Remote corrosion-monitoring system

Abstract

The present invention relates to a remote corrosion-monitoring system for end-to-end application in the inspection of metal structures located in high humidity zones that is intended to protect steel

Description

REMOTE CORROSION~MONITORING SYSTEM Field of the Invention

[0001] The invention addresses to a Corrosion Remote Monitoring System (CEMS) with application in the field of inspection technologies, materials, equipment and corrosion in production units aiming at optimizing the maintenance and inspection practices of pipelines located in the tidal variation zone (TVZ) and, consequently, significant savings of financial resources. Description of the State of the Art

[0002] Currently, the maintenance and inspection technique used dates back to the 70s, when there were a small number of pipelines to be evaluated. The productivity of the used technique ls low, the functicnal risk of the workforce is high, such as scaffolding and climbing, and the operating cost is high. Furthermore, interventions can only be carried out. in & short period of the year when weather conditions are favorable.

[0003] The inspection mainly aims at identifying areas where the loss of thickness of the pipeline wall is significant, due to the external corrosion, jeopardizing the production process.

[0004] The inspection method consists of {1} removing the anti-corrosion external coating, (2) preparing the surface of the pipeline in the almost white metal pattern, (3) mapping and measuring the remaining thickness, with ultrasound, of the wall of the corroded area and, finally, (4) perform the repair with an anti-corrosion composite material, to ensure the operational continuity of the piping. The access to the workplace (TVZ) is via fixed scaffolding or with climbers, the operator suspended from ropes, subisct te bad weather, strong winds and rough seas, factors that impade good productivity in operations. The risk of accidents is high. There are reccrds of fatal accidents with fixed scaffolding.

[0005] The tools used are mechanical and hydraulic equipment that require good stability from cpsrators to perform the work, a fact difficult te achieve with the climbing technique. The productivity is low. [000€] This work evaluates the integrity of the pipeline, following the Technical Inspection Recommendations (IIR) for the correction of detected nonconformities. Depending on the characteristics of the damage, a specific repair is recommended - split clamp, double welded rails, mechanical connector, structural reinforcement with composite material and anti-corrosion protection. In the case of a repair carried out with a composite material, the expiraticn date of the repair is randomly defined. After the expiration date, a new inspection is requested to guarantee the integrity of the pipeline. This fact jeopardizes the carrying out of the annual inspection schedule, as it prioritizes the service of revalidation of repairs. {00071 This inspection procadure is the same &s in the 70s, when there were few pipelines to be inspected. This ingpection paradigm is mainly responsible for the failure to fully comply with the inspection program advocated today. fooog] Nowadays, the inspection program includes 9% pipelines distributed across the Campos, Espirito Santo and Santos basins. With the available resources, the defined goal is not met, always remaining a repressed demand, which poses a risk to the integrity of the piping.

[0009] This situation leaves companies vulneérable to sanctions by the Brazilian Navy, IBAMA - Brazilian Institute fer the Environment and Renewable Natural Rescurces and the ANP (Naticnal Agency for Petroleum, Natural Gas and Biofuels), the latter, for not having complied with the explicit recommendations of ths Operational Safety System of the Subsea System (SGSS). No less worrying are the records shown in the GIDES - Subsea Pipeline and Equipment Integrity Management-, which indicate 951 registered risers, in the three basins, by June 2017. The trend for this number is to increase with the installation of new units.

[0010] Within this scenario, the need arises to find some other inspection technique capable of meeting the fellowing premises: (1) minimizing the operational risks of the workforce, (2) avoiding repetitive inspections for revalidation of «repairs, and, finally, (3) having low operating costs. The corrosive process, if neglected, is a constant threat to the integrity of installations, occupational health and preservation of the environment, due to the risk of undesirable leaks. [0011} Document WOOQ0509%07 discloses a sensor device to record voltage drops in structures exposed to corrosion, such as pipes and supports, in offshore environments. The sensors are coupled to a surface area, to which voltage is supplied via electrodes, causing an excitation current in the area. The cables are connected to sald sensors, arranged in a matrix that defines measurement points with defined distances, to transmit material thickness and / or structural defects (erasion, corrosion and others) in the measurement area. Such a sensing device comprises a flexible sheet of a non-conducting electrical material in which conductive paths are incorporated, leading to several distributed and exposed measuring points, encompassing a hinged chain te which individual contact joints are connected by means of connection pins, each contact joint holding at least one, preferably two contact pins, under stress by a& coil spring. However, said sensor device does not focus on optimizing maintenance and inspection practices of pipelines in the TVZ (tidal variation zone) based on the operation of the electrochemical cell or Daniell cell. foo1z2] Patent CN101430271 discloses a device for monitoring metal corrosion, in particular a device for monitoring metal corrosion under an organic coating and a method for monitoring the same. The device comprises an electrolytic cell cover, a barrel made of the same material as the metallic material to be monitored, a nickel bar and a socket connector. However, the system does not have components such as a conductor cable connected to the galvanic cell and LED, nor does it have a specimen configured with all the parameters of the galvanic cell. {0013} Document US85306414 discloses a set of corrosion sensors that incorporate individual elements to measure various =lements and ions, and elements to evaluate the flash corrosion properties of structural materials. The exact combination and number of elements measured or monitored would depend on the envircnmental conditicns and materials used which are subject to corrosive effects. Such a corrosion monitoring system incorporated or mounted in a structure exposed to the environment would serve as an early warning system for the appearance of serious corrosion problems in the structure, providing both a safety factor and economic factors. The set of sensors is accessed by an elsctronic / computer system, which provides a ms=ans of data collection and analysis. However, this system does not claim a specimen configured with all the parameters of the galvanic cell, nor does it mention components such as a conductor cable connected to the galvanic cell and LED. {0014] No document of the state of the art discloses a system for detecting external corrosion in steel pipings such as that of the present invention.

[0015] Thus, the present invention was developed with a disruptive technology that allows monitoring, in real time, on the platform deck, the corrosive process acting in specific areas of the piping, the main focus of inspection programs.

[0016] The invention mainly aims at reducing the number of pipelines to be inspected, addressing only to the pipelines with indication of corrosion detected by the Corrosion Detection System (CDS). {0017] The present invention fills an important gap in the field of inspection and maintenance of pipelines located in the TVZ, due to the following advantages: 1- Any quantity of pipelines can be simultaneously menitored; Z2= It significantly reduces the number of pipelines to bs inspected, where only pipelines with signs of corrosion, evidenced by the CDS, will be inspected; 3- It reduces the number of teams mobilized for inspection; 4- It reduces the cost of logistical support due to the smaller number of transfers of teams and materials; 5- It reduces consumption of material used in maintenance; 6-~ It reduces the number of interventions to meet Inspection Treatment Recommendations (ITRs); 7- It provides better conditions for planning intervention schedules; 8- It eliminates inspection rework on expired expiration dates; J It minimizes climbers’! risks due to the reduction in the number of interventions; 10~ It eliminates the risk of oil leakage at sea due to the prior indication of the weakened section of the pPlLping. Brief Description of the Invention {o018] The present invention addresses to a Corrosion Remote Monitoring System (CRMS) with application in the field of inspection technologies, materials, equipment and corrosion aiming at optimizing the maintenance and inspection practices of pipelines located in the tidal variation zone (TVZ).

[0018] The present invention was conceived for the integral application in the inspection of metallic structures, located in environments with high humidity index (TVZ), aiming at protecting the pipings from the action of external corrosion in the oil and gas industry sagment, as it is of great importance for the preservation of the structural integrity of the installations, operational safety and preservation of the environment, in the latter aspect, for preventing oil spills at sea. The installation of the Corrosion Detection System (CDS) in any Production Unit (PU) does not require any type of adaptation and additional space, and can be implemented in offshore units. Brief Description of the Drawings {0020} The present invention will be described in more detail below, with reference to the attached figures which, in a schematic way and not limiting the inventive scope, represent examples of its embodiment. In the drawings, there are: Figure 1 illustrating a schematic of a Daniell electrochemical cell; Figure 2 illustrating a specimen (CP) prepared with almost white metal completely involved by the moisture inhibitor product, for testing the sealing barrier; Figure 3 illustrating the assembly of a galvanic cell, in which the CP shown includes all the constituents of the cell; Figure 4 illustrating a protoboard with the system components, energized with 127 V, consisting of a conductor cable (white) connected to a galvanic cell (sensor) and the LED on, indicating the detection of a voltage of 0.75% V; Figure 5 illustrating a CFP with all the system components and lmmersed in a container containing salt water, for 72 hours, simulating the TVZ environment; Figure 6 illustrating the induction of sodium chloride saline solution in the corrosion detection system {CDS ; Figures 7 illustrating the electronic panel turned off to receive the signal from a set of five sensors; Figure 8 illustrating the electronic panel powered up {LED on): Figure 9 illustrating the electronic panel energized {LED on) indicating the beginning of corrosion in one of the sensors; Figure 10 shows in details the applied invention, where {1) insulating =lement, (2) sensors, (3) anti-corrosion protection, (5) permo-porous element, (6) composites material, (7) electrical signai conductor cable and (8) sensor panei; Figure 11 shows in detail the applied invention, wheres (1) insulating element, (2) sensors, (3) anti-corrosion protection, (4) sensor collar, (5) permo~porous element, (&) composite material, (7) electrical signal conductor cable and (8) sensor panel; Figure 12 shows the layer of composite material (6) that is applied; Figure 12 1llustrates the wiring diagram of the sensors (4) with the =slectronic panel (8). Detailed Dascription of the Invention

[0021] The present invention addresses to a system to monitor the corrosive process acting in the pipelines located in the tidal variation zone (TVZ}), wherein with this system is possible to monitor, on the deck of the Production Unit (PU}, the action of corrosion at any point of the risers, J-Tubes and I-Tubes installed in the PUs. {og22} The Corrosion Detection System {CDs} according to the present invention and illustrated in Figure 10 comprises an electrical source (10), an electronic panel (8) with five electrical senscrs (9) with LED connected to the cable conductor (7) reinforced with aramid wire, which captures the electrical signal generated by external corrosion through the electrodes {sensors - 2) positioned on the insulating element (1) and covered by the permo-porous material (5;, and this whole set, which is installed on the surface of the pipeline completely surrounded by the sealing barrier (3) and, finally, the entire set covered with composite material (6).

[0023] The corrosion can be monitored, in real time, on the deck of the platform, eliminating the need to mobilize a team of climbers and scaffolding to evaluate the corrosive process, which significantly reduces the number of inspection teams to evaluate corrosion in equipment such as risers.

[0024] Furthermore, the present invention simplifies planning by prioritizing the pipings (30) that must be inspected based on the information collected, in real time, through the installed sensors.

[0025] The cleaning of the piping for thickness measurement will be minimized, and should only occur if there 1s a need to replace the composite material. [ooz8]} Regarding the structural strength with the composite material, the displacement of the fiberglass fabric or other material will be easily detected by the sensors, thus avoiding the use of empirical methods for this, such as hammer blows in the repalr.

[0027] The expiration date of the structural reinforcement {(anticorrosive protection) is formulated with technical criteria guaranteeing the life of the pipe, in which the date is controlled in real time by the installed sensing system. EYAMPLES = {oo28] For this study, the following tests were performed, which represent examples of the steps of grounding of the present invention. EXAMPLE 1: Analysis of the corrosive process acting on the —_

[0028] This study was addressed to understand the mechanism of the external corresive process, acting in the pipelines located in the TVZ. Multidisciplinary studies were carried out, addressing to the mechanisms of corrosion of different origins. Metallurgical, electrochemical, physical- chemical and thermodynamic processes were studied in detail in order to define which process best characterizes the corrcsion mechanisms in the TV? environment.

[0030] The result of this research concluded that the electrochemical model or Daniell cell (1836) is the one that best represents this corrosion environment, as illustrated in Figure 1. It further supports the concept of corrosion - destruction or deterioration of a material due to chemical or electrochemical action with the medium.

[0031] The Daniell cell shows that it is possible to detect corrosion by icon exchange between the cathode and anode in an aquecus environment (electrolyte), with low voltage electric current generation: 0.75 V. This model was simulated in a specimen (CP) (20), configured with all the parameters of the galvanic cell, so that it was possible to capture the electrical signal generated by the corrosion. EXAMPLE 2: - Engineering of the corresion detection system in the TV2 environment

[0032] Having def ined the model of the electrochemical process of corrosicn, the next step was to engineer a specimen (CP) (20) to simulate the Daniell galvanic ceil. {0033} Thus, a CP was built with the same material used in the TVZ pipelines (API-5LX-60), and in analogy to the galvanic cell some assumptions were considered, namely, {1} the presence of corrosion is evidenced when the electrical circuit closes between the two electrodes, induced by the electrolyte (sea air); (2) thus, low voltage (0.75 V}) is generated, which must be captured through an electronic-electrical device positioned on the surface; (3) the two electrodes must be isolated from the pipeline wall, so as not to have the circuit closed without the presence of the electrolyte; (4) the electrodes must be protected against the action of the sea air (electrolyte); (3) the protection material for the corroded area and for the electronic- electrical set must be inert, impermeable to water, oxygen and bacterial action and withstand temperatures of up to 90 °C; (6) the beginning of corrosion, caused by the invasion of electrolyte due to failure in the pipeline protection system, will be immediately indicated through light signals displayed on electronic panels, positioned on the PU deck. EXAMPLE 3: Simulation of premises

[0034] Initially, a simulation was performed to evaluate the effectiveness of the product used as a sealing barrier between the pipeline and the environment. [GO35] Figure ¢ shows the CP prepared to the almost- white metal that was completely involved by the moisture inhibitor product. This environmentally friendly material is widely used in the Netherlands to waterproof canals, which is availiable on the marker.

[0036] Simulating the electrolyte, a porous and permeable slement (white material) containing crystallized sugar was placed. The expectation would be, in case of inhibitor failure, that the water where the CP was submerged would percolate the inhibitor and dissolve the sugar. That sald, the whole set was immersed in water for 72 hours. After this period, the CP was removed from the water to evaluate the conditions of the porous element containing sugar.

[0037] As can be seen in Figure 2, the porous element showed no evidence of moisture and the sugar was perfectly friable. It is concluded that the wmeisture inhibitor is effective, thus meeting premise (5) as mentioned above. EXAMPLE 4: Galvanic cell [oc3s} In this step, the galvanic cell was assembled, as shown in Figure 3, which shows the CP with all the constituent elements of the cell.

[0039] The top of the CP comprises an electrical source, conductors with LED, and electronic components.

[0040] The body of the CF comprises a sealing barrier material, a permo-perous element, an insulating material and electrodes.

[0041] The sealing barrier, made of viscoelastic material, easily molded, is fragile, the reason why it must be protected from mechanical shocks - dark material, on the right, at the base of the CP.

[0042] The permo-porous element 1s fundamental in the composition of the system for providing the capture of a minimum amount of electrolyte to close the electrical circuit, indicative of corrosion. It further prevents the accumulation cof electrolyte around the electrodes, dus to surface tension, giving rise to the formation of an agueous body in the form cof a lemniscate, generating punctual corresion and without actuating the electrical circuit. EXAMPLE 5: Electronic system design

[0043] At this step, an electronic system was designed to capture the voltage of 0.75 V, product of the corresive reaction and powered by a source of 125 V and / or 220 V. The system was simulated on a protoboard, as shown in Figure 5.

[0044] As can be seen in Figure 4, which shows all the components of the system, energized with a source of 127 V, conductor cable (white) connected to the galvanic cell {sensox) and the LED on, indicating the detection of the voltage of $.75 V. EXAMPLE 6: Field test of the corrosion monitoring system

[0045] BA CP was assembled with all the system components and immersed in a container containing salt water for 72 hours, simulating the TVZ envircenment, as shown in Figure 5. {0046} During the entire test period, the system did net alarm, that 1s, the LED did not light up. In this way, it would not be possible to evaluate wheather there was a failure in the configuration of the set or whether the blockage was effective, preventing the penetration of moisture (electrolyte), saturating the salt bridge and, consequently, generating electrical voltage. Thus, a sodium chloride saline solution was induced in the set in the expectation of forming the salt bridge. Immediately the LED lit up, as shown in Figure 6. Thus, the effectiveness of the Corrosion Detection System (CDS) was confirmed.

[0047] The results of this simulation showed that it is possible tc detect, immediately, the beginning of the corrosive process through the electrical signal. The most important thing is that by keeping the system energized, we can uninterruptediy moniter the action of corrosion at various points in the piping.

[0048] Thus, two prototypes of the External Corrosion Monitoring System (CMS) were built in steel pipelines located in the tidal variation zone {(TVZ) for field application.

[0049] As can be seen, Figure 7 represents the turnad off electronic panel with the set of five sensors, and Figure 8 shows the same panel, but energized (LED on) indicating that the system is active. When there is active corrosion activity, the panel will indicate in which sensor the corrosive process is occurring, Figure 9.

[0050] The panels are placed in a compartment on the platform, preferably protected from sunlight. The electronic system 1s housed in a watertight box protected from moisture. At the bottom of the panel, there are two entrances to receive the conductors connected to the sensors, these latter positioned at previously defined points of the pipeline.

[0051] As can be seen, the application of this technology involves several steps, all intrinsically linked to each other, which requires well-trained workforce to apply the CMS.

[0052] The invention applied in a pipeline is shown in detail in Figures 11 and 12. The assembly sequence is as follows, starting from the pipeline: a. = piace an insulating element (1}, bh. - the sensors (2) and / or sensor cellar (4) are placed on the insulating element and connected to the respective cables (7), Su - the permo-porocus material (5) 1s placed over the SenEQrs, d. - an anti-corrosive protection is applied to this entire seb (3) and, finally, covering all these elements, 2. - a layer of composite material (6) is applied to protect the system.

[0053] It should be noted that, although the present invention has been described in relation to the attached drawings, it may undergo modifications and adaptations by technicians skilled on the subject, depending on the specific situation, but as long as it is within the inventive scope defined herein.

Claims

1- A PIPELINE CORROSION REMOTE MONITORING SYSTEM for pipelines located in a tidal variation zone (TVZ), characterized in that it comprises:an insulating element (1),sensors (2),a sealing barrier (3),a permo-porous material (5),a composite material (6),an electrical conductor cable (7),an electronic sensor panel (8), connectable to an electrical source, wherein the electronic panel (8) comprises five electrical sensors with LED connected to the conductor cable (7) reinforced with aramid wire, wherein the sensors (2) are positioned at various points in the pipeline, wherein the electronic panel (8) captures an electrical signal generated by external corrosion through the sensor electrodes (2), the sensor electrodes (2) being positioned on the insulating element (1), so that the sensor electrodes (2) are isolated from the pipeline wall and covered by the permo-porous material (5) for capturing an amount of electrolyte to close an electrical circuit indicative of corrosion, wherein the electrical circuit is formed between the electrodes of a sensor (2), wherein the electronic panel (8) is further configured to indicate which sensor (2) detects the corrosion, the corrosion remote monitoring system being installed, in use, on the surface of the pipeline completely surrounded by the sealing barrier (3) and, covered with the composite material (6).2- THE CORROSION REMOTE MONITORING SYSTEM according to claim 1, characterized in that the pipeline is chosen from risers, J-Tubes and I-Tubes.LOCM

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