Stack of electrochemical cells distributed in distinct groups and comprising bipolar plates with short-circuit flow reduction

Abstract

The invention relates to a stack of electrochemical cells arranged in N groups for supplying reactive fluids. Each bipolar plate (1a) comprises N first collectors (4a, 4b) for supplying the same first reactive fluid, at least one internal sealing line (5b), N first sealing lines (10a, 10b), and a homogenization compartment (20). The internal sealing line (5b) is located between the first non-supplying collector (4b) and the associated first sealing line (10b). The first plate (2) extends continuously between the downstream injection tunnels (14a, 14b) and the homogenization compartment (20), remaining spaced from the second plate (3), so that the first reactive fluid flows from the downstream injection tunnels (14a) into the homogenization compartment (20) while being confined between the two plates (2, 3). Figure for the abbreviation: Fig. 2

Description

Title of the invention: Stack of electrochemical cells distributed in distinct groups and comprising bipolar plates with short-circuit flow reduction. Technical field

[0001] The field of the invention is that of electrochemical reactors such as fuel cells and electrolyzers, comprising a stack of electrochemical cells, and relates more particularly to bipolar plates of the conductive sheet type. PREVIOUS STATE OF THE ART

[0002] An electrochemical reactor, such as a fuel cell or an electrolyzer, usually comprises a stack of electrochemical cells, each of which includes two bipolar plates between which are located an anode and a cathode arranged on either side of an electrolyte. The cells are the site of an electrochemical reaction between two reactive fluids introduced continuously.

[0003] Generally, in the case of a fuel cell, the fuel fluid (for example, hydrogen) is supplied to the anode, while the oxidizing fluid (for example, air) is supplied to the cathode. The electrochemical reaction is subdivided into two half-reactions: an oxidation reaction at the anode / electrolyte interface, and a reduction reaction at the cathode / electrolyte interface. For the electrochemical reaction to occur, it requires the presence of an ionic conductor between the two electrodes, namely the electrolyte, and an electronic conductor formed by the external electrical circuit. The stack of cells is thus the site of the electrochemical reaction: the reactive fluids must be supplied to it, the products and non-reactive species must be removed, as well as the heat produced during the reaction.

[0004] Electrochemical cells are usually separated from each other by bipolar plates that provide both electrical interconnection between the cells and the flow of reactive fluids. The bipolar plates have an anodic face with a fuel fluid distribution circuit and an opposite cathodic face with an oxidizing fluid distribution circuit. Each distribution circuit takes the form of a network of channels arranged to deliver the reactive fluid to the corresponding electrode. The bipolar plates may also include a cooling circuit consisting of a network of internal channels that carry a heat transfer fluid to dissipate the heat produced.

[0005] The stacking of electrochemical cells can have an architecture that prevents the accumulation of non-reactive species within the cells. To achieve this, the electrochemical cells can be distributed into several distinct groups of cells that are selectively supplied with the same reactive fluid from dedicated supply manifolds. Document EP3136492A1 describes examples of such an architecture, in the case where the bipolar plates are made of conductive sheets.

[0006] As such, [Fig. 1] is a schematic and partial view, in perspective and exploded view, of an electrochemical cell described in document EP3136492A1. It shows in particular the arrangement of first manifolds A4a, A4b supplying the first reactive fluid, for example here hydrogen, of a homogenization compartment A20, and of the inlet of the first distribution circuit A30.

[0007] The electrochemical cell comprises two bipolar plates Ala, Alb between which a membrane-electrode assembly A40 (MEA) is located. Each bipolar plate Ala, Alb is formed of two sheets made of an electrically conductive material and superimposed one on top of the other. Only sheet A2 is visible in [Fig. 1]. The MEA A40 consists of a first electrode A41 (here the anode), a second electrode A42 (cathode), and an electrolytic membrane A43. An insulating membrane A7 also extends around the first two hydrogen supply collectors A4a, A4b.

[0008] The electrochemical cells are divided here into two distinct groups: "a" and "b". Thus, the anodes of the cells in group "a" are supplied with hydrogen solely from the same first collector A4a, while the anodes of group "b" are supplied with hydrogen solely from the same first collector A4b. The two hydrogen supply collectors A4a and A4b pass through the bipolar plates Ala, Alb. They are adjacent to each other and are located opposite, in the XY plane of the bipolar plate, the inlet of the first distribution circuit A30.

[0009] The first hydrogen supply manifolds A4a and A4b are each continuously surrounded by a seal line AlOa, AlOb, which is formed by a longitudinal rib Alla, Allb over which a sealing gasket extends. Transverse ribs form first and second injection tunnels (the latter are referenced A12a, A12b) which communicate with the longitudinal rib Al1a, Al1b, and are located between the corresponding manifold A4a, A4b and the distribution circuit A30.

[0010] An internal sealing line surrounds the first non-powering collector, i.e. collector A4b in the case of the bipolar plate Ala (internal sealing line A5b), and the collector A4a in the case of the bipolar plate Alb (internal sealing line A5a). This sealing line is formed by a sealed contact line between the two sheets, created for example by welding or brazing. It prevents hydrogen from the supplying collector and present in the inter-sheet space from reaching the non-supplying collector (and vice versa).

[0011] In the case of a bipolar plate A of a cell of group "a" where the anode A41 is supplied with hydrogen by the collector A4a, the downstream injection tunnels A12a of the AlOa seal line are open (open ends): hydrogen can flow from the collector A4a through the AlOa seal line and emerge at the anodic face of the bipolar plate A1a. Conversely, the downstream injection tunnels A12b of the AlOb seal line are closed (closed ends): hydrogen can flow from the collector A4b to the AlOb seal line, but cannot emerge at the anodic face.

[0012] A homogenization compartment A20 is located between the collector joint lines AlOa, AlOb and the distribution circuit A30. It is formed here by a longitudinal rib A21 and transverse ribs also forming upstream injection tunnels A22 and downstream injection tunnels A23. The latter are open, so that the hydrogen exiting the joint line B enters the homogenization compartment and exits on the first face at the inlet of the distribution circuit.

[0013] Finally, an additional sealing line A6 surrounds the first two manifolds A4a, A4b and the homogenization compartment A20, extending in particular between the latter and the distribution circuit A30. This sealing line A6 is also formed by a sealed contact line between the two sheets. It prevents the heat transfer fluid present between the two sheets, at the level of the active zone where the electrodes A41, A42 are located, from also flowing between the sheets into the homogenization compartment A20, into the joint line associated with the supplying manifold, and into the latter.

[0014] Thus, during operation and for the bipolar plate Ala, hydrogen flows in the non-supplying collector A4b but remains blocked by the closed seal line AlOb: it cannot reach the homogenization compartment A20 nor subsequently the distribution circuit A30. On the other hand, hydrogen flows in the collector A4a, passes through the seal line AlOa whose downstream injection tunnels A12a are open, exits at the anodic face, then enters the homogenization compartment A20. It then exits again at the anodic face, and enters the channels of the distribution circuit A30.

[0015] However, it appears that hydrogen can flow on either side of the homogenization compartment A20 in the XY plane and thus at least partially bypass it. Therefore, the hydrogen will not be properly distributed to the input of the A30 distribution circuit, which can result in a degradation of the performance of the electrochemical cell.

[0016] Document EP3136492A1 also describes a variant where the longitudinal rib A21 of the homogenization compartment A20 extends so as to continuously surround the first two collectors A4a, A4b: hydrogen can then not bypass the homogenization compartment A20 and directly enter the distribution circuit A30. However, such a configuration results in less compactness, particularly around the first collectors A4a, A4b, due to the presence of the longitudinal rib A21. Description of the invention

[0017] The invention aims to remedy at least in part the disadvantages of the prior art, and more particularly to propose a stack of electrochemical cells whose configuration of bipolar plates makes it possible to avoid short-circuit flows from the homogenization compartment while preserving a high compactness.

[0018] For this purpose, the object of the invention is a stack of electrochemical cells, where each electrochemical cell comprises a first and a second bipolar plate to supply respectively a first and a second electrode with a first and a second reactive fluid; and where said electrochemical cells are distributed into N distinct groups, with N > 2, the first electrodes of the same group being supplied with the first reactive fluid from the same first supply collector (2a).

[0019] Each bipolar plate is formed of a first plate oriented towards the first electrode and a second plate opposite it, and comprises: • the first N supply manifolds for the first reactive fluid, arranged opposite an inlet of a first distribution circuit of the first reactive fluid to the first electrode, of which a first manifold, called supplying, to provide the first reactive fluid, the other first manifold(s), called non-supplying, not providing the first reactive fluid; • at least one internal sealing line, formed by a sealed contact line between the two sheets, continuously surrounding a first non-supplying manifold; • N initial joint lines, each surrounding a different first manifold, and each comprising: • a longitudinal rib of the first sheet, and a longitudinal joint in contact with the longitudinal rib, which extend continuously around a first collector; • transverse ribs of the first sheet forming upstream and downstream injection tunnels, located on either side and communicating with the corresponding longitudinal rib, and arranged between the first corresponding collector and a homogenization compartment; - in the case of a first supplying manifold, the upstream injection tunnels are open, thus allowing the first reactive fluid to flow from the first supplying manifold to the homogenization compartment; - in the case of a first non-supplying manifold, the upstream injection tunnels are closed, therefore not allowing the first reactive fluid to flow from the first non-supplying manifold to the homogenization compartment; • the homogenization compartment, formed by a gap between the two sheets, having an inlet communicating with the downstream injection tunnels of the first joint lines, and an outlet communicating with the first distribution circuit.

[0020] According to the invention, the internal sealing line is located between the first non-feeding manifold and the first associated seal line. Furthermore, the first sheet metal extends continuously between the downstream injection tunnels and the homogenization compartment, remaining spaced from the second sheet metal, so that the first reactive fluid flows from the downstream injection tunnels into the homogenization compartment while being confined between the two sheets metal.

[0021] Some preferred but not limiting aspects of this stack of electrochemical cells are as follows.

[0022] Each bipolar plate may include an internal sealing line, formed by a sealed contact line between the two sheets, continuously surrounding the first supplying collector.

[0023] Each electrochemical cell may include an electrically insulating membrane, extending between the first joint lines and the first collectors of each bipolar plate, which includes supports arranged on the edge of the first collectors and keeping the insulating membrane away from the first sheet, thus avoiding any fluidic obstruction of the opening of the upstream injection tunnels by the insulating membrane.

[0024] The homogenizing compartment may include local recesses where the two sheets come into contact with each other, located between an inlet and an outlet of the homogenizing compartment, thus preventing the sheets from sagging towards each other.

[0025] The homogenizing compartment may include outlet recesses defining outlet tunnels, where the two sheets come into contact with each other, located at the outlet of the homogenizing compartment.

[0026] Each bipolar plate may include a peripheral internal sealing line, formed by a sealed contact line between the two sheets, continuously surrounding the first collectors, the collector joint lines and the homogenization compartment.

[0027] The homogenization compartment can extend from the downstream injection tunnels of the manifold joint lines to the peripheral internal sealing line.

[0028] An inlet of the homogenization compartment can extend continuously with respect to the downstream injection tunnels associated with the first supplying manifold and continuously with respect to the downstream injection tunnels associated with the first non-supplying manifold.

[0029] An outlet of the homogenization compartment can extend in a straight line with respect to the distribution circuit.

[0030] The bipolar plates can be identical to each other, and differ from each other only by the opening of the upstream injection tunnels.

[0031] The invention also relates to an electrochemical reactor, comprising a stack of electrochemical cells according to any one of the preceding characteristics, the reactor being a fuel cell or an electrolyzer. Brief description of the drawings

[0032] Other aspects, objects, advantages and features of the invention will become more apparent upon reading the following detailed description of preferred embodiments thereof, given by way of non-limiting example, and made with reference to the accompanying drawings in which:

[0033] Fig. 1, already described, is a schematic and partial view, in perspective and exploded view, of electrochemical cells according to an example of the prior art;

[0034] [Fig.2] is a schematic and partial top view of a bipolar plate of an electrochemical cell of the stack of electrochemical cells according to an embodiment;

[0035] [Fig.3] is a view which shows in more detail a part of the bipolar plate of [Fig.2];

[0036] [Fig.4] is a perspective view which also shows in more detail a part of the bipolar plate of [Fig.2].

[0037] DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS

[0038] In the figures and in the rest of the description, the same reference numerals represent identical or similar elements. Furthermore, the different elements are not The figures are shown to scale to ensure clarity. Furthermore, the various embodiments and variants are not mutually exclusive and may be combined. Unless otherwise specified, the terms "approximately," "around," and "in the order of" mean within 10%, and preferably within 5%. Moreover, the terms "between ... and ..." and equivalents mean that the limits are inclusive, unless otherwise stated.

[0039] The invention relates to a stack of electrochemical cells for electrochemical reactors such as fuel cells and electrolyzers. The electrochemical cells are arranged in separate groups for supplying reactive fluids. Furthermore, the bipolar plates are each formed of two conductive sheets.

[0040] The invention relates more specifically to bipolar plates comprising: several first manifolds for supplying the same first reactive fluid, which are surrounded by manifold seal lines; a homogenization compartment; and a distribution circuit for the first reactive fluid. The architecture of the bipolar plates, and in particular the fluidic junction between the manifold seal lines and the homogenization compartment, makes it possible to avoid short-circuit flows from the homogenization compartment, without leading to a degradation of the compactness of the bipolar plate.

[0041] Various embodiments and variants will be described with reference to a PEM (Proton Exchange Membrane) type fuel cell in which the anode is supplied with hydrogen and the cathode with oxygen. However, the invention applies to any type of fuel cell, whether it operates at low temperature (below 200°C) or at high temperature, such as solid oxide fuel cells (SOFCs), as well as to electrochemical electrolyzers.

[0042] Figure 2 is a schematic, partial top view of a bipolar plate of a cell belonging to a stack of electrochemical cells according to one embodiment. Two first manifolds 4a, 4b for supplying a first reactive fluid, internal sealing lines 5a, 5b, manifold joint lines 10a, 10b, and a homogenization compartment 20 are shown in detail. The distribution circuit for the first reactive fluid is not shown. The electrochemical cells are considered here to be those of a PEM-type fuel cell supplied with hydrogen and oxygen.

[0043] Here and for the remainder of the description, a three-dimensional orthogonal XYZ direct frame is defined, where the X and Y axes form a plane parallel to the principal plane of the bipolar plate la, and where the X axis extends from the collectors 4a, 4b towards the distribution circuit, the Y axis along the width of the bipolar plate la and the Z axis along its thickness. Furthermore, the terms "lower" and "upper" are understood to be relative to an increasing positioning along the +Z direction.

[0044] Electrochemical cells belong to a stack of fuel cell cells. Each electrochemical cell comprises a membrane / electrode assembly (MEA) (not shown) consisting of a first electrode (anode) intended to be supplied with the first reactive fluid (hydrogen) and a second electrode (cathode) intended to be supplied with the second reactive fluid (oxygen), separated from each other by an electrolytic membrane. The MEAs are arranged between bipolar plates, which are adapted to supply the reactive fluids to the electrodes and to remove the heat produced, as well as the non-reactive species and the products of the electrochemical reactions.

[0045] Furthermore, the electrochemical cells are distributed into N distinct groups, with N>2, where the first electrodes of the cells in the same group are supplied with the same first reactive fluid from the same first supply manifold.

[0046] Here, "a" and "b" denote the two groups of electrochemical cells (N=2). In the cells of group "a", the first electrodes, here the anodes, are supplied with hydrogen solely by the same collector 4a, which is then called the supply collector; collector 4b is then called the non-supply collector. Conversely, in the cells of group "b", the anodes are supplied with hydrogen solely by the same collector 4b (supply collector); collector 4a is then the non-supply collector.

[0047] The bipolar plates are each formed of two sheets 2, 3 made of an electrically conductive material, superimposed one on top of the other. These sheets 2, 3 are locally deformed to form ribs and indentations, which then define the ribs of the joint lines 10a, 10b, the homogenization compartment 20 and the channels of the distribution circuit.

[0048] The bipolar plate has an anodic outer face oriented towards the anode (the face shown in [Fig. 2]), and an opposite cathodic outer face oriented towards the cathode. The anodic outer face corresponds to the outer face of the anodic plate 2 (upper plate), and the cathodic outer face is the outer face of the cathodic plate 3 (lower plate). The anodic distribution circuit is formed at the anodic outer face. Between the two plates 2 and 3, and more precisely in the active zone where the anodic and cathodic distribution circuits are located, there is a cooling circuit in which a heat transfer fluid circulates.

[0049] The sheets 2, 3 are in the form of thin sheets or plates. The electrically conductive material can be a metal or a composite material, for example, one filled with graphite. The thickness can be on the order of a few tens to a few hundred microns, for example, from approximately 50 µm to 200 µm in the case of metal sheets.

[0050] At least the sheet metal 2 has ribs and indentations, obtained for example by deep drawing, stamping or any other forming technique, the shape of which on one face is the complement of the shape on the opposite face. The ribs notably allow for defining the distribution circuit of the reactive fluid on the outer face of the sheet metal, as well as the cooling circuit of the heat transfer fluid on the inner face.

[0051] Each bipolar plate comprises at a minimum: - N first collectors 4a, 4b, for supplying the first electrodes (anodes) with the same first reactive fluid (hydrogen), of which a first collector is called supplying (here collector 4a), the other first collectors being called non-supplying (here collector 4b); - at least one first internal sealing line 5b, which surrounds the first non-supplying manifold 4b; - N first lines of manifold joint 10a, 10b, each surrounding a different first manifold 4a, 4b; - a homogenization compartment 20 of the first reactive fluid; - a distribution circuit (not shown) of the first reactive fluid (hydrogen) at the level of the first electrode (anode).

[0052] The first collectors 4a, 4b are openings that pass through each of the bipolar plates. The reactive fluid collectors are located on either side of the active zone (reaction zone) along the principal flow axis of the reactive fluids, here along the X-axis. The heat transfer fluid collector (not shown) can also be located on either side of the reaction zone along the X-axis, or alternatively, can be located on either side of this zone along the Y-axis.

[0053] As stated above, the bipolar plates each have N first collectors 4a, 4b for supplying the same first reactive fluid, with N>2. In this example, there are 2 first collectors 4a, 4b for supplying hydrogen. The collectors 4a, 4b are adjacent to each other and are located opposite each other, in the XY plane, in the same homogenization compartment 20. In the example in [Fig. 2], the bipolar plate 1 belongs to a cell of group 'a', so collector 4a is said to be 'supplying' hydrogen while collector 4b is said to be 'non-supplying'.

[0054] Each bipolar plate has at least one first internal sealing line. This corresponds to a watertight contact line between the two plates on their inner face. The watertight contact can be achieved by welding or brazing, among other methods.

[0055] At a minimum, the bipolar plate includes an internal sealing line 5b which surrounds the first non-feeding collector 4b. This prevents hydrogen circulating in a first collector from reaching the other first collector(s). collectors. More precisely, the hydrogen which flows from the collector supplying 4a to the distribution circuit, passing in particular between the two sheets 2, 3, cannot reach the non-supplying collector 4b (and vice versa).

[0056] Preferably, the bipolar plate has N internal sealing lines 5a, 5b, each surrounding a first different collector 4a, 4b. Here, an internal sealing line 5a surrounds the collector supplying 4a, and the internal sealing line 5b surrounds the non-supplying collector 4b.

[0057] The internal sealing lines 5a, 5b extend here in a substantially straight line between the supports 8 and the upstream injection tunnels 13a, 13b. Alternatively, they can meander between the supports 8 and the upstream injection tunnels 13a, 13b, so as to increase the intercalated surface area and gain in compactness.

[0058] A flexible membrane (see [Fig. 1]), made of an electrically insulating material, may be present between two adjacent bipolar plates to prevent any electrical contact between them. It can therefore extend around the first collectors 4a, 4b.

[0059] To prevent it from pressing against the upper plate 2, between the first manifold supplying 4a and the upstream injection tunnels 13a, which would then obstruct the flow of hydrogen, supports 8 are provided to keep the flexible membrane away from the upper plate 2. In this example, these supports 8 are located at the edges of the first manifolds 4a, 4b. They are truncated studs. Alternatively, they may be one or more ribs (elongated studs).

[0060] The bipolar plates each have N first collector joint lines, each continuously surrounding a different first collector. Here, the collector supplying 4a is surrounded by joint line 10a, and the non-supplying collector 4b is surrounded by joint line 10b.

[0061] Each joint line 10a, 10b is formed by a longitudinal rib 1la, 11b of the anodic plate 2 and a longitudinal joint 12a, 12b which rests on and is in contact with the longitudinal rib 1la, 11b. Both extend continuously around the corresponding manifold. Each joint line 10a, 10b also includes transverse ribs that form upstream injection tunnels 13a, 13b and downstream injection tunnels 14a, 14b. These injection tunnels are located on either side of the longitudinal rib 1la, 11b and communicate with it. They are arranged between the corresponding manifold 4a, 4b and the homogenization compartment 20.

[0062] The injection tunnels 13a, 13b, 14a, 14b are formed here by transverse ribs where the two sheets are spaced apart, and are laterally delimited by recesses where the sheets are in contact with each other. These injection tunnels ensure the fluidic transmission of the first reactive fluid on either side of the parting line (when they are associated with a first manifold). supplying), as well as the mechanical support of the longitudinal rib to prevent any sagging of the latter.

[0063] In this example, the transverse ribs are to be understood in a broad sense: here they have an elongated shape in the XY plane, which improves the fluid orientation, but this is not essential. Thus, these ribs could be straight, and could then have a stud-like shape. The fluidic connection and mechanical support functions remain intact.

[0064] The upstream injection tunnels 13a associated with the supply manifold 4a are open, meaning that their end facing the manifold 4a is open. Hydrogen can then flow from the supply manifold 4a and enter the upstream injection tunnels 13a, then the longitudinal rib 1a, and subsequently the downstream injection tunnels 14a. Conversely, the upstream injection tunnels 13b associated with the non-supply manifold 4b are closed, meaning that their end facing the manifold 4b is closed. The hydrogen flowing into the non-supply manifold 4b cannot enter the upstream injection tunnels 13b.

[0065] The local opening of the upstream injection tunnels 13a is achieved by a localized cut in the upper (anodic) plate 2, while the lower (cathodic) plate 3 remains uncut. Alternatively, both plates 2 and 3 may be cut, or even only the lower plate 3 may be cut.

[0066] Each bipolar plate includes a homogenization compartment 20, located between the downstream injection tunnels 14a, 14b of the manifold joint lines 10a, 10b on one side, and the inlet of the distribution circuit on the other. The homogenization compartment 20 is a region in the XY plane where the two plates 2, 3 are spaced apart. It extends from the downstream injection tunnels 14a, 14b to the distribution circuit and has significant dimensions that optimize the homogenization of the hydrogen flow. These same downstream injection tunnels 14a, 14b thus fluidly connect the longitudinal rib 11a, 11b and the homogenization compartment 20.

[0067] The homogenization compartment 20 has a continuous inlet (spacing between the two plates 2, 3) opposite the downstream injection tunnels 14a, 14b. This inlet extends continuously (and here in a straight line) opposite the downstream injection tunnels 14a, and also extends continuously (and here in a straight line) opposite the downstream injection tunnels 14b. Furthermore, the homogenization compartment 20 has an outlet that extends in a straight line opposite the distribution circuit.

[0068] The homogenization compartment 20 here includes local recesses 21 where the two plates 2, 3 come into contact with each other. These recesses provide mechanical support for the two plates, thus reducing the risk of one sagging towards the other. the other. These local recesses 21 are distributed in a substantially regular manner in the XY plane between the inlet and outlet of compartment 20. These local recesses 21 have substantially circular dimensions in the XY plane, but may have an oblong shape, allowing in particular to direct the flow of hydrogen towards the outlet.

[0069] The homogenization compartment 20 may include downstream tunnels 22, located at its outlet. These tunnels improve the direction of the hydrogen flow towards the distribution circuit, while preventing the plates from sagging towards each other. They are laterally delimited by oblong recesses where the plates 2, 3 come into contact with each other.

[0070] The outlet of the homogenization compartment 20 is located opposite the distribution circuit and its channels. This outlet is formed by one or more openings in the upper plate 2 at the level of the downstream tunnels 22 of the homogenization compartment 20. These openings may be formed by a localized cut in the upper plate 2. The hydrogen then exits the homogenization compartment 20 and comes into contact with the anodic outer face of the bipolar plate la. It can then flow into the distribution circuit.

[0071] The bipolar plates may each include an internal sealing line 6, which continuously surrounds the two manifolds 4a, 4b (and the joint lines 10a, 10b) as well as the homogenization compartment 20. It is formed by a watertight contact line between the two sheets 2, 3, created, for example, by welding or brazing. In particular, it passes between the outlet of the homogenization compartment 20 and the inlet of the distribution circuit.

[0072] According to the invention, between the downstream injection tunnels 14a, 14b and the homogenization compartment 20, the upper (anodic) sheet 2 extends continuously while being spaced from the lower sheet 2, so that the hydrogen circulating in the injection tunnels 14a reaches the homogenization compartment 20 while remaining between the two sheets 2, 3, and therefore without leaving the space between the two sheets 2, 3 to come onto the anodic external face.

[0073] In other words, the upper plate 2 remains continuously separated from the lower plate 3 between the longitudinal ribs 1a, 11b and the homogenization compartment 20, by means of the downstream injection tunnels 14a, 14b. The longitudinal ribs 1a, 11b are thus fluidly connected to the homogenization compartment 20 by the downstream injection tunnels 14a, 14b. Therefore, there is no gap between the longitudinal ribs 1a, 11b and the homogenization compartment 20 where the upper plate 2 would be open, allowing hydrogen to escape from the gap between the two plates 2, 3 and come into contact with the anodic outer face. The hydrogen thus passes from the downstream injection tunnels 14a to the homogenization compartment 20 while remaining confined. In the case of a bipolar plate 1b (i.e., where the first supplying collector is the collector 4b), the hydrogen would therefore pass from the downstream injection tunnels 14b to the homogenization compartment 20 while also remaining confined.

[0074] This arrangement is made possible by the fact that the internal sealing lines 5a, 5b are located between the manifolds 4a, 4b and the manifold joint lines 10a, 10b. Thus, as the hydrogen passes directly from the longitudinal rib lia to the homogenization compartment 20 (via the downstream injection tunnels 14a) without exiting the space between the two sheets 2, 3, it cannot short-circuit the homogenization compartment 20 as in the prior art example illustrated in [Fig. 1].

[0075] It is therefore not necessary for the homogenization compartment 20 to continuously surround the first collectors 4a, 4b by being associated with a longitudinal joint, as in the variant of document EP3136492A1 mentioned above, which makes it possible to preserve the compactness of the bipolar plate.

[0076] The homogenization compartment 20 can therefore extend freely in the XY plane and thus present a widening in the XY plane compared to that of [Fig.1], which ensures better homogenization of hydrogen at the inlet of the distribution circuit.

[0077] Note that the bipolar plates can have an identical configuration, in particular when each collector 4a, 4b is surrounded by an internal sealing line 5a, 5b as in the case of [Fig.2], and differ from each other only by the location of the opening of the upstream injection tunnels 13a or 13b.

[0078] Specific embodiments have just been described. Various variants and modifications will be apparent to those skilled in the art.

[0079] In this respect, the contact plane between the two sheets 2, 3, where the internal sealing lines 5a, 5b are formed, is offset here to the plane of the longitudinal rib of the lower parting line (lower cathodic sheet). Thus, most of the ribs are formed here by deformation of the upper sheet 2 only. However, the contact plane could just as easily be a median plane, resulting in the formation of ribs in each of the two sheets.

Claims

1. Demands Stack of electrochemical cells, • each electrochemical cell comprising a first and a second bipolar plates to supply respectively a first and a second electrode with a first and a second reactive fluids; • said electrochemical cells being distributed into N distinct groups, with N > 2, the first electrodes of the same group being supplied with the first reactive fluid from the same first supply manifold (2a); • each bipolar plate (la), formed of a first plate (2) oriented towards the first electrode and a second plate (3) opposite, comprising: • the first N manifolds (4a, 4b) supplying the first reactive fluid, arranged opposite an inlet of a first distribution circuit of the first reactive fluid to the first electrode, of which a first manifold (4a), called supplying, to provide the first reactive fluid, the other first manifold(s) (4b), called non-supplying, not providing the first reactive fluid; • at least one internal sealing line (5b), formed by a sealed contact line between the two sheets (2, 3), continuously surrounding a first non-supplying collector (4b); • N initial joint lines (10a, 10b), each surrounding a different first manifold (4a, 4b), and each comprising: • a longitudinal rib (lia, 11b) of the first sheet (2), and a longitudinal joint (12a, 12b) in contact with the longitudinal rib, which extend continuously around a first collector (4a, 4b); • transverse ribs of the first sheet (2) forming injection tunnels upstream (13a, 13b) and downstream (14a, 14b), located on either side and communicating with the corresponding longitudinal rib (lia, 11b), and arranged between the corresponding first collector (4a, 4b) and a homogenization compartment (20); - in the case of a first manifold supplying (4a), the upstream injection tunnels (13a) are open, thus allowing the first reactive fluid to flow from the first manifold supplying (4a) to the homogenization compartment (20); - in the case of a first non-supplying manifold (4b), the upstream injection tunnels (13b) are closed, therefore not allowing the first reactive fluid to flow from the first non-supplying manifold (4b) to the homogenization compartment (20); • the homogenization compartment (20), formed by a spacing between the two sheets (2, 3), having an inlet communicating with the downstream injection tunnels (14a, 14b) of the first joint lines (10a, 10b), and an outlet communicating with the first distribution circuit; characterized in that: • the internal sealing line (5b) is located between the first non-supplying manifold (4b) and the first associated seal line (10b); • the first sheet (2) extends continuously between the downstream injection tunnels (14a, 14b) and the homogenization compartment (20) while remaining spaced from the second plate (3), so that the first reactive fluid flows from the downstream injection tunnels (14a) into the homogenization compartment (20) while being confined between the two plates (2, 3).

2. Stack of electrochemical cells according to claim 1, wherein each bipolar plate (la) has an internal sealing line (5a), formed by a sealed contact line between the two sheets (2, 3), continuously surrounding the first supplying collector (4a).

3. Stack of electrochemical cells according to claim 1 or 2, wherein each electrochemical cell comprises an electrically insulating membrane, extending between the first joint lines (10a, 10b) and the first collectors (4a, 4b) of each bipolar plate (la), which comprises supports (8) arranged on the edge of the first collectors (4a, 4b) and keeping the insulating membrane away from the first sheet (2), thus avoiding any fluidic obstruction of the opening of the upstream injection tunnels (13a) by the insulating membrane.

4. Stack of electrochemical cells according to any one of claims 1 to 3, wherein the homogenization compartment (20) has local recesses (21) where the two sheets (2, 3) come into contact with each other, located between an inlet and an outlet of the homogenization compartment, thus preventing the sheets from sagging towards each other.

5. Stack of electrochemical cells according to any one of claims 1 to 4, wherein the homogenization compartment (20) has outlet recesses (22) defining outlet tunnels, where the two sheets (2, 3) come into contact with each other, located at the outlet of the homogenization compartment.

6. Stack of electrochemical cells according to any one of claims 1 to 5, wherein each bipolar plate has a peripheral internal sealing line (6), formed by a sealed contact line between the two sheets (2, 3), continuously surrounding the first collectors (4a, 4b), the collector joint lines (10a, 10b) and the homogenization compartment (20).

7. Electrochemical cell stack according to claim 6, wherein the homogenization compartment (20) extends from the downstream injection tunnels (14a, 14b) of the manifold seal lines (10a, 10b) to the peripheral internal sealing line (6).

8. Stack of electrochemical cells according to any one of the preceding claims, wherein an inlet of the homogenizing compartment (20) extends continuously with respect to the downstream injection tunnels (14a) associated with the first feeding collector (4a) and continuously with respect to the downstream injection tunnels (14b) associated with the first non-feeding collector (4b).

9. Stack of electrochemical cells according to any one of the preceding claims, wherein an outlet of the homogenization compartment (20) extends in a straight line with respect to the distribution circuit.

10. Stack of electrochemical cells according to any one of the preceding claims, wherein the bipolar plates are identical to each other, and differ from each other only by the opening of the upstream injection tunnels (13a, 13b).

11. Electrochemical reactor, comprising a stack of electrochemical cells according to any one of the preceding claims, the reactor being a fuel cell or an electrolyzer.

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