Layer element suitable as integrated back sheet for bifacial photovoltaic module

Abstract

To provide layer elements on the rear side of solar cells that show a high transparency, an article having the layer element as an integrated back sheet element, and a method for producing the layer elements.SOLUTION: There is provided a layer element comprising at least two layers (A) and (B), wherein the layer (A) comprises a polyethylene composition comprising: a copolymer of ethylene, which bears silane group(s) containing units; or a copolymer of ethylene with polar comonomer, which bears silane group(s) containing units; or a copolymer of ethylene with vinyl acetate comonomer; wherein the layer (B) comprises a polypropylene composition comprising: a random copolymer of propylene monomer units with alpha olefin comonomer units; or a heterophasic copolymer of propylene which comprises, a polypropylene matrix component and an elastomeric propylene copolymer component which is dispersed in the polypropylene matrix; and wherein the layer (B) has a total luminous transmittance of at least 80.0%.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a layer element having a polyethylene base layer and a polypropylene base layer with a total transparency of at least 80%, to an article having said layer element as an integrated backsheet element, preferably a photovoltaic module such as a bifacial photovoltaic module, to a method for producing said layer element, to a method for producing said photovoltaic module and to the use of said layer element as an integrated backsheet element in a bifacial photovoltaic module. [Background technology]

[0002] In certain end-use applications, such as outdoor end-use applications where temperatures vary over a wide range and the articles are exposed to sunlight, special requirements are placed on the polymeric articles, for example, in terms of mechanical properties, long-term thermal stability, especially at high temperatures, barrier properties and UV stability.

[0003] Photovoltaic (PV) modules, also known as solar cell modules, generate electricity from light and are used in various applications well known in the art, especially outdoor applications. There are various types of photovoltaic modules. Modules usually have a multi-layer structure, i.e. several different layer elements with different functions. The layer elements of a photovoltaic module vary in terms of layer materials and layer structures. The final photovoltaic module can be rigid or flexible. The layer elements exemplified above can be single layer or multi-layer elements. Usually, the layer elements of a PV module are assembled in a sequence based on their function and then stacked to form an integrated PV module. Furthermore, adhesive layers may be present between layers of elements or between different layer elements. A photovoltaic (PV) module can have, for example, in the order described, a protective front layer element (e.g. glass layer element), which may be flexible or rigid, a front encapsulation layer element, a photovoltaic element, a rear encapsulation layer element, a protective back layer element, also called a backsheet layer element, which may be rigid or flexible; and, optionally, for example, an aluminum frame. Thus, some or all of the layer elements of a PV module, such as the front and rear encapsulation layer elements and, in many cases, the backsheet layer, are typically polymeric materials, such as ethylene vinyl acetate (EVA)-based materials, polyester-based materials or polyamide-based materials and fluoropolymer-based materials.

[0004] Bifacial PV modules generate solar energy from both sides of the panel. While traditional opaque backsheet panels are monofacial, bifacial modules expose both the front and rear sides of the solar cells. Because solar energy is also generated from the rear side, bifacial PV modules can generate up to 30% more power than monofacial PV modules. Bifacial module designs vary. Some have frames, some do not. Some are double-glazed, and some use transparent backsheets. Most use monocrystalline cells, but some have polycrystalline designs. What they have in common is that they generate electricity from both sides. There are unframed double-glazed modules that expose the rear side of the cells, but are not bifacial. True bifacial modules have contacts / busbars on both the front and rear sides of these cells. A prerequisite for a PV module to be used as a bifacial PV module is that the layer elements on the rear side of the solar cells have high transparency, which increases the power output from the rear side of the solar cells. However, the backsheet layer element still needs to exhibit good mechanical stability in its function as a protective backlayer element. Most bifacial PV modules are therefore double-glass modules in which both the front and rear side protective elements are glass elements.

[0005] The main drawback of glass-glass modules with bifacial solar cells is their weight, which makes handling and installation laborious and unfavourable from the point of view of logistics costs.

[0006] Since glass is a large source of Na+ ions and bifacial solar cells (especially the rear side) are susceptible to potential induced degradation (PID), bifacial modules tend to show high PID degradation. Currently, the industry solves this with PID-resistant encapsulants and / or Na-free glass. An alternative and cheaper solution would be to replace the rear glass with a PP-based transparent backsheet.

[0007] Another problem with glass-glass modules is that the lamination process takes longer and process optimization is very tedious with traditional film-based laminators. Therefore, plate-plate laminators or autoclave-based lamination are ideal for producing good quality glass-glass modules. However, since more than 95% of solar cell laminators are film-based laminators, many module manufacturers cannot easily switch to bifacial modules for this lamination. A transparent polymer backsheet would completely solve this problem.

[0008] The challenges associated with competitive polymeric transparent backsheets are also manifold, such as high cost, weak interlayer adhesion, incompatibility with different types of encapsulants, limited hydrolytic stability (especially for PET-based backsheets) and environmental aspects (presence of fluorinated polymers). Summary of the Invention [Problem to be solved by the invention]

[0009] There is still room for improvement in the balance of properties of the layer elements on the rear side of the solar cell for bifacial PV modules: The layer elements on the rear side of the solar cell should exhibit high transparency. [Means for solving the problem]

[0010] According to the invention, a layer element is provided having a polyethylene-based layer and a polypropylene-based layer with high total transmittance, which can be used as an integrated backsheet element for a PV module. It has been found that the use of the integrated backsheet element in a bifacial PV module surprisingly results in good power output from the rear side of the solar cells.

[0011] Summary of the Invention The present invention relates to a layer element having at least two layers (A) and (B), The layer (A) has a polyethylene composition (PE-A), and the polyethylene composition (PE-A) is (PE-Aa) a copolymer of ethylene having silane group-containing units; or (PE-Ab) a copolymer of ethylene with polar comonomer units selected from one or more of (C1-C6)-alkyl acrylate or (C1-C6)-alkyl(C1-C6)-alkyl acrylate comonomer units, further comprising silane group-containing units; or (PE-Ac) copolymer of ethylene with vinyl acetate comonomer units; having Copolymers of ethylene (PE-Aa) are different from copolymers of ethylene (PE-Ab); The layer (B) has a polypropylene composition (PP-B), which is (PP-Ba) a random copolymer of propylene monomer units with alpha-olefin comonomer units selected from ethylene and alpha-olefins having 4 to 12 carbon atoms; or (PP-Bb) heterophasic copolymers of propylene, a polypropylene matrix component, and - an elastomeric propylene copolymer component dispersed within said polypropylene matrix; a heterophasic copolymer of propylene having the formula: having; Layer (B) has a total light transmittance of at least 80.0%; Concerning layer elements.

[0012] Furthermore, the present invention relates to an article comprising the above-mentioned or below-mentioned layer elements, said article being preferably a photovoltaic module, most preferably a bifacial photovoltaic module.

[0013] The present invention furthermore relates to a method for the manufacture of the above-mentioned or below-mentioned layer element, comprising the steps of: - bonding layers (A), (B) and, optionally, layer (C) of said layer element by extrusion or lamination to give the structure AB or ACB; and - Recovering the formed layer elements.

[0014] Furthermore, the present invention relates to a method for producing the above-mentioned or below-mentioned photovoltaic (PV) module, comprising the steps of: - assembling the photovoltaic element, the layer element and any further layer elements into a photovoltaic (PV) module assembly; - laminating the layer elements of a photovoltaic (PV) module assembly at an elevated temperature to bond the elements together; and - Recovering the resulting photovoltaic (PV) modules.

[0015] Finally, the present invention relates to the use of a layer element as described above or below as an integrated backsheet element of a double-sided photovoltaic module comprising a photovoltaic element and said layer element, said photovoltaic element being in adhesive contact with layer (A) of said layer element.

[0016] definition An olefin homopolymer is a polymer consisting essentially of one olefin monomer unit. Due to impurities, particularly in commercial polymerization processes, an olefin homopolymer may have at most 0.1 mol% of comonomer units, preferably at most 0.05 mol% of comonomer units, and most preferably at most 0.01 mol% of comonomer units.

[0017] In this regard, a propylene homopolymer is a polymer consisting essentially of propylene monomer units, and an ethylene homopolymer is a polymer consisting essentially of ethylene monomer units.

[0018] Olefin copolymers are polymers that, in addition to olefin monomer units, also contain minor molar amounts of one or more comonomer units.

[0019] Thus, in copolymers of propylene, propylene monomer units will comprise the majority molar amount, and in copolymers of ethylene, ethylene monomer units will comprise the majority molar amount.

[0020] Random olefin copolymers are those in which the olefin monomer units constitute the majority molar amount and the comonomer units are randomly distributed throughout the polymer chain.

[0021] Heterophasic polypropylenes are propylene-based copolymers having a crystalline matrix phase and an elastomeric phase dispersed therein, the crystalline matrix phase can be a propylene homopolymer or a random copolymer of propylene and at least one alpha-olefin comonomer, the elastomeric phase can be a propylene copolymer having a large amount of comonomer, which is not randomly distributed in the polymer chain, but is distributed in comonomer-rich and propylene-rich block structures.

[0022] Heterophasic polypropylenes differ from single-phase propylene copolymers in that they usually exhibit two distinct glass transition temperatures, Tg, corresponding to the matrix phase and the elastomeric phase.

[0023] Plastomers are polymers that combine the properties of elastomers and plastics (eg, rubber-like properties and the processability of plastics).

[0024] Ethylene-based plastomers are plastomers in which ethylene monomer units make up the majority molar amount.

[0025] In the present invention, a layer element is a structure of one or more layers with a defined function that serves a specific purpose in an article that contains the layer element. In the field of PV modules, a layer element is a structure of one or more layers that serves one of several functions, such as external protection (i.e., a protective front layer element or a protective back layer element), encapsulation of the photovoltaic element (i.e., a front encapsulation layer element or a rear encapsulation layer element) and energy conversion (i.e., the photovoltaic element). A layer element can have other components that are not layers, such as fixtures, spacers, frames, etc.

[0026] An integrated backsheet element of a PV module is a structure of two or more layers that encompasses two or more functions of a PV module. The integrated backsheet element preferably encompasses the external protection function of a protective back layer element and the encapsulation of the photovoltaic element function of a rear encapsulation layer element. These functions are usually encompassed by different layers of the integrated backsheet element.

[0027] A bifacial photovoltaic module is a photovoltaic module that generates solar power from the front and rear sides of the solar cells of the photovoltaic element.

[0028] Two layers in adhesive contact mean that the surface of one layer is in direct contact with the surface of the other layer, without any layer or any spacer between them.

[0029] Different in the context of the present invention means that the two polymers differ in at least one property or component. [Brief description of the drawings]

[0030] FIG. 1 shows the construction of a double-sided glass-glass photovoltaic module with two glass layers as the front and rear protective layer elements. FIG. 2 shows the construction of a bifacial photovoltaic module with a glass layer as a front protective layer element and an embodiment of the layer element of the present invention as an integrated backsheet element with layer (A) which is an encapsulant layer under the cell layer, layer (C) which is a tie layer and layer (B) which is a PP base layer. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0031] Detailed Description Layer Element The layer element of the present invention comprises two layers, (A) and (B). In one embodiment, the two layers (A) and (B) are in adhesive contact with each other.

[0032] In this embodiment, the layer element may consist of layers (A) and (B) forming the structure AB, i.e. the layer element is a two-layer element.

[0033] Alternatively, in this embodiment, the layer element comprises one or more layers in addition to layers (A) and (B). These further layers can be added to the surface of layer (A) that is not in adhesive contact with layer (B) (i.e. layer (X)), or to the surface of layer (B) that is not in adhesive contact with layer (A) (i.e. layer (Y)), or to both (layers (X) and (Y)).

[0034] Possible configurations are XAB, ABY and XABY.

[0035] Layer (X) can be one or more further layers (e.g. 1, 2, 3 or 4 further layers (X)), preferably one further layer (X). Layer (X) can be the same as layer (A) or can be different from layer (A).

[0036] Layer (Y) can be one or more further layers (e.g. 1, 2, 3 or 4 further layers (Y)), preferably one further layer (Y). Layer Y can be the same as layer (B) or can be different from layer (B).

[0037] Usually, layers (A) and (B) have approximately the same thickness.

[0038] In the two-layer element, the thickness of layer (A) is preferably 40 to 60% of the total thickness of the two-layer element.

[0039] In the two-layer element, the thickness of layer (B) is preferably 40 to 60% of the total thickness of the two-layer element.

[0040] The thickness ratio of layers (A):(B) of the two-layer element is preferably in the range of 40:60 to 70:30.

[0041] In the four-layer element, the thickness of each of layers (X), (A), (B), (Y) is preferably independently 15 to 35% of the total thickness of the four-layer element.

[0042] In another embodiment, the layer element may further comprise, in addition to layers (A) and (B), a layer (C).

[0043] In this embodiment, the layer element has three layers (A), (B) and (C) that form the structure ACB. This means that layer (A) is in adhesive contact with layer (C) on one surface of layer (C), and layer (C) is in adhesive contact with layer (B) on the other surface of layer (C). Thus, layers (A) and (B) are not in adhesive contact with each other. Instead, layers (A) and (B) sandwich layer (C) between them.

[0044] In this embodiment, the layer element can consist of layers (A), (B) and (C) forming the component ACB, In this embodiment, the layer element is a three-layer element.

[0045] Alternatively, in this embodiment, the layer element may have one or more layers in addition to layers (A), (B) and (C). These further layers may be added to the surface of layer (A) that is not in adhesive contact with layer (C) (i.e. layer (X)), or to the surface of layer (B) that is not in adhesive contact with layer (C) (i.e. layer (Y)), or to both (layers (X) and (Y)).

[0046] The possible configurations are XACB, ACBY and XACBY.

[0047] Layer (X) can be one or more further layers (e.g. 1, 2, 3 or 4 further layers (X)), preferably one further layer X. Layer (X) can be the same as layer (A) or can be different from layer (A).

[0048] Layer (Y) can be one or more further layers (e.g. 1, 2, 3 or 4 further layers (Y)), preferably one further layer (Y). Layer (Y) can be the same as layer (B) or can be different from layer (B).

[0049] Typically, layers (A) and (B) have the same thickness as layer (C) or a greater thickness than layer (C).

[0050] In the three-layer element, the thickness of layer (A) is preferably 30 to 50% of the total thickness of the three-layer element.

[0051] In the three-layer element, the thickness of layer (C) is preferably 5 to 33.3% of the total thickness of the three-layer element.

[0052] In the three-layer element, the thickness of layer (B) is preferably 30 to 50% of the total thickness of the three-layer element.

[0053] In a three-layer element, the ratio of thicknesses of layers (A):(C):(B) is preferably in the range of 45:10:45 to 33.3:33.3:33.3.

[0054] In the five-layer element, the thickness of each of layers (X), (A), (C), (B) and (Y) is preferably independently 10 to 30% of the total thickness of the three-layer element.

[0055] In a five-layer element, the thickness ratio of layers (X):(A):(C):(B):(Y) preferably ranges from 20:25:10:25:20 to 20:20:20:20:20.

[0056] The layer elements usually have a total thickness of from 250 μm to 2000 μm, preferably from 400 μm to 1750 μm, most preferably from 600 μm to 1500 μm.

[0057] It is preferred that none of the layers of the layer element comprises titanium dioxide, preferably a pigment as defined below. This preferably means that the layer element does not contain titanium dioxide, preferably a pigment. In some embodiments it is preferred that none of the layers of the layer element comprises a flame retardant as defined below.

[0058] In the present application, the pigment is preferably selected from mica, titanium dioxide, CaCO3, dolomite, carbon black or any kind of color pigment (e.g., yellow, green, red, blue, etc.), which may be included from an aesthetic point of view.

[0059] Concerning the optical properties, the layer elements were found to exhibit relatively low transparency and high haze, measured on laminates produced as described in the Examples section:

[0060] In the Examples section, the layer elements, the laminates, have a haze of 63% to 97%.

[0061] Furthermore, in the Examples section, the layer element, the laminate, has a transparency of 6% to 35%.

[0062] The layer elements of the present invention preferably have the following transmission properties, measured on laminates produced as described in the Examples section:

[0063] The layer elements have a total light transmittance of at least 65%, more preferably at least 70%, and most preferably at least 80%.

[0064] The upper limit of the total light transmittance is usually 99% or less, preferably 97% or less.

[0065] The layer elements have a diffuse luminous transmittance of at least 45%, more preferably at least 48%, and most preferably at least 50%.

[0066] The upper limit of the diffuse luminous transmittance is usually 85% or less, and preferably 80% or less.

[0067] Despite the lower optical properties in terms of transparency and haze of the layer element of the invention, this layer element surprisingly exhibits high transmission properties, as measured on laminates produced as described in the Examples section.

[0068] Layer A Layer A comprises, and preferably consists of, a polyethylene composition (PE-A).

[0069] The polyethylene composition (PE-A) is (PE-Aa) a copolymer of ethylene having silane group-containing units; or (PE-Ab) a copolymer of ethylene with polar comonomer units selected from one or more of (C1-C6)-alkyl acrylate or (C1-C6)-alkyl(C1-C6)-alkyl acrylate comonomer units, further comprising silane group-containing units; or (PE-Ac) Copolymer of ethylene with vinyl acetate comonomer units. wherein the copolymer of ethylene (PE-Aa) is different from the copolymer of ethylene (PE-Ab).

[0070] The ethylene copolymers (PE-Aa) and (PE-Ab) have silane group-containing units.

[0071] The silane group-containing units can be present as comonomer units of the ethylene copolymer or as compounds chemically grafted to the ethylene copolymer. By "silane group-containing comonomer units" hereinbefore, hereinafter or in the claims, it is meant that the silane group-containing units are present as comonomer units in the ethylene copolymer.

[0072] In the case of silane group-containing units incorporated as comonomer units in the ethylene copolymer, the silane group-containing units are copolymerized with ethylene monomer units as comonomer units during the polymerization process of the ethylene copolymer.

[0073] When the silane group-containing units are incorporated into the ethylene copolymer by grafting, the silane group-containing units are chemically reacted (also called grafting) with the ethylene copolymer after polymerization of the ethylene copolymer. The chemical reaction, i.e., grafting, is usually carried out using a radical former such as a peroxide. Such a chemical reaction may be carried out before or during the lamination process of the present invention. In general, the copolymerization and grafting of silane group-containing units to ethylene is a well-known technique, well described in the polymer literature and within the skill of the person skilled in the art.

[0074] It is also well known that the use of peroxides in grafting practices reduces the melt flow rate (MFR) of ethylene polymers due to the simultaneous crosslinking reaction. As a result, grafting practices may limit the selection of MFR of the copolymer of ethylene as the starting polymer, which may adversely affect the quality of the polymer in the end-use application. Furthermore, by-products formed from peroxides during the grafting process may adversely affect the use of the polyethylene composition (PE-A) in the end-use application.

[0075] Copolymerization of silane group-containing comonomer units into the polymer backbone results in more uniform incorporation of such units compared to grafting of such units, and, in contrast to grafting, copolymerization does not require the addition of peroxide after polymer preparation.

[0076] Thus, the silane group-containing units are preferably present as comonomer units in copolymers of ethylene.

[0077] That is, in the case of the copolymer of ethylene (PE-Aa), the silane group-containing units are copolymerized together with the ethylene monomer units as comonomer units during the polymerization process of the copolymer of ethylene (PE-Aa).

[0078] In the case of copolymers of ethylene (PE-Ab), the silane group-containing units are copolymerized as comonomer units together with the polar comonomer units and ethylene monomer units during the polymerization process of the copolymers of ethylene (PE-Ab).

[0079] The silane group-containing units, preferably silane group-containing comonomer units, of the copolymer of ethylene (PE-Aa) or the copolymer of ethylene (PE-Ab) are preferably hydrolyzable unsaturated silane compounds represented by formula (I): R 1 SiR 2 q Y 3-q (I) (In the formula, R 1 is an ethylenically unsaturated hydrocarbyl, hydrocarbyloxy or acryl(or methacryl)oxy hydrocarbyl group, Each R 2 are independently an aliphatic saturated hydrocarbyl group; Y, which may be the same or different, is a hydrolyzable organic group; q is 0, 1 or 2.

[0080] Further suitable silane group-containing comonomers are, for example, gamma-acryl(or methacryl)-oxypropyltrimethoxysilane, gamma-acryl(or methacryl)-oxypropyltriethoxysilane and vinyltriacetoxysilane or a combination of two or more of these.

[0081] One suitable subgroup of compounds of formula (I) is the unsaturated silane compound or, preferably, the comonomer of formula (II): CH2=CHSi(OA)3(II) wherein each A is independently a hydrocarbyl group having 1 to 8 carbon atoms, preferably 1 to 4 carbon atoms.

[0082] The silane group containing unit, or preferably comonomer, of the present invention is preferably a compound of formula (II) which is vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane, more preferably vinyltrimethoxysilane or vinyltriethoxysilane.

[0083] The amount of silane group-containing units present, preferably as comonomer units, relative to the total amount of monomer units in the ethylene copolymer (PE-Aa) or ethylene copolymer (PE-Ab), is preferably in the range of 0.01 to 1.5 mol %, more preferably 0.01 to 1.00 mol %, still more preferably 0.05 to 0.80 mol %, even more preferably 0.10 to 0.60 mol %, and most preferably 0.10 to 0.50 mol %, based on the total amount of monomer units in the ethylene copolymer (PE-Aa) or ethylene copolymer (PE-Ab).

[0084] In one preferred embodiment, the ethylene copolymer is an ethylene copolymer (PE-Aa) with silane group-containing units, preferably an ethylene copolymer (PE-Aa) with silane group-containing comonomer units. In this embodiment, the ethylene copolymer (PE-Aa) does not have a polar comonomer as defined for the ethylene copolymer (PE-Ab), i.e., the polar comonomer is not present. Preferably, the silane group-containing comonomer units are the only comonomer units present in the ethylene copolymer (PE-Aa). Thus, the ethylene copolymer (PE-Aa) is preferably produced by copolymerizing ethylene monomer units in a high pressure polymerization process using a radical initiator in the presence of silane group-containing comonomer units.

[0085] In this preferred embodiment, the copolymer of ethylene (PE-Aa) is preferably a copolymer of ethylene with a silane group-containing comonomer unit of formula (I), more preferably a silane group-containing comonomer unit of formula (II), even more preferably a silane group-containing comonomer unit selected from vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane or vinyltrimethoxysilane comonomers. It is particularly preferred that the copolymer of ethylene (PE-Aa) is a copolymer of ethylene with vinyltrimethoxysilane or vinyltriethoxysilane comonomers, most preferably a copolymer of ethylene with vinyltrimethoxysilane.

[0086] In another preferred embodiment, the copolymer of ethylene is a copolymer of ethylene with one or more, preferably one, polar comonomer unit selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl(C1-C6)-alkyl acrylate comonomer units, further comprising a silane group-containing unit (PE-Ab). Preferably, the silane group-containing unit is present as a comonomer unit. Thus, in this embodiment, the copolymer of ethylene (PE-Ab) is preferably a copolymer of ethylene with one or more, preferably one, polar comonomer unit selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl(C1-C6)-alkyl acrylate; and a silane group-containing comonomer unit. Preferably, the polar comonomer unit and the silane group-containing comonomer unit are the only comonomer units present in the copolymer of ethylene (PE-Ab). Thus, copolymers of ethylene (PE-Ab) are preferably prepared by copolymerizing ethylene monomer units in the presence of polar comonomer units and silane group-containing comonomer units using a radical initiator in a high pressure polymerization process.

[0087] Preferably, the polar comonomer units of the copolymer of ethylene (PE-Ab) are selected from (C1-C6)-alkyl acrylate comonomer units, more preferably from methyl acrylate (MA), ethyl acrylate (EA) or butyl acrylate (BA) comonomer units, most preferably from methyl acrylate comonomer units.

[0088] Without being bound by any theory, for example, methyl acrylate (MA) is the only acrylate that does not undergo ester pyrolysis reactions because it does not have this reaction pathway. Thus, copolymers of ethylene with MA comonomer units (PE-Ab) do not form any harmful free acid (acrylic acid) decomposition products at high temperatures, and therefore copolymers of ethylene with methyl acrylate comonomer units (PE-Ab) contribute to good quality and life cycle of the final article. This is not true for the vinyl acetate units of, for example, EVA, because EVA forms harmful acetic acid decomposition products at constant temperatures. Furthermore, other acrylates such as ethyl acrylate (EA) or butyl acrylate (BA) can undergo ester pyrolysis reactions and would form volatile olefinic by-products when decomposed.

[0089] The amount of polar comonomer units present in the ethylene copolymer (PE-Ab) is preferably in the range of 0.5-30.0 mol%, preferably 2.5-20.0 mol%, even more preferably 5.0-15.0 mol%, and most preferably 7.5-12.5 mol%, based on the total amount of monomer units in the ethylene copolymer (PE-Ab).

[0090] The copolymers of ethylene (PE-Ab) are preferably copolymers of ethylene with methyl acrylate, ethyl acrylate or butyl acrylate comonomer units and with vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane or vinyltrimethoxysilane comonomer units, more preferably with vinyltrimethoxysilane or vinyltriethoxysilane comonomer units.

[0091] More preferably, the copolymer of ethylene (PE-Ab) is a copolymer of ethylene with methyl acrylate comonomer units and vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane or vinyltrimethoxysilane comonomers, even more preferably a copolymer of ethylene with methyl acrylate comonomer units and vinyltrimethoxysilane or vinyltriethoxysilane comonomer units, most preferably a copolymer of ethylene with methyl acrylate comonomer units, vinyltrimethoxysilane.

[0092] The polyethylene composition (PE-A) can optionally reduce the melt flow rate (MFR) of the ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) in comparison with the prior art and therefore provide a higher resistance to flow during the manufacture of the layer (A) and the layer element of the invention. As a result, a favorable MFR can optionally further contribute to the quality of the layer element and the article comprising this layer element, preferably a PV module.

[0093] The melt flow rate, MFR2, of the ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) is preferably less than 20 g / 10 min, preferably less than 15 g / 10 min, more preferably from 0.1 to 13 g / 10 min, still more preferably from 0.5 to 10 g / 10 min, even more preferably from 1.0 to 8.0 g / 10 min, more preferably from 1.5 to 6.0 g / 10 min.

[0094] The ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) preferably has a shear thinning index, SHI, of 30.0 to 100.0, more preferably 40.0 to 80.0, and most preferably 50.0 to 75.0. 0.05 / 300 has.

[0095] The preferred SHI range further contributes to advantageous rheological properties of the polyethylene composition (PE-A).

[0096] Thus, the combination of the preferred MFR range of the polyethylene composition (PE-A) and the preferred SHI range further contributes to the quality of the layer A and the layer element of the present invention. As a result, the preferred MFR can optionally contribute to the quality of said layer element and to the article, preferably a PV module, comprising said layer element.

[0097] The ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) preferably has a melting temperature of 70-120° C., more preferably 75-110° C., even more preferably 80-100° C., and most preferably 85-95° C. The preferred melting temperature is beneficial for e.g. lamination processes, since the time of the melting / softening process can be reduced.

[0098] Preferably, the density of the ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) is 920 to 960 kg / m 3 , preferably 925 to 955 kg / m 3 , and most preferably 930 to 950 kg / m 3 It is.

[0099] The copolymers of ethylene (PE-Aa) or copolymers of ethylene (PE-Ab) are, for example, commercially available or can be prepared according to or analogous to known polymerization processes described in the chemical literature.

[0100] In a preferred embodiment, the copolymers of ethylene (PE-Aa) or copolymers of ethylene (PE-Ab) are prepared by polymerizing ethylene in a high pressure (HP) process using free radical polymerization in the presence of one or more initiators, optionally using chain transfer agents (CTAs) to control the MFR of the polymer, suitably with silane group-containing comonomer units as defined above and, in the case of copolymers of ethylene (PE-Ab), additionally with polar comonomer units as described above.

[0101] A suitable high pressure (HP) process with suitable polymerization conditions is described in WO2018 / 141672.

[0102] Such HP polymerizations result in so-called low density polymers of ethylene (LDPE), here copolymers of ethylene (PE-Aa) or copolymers of ethylene (PE-Ab). The term LDPE has a well-known meaning in the polymer art and describes the properties, i.e. typical characteristics, of polyethylene produced in HP, such as different branching structures, to distinguish LDPE from PE produced in the presence of olefin polymerization catalysts (also known as coordination catalysts). The term LDPE is an abbreviation for low density polyethylene, but the term is understood to include low, medium and higher density LDPE-like HP polyethylenes without limiting the density range.

[0103] In another preferred embodiment, the polyethylene composition (PE-A) comprises a copolymer (PE-Ac) of ethylene monomer units and vinyl acetate comonomer units (EVA).

[0104] Preferably, the amount of vinyl acetate (VA) comonomer units present in the copolymer of ethylene (PE-Ac) ranges from 0.5 to 30.0 mol%, preferably from 2.5 to 20.0 mol%, even more preferably from 5.0 to 15.0 mol%, and most preferably from 7.5 to 12.5 mol%, based on the total amount of monomer units in the copolymer of ethylene (PE-Ac).

[0105] The melt flow rate, MFR2, of the ethylene copolymer (PE-Ac), measured according to ISO 1133 at 190°C and a load of 2.16 kg, is preferably 0.1 to 13 g / 10 min, even more preferably 1.0 to 50 g / 10 min, more preferably 5.0 to 45.0 g / 10 min, more preferably 7.5 to 40.0 g / 10 min, and most preferably 10.0 to 35.0 g / 10 min.

[0106] The copolymer of ethylene (PE-Ac) preferably has a melting temperature of 25-95° C., more preferably 30° C.-90° C., even more preferably 35° C.-85° C., and most preferably 40° C.-80° C. The preferred melting temperature is beneficial for e.g. lamination processes, since the time of the melting / softening process can be reduced.

[0107] Preferably, the density of the ethylene copolymer (PE-Ac) is 940 to 975 kg / m 3 , preferably 945 to 970 kg / m 3 , and most preferably 950 to 965 kg / m 3 It is.

[0108] Copolymers of ethylene (PE-Ac) are generally commercially available, but may be prepared according to or analogous to known polymerization processes described in the chemical literature.

[0109] Suitable commercially available copolymers of ethylene (PE-Ac) can be purchased, for example, from Hangzhou First Applied Material Co., Ltd (People's Republic of China).

[0110] The polyethylene composition (PE-A) preferably comprises the ethylene copolymer (PE-Aa), (PE-Ab) or (PE-Ac) in an amount of 20.0 wt% to 100 wt%, more preferably 20.0 wt% to 99.9999 wt%, even more preferably 65.0 to 99.999, most preferably 87.5 wt% to 99.99 wt%, based on the total weight of the polyethylene composition (PE-A).

[0111] The amount of ethylene copolymer (PE-Aa), (PE-Ab) or (PE-Ac) in the polyethylene composition (PE-A) depends on the presence of further components in the polyethylene composition (PE-A).

[0112] The polyethylene composition (PE-A) preferably comprises additives other than fillers, pigments, carbon black or flame retardants, these terms having the meanings known in the prior art.

[0113] The optional additives are, for example, conventional additives appropriate for the desired end use and within the skill of the art, preferably including at least, but not limited to, antioxidants, UV light stabilizers and / or UV light absorbers, and may further include metal deactivators, clarifiers, brighteners, acid scavengers, slip agents, etc. Each additive may be used, for example, in conventional amounts, and the total amount of additives present in the PE composition (PE-A) is preferably as defined below. Such additives are generally commercially available and are described, for example, in "Plastic Additives Handbook", 5th edition, 2001, by Hans Zweifel.

[0114] The amount of the additive is preferably up to 10.0 wt%, for example in the range of 0.0001 to 10.0 wt%, more preferably 0.001 and 5.0 wt%, and most preferably 0.01 to 2.5 wt%, based on the total weight of the polyethylene composition (PE-A).

[0115] The polyethylene composition (PE-A) may further comprise a flame retardant.

[0116] The optional flame retardants are typically conventional and commercially available. Suitable optional flame retardants are as defined herein for Layer C - Filler.

[0117] The amount of the flame retardant is preferably up to 40.0 wt%, for example in the range of 0.1 to 40.0 wt%, preferably 0.5 to 30.0 wt%, most preferably 1.0 to 15.0 wt%, based on the total weight of the polyethylene composition (PE-A).

[0118] The polyethylene composition (PE-A) may further comprise a polymer different from the copolymer of ethylene (PE-Aa) or (PE-Ab) or (PE-Ac).

[0119] However, it is preferred that the polyethylene composition (PE-A) has only copolymers of ethylene (PE-Aa) or (PE-Ab) or (PE-Ac) as polymeric components.

[0120] "Polymer component" as used herein excludes any carrier polymer of any additive or filler, such as a carrier polymer used in a masterbatch of an additive or filler optionally present in the polyethylene composition (PE-A), which is included in the amount of each additive or filler relative to the amount (100 wt%) of the polyethylene composition (PE-A).

[0121] In a particularly preferred embodiment, the polyethylene composition (PE-A) is free of fillers, pigments and / or carbon black.

[0122] It has been found that the absence of fillers, pigments and / or carbon black increases the transparency of layer (A) which helps to improve the power output of the bifacial photovoltaic module.

[0123] It is further preferred that the polyethylene composition (PE-A) additionally does not comprise any flame retardant as defined above. In this embodiment, the polyethylene composition (PE-A) is preferably free of fillers, pigments, carbon black and / or flame retardants.

[0124] In one embodiment, the polyethylene composition (PE-A) preferably comprises - 70.0 to 99.9999 wt.%, preferably 80.0 to 99.499 wt.%, most preferably 87.5 to 98.99 wt.% of a copolymer of ethylene; - 0.0001 to 10.0 wt %, preferably 0.001 and 5.0 wt %, most preferably 0.01 and 2.5 wt % of an additive; and - 0-20.0 wt%, preferably 0.5-15.0 wt%, most preferably 1.0-10.0 wt% of a flame retardant; and preferably consists of these.

[0125] In this embodiment, the polyethylene composition (PE-A) typically has a melt flow rate MFR2 and a shear thinning index SHI as defined above for the copolymer of ethylene (PE-Aa), the copolymer of ethylene (PE-Ab) or the copolymer of ethylene (PE-Ac). 0.05 / 300 It has the same range of properties.

[0126] In another embodiment, the polyethylene composition (PE-A) has an additive but does not have a flame retardant as defined above. In this case, the polyethylene composition (PE-A) has, relative to the amount of polyethylene composition (PE-A) (100 wt%): - copolymers of ethylene from 90.0 to 99.9999 wt%, preferably from 95.0 to 99.999 wt%, most preferably from 97.5 to 99.99; and - 0.0001 to 10.0 wt %, preferably 0.001 and 5.0 wt %, most preferably 0.01 and 2.5 wt % of additives; and preferably consists of these.

[0127] In this embodiment, the polyethylene composition (PE-A) typically has a melt flow rate MFR2, density, melt temperature Tm and shear thinning index SHI as defined above for the copolymer of ethylene (PE-Aa), the copolymer of ethylene (PE-Ab) or the copolymer of ethylene (PE-Ac). 0.05 / 300 It has the same range of properties.

[0128] This embodiment is particularly preferred for the polyethylene composition (PE-A) of the layer element of the invention.

[0129] Preferably, layer A of the layer element consists of a polyethylene composition (PE-A) comprising a copolymer of ethylene as defined above, below and in the claims.

[0130] Layer (A), preferably the polyethylene composition (PE-A), most preferably the copolymer of ethylene (PE-Aa) or (PE-Ab), is preferably not crosslinked using peroxide. When using a copolymer of ethylene (PE-Ac), layer (A), preferably the polyethylene composition (PE-A), most preferably the copolymer of ethylene (PE-Ac), can be crosslinked using a peroxide, preferably in the presence of an organic peroxide. Crosslinking processes and conditions are well known in the art and depend on the nature of the peroxide used.

[0131] However, if necessary, depending on the end use, the polyethylene composition (PE-A) can be crosslinked via the silane group-containing units of the ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) before or during the lamination process of the layer element of the invention using a silanol condensation catalyst (SCC), preferably selected from the group of the tin, zinc, iron, lead or cobalt carboxylates or aromatic organic sulfonic acids. Such SCCs are, for example, commercially available.

[0132] It is to be understood that the SCC defined above is that which is conventionally supplied for crosslinking purposes.

[0133] When present, the amount of optional crosslinker (SCC) is preferably 0 to 0.1 mol / kg, for example 0.00001 to 0.1, preferably 0.0001 to 0.01, more preferably 0.0002 to 0.005, more preferably 0.0005 to 0.005 mol / kg, based on the ethylene copolymer.

[0134] Preferably no crosslinker (SCC) is present in the layer element (LE).

[0135] In a preferred embodiment, no silane condensation catalyst (SCC) selected from the SCC group of tin organocatalysts or aromatic organic sulfonic acids is present in the polyethylene composition (PE-A). In a further preferred embodiment, no peroxide or silane condensation catalyst (SCC) as defined above is present in the polyethylene composition (PE-A).

[0136] It is particularly preferred that the polyethylene composition is not crosslinked. As already mentioned, the polyethylene composition (PE-A) makes it possible to avoid crosslinking of the layer (A) of the layer element, which contributes to obtaining a good quality layer element.

[0137] Layer (A) preferably has a thickness of 100 μm to 750 μm, preferably 150 μm to 650 μm, most preferably 200 μm to 550 μm.

[0138] Layer (B) Layer (B) is (PP-Ba) a random copolymer of propylene monomer units with alpha-olefin comonomer units selected from ethylene and alpha-olefins having 4 to 12 carbon atoms; or (PP-Bb) heterophasic copolymers of propylene, a polypropylene matrix component, and - an elastomeric propylene copolymer component dispersed within said polypropylene matrix; a heterophasic copolymer of propylene having the formula: A polypropylene composition (PP-B) having the following formula: Layer (B) has a total light transmittance of at least 80.0%.

[0139] In one embodiment, the polypropylene composition (PP-B) comprises a random copolymer of propylene monomer units with alpha-olefin comonomer units selected from ethylene and alpha-olefins having from 4 to 12 carbon atoms (PP-Ba).

[0140] The comonomer units are selected from ethylene and alpha-olefins having 4 to 12 carbon atoms, preferably from ethylene and alpha-olefins having 4 to 8 carbon atoms, more preferably from ethylene, 1-butene and 1-hexene, even more preferably from ethylene and 1-butene, most preferably from ethylene.

[0141] Preferably, the random copolymer (PP-Ba) comprises only one type of comonomer unit as described above, in which case the random copolymer is a random copolymer of propylene monomer units with alpha-olefin comonomer units selected from ethylene and one of the alpha-olefins having from 4 to 12 carbon atoms.

[0142] Alternatively, the random copolymer (PP-Ba) comprises two or more, such as two or three, of the comonomer units described above, in which case the random copolymer is a random copolymer of propylene monomer units with two or more, such as two or three, alpha-olefin comonomer units selected from ethylene and one of the alpha-olefins having from 4 to 12 carbon atoms.

[0143] The comonomer content in the random copolymer (PP-Ba) is preferably in the range of 0.5 to 15.0 wt%, more preferably in the range of more than 1.0 wt% and not more than 12.5 wt%, even more preferably in the range of 1.5 to 10.0 wt%, and most preferably in the range of 2.0 to 8.0 wt.

[0144] The random copolymer (PP-Ba) preferably has a melt flow rate MFR2(230°C), measured according to ISO 1133, in the range of 0.5 to 20.0 g / 10 min, more preferably in the range of 1.0 to 15.0 g / 10 min, even more preferably in the range of 1.5 to 12.0 g / 10 min, and even more preferably in the range of 1.8 to 10.0 g / 10 min.

[0145] Furthermore, the random copolymer (PP-Ba) can be defined by its xylene cold solubles (XCS) content measured according to ISO 6427. Thus, the propylene polymer is preferably characterized by a xylene cold solubles (XCS) content of less than 25.0 wt%, more preferably less than 20.0 wt%.

[0146] Therefore, it is particularly preferred that the random copolymer (PP-Ba) has a low temperature xylene soluble component (XCS) content in the range of 2.0 to less than 20.0 wt%, and most preferably in the range of 3.0 to 18.0 wt%.

[0147] Still further, the random copolymer (PP-Ba) can be defined by its melting temperature (Tm). Thus, the propylene polymer preferably has a melting temperature Tm of 120°C or higher. Even more preferably, the melting temperature Tm is in the range of 125°C to 160°C, and most preferably in the range of 125°C to 155°C.

[0148] The random copolymer (PP-Ba) preferably has a viscosity of 900 to 910 kg / m 3 The density is in the range of

[0149] The crystallization temperature of the random copolymer (PP-Ba), measured by DSC according to ISO 11357, can be equal to or greater than 85°C, preferably in the range of 85°C to 150°C, even more preferably in the range of 90°C to 130°C.

[0150] The random copolymers (PP-Ba) can furthermore be unimodal or multimodal, for example bimodal with respect to the molecular weight distribution and / or the comonomer content distribution; both unimodal and bimodal propylene polymers are equally preferred.

[0151] If the random copolymer (PP-Ba) is unimodal, it is preferably produced in a single polymerization step in one polymerization reactor (R1). Alternatively, the unimodal propylene polymer can be produced in a sequential polymerization process, using the same polymerization conditions in all reactors.

[0152] When the propylene polymer is multimodal, it is preferably produced in a sequential polymerization process using different polymerization conditions in the reactors (amount of comonomer, amount of hydrogen, etc.) In some embodiments, a propylene homopolymer fraction is polymerized in one reaction step of the sequential polymerization process and a propylene copolymer fraction is polymerized in a second reaction step of the sequential polymerization process.

[0153] The random copolymers (PP-Ba) are preferably propylene polymers prepared in the presence of a Ziegler-Natta catalyst system or a single-site catalyst system, such as a metallocene catalyst system. Suitable catalyst systems are the same as those described below for the heterophasic copolymers of propylene (PP-Bb).

[0154] The random copolymer (PP-Ba) can be produced in a single polymerization step with a single polymerization reactor (R1) or in a sequential polymerization process with at least two polymerization reactors (R1) and (R2), in which a first propylene polymer fraction is produced in the first polymerization reactor (R1) and then transferred into a second polymerization reactor (R2), in which a second propylene polymer fraction is then produced in the presence of the first propylene polymer fraction.

[0155] Polymerization processes suitable for the production of random copolymers (PP-Ba) generally have one or two polymerization stages, each of which can be carried out in solution, slurry, fluidized bed, bulk or gas phase.

[0156] The term "polymerization reactor" indicates where the main polymerization takes place. Thus, if the process consists of one or two polymerization reactors, this definition does not exclude the option that the overall system has a prepolymerization step, for example in a prepolymerization reactor. The term "consist of" is only a restrictive expression in relation to the main polymerization reactor.

[0157] The term "sequential polymerization process" indicates that the random copolymer (PP-Ba) is produced in at least two reactors connected in series. Thus, such a polymerization system has at least a first polymerization reactor (R1) and a second polymerization reactor (R2), and optionally a third polymerization reactor (R3).

[0158] The first, or only, polymerization reactor (R1) is preferably a slurry reactor and can be any continuous or simply stirred batch tank reactor or loop reactor operating in bulk or slurry conditions. By bulk it is meant polymerization in a reaction medium containing at least 60% (w / w) of monomer. According to the invention the slurry reactor is preferably a (bulk) loop reactor.

[0159] In case of applying the "sequential polymerization process", the second polymerization reactor (R2) and the optional third polymerization reactor (R3) are gas phase reactors (GPR), i.e. the first gas phase reactor (GPR1) and the second gas phase reactor (GPR2). The gas phase reactors (GPR) according to the present invention are preferably fluidized bed reactors, fast fluidized bed reactors or fixed bed reactors or any combination thereof.

[0160] Preferred multi-stage processes are "loop-gas-phase" processes, such as those developed by Borealis (known as BORSTAR® technology) and described in patent documents such as, for example, EP 0887379, WO 92 / 12182, WO 2004 / 000899, WO 2004 / 111095, WO 99 / 24478, WO 99 / 24479 or WO 00 / 68315.

[0161] A further suitable slurry-gas phase process is Basell's Spheripol® process.

[0162] Suitable polymerization conditions are the same as those described below for the polypropylene matrix component of the heterophasic copolymer of propylene (PP-Bb).

[0163] In another embodiment, the polypropylene composition (PP-B) comprises a heterophasic copolymer of propylene (PP-Bb) having a polypropylene matrix component and an elastomeric propylene copolymer component dispersed in the polypropylene matrix.

[0164] The matrix component of the heterophasic copolymer of propylene (PP-Bb) can be a propylene homopolymer component or a propylene random copolymer component.

[0165] When the matrix component is a propylene random copolymer, it is preferably a random copolymer of propylene with one or more of ethylene and / or C4-C8 alpha-olefin comonomers. The propylene random copolymer component is preferably a propylene-ethylene random copolymer.

[0166] Preferably, the polypropylene matrix component of the heterophasic copolymer of propylene (PP-Bb) is a homopolymer of propylene.

[0167] Since the amount of XCS fraction in the matrix component is conventionally significantly low, the XCS fraction of the heterophasic copolymer of propylene (PP-Bb) is considered as the elastomeric component in this specification. For example, when the matrix component is a homopolymer of propylene, the weight of the low temperature xylene soluble component (XCS) fraction of the heterophasic copolymer of propylene (PP-Bb) is understood in this application to also be the amount of elastomeric propylene copolymer component present in the heterophasic copolymer of propylene (PP-Bb).

[0168] The total comonomer content of the heterophasic copolymer of propylene (PP-Bb) is preferably 2.0-25.0 wt %, more preferably 3.0-20.0 wt %.

[0169] The comonomer units of the heterophasic copolymer of propylene (PP-Bb) are preferably selected from ethylene and / or C4-C8 alpha-olefin comonomers, more preferably from ethylene.

[0170] The melting temperature Tm of the heterophasic copolymer of propylene (PP-Bb) is preferably at least 145°C, more preferably 150-170°C, most preferably 155-170°C.

[0171] Preferably, the heterophasic copolymer of propylene (PP-Bb) has a Vicat softening temperature (Vicat A) of at least 90°C, preferably 105-160°C, most preferably 120-155°C.

[0172] Preferably, the heterophasic copolymer of propylene (PP-Bb) has a melt flow rate MFR2 (2.16 kg, 230° C.) of 1.0 to 20.0 g / 10 min, preferably 2.0 to 17.5 g / 10 min, preferably 3.0 to 15.0 g / 10 min.

[0173] Furthermore, the heterophasic copolymer of propylene (PP-Bb) preferably has a xylene cold soluble component (XCS) fraction in an amount of 5-40 wt%, more preferably 10-37 wt%, based on the total amount of the heterophasic copolymer of propylene (PP-Bb).

[0174] Still further, the heterophasic copolymer of propylene (PP-Bb) preferably has a flexural modulus of at least 700 MPa, preferably between 750 and 2500 MPa.

[0175] Furthermore, the heterophasic copolymer of propylene (PP-Bb) is preferably 900 to 910 kg / m 3has a density of

[0176] In a preferred embodiment, the heterophasic copolymer of propylene (PP-Bb) meets all the above mentioned properties of comonomer content, Tm, Bicatad A, MFR2, XCS fraction, flexural modulus and density.

[0177] The polypropylene composition (PP-B) may also comprise a mixture of two or more, for example two different, such heterophasic copolymers of propylene.

[0178] The heterophasic copolymers of propylene can be commercial grades or can be prepared by conventional polymerization processes and process conditions using, for example, conventional catalyst systems known in the literature.

[0179] The heterophasic copolymers of propylene described herein can be polymerized in a sequential polymerization process, such as a multi-stage process.

[0180] A suitable process is described in WO2018 / 141672.

[0181] Preferred multi-stage processes are "loop-gas-phase" processes, such as those developed by Borealis A / S of Denmark (known as BORSTAR® technology) and described in patent documents such as, for example, EP 0887379, WO 92 / 12182, WO 2004 / 000899, WO 2004 / 111095, WO 99 / 24478, WO 99 / 24479 or WO 00 / 68315.

[0182] A further suitable slurry-gas phase process is LyondellBasell's Spheripol® process.

[0183] After the random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb) is removed from the last polymerization stage, it is preferably subjected to a process step to remove residual hydrocarbons from the polymer. Such processes are well known in the art and may include depressurization, purging, stripping, extraction, etc. Combinations of these steps are also possible. After removal of residual hydrocarbons, the heterophasic copolymer of propylene is preferably mixed with additives, as is well known in the art. Such additives are as described above for the polypropylene composition (PP-B). The polymer particles are then extruded into pellets, as is well known in the art. Preferably, a co-rotating twin screw extruder is used for the extrusion step. Such extruders are manufactured, for example, by Coperion (Werner & Pfleiderer) and Japan Steel Works.

[0184] The random copolymers of propylene (PP-Ba) or heterophasic copolymers of propylene (PP-Bb) are preferably produced by polymerization using any suitable Ziegler-Natta type. A typical suitable Ziegler-Natta type catalyst is a stereospecific solid high-yield Ziegler-Natta catalyst component having Mg, Ti and Cl as essential components. In addition to the solid catalyst, cocatalysts and external donors are usually used in the polymerization process.

[0185] The components of the catalyst may be supported on a particulate support such as an inorganic oxide such as silica or alumina, or typically magnesium halide may form the solid support. It is also possible that the catalyst components are not supported on an external support and the catalyst is prepared by emulsion-coagulation or precipitation techniques.

[0186] Alternatively, the random copolymers of propylene (PP-Ba) or the heterophasic copolymers of propylene (PP-Bb) of the present invention can be prepared using modified catalyst systems as described below.

[0187] More preferably, a vinyl compound of formula (I) is used for the modification of the catalyst: CH2=CH-CHR 1 R 2 (IV) (In the formula, R 1 and R 2 together form a 5- or 6-membered saturated, unsaturated or aromatic ring optionally having substituents, or independently represent an alkyl group having 1 to 4 carbon atoms; R 1 and R 2 When it forms an aromatic ring, -CHR 1 R 2 There are no hydrogen atoms in the group.

[0188] More preferably, the vinyl compound (IV) is selected from vinylcycloalkanes, preferably vinylcyclohexane (VCH), vinylcyclopentane, 3-methyl-1-butene polymers and vinyl-2-methylcyclohexane polymers. Most preferably, the vinyl compound (IV) is a vinylcyclohexane (VCH) polymer.

[0189] The solid catalyst also usually has an electron donor (internal electron donor) and optionally aluminum.Suitable internal electron donors are in particular esters of carboxylic or dicarboxylic acids, such as phthalates, maleates, benzoates, citraconic and succinic acids, 1,3-diethers or oxygen- or nitrogen-containing silicon compounds.In addition, mixtures of donors can be used.

[0190] The cocatalyst usually comprises an aluminum alkyl compound, which is preferably a trialkylaluminum such as trimethylaluminum, triethylaluminum, triisobutylaluminum or tri-n-octylaluminum, but may also be an alkylaluminum halide such as diethylaluminum chloride, dimethylaluminum chloride and ethylaluminum sesquichloride.

[0191] Suitable external electron donors for use in polymerization are well known in the art, and include, for example, ethers, ketones, amines, alcohols, phenols, phosphines and silanes. Silane-type external donors are typically organosilane compounds having Si-OCOR, Si-OR or Si-NR2 bonds, with silicon as the central atom, and R is alkyl, alkenyl, aryl, arylalkyl or cycloalkyl having 1-20 carbon atoms, and are well known in the art.

[0192] Examples of suitable catalysts and compounds therein are in particular those described in WO87 / 07620, WO92 / 21705, WO93 / 11165, WO93 / 11166, WO93 / 19100, WO97 / 36939, WO98 / 12234, WO99 / 33842, WO03 / 000756, WO03 / 000757, WO03 / 000754, WO03 / 000755, WO2004 / 029112, EP2610271, WO2012 / 007430.WO92 / 19659, WO92 / 19653, WO92 / 1965 8, US4382019, US4435550, US4465782, US4473660, US4560671, US5539067, US5618771, EP45975, EP45976, EP45977, WO95 / 32994, US4107414, US4186107, US4226963, US4347160, US4472524, US4522930, US4530912, US4532313, US4657882, US4581342, US4657882.

[0193] Alternatively, the random copolymers of propylene (PP-Ba) or the heterophasic copolymers of propylene (PP-Bb) can be prepared in the presence of a single-site catalyst, such as a single-site solid particulate catalyst without an external support, preferably a catalyst having (i) a complex of formula (I); and (ii) a co-catalyst having a compound of a Group 13 metal, such as Al, or a boron compound. [ka]

[0194] (In the formula, M is zirconium or hafnium; each X is a sigma ligand; L is -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge- (each R' is independently a hydrogen atom, C1-C 20 -Hydrocarbyl, tri(C1-C 20 -alkyl)silyl, C6-C 20 -Aryl, C7-C 20 -arylalkyl or C7-C 20 -alkylaryl; R 2 and R 2’ each independently represents a C1-C 20 is a hydrocarbyl radical; R 5’ C containing one or more heteroatoms of Groups 14-16, optionally substituted with one or more halo atoms. 1-20 is a hydrocarbyl group; R 6 and R 6’ each independently represents hydrogen or C optionally having one or more heteroatoms of Groups 14 to 16 1-20 is a hydrocarbyl group; R 7 and R 7’ each independently represents hydrogen or C optionally having one or more heteroatoms of Groups 14 to 16 1-20 is a hydrocarbyl group; Ar independently represents one or more groups R 1 an aryl or heteroaryl group having up to 20 carbon atoms, optionally substituted with Ar′ independently represents one or more groups R 1 an aryl or heteroaryl group having up to 20 carbon atoms, optionally substituted with Each R 1 is C 1-20a hydrocarbyl group or two R on adjacent carbon atoms 1 The groups may together form a 5- or 6-membered non-aromatic ring fused to the Ar group, which ring may itself contain one or more groups R 4 is optionally substituted with; Each R 4 is C 1-20 is a hydrocarbyl group.

[0195] The catalyst used in the process of the present invention is in solid particulate form without an external support. Ideally, the catalyst is (a) a liquid / liquid emulsion system is formed, the liquid / liquid emulsion system having a solution of catalyst components (i) and (ii) dispersed in a solvent to form dispersed droplets; and (b) solidifying the dispersed droplets to form solid particles; It can be obtained by the process.

[0196] Thus, viewed from another aspect, the present invention provides a process for the preparation of a random copolymer of propylene (PP-Ba) or a heterophasic propylene copolymer (PP-Bb) as defined above, in which a catalyst as defined above is prepared by obtaining (i) a complex of formula (I) as defined above and a cocatalyst (ii); A liquid / liquid emulsion system is formed having a solution of catalyst components (i) and (ii) dispersed in a solvent, and the dispersed droplets are solidified to form solid particles.

[0197] C 1-20 The term hydrocarbyl group means 1-20 Alkyl, C 2-20 Alkenyl, C 2-20 Alkynyl, C 3-20 Cycloalkyl, C 3-20 Cycloalkenyl, C 6-20 Aryl group, C 7-20 Alkylaryl group or C 7-20 Arylalkyl groups or, of course, mixtures of these groups such as cycloalkyl substituted with alkyl are included.

[0198] Unless otherwise stated, the preferred C 1-20 The hydrocarbyl group is C 1-20 Alkyl, C 4-20 Cycloalkyl, C 5-20 Cycloalkyl-alkyl groups, C 7-20 Alkylaryl group, C 7-20 Arylalkyl group or C 6-20 Aryl groups, especially C 1-10 Alkyl group, C 6-10 Aryl group or C 7-12 Arylalkyl groups, such as C 1-8 The most particularly preferred hydrocarbyl groups are methyl, ethyl, propyl, isopropyl, tertbutyl, isobutyl, C 5-6 -cycloalkyl, cyclohexylmethyl, phenyl or benzyl.

[0199] The term halo includes fluoro, chloro, bromo and iodo groups, and in the context of the definition of the complex is in particular the chloro group.

[0200] The oxidation states of metal ions are governed primarily by the nature of the metal ion in question and the stability of each metal ion's particular oxidation state.

[0201] In the complexes of the invention, the metal ion M is preferably coordinated by ligands X to satisfy the valence of the metal ion and fill its available coordination sites. The nature of these σ-ligands can vary.

[0202] Such catalysts are described in WO2013 / 007650, which is incorporated herein by reference.

[0203] The polypropylene composition (PP-B) preferably comprises an additive.

[0204] In this specification, the term additives excludes any fillers, any pigments and any flame retardants. Such additives are preferably conventional and commercially available and include, but are not limited to, UV stabilizers, antioxidants, nucleating agents, clarifiers, gloss agents, acid scavengers, as well as slip agents, processing aids, etc. Such additives are generally commercially available and are described, for example, in Hans Zweifel's "Plastic Additives Handbook", 5th edition, 2001.

[0205] Each additive can be used, for example, in conventional amounts. A person skilled in the art can select appropriate additives and their amounts for layer (B) depending on the desired article and its end use.

[0206] Preferably, the additive is selected from at least a UV stabilizer having a hindered amine compound and an antioxidant having a dialkylamine compound. More preferably, the additive is selected from at least a UV stabilizer having a hindered amine compound and an antioxidant having a dialkylamine compound, and said additive does not have a phenolic unit. The expression "the additive does not have a phenolic unit" means in this specification that any additive compound, including UV stabilizers and antioxidants present in the polypropylene composition (PP-B), does not carry a phenolic unit. Preferably, said composition does not have any components (additives, etc.) having a phenolic unit.

[0207] Thus, fillers, pigments and flame retardants are not understood or defined as additives herein.

[0208] Preferably, the polypropylene composition (PP-B) comprises additives and / or, optionally, one or more selected from fillers and flame retardants.

[0209] If any filler is present, it is preferably an inorganic filler, more preferably one type of inorganic filler. As known to those skilled in the art, the particle size and / or aspect ratio of the filler may vary. Preferably, the filler is selected from one or more of wollastonite, talc or glass fiber. Such filler products are commercially available products with various particle sizes and / or aspect ratios and can be selected by the skilled artisan depending on the desired final article and end use. The filler can be, for example, a conventional commercially available one. If present, the amount of filler is preferably 1-30 wt%, preferably 2-25 wt%, based on the total amount (100 wt%) of the polypropylene composition (PP-B).

[0210] If any flame retardant is present, it can be, for example, any commercially available flame retardant product, preferably a flame retardant with inorganic phosphorus. If a flame retardant is present, its amount is preferably 1-20wt%, preferably 2-15wt%, more preferably 3-12wt%, based on the amount of the polypropylene composition (PP-B).

[0211] As a further component, an alpha-nucleating agent may be present in the polypropylene composition (PP-B).

[0212] One type of preferred alpha-nucleating agent is one that is soluble in random copolymers of propylene (PP-Ba) or heterophasic copolymers of propylene (PP-Bb). Soluble alpha-nucleating agents are characterized by an improved degree of dispersion due to a sequence of dissolution on heating and recrystallization on cooling. Methods for measuring said dissolution and recrystallization are described, for example, by Kristiansen et al. in Macromolecules 38 (2005), pp. 10461-10465, and by Balzano et al. in Macromolecules 41 (2008), pp. 5350-5355. In particular, dissolution and recrystallization can be monitored using melt rheology in a dynamic mode as specified in ISO 6271-10:1999.

[0213] The soluble alpha-nucleating agent may be selected from the group consisting of sorbitol derivatives, nonitol derivatives, benzene derivatives of formula NI as defined below, such as benzene-trisamide, and mixtures thereof.

[0214] Suitable sorbitol derivatives are di(alkylbenzylidene)sorbitols, for example 1,3:2,4-dibenzylidene sorbitol or bis-(3,4-dimethylbenzylidene) sorbitol.

[0215] Suitable nonitol derivatives include 1,2,3-trideoxy-4,6:5,7-bis-O-[(4-propylphenyl)methylene]-nonitol.

[0216] Suitable benzene derivatives include N,N',N''-tris-tert-butyl-1,3,5-benzenetricarboxamide or N,N',N''-tris-cyclohexyl-1,3,5-benzene-tricarboxamide.

[0217] Another type of preferred alpha-nucleating agent is a polymeric alpha-nucleating agent. The polymeric alpha-nucleating agent has the formula CH2=CH-CHR 6 R 7 is a polymer of vinyl compound R 6 and R 7 together form a 5- or 6-membered saturated, unsaturated or aromatic ring, or independently represent an alkyl group having 1 to 4 carbon atoms. Preferably, the polymeric alpha-nucleating agent has the formula CH2=CH-CHR 6 R 7 It is a homopolymer of the vinyl compound.

[0218] One method of incorporating a polymeric α-nucleating agent into a polypropylene composition (PP-B) is to incorporate a polymerization catalyst having the formula CH2=CH-CHR 6 R 7 (R 6 and R 7and , taken together, form a 5- or 6-membered saturated, unsaturated or aromatic ring, or independently represent an alkyl group having 1 to 4 carbon atoms.) are prepolymerized by contacting the propylene with a vinyl compound of the formula (I). Propylene is then polymerized in the presence of the prepolymerized catalyst described above.

[0219] In the prepolymerization, the catalyst is prepolymerized to contain up to 5 grams of prepolymer per gram of solid catalyst component, preferably 0.1 to 4 grams of prepolymer per gram of solid catalyst component. The catalyst is then reacted with a tertiary amine of formula CH2=CH-CHR under polymerization conditions. 6 R 7 (R 6 and R 7 is as defined above.) Particularly preferably, the vinyl compound is contacted with 6 and R 7 which then forms a saturated 5- or 6-membered ring. Particularly preferably, the vinyl compound is vinylcyclohexane. Particularly preferably, the catalyst comprises 0.5 to 2 grams of polymerized vinyl compound, such as poly(vinylcyclohexane), per gram of solid catalyst component. This allows the production of nucleated polypropylene, as disclosed in EP-A-607703, EP-A-1028984, EP-A-1028985 and EP-A-1030878.

[0220] The polypropylene composition may also include an alpha-nucleating agent that is insoluble in the random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb), such as talc, as a suitable alpha-nucleating agent.

[0221] The polypropylene composition (PP-B) may optionally comprise up to 5.0 wt.-%, preferably 0.0001 to 5.0 wt.-%, of an alpha-nucleating agent, preferably 0.001 to 1.5 wt.-%, particularly preferably 0.01 to 1.0 wt.-%, of an alpha-nucleating agent, based on the total weight of the polypropylene composition (PP-B).

[0222] Any optional carrier polymer of the additives, of any fillers, of any nucleating agents, for example a masterbatch of the component together with its carrier polymer, is included in the amount of each component mentioned above relative to the amount of polypropylene composition (PP-B) (100%).

[0223] It is particularly preferred that the polypropylene composition (PP-B) does not have any pigments. The absence of pigments has been found to increase the transparency of layer (A), which helps to improve the power output of the bifacial photovoltaic module.

[0224] The polypropylene composition (PP-B) is preferably free of fillers as defined above.

[0225] It is particularly preferred that the polypropylene composition (PP-B) does not have any fillers or pigments as defined above.

[0226] In some embodiments, the polypropylene composition (PP-B) does not have a flame retardant as defined above.

[0227] The polypropylene composition may further comprise a further polymer component. The optional further polymer component may be any polymer other than the random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb), preferably a polyolefin-based polymer. Typical examples of further polymer components are either or both of plastomers or functionalised polymers, which have their well-known meanings.

[0228] If an optional plastomer is present, it is preferably a copolymer of ethylene with at least one C3-C10 alpha-olefin. If a plastomer is present, it preferably has one or all, preferably all, of the following characteristics: - 850-915, preferably 860-910 kg / m 3 density; - MFR2 between 0.1 and 50, preferably between 0.2 and 40 g / 10 min (190 ° C, 2.16 kg); and / or The alpha-olefin comonomer is octene.

[0229] If present, the optional plastomer is preferably produced using a metallocene catalyst, the term having its well-known meaning in the prior art. Suitable plastomers are commercially available, for example, plastomer products under the trade names QUEO™ supplied by Borealis, or Engage™ supplied by ExxonMobil, Lucene supplied by LG, or Tafmer supplied by Mitsui. If present, the amount of said optional plastomer is less than the amount of the polymer of propylene (PP-Ca).

[0230] If the optional functionalized polymer is present, it is a polymer functionalized, for example by grafting. For example, a polar functional group, such as maleic anhydride (MAH), can be grafted onto the polyolefin to form the functional polymer. The random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb) is different from the optional functionalized polymer. The random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb) does not have a grafted functional unit. That is, the term random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb) excludes a polymer of propylene grafted with a functional group. If present, the amount of said optional functionalized polymer is preferably 3-30 wt%, preferably 3-20 wt%, preferably 3-18 wt%, more preferably 4-15 wt%, based on the amount of the polypropylene composition (PP-B). When present, the amount of said optional functionalized polymer is less than the amount of the random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb).

[0231] The polypropylene composition (PP-B) preferably contains, relative to the total amount of the polypropylene composition (PP-B), - more than 25.0 wt. %, preferably 30.0-98.8 wt. %, preferably 30.0-98.5 wt. % of random copolymers of propylene (PP-Ba) or heterophasic copolymers of propylene (PP-Bb); - 0.2-5.0 wt. %, preferably 0.5-5.0 wt. % of additives; - 0-30.0 wt. %, preferably 0-25.0 wt. % of fillers; - 0 to 50.0 wt. % of a further polymer component different from a random copolymer of propylene (PP-Ba) or a heterophasic copolymer of propylene (PP-Bb); - 0 to 5.0 wt. %, preferably 0.0001 to 5.0 wt. %, of an α-nucleating agent, preferably 0.001 to 1.5 wt. %, particularly preferably 0.005 to 1.0 wt. % of an α-nucleating agent; and preferably consists of these.

[0232] The random copolymer of propylene (PP-Ba) or the heterophasic copolymer of propylene (PP-Bb) is then compounded in a known manner with the additives and optionally one or more of the optional components described above. Compounding can be carried out, for example, in a conventional extruder as described above, and the resulting molten mixture is fabricated into an article or, preferably, pelletized before use in an end-use application. Some or all of the additives or optional components described above may be added during the compounding process.

[0233] The polypropylene composition (PP-B) preferably has an MFR2 (230°C, 2.16 kg) of 1.0 to 20.0 / 10 min, more preferably 1.5 to 18 / 10 min, even more preferably 1.7 to 15 g / 10 min, and most preferably 2.0 to 12 g / 10 min.

[0234] The polypropylene composition (PP-B) of the present invention preferably has a cold xylene soluble component (XCS) content in an amount of 10 to 40 wt%, more preferably 15 to 35 wt%, and most preferably 15 to 30 wt%, based on the total amount of the polypropylene composition (PP-C).

[0235] The polypropylene composition (PP-B) has a Vicat softening temperature (Vicat A) of preferably 90 to 175°C, more preferably 95 to 165°C, even more preferably 100 to 160°C, and most preferably 105 to 155°C.

[0236] The polypropylene composition (PP-B) preferably has a melting temperature (Tm) of above 110°C, more preferably from 115 to 175°C, even more preferably from 120 to 175°C, and most preferably from 125 to 170°C.

[0237] The polypropylene composition (PP-B) has a crystallization temperature (Tc) of preferably 90 to 150°C, more preferably 95 to 145°C, even more preferably 100 to 140°C, and most preferably 100 to 135°C.

[0238] The polypropylene composition (PP-B) preferably has a flexural modulus of at least 500 MPa, more preferably from 550 to 3000 MPa, even more preferably from 600 to 2700 MPa, and most preferably from 650 to 2500 MPa.

[0239] The polypropylene composition (PP-B) preferably has a tensile modulus of at least 500 MPa, more preferably from 525 to 1500 MPa, measured in the machine direction from a 200 μm monolayer cast film.

[0240] The polypropylene composition (PP-B) preferably has a tensile strength of at least 20 MPa, more preferably from 25 to 75 MPa, measured in the machine direction from a 250 μm monolayer cast film.

[0241] The polypropylene composition (PP-B) preferably has a tensile strain at break of at least 450%, more preferably at least 500%, more preferably 510-1500%, and most preferably 520-1200%, as measured from a 200 μm monolayer cast film.

[0242] The layer (B) has a thickness of preferably 125 μm to 750 μm, more preferably 150 μm to 650 μm, and most preferably 200 μm to 550 μm.

[0243] The layer (B) with the polypropylene composition (PP-B) exhibits a high total light transmittance, which has been found to contribute to improving the power output of bifacial PV modules using the polypropylene composition (PP-B) in its backsheet element at the rear side of the photovoltaic element.

[0244] Layer (B) has a total light transmittance of at least 80%, preferably at least 85%, more preferably at least 89%.

[0245] The upper limit of the total light transmittance is usually 99% or less, preferably 97% or less.

[0246] In this respect, the total light transmittance depends not only on the optical properties of the polypropylene composition (PP-B), but also on the thickness of the layer: the thicker the layer, the lower the total light transmittance, of course.

[0247] For layers (B) having a thickness of 400 μm or less, the total light transmittance is preferably at least 85%, more preferably at least 90%, even more preferably at least 92%.

[0248] For layers (B) having a thickness of more than 400 μm, the total light transmittance is preferably at least 80%, more preferably at least 85%, even more preferably at least 89%.

[0249] Layer (B) preferably has a transparency of at least 50%, more preferably at least 60%, even more preferably at least 70%.

[0250] The upper limit of the transparency is usually 99% or less, preferably 97% or less.

[0251] Layer (B) preferably has a haze of less than or equal to 25%, more preferably less than or equal to 22%, and even more preferably less than or equal to 20%.

[0252] The lower limit of the haze is usually at least 0.5%, preferably at least 1.0%.

[0253] Layer (C) In one embodiment, the layer element comprises, in addition to layers (A) and (B), a layer (C).

[0254] Layer (C) comprises, and preferably consists of, a polyethylene composition (PE-C).

[0255] The polyethylene composition (PE-C) is - a copolymer of ethylene and a comonomer unit selected from one or more alpha-olefins having 3 to 12 carbon atoms (PE-Ca), having a viscosity of 850 kg / m 3 ~905kg / m 3 or a copolymer having a density of - a copolymer of ethylene and one or more comonomer units selected from alpha-olefins having 3 to 12 carbon atoms, further comprising silane group-containing units (PE-Cb), having a viscosity of 850 kg / m 3 ~905kg / m 3 or a copolymer having a density of - a copolymer of ethylene and comonomer units selected from one or more alpha-olefins having 3 to 12 carbon atoms, further comprising functional group-containing units derived from at least one of unsaturated carboxylic acids and / or their anhydrides, metal salts, esters, amides or imides and mixtures thereof (PE-Cc), having a molecular weight of 850 kg / m 3 ~905kg / m 3 a copolymer having a density of The copolymer of ethylene is selected from the group consisting of:

[0256] All of the alternative ethylene copolymers (PE-Ca), (PE-Cb) and (PE-Cc) have comonomer units selected from one or more alpha-olefins having from 3 to 12 carbon atoms.

[0257] Suitable alpha-olefins having 3 to 12 carbon atoms include 1-butene, 1-hexene and 1-octene, preferably 1-butene or 1-octene, more preferably 1-octene.

[0258] Preferably, a copolymer of ethylene and 1-octene is used.

[0259] The copolymer of ethylene (PE-Cb) differs from the copolymer of ethylene (PE-Ca) in that it further comprises a silane group-containing unit (PE-Cb).

[0260] The silane group-containing units are preferably grafted onto the polymer backbone of the copolymer of ethylene (PE-Cb).

[0261] Preferably, the silane group-containing units of the copolymer of ethylene (PE-Cb) are independently the same as the silane group-containing units of said copolymer of ethylene (PE-Aa) or said copolymer of ethylene (PE-Ab).

[0262] Thus, all of the aspects and amounts described above for the silane group-containing units of the ethylene copolymer (PE-Aa) or the ethylene copolymer (PE-Ab) also apply independently to the silane group-containing units (PE-Cb), except that the silane group-containing units are preferably grafted onto the polymer backbone of the ethylene copolymer (PE-Cb).

[0263] The ethylene copolymer (PE-Cb) is preferably a copolymer of ethylene and 1-butene, a copolymer of ethylene and 1-hexene or a copolymer of ethylene and 1-octene to which silane group-containing units have been grafted, and most preferably a copolymer of ethylene and 1-octene to which silane group-containing units have been grafted.

[0264] The ethylene copolymer (PE-Cb) is preferably a copolymer of ethylene and 1-butene, a copolymer of ethylene and 1-hexene or a copolymer of ethylene and 1-octene, to which a silane group-containing unit selected from vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane, more preferably vinyltrimethoxysilane or vinyltriethoxysilane, is grafted, and more preferably a copolymer of ethylene and 1-octene to which a silane group-containing unit selected from vinyltrimethoxysilane, vinylbismethoxyethoxysilane, vinyltriethoxysilane, more preferably vinyltrimethoxysilane or vinyltriethoxysilane, is particularly preferred.

[0265] Most preferred is a copolymer of ethylene and 1-octene grafted with vinyltrimethoxysilane.

[0266] The copolymer of ethylene (PE-Ca) is preferably a copolymer of ethylene and 1-butene, a copolymer of ethylene and 1-hexene or a copolymer of ethylene and 1-octene, most preferably a copolymer of ethylene and 1-octene.

[0267] The copolymer of ethylene (PE-Cc) differs from the copolymer of ethylene (PE-Ca) in that it further comprises functional group-containing units derived from at least one of an unsaturated carboxylic acid and / or its anhydride, metal salt, ester, amide or imide, and mixtures thereof (PE-Cc).

[0268] The functional group-containing units are preferably grafted onto the polymer backbone of the copolymer of ethylene (PE-Cc).

[0269] The functional group-containing units are preferably derived from a compound selected from the group consisting of maleic anhydride, acrylic acid, methacrylic acid, crotonic acid, fumaric acid, fumaric anhydride, maleic acid, citraconic acid, and mixtures thereof, and are preferably derived from maleic anhydride.

[0270] The amount of the functional group-containing units present in the ethylene copolymer (PE-Cc) is preferably within the range of 0.01 to 1.5 mol%, more preferably 0.01 to 1.00 mol%, even more preferably 0.02 to 0.80 mol%, still more preferably 0.02 to 0.60 mol%, and most preferably 0.03 to 0.50 mol%, based on the total amount of monomer units in the ethylene copolymer (PEC-c).

[0271] The ethylene copolymer (PE-Cc) is preferably a copolymer of ethylene and 1-butene, a copolymer of ethylene and 1-hexene or a copolymer of ethylene and 1-octene to which functional group-containing units have been grafted, most preferably a copolymer of ethylene and 1-octene to which functional group-containing units have been grafted.

[0272] The copolymers of ethylene (PE-Cc) are preferably copolymers of ethylene and 1-butene, copolymers of ethylene and 1-hexene or copolymers of ethylene and 1-octene grafted with functional group-containing units derived from maleic anhydride, acrylic acid, methacrylic acid, crotonic acid, fumaric acid, fumaric anhydride, maleic acid, citraconic acid and mixtures thereof, more preferably maleic anhydride, and more preferably copolymers of ethylene and 1-octene grafted with functional group-containing units derived from maleic anhydride, acrylic acid, methacrylic acid, crotonic acid, fumaric acid, fumaric anhydride, maleic acid, citraconic acid and mixtures thereof, most preferably maleic anhydride.

[0273] In a preferred embodiment, the polyethylene composition (PE-C) comprises - a copolymer of ethylene and a comonomer unit selected from one or more alpha-olefins having 3 to 12 carbon atoms (PE-Ca), having a viscosity of 850 kg / m 3 ~905kg / m 3 or a copolymer having a density of - a copolymer of ethylene and one or more comonomer units selected from alpha-olefins having 3 to 12 carbon atoms, further comprising silane group-containing units (PE-Cb), having a molecular weight of 850 kg / m 3 ~905kg / m 3 a copolymer having a density of; The copolymer of ethylene is selected from the group consisting of:

[0274] The following properties characterize all the selected ethylene copolymers (PE-Ca), (PE-Cb) and (PE-Cc):

[0275] The copolymer of ethylene is preferably an ethylene-based plastomer.

[0276] The ethylene copolymer has a viscosity of 850 to 905 kg / m 3within the range of 855 to 900 kg / m 3 within the range of 860 to 895 kg / m 3 in the range of 865 to 890 kg / m 3 The density is in the range of

[0277] The MFR2 of the ethylene copolymer is preferably less than 20 g / min, more preferably less than 15 g / 10 min, even more preferably 0.1 to 13 g / 10 min, even more preferably 0.5 to 10 g / 10 min, and most preferably 0.8 to 8.0 g / 10 min.

[0278] The melting temperature of the ethylene copolymer is preferably less than 130°C, preferably less than 120°C, more preferably less than 110°C, and most preferably less than 100°C.

[0279] Furthermore, the copolymers of ethylene preferably have a glass transition temperature Tg (measured by DMTA according to ISO 6721-7) of less than -25°C, preferably less than -30°C, more preferably less than -35°C.

[0280] The ethylene copolymer preferably has an ethylene content of 55.0 to 95.0 wt %, preferably 60.0 to 90.0 wt %, more preferably 65.0 to 88.0 wt %.

[0281] The molecular weight distribution Mw / Mn of the ethylene copolymers is in most cases less than 4.0, for example 3.8 or less, but at least 1.7, preferably between 3.5 and 1.8.

[0282] The copolymer of ethylene can be any copolymer of ethylene having the characteristics defined above, which are in particular commercially available from Borealis under the trade name Queo, from DOW under the trade name Engage or Affinity or from Mitsui under the trade name Tafmer.

[0283] Alternatively, copolymers of ethylene can be produced by known processes in the presence of a suitable catalyst, such as vanadium oxide catalysts or single-site catalysts, such as metallocene or constrained geometry catalysts, known to those skilled in the art, in a one or two stage polymerization process having solution polymerization, slurry polymerization, gas phase polymerization or combinations thereof.

[0284] Suitable polymerization processes are described in WO2019 / 134904.

[0285] The polyethylene composition (PE-C) preferably comprises the ethylene copolymer (PE-Ca), (PE-Cb) or (PE-Cc) in an amount of 30.0 wt% to 100 wt%, more preferably 30.0 wt% to 99.9999 wt%, even more preferably 40.0 wt% to 99.999 wt%, and most preferably 50.0 wt% to 99.99 wt%, based on the total weight of the polyethylene composition (PE-C).

[0286] The amount of ethylene copolymer (PE-Ca), (PE-Cb) or (PE-Cc) in the polyethylene composition (PE-C) depends on the above-mentioned further components in the polyethylene composition (PE-C).

[0287] The polyethylene composition (PE-C) preferably comprises additives other than fillers, pigments, carbon black or flame retardants, these terms having the meanings known in the prior art.

[0288] The optional additives are preferably independently selected from the list of additives described above for the polyethylene composition (PE-A) and in the amounts described above.

[0289] The polyethylene composition (PE-C) may further comprise a polymer different from the copolymer of ethylene (PE-Ca), (PE-Cb) or (PE-Cc).

[0290] The optional polymer is preferably selected from propylene-based polymers or ethylene-based polymers or mixtures thereof.

[0291] The optional propylene-based polymer is preferably selected from propylene-alpha-olefin random copolymers and heterophasic copolymers of propylene or mixtures thereof.

[0292] The optional ethylene-based polymer is preferably selected from ethylene-alpha-olefin copolymers or mixtures thereof.

[0293] The amount of polymer other than the ethylene copolymer (PE-Ca), (PE-Cb) or (PE-Cc) is preferably at most 50.0 wt%, for example in the range of 0.1 to 50.0 wt%, preferably 0.5 to 30.0 wt%, most preferably 1.0 to 10.0 wt%, based on the total weight of the polyethylene composition (PE-C).

[0294] The polyethylene composition (PE-C) is preferably free of pigments and / or flame retardants.

[0295] The polyethylene composition (PE-C) is preferably free of fillers as defined above or below for layers (A) and (B).

[0296] It is particularly preferred that the polyethylene composition (PE-C) is free of fillers, pigments and / or flame retardants.

[0297] In one embodiment, the polyethylene composition (PE-C) comprises, relative to the amount (100 wt%) of the polyethylene composition (PE-C), - 90.0 to 99.9999 wt.%, preferably 95.0 to 99.999 wt.%, most preferably 97.5 to 99.99 wt.% of said copolymer of ethylene; and - 0.0001 to 10.0 wt. %, preferably 0.001 and 5.0 wt. %, most preferably 0.01 and 2.5 wt. % of said additives; and preferably consists of these.

[0298] In this embodiment, the polyethylene composition (PE-C) typically has the same ranges of properties as melt flow rate MFR2, density, melting temperature Tm and glass transition temperature Tg as defined above for the copolymers of ethylene (PE-Ca), (PE-Cb) or (PE-Cc).

[0299] In another embodiment, the polyethylene composition (PE-C) comprises an additive as defined above and one or more polymers as defined above, different from the ethylene copolymers (PE-Ca), (PE-Cb) or (PE-Cc), in which case the polyethylene composition (PE-C) comprises, relative to the total amount (100 wt%) of the polyethylene composition (PE-C), - 40.0 to 99.8999 wt.%, preferably 65.0 to 99.499 wt.%, most preferably 87.5 to 98.99 wt.% of said copolymer of ethylene; - 0.0001 to 10.0 wt. %, preferably 0.001 and 5.0 wt. %, most preferably 0.01 and 2.5 wt. % of the above additives; and - 0.1 to 50.0 wt. %, preferably 0.5 to 30.0 wt. %, most preferably 1.0 to 10.0 wt. % of said one or more different polymers; and preferably consists of these.

[0300] In the presence of one or more different polymers, the properties of the polyethylene composition (PE-C) are usually influenced not only by the properties of the ethylene copolymer, but also by the properties of the one or more different polymers, and therefore may differ from the properties of the ethylene copolymer (PE-Ca), (PE-Cb) or (PE-Cc).

[0301] Preferably, layer (C) of said layer element consists of a polyethylene composition (PE-C) comprising a copolymer of ethylene as defined above, below or in the claims.

[0302] Layer (C) preferably has a thickness of 50 μm to 500 μm, preferably 75 μm to 400 μm, most preferably 100 μm to 300 μm.

[0303] Method for manufacturing layer elements The present invention further provides a method for the manufacture of a layer element as defined above or below, comprising the following steps: - bonding layers (A), (B) and, optionally, layer (C) of said layer element by extrusion or lamination to form the configuration AB or ACB; and - Recovering the formed layer elements.

[0304] In one embodiment, layers (A) and (B) or layers (A), (B) and (C) of the layer element are produced by extrusion, preferably coextrusion.

[0305] The term "extrusion" as used herein means that at least two layers of the layer element can be extruded in separate steps or in the same extrusion step, as is well known in the art. One and preferred embodiment of the "extrusion" process for producing at least three layers of the layer element is a coextrusion process. The term "coextrusion" as used herein means that at least two layers of the layer element, such as layers (A) and (B), or at least three layers (A), (B) and (C), can be coextruded in the same extrusion step, as is well known in the art. The term "coextrusion" as used herein means that in addition to the at least two layers (A) and (B) and optionally (C), if all or part of the further layers described above of the layer element are present, such further layers can also be formed simultaneously using one or more extrusion heads.

[0306] The extrusion, and preferably co-extrusion steps, can be carried out, for example, using blown film or cast film extrusion processes, both of which are well known and well described in the art literature.

[0307] Moreover, the extrusion process, and preferably the coextrusion process, can be carried out in any conventional film extruder, preferably in a conventional cast film extruder, such as a single screw or twin screw extruder. Extrusion equipment, such as cast film extrusion equipment, is well described in the literature and is commercially available.

[0308] Other suitable extrusion techniques suitable for the manufacture of the layer elements of the present invention are extrusion processes such as blown-film extrusion, for example blown-film coextrusion, cast-film extrusion processes, preferably cast-film coextrusion processes with a subsequent calendering process, which techniques are well known in the art.

[0309] Extrusion conditions can be selected by one skilled in the art depending on the layer materials selected.

[0310] Preferably, the extrusion, preferably coextrusion, of the layer elements is carried out by cast film extrusion, preferably cast film coextrusion.

[0311] In the extrusion embodiment, in the case of an adhesive layer between the adhesive sides of the first and second layers, the adhesive layer is typically extruded or coextruded during the extrusion process of the first and second layers.

[0312] Part or all of the optional further layers of the layer element can be extruded, for example coextruded, on the side of layer (A) or layer (B), or on the side of both layers (A) and (B) that is not in adhesive contact with layer (A), (B) or one of the previously described optional layers (C). The extrusion of the optional further layers can be carried out during the extrusion, preferably coextrusion step, of layers (A) and (B). Alternatively, or in addition, part or all of the optional further layers can be laminated on the opposite side of one or both of layers (A) and (B) after the extrusion, preferably coextrusion step, of layers (A), (B) and optional layer (C).

[0313] In another embodiment, the layer element is produced by laminating at least two of the layers (A), (B) and optional layer (C) into adhesive contact. The lamination is carried out in a conventional lamination process using conventional lamination equipment well known in the art. In a typical lamination process, the separately formed layers of the layer element are arranged to form the layer element assembly; the layer element assembly is then subjected to a heating step, typically under reduced pressure in a lamination chamber; the layer element assembly is then subjected to a pressurizing step, in which the pressure on the layer element assembly is elevated and maintained under heated conditions to cause lamination of the assembly; the layer element is then subjected to a recovery step, in which the resulting layer element is cooled and removed.

[0314] Similarly, in another lamination embodiment, in addition to layers (A), (B) and optional layer (C), the layer element may have an additional layer on the side opposite to the adhesive side of one or both of layers (A) and (B). In this case, part or all of the optional additional layer of the layer element may be laminated and / or extruded on the side of layer (A) or (B), or on the side of both layers (A) and (B) that is not in adhesive contact with layer (A), (B) or one of the optional layers (C) described above. The extrusion of the optional additional layer may be carried out before the lamination of at least two layers (A), (B) and optional layer (C). The lamination of the optional additional layer may be carried out in a step prior to the lamination of at least two layers (A), (B) and optional layer (C), during the lamination of at least two layers (A), (B) and optional layer (C), or after the lamination of at least two layers (A), (B) and optional layer (C).

[0315] In another embodiment where at least two of layers (A), (B) and optional layer (C) are produced by lamination, layer (C) is applied to the surface of layer (A) or to the surface of layer (B) using known techniques.

[0316] If necessary, the formed layer element can be subjected to further treatments, for example to improve the adhesion of the layer element or to modify the outer surface of the layer element, for example the outer sides (opposite the "glue" sides) of layers (A) and (B) or, in the case of producing the layer element by lamination, also the "glue" sides of the layers to be laminated, can be surface treated using conventional techniques and equipment well known to those skilled in the art.

[0317] The most preferred process for the production of the layer element of the present invention is the extrusion process, preferably the coextrusion process. More preferably, the extrusion process for the production of said layer element is a cast film extrusion, most preferably a cast film coextrusion process.

[0318] The extrusion process is particularly suitable for the manufacture of layer elements in which the polymers of the different layers exhibit similar melting temperatures. This means that coextrusion is particularly suitable when ethylene copolymers (PE-Aa) and (PE-Ab) are used in layer (A). Coextrusion is generally not suitable for layer elements in which ethylene copolymers (PE-Ac) are used in layer (A), especially when they are crosslinked.

[0319] Thus, a preferred process for the production of the layer elements of the present invention is an extrusion process, preferably a coextrusion process, comprising the following steps: - mixing in separate mixing devices, preferably melt-mixing in separate extruders, the polyethylene composition (PE-A) of layer (A), preferably comprising one of the copolymers of ethylene (PE-Aa) or (PE-Ab), the polypropylene composition (PP-B) of layer (B) and, optionally, the polyethylene composition (PE-C) of layer (C); - producing at least distinct layers (A) and (B) and optionally (C), or coextruded layers (B) and (C), in which at least distinct layers (A) and layers (B) and (C) are in adhesive contact with each other to form a structure BC; - laminating at least said separate layers (A) and (B) to form a layer element of at least layers (A) and (B) in which layers A and B are in adhesive contact with one another to form the structure AB, or laminating at least separate layers (A), (B) and (C) to form the structure ACB in which layers (A) and (C) as well as layers (B) and (C) are in adhesive contact with one another, or laminating at least separate layers (A) and layers (B) and (C) which are coextruded to form the structure BC to form the structure ACB in which layers (A) and (C) as well as layers (B) and (C) are in adhesive contact with one another; - Recovering the layer elements obtained.

[0320] As is well known, a melt mixture of the polymer composition or its components is used to form the layers. Melt mixing means herein mixing at a temperature higher than the melting or softening point of at least the main polymeric component of the resulting mixture, for example but not limited to at least 10-15° C. higher than the melting or softening point of the polymeric component. This mixing step can be carried out in an extruder, for example a film extruder, for example a cast film extruder. The melt mixing step may comprise a separate mixing step in a separate mixer, for example a kneader connected before the extruder of the layer element production line. The mixing in said preceding separate mixer can be carried out by mixing with or without external heating (heating by an external source) of the components.

[0321] In the above preferred processes, the extrusion process is preferably a cast film extrusion, preferably a cast film coextrusion process. The extrusion process can also be a blown film extrusion process, preferably a blown film coextrusion process, or an extrusion process with a subsequent calendering process, such as a cast film extrusion process, preferably a cast film coextrusion process.

[0322] As already mentioned, the extrusion process for forming the layer element of the present invention may also comprise further steps after extrusion, such as further processing steps or lamination steps preferably following the extrusion step described above.

[0323] In another preferred embodiment, the layer elements are produced by lamination as described above. This lamination process is particularly suitable for layer elements in which the polymers of the different layers exhibit different melting temperatures. This means that coextrusion is particularly suitable when copolymers of ethylene (PE-Ac) are used in layer (A), especially when they are crosslinked.

[0324] Thus, a preferred process for the manufacture of the layer element of the present invention is a lamination process comprising the following steps: - mixing in separate mixing devices, preferably melt-mixing in separate extruders, the polyethylene composition of layer (A) (PE-A), preferably comprising a copolymer of ethylene (PE-Ac), the polypropylene composition of layer (B) (PP-B) and, optionally, the polyethylene composition of layer (C) (PE-C); - applying, preferably simultaneously, said molten mixture of the polyethylene composition of layer (A) (PE-A), the polypropylene composition of layer (B) (PP-B) and, optionally, the polyethylene composition of layer (C) (PE-C) by means of a die to form a layer element of at least layers (A) and (B), in which layers A and B are in adhesive contact with one another to form the configuration AB, or to form a layer element of at least layers (A), (B) and (C), in which layers (A) and (C) as well as layers (B) and (C) are in adhesive contact with one another to form the configuration ACB; - Recovering the layer elements obtained.

[0325] As is well known, a melt mixture of the polymer composition or its components is used to form the layers. Melt mixing means herein mixing at a temperature higher than the melting or softening point of at least the main polymeric component of the resulting mixture, for example but not limited to at least 10-15° C. higher than the melting or softening point of the polymeric component. This mixing step can be carried out in an extruder, for example a film extruder, for example a cast film extruder. The melt mixing step may comprise a separate mixing step in a separate mixer, for example a kneader connected before the extruder of the layer element production line. The mixing in said preceding separate mixer can be carried out by mixing with or without external heating (heating by an external source) of the components.

[0326] Goods The article having the layer element can be any article in which the properties of the layer element of the present invention are, for example, desirable or suitable.

[0327] The layer elements can be part of an article or can form the article, such as a film.

[0328] Examples of such articles include, but are not limited to, extruded articles or molded articles or combinations thereof. For example, molded articles may be for any type of packaging (including boxes, cases, containers, bottles, etc.), for household applications, for vehicle parts, for construction, and for electronics. Extruded articles can be, for example, different types of films for any purpose, such as plastic bags or packaging (e.g., wrappers, shrink films, etc.); any type of electronics; pipes, etc., with the above layer elements. A combination of molded and extruded articles is, for example, a molded container or bottle with an extruded label with the above layer elements.

[0329] In one embodiment, the article is a multilayer film having, preferably consisting of, the layer elements. In this embodiment, the layer elements of the article are preferably films for various end uses, such as, but not limited to, packaging applications. In the present invention, the term "film" also includes thicker sheet structures, such as for thermoforming.

[0330] In a second embodiment, the article is an assembly having two or more layer elements, at least one of which is a layer element of the invention. The further layer elements of the assembly can be different from or the same as the layer elements of the invention.

[0331] The second embodiment is the preferred embodiment of the invention.

[0332] The assembly of the second preferred embodiment is preferably a photovoltaic (PV) module comprising a photovoltaic element and one or more further layer elements, at least one layer element being a layer element according to the invention.

[0333] The preferred photovoltaic (PV) module of the present invention comprises, in that order, a protective front layer element, preferably a glass layer element, a front encapsulation layer element, a photovoltaic element and a layer element (LE) of the present invention.

[0334] In this preferred embodiment, the layer element of the present invention is multifunctional, i.e., the layer element of the present invention functions as a rear encapsulation layer element and as a protective back layer element. More preferably, layer (A) functions as an encapsulation layer element and layer (B) functions as a protective back layer element, also referred to herein as a backsheet layer element. Optional layer (C) functions as an adhesive layer, improving the adhesion between the encapsulation layer element and the protective back layer element. Of course, as described above in "Layer element of the present invention", there may be additional layers attached to the outer surface of layer (A) to enhance the "encapsulation layer element" function. Furthermore, of course, there may be additional layers attached to the outer surface of layer (B) to enhance the "protective back layer element" function. Such additional layers can be introduced into layers (A) and (B), respectively, by extrusion, for example coextrusion, or by lamination, or by combinations thereof in any order.

[0335] In the above preferred photovoltaic (PV) modules of the invention, the side of layer (A) opposite that which is adhered to layer (B) or optional layer (C) is preferably in adhesive contact with the photovoltaic element of the PV module.

[0336] Furthermore, as is known in the art for backsheet layer elements of PV modules, the side of layer (B) opposite to the side adhering to layer (A) or optional layer (C) can be in adhesive contact with a further layer or layer element.

[0337] The final photovoltaic module can be rigid or flexible.

[0338] Furthermore, the final PV module of the present invention may be placed in a metal frame, for example aluminum.

[0339] All such terms have their known meanings in the art.

[0340] The raw materials of the above elements other than the layer elements of the present invention are well known in the prior art and can be selected by the skilled artisan depending on the desired PV module.

[0341] The above-exemplified layer elements other than the layer element of the present invention can be single layer or multilayer elements, and furthermore, the other layer elements or parts of the layers thereof can be produced by extrusion, for example coextrusion, by lamination, or by a combination of extrusion and lamination in any order, depending on the desired end use, as is well known in the art.

[0342] By "photovoltaic element" is meant that the element has photovoltaic activity. The photovoltaic element can be, for example, an element of a photovoltaic cell, with the meaning known in the art. Silicon-based materials, such as crystalline silicon, are non-limiting examples of materials used in photovoltaic cells. As known to those skilled in the art, crystalline silicon materials can vary in terms of crystallinity and crystal size. Alternatively, the photovoltaic element can be a substrate layer provided on one surface with a further layer or deposit with photovoltaic activity, for example a glass layer printed on one side with an ink material with photovoltaic activity, or a substrate layer on one side with a material with photovoltaic activity deposited. For example, in the known thin layer solution of photovoltaic elements, for example an ink with photovoltaic activity is printed on one side of a substrate, typically a glass substrate.

[0343] The photovoltaic element is most preferably an element of a photovoltaic cell.

[0344] By "photovoltaic cell" herein is meant the layer elements of the photovoltaic cell described above together with the connectors.

[0345] The detailed description given above of the layer elements of the present invention applies to the layer elements present in the article, preferably a photovoltaic module.

[0346] In some embodiments of the PV module, adhesive layers may be present between different layer elements and / or between layers of a multi-layer element, as is well known in the art. Such adhesive layers have the function of improving the adhesion between two elements and have a well-known meaning in the lamination field. As will be clear to a person skilled in the art, the adhesive layers are distinct from other functional layer elements of the PV module, such as those specified above, below or in the claims.

[0347] Preferably, there is no adhesive layer between the photovoltaic element and the front encapsulation layer element. Alternatively, there is preferably no adhesive layer between the photovoltaic layer element and the layer element of the invention. More preferably, there is no adhesive layer between the photovoltaic element and the front encapsulation layer element, and there is no adhesive layer between the photovoltaic layer element and the layer element of the invention.

[0348] As is well known in the PV field, the thicknesses of the above elements as well as any further elements of the article of the present invention, preferably of the laminated photovoltaic module, can vary depending on the desired end use application, e.g., the desired embodiment of the photovoltaic module, and can be selected accordingly by those skilled in the PV field.

[0349] The thickness of a photovoltaic element, such as a single crystal photovoltaic cell, is typically between 100 and 500 microns, but is not limited thereto.

[0350] Layer (A) of the layer element of the photovoltaic (PV) module of the invention preferably serves as a rear encapsulation layer element, the thickness of which can of course vary depending on the desired PV module, as will be clear to the skilled person. Typically, the thickness of layer (A) is as defined above. The rear encapsulation layer element can have, in addition to layer (A), a further layer (X), the thickness of which, if present, can usually be up to 2 mm, preferably up to 1 mm, typically 0.15 to 0.6 mm. Of course, as already stated, the thickness depends on the desired end use and can be selected by the skilled person.

[0351] Similarly, the layer (B) of the layer element preferably serves as a protective back layer element (backsheet element) of the photovoltaic (PV) module of the invention or as part of such a protective back layer element, the thickness of which is generally as defined above. The protective back layer element may have, in addition to the layer (B), a further layer (Y), the thickness of which may of course vary depending on the desired application of the PV module, as will be clear to the skilled person. The thickness of the protective back layer element of the preferred PV module, if layer (Y) is present, may generally be up to 2 mm, preferably up to 1 mm, typically 0.15 to 0.6 mm, but is not limited thereto. Of course, as already stated, the thickness may vary depending on the desired end application and may be selected by the skilled person.

[0352] Photovoltaic modules comprising a layer element according to the invention are preferably bifacial photovoltaic modules, which means that the photovoltaic cells of said photovoltaic element produce photovoltaic activity on their front side and on their rear side.

[0353] In the above bifacial photovoltaic modules, the photovoltaic cells preferably have terminals / busbars on both their front and rear sides.

[0354] A bifacial photovoltaic module comprising a layer element of the present invention exhibits good power output on both the front and rear sides of the photovoltaic element.

[0355] Preferably, the bifacial photovoltaic module has one or more of the following characteristics: When measured by flash test on the front and rear sides of the photovoltaic element, a short circuit current I of at least 5.00 A, preferably at least 5.50 A, more preferably at least 5.80 A, even more preferably at least 6.50 A, typically at most 12.00 A, preferably at most 10.00 A; sc ; an open circuit voltage V of at least 0.60 V, preferably at least 0.62 V, more preferably at least 0.63 V, even more preferably at least 0.65 V, typically at most 0.80 V, preferably at most 0.75 V; oc ; a fill factor FF of at least 65.00%, preferably at least 67.00%, more preferably at least 69.00%, even more preferably at least 70.00%, typically at most 85.00%, preferably at most 80.00%; or a maximum power output P of at least 2.50 W, preferably at least 2.75 W, more preferably at least 3.00 W, even more preferably at least 3.25 W, typically at most 5.50 W, preferably at most 5.00 W; max .

[0356] At the front side of the photovoltaic elements, the bifacial photovoltaic module preferably has one or more of the following characteristics: When measured by flash testing on the front side of the photovoltaic element, a short circuit current I of at least 8.00 A, preferably at least 8.50 A, more preferably at least 8.75 A, typically at most 12.00 A, preferably at most 10.00 A; sc; an open circuit voltage V of at least 0.60 V, preferably at least 0.62 V, more preferably at least 0.63 V, typically at most 0.80 V, preferably at most 0.75 V oc ; a fill factor FF of at least 65.00%, preferably at least 67.00%, more preferably at least 69.00%, even more preferably at least 70.00%, typically at most 85.00%, preferably at most 80.00%; or a maximum power output P of at least 3.50 W, preferably at least 3.75 W, more preferably at least 4.00 W, typically at most 5.50 W, preferably at most 5.00 W; max .

[0357] At the rear side of the photovoltaic elements, the bifacial photovoltaic module preferably has one or more of the following characteristics: When measured by flash test at the rear side of the photovoltaic element, a short circuit current I of at least 5.00 A, preferably at least 5.50 A, more preferably at least 5.80 A, even more preferably at least 6.50 A, typically at most 10.00 A, preferably at most 8.00 A; sc ; an open circuit voltage V of at least 0.60 V, preferably at least 0.62 V, more preferably at least 0.63 V, even more preferably at least 0.65 V, typically at most 0.80 V, preferably at most 0.75 V; oc ; a fill factor FF of at least 70.00%, preferably at least 71.50%, more preferably at least 72.50%, even more preferably at least 74.00%, typically at most 85.00%, preferably at most 80.00%; or a maximum power output P of at least 2.50 W, preferably at least 2.75 W, more preferably at least 3.00 W, even more preferably at least 3.25 W, typically at most 4.50 W, preferably at most 4.00 W; max .

[0358] The bifacial photovoltaic modules with the layer elements of the present invention surprisingly show the same power output at the rear side of the photovoltaic elements as bifacial photovoltaic modules with a glass element as a rear protective element, but are lighter and are faster to stack. The general handling of the bifacial photovoltaic modules with the layer elements of the present invention can also be carried out with less effort than bifacial photovoltaic modules with a glass element as a rear protective element.

[0359] Compared to bifacial photovoltaic modules having a different polymer material (e.g., PET or fluoropolymer) as a rear protective element, bifacial photovoltaic modules having the layer elements of the present invention have improved adhesion of the backsheet layer element (in this case layer (B)) to the rear encapsulation layer element (in this case layer (A)) and good reusability.

[0360] Furthermore, the layer elements of the invention exhibit poorer optical properties in terms of haze and transparency, as measured on laminates produced as described in the Examples section, compared to the optical properties of layer (B). However, it has surprisingly been found that, despite the poor optical properties of the layer elements of the invention, bifacial PV modules using said layer elements on the rear side of the photovoltaic element, as already described, exhibit an unexpectedly improved power output of the bifacial PV module. The reason for this surprising effect appears to be the surprisingly high light transmission of the layer elements of the invention, as measured on laminates produced as described in the Examples section.

[0361] The layer elements of the article, preferably of the photovoltaic module, can be produced as described above for the layer elements of the invention.

[0362] Said separate further elements of the PV module other than the layer elements of the invention can be produced by methods well known in the photovoltaic art or are commercially available.

[0363] Method for manufacturing a photovoltaic module The present invention further provides a method for manufacturing an assembly of the present invention, the method comprising the steps of: - assembling the layer element of the invention and the further layer element into an assembly; - laminating the elements of the assembly at elevated temperature to bond the elements together; and - recovering the resulting assembly.

[0364] The layer elements can be provided to the assembly process separately or, alternatively, parts of the layer elements or parts of layers of two layer elements can already be adhered to one another, i.e. integrated, before being provided to the assembly process.

[0365] A preferred method for manufacturing the above assembly comprises the steps of: - assembling said photovoltaic element, the layer element of the invention and any further layer elements into a photovoltaic (PV) module assembly; - laminating the layer elements of the photovoltaic (PV) module assembly at elevated temperature to bond the elements together; and - recovering the resulting photovoltaic (PV) modules; This is a method for manufacturing photovoltaic (PV) modules by

[0366] Conventional conditions and conventional equipment are well known and have been described in the art of photovoltaic modules and can be selected by one of ordinary skill in the art.

[0367] As mentioned above, parts of the layer elements may be in integrated form, i.e. two or more of the PV elements may be integrated, for example by lamination, before being subjected to the lamination process of the present invention.

[0368] A preferred embodiment of the method for forming the preferred photovoltaic (PV) modules of the present invention is a lamination process having the following steps: - an assembly step of arranging a photovoltaic element and a layer element of the invention to form a multilayer assembly, with layer (A) of said layer element being placed in contact with said photovoltaic element, preferably an assembly step of arranging a front protective layer element, a front encapsulation layer element, a photovoltaic element and a layer element of the invention in the stated order to form a multilayer assembly, with layer (A) of said layer element being placed in contact with the photovoltaic element; - a heating step of heating the formed PV module assembly, optionally and preferably in a chamber under reduced pressure; - applying and maintaining an elevated pressure on the PV module assembly under heated conditions to cause lamination of the assembly; and - A recovery step in which the resulting PV module with said layer elements is cooled and removed.

[0369] The lamination process can be carried out in a lamination machine, which can be, for example, any conventional laminator suitable for laminating multi-laminates, such as laminators conventionally used in PV module manufacturing. The choice of laminator is within the skill of the person skilled in the art. Typically, a laminator has a chamber in which the steps of heating, optionally and preferably evacuating, pressurizing, and recovering (including cooling) are carried out.

[0370] use Use of a layer element of the invention as defined above or below as an integrated backsheet element of a double-sided photovoltaic module comprising a photovoltaic element and said layer element, said photovoltaic element being in contact with layer (A) of said layer element.

[0371] In this respect, said layer elements and said photovoltaic modules preferably have the properties and definitions of the layer elements and photovoltaic modules described above or below. EXAMPLES

[0372] Measurement method Melt flow rate: The melt flow rate (MFR) is measured according to ISO 1133 and is expressed in g / 10 min. The MFR is a measure of the flowability and therefore processability of a polymer. The higher the melt flow rate, the lower the viscosity of the polymer. The MFR2 of polypropylene is measured at a temperature of 230°C and a load of 2.16 kg. The MFR2 of polyethylene is measured at a temperature of 190°C and a load of 2.16 kg.

[0373] Density: ISO 1183, measured on compression moulded plaques.

[0374] Comonomer Content: The content (wt% and mol%) of polar comonomers present in the copolymers of ethylene (PE-Ab) and the content (wt% and mol%) of silane group-containing units present in the copolymers of ethylene (PE-Aa), (PE-Ab) and (PE-Ac) were determined as described in WO 2018 / 141672 for the content (wt% and mol%) of polar comonomers present in polymer (a) and the content (wt% and mol%) of silane group-containing units (preferably comonomers) present in polymer (a).

[0375] The alpha-olefin comonomer content present in the copolymers of ethylene (PE-Ca), (PE-Cb) and (PE-Cc) was determined as described in WO2019 / 134904 for the comonomer content determination of poly(ethylene-co-1-octene) copolymers.

[0376] The comonomer content present in the propylene polymer (PP-Ba) was determined as described in WO2017 / 071847 for determining the comonomer content.

[0377] Rheological properties: Dynamic shear measurement (frequency sweep measurement) Rheological properties are measured as described in WO2018 / 141672.

[0378] Melting temperature (T m ) and heat of fusion (H f ) was measured as described in WO2018 / 141672.

[0379] Xylene cold solubles (XCS) were measured as described in WO2018 / 141672.

[0380] The Vicat softening temperature was measured according to ASTM D 1525 Method A (50° C. / h, 10 N).

[0381] Tensile modulus; tensile stress at yield and tensile strain at break were measured as described in WO2018 / 141672.

[0382] Flexural modulus was measured as described in WO2017 / 071847.

[0383] Production of monolayer and trilayer films: Monolayer cast films of the invention with a thickness of 250 or 450 μm were produced on a Dr Collin extruder with 5 heating zones, equipped with a PP screw with a diameter of 30 mm and a LD of 30, a 300 mm die with a die gap of 0.5 mm. A melt temperature of 250° C. and a chill roll temperature of 20° C. were used.

[0384] Three-layer coextruded film samples of the invention were produced on a Dr. Collin cast film line consisting of three automatically controlled extruders, a chill roll unit, a take-off unit with cut-off stations, and three winders for winding up the film and edge strips.

[0385] Each layer was extruded in a separate extruder: the two outer layers (layer A and layer B) were extruded using an extruder equipped with a 25 mm screw with LD of 30. The core layer (layer C) was extruded using an extruder equipped with a 30 mm screw with LD of 30. The thickness of each layer A was 250 μm, for each layer C 200 μm and for each layer B 250 μm, resulting in a film thickness of the layer element of the invention of 700 μm. The chill roll is cooled to 25° C. The melt temperatures were 140-190° C. for the polyethylene compositions (PE-A) and (PE-C) and 210-215° C. for the polypropylene composition PP-B. The die width is 300 mm.

[0386] Compression Molding Pellets of the test polyolefin composition were melted at 180°C for 10 min between a platen press, Collin P 300M, under 0 bar pressure. The pressure was then increased to 187 bar and the temperature was increased for 5 min. They were then cooled to room temperature at 187 bar at a rate of 15°C / min. The thickness of the test specimens was approximately 0.5 mm.

[0387] Measuring power output The current-voltage (IV) characteristics of the 1-cell modules were obtained using a HALM cetisPV-Celltest3 flash tester. Prior to the measurements, the system was calibrated using standard cells with known IV response. The 1-cell modules were flashed with a 30 ms light pulse from a xenon light source. All results of the IV measurements were automatically converted to standard test conditions (STC) at 25°C by the software PV Control from HALM. All sample setups were flashed three times on both sides of the bifacial module and the IV parameters listed are the average values ​​calculated from these three individual measurements. All modules were flash tested with a black mask when flashed from the front side. No mask was used when flashed from the rear side. The black mask was made from standard black colored paper and had a square opening of 160*160 mm. During the flash test, the black mask was placed in such a way that the solar cells in the solar module were fully exposed to the flash pulse and there was a 2 mm gap between the edge of the solar cells and the black mask. The black mask was fixed to the module using tape. All IV performance tests were performed according to the IEC 60904 series.

[0388] The retained Pmax is determined according to IEC 60904. Pmax is the power that a PV module produces from a flash pulse of 1000 W / m2 under standard test conditions (STC). From the IV curve generated in the flash test, Pmax is obtained by the following equation (Isc is the short circuit current, Voc is the open circuit voltage, and FF is the fill factor): P max =V oc *I sc *FF

[0389] Optical properties Total light transmittance, diffuse luminous transmittance and haze were measured according to ASTM D1003-13 (Method A - Haze Meter). Clarity is measured using the same equipment and principles as haze, but at angles less than 2.5° from the norm. For clarity measurements, the specimen is placed in a "clarity port". Measurements were performed as follows:

[0390] Equipment: Haze gard plus Manufacturer: BYK-Gardner GmbH Type: 4725 Illuminant C

[0391] conditions: Conditioning time:>96h Temperature: 23℃ Test Procedure: A-Haze Meter

[0392] Experimental section Polyethylene Composition of Layer A (PE-A) For layer A, the following polyethylene composition was used:

[0393] Polyethylene composition 1 (PE-A-1) is the polymer described in Example 1 of WO2019 / 158520A1 blended with the additive INV.HALS1 mentioned in Table 2 on page 44 (see Table 1 on page 43).

[0394] Polyethylene composition 2 (PE-A-2) was prepared as described for modules 3 and 4 in the international patent application by the same applicant, which was unpublished at the time of filing this application (application number: PCT / EP2021 / 055764, filed on March 8, 2021, page 31, Table 2A).

[0395] Polyethylene composition 3 (PE-A-3) consisted of an ethylene vinyl acetate copolymer (PE-Ac) composition EVA Hangzhou First F406P (commercially available from Hangzhou First Applied Material Co., Ltd, People's Republic of China) having 28% vinyl acetate and MFR2=about 35 g / 10 min.

[0396] Preparation of the polypropylene composition of layer B (PP-B) The propylene random copolymers PP-BaA and PP-BaB are polymerized as shown in Table 2 below.

[0397] As the polymerization catalyst for PP-BaA, the same metallocene catalyst system as used in the polymerization of the inventive examples of WO2019 / 215156 was used.

[0398] The following catalyst system was used as the polymerization catalyst for PP-BaB: Preparation of catalyst components for olefin polymerization: (a) Acid and base treatment of ion-exchangeable layered silicate particles Benclay SL, the main component of which is 2:1-layered montmorillonite (smectite), was purchased from Mizusawa Chemical Industry Co., Ltd. and used in the catalyst preparation. Benclay SL has the following properties:

[0399] Dp50=46.9μm Chemical composition [wt.%]: Al9.09, Si32.8, Fe2.63, Mg2.12, Na2.39, Al / Si 0.289mol / mol

[0400] Acid Treatment In a 2 L flask equipped with a reflux condenser and a mechanical stirring unit, 1300 g of distilled water and 168 g of sulfuric acid (96%) were introduced. The mixture was heated to 95° C. in an oil bath and 200 g of Benclay SL were added. The mixture was then stirred at 95° C. for 840 min. The reaction was quenched by pouring the mixture into 2 L of pure water. The crude product was filtered through a Büchner funnel connected to an aspirator and washed with 1 L of distilled water. The washed cake was then redispersed in 902.1 g of distilled water. The pH of the dispersion was 1.7.

[0401] Base Treatment An aqueous solution of LiOH was prepared by dissolving 3.54 g of lithium hydroxide monohydrate in 42.11 g of distilled water. The aqueous LiOH solution was then introduced into a dropping funnel and added dropwise to the previously obtained dispersion at 40° C. The mixture was stirred for 90 min at 40° C. The pH of the dispersion, monitored throughout the reaction, remained below 8. The pH of the reaction mixture was 5.68. The crude product was filtered using a Büchner funnel connected to an aspirator and washed three times with 2 L of distilled water each.

[0402] Chemically treated ion-exchangeable layered silicate particles were obtained by drying the above cake at 110°C overnight. The yield was 140.8g. The silicate particles were then introduced into a 1L flask and heated to 200°C under vacuum. After confirming that gas evolution had ceased, the silicate particles were dried at 200°C under vacuum for 2h. The catalyst component for olefin polymerization of the present invention was obtained.

[0403] Olefin polymerization catalyst production (b) Reaction with organoaluminum In a 1000 ml flask, 10 g of the previously obtained chemically treated ion-exchangeable layered silicate particles (catalyst component for olefin polymerization of the present invention) and 36 ml of heptane were introduced. Into this flask, 64 ml of a heptane solution of tri-n-octyl-aluminum (TnOA) (containing 25 mmol of TnOA) was introduced. The mixture was stirred at ambient temperature for 1 h. The supernatant liquid was decanted off and the solid material was washed twice with 900 ml of heptane. The total volume of the reaction mixture was then adjusted to 50 ml by adding heptane.

[0404] (c) Prepolymerization To a heptane slurry of the ion-exchangeable layered silicate particles treated with TnOA as described above was added 31 ml of a heptane solution of TnOA (12.2 mmol of TnOA).

[0405] In a 200 ml flask, 283 mg of (r)-dichlorosilacyclobutylene-bis[2-(5-methyl-2-furyl)-4-(4-t-butylphenyl)-5,6-dimethyl-1-indenyl]zirconium (300 μmol) and 30 ml of toluene were introduced. The resulting complex solution was then introduced into the heptane slurry of the silicate particles. The mixture was stirred at 40° C. for 60 min.

[0406] The mixture was then introduced into a 1 L autoclave equipped with a mechanical stirrer. The atmosphere inside the autoclave was completely replaced with nitrogen prior to use. The autoclave was heated to 40° C. After confirming that the inside temperature was stable at 40° C., propylene was introduced at 40° C. at a rate of 10 g / h. After 2 h, the propylene feed was stopped and the mixture was stirred at 40° C. for 1 h.

[0407] The remaining propylene gas was then purged and the reaction mixture was discharged into a glass flask. After sufficient settling, the supernatant solvent was drained. Then, 8.3 ml of a heptane solution of TiBAL (6 mmol) was added to the solid portion. The mixture was dried under vacuum. The yield of the solid catalyst for olefin polymerization (prepolymerized catalyst) was 35.83 g. The degree of prepolymerization (weight of prepolymer divided by weight of solid catalyst) was 2.42.

[0408] [Table 1]

[0409] The heterophasic propylene copolymers PP-BbA and PP-BbB were polymerized as described for HECO A (PP-BbA) and HECO B (PP-BbB) in WO2017 / 071847.

[0410] The PP-BaA, PP-BaB, PP-BbA and PP-BbB powders were further melt homogenised and pelletised using a Coperion ZSK57 co-rotating twin screw extruder with screw diameter of 20-57mm and L / D of 22. The screw speed was 200 rpm and the barrel temperature was 200-220°C. The following additives were added during the melt homogenisation process:

[0411] 1500 ppm ADK-STAB A-612 (supplied by ADEKA Corporation) and 300 ppm Synthetic hydrotalcite (ADK STAB HT supplied by ADEKA Corporation).

[0412] Layer B Example Formulation: The compositions PP-B-1 to PP-B-4 were prepared by compounding the above propylene polymers PP-BaA, PP-BaB, PP-BbA and PP-BbB with other components and conventional additives in a co-rotating twin screw extruder (ZSK32, Coperion) using a screw speed of 400 rpm and a throughput of 90-100 kg / h. The melt temperatures were in the range of 210-230°C. The components and their amounts are given below.

[0413] For polypropylene composition PP-B-1, 99.6 wt. % PP-BaB was blended with 0.4 wt. % alpha nucleating agent Millad NX8000K (available from Milliken Chemical).

[0414] For the polypropylene composition PP-B-2, the composition described in Example IE6 of WO2017 / 071847 was used.

[0415] Thus, the polypropylene composition comprises: 40.7 wt% heterophasic propylene copolymer B (PP-BbB); 27.2 wt% heterophasic propylene copolymer A (PP-BbA); 23wt% talc; 8 wt% Queo 8230 (supplied by Borealis. It is an ethylene-based octene plastomer produced by a solution polymerization process using a metallocene catalyst. It has a MFR2 (190°C) of 30 g / 10 min and a MFR of 882 kg / m 3 density); and 1.1 wt. % of additives (as described in the Examples section of WO2017 / 071847).

[0416] For polypropylene composition PP-B-3, 99.6 wt. % PP-BaA was blended with 0.4 wt. % alpha nucleating agent Millad NX8000K (available from Milliken Chemical).

[0417] For the polypropylene composition PP-B-4, 99.6 wt % PP-BbA was blended with 0.4 wt % alpha nucleating agent Millad NX8000K (available from Milliken Chemical).

[0418] Polypropylene composition PP-B-5 consists of the stabilized PP-BbA polymer described above without further compounding steps / additives etc.

[0419] Preparation of Polyethylene Composition for Optional Layer C (PE-C) Polyethylene composition 2 (PE-C-1) consisted of Queo 7007LA, commercially available from Borealis AG, which is an ethylene-based plastomer with 1-octene comonomer units and has a melt flow rate MFR2 of 6.5 g / 10 min (190° C., 2.16 kg) and a melt flow rate of 870 kg / m 3 The Queo7007LA has a density (including stabilizers) of 1 wt. % vinyltrimethoxysilane units (VTMS) grafted. The grafting is carried out as described in the Examples section of WO2019 / 201934.

[0420] Layer C in the inventive examples is a compression molded 400 μm film unless otherwise noted.

[0421] Mechanical properties of compositions PP-B-1 to PP-B-5 The mechanical properties of compositions PP-B-1 to PP-B-5 were measured and are listed below in Table 3. In this regard, the tensile properties were measured on films having a thickness of 250 μm in the machine direction (MD).

[0422] [Table 2]

[0423] Optical properties of layer B The optical properties of the inventive Layer B compositions at different thicknesses are shown in Table 4. PP-B-1 is prepared by compression molding, while PP-B-2 to PP-B-5 are prepared by the monolayer cast film process described above.

[0424] [Table 3]

[0425] Manufacturing of layer elements The layer elements were prepared from compositions PE-A, PP-B and optionally PE-C as described in Table 1 below.

[0426] In this respect, in all layer elements, layer (A) has a thickness of 450 μm.

[0427] If present, the optional layer (C) has a thickness of 400 μm or 200 μm (LE2 and LE3).

[0428] The thickness of layer (B) varies between 250 μm and 500 μm for the different layer elements and is disclosed in Table 5 below.

[0429] [Table 4]

[0430] The layer element Inv.LE2 was produced by the following coextrusion process: A three-layer calendered film for the layer element Inv. LE2 of the invention was prepared by Dr. Collin cast film.

[0431] The thickness of layer A was 250 μm, for layer C 200 μm and for layer B 250 μm, resulting in a film thickness of the layer element of the invention Inv. LE2 of 700 μm.

[0432] Layer C was sandwiched between layers A and B, and layer A was extruded onto the embossed side of the calendar unit and layer B was extruded onto the smooth side of the calendar unit. The chill rolls were cooled to 25° C. The melt temperatures were 140-190° C. for the polyethylene compositions (PE-A) and (PE-C) and 210-215° C. for the polypropylene composition PP-B.

[0433] All other layer elements were fabricated during lamination of the PV mini-module by the lamination process described below.

[0434] PV mini module manufacturing For PV modules having the layer elements described above as an integrated backsheet element, 300mm x 200mm laminates of glass / encapsulant / cell / layer elements with terminations as described above were produced using a PEnergy L036LAB vacuum laminator.

[0435] Glass layer, structured solar glass supplied by InterFloat, low iron glass, length: 300mm, width: 200mm, total thickness of 3.2mm.

[0436] Before the first encapsulation layer element film was placed on the solar glass, the front protective glass element was washed with isopropanol. The front encapsulation layer element was cut to the same dimensions as the solar glass element. After the front encapsulation layer element was placed on the front protective glass element, the soldered solar cell was placed on the front encapsulation layer element. Furthermore, the layer element of the present invention was placed on the obtained PV cell element. The obtained PV module assembly was then subjected to a lamination process as described below.

[0437] [Table 5]

[0438] As front encapsulants the compositions PE-A-1, PE-A-2 and PE-A-3 described above for layer (A) were used. The thickness of all front encapsulants was 450 μm.

[0439] The same type of structured solar glass (Ducat) with a thickness of 3.2 mm was used for all cells.

[0440] For examples CE1, IE1, IE2 and IE3, a P-type monocrystalline silica cell (pseudosquare) with 5 busbars and dimensions of 156x156 mm was used as the photovoltaic cell. The cell was supplied by Trina Solar. The composition of the soldering wire was Sn:Pb:Ag (62:36:2).

[0441] For all other examples, a P-type monocrystalline silica cell with five busbars and dimensions of 156x156 mm was used as the photovoltaic cell. The cell was supplied by LightWay. The composition of the soldering wire was Sn:Pb:Ag (62:36:2).

[0442] For comparative examples CE1 and CE2, the same structured solar glass as for the front glass layer was also used as the rear glass layer.

[0443] For the inventive examples, layer elements manufactured as described above are used.

[0444] Vacuum lamination was performed at 150° C. using a lamination program of 5 minutes degassing time followed by 15 minutes pressurization time with an upper chamber pressure of 800 mbar.

[0445] The composition of the example PV module is shown in Table 7.

[0446] [Table 6]

[0447] The power output of the manufactured PV modules (front-flash and rear-flash only) was tested and reported in Table 8. RE1 indicates the power output of the non-stacked ("naked") bifacial solar cell used in most of the examples (except for Examples CE1, IE1, IE2, and IE3).

[0448] [Table 7]

[0449] Preparation of laminates for the measurement of optical properties: To measure the optical properties (transparency, haze, diffuse luminous transmittance and total light transmittance) of the laminate I-Lam1-10 of the present invention, a 300 mm x 200 mm laminate consisting of glass / Teflon film / layer element / Teflon film / glass was prepared using a PEnergy L036LAB vacuum laminator.

[0450] For the reference laminate RE-Lam, which simulates the rear side of the glass-glass module, a 300mmx200mm laminate of glass / PE-A-1 / Teflon film / glass was produced using a PEnergy L036LAB vacuum laminator.

[0451] Glass layer: Solar Glass GMB SINA, 3.2 mm thick, commercially available from Interfloat Corporation; Teflon film: Fluteck P1000, 50 μm thick, commercially available from Vital Polymers; PE-A-1: As above, thickness 450 μm.

[0452] Vacuum lamination was performed at 150° C. using a lamination program of 5 minutes degassing time followed by 15 minutes pressurization time with an upper chamber pressure of 800 mbar.

[0453] After lamination, the glass layer and Teflon film are removed from both sides of the laminate of the invention, whereas the glass layer and Teflon film are removed from one side of the reference laminate.

[0454] The optical properties (clarity, haze, diffuse luminous transmittance and total light transmittance) of the produced laminates (there is no glass layer for the laminate of the invention and a glass layer on one side of the reference laminate representing the rear side of the glass-glass PV module) are tested and reported in Table 9 along with the thickness of the laminate.

[0455] [Table 8]

[0456] Despite the poor optical properties due to low transparency and high haze, it is surprisingly found that high diffuse and total light transmittance can be obtained with the laminate of the present invention.

Claims

1. A layer element having at least two layers (A) and (B), The layer (A) has a polyethylene composition (PE-A), and the polyethylene composition (PE-A) comprises: (PE-A-a) a copolymer of ethylene having silane group-containing units; Or, (PE-A-b) (C １ -C ６ )-alkyl acrylate or (C １ -C ６ )-alkyl(C １ -C ６ a copolymer of ethylene with polar comonomer units selected from one or more of 1,2-dichloro-1,2-diphenyl ether (III)-alkyl acrylate comonomer units, further comprising silane group-containing units; or (PE-Ac) copolymers of ethylene with vinyl acetate comonomer units; having The copolymer of ethylene (PE-A-a) is different from the copolymer of ethylene (PE-A-b); The layer (B) has a polypropylene composition (PP-B), and the polypropylene composition (PP-B) comprises (PP-Ba) random copolymers of propylene monomer units with alpha-olefin comonomer units selected from ethylene and alpha-olefins having 4 to 12 carbon atoms; Or, (PP-B-b) a heterophasic copolymer of propylene, a polypropylene matrix component, and - an elastomeric propylene copolymer component dispersed in said polypropylene matrix; a heterophasic copolymer of propylene having the formula: having Layer (B) has a total light transmittance of at least 80.0%; Layer element.

2. 2. A layer element according to claim 1, wherein the polypropylene composition of layer (B) comprises a nucleating agent.

3. 3. A layer element according to claim 2, wherein the nucleating agent is selected from polymeric nucleating agents and soluble nucleating agents or mixtures thereof.

4. 4. Layer element according to claim 1, wherein layers (A) and (B) are in adhesive contact with one another to form the structure AB.

5. The layer (C) further comprises: (PE-Ca) A copolymer of ethylene and a comonomer unit selected from one or more alpha-olefins having 3 to 12 carbon atoms, having a viscosity of 850 kg / m ３ ~905kg / m ３ or a copolymer having a density of (PE-C-b) A copolymer of ethylene and a comonomer unit selected from one or more alpha-olefins having 3 to 12 carbon atoms, further having a silane group-containing unit, and having a viscosity of 850 kg / m ３ ~905kg / m ３ or a copolymer having a density of (PE-C-c) copolymers of ethylene and comonomer units selected from one or more alpha-olefins having 3 to 12 carbon atoms, further comprising functional group-containing units derived from at least one of unsaturated carboxylic acids and / or their anhydrides, metal salts, esters, amides or imides, and mixtures thereof; a polyethylene composition (PE-C) having an ethylene copolymer selected from layers (A) and (C), and layers (B) and (C) are in adhering contact with one another to form structure A-C-B; Layer element according to any one of claims 1 to 3.

6. 6. A layer element according to claim 1, wherein all layers of the layer element are free of titanium dioxide and preferably free of pigments.

7. Layer element according to any one of the preceding claims, wherein the layer element has a total thickness of from 325 μm to 2000 μm.

8. 8. Layer element according to claim 1, wherein layer (A) has a thickness of 100 μm to 750 μm, layer (B) has a thickness of 125 μm to 750 μm and optional layer (C) has a thickness of 50 μm to 500 μm.

9. An article comprising a layer element according to any one of claims 1 to 8.

10. 10. The article of claim 9, which is a photovoltaic module comprising a photovoltaic element and said layer element, said photovoltaic element being in adhesive contact with layer (A) of said layer element.

11. 11. An article according to claim 10 comprising, in that order, a protective front layer element, a front encapsulation layer element, a photovoltaic element and an integrated backsheet element, said integrated backsheet element comprising, preferably consisting of, said layer elements.

12. 12. An article that is a photovoltaic module according to claim 10 or 11, having one or more of the following characteristics when measured by a flash test on the front and rear sides of the photovoltaic element: - short circuit current I of at least 5.00 A ｓｃ ; - an open circuit voltage V of at least 0.60 V ｏｃ ; a fill factor FF of at least 70.00%; or - Maximum power output P of at least 2.50 W ｍａｘ .

13. A method for producing a layer element according to any one of claims 1 to 8, comprising the following steps: - bonding, by extrusion or lamination, layers (A), (B) and optionally layer (C) of said layer element in the configuration AB or A-C-B; and - Recovering the formed layer elements.

14. A method for producing a photovoltaic (PV) module according to claim 10 or 11, comprising the steps of: - assembling the photovoltaic element, the layer elements and any further layer elements into a photovoltaic (PV) module assembly; - laminating the layer elements of the photovoltaic (PV) module assembly at elevated temperature to bond the elements together; and - Recovering the photovoltaic (PV) module obtained.

15. 9. Use of a layer element according to any one of claims 1 to 8 as an integrated backsheet element of a double-sided photovoltaic module comprising a photovoltaic element and said layer element, said photovoltaic element being in adhesive contact with layer (A) of said layer element.

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