mixtures thereof. Preferred products are glyceryl monostearate, 12-hydroxystearic acid, and mixtures thereof.

[0123] Wax(s)

[0124] Hair care compositions may, in some cases, include one or more waxes. The total quantity of waxes, if present in the hair care composition, may be from approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight; approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, approximately 1 to approximately 3% by weight; approximately 2 to approximately 8% by weight, approximately 2 to approximately 6% by weight, approximately 2 to approximately 5% by weight, approximately 2 to approximately 4% by weight; approximately 3 to approximately 8% by weight, approximately 3 to approximately 6% by weight, approximately 3 to approximately 5% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0125] Non-limiting examples of waxes in this category include, for example, synthetic wax, ceresin, paraffin, ozokerite, polyethylene waxes, illipe butter, beeswax, carnauba wax, microcrystalline wax, lanolin, lanolin derivatives, candelilla wax, cocoa butter, shellac wax, spermaceti, bran wax, kapok wax, sugarcane wax, lignite wax, whale wax, berry wax, acacia flower wax, vegetable waxes (such as sunflower (Helianthus annuus) seed wax, carnauba, candelilla, ouricury or Japanese wax, or cork or sugarcane fiber waxes), or a mixture thereof. Hair care compositions may include two or more waxes, such as two or more waxes selected from those mentioned above. In one embodiment, the hair care composition includes butyrospermum parkii (shea) butter, euphorbia cerifera (candelilla) wax and beeswax.

[0126] Other fatty compound(s)

[0127] Hair care compositions include fatty compounds other than those mentioned above. In general, the following fatty compounds are considered to be oil(s). As indicated above, the total amount of oil may include oils that are fatty alcohols, fatty esters, fatty ethers, fatty acids, silicones, and / or similar substances. The total amount of oil may be from about 1 to about 20% by weight, relative to the total weight of the hair care composition. In some cases, the total amount of selected fatty compounds of oil and silicones may be from about 1 to about 20% by weight, about 2 to about 20% by weight, about 3 to about 20% by weight, about 4 to about 20% by weight, about 5 to about 20% by weight, about 6 to about 20% by weight, about 8 to about 20% by weight, about 10 to about 20% by weight, about 12.5 to about 20% by weight, about 15 to about 20% by weight;about 1 to about 18% by weight, about 2 to about 18% by weight, about 3 to about 18% by weight, about 4 to about 18% by weight, about 5 to about 18% by weight, about 6 to about 18% by weight, about 8 to about 18% by weight, about 10 to about 18% by weight, about 12.5 to about 18% by weight, about 15 to about 18% by weight; approximately 1 to approximately 16% by weight, approximately 2 to approximately 16% by weight, approximately 3 to approximately 16% by weight, approximately 4 to approximately 16% by weight, approximately 5 to approximately 16% by weight, approximately 6 to approximately 16% by weight, approximately 8 to approximately 16% by weight, approximately 10 to approximately 16% by weight, approximately 12.5 to approximately 16% by weight, approximately 15 to approximately 16% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0128] Non-limiting examples of fatty compounds that are oils include, but are not limited to, natural fatty oils, such as coconut oil; hydrocarbons, such as mineral oil and hydrogenated polyisobutene; esters, such as C12-C15 alkyl benzoate; diesters, such as propylene dipelarganate; and triesters, such as glyceryl trioctanoate.Other examples of fatty compounds that are oils include isotridecyl isononanoate, PEG-4 diheptanoate, isostearyl neopentanoate, tridecyl neopentanoate, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, coconut caprate / dicaprylate, decyl isostearate, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, octyl palmitate, dioctyl malate, tridecyl octanoate, myristyle myristate, octododecanol, or combinations of octyldodecanol, acetylated lanolin alcohol, cetyl acetate, isododecanol, polyglyceryl-3-diisostearate, oil of castor oil, lanolin and lanolin derivatives, triisocetyl citrate, sorbitan sesquioleate, Ci0-Ci8 triglycerides, caprylic / capric triglycerides, coconut oil, corn oil, cottonseed oil, glyceryl hydroxystearate. triacetyl, glyceryl ricinoleate triacetyl, glyceryl trioctanoate, hydrogenated castor oil, linseed oil, mink oil, olive oil, palm oil, illipe butter, rapeseed oil, soybean oil, sunflower oil, tallow, tricaprine, trihydrostearine, triisostearin, trilaurin, trilinolein, trimyristin, triolein, tripalmitin, tristearin, walnut oil, wheat germ oil, cholesterol, or combinations thereof.

[0129] In addition or alternatively, the fatty compounds, which are oils, may be chosen from plant-based oils and / or vegetable oils. Non-exhaustive examples of vegetable or plant-based oils include acai oil, almond oil, aloe vera oil, andiroba oil, annatto oil, avocado oil, babassu oil, borage oil, Brazil nut oil, buriti oil, camelina oil, coffee oil, copaiba oil, emu oil, passion fruit oil, almond oil, castor seed oil, coconut oil, grapeseed oil, jojoba oil, macadamia nut oil, rosehip oil, ajowan oil, angelica root oil, anise oil, argan oil, asafetida oil, balsam oil, basil oil, bay leaf oil, bergamot oil, black pepper oil, buchu oil, birch oil, camphor oil, cannabis oil, and oil of caraway, cardamom seed oil,carrot seed oil, chamomile oil, calamus root oil, cinnamon oil, lemongrass oil, clary sage oil, clove leaf oil, coffee oil, coriander oil, rosemary oil, cranberry seed oil, cubeb oil, cumin oil, cypress oil, cypriol, curry leaf oil, davana oil, dill oil, elecampane oil, eucalyptus oil, fennel seed oil, fenugreek oil, fir oil, frankincense oil, galangal oil, geranium oil, ginger oil, goldenrod oil, grapefruit oil, grapeseed oil, henna oil, helichrysum oil, horseradish oil, hyssop oil, Idaho tansy oil, jasmine oil, juniper berry oil, lavender oil, oil of lemon, lemongrass oil, marjoram oil, tea tree oil, lemon balm oil, mountain savory oil, mugwort oil, mustard oil, myrrh oil, myrtle oilneem oil, neroli oil, nutmeg oil, orange oil, oregano oil, iris oil, palo santo oil, parsley oil, patchouli oil, perilla oil, pennyroyal oil, peppermint oil, petitgrain oil, pine oil, plum oil, ravensara oil, red cedar oil, Roman chamomile oil, rose oil, rosehip oil, rosemary oil, rosewood oil, sandalwood oil, sassafras oil, savory oil, schisandra oil, spikenard oil, spruce oil, star anise oil, mandarin oil, tarragon oil, tea tree oil, thyme oil, hemlock oil, turmeric oil, valerian oil, vetiver oil, western red cedar oil, wintergreen oil yarrow, ylang-ylang oil and zedoary oil.

[0130] Non-limiting examples of vegetable-derived fatty oils include Alexandrian laurel oil, avocado oil, apricot kernel oil, barley oil, borage seed oil, calendula oil, cinnamon nut oil, canola oil, caprylic / capric triglyceride, castor oil, coconut oil, corn oil, cottonseed oil, cottonseed oil, evening primrose oil, linseed oil, peanut oil, hazelnut oil, glyceryl triacetate, glyceryl triheptanoate, glyceryl trioctanoate, glyceryl triundecanoate, hemp oil, jojoba oil, alfalfa oil, corn germ oil, pumpkin seed oil, millet oil, neopentyl glycol dicaprylate / dicaprate, olive oil, palm oil, passionflower oil, tetrastearate pentaerythrityl, poppy oil, propylene glycol ricinoleate, rapeseed oil, rye oil, safflower oil, sesame oil, shea butter, soybean oil, soybean oil,Sweet almond oil, sunflower oil, sysymbrium oil, syzygium aromaticum oil, tea tree oil, walnut oil, wheat germ glycerides, and wheat germ oil.

[0131] Silicone(s)

[0132] Hair care compositions include one or more silicones comprising polysilicone-11. Polysilicone-11 is commercially available as a mixture with dimethicone under the brand name GRANSIL DMG-6LC from Grant Industries.

[0133] The total amount of silicone(s) present in the hair care composition can be between approximately 0.5 and approximately 10% by weight, relative to the total weight of the hair care composition. For example, the total amount of silicone(s) present in the hair care composition can be from approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight; approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, approximately 1 to approximately 3% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight, about 2 to about 4% by weight;approximately 3 to approximately 10% by weight, approximately 3 to approximately 8% by weight, approximately 3 to approximately 6% by weight, or approximately 3 to approximately 5% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0134] Hair care compositions may include one or more silicones in addition to polysilicone-11. The silicones may optionally be functionalized with an amino group or functionalized with a methacrylic group. The term "amino-functional silicone" or "amino silicones" refers to a silicone containing at least minus one primary amino, secondary amino, tertiary amino, and / or quaternary ammonium group. The structure of amino-functional silicone can be linear or branched, cyclic or non-cyclic. The amino functional group can be located at any position in the silicone molecule, preferably at the end of the backbone (e.g., in the case of amodimethicones) and / or in the side chain.

[0135] Non-limiting examples of silicones include amine functional silicones (e.g., amodimethicone), dimethicone, bis-aminopropyl dimethicone, trimethyl sily-lamodimethicone, dimethicone copolyols, etc. The composition of hair care products may, in some cases, include one or more silicones selected from among polydimethylsiloxanes (dimethicones), polydiethylsiloxanes, polydimethylsiloxanes with terminal hydroxyl groups (dimethiconols), polymethylphenylsiloxanes, phenylmethylsiloxanes, amino-functional polydimethylsiloxane (amodimethicone), bis-aminopropyl dimethicone, trimethylsilylamodimethicone, dimethicone copolyols, dimethicone copolyol esters, quaternary nitrogenous compounds of dimethicone copolyol, phosphate esters of dimethicone copolyol, and mixtures thereof. For example, one or more silicones may be or include one or more dimethicone copolyols.The copolyols can be chosen from PEG-8 dimethicone adipate, PEG-8 dimethicone benzoate, PEG-7 dimethicone phosphate, PEG-10 dimethicone phosphate, PEG / PPG-20 / 23 dimethicone benzoate, PEG / PPG-7 / 4 dimethicone phosphate, PEG / PPG-12 / 4 dimethicone phosphate, PEG-3 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, PEG / PPG-3 / 10 dimethicone, PEG / PPG-4 / 12 dimethicone, PEG / PPG-6 / 11 dimethicone, PEG / PPG-8 / 14 dimethicone, PEG / PPG-14 / 4 dimethicone, PEG / PPG-15 / 15 dimethicone, PEG / PPG-16 / 2 dimethicone, PEG / PPG-17 / 18 dimethicone, PEG / PPG-18 / 18 dimethicone, PEG / PPG-19 / 19 dimethicone, PEG / PPG-20 / 6 dimethicone, PEG / PPG-20 / 15 dimethicone, PEG / PPG-20 / 20 dimethicone, PEG / PPG-20 / 23 dimethicone, PEG / PPG-20 / 29 dimethicone, PEG / PPG-22 / 23 dimethicone, PEG / PPG-22 / 24 dimethicone, PEG / PPG-23 / 6 dimethicone, PEG / PPG-25 / 25 dimethicone, PEG / PPG-27 / 27 dimethicone, and a mixture thereof..

[0136] The silicone(s) may optionally include or be selected from a siloxane with a methacrylic group on one of its molecular ends, a polydimethylsiloxane containing a styryl group on one of its molecular ends, or a similar silicone compound containing unsaturated groups; butadiene; vinyl chloride; vinylidene chloride; methacrylonitrile; dibutyl fumarate; anhydrous maleic acid; anhydrous succinic acid; glycidyl methacrylic ether; an organic salt of an amine, an ammonium salt, and an alkali metal salt of methacrylic acid, itaconic acid, or crotonic, maleic acid or fumaric acid; a radically polymerizable unsaturated monomer containing a sulfonic acid group such as a styrenesulfonic acid group; a quaternary ammonium salt derived from methacrylic acid, such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride; and a methacrylic acid ester of an alcohol containing a tertiary amine group, such as a methacrylic acid ester of diethylamine.

[0137] One or more silicones may be included in the composition of hair care products as emulsifiers. For example, the silicone may be an organosiloxane emulsifier, an oxyalkylated organosiloxane emulsifier, a PEGylated organic siloxane emulsifier, or a cross-linked organosiloxane emulsifier. Although not specifically identified, some of the silicones listed below may be used as emulsifiers.

[0138] In some cases, silicones optionally include or are selected from siloxanes having an organic functional group, such as polyalkylsiloxanes, where at least one alkyl group is other than methyl, for example, organopolysiloxanes with the INCI name Stearyl Dimethicone, Cetyl Dimethicone, or C26-28 Alkyl Dimethicone, or, for example, polyarylsiloxanes and polyarylalkylsiloxanes, for example, organopolysiloxanes with the INCI name Phenyl Trimethicone, Trime-Thylsiloxyphenyl Dimethicone, or Dimethylphenyl Dimethicone, or, for example, organopolysiloxanes having an organofunctional group such as an aminopropyl, aminopropyl-aminoethyl, or aminopropyl-aminoisobutyl group, for example, organopolysiloxanes with the INCI name Amodimethicone, or, for example, organopolysiloxanes having a polyethylene glycol or polyalkylene glycol radical, for example organopolysiloxanes having the INCI name PEG-12 Dimethicone, PEG / PPG-25,25-Dimethicone or Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone. ,

[0139] In some cases, an amino-functionalized silicone is chosen from compounds having the following formula: Q

[0140] wherein each R1 is independently chosen from an alkyl group at Cmo, an alkoxy group at C13o, an aryl group at C53o, an aralkyl group at C63o, an aralkyloxy group at C63o, an alkaryl group at C30, an alkoxyaryl group at C30 and a hydroxyl group (preferably, each R1 is independently chosen from a alkyl group in Ci_30, an alkoxy group in Ci_30 and a hydroxy group);

[0141] each R2 is independently a divalent alkylene radical having one to ten carbon atoms (preferably, R2 is a divalent alkylene radical having three to six carbon atoms);

[0142] each R3 is independently chosen from an alkyl group in C1 30, an aryl group in C5 30, an aralkyl group in C6 30 and an alkaryl group in C1 30 (preferably, each R3 is independently chosen from an alkyl group in C1 30);

[0143] Q is a monovalent radical chosen from NR42 and NR4(CH2)XNR42;

[0144] each R4 is chosen independently from a hydrogen and an alkyl group in C i-4;

[0145] x is worth from 2 to 6;

[0146] z is equal to 0 or 1;

[0147] n is worth from 25 to 3,000 (preferably, from 25 to 2,000; more preferably, from 25 to 1,000; most particularly from 25 to 500); and

[0148] m is worth from 0 to 3,000 (preferably from 0 to 2,000, more preferably from 0 to 1,000, most particularly from 0 to 100);

[0149] provided that at least 50% by moles of the total number of R1 and R3 groups are methyl groups and provided that, when m is equal to 0, z is equal to 1.

[0150] Preferred R1 groups include methyl, methoxy, ethyl, ethoxy, propyl, propoxy, isopropyl, isopropoxy, butyl, butoxy, isobutyl, isobutoxy, phenyl, xenyl, benzyl, phenylethyl, tolyl, and hydroxy groups. Preferred R2 divalent alkylene radicals include trimethylene, tetramethylene, pentamethylene, -CH2 CH(CH3)CH2-, and -CH2CH2CH(CH3)CH2-. Preferred R3 groups include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, phenyl, xenyl, benzyl, phenylethyl, and tolyl groups. Preferred R4 groups include methyl, ethyl, propyl, isopropyl, butyl, and isobutyl groups. When z equals 0, the amino-functional silicin has only pendant amine-functional substituents in the polymer chain.When z equals 1, the amino-functional silicone may have only terminal amine substituents (e.g., m=0) or may have both terminal and pendant amine substituents in the polymer chain (e.g., m>0). Preferably, n + m ranges from 50 to 1000. More preferably, n + m ranges from 50 to 750. Even more preferably, n + m ranges from 50 to 500. Most preferably, n + m ranges from 50 to 250.

[0151] In some cases, amino-functional silicones are alkoxylated and / or hydroxylated amino silicones. Suitable alkoxylated and / or hydroxylated amino silicones may be selected from compounds of the following formula: R3 CH3 XL ->V OSi- ch3 R3

[0152] in which R3 is a hydroxyl group or OR5, R5 is an alkyl group in C1 to C4, R4 is a group whose structure conforms to the following formula: - CH2 CH CH2 NH (CH2)n nh2 r6

[0153] ,

[0154] R6 is a C4-Ci alkyl group, n is a number from 1 to 4, x is identical to "n" described above, and y is identical to "m" described above.

[0155] The silicone may be a polysiloxane corresponding to the following formula:

[0156] in which x' and y' are integers such that the weight-average molecular weight (Mw) is between approximately 5,000 and 500,000;

[0157] b) amino silicones corresponding to the following formula:

[0158] R' aG3 a-Si(OSiG2)n-(OSiGbR' 2 b)mO-SiG3 a-R'a

[0159] in which:

[0160] G, which may be identical or different, designate a hydrogen atom, or a phenyl, OH or alkyl group in CrC8, for example methyl, or alkoxy group in CrC8, for example methoxy,

[0161] a, identical or different, denote the number 0 or an integer from 1 to 3, in particular 0;

[0162] b represents the number 0 or 1, and in particular 1;

[0163] m and n are numbers such that the sum (n + m) ranges from 1 to 2000 and in particular from 50 to 150, n being able to represent a number from 0 to 1999 and in particular from 49 to 149, and m a number from 1 to 2,000 and in particular from 1 to 10;

[0164]

[0165]

[0166]

[0167]

[0168]

[0169]

[0170]

[0171]

[0172]

[0173]

[0174]

[0175]

[0176]

[0177]

[0178] R', identical or different, denotes a monovalent radical of formula -CqH2qL in which q is a number from 2 to 8 and L is an optionally quantized amino group chosen from the following groups: -NR"-QN(R")2 -N(R")2 -N+(R")3 a -N+H(R")2 a -N+H2(R") a -N(R")-Q-N+R "H2 A -NR"-Q-N+ (R")2H A -NR"-Q-N+ (R")3 A, in which R", identical or different, represent hydrogen, phenyl, benzyl, a monovalent saturated hydrocarbon radical, for example a Ci-C20 alkyl radical; Q represents a linear or branched CrH2r group, r being an integer from 2 to 6, preferably from 2 to 4; and A represents a cosmetically acceptable ion, in particular a halide such as fluoride, chloride, bromide, or iodide. Another group of amino silicones corresponding to this definition is represented by silicones with the following formula: in which m and n are numbers such that the sum (n + m) goes from 1 to 1,000, in particular from 50 to 250 and more particularly from 100 to 200, n being able to designate a number from 0 to 999 and in particular from 49 to 249, and more particularly from 125 to 175, and m being able to designate a number from 1 to 1,000 and in particular from 1 to 10, and more particularly from 1 to 5; Ri, R2, R3, identical or different, represent a hydroxy or alkoxy radical in Ci-C4, at least one of the radicals Ri to R3 designating an alkoxy radical. The alkoxy radical is preferably a methoxy radical. The hydroxyl / alkoxy molar ratio preferably varies from 0.2:1 to 0.4:1 and preferably from 0.25:1 to 0.35:1 and above. particularly is equal to 0.3:1- The average molecular mass by weight (Mw) of silicone preferably goes from 2,000 to 1,000,000, more particularly from 3,500 to 200,000.

[0179] Another group of amino silicones corresponding to this definition is represented by the following formula:

[0180]

[0181]

[0182]

[0183]

[0184] in which p and q are numbers such that the sum (p + q) ranges from 1 to 1,000, in particular from 50 to 350, and more particularly from 150 to 250; p can represent a number from 0 to 999, in particular from 49 to 349, and more particularly from 159 to 239 and q a number from 1 to 1,000, in particular from 1 to 10, and more particularly from 1 to 5; Ri, R2, identical or different, represent a hydroxy or alkoxy radical in C1-C4, at least one of the radicals Ri or R2 designating an alkoxy radical. The alkoxy radical is preferably a methoxy radical. The hydroxyl / alkoxy molar ratio generally ranges from 1:0.8 to 1:1.1 and preferably from 1:0.9 to 1:1, and most particularly equal to 1:0.95. Another group of amino silicones is represented by the following formula:

[0185]

[0186] in which m and n are numbers such that the sum (n + m) goes from 1 to 2000 and in particular from 50 to 150, n being able to designate a number from 0 to 1999 and in particular from 49 to 149, and m a number from 1 to 2000 and in particular from 1 to 10;

[0187] A designates a linear or branched alkylene radical containing 4 to 8 carbon atoms, and preferably 4 carbon atoms. This radical is preferably linear. The weight-average molecular mass (Mw) of these amine silicones preferably ranges from 2,000 to 1,000,000, and even more particularly from 3,500 to 200,000.

[0188] Another group of amino silicones is represented by the following formula:

[0189] in which

[0190] m and n are numbers such that the sum (n + m) goes from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149, and m a number from 1 to 2,000 and in particular from 1 to 10;

[0191] A designates a linear or branched alkylene radical containing from 4 to 8 carbon atoms, and preferably 4 carbon atoms. This radical is preferably branched. The weight-average molecular mass (Mw) of these amine silicones preferably ranges from 500 to 1,000,000, and even more particularly from 1,000 to 200,000.

[0192] Another group of amino silicones is represented by the following formula: (H)

[0193] in which

[0194] R5 represents a monovalent hydrocarbon radical containing from 1 to 18 carbon atoms, and in particular an alkyl radical in CrCi8 or alkenyl in C2-Ci8, for example methyl;

[0195] R6 represents a divalent hydrocarbon radical, in particular an alkylene radical in Ci-Ci8 or a divalent alkyleneoxy radical in CrCi8, for example in CrC8, linked to Si by a SiC bond;

[0196] Q is an anion such as a halide ion, in particular chloride, or an acid salt

[0197]

[0198]

[0199]

[0200]

[0201]

[0202]

[0203]

[0204]

[0205]

[0206]

[0207]

[0208]

[0209] organic (e.g. acetate); r represents an average statistical value from 2 to 20 and in particular from 2 to 8; s represents an average statistical value of 20 to 200 and in particular of 20 to 50. Such amino silicones are described more particularly in US patent no. 4,185,087. A group of quaternary ammonium silicones is represented by the following formula: in which: R7, identical or different, represent a monovalent hydrocarbon radical containing from 1 to 18 carbon atoms, and in particular an alkyl radical in CrCi8, an alkenyl radical in C2-C[8 or a ring containing 5 or 6 carbon atoms, for example methyl; R6 represents a divalent hydrocarbon radical, in particular an alkylene radical in Ci-Ci8 or a divalent alkyleneoxy radical in CrCi8, for example in CrC8, linked to Si by a SiC bond; R8, identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical containing from 1 to 18 carbon atoms, and in particular an alkyl radical in Ci-Ci8, an alkenyl radical in C2-Ci8 or an -R6-NHCOR7 radical; X is an anion such as a halide ion, in particular chloride, or a salt of organic acid (e.g. acetate); r represents an average statistical value of 2 to 200 and in particular of 5 to 100. These silicones are described, for example, in European patent application no. 0530974. A group of quaternary ammonium silicones is represented by the following formula: HgN - - HH ™ (C / y - Si - r- in which: Ri, R2, R3 and R4, identical or different, designate a C1-C4 alkyl radical or a phenyl group; R5 designates a C1-C4 alkyl radical or a hydroxyl group;

[0210] n is an integer from 1 to 5;

[0211] m is an integer from 1 to 5;

[0212] and in which x is chosen such that the amine index is between 0.01 and 1 meq / g;

[0213] polyoxyalkylened multi-sequenced amine silicones, of type (AB)n, A being a polysiloxane sequence and B a polyoxyalkylated sequence comprising at least one amine group.

[0214] Said silicones are preferably made up of repeating motifs having the following general formulas:

[0215] [-(SiMe2O)xSiMe2 - R -N(R")- R'-O(C2H4O)a(C3H6O)b -R'-N(H)-R-]

[0216] or alternatively

[0217] [-(SiMe2O)xSiMe2 - R -N(R")- R' - O(C2H4O)a(C3H6O)b -].

[0218] in which:

[0219] a is an integer greater than or equal to 1, preferably from 5 to 200, more particularly from 10 to 100;

[0220] b is an integer between 0 and 200, preferably from 4 to 100, more particularly from 5 to 30;

[0221] x is an integer ranging from 1 to 10,000, more particularly from 10 to 5,000;

[0222] R" is a hydrogen atom or a methyl;

[0223] R, identical or different, represent a divalent, linear or branched, C2-Ci2 hydrocarbon radical, optionally including one or more heteroatoms such as oxygen; preferably, R denotes an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, a -CH2CH2CH2 OCH(OH)CH2- radical; preferably, R denotes a -CH2CH2CH2 OCH(OH)CH2- radical;

[0224] R', identical or different, represent a divalent radical, linear or branched, hy drocarbon in the C2-Ci2 configuration, optionally including one or more heteroatoms such as oxygen; preferably, R' designates an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, a -CH2CH2CH2 OCH(OH)CH2- radical; preferably R' designates -CH(CH3)-CH2-. The siloxane sequences preferably represent between 50 and 95 mol% of the total weight of the silicone, more particularly between 70 and 85 mol%.

[0225] The amine content is preferably between 0.02 and 0.5 meq / g of copolymer in 30% solution in dipropylene glycol, more particularly between 0.05 and 0.2. The weight average molecular weight (Mw) of the silicone oil is preferably between 5,000 and 1,000,000, more particularly between 10,000 and 200,000.

[0226] The silicone may be selected from those having at least one quaternary ammonium group. Suitable non-limiting examples are quaternium-80, silicone quatemium-1, silicone quaternium-2, silicone quaternium-2 panthenol succinate, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium-7, silicone quaternium-8, silicone quaternium-9, silicone quaternium-10, silicone quaternium-11, silicone quaternium-12, silicone quaternium-15, silicone quaternium-16, silicone quaternium-16 / glycidoxy dimethicone cross-linked polymer, silicone quaternium-17, silicone quaternium-18, silicone quaternium-20 and silicone quaternium-21. We prefer quaternium 80, silicone quaternium-16, silicone quaternium-18, silicone quaternium-1, silicone quaternium-2, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium-7, silicone quaternium-8, silicone quaternium-9, silicone quaternium-10, silicone quaternium-11, silicone quaternium-12, silicone quaternium-15, silicone quaternium-17, silicone quaternium-20 and silicone quaternium-21.Quaternium 80, quaternium-16, quaternium-18, quaternium-3, quaternium-4, quaternium-5, quaternium-6, quaternium-7, quaternium-8, quaternium-9, quaternium-10, quaternium-11, quaternium-12, quaternium-15, and quaternium-17 are preferred. Quaternium 80, quaternium-16, quaternium-18, quaternium-15, and mixtures thereof are preferred. In one embodiment, one or more of the silicone oils of this disclosure are non-amine silicone oils such as dimethicone.

[0227] Non-limiting examples of amino-functionalized silicones include bis-hydroxy / methoxy amodimethicones, bis-cetearyl amodimethicone, amodimethicone, bis (alkoxy in Ci3_i5) PG amodimethicones, aminopropyl phenyl trimethicones, ami-nopropyl dimethicones, bis-amino PEG / PPG-41 / 3 aminoethyl PG-propyl dimethicones, caprylyl methicones, and mixtures thereof. In some cases, a particularly useful amino-functional silicone is bis-hydroxy / methoxy amodimethicone, in which X is isobutyl and one of the Rs is OH and the other is OCH3 in the structure above, also known as "bis-hydroxy / methoxy amodimethicone" and "3-[(2-aminoethyl)amino]-2-methylpropyl Me, di-Me, [(hydroxydimethylsilyl)oxy]- and [(methoxydimethylsilyl)oxy]-terminated." Bis-hydroxy / methoxy amodimethicone is commercially available under the brand name DOWSIL AP-8087 FLUID from The Dow Chemical Company.A non-limiting example of amodimethicone products containing amino silicones having structure (D) is sold by Wacker under the name BELSIL ADM 652, BELSIL ADM 4000 E, or BELSIL ADM LOG 1. A product containing amino silicones having structure (E) is sold by Wacker under the name FLUID WR 1300. In addition or alternatively, the weight-average molecular weight (Mw) of the silicone preferably ranges from 2,000 to 200,000, even more particularly from 5,000 to 100,000 and more particularly. a link of 10,000 to 50,000.

[0228] The silicone(s) in the hair care compositions of this disclosure is / are included in the form of a silicone emulsion comprising at least one silicone and at least one surfactant, for example, nonionic surfactants, cationic surfactants, amphoteric surfactants, anionic surfactants. Silicone emulsions may be nanoemulsions, microemulsions, or macroemulsions. Suitable examples of nonionic surfactants are alkoxylated fatty alcohols or polyethylene glycol ethers of C8-C30 fatty alcohol mixtures with an average mole number of ethylene oxide, such as Cms pareth-7, laureth-9, laureth-12, deceth-7, deceth-10, trideceth-6, trideceth-10, trideceth-12, or a mixture thereof. Suitable examples of amphoteric surfactants are cocamidopropyl betaine, coco-betaine, or a mixture thereof.Suitable examples of cationic surfactants are quaternary ammonium compounds such as behentrimonium chloride, cetrimonium chloride, behentrimonium methosulfate, or mixtures thereof. Suitable examples of anionic surfactants are sulfate-based compounds such as, further comprising up to 5% by weight of a surfactant, for example, sodium (or ammonium) lauryl sulfate, sodium (or ammonium) laureth sulfate, or mixtures thereof.

[0229] Thickening agent(s)

[0230] The hair care compositions described herein include one or more thickening agents. The amount of thickening agents may vary but is typically between approximately 0.1 and approximately 7% by weight, based on the total weight of the hair care composition.In some cases, the amount of thickening agents present in cosmetic hair compositions is approximately 0.1 to approximately 7% by weight, approximately 0.1 to approximately 6% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.1 to approximately 1% by weight; approximately 0.5 to approximately 7% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight, approximately 0.5 to approximately 1% by weight; approximately 1 to approximately 7% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, approximately 1 to approximately 3% by weight, approximately 1 to approximately 2% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the cosmetic hair composition.

[0231] According to preferred embodiments, the thickening agent is an anionic acrylic polymer further comprising at least one monomer performing a strong acid function such as, for example, monomers having an acid-type function sulfonic or phosphonic acid, such as 2-acrylamido-2-methylpropane sulfonic acid (AMPS).

[0232] According to preferred embodiments, the anionic acrylic polymer can be crosslinked (or branched). Suitable examples of acceptable crosslinking agents include, but are not limited to, methylene bisacrylamide (MBA), ethylene glycol diacrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethacrylate, vinyl oxyethacrylate or methacrylate, formaldehyde, glyoxal, and glycidyl ether-type compositions such as ethylene glycol diglycidyl ether, or epoxides.

[0233] Particularly preferred thickening agents are of the taurate copolymer type.

[0234] Suitable examples are sodium acrylate / sodium acryloyldimethyl taurate copolymer, acrylamide / sodium acryloyldimethyltaurate copolymer, ammonium polyacryloyldimethyl taurate, ammonium acryloyldimethyl taurate / VP copolymer, ammonium polyacryloyldimethyl taurate, ammonium acryloyldimethyltaurate / steareth-25 crosslinked polymer, ammonium acryloyldimethyltaurate / steareth-8 methacrylate copolymer, sorbitol / sebatic acid copolymer behenate, ethylenediamines / stearyl dilinoleate dimer copolymer, acrylamide / sodium acryloyldimethyltaurate copolymer, and mixtures thereof.

[0235] Other suitable examples include crosslinked polymers or copolymers of polyacryloyl / taurate or polyacryloyl / dimethyltaurate. Non-limiting examples of such polymers include ammonium acryloyldimethyltaurate / steareth-25 methacrylate crosslinked polymer, ammonium acryloyldimethyltaurate / steareth-8 methacrylate copolymer, ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosslinked polymer, and ammonium acryloyldimethyltaurate / laureth-7 methacrylate copolymer, and mixtures thereof.

[0236] A commercially available product containing a thickening agent is sold under the INCI name Sodium Acrylate / Sodium Acryloyldimethyl Taurate Copolymer and Hydrogenated Polydecene and Sorbitan Laurate and Trideceth-6, which is marketed by Arch Personal Care Products, South Plainfield, NJ, USA under the brand name ViscUp® EZ. Other commercially available products include SEPPIC's SEPIPLUS S (hydroxyethyl acrylate and sodium acryloyldimethyl taurate copolymer and polyisobutene and PEG-7 trimethyloylpropane coconut ether) and SEPINOV EMT 10 (hydroxyethyl acrylate and sodium acryloyldimethyl taurate copolymer).

[0237] According to other embodiments of the present invention, the thickening agent is in powder form. Suitable examples of such a thickening agent include SEPINOV EMT 10 discussed above and SEPIMAX Zen (crosslinked poly- polymer). acrylate 6).

[0238] According to preferred embodiments of the present invention, the thickening agent comprises an acrylamide monomer. Examples include optionally crosslinked and / or neutralized 2-acrylamide-2-methylpropanesulfonic acid polymers and copolymers, for example poly(2-acrylamide-2-methylpropanesulfonic acid) such as that marketed under the brand name HOSTACERIN AMPS (INCI name: ammonium polyacryldimethyltauramide) by Clariant, and crosslinked anionic copolymers of acrylamide and AMPS, for example in the form of a water-in-oil emulsion, such as those sold under the brand name SEPIGEL 305 (INCI name: Polyacrylamide / C13-14 Isoparaffin / Laureth-7) and under the brand name SIMULGEL 600 (CTFA name: Acrylamide / Sodium acryloyldimethyltaurate copolymer / Isohexadecane / Polysorbate 80) by Seppic.

[0239] In one embodiment, the thickening agent in the compositions of this disclosure comprises a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer. This thickening agent may be commercially available as a mixture with sorbitan isostearate and polysorbate 60 under the brand name SEPINOV EMT 10 of Seppic.

[0240] The thickening agent(s) may be selected from guar gum, biosaccharide gum, cellulose, acacia seneca gum, sclerotium gum, agarose, pectin, gellan gum, hyaluronic acid. In some cases, the hair cosmetic composition may be free or substantially free of xanthan gum.

[0241] In addition or alternatively, one or more thickening agents may include polymer thickening agents selected from the group consisting of ammonium polyacryloyldimethyltaurate, ammonium acryloyldimethyltaurate / VP copolymer, sodium polyacrylate, acrylate copolymers, polyacrylamide, carbomer, and C10-30 acrylate / alkyl acrylate crosslinked polymer. Other examples of thickening agents that may be suitable can be found in U.S. Patent Application No. 16 / 731,654.

[0242] Many thickening agents are water-soluble and increase the viscosity of water or form an aqueous gel when the cosmetic composition of the invention is dispersed / dissolved in water. The aqueous solution can be heated and cooled, or neutralized, to form the gel, if necessary. The thickening agent can be dispersed / dissolved in an aqueous solvent that is water-soluble, for example, ethyl alcohol when dispersed / dissolved in water.

[0243] Specific types of thickening agents that may be mentioned include the following:

[0244] One or more thickening agents may optionally be included in the cosmetic compositions of this disclosure. Thickening agents may be referred to as "thickeners" or "viscosity modifiers." Thickening agents are typically included to increase the viscosity of cosmetic compositions. However, in some cases, certain thickening agents provide additional and surprising benefits to hair cosmetic compositions. Non-limiting examples of thickening agents include crosslinked polyacrylate or polyacrylate polymers, cationic acrylate copolymers, anionic acrylic or carboxylic acid polymers, polyacrylamide polymers, polysaccharides such as cellulose derivatives, gums, polyquaterniums, vinylpyrrolidone homopolymers / copolymers, C8-24 hydroxyl-substituted aliphatic acids, C8-24 conjugated aliphatic acids, sugar fatty acid esters, polyglyceryl esters, and mixtures thereof.The particular types of thickening agents that may be mentioned include the following:

[0245] (i) Homopolymer or copolymer based on carboxylic acid or carboxylate, which . can be linear or reticulated:

[0246] These polymers contain one or more monomers derived from acrylic acid, substituted acrylic acids, and salts and esters of these acrylic acids (acrylates) and substituted acrylic acids. Commercially available polymers include those sold under the trade names CARBOPOL, ACRYSOL, POLYGEL, SOKALAN, CARBOPOL ULTREZ, and POLYGEL. Examples of commercially available carboxylic acid polymers include carbomers, which are homopolymers of acrylic acid crosslinked with alkyl ethers of sucrose or pentaerythritol. Carbomers are available in BF Goodrich's CARBOPOL 900 series (e.g., CARBOPOL 954). In addition, other suitable carboxylic acid polymer agents include ULTREZ 10 (BF Goodrich) and alkyl acrylate copolymers in CiO_3o with one or more monomers of acrylic acid, methacrylic acid or one of their short-chain esters (i.e. an alcohol in Ci.4), in which the crosslinking agent is an allylic sucrose ether or pentaerythritol. These copolymers are known as Cw-Cw acrylate / alkyl acrylate crosslinked polymers and are commercially available under the names CARBOPOL 1342, CARBOPOL 1382, PEMULEN TR-1 and PEMULEN TR-2, from BF Goodrich.

[0247] Other suitable carboxylic acid or carboxylate polymer agents include C5-C10 alkyl acrylic acid and acrylate copolymers, acrylic acid and maleic anhydride copolymers, and polyacrylate-6 crosslinked polymer. Polyacrylate-6 crosslinked polymer is available in the raw material known as Seppic's SEPIMAX ZEN.

[0248] Another suitable carboxylic acid or carboxylate polymeric agent includes the acrylamidopropyltrimonium chloride / acrylates copolymer, a cationic acrylates copolymer (or a quaternary ammonium compound), available as a raw material known as Seppic's SIMULQUAT HC 305.

[0249] In some embodiments, the carboxylic acid-based or carboxylate polymer thickening agents useful here are those selected from carbomers, C10-C30 alkyl acrylate crosslinked polymers, poly-acrylate-6 crosslinked polymer, acrylamidopropyltrimonium chloride / acrylates copolymer, and mixtures thereof.

[0250] (ii) Celluloses:

[0251] Non-limiting examples of celluloses include cellulose, carboxymethylhydroxyethylcellulose, cellulose acetate propionate carboxylate, hydroxyethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylhydroxyethylcellulose, microcrystalline cellulose, sodium cellulose sulfate, and mixtures thereof. In some cases, the cellulose is selected from water-soluble cellulose derivatives (e.g., carboxymethylcellulose, methylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, sodium salt of cellulose sulfate). In addition, in some cases, the cellulose is preferably hydroxypropylcellulose (HPC).

[0252] (iii)Polyvinylpyrrolidone (PVP) and copolymers:

[0253] Non-limiting examples include polyvinylpyrrolidone (PVP), polyvinylpyrrolidone (PVP) / vinyl acetate copolymer (PVP / VA copolymer), polyvinylpyrrolidone (PVP) / eicosene copolymer, PVP / hexadecene copolymer, etc. Commercially available polyvinylpyrrolidones include LUVISKOL K30, K85, and K90, available from BASF. Commercially available vinylpyrrolidone and vinyl acetate copolymers include LUVISKOL VA37 and VA64, available from BASF; vinylpyrrolidone, methacrylamide, and vinylimidazole copolymers (INCI: VP / Methacrylamide / Vinyl Imidazole Copolymer) are commercially available under the name LUVISET from BASF. In some cases, PVP and PVP / VA copolymer are preferred.

[0254] (iv) Sucrose esters:

[0255] Non-limiting examples include sucrose palmitate, sucrose cocoate, sucrose monooctanoate, sucrose monodecanoate, sucrose mono- or dilaurate, sucrose monomyristate, sucrose mono- or dipalmitate, sucrose mono- and distearate, sucrose mono-, di- or trioleate, sucrose mono- or dilinoleate, sucrose pentaoleate, sucrose hexaoleate, sucrose heptaoleate or sucrose octooleate, and mixed esters, such as sucrose palmitate / stearate, and mixtures thereof.

[0256] (v) Polyglyceryl esters:

[0257] Non-limiting fatty acid polyglycerol esters (polyglyceryl esters) include those of the following formula: OR2 RMOCH2Lh~CH2OVR 3

[0258] in which n is from 2 to 20 or from 2 to 10 or from 2 to 5, or is equal to 2, 3, 4, 5, 6, 7, 8, 9 or 10, and R1, R2 and R3 can each independently be a fatty acid fraction or a hydrogen, provided that at least one of R1, R2 and R3 is a fatty acid fraction. For example, R1, R2 and R3 can be saturated or unsaturated, linear or branched, and have a length of Ci-C40, Ci-C30, Ci-C25, or Ci-C20, Ci-Ci6, or Ci-Ci0. In addition, non-limiting examples of non-ionic polyglycerol esters of fatty acids include polyglyceryl-4 caprylate / caprate, polyglyceryl-10 caprylate / caprate, polyglyceryl-4 caprate, polyglyceryl-10 caprate, polyglyceryl-4 laurate, polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-10 laurate, polyglyceryl-10 cocoate, polyglyceryl-10 myristate, polyglyceryl-10 oleate, polyglyceryl-10 stearate, and mixtures thereof.

[0259] (vi) Erasers:

[0260] Non-limiting examples of gums include gum arabic, tragacanth gum, karaya gum, guar gum, gellan gum, tara gum, carob gum, tamarind gum, Seneca gum, sclerotium gum, etc.

[0261] Polyol(s)

[0262] The hair care composition may preferably include one or more polyols. The total amount of polyols in the hair care composition may vary, for example, from about 0.5 to about 30% by weight, based on the total weight of the hair care composition. For example, the total amount of polyols may be from about 0.5 to about 30% by weight, about 0.5 to about 25% by weight, about 0.5 to 20% by weight, about 0.5 to about 18% by weight, about 0.5 to about 16% by weight, about 0.5 to about 14% by weight, about 0.5 to about 12% by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0.5 to about 7% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight;about 1 to about 30% by weight, about 1 to about 25% by weight, about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 7% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight; about 2 to about 30% by weight, about 2 to about 25% by weight, about 2 to about 20% by weight, about 2 to about 18% by weight, about 2 to about 16% by weight, about 2 to about 14% by weight, about 2 to about 12%; by weight, about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 7% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight; about 3 to about 30% by weight, about 3 to about 25% by weight, about 3 to about 20% by weight, about 3 to about 18% by weight, about 3 to about 16% by weight, about 3 to about 14% by weight, about 3 to about 12% by weight, about 3 to about 10% by weight, about 3 to about 8% by weight, about 3 to about 7% by weight, about 3 to about 6% by weight, about 3 to about 5% by weight;about 4 to about 30% by weight, about 4 to about 25% by weight, about 4 to about 20% by weight, about 4 to about 18% by weight, about 4 to about 16% by weight, about 4 to about 14% by weight, about 4 to about 12% by weight, about 4 to about 10% by weight, about 4 to about 8% by weight, about 4 to about 7% by weight, about 4 to about 6% by weight, about 4 to about 5% by weight; about 5 to about 30% by weight, about 5 to about 25% by weight, about 5 to about 20% by weight, about 5 to about 18% by weight, about 5 to about 16% by weight, about 5 to about 14% by weight, about 5 to about 12% by weight, about 5 to about 10% by weight, about 5 to about 8% by weight, about 5 to about 7% by weight, about 5 to about 6% by weight;approximately 7 to approximately 30% by weight, approximately 7 to approximately 25% by weight, approximately 7 to approximately 20% by weight, approximately 7 to approximately 18% by weight, approximately 7 to approximately 16% by weight, approximately 7 to approximately 14% by weight, approximately 7 to approximately 12% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0263] The polyols in the hair care composition may comprise or be selected from polyols having from 2 to 15 carbon atoms and at least two hydroxyl groups. Examples of polyols that may be used in the hair care composition include and / or may be selected from alkanediols such as glycerin, 1,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, dipropylene glycol, 2-butene-1,4-diol, 2-ethyl-1,3-hexanediol, 2-methyl-2,4-pentanediol, caprylyl glycol, 1,2-hexanediol, 1,2-pentanediol and 4-methyl-1,2-pentanediol;glycol ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, ethylene glycol mono-isopropyl ether, diethylene glycol mono-isopropyl ether, ethylene glycol mono-n-butyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol mono-t-butyl ether, 1-methyl-l-methoxybutanol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, ether; mono-t-butyl propylene glycol, mono-n-propyl ether propylene glycol, mono-isopropyl ether propylene glycol, monomethyl ether dipropylene glycol, monoethyl ether dipropylene glycol, mono-n-propyl ether dipropylene glycol and mono-isopropyl ether dipropylene glycol; sorbitol; sorbitan; triacetin; and a mixture of these.

[0264] The polyol(s) may be glycols or glycol ethers such as, for example, monomethyl, monoethyl, and monobutyl ethers of ethylene glycol, propylene glycol, or ethers thereof such as, for example, monomethyl ether of propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol, and alkyl ethers of diethylene glycol, for example, monoethyl ether or monobutyl ether of diethylene glycol. In one case, the one or more polyols include or are selected from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, 1,3-propanediol, diethylene glycol, dipropylene glycol, caprylyl glycol, glycerin, and a mixture thereof. In another case, the hair care composition includes or is chosen from caprylyl glycol, glycerin and a mixture of these.

[0265] Cationic polymer(s)

[0266] Hair care compositions may include one or more cationic polymers. The amount of cationic polymers in the hair treatment composition typically ranges from about 0.01 to about 10% by weight of the total weight of the hair treatment composition. In some cases, conditioning agents are present in amounts ranging from about 0.01 to about 10% by weight, about 0.01 to about 8% by weight, about 0.01 to about 6% by weight, about 0.01 to about 5% by weight, about 0.01 to about 4% by weight, about 0.01 to about 3% by weight, about 0.01 to about 2% by weight, about 0.01 to about 1% by weight; about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight;about 0.25 to about 10% by weight, about 0.25 to about 8% by weight, about 0.25 to about 6% by weight, about 0.25 to about 5% by weight, about 0.25 to about 4% by weight, about 0.25 to about 3% by weight, about 0.25 to about 2% by weight, about 0.25 to about 1% by weight; about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight; about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, or about 2 to about 5% by weight, including the in- ranges and sub-ranges; termedial, based on the total weight of the hair care composition.

[0267] Cationic polymers may include mixtures of monomer units derived from monomers substituted with a quaternary amine and / or ammonium and / or compatible spacer monomers. Suitable cationic polymers include, for example: copolymers of l-vinyl-2-pyrrolidine and l-vinyl-3-methylimidazolium salt (e.g., the chloride salt) (called Poly-quatemium-16) such as those commercially available from BASF under the brand name LUVIQUAT (e.g., LUVIQUAT FC 370); copolymers of l-vinyl-2-pyrrolidine and dimethylaminoethyl methacrylate (called Poly-quatemium-11) such as those marketed by Gar Corporation (Wayne, NJ), USA) under the brand name GAFQUAT (for example, GAFQUAT 755N); and a cationic polymer containing a diallyl quaternary ammonium including, for example, a dimethyldiallyammonium chloride homopolymer and acrylamide and dimethyldiallyammonium chloride copolymers (called Polyquatemium-6 and Polyquaternium-7).

[0268] Other cationic polymers that can be used include polysaccharide polymers, such as cationic cellulose derivatives and cationic starch derivatives. Cationic cellulose is available from Amerchol Corp. (Edison, NJ, USA) in its Polymer JR (registered trademark) and LR (registered trademark) series of polymers, in the form of hydroxyethylcellulose salts that have reacted with a trimethylammonium substituted epoxide (called Polyquaternium-10). Another type of cationic cellulose includes quaternary ammonium polymer salts of hydroxyethylcellulose that have reacted with a lauryldimethyllammonium substituted epoxide (called Polyquaternium-24). These materials are available from Amerchol Corp. (Edison, NJ, USA) under the trade name Polymer LM-200.In addition, or alternatively, the cationic conditioning polymers may include or be selected from cationic derivatives of guar gum, such as guar hydroxypropyltrimonium chloride.

[0269] The hair treatment composition may include or be selected from poly-quatemiums. For example, the composition of hair treatment products may include Polyquaternium-1 (ethanol, 2,2',2"-nitrilotris-, polymer with 1,4-dichloro-2-butene and N,N,N',N'-tetramethyl-2-butene-1,4-diamine), Polyquaternium-2 (poly[bis(2-chloroethyl) ether-alt-1,3-bis[3-(dimethylamino)propyl]urea]), Polyquaternium-4 (copolymer of hydroxyethylcellulose-dimethyl diallylammonium chloride; copolymer of diallyldimethylammonium chloride and hydroxyethylcellulose), Polyquaternium-5 (copolymer of acrylamide and quaternized methyl dimethylammonium methacrylate), Polyquaternium-6 (poly(diallyldimethylammonium chloride)), Polyquaternium-7 (copolymeracrylamide and diallyldimethylammonium chloride), Polyquaternium-8 (dimethylaminoethyl methacrylic acid methyl and stearyl ester copolymer, quaternized with dimethyl sulfate), Polyquaternium-9 (n,N-(dimethylamino)ethyl methacrylic acid ester homopolymer, quaternized with bromomethane), Polyquaternium-10 (quaternized hydroxyethylcellulose), Polyquaternium-11 (quaternized vinylpyrrolidone and dimethylaminoethyl methacrylate copolymer), Polyquaternium-12 (quaternized ethyl methacrylate / abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate), Polyquaternium-13 (ethyl methacrylate / oleyl methacrylate / methacrylate copolymer quaternized diethylaminoethyl with dimethyl sulfate), Polyquaternium-14 (trimethylaminoethyl methacrylate homopolymer), Polyquaternium-15 (acrylamide methyl chloride and dimethylaminoethyl methacrylate copolymer),Polyquaternium-16 (copolymer of vinylpyrrolidone and quaternized vinylimidazole), Polyquaternium-17 (copolymer of adipic acid, dimethylaminopropylamine, and dichloroethyl ether), Polyquaternium-18 (copolymer of azelanic acid, dimethylaminopropylamine, and dichloroethyl ether), Polyquaternium-19 (copolymer of polyvinyl alcohol and 2,3-epoxypropylamine), Polyquaternium-20 (copolymer of polyvinyl octadecyl ether and 2,3-epoxypropylamine), Polyquaternium-22 (copolymer of acrylic acid and diallyldimethylammonium chloride), Polyquaternium-24 (quaternary ammonium salt of hydroxyethylcellulose reacted with a lauryldimethylammonium substituted epoxide), Polyquaternium-27 (sequenced copolymer of Polyquatemium-2 and Polyquaternium-17), Polyquatemium-28 (copolymer of vinylpyrrolidone and methacrylamidopropyl trimethylammonium), Polyquaternium-29 (chitosan modified with propylene oxide and quaternized with epichlorohydrin),Polyquaternium-30 (ethanaminium, N-(carboxymethyl)-N,N-dimethyl-2-[(2-methyl-l-oxo-2-propen-l-yl)oxy]-, internal salt, polymer with methyl 2-methyl-2-propenoate), Polyquaternium-31 (N,N-dimethylaminopropyl-N-acrylamidine quaternized with diethyl sulfate linked to a polyacrylonitrile sequence), Polyquaternium-32 (poly(acrylamide 2-methacryloxyethyltrimethylammonium chloride)), Polyquaternium-33 (copolymer of trimethylaminoethyl acrylate salt and acrylamide), Polyquaternium-34 (copolymer of 1,3-dibromopropane and N,N-diethyl-N',N'-dimethyl-l,3-propanediamine), Polyquaternium-35 (methosulfate of copolymer of methacryloyloxyethyltrimethylammonium and methacryloyloxyethyldimethylacetylammonium), Polyquaternium-36 (copolymer of N,N-dimethylaminoethyl methacrylate and butyl methacrylate, quaternized with dimethyl sulfate), Polyquaternium-37 (poly(2-methacryloxyethyltrimethylammonium) chloride), Polyquaternium-39 (terpolymer, of acrylic acid, acrylamide and diallyldimethylammonium chloride), Poly-quatemium-42 (poly[oxyethylene(dimethylimino)ethylene (dimethylimino)ethylene] dichloride), Polyquatemium-43 (copolymer of acrylamide, acrylamidopropyltrimonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine), Polyquatemium-44 (copolymer of 3-methyl-l-vinylimidazolium methyl sulfate and N-vinylpyrrolidone), Polyquaternium-45 (copolymer of (N-methyl-N-ethoxyglycine) methacrylate and N,N-dimethylaminoethyl methacrylate, quaternized with dimethyl sulfate), Polyquaternium-46 (terpolymer of vinylcaprolactam, vinylpyrrolidone and quaternized vinylimidazole), Polyquaternium-47 (terpolymer of acrylic acid, methacrylamidopropyl trimethylammonium chloride and methyl acrylate) and / or Polyquaternium-67.

[0270] In some cases, the hair treatment compositions of this disclosure include one or more cationic polymers selected from cationic derivatives of cellulose, quaternized hydroxyethylcellulose (e.g., poly-quaternium-10), cationic derivatives of starch, cationic derivatives of guar gum, copolymers of acrylamide and dimethyldiallyammonium chloride (e.g., polyquaternium-7), polyquatemiums, and a mixture thereof. For example, the cationic polymer(s) can be chosen from among the polyquatemiums, for example, polyquatemiums chosen from polyquatemium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, polyquaternium-37, polyquaternium-39, polyquaternium-47, polyquaternium-53, polyquaternium-67 and a mixture thereof. A combination of two or more polyquatemiums can be useful.

[0271] Dans un cas, les un ou plusieurs polymères cationiques sont choisis parmi poly-quatemium 4, polyquaternium 6, polyquaternium 7, polyquaternium 10, poly-quatemium 11, polyquaternium 16, polyquaternium 22, polyquaternium 28, poly-quatemium 32, polyquaternium-46, polyquaternium-51, polyquaternium-52, poly-quatemium-53, polyquaternium-54, polyquaternium-55, polyquaternium-56, poly-quatemium-57, polyquaternium-58, polyquaternium-59, polyquaternium-60, poly-quatemium-63, polyquaternium-64, polyquaternium-65, polyquaternium-66, poly-quatemium-67, polyquaternium-70, polyquaternium-73, polyquaternium-74, poly-quatemium-75, polyquaternium-76, polyquaternium-77, polyquaternium-78, poly-quatemium-79, polyquaternium-80, polyquaternium-81, polyquaternium-82, poly-quatemium-84, polyquaternium-85, polyquaternium-86, polyquaternium-87, poly-quatemium-90, polyquaternium-91, polyquaternium-92, polyquaternium-94, chlorure de guar hydroxypropyltrimonium, et un mélange de ceux-ci.

[0272] Water

[0273] The composition of hair care products may include an amount of water which may be from about 30 to about 95% by weight, based on the total weight of the hair care composition. In some cases, the hair care composition includes water in an amount of about 30 to about 95% by weight, about 35 to about 95% by weight, about 40 to about 95% by weight, about 45 to about 95% by weight, about 50 to about 95% by weight, about 55 to about 95% by weight, about 60 to about 95% by weight; about 30 to about 90% by weight, about 35 to about 90% by weight, about 40 to about 90% by weight, about 45 to about 90% by weight, about 50 to about 90% by weight, about 55 to about 90% by weight, about 60 to about 90% by weight; about 30 to about 85% by weight, about 35 to about 85% by weight, about 40 to about 85% by weight, about 45 to about 85% by weight, about 50 to about 85% by weight, about 55 to about 85% by weight, about 60 to about 85% by weight;about 30 to about 80% by weight, about 35 to about 80% by weight, about 40 to about 80% by weight, about 45 to about 80% by weight, about 50 to about 80% by weight, about 55 to about 80% by weight, about 60 to about 80% by weight; about 30 to about 75% by weight, about 35 to about 75% by weight, about 40 to about 75% by weight, about 45 to about 75% by weight, about 50 to about 75% by weight, about 55 to about 75% by weight, about 60 to about 75% by weight; approximately 30 to approximately 70% by weight, approximately 35 to approximately 70% by weight, approximately 40 to approximately 70% by weight, approximately 45 to approximately 70% by weight, approximately 50 to approximately 70% by weight, approximately 55 to approximately 70% by weight, approximately 60 to approximately 70% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0274] pH adjuster(s)

[0275] The hair care composition may include one or more pH adjusters to raise or lower the overall pH of the hair care composition. For example, one or more acids may be included to lower the pH of the hair care composition. Examples of acids suitable for lowering the pH of the hair care composition include, but are not limited to, citric acid, acetic acid, and the like. The hair care composition may include one or more bases, such as sodium hydroxide, potassium hydroxide, and the like, to raise the pH of the hair care composition. Additional or alternative acids and bases that are suitable for adjusting the pH of the hair care composition are readily known to a person with ordinary competence in the art.

[0276] The amount of pH adjuster in the hair care composition can be based on the desired pH of the composition and / or the final hair care product. For example, the hair care composition may contain an amount of pH adjuster such that the pH of the composition is from approximately 3 to approximately 9, preferably from about 3.5 to about 8.

[0277] The amount of pH adjuster in the hair care composition can be based on the desired pH of the composition and / or the final hair care product. For example, the total amount of pH adjuster can range from about 0.05 to about 20% by weight, relative to the total weight of the hair care composition. In some cases, the total amount of pH adjuster is about 0.05 to about 15% by weight, about 0.1 to about 10% by weight, or about 0.12 to about 5% by weight, including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0278] Chelating agent(s)

[0279] The hair care composition may optionally include chelating agents. The amount of chelating agent present in the hair care composition may be, for example, from about 0.01 to about 20% by weight, about 0.01 to about 15% by weight, about 0.01 to about 10% by weight, about 0.01 to about 8% by weight, about 0.01 to about 6% by weight, about 0.01 to about 5% by weight, about 0.01 to about 4% by weight, about 0.01 to about 3% by weight, about 0.01 to about 2% by weight, about 0.01 to about 1% by weight; about 0.1 to about 20% by weight, about 0.1 to about 15% by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight;about 0.25 to about 20% by weight, about 0.25 to about 15% by weight, about 0.25 to about 10% by weight, about 0.25 to about 8% by weight, about 0.25 to about 6% by weight, about 0.25 to about 5% by weight, about 0.25 to about 4% by weight, about 0.25 to about 3% by weight, about 0.25 to about 2% by weight, about 0.25 to about 1% by weight; about 0.5 to about 20% by weight, about 0.5 to about 15% by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight, about 0.5 to about 4% by weight, about 0.5 to about 3% by weight, about 0.5 to about 2% by weight, about 0.5 to about 1% by weight;about 0.75 to about 20% by weight, about 0.75 to about 15% by weight, about 0.75 to about 10% by weight, about 0.75 to about 8% by weight, about 0.75 to about 6% by weight, about 0.75 to about 5% by weight, about 0.75 to about 4% by weight, about 0.75 to about 3% by weight, about 0.75 to about 2% by weight; about 1 to about 20% by weight, about 1 to about 15% by weight, about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight, about 1 to about 4% by weight, about 1 to about 3% by weight, or about 1 to about 2% by weight, y; including intermediate ranges and sub-ranges, based on the total weight of the hair care composition.

[0280] Non-limiting examples of chemical chelating agents include amino-trimethylphosphonic acid, β-alanine diacetyl, cyclodextrin, cyclohexanediamine tetraacetic acid, diethylenetriamine pentamethylenephosphonic acid, diethanolamine N-acetic acid, ethylenediamine tetraacetic acid (EDTA or YH4) and its sodium salts (YH3Na, Y2H2Na2, YHNa3 and YNa4), potassium salts (YH3K, Y2H3K3 and YK4), calcium disodium and diammonium salts and its salts with triethanolamine (TEA-EDTA), etidronic acid, galactanic acid, hydroxyethylethylenediamine tetraacetic acid (HEDTA) and its trisodium salt, gluconic acid, glucuronic acid, nitrilotriacetic acid (NTA) and its trisodium salt, pentetic acid, phytic acid, ribonic acid, citrate diammonium, azacycloheptane disodium diphosphonate, disodium pyrophosphate, hydroxypropyl cyclodextrin, methyl cyclodextrin, pentapotassium triphosphate, pentasodium aminotrimethylene phosphonate,ethylenediamine tetramethylene phosphonate pentasodium, pentasodium pentetate, pentasodium triphosphate, potassium citrate, potassium EDTMP, sodium EDTMP, sodium chitosan methylene phosphonate, sodium hexametaphosphate, sodium metaphosphate, potassium polyphosphate, sodium polyphosphate, sodium trimetaphosphate, sodium dihydroxyethylglycinate, potassium gluconate, sodium gluconate, sodium glucoptate, sodium glycereth-1 polyphosphate, tetrapotassium pyrophosphate, triethanolamine polyphosphate (TEA), tetrasodium pyrophosphate, trisodium phosphate, potassium triphosphonomethylamine oxide, sodium metasilicate, sodium phytate, sodium polydimethylglycinophenolsulfonate, tetrahydroxyethyl ethylenediamine, tetrahydroxypropyl ethylenediamine, tetrapotassium etidronate, tetrasodium etidronate, tetrasodium iminodisuccinate, ethylenediamine disuccinate trisodium, ethanolamine N,N-diacetic acid,disodium acetate, dimercaprol, deferoxamine, Zylox, and / or the iron-chelating agent disclosed and claimed in international patent application WO 94 / 61338. Examples of biological chelating agents include metallothionein, transferrin, calmodulin, and sodium chitosan methylene phosphonate. In at least one case, the chelating agent is trisodium ethylenediamine disuccinate.

[0281] Conservative(s)

[0282] Preservatives may be included in the composition of hair care products in quantities typically ranging from about 0.01 to about 20% by weight, about 0.01 to about 18% by weight, about 0.01 to about 16% by weight, about 0.01 to about 14% by weight, about 0.01 to about 12% by weight, about 0.01 to about 10% by weight, about 0.01 to about 8% by weight, about 0.01 to about 7% by weight, about 0.01 to about 6% by weight, about 0.01 to about 5% by weight; about 0.1 to about 20% by weight, about 0.1 to about 18% by weight, about 0.1 to about 16% by weight, about 0.1 to about 14% by weight, about 0.1 to about 12% by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.1 to about 7% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight; about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 7% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight;approximately 4 to approximately 20% by weight, approximately 4 to approximately 18% by weight, approximately 4 to approximately 16% by weight, approximately 4 to approximately 14% by weight, approximately 4 to approximately 12% by weight, approximately 4 to approximately 10% by weight, approximately 4 to approximately 8% by weight, or approximately 4 to approximately 7% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition. Non-limiting examples of preservatives include sodium benzoate, potassium sorbate, phenoxyethanol, salicylic acid, tocopherol, chlorphenesin, BHT, disodium EDTA, pentaerythrityl tetra-di-t-butyl hydroxyhydrocinnamate, and mixtures thereof.

[0283] Miscellaneous ingredient(s)

[0284] Hair care compositions may include one or more miscellaneous ingredients, such as colorants, opacifiers, absorbents, active ingredients, perfumes, extracts (e.g., natural extracts), fillers (e.g., organic fillers, inorganic fillers, silica, mica, etc.), or the like. The total amount of miscellaneous ingredients is typically about 15% by weight or less, based on the total weight of the hair care compositions. For example, the hair care composition may include miscellaneous ingredients in an amount of about 12.5% ​​by weight or less, about 10% by weight or less, about 8% by weight or less, about 6% by weight or less, about 5% by weight or less, about 4% by weight or less, about 3% by weight or less, about 2% by weight or less, or about 1% by weight or less, based on the total weight of the hair care composition.In some cases, the quantity of various ingredients present in the composition of hair care products is from about 0.01 to about 15% by weight, about 0.01 to about 12.5% ​​by weight, about 0.01 to about 10% by weight, about 0.01 to about 8% by weight, about 0.01 to about 6% by weight, about 0.01 to about 5% by weight, about 0.01 to about 4% by weight, about 0.01 to about 3% by weight, about 0.01 to about 2% by weight, about 0.01 to about 1% by weight; about 0.1 to about 15% by weight, about 0.1 to about 12.5% ​​by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.1 to . about 6% by weight, about 0.1 to about 5% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight; about 0.5 to about 15% by weight, about 0.5 to about 12.5% ​​by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight, about 0.5 to about 4% by weight, about 0.5 to about 3% by weight, about 0.5 to about 2% by weight, about 0.5 to about 1% by weight; about 1 to about 15% by weight, about 1 to about 12.5% ​​by weight, about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 5% by weight, about 1 to about 4% by weight, about 1 to about 3% by weight, about 1 to about 2% by weight;about 2 to about 15% by weight, about 2 to about 12.5% ​​by weight, about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight, about 2 to about 4% by weight; about 4 to about 15% by weight, about 4 to about 12.5% ​​by weight, about 4 to about 10% by weight, about 4 to about 8% by weight, about 4 to about 6% by weight; about 6 to about 15% by weight, about 6 to about 12.5% ​​by weight, about 6 to about 10% by weight, about 6 to about 8% by weight; about 8 to about 15% by weight, about 8 to about 12.5% ​​by weight, about 8 to about 10% by weight; approximately 10 to approximately 15% by weight, approximately 10 to approximately 12.5% ​​by weight; or approximately 12 to approximately 15% by weight, including all intermediate ranges and sub-ranges, based on the total weight of the hair care composition. methods of disclosure

[0285] In certain embodiments of the disclosure, a hair care composition is provided comprising:

[0286] - one or more non-ionic surfactants comprising one or more poly- alkyl glucosides, preferably in an amount of about 1 to about 15% by weight, more preferably in an amount of about 2 to about 13% by weight, wherein the one or more alkyl polyglucosides comprise an alkyl glucoside in Ci2_20 and, optionally, the one or more nonionic surfactants further comprise PEG-40 hydrogenated castor oil;

[0287] - one or more fatty alcohols, preferably in an amount of about 0.5 to about 10% by weight, more preferably in an amount of about 1 to about 8% by weight, in which one or more fatty alcohols may include Ci4 22 alcohols and / or octyldodecanol;

[0288] - one or more fatty esters, preferably in an amount of about 1 to about 20% by weight, more preferably in an amount of about 3 to about 16% by weight, one or more fatty esters comprising caprylic triglyceride / capric and, optionally, isopropyl myristate, glyceryl stearate, sorbitan isostearate, or a mixture thereof;

[0289] - about 0.5 to about 30% by weight, preferably about 0.5 to about 20% by weight, more preferably about 2 to about 20% by weight, of a fatty compound other than a fatty alcohol and a fatty ester, such as isododecane, hydrogenated vegetable oil, butyrospermum parkii (shea) butter, euphorbia cerifera (candelilla) wax, beeswax, or a mixture thereof;

[0290] - one or more silicones, preferably in an amount of about 0.5 to about 10% by weight, more preferably in an amount of about 0.5 to about 6% by weight, wherein one or more silicones comprise polysilicone-11 and, optionally, dimethicone;

[0291] - one or more thickening agents, preferably in an amount of about 0.1 to about 7% by weight, more preferably in an amount of about 0.1 to about 5% by weight, wherein the thickening agents preferably comprise a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer; and

[0292] - water, preferably in a quantity of about 30 to about 95% by weight, of a more preferred manner in an amount of about 45 to about 80% by weight, in which the hair care composition is an emulsion, and all percentages by weight are based on the total weight of the hair care composition.

[0293] In other embodiments of the disclosure, a hair care composition is provided comprising:

[0294] - about 2 to about 15% by weight, preferably about 2 to about 13% by weight, more preferably about 2 to about 10% by weight, of one or more nonionic surfactants comprising alkyl polyglucosides, wherein the one or more nonionic surfactants comprise a Ci2_20 alkyl glucoside and, optionally, PEG-40 hydrogenated castor oil;

[0295] - about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, more preferably about 1 to about 5% by weight, of one or more fatty alcohols, in which the one or more fatty alcohols may include Ci4.22 alcohols and / or octyldodecanol;

[0296] - about 1 to about 20% by weight, preferably about 3 to about 20% by weight, more preferably about 3 to about 16% by weight, of one or more fatty esters, wherein the one or more fatty esters comprise caprylic / capric triglyceride and optionally isopropyl myristate, glyceryl stearate, sorbitan isostearate, or a mixture thereof;

[0297] - about 0.5 to about 30% by weight, preferably about 0.5 to about 20% by weight, preferably about 2 to about 20% by weight, of a fatty compound other than a fatty alcohol and a fatty ester, such as isododecane, oil hydrogenated vegetable oil, butyrospermum parkii (shea) butter, euphorbia cerifera (candelilla) wax, beeswax, or a mixture of these;

[0298] - about 0.5 to about 10% by weight, preferably about 0.5 to about 8% by weight, more preferably from about 0.5 to about 6% by weight, of one or more silicones, wherein the one or more silicones comprise poly-silicone-11 and, optionally, dimethicone;

[0299] - about 0.1 to about 10% by weight, preferably about 0.1 to about 7% by weight, more preferably about 0.1 to about 5% by weight, of one or more thickening agents, in which the thickening agents preferably comprise a copolymer of hydroxyethyl acrylate / sodium acryloyldimethyl taurate;

[0300] - water, preferably in a quantity of about 30 to about 95% by weight, of preferred method in an amount of about 45 to about 80% by weight;

[0301] - optionally, about 0.5 to about 30% by weight, preferably about 0.5 to 20% by weight, more preferably about 2 to about 20% by weight, of a polyol, such as those selected from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, 1,3-propanediol, diethylene glycol, dipropylene glycol, caprylyl glycol, glycerin, and mixtures thereof;

[0302] - optionally, about 0.01 to about 10% by weight, preferably about 0.1 to environ 8 % en poids, de manière davantage préférée environ 0,1 à environ 6 % en poids, d’un polymère cationique choisi parmi les polyquaternium-4, polyquatemium-6, polyquaternium-7, polyquaternium-10, polyquaternium-11, polyquaternium-16, poly-quatemium-22, polyquaternium-28, polyquaternium-32, polyquaternium-46, poly-quatemium-51, polyquaternium-52, polyquaternium-53, polyquaternium-54, poly-quatemium-55, polyquaternium-56, polyquaternium-57, polyquaternium-58, poly-quatemium-59, polyquaternium-60, polyquaternium-63, polyquaternium-64, poly-quatemium-65, polyquaternium-66, polyquaternium-67, polyquaternium-70, poly-quatemium-73, polyquaternium-74, polyquaternium-75, polyquaternium-76, poly-quatemium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, poly-quatemium-81, polyquaternium-82, polyquaternium-84, polyquaternium-85, poly-quatemium-86, polyquaternium-87, polyquaternium-90, polyquaternium-91, poly-quatemium-92, polyquaternium-94,guar chloride hydroxypropyltrimonium, and a mixture thereof,

[0303] in which all percentages by weight are based on the total weight of the hair care composition.

[0304] In other embodiments of the disclosure, a method is provided for improving hair comprising:

[0305] (I) the application of a hair care composition to the hair, the com- Hair care package including:

[0306] - one or more non-ionic surfactants comprising alkyl polyglucosides, preferably in an amount of about 1 to about 15% by weight, more preferably in an amount of about 2 to about 13% by weight, wherein one or more non-ionic surfactants may comprise a C12-20 alkyl glucoside and / or PEG-40 hydrogenated castor oil,

[0307] - one or more fatty alcohols, preferably in an amount of about 0.5 to about 10% by weight, more preferably in an amount of about 1 to about 8% by weight, wherein one or more fatty alcohols may comprise Ci4 22 alcohols and / or octyldodecanol,

[0308] - one or more fatty esters, preferably in an amount of about 1 to about 20% by weight, more preferably in an amount of about 3 to about 16% by weight, one or more fatty esters comprising caprylic / capric triglyceride and, optionally, isopropyl myristate, glyceryl stearate, sorbitan isostearate, or a mixture thereof,

[0309] - about 0.5 to about 30% by weight, preferably about 0.5 to about 20% by weight, preferably about 2 to about 20% by weight, of a fatty compound other than a fatty alcohol and a fatty ester, such as isododecane, hydrogenated vegetable oil, butyrospermum parkii (shea) butter, euphorbia cerifera (candelilla) wax, beeswax, or a mixture thereof,

[0310] - one or more silicones, preferably in an amount of about 0.5 to about 10% by weight, more preferably in an amount of about 0.5 to about 6% by weight, wherein one or more silicones comprise polysilicone-11 and, optionally, dimethicone,

[0311] - one or more thickening agents, preferably in an amount of about 0.1 to about 7% by weight, more preferably in an amount of about 0.1 to about 5% by weight, wherein the thickening agents preferably comprise a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer, and

[0312] - water, preferably in a quantity of about 30 to about 95% by weight, of a more preferred manner in an amount of about 45 to about 80% by weight, in which the hair care composition is an emulsion, and all percentages by weight are based on the total weight of the hair care composition;

[0313] (II) optionally, rinsing hair care compositions from hair.

[0314] The terms “comprising,” “having,” and “including” are used in their broad and non-limiting sense. The compositions and processes of this disclosure may include, consist, or consist substantially of the essential elements and limitations of the disclosure described herein, as well as any additional or optional ingredient, component, or limitation described herein or otherwise useful.

[0315] All percentages, parts, and ratios stated herein are based on the total weight of the compositions in this disclosure, unless otherwise stated. All ranges and values ​​disclosed herein are inclusive and combinable. The term "inclusive" for a range of concentrations means that the boundaries of the range are included within the defined interval. For example, any value or point described herein that lies within a range described herein may serve as a minimum or maximum value for deriving a subrange, and so on. Furthermore, all ranges provided are intended to include each specific range within the given ranges, as well as any combination of subranges between them. Thus, a range of 1 to 5 specifically includes 1, 2, 3, 4, and 5, as well as subranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, and so on.In this document, the expression "at least one" is interchangeable with the expression "one or more" and therefore includes individual components as well as mixtures / combinations.

[0316] The term “substantially free” or “essentially free” as used here means that there is less than about 5% by weight of a specific material added to a composition, based on the total weight of the compositions. However, the compositions may include less than about 2% by weight, less than about 1% by weight, less than about 0.5% by weight, less than about 0.1% by weight, less than 0.01% by weight, or none of the specified material.

[0317] The term "active substance", as used here in relation to the percentage quantity of an ingredient or raw material, refers to 100% activity of the ingredient or raw material.

[0318] Throughout the disclosure, the phrase "a mixture of these" may be used following a list of items, as shown in the following example where the letters A through F represent the items: "one or more items selected from the group consisting of A, B, C, D, E, F, and a mixture of these." The phrase "a mixture of these" does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a mixture of two or more of A, B, C, D, E, and F may be included. In other words, it is equivalent to the phrase "one or more items selected from the group consisting of A, B, C, D, E, F, and a mixture of two or more of A, B, C, D, E, and F."

[0319] Similarly, the term "a salt of it" also refers to "salts of it." Thus, when the disclosure refers to "an element selected from the group consisting of A, B, C, D, E, F, a salt of it, and a mixture of these," it indicates that one or more of A, B, C, D, and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included, or a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included. The salts The counterions mentioned throughout the disclosure may include salts with a counterion such as an alkali metal, an alkaline earth metal, or an ammonium counterion. However, this list of counterions is not exhaustive.

[0320] “Volatile”, as used here, means having a flash point less than about 100°C. “Non-volatile”, as used here, means having a flash point above approximately 100°C.

[0321] The term "polymers", as defined herein, includes homopolymers and copolymers formed from at least two different types of monomers.

[0322] The term “INCI” is an abbreviation for International Nomenclature of Cosmetic Ingredients, which is a system of names provided by the International Nomenclature Committee of the Personal Care Products Council to describe personal care ingredients.

[0323] All components and elements positively presented in this disclosure may be negatively excluded from the claims. In other words, the compositions (nanoemulsions) of this disclosure may be free or substantially free of all the components and elements positively cited in this disclosure.

[0324] Some of the various categories of identified components may overlap. In such cases where an overlap may exist and the composition includes both components (or the composition includes more than two overlapping components), an overlapping compound does not represent more than one component. For example, a fatty acid may be characterized as both a nonionic surfactant and a fatty compound. If a particular composition includes both a nonionic surfactant and a fatty compound, a single fatty acid will serve only as a nonionic surfactant or only as a fatty compound (the single fatty acid does not serve as both a nonionic surfactant and a fatty compound). However, fatty compounds (such as fatty alcohols) may or may not be an oil, depending on the fatty alcohol in question. EXAMPLES

[0325] The implementation of this disclosure is provided by means of the following examples. The following examples serve to elucidate aspects of the technology without being exhaustive in nature. Example 1

[0326] Two non-limiting example compositions (Ex. A and B) were prepared according to the disclosure aspects. A comparative composition (Comp. 1) was also prepared according to the formula provided below. The formulations of Example Compositions A and B and Comparative Composition 1 are shown in Table 1 below.

[0327] [Tables 1] Nom INCI US Ex. A Ex. B Comp. 1 (a) Tensioactif non ionique POLYSORBATE 60, and PEG-40 HY- DROGENATED CASTOR OIL 5,1 5,1 5,1 C12-20 ALKYL GLUCOSIDE 0,2 0,2 0,2 (b) Alcool gras OCTYLDODECANOL 1 1 1 C14-22 ALCOHOLS 0,8 0,8 0,8 (c) Ester gras ISOPROPYL MYRISTATE, GLYCERYL STEARATE, and SORBITAN ISOSTEARATE 7,3 7,2 7,3 CAPRYLIC / CAPRIC TRIGLYCERIDE 0,1 0,1 (d) Composé gras autre qu’alcool gras et ester gras ISODODECANE and HY- DROGENATED VEGETABLE OIL 4,5 4 4,5 Cire BUTYROSPERMUM PARKII (SHEA) BUTTER, EUPHORBIA CERIFERA (CANDELILLA) WAX, and BEESWAX 2,8 1,9 2,8 (e) Silicone DIMETHICONE 1,6 1,6 1,6 POLYSILICONE-11 <0,1 <0,1 <0,1 (f) Agent épaississant acrylique HYDROXYETHYL ACRYLATE / SODIUM ACRYLOYLDIMETHYL TAURATE COPOLYMER 0,89 0,89 0,89 (h) Polyol GLYCERIN 10 10 10 (i) Polymère cationique POLYQUATERNIUM-10 0,1 0,1 0,1 Conservateurs ETHYLHEXYLGLYCERIN, TO-COPHEROL, PHENOXYETHANOL, and CITRIC ACID ~ 0,9 ~ 0,9 ~ 0,9 Parfum FRAGRANCE < 1 < 1 < 1 (g) Eau WATER 64,31 65,81 64,41 Example 2

[0328] Three comparative compositions (comparative compositions 2 to 4) were prepared to have the same formulation as the composition of Example A, except that comparative compositions 2 to 4 had a cationic surfactant instead of the alkyl glucoside in Ci2_20 and the alcohols in Ci4_22. In particular, comparative composition 2 included 1 gram of cetrimonium chloride, comparative composition 3 included 1 gram of behentrimonium chloride, and comparative composition 4 included 1 gram of dicetyldimonium chloride instead of the alkyl glucoside in Ci2_20 and the alcohols in CM_22 used in the composition of Example A. The steps in the process of producing comparative compositions 2 to 4 were the same as those used to produce the composition of Example A.

[0329] Comparative compositions 2 to 4 and example compositions A and B were then evaluated to determine the stability of their respective emulsions. Specifically, two samples of comparative compositions 2 to 4 and example compositions A and B were maintained under certain environmental conditions for 8 weeks and visually assessed at different times to determine the stability of the respective emulsions. The first sample of each composition was maintained at room temperature and the second sample of each composition was maintained at a temperature of 45°C.

[0330] Comparative composition 2 exhibited an unstable emulsion; the sample, maintained at 45 °C, showed the hydrophobic phase separating from the hydrophilic phase. Samples of comparative composition 3 exhibited an unstable emulsion at both room temperature and 45 °C. Comparative composition 4 did not form an emulsion. Example compositions A and B each exhibited a stable emulsion at both room temperature and elevated temperatures. Surprisingly, example compositions A and B exhibited and maintained a stable emulsion at both room temperature and elevated temperatures, given that both compositions contain large quantities of oils and silicone compounds. Example 3

[0331] Four comparative compositions (comparative compositions 5 to 8) were prepared to have the same formulation as composition of example A, except that comparative compositions 5 to 8 had isopropyl myristate replaced by olive oil, sunflower oil, linseed oil, or alkane esters. More specifically, comparative composition 5 included 7 grams of olive oil, comparative composition 6 included 7 grams of sunflower oil, comparative composition 7 included 7 grams of linseed oil, and comparative composition 8 included 7 grams of alkane esters. In addition, comparative compositions 5 to 8 were produced using the same processing steps as those used to produce example composition A.

[0332] Comparative compositions 5 to 8 and example compositions A and B were then evaluated to determine their respective conditioning properties. In particular, a sample of comparative compositions 5 to 8 and example compositions A and B was applied separately to respective hair strands in an amount of 2 grams (g) of composition per 10 g of hair. The hair strands were then combined to ensure uniform application of the sample to the hair strand. The hair strands were then rinsed. After drying, the hair strands were evaluated to determine the conditioning properties of comparative compositions 5 to 8 and example compositions A and B.

[0333] Comparative composition 5 left the hair feeling very heavy and was unsuitable for leave-in products. Comparative compositions 6 and 7 left the hair feeling greasy. Comparative composition 8 did not provide sufficient coating or a conditioning sensation. Example compositions A and B did not weigh down the hair and provided significant conditioning properties. Example 4

[0334] Four comparative compositions (comparative compositions 9 to 12) were prepared to have the same formulation as composition of example A, except that in comparative compositions 9 to 12 octyldodecanol was replaced by cetearyl alcohol, glyceryl stearate, cetearyl alcohol in conjunction with cetearyl glucoside, and tribehenin. More specifically, comparative composition 9 included 1 gram of cetearyl alcohol, comparative composition 10 included 1 gram of glyceryl stearate, comparative composition 11 included 0.5 gram of cetearyl alcohol and 0.5 gram of cetearyl glucoside, and comparative composition 12 included 1 gram of tribehenin. In addition, the steps in the production process of comparative compositions 9 to 12 were the same as those used to produce example composition A.

[0335] Comparative compositions 9 to 12 and example compositions A and B were then evaluated to determine the stability of their respective emulsions. Specifically, samples of comparative compositions 2 to 4 and example compositions A and B were kept at room temperature for 8 weeks and visually assessed at various times to determine the stability of the respective emulsions. Comparative composition 9 did not form a stable emulsion. Comparative composition 10 was unable to contain the large quantities of oil in The emulsion formed, and consequently, the hydrophilic phase separated from the emulsion. Comparative compositions 11 and 12 also failed to form a stable emulsion. Example 5

[0336] Seven comparative compositions (comparative compositions 13 to 19) were prepared to have the same formulation as Example Composition A, except that in comparative compositions 13 to 19, dimethicone and polysilicone-11 were replaced by different dimethicones, dimethiconol, and a crosslinked dimethicone-PEG-10 / 15 polymer. Specifically, comparative composition 13 included 1.6 g of dimethicone having a viscosity of 350 centistokes (cST). Comparative composition 14 included 1.6 g of dimethicone having a viscosity of 300,000 cST. Comparative composition 15 included 1.6 g of dimethicone having a viscosity of 5 cST. Comparative composition 16 included 1.6 g of a combination of dimethicone and dimethiconol, the combination having a viscosity of 300,000 cSt. Comparative composition 17 included 1.6 g of a combination of dimethicone and PEG-10 / 15 crosslinked polymer, the combination having a viscosity of 500,000 cSt.Comparative composition 18 included 1.6 g of a dimethicone having a viscosity of 6900 cSt. Comparative composition 19 included 1.6 g of dimethiconol having a viscosity of 1500 cSt. Furthermore, the steps in the production process of comparative compositions 13 to 19 were the same as those used to produce example composition A.

[0337] Comparative compositions 13 to 19 and example compositions A and B were then evaluated to assess the stability and coating properties of their respective compositions. In particular, a sample of comparative compositions 13 to 19 and example compositions A and B was applied separately to respective hair strands in an amount of 2 grams (g) of composition per 10 g of hair. The hair strands were then combined to ensure uniform application of the sample to the hair strand. The hair strands were then rinsed. After drying, the hair strands were evaluated to determine the conditioning properties of comparative compositions 13 to 19 and example compositions A and B.

[0338] Comparative composition 13 produced a light coating on the hair, which did not persist after shampooing. Comparative composition 14 provided a heavy coating that weighed down the hair. Although comparative composition 15 provided a good coating, the coating did not last after shampooing. Comparative composition 16 provided a slightly heavy coating that was undesirable. Comparative composition 17 did not form an emulsion. Comparative composition 18 provided a slightly heavy coating that was undesirable. Comparative composition 19 provided an undesirable light coating.

[0339] Example 6

[0340] It is believed that certain exemplary compositions presented in Example 1 produce emulsions with an aqueous phase and an oily phase. Table 2, provided below, shows the combination of certain ingredients in an aqueous phase or in an oily phase before the formation of the emulsion, as well as the ingredients added after the formation of the emulsion.

[0341] [Tables2] Phase: A = aqueous B = oil E = after formation of the emulsion Name of the compound INCI US A C14-22 ALCOHOLS A C12-20 ALKYL GLUCOSIDE A POLYQUATERNIUM-10 A GLYCERIN A POLYQUATERNIUM-10 A WATER B HYDROXYETHYL ACRYLATE / SODIUM ACRY- LOYLDIMETHYL TAURATE COPOLYMER B PEG-40 HYDROGENATED CASTOR OIL B HYDROGENATED VEGETABLE OIL B EUPHORBIA CERIFERA (CANDELILLA) WAX B BEESWAX B GLYCERYL STEARATE B ISOPROPYL MYRISTATE B CAPRYLIC / CAPRIC TRIGLYCERIDE E OCTYLDODECANOL E DIMETHICONE E POLYSILICONE-11 E PHENOXYETHANOL E ETHYLHEXYLGLYCERIN E FRAGRANCE

Claims

Demands

1. A hair care composition comprising: (a) one or more nonionic surfactants comprising one or more alkyl polyglucosides; (b) one or more fatty alcohols; (c) one or more fatty esters comprising a caprylic / capric triglyceride; (d) about 0.5 to about 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester; (e) one or more silicones comprising polysilicone-11; (f) one or more thickening agents; and (g) water, wherein: the one or more alkyl polyglucosides include alkyl glucosides in the C12-20 group; the one or more fatty alcohols include alcohols in the C12-22 group and further comprise octyldodecanol; and the one or more thickening agents include a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer;and in which the hair care composition is an emulsion, and all percentages by weight are based on the total weight of the hair care composition.

2. Hair care composition according to claim 1, wherein a weight ratio of the total amount of alkyl glucoside in Ci2 20 and alcohols in Ci4 22 to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer is about 0.1:1 to about 1:0.

1.

3. A hair care composition according to any one of the preceding claims, wherein one or more fatty esters comprising caprylic / capric triglyceride further comprise one or more of the following: cetyl ester, purcellin oil, isopropyl myristate, isopropyl palmitate, glyceryl stearate, sorbitan isostearate, Ci2-Ci5 alkyl benzoate, 2-ethylphenyl benzoate, isopropyl lanolate, hexyl laurate, dii-sopropyl adipate, isononyl isononanoate, oleyl erucate, 2-ethylhexyl palmitate, isostearyl isostearate, diisopropyl sebacate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, esters hydroxylated, dicaprylyl carbonate, pentaerythritol esters, or a mixture thereof.

4. Hair care composition according to any one of the preceding claims, wherein the one or more fatty esters comprising caprylic / capric triglyceride further comprise isopropyl myristate.

5. Hair care composition according to any one of the preceding claims, wherein the wax is selected from illipe butter, beeswax, butyrospermum parkii butter, euphorbia cerifera wax, carnauba, lanolin, lanolin derivatives, candelilla, cocoa butter, sugar cane wax, lignite wax, whale wax, berry wax, acacia flower wax, vegetable waxes, and a mixture thereof.

6. Hair care composition comprising: (a) about 2 to about 15% by weight of one or more nonionic surfactants comprising a Ci2_20 alkyl glucoside; (b) about 0.5 to about 10% by weight of one or more fatty alcohols comprising Ci4 22 alcohols; (c) about 1 to about 20% by weight of one or more fatty esters comprising a caprylic / capric triglyceride; (d) about 0.5 to about 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester, wherein optionally the fatty compound other than the fatty alcohol and the fatty ester comprises about 0.1 to about 10% by weight of a wax; (e) about 0.5 to about 10% by weight of one or more silicones comprising polysilicone-11, and optionally, further comprising a second silicone selected from dimethicone, dimethiconol, decamethylcyclopentasiloxane, cyclomethicone, or a mixture thereof;(f) about 0.1 to about 10% by weight of one or more thickening agents comprising a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer; wherein the weight ratio of the total amount of alkyl glucoside in Ci2 20 of (a) and alcohols in Ci4 22 of (b) to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer (f) is about 0.1:1 to about 1:0.1, (g) about 40% by weight or more of water; (h) optionally, about 0.5 to about 30% by weight of a polyol selected from ethylene glycol, propylene glycol, butylene glycol,;

7. hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1,3 propanediol, glycerin, polyethylene glycols, and a mixture thereof; (i) optionally, about 0.01 to about 10% by weight.% en poids d’un polymère cationique choisi parmi les polyquaternium-4, poly-quaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-11, polyquaternium-16, polyquaternium-22, polyquatemium-28, poly-quaternium-32, polyquaternium-46, polyquaternium-51, poly-quaternium-52, polyquaternium-53, polyquaternium-54, poly-quaternium-55, polyquaternium-56, polyquaternium-57, poly-quaternium-58, polyquaternium-59, polyquaternium-60, poly-quaternium-63, polyquaternium-64, polyquaternium-65, poly-quaternium-66, polyquaternium-67, polyquaternium-70, poly-quaternium-73, polyquaternium-74, polyquaternium-75, poly-quaternium-76, polyquaternium-77, polyquaternium-78, poly-quaternium-79, polyquaternium-80, polyquaternium-81, poly-quaternium-82, polyquaternium-84, polyquaternium-85, poly-quaternium-86, polyquaternium-87, polyquaternium-90, poly-quaternium-91, polyquaternium-92, polyquaternium-94, chlorure de guar hydroxypropyltrimonium, et un mélange de ceux-ci,. in which all percentages by weight are based on the total weight of the hair care composition. A process for improving hair, the process comprising: (I) the application of a hair care composition to the hair, the hair care composition comprising: (a) one or more non-ionic surfactants comprising one or more alkyl polyglucosides; (b) one or more fatty alcohols; (c) one or more fatty esters comprising a caprylic / capric triglyceride; (d) about 0.5 to about 30% by weight of a fatty compound other than a fatty alcohol and a fatty ester; (e) one or more silicones comprising polysilicone-11; (f) one or more thickening agents; and (g) water; (h) optionally, about 0.5 to about 30% by weight of a polyol; and (i) optionally, about 0.01 to about 10% by weight of a cationic polymer; and wherein one or more alkyl polyglucosides include alkyl glucosides in Ci2_20; one or more fatty alcohols include alcohols in Ci4 22 and further comprise octyldodecanol; and one or more thickening agents include a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer; and wherein all weight percentages are based on the total weight of the hair care composition, (II) optionally, rinsing the hair care compositions from the hair.

8. A process according to claim 9, wherein: - the fatty compound other than a fatty alcohol and a fatty ester includes from 0.1 to 10% by weight of a wax, or a mixture thereof, and - the one or more acrylic thickening agents comprise a hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer such that the weight ratio of the total amount of alkyl glucoside in Ci2 20 and alcohols in Ci4 22 to the total amount of hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer is about 0.1:1 to about 1:0.1.