Composition containing cationic polymer and at least two fatty acids

Abstract

To provide a stable composition containing at least one cationic polymer and at least two fatty acids, where the composition may contain at least one environmentally compatible component.SOLUTION: A composition contains (a) at least one cationic polymer, (b) at least one monovalent non-polymeric acid or a salt thereof, (c) water, and (d) at least two fatty acids, where the pH of the composition is less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a composition comprising at least one cationic polymer and at least two fatty acids, and to a cosmetic method of using the composition. [Background technology]

[0002] Environmentally compatible cosmetic formulations, which are designed and developed with environmental issues in mind, have become a major goal to meet global challenges.

[0003] It is therefore essential to propose more sustainable compositions, preparation methods and ingredients to address these environmental issues.

[0004] In this context, it is important to develop new cosmetic compositions that have a better carbon footprint, in particular by promoting the use of renewable raw materials and / or materials with a good natural index and / or materials of natural origin, more particularly materials of plant origin, while reducing the use of compounds of petrochemical origin.

[0005] Polyion complexes formed from anionic polymers and cationic polymers are already known.

[0006] For example, WO2021 / 125069 discloses a composition useful for cosmetic treatment, comprising at least one cationic polymer, at least one anionic polymer, and at least one polyion complex particle comprising a non-polymeric acid having two or more pKa values. WO2021 / 125069 also discloses that the composition disclosed herein may include an oil and may be in the form of an emulsion. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] WO2021 / 125069 [Patent Document 2] European Patent Application No. 0080976 [Patent Document 3] French Patent No. 2077143 [Patent Document 4] French Patent No. 2393573 [Patent Document 5] French Patent No. 1492597 [Patent Document 6] U.S. Patent No. 4,131,576 [Patent Document 7] U.S. Patent No. 3,589,578 [Patent Document 8] U.S. Patent No. 4,031,307 [Patent Document 9] French Patent No. 2162025 [Patent Document 10] French Patent No. 2280361 [Patent Document 11] French Patent No. 2252840 [Patent Document 12] French Patent No. 2368508 [Patent Document 13] French Patent No. 1,583,363 [Patent Document 14] U.S. Patent No. 3,227,615 [Patent Document 15] U.S. Patent No. 2,961,347 [Patent Document 16] French Patent No. 2080759 [Patent Document 17] French Patent No. 2320330 [Patent Document 18] French Patent No. 2270846 [Patent Document 19] French Patent No. 2316271 [Patent Document 20] French Patent No. 2336434 [Patent Document 21] French Patent No. 2413907 [Patent Document 22] U.S. Patent No. 2,273,780 [Patent Document 23] U.S. Patent No. 2,375,853 [Patent Document 24] U.S. Patent No. 2,388,614 [Patent Document 25] U.S. Patent No. 2,454,547 [Patent Document 26] U.S. Patent No. 3,206,462 [Patent Document 27] U.S. Patent No. 2,261,002 [Patent Document 28] U.S. Patent No. 2,271,378 [Patent Document 29] U.S. Patent No. 3,874,870 [Patent Document 30] U.S. Patent No. 4,001,432 [Patent Document 31] U.S. Patent No. 3,929,990 [Patent Document 32] U.S. Patent No. 3,966,904 [Patent Document 33] U.S. Patent No. 4,005,193 [Patent Document 34] U.S. Patent No. 4,025,617 [Patent Document 35] U.S. Patent No. 4,025,627 [Patent Document 36] U.S. Patent No. 4,025,653 [Patent Document 37] U.S. Patent No. 4,026,945 [Patent Document 38] U.S. Patent No. 4,027,020 [Patent Document 39] European Patent Application No. 0122324 [Patent Document 40] WO03 / 068824 [Non-patent literature]

[0008] [Non-Patent Document 1] Walter Noll, Chemistry and Technology of Silicones (1968), Academic Press [Non-Patent Document 2] Cosmetics and Toiletries, Vol. 91, January 1976, pp. 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics Summary of the Invention [Problem to be solved by the invention]

[0009] A first object of the present invention is to provide a stable composition that can include at least one cationic polymer and at least two fatty acids.

[0010] Additionally, a second object of the present invention is to provide a composition that can include at least one environmentally compatible ingredient. [Means for solving the problem]

[0011] The above object of the present invention is to (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof; (c) water, and (d) at least two fatty acids A composition, preferably a cosmetic composition, more preferably a dermocosmetic composition, comprising: This can be achieved by the composition having a pH of less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.

[0012] (a) The cationic polymer may have a molecular weight (Da) of greater than 20,000.

[0013] (a) The cationic polymer may be selected from the group consisting of cyclopolymers of alkyldiallylamine and cyclopolymers of dialkyldiallylammonium, such as (co)polydiallyldialkylammonium chloride, (co)polyamines, such as (co)polylysine and chitosan, cationic (co)polyamino acids, such as collagen, cationic cellulose polymers, and salts thereof.

[0014] The amount of the (a) cationic polymer in the composition of the present invention can be 0.001% to 15% by mass, preferably 0.005% to 10% by mass, and more preferably 0.01% to 5% by mass, relative to the total mass of the composition.

[0015] (b) The monovalent non-polymeric acid may be a monovalent non-polymeric organic acid, preferably a monovalent non-polymeric carboxylic acid, more preferably a monovalent hydroxy acid, such as lactic acid and salicylic acid.

[0016] The amount of (b) monovalent non-polymeric acid or its salt in the composition of the present invention may be 0.001% by mass to 15% by mass, preferably 0.005% by mass to 10% by mass, and more preferably 0.01% by mass to 5% by mass, relative to the total mass of the composition.

[0017] The amount of (c) water in the composition of the present invention may be 20% by mass to 99% by mass, preferably 30% by mass to 95% by mass, and more preferably 50% by mass to 90% by mass, based on the total mass of the composition.

[0018] (d) The fatty acids may be selected from linoleic acid, oleic acid, linolenic acid, palmitic acid, stearic acid, and mixtures thereof, preferably linoleic acid, oleic acid, and mixtures thereof.

[0019] The amount of the (d) fatty acid in the composition of the present invention may be 0.001% by mass to 30% by mass, preferably 0.005% by mass to 20% by mass, and more preferably 0.01% by mass to 10% by mass, relative to the total mass of the composition.

[0020] The compositions of the present invention may further comprise (e) at least one organic alkaline agent.

[0021] (e) The organic alkaline agent may be selected from alkanolamines and basic amino acids, preferably from the group consisting of mono-, di- and tri-ethanolamine, lysine, histidine, arginine, and mixtures thereof, more preferably from the group consisting of triethanolamine, arginine, and mixtures thereof.

[0022] The amount of the (e) organic alkaline agent in the composition of the present invention may be 0.001% by mass to 15% by mass, preferably 0.005% by mass to 10% by mass, and more preferably 0.01% by mass to 5% by mass, relative to the total mass of the composition.

[0023] The compositions of the present invention may further comprise (f) at least one oil.

[0024] The amount of the (f) oil in the composition of the present invention may be 0.001% by mass to 50% by mass, preferably 0.01% by mass to 45% by mass, and more preferably 0.1% by mass to 40% by mass, relative to the total mass of the composition.

[0025] The present invention also provides a cosmetic method for keratinous materials, such as the skin, comprising the steps of: applying a composition of the present invention to a keratinous material; drying the composition to form a cosmetic film on the keratinous material; The present invention also relates to a cosmetic method including: DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0026] After extensive investigation, the inventors have discovered that it is possible to provide a stable composition comprising at least one cationic polymer and at least two fatty acids, and which may include at least one environmentally compatible ingredient.

[0027] The composition of the present invention comprises (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof; (c) water, and (d) at least two fatty acids Including, The pH of the composition is less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.

[0028] The compositions of the present invention are stable and can include at least one environmentally compatible component.

[0029] The compositions of the present invention are stable and therefore capable of maintaining a uniform appearance over an extended period of time without the formation of large particles of the composition.

[0030] The compositions of the present invention are capable of providing an immediate mattifying effect, which can reduce the shininess of keratinous materials such as the skin, for example due to sebum.

[0031] Even when the composition of the present invention contains oil, the composition of the present invention can provide an immediate matte effect. Moreover, the immediate matte effect is not dependent on the amount of oil. Therefore, for example, even when the amount of oil is increased, the composition of the present invention can provide an immediate matte effect.

[0032] Accordingly, the compositions of the present invention are useful for cosmetic applications.

[0033] When the (a) at least one cationic polymer is obtained from a natural source, the (a) cationic polymer can be an environmentally compatible component. For example, the (a) cationic polymer can be selected from environmentally compatible chitosan. Thus, the composition of the present invention can include an environmentally compatible component.

[0034] In addition, components (b), (c) and (d) can originate from renewable and / or biodegradable materials, such as plants, and therefore the compositions of the present invention can be environmentally compatible.

[0035] The present invention will now be described in more detail.

[0036] [Composition] The composition of the present invention comprises (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof; (c) water, and (d) at least two fatty acids Including, The pH of the composition is less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.

[0037] In the composition of the present invention, (a) the cationic polymer and (d) the fatty acid can form at least one type of complex.

[0038] (a) Cationic polymers of amino (-NH2) or ammonium (-NH3 + (d) a carboxylic acid (-COOH) or carboxylate (-COO) group of a fatty acid; - ) group. The complex contains at least one hydrophobic moiety derived from the fatty portion of the (d) fatty acid. Thus, the (a) cationic polymer can be hydrophobized by the (d) fatty acid by forming a complex.

[0039] (cationic polymer) The composition of the present invention comprises (a) at least one cationic polymer. A single type of cationic polymer may be used, but two or more different types of cationic polymers may also be used in combination.

[0040] The cationic polymer has a positive charge density. (a) The charge density of the cationic polymer may be 0.01 meq / g to 20 meq / g, preferably 0.05 meq / g to 15 meq / g, and more preferably 0.1 meq / g to 10 meq / g.

[0041] It may be preferred that the molecular weight of the (a) cationic polymer is 1,000 or more, preferably 2,000 or more, more preferably 3,000 or more, and even more preferably 4,000 or more.

[0042] It may be particularly preferred that the (a) cationic polymer have a molecular weight of greater than 20,000.

[0043] Unless otherwise defined in the description, "molecular weight" means weight average molecular weight.

[0044] (a) The cationic polymer may have at least one positively charged and / or positively charged moiety selected from the group consisting of primary, secondary or tertiary amino groups, quaternary ammonium groups, guanidine groups, biguanide groups, imidazole groups, imino groups, and pyridyl groups. The term (primary) "amino group" as used herein means an -NH2 group.

[0045] (a) The cationic polymer may be a homopolymer or a copolymer. The term "copolymer" is understood to mean both copolymers resulting from two types of monomers and those resulting from more than two types of monomers, for example terpolymers resulting from three types of monomers.

[0046] (a) The cationic polymer may be selected from natural and synthetic cationic polymers, preferably natural cationic polymers. Non-limiting examples of cationic polymers are:

[0047] (1) Homopolymers and copolymers derived from esters and amides of acrylic or methacrylic acid and containing at least one unit selected from units of the following formulae:

[0048] [ka]

[0049] (In the formula: R1 and R2 may be the same or different and are selected from hydrogen and alkyl groups containing 1 to 6 carbon atoms, such as methyl and ethyl groups; R3, which may be the same or different, is selected from hydrogen and CH3; the symbols A may be the same or different and are selected from linear or branched alkyl groups containing 1 to 6 carbon atoms, for example 2 to 3 carbon atoms, and hydroxyalkyl groups containing 1 to 4 carbon atoms, R4, R5 and R6 may be the same or different and are selected from alkyl groups containing 1 to 18 carbon atoms, and benzyl groups, and in at least one embodiment alkyl groups containing 1 to 6 carbon atoms; X is an anion derived from an inorganic or organic acid, such as methosulfate and halide ions, such as chloride and bromide.

[0050] The copolymers of family (1) may also contain at least one unit derived from a comonomer, which may be selected from acrylamide, methacrylamide, diacetone acrylamide, acrylamides and methacrylamides in which the nitrogen atom is substituted with a (C1-C4) lower alkyl group, groups derived from acrylic or methacrylic acid and their esters, vinyl lactams such as vinyl pyrrolidone and vinyl caprolactam, and vinyl esters.

[0051] Examples of family (1) copolymers include, but are not limited to, the following: Copolymers of acrylamide and dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or dimethyl halides; Copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, such as those described in European Patent Application No. 0080976; Copolymers of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, quaternized or non-quaternized vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers, such as those described in French Patents Nos. 2 077 143 and 2 393 573; Dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymer, Vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymer, quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymer, and Crosslinked methacryloyloxy(C1-C4)alkyltri(C1-C4)alkylammonium salt polymers, for example those obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride or by copolymerization of acrylamide and dimethylaminoethyl methacrylate quaternized with methyl chloride, followed by crosslinking with a compound containing olefinic unsaturation, for example methylenebisacrylamide.

[0052] (2) Cationic cellulose polymers, such as the cellulose ether derivatives containing one or more quaternary ammonium groups described in French Patent No. 1 492 597, such as the polymers sold under the names "JR" (JR 400, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by Union Carbide Corporation, which are also defined in the CTFA dictionary as quaternary ammonium of hydroxyethylcellulose reacted with epoxides substituted with trimethylammonium groups.

[0053] It is preferred that the cationic cellulose polymer has at least one quaternary ammonium group, preferably a quaternary trialkylammonium group, more preferably a quaternary trimethylammonium group.

[0054] The quaternary ammonium group may be present in a quaternary ammonium group-containing group, which may be represented by the following chemical formula (I):

[0055] [ka]

[0056] (In the formula, Each of R1 and R2 is C 1~3 represents an alkyl group, preferably a methyl group or an ethyl group, more preferably a methyl group; R3 is C 1~24 represents an alkyl group, preferably a methyl group or an ethyl group, more preferably a methyl group; X - represents an anion, preferably a halide ion, more preferably a chloride ion, n represents an integer of 0 to 30, preferably 0 to 10, and more preferably 0; R4 is C 1~4 It represents an alkylene group, preferably an ethylene group or a propylene group.

[0057] The left-most ether linkage (-O-) in the above chemical formula (I) can be attached to a sugar ring of a polysaccharide.

[0058] The quaternary ammonium group-containing group is -O-CH2-CH(OH)-CH2-N + It is preferably (CH3)3.

[0059] (3) Cationic cellulose polymers such as cellulose copolymers and cellulose derivatives grafted with quaternary ammonium water-soluble monomers, for example those described in U.S. Pat. No. 4,131,576, such as hydroxyalkylcelluloses, e.g., hydroxymethyl, hydroxyethyl, and hydroxypropylcelluloses, grafted with salts selected from methacryloylethyltrimethylammonium, methacrylamidepropyltrimethylammonium, and dimethyldiallylammonium salts.

[0060] Commercially available products corresponding to these polymers include, for example, the products sold under the names "Celquat® L 200" and "Celquat® H 100" by National Starch.

[0061] (4) Non-cellulosic cationic polysaccharides such as guar gum containing cationic trialkylammonium groups, cationic hyaluronic acid and dextran hydroxypropyltrimonium chloride, as described in U.S. Patents 3,589,578 and 4,031,307. Guar gum modified with salts such as 2,3-epoxypropyltrimethylammonium chloride (guar hydroxypropyltrimonium chloride) can also be used.

[0062] Such products are, for example, sold by the company MEYHALL under the trade names JAGUAR® C13 S, JAGUAR® C15, JAGUAR® C17 and JAGUAR® C162.

[0063] (5) Polymers containing piperazinyl units and divalent alkylene or hydroxyalkylene groups, optionally containing linear or branched chains, optionally interrupted by at least one element selected from oxygen, sulfur, nitrogen, aromatic rings and heterocyclic rings, and also the oxidation and / or quaternization products of these polymers. Such polymers are described, for example, in French Patents Nos. 2 162 025 and 2 280 361.

[0064] (6) Water-soluble polyaminoamides, for example prepared by polycondensation of acidic compounds with polyamines, which may be crosslinked with an element selected from epihalohydrins; diepoxides; dianhydrides; unsaturated dianhydrides; bisunsaturated derivatives; bishalohydrins; bisazetidiniums; bishaloacyldiamines; bisalkylhalides; oligomers obtained by reaction of bifunctional compounds reactive with elements selected from bishalohydrins, bisazetidiniums, bishaloacyldiamines, bisalkylhalides, epihalohydrins, diepoxides and bisunsaturated derivatives; the crosslinking agent is used in an amount ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamides may be optionally alkylated or, if they contain at least one tertiary amine function, they may be quaternized. Such polymers are described, for example, in French patents nos. 2,252,840 and 2,368,508.

[0065] (7) Polyaminoamide derivatives obtained by condensation of polyalkylenepolyamines with polycarboxylic acids followed by alkylation with bifunctional agents, such as adipic acid / dialkylaminohydroxyalkyldialkylenetriamine polymers, in which the alkyl groups contain from 1 to 4 carbon atoms, such as methyl, ethyl and propyl groups, and the alkylene groups contain from 1 to 4 carbon atoms, such as ethylene groups. Such polymers are described, for example, in French Patent No. 1,583,363. In at least one embodiment, these derivatives may be chosen from adipic acid / dimethylaminohydroxypropyldiethylenetriamine polymers.

[0066] (8) Polymers obtained by reacting polyalkylenepolyamines containing two primary amine groups and at least one secondary amine group with dicarboxylic acids selected from diglycolic acid and saturated aliphatic dicarboxylic acids containing 3 to 8 carbon atoms. The molar ratio of polyalkylenepolyamine to dicarboxylic acid may range from 0.8:1 to 1.4:1, and the polyaminoamides obtained therefrom are reacted with epichlorohydrin in a molar ratio of epichlorohydrin to secondary amine groups of polyaminoamide ranging from 0.5:1 to 1.8:1. Such polymers are described, for example, in U.S. Pat. Nos. 3,227,615 and 2,961,347.

[0067] (9) Cyclopolymers of alkyldiallylamine and cyclopolymers of dialkyldiallyl-ammonium, for example homopolymers and copolymers which contain, as main chain building blocks, at least one unit selected from units of formulae (Ia) and (Ib) below:

[0068] [ka]

[0069] (In the formula: k and t may be the same or different and are equal to 0 or 1, the sum k+t being equal to 1; R 12 is selected from hydrogen and a methyl group; R 10 and R 11 may be the same or different and are selected from alkyl groups containing 1 to 6 carbon atoms, hydroxyalkyl groups, the alkyl group containing, for example, 1 to 5 carbon atoms, and lower (C1 to C4) amidoalkyl groups, or R 10 and R 11 may, together with the nitrogen atom to which they are attached, form a heterocyclic group, such as piperidinyl and morpholinyl; Y' is an anion, such as bromide, chloride, acetate, borate, citrate, tartrate, hydrogen sulfate, hydrogen sulfite, sulfate and phosphate.) These polymers are described, for example, in French Patent No. 2 080 759 and its addition No. 2 190 406.

[0070] In one embodiment, R 10 and R 11 may be the same or different and are selected from alkyl groups containing 1 to 4 carbon atoms.

[0071] Examples of such polymers include, but are not limited to, (co)polydiallyldialkylammonium chlorides, such as the dimethyldiallylammonium chloride homopolymer sold under the name "MERQUAT® 100" by CALGON (and its homologs of lower weight average molecular weight), and the copolymer of diallyldimethylammonium chloride and acrylamide sold under the name "MERQUAT® 550".

[0072] A quaternary diammonium polymer comprising at least one repeat unit of formula (II):

[0073] [ka]

[0074] [In formula: R 13 , R 14 , R 15 and R 16 are the same or different and are selected from aliphatic, alicyclic and arylaliphatic groups containing 1 to 20 carbon atoms, and lower hydroxyalkyl aliphatic groups; or R 13 , R 14 , R 15 and R 16may be taken together with the nitrogen atom to which they are attached or separately form a heterocycle which optionally contains a second heteroatom other than nitrogen, or R 13 , R 14 , R 15 and R 16 may be the same or different, and may be a nitrile group, an ester group, an acyl group, an amide group, -CO-OR 17 -E group and -CO-NH-R 17 -E group (wherein, R 17 is an alkylene group, and E is a quaternary ammonium group); A1 and B1 may be identical or different and are selected from polymethylene groups containing 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and which may contain, linked or inserted in the main chain, at least one element selected from aromatic rings, oxygen, sulfur, sulfoxide groups, sulfone groups, disulfide groups, amino groups, alkylamino groups, hydroxyl groups, quaternary ammonium groups, ureido groups, amide groups and ester groups; X - is an anion derived from an inorganic or organic acid, A1, R 13 and R 15 may form a piperazine ring together with the two nitrogen atoms to which they are attached; When A1 is selected from linear or branched, saturated or unsaturated alkylene or hydroxyalkylene groups, B1 is selected from the following: -(CH2) n -CO-E'-OC-(CH2) n - wherein E′ is: a) glycol residues of the formula -OZO-, in which Z is a linear or branched hydrocarbon-based group and a group of the formula: -(CH2-CH2-O) x -CH2-CH2- -[CH2-CH(CH3)-O] y -CH2-CH(CH3)- (wherein x and y may be the same or different and are selected from integers ranging from 1 to 4 representing a unique defined degree of polymerization, and numbers ranging from 1 to 4 representing an average degree of polymerization). selected from], b) bis-secondary diamine residues, such as piperazine derivatives; c) bis-primary diamine residues of the formula -NH-Y-NH-, where Y is selected from linear or branched hydrocarbon-based radicals and the divalent radical -CH-CH-SS-CH-CH-, and d) a ureylene group of the formula -NH-CO-NH- selected from can be selected from].

[0075] In at least one embodiment, X - is an anion, for example chloride or bromide.

[0076] Polymers of this type are described, for example, in French Patents Nos. 2320330, 2270846, 2316271, 2336434 and 2413907, and in U.S. Pat. Nos. 2,273,780, 2,375,853, 2,388,614, 2,454,547, 3,206,462, 2,261,000, and 2,372,411. 2, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945, and 4,027,020.

[0077] Non-limiting examples of such polymers include those that contain at least one repeat unit of formula (III):

[0078] [ka]

[0079] (In the formula, R 13 , R 14 , R 15 and R 16 are the same or different and are selected from alkyl and hydroxyalkyl groups containing 1 to 4 carbon atoms; n and p are the same or different and are integers ranging from 2 to 20; X - is an anion derived from an inorganic or organic acid).

[0080] (11) Polyquaternary ammonium polymers comprising units of formula (IV):

[0081] [ka]

[0082] [In formula: R 18 , R 19 , R 20 and R 21 may be the same or different and are hydrogen, methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl, -CH2CH2(OCH2CH2) p OH group (wherein p is selected from an integer ranging from 0 to 6), provided that R 18 , R 19 , R 20 and R 21 is not hydrogen at the same time, r and s may be the same or different and are selected from integers ranging from 1 to 6; q is selected from an integer ranging from 0 to 34; X - is an anion, for example a halide ion, A is selected from dihalides and -CH2-CH2-O-CH2-CH2- groups.

[0083] Such compounds are described, for example, in European Patent Application No. 0122324.

[0084] (12) Quaternary polymers of vinylpyrrolidone and vinylimidazole.

[0085] Other examples of suitable cationic polymers include, but are not limited to, cationic proteins and cationic protein hydrolysates, polyalkyleneimines, such as polyethyleneimines, polymers comprising units selected from vinylpyridine units and vinylpyridinium units, condensates of polyamines with epichlorohydrin, quaternary polyureylenes, and chitin derivatives.

[0086] According to one embodiment of the present invention, the (a) cationic polymer is selected from cellulose ether derivatives containing quaternary ammonium groups, such as the product sold under the name "JR 400" by UNION CARBIDE CORPORATION, cationic cyclopolymers, such as the homopolymers and copolymers of dimethyldiallylammonium chloride sold under the names MERQUAT® 100, MERQUAT® 550 and MERQUAT® S by CALGON, guar gum modified with 2,3-epoxypropyltrimethylammonium salt, and quaternary polymers of vinylpyrrolidone and vinylimidazole.

[0087] (13) Polyamines (a) As cationic polymers it is also possible to use (co)polyamines, which may be homopolymers or copolymers, having a plurality of amino groups. The amino groups may be primary, secondary, tertiary or quaternary amino groups. The amino groups may be present in the polymer backbone of the (co)polyamine or, if present, in pendant groups.

[0088] Examples of (co)polyamines include chitosan, (co)polyallylamine, (co)polyvinylamine, (co)polyaniline, (co)polyvinylimidazole, (co)polydimethylaminoethylene methacrylate, (co)polyvinylpyridine such as (co)poly-1-methyl-2-vinylpyridine, (co)polyimines such as (co)polyethylenimine, (co)polypyridines such as (co)poly(quaternary pyridine), (co)polybiguanides such as (co)polyaminopropyl biguanide, (co)polylysine, (co)polyornithine, (co)polyarginine, (co)polyhistidine, aminodextran, aminocellulose, amino(co)polyvinyl acetal, and salts thereof.

[0089] As the (co)polyamine, it may be preferred to use (co)polylysine. Polylysine is well known. Polylysine can be a natural homopolymer of L-lysine that can be produced by bacterial fermentation. For example, polylysine can be ε-poly-L-lysine, which is typically used as a natural preservative in food. Polylysine is a polyelectrolyte that is soluble in polar solvents, such as water, propylene glycol and glycerol. Polylysine is commercially available in various forms, such as poly-D-lysine and poly-L-lysine. Poly-L-lysine is preferred. Polylysine may be in the form of a salt and / or a solution.

[0090] (14) Cationic polyamino acids (a) As cationic polymer it may be possible to use cationic polyamino acids, which may be cationic homopolymers or copolymers having multiple amino and carboxyl groups. The amino groups may be primary, secondary, tertiary or quaternary amino groups. The amino groups may be present in the polymer backbone of the cationic polyamino acid or in pendant groups, if present. The carboxyl groups may be present in pendant groups, if present, of the cationic polyamino acid.

[0091] Examples of cationic polyamino acids include cationized collagen, cationized gelatin, steardimonium hydroxypropyl hydrolyzed wheat protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, hydroxypropyltrimonium hydrolyzed conchiolin protein, steardimonium hydroxypropyl hydrolyzed soy protein, hydroxypropyltrimonium hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed soy protein, and the like.

[0092] The following description relates to preferred embodiments of the cationic polymer.

[0093] It is preferred that the (a) cationic polymer is selected from the group consisting of cyclopolymers of alkyldiallylamine and cyclopolymers of dialkyldiallylammonium, such as (co)polydiallyldialkylammonium chloride, (co)polyamines, such as (co)polylysine and chitosan, cationic (co)polyamino acids, such as collagen, cationic cellulose polymers, and salts thereof.

[0094] More preferably, the (a) cationic polymer is selected from chitosan.

[0095] The chitosan preferably has a molecular weight (Da) of more than 20,000, preferably more than 50,000, more preferably more than 80,000. In other words, the (a) cationic polymer is a high molecular weight chitosan.

[0096] The molecular weight (Da) of chitosan may be less than 1,000,000, preferably less than 500,000, more preferably less than 300,000.

[0097] The molecular weight (Da) of chitosan may be greater than 20,000 and less than 1,000,000, preferably greater than 50,000 and less than 500,000, more preferably greater than 80,000 and less than 300,000.

[0098] Unless otherwise defined in the description, "molecular weight" means the weight average molecular weight. Molecular weight can be measured or determined, for example, by gel permeation chromatography according to ASTM D5296-19.

[0099] Chitosan is very rare in nature: it has only been reported in the exoskeletons of certain insects, such as termite queens, and in the cell walls of a certain class of fungi, the Zygomycetes.

[0100] Chitosan can be obtained by deacetylation of chitin, a polysaccharide composed of several N-acetyl-D-glucosamine units linked together by β-type bonds (1,4).

[0101] The idealized chemical structure of chitosan is a sequence of β-D-glucosamine monomers linked by glycosidic bonds (1→4).

[0102] "Chitosan" in the present invention means any copolymer formed from the building blocks N-acetyl-D-glucosamine and D-glucosamine, the degree of acetylation of which is less than 90%, preferably less than 80%, preferably less than 70%, preferably less than 60%, preferably less than 50%. Chitosan consists of glucosamine sugar units (deacetylated units) and N-acetyl-D-glucosamine units (acetylated units) linked together by β-type bonds (1,4), and is a polymer of the poly(N-acetyl-D-glucosamine)-poly(D-glucosamine) type.

[0103] More preferably, the degree of acetylation of chitosan is not more than 40%, preferably not more than 35%, preferably not more than 25%, preferably not more than 15%, preferably not more than 10%.

[0104] The degree of acetylation is the percentage of acetylated units relative to the total number of units and can be determined by Fourier transform infrared spectroscopy (FT-IR) or titration with a strong base.

[0105] The chitosan in the present invention is preferably a polysaccharide prepared from a fungal source, in particular, chitosan is extracted and purified from safe and abundant food or biotechnological fungal sources such as mushroom (Agaricus bisporus) or Aspergillus niger).

[0106] The chitosan according to the invention is preferably derived from the mycelium of fungi of the Ascomycete type, in particular Aspergillus niger and / or Basidiomycete fungus, in particular Lentinula edodes and / or Agaricus bisporus. Preferably, the fungus is Aspergillus niger.

[0107] The chitosan may be of Genetically Modified Organisms (GMO) origin, but is preferably of non-GMO origin.

[0108] The chitosan according to the invention is natural, i.e. unmodified, in particular does not contain any chemical modifications.

[0109] One method for preparing chitosan is that described in WO03 / 068824.

[0110] Preferably, the chitosan used in the present invention is in the form of a powder. It is marketed under the name Kiosmetine or Kionutrime by the company Kitozyme, e.g. Kiosmetine-CSH and Kiosmetine P.

[0111] (a) is preferably selected from chitosan, more preferably from chitosan having a molecular weight (Da) of more than 20,000.

[0112] The amount of (a) cationic polymer in the composition of the present invention may be 0.001% by weight or more, preferably 0.005% by weight or more, more preferably 0.01% by weight or more, based on the total weight of the composition.

[0113] The amount of (a) cationic polymer in the composition of the present invention may be 15% by weight or less, preferably 10% by weight or less, more preferably 5% by weight or less, based on the total weight of the composition.

[0114] The amount of the (a) cationic polymer in the composition of the present invention can be 0.001% to 15% by mass, preferably 0.005% to 10% by mass, and more preferably 0.01% to 5% by mass, relative to the total mass of the composition.

[0115] (Monovalent non-polymeric acid or its salt) The compositions of the present invention include (b) at least one monovalent non-polymeric acid or salt thereof. A single type of monovalent non-polymeric acid or salt thereof or a combination of different types of monovalent non-polymeric acids or salts thereof can be used.

[0116] The term "non-polymeric" as used herein means that the acid is not obtained by polymerizing two or more monomers, and thus does not correspond to acids obtained by polymerizing two or more monomers, such as polyacrylic acid.

[0117] The term "salt" as used herein refers to a salt formed by adding a suitable base to a monovalent non-polymeric acid, which can be obtained from the reaction of a monovalent non-polymeric acid with a base according to methods known to those skilled in the art. The salt can include metal salts, such as salts with alkali metals such as Na and K, and salts with alkaline earth metals such as Mg and Ca, and ammonium salts.

[0118] (b) The molecular weight of the monovalent non-polymeric acid or salt thereof is preferably less than 1,000, more preferably 500 or less, and even more preferably 200 or less.

[0119] (b) The monovalent non-polymeric acids have a single acid group which may be selected from the group consisting of carboxylate groups, sulfate groups, sulfonate groups, phosphate groups, phosphonate groups, and mixtures thereof.

[0120] (b) The monovalent non-polymeric acid or salt thereof may be selected from monovalent organic or inorganic acids and their salts.

[0121] (b) The monovalent non-polymeric acid is preferably a monovalent organic acid, more preferably a monovalent non-polymeric carboxylic acid.

[0122] The monovalent non-polymeric carboxylic acid may be selected from hydroxy acids, preferably alpha-hydroxy acids and beta-hydroxy acids. The alpha-hydroxy acids may include, for example, lactic acid and glycolic acid. The beta-hydroxy acids may include, for example, salicylic acid.

[0123] The monovalent non-polymeric acid may be a monovalent non-polymeric organic acid, preferably a monovalent non-polymeric carboxylic acid, more preferably a monovalent hydroxy acid, such as lactic acid and salicylic acid.

[0124] The amount of (b) monovalent non-polymeric acid or salt thereof in the composition of the present invention may be 0.001% by weight or more, preferably 0.005% by weight or more, and more preferably 0.01% by weight or more, based on the total weight of the composition.

[0125] The amount of (b) monovalent non-polymeric acid or salt thereof in the composition of the present invention may be 15% by weight or less, preferably 10% by weight or less, and more preferably 5% by weight or less, based on the total weight of the composition.

[0126] The amount of (b) monovalent non-polymeric acid or its salt in the composition of the present invention may be 0.001% by mass to 15% by mass, preferably 0.005% by mass to 10% by mass, and more preferably 0.01% by mass to 5% by mass, relative to the total mass of the composition.

[0127] (water) The composition of the present invention comprises (c) water.

[0128] The amount of (c) water may be 20% by weight or more, preferably 30% by weight or more, and more preferably 50% by weight or more, based on the total weight of the composition.

[0129] (c) The amount of water may be up to 99% by weight, preferably up to 95% by weight, and more preferably up to 90% by weight, based on the total weight of the composition.

[0130] The amount of (c) water may be from 20% to 99% by mass, preferably from 30% to 95% by mass, and more preferably from 50% to 90% by mass, based on the total mass of the composition.

[0131] (fatty acid) The composition of the present invention includes (d) at least two fatty acids. Three or more different types of fatty acids may be used in combination.

[0132] (d) the fatty acid is different from (b) the monovalent non-polymeric acid or a salt thereof.

[0133] (d) The fatty acid can hydrophobize the (a) cationic polymer.

[0134] As used herein, the term "fatty acid" refers to a carboxylic acid having a long chain of aliphatic carbons.

[0135] (d) Each of the fatty acids has at least 4 carbon atoms, preferably at least 6 carbon atoms, more preferably at least 8 carbon atoms. (d) Each of the fatty acids may contain up to 26 carbon atoms, preferably up to 24 carbon atoms, more preferably up to 22 carbon atoms. (d) Each of the fatty acids may contain up to C4-C 26 Fatty acids, preferably C6-C 24 Fatty acids, even more preferably C8-C 22 It is preferably selected from fatty acids.

[0136] Each of the (d) fatty acids may be selected from saturated or unsaturated, linear or branched fatty acids. Thus, the (d) fatty acids may be selected from C4 to C 26 , preferably C6 to C 24 , more preferably C8 to C 22 They may be chosen from saturated and unsaturated, straight-chain or branched fatty acids.

[0137] As the unsaturated linear or branched fatty acid, monounsaturated linear or branched fatty acid or polyunsaturated linear or branched fatty acid may be used. The unsaturated portion of the unsaturated linear or branched fatty acid may include a carbon-carbon double bond or a carbon-carbon triple bond.

[0138] Saturated fatty acids include, for example, caprylic acid (C8), pelargonic acid (C9), and capric acid (C 10 ), lauric acid (C 12 ), myristic acid (C 14 ), pentadecanoic acid (C 15 ), palmitic acid (C 16 ), heptadecanoic acid (C 17 ), stearic acid (C 18 ), Isostearic acid (C 18 ), nonadecanoic acid (C 19 ), arachidic acid (C 20 ), behenic acid (C 22 ), and lignoceric acid (C 24 ) can be mentioned.

[0139] Examples of unsaturated fatty acids include myristoleic acid (C 14 ), palmitoleic acid (C 16 ), oleic acid (C 18 ), linoleic acid (C 18 ), linoleic acid (C 18 ), elaidic acid (C 18 ), arachidonic acid (C 20 ), eicosenoic acid (C 20 ), erucic acid (C 22 ), and nervonic acid (C 24 ) can be mentioned.

[0140] (d) Each of the fatty acids is preferably selected from unsaturated fatty acids, more preferably C to C 22 Unsaturated fatty acids, even more preferably C8-C having one, two or three carbon-carbon double bonds 22 The fatty acids are selected from unsaturated fatty acids.

[0141] More preferably, each of the (d) fatty acids is selected from linoleic acid, oleic acid, linolenic acid, palmitic acid, stearic acid, and mixtures thereof, and even more preferably, linoleic acid, oleic acid, and mixtures thereof.

[0142] (d) Vitamin F may be used as the fatty acid. Vitamin F herein means a mixture of a plurality of unsaturated fatty acids including at least linoleic acid. Vitamin F preferably includes linoleic acid and linolenic acid. More preferably, vitamin F includes linoleic acid, oleic acid, palmitic acid, stearic acid and linolenic acid.

[0143] The amount of (d) fatty acid in the composition of the present invention may be 0.001% by mass or more, preferably 0.005% by mass or more, and more preferably 0.01% by mass or more, based on the total mass of the composition.

[0144] On the other hand, the amount of (d) fatty acid in the composition of the present invention may be 30% by mass or less, preferably 20% by mass or less, and more preferably 10% by mass or less, based on the total mass of the composition.

[0145] Accordingly, the amount of (d) fatty acid in the composition of the present invention may be in the range of 0.001% by mass to 30% by mass, preferably 0.005% by mass to 20% by mass, and more preferably 0.01% by mass to 10% by mass, relative to the total mass of the composition.

[0146] (Organic alkaline agent) The composition of the present invention may include (e) at least one organic alkaline agent. A single type of organic alkaline agent may be used, or two or more different types of organic alkaline agents may be used in combination.

[0147] (e) As the organic alkaline agent, any conventional organic alkaline agent in the field of cosmetics may be used.

[0148] (e) The organic alkaline agent is preferably selected from the group consisting of monoamines and derivatives thereof; diamines and derivatives thereof; polyamines and derivatives thereof; basic amino acids and derivatives thereof; oligomers of basic amino acids and derivatives thereof; polymers of basic amino acids and derivatives thereof; urea and derivatives thereof; and guanidine and derivatives thereof (such as guanidine carbonate).

[0149] (e) Examples of organic alkaline agents include alkanolamines, such as mono-, di-, and tri-ethanolamine, and isopropanolamine; urea, guanidine and their derivatives; basic amino acids, such as lysine, histidine, ornithine, or arginine; and diamines, such as those having the following structures:

[0150] [ka]

[0151] (wherein R represents an alkylene such as propylene optionally substituted with a hydroxyl group or a C1-C4 alkyl group, and R1, R2, R3 and R4 each independently represent a hydrogen atom, an alkyl group or a C1-C4 hydroxyalkyl group), and examples thereof include 1,3-propanediamine and derivatives thereof.

[0152] (e) The organic alkaline agent is preferably selected from alkanolamines and basic amino acids, more preferably from the group consisting of mono-, di- and triethanolamine, lysine, histidine, arginine, and mixtures thereof, even more preferably from the group consisting of triethanolamine, arginine, and mixtures thereof.

[0153] The amount of (e) the organic alkaline agent in the composition of the present invention may be 0.001% by mass or more, preferably 0.005% by mass or more, and more preferably 0.01% by mass or more, based on the total mass of the composition.

[0154] The amount of (e) the organic alkaline agent in the composition of the present invention may be 15% by weight or less, preferably 10% by weight or less, and more preferably 5% by weight or less, based on the total weight of the composition.

[0155] The amount of the (e) organic alkaline agent in the composition of the present invention may be 0.001% by mass to 15% by mass, preferably 0.005% by mass to 10% by mass, and more preferably 0.01% by mass to 5% by mass, relative to the total mass of the composition.

[0156] (oil) The composition of the present invention may comprise (f) at least one oil. A single type of oil may be used, but two or more different types of oil may also be used in combination.

[0157] In this specification, "oil" means a fatty compound or substance that is in the form of a liquid or paste (non-solid) at atmospheric pressure (760 mmHg) and at room temperature (25°C). As oils, those commonly used in cosmetics can be used, alone or in combination. These oils can be volatile or non-volatile.

[0158] (f) The oil may be a non-polar oil, such as a hydrocarbon oil or a silicone oil, a vegetable oil or an animal oil, and a polar oil, such as an ester oil or an ether oil, or a mixture thereof.

[0159] (f) The oil may be selected from the group consisting of oils of vegetable or animal origin, synthetic oils, silicone oils, hydrocarbon oils and fatty alcohols.

[0160] Examples of vegetable oils include, for example, apricot oil, linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, camellia oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, soybean oil, peanut oil, and mixtures thereof.

[0161] Examples of animal oils include, for example, squalene and squalane.

[0162] Examples of synthetic oils include alkane oils such as isododecane and isohexadecane, ester oils, ether oils, and artificial triglycerides.

[0163] The ester oil is preferably a saturated or unsaturated, linear or branched C1-C 26 Aliphatic mono- or polyacids and saturated or unsaturated, linear or branched C1-C 26 They are liquid esters with aliphatic monohydric or polyhydric alcohols, the total number of carbon atoms in the ester being 10 or more.

[0164] Preferably, in the case of esters of monohydric alcohols, at least one of the alcohol and acid from which the esters of the invention are derived is branched.

[0165] Among the monoesters of monoacids and monohydric alcohols, mention may be made of ethyl palmitate, ethylhexyl palmitate, isopropyl palmitate, dicaprylyl carbonate, alkyl myristates such as isopropyl myristate or ethyl myristate, isocetyl stearate, 2-ethylhexyl isononanoate, isononyl isononanoate, isodecyl neopentanoate, and isostearyl neopentanoate.

[0166] C4~C22 Dicarboxylic or tricarboxylic acids and C1-C 22 Esters with alcohols, and mono-, di- or tricarboxylic acids and non-sugar C4-C 26 Esters with dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy alcohols can also be used.

[0167] Mention may in particular be made of the following: diethyl sebacate, isopropyl lauroyl sarcosinate, diisopropyl sebacate, bis(2-ethylhexyl) sebacate, diisopropyl adipate, di-n-propyl adipate, dioctyl adipate, bis(2-ethylhexyl) adipate, diisostearyl adipate, bis(2-ethylhexyl) maleate, triisopropyl citrate, triisocetyl citrate, triisostearyl citrate, glyceryl trilactate, glyceryl trioctanoate, trioctyldodecyl citrate, trioleyl citrate, neopentyl glycol diheptanoate and diethylene glycol diisononanoate.

[0168] As ester oil, C6-C 30 , preferably C 12 ~C 22 Sugar esters and diesters of fatty acids can be used. It is recalled that the term "sugar" means an oxygen-bearing hydrocarbon-based compound containing several alcohol functional groups, with or without aldehyde or ketone functional groups, and containing at least four carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides.

[0169] Examples of suitable sugars that may be mentioned are sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose and lactose, as well as derivatives thereof, in particular alkyl derivatives, such as methyl derivatives, for example methylglucose.

[0170] Sugar esters of fatty acids are in particular those which are composed of the aforementioned sugars and linear or branched, saturated or unsaturated C6-C 30 , preferably C 12 ~C 22 They can be selected from the group comprising esters or mixtures of esters with fatty acids, which, when unsaturated, can have from 1 to 3 conjugated or non-conjugated carbon-carbon double bonds.

[0171] The esters of this variant can also be chosen from monoesters, diesters, triesters, tetraesters and polyesters, and mixtures thereof.

[0172] These esters may be, for example, oleate, laurate, palmitate, myristate, behenate, coconut oil fatty acid esters, stearate, linoleate, linolenate, caprate and arachidonic acid esters, or mixtures thereof, such as, in particular, the mixed esters of oleopalmitate, oleostearate and palmitostearate, and pentaerythrityl tetraethylhexanoate.

[0173] More particularly, mono- and diesters are used, in particular the mono- or dioleate, stearate, behenate, oleopalmitate, linoleate, linolenate and oleostearate of sucrose, glucose or methylglucose.

[0174] An example that may be mentioned is the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.

[0175] Examples of preferred ester oils include diisopropyl adipate, dioctyl adipate, 2-ethylhexyl hexanoate, ethyl laurate, cetyl octanoate, octyldodecyl octanoate, isodecyl neopentanoate, myristyl propionate, 2-ethylhexyl 2-ethylhexanoate, 2-ethylhexyl octanoate, 2-ethylhexyl caprylate / 2-ethylhexyl caprate, methyl palmitate, ethyl palmitate, isopropyl palmitate, carbon black, and the like. Examples of suitable oleic acid salts include dicaprylyl acetate, isopropyl lauroyl sarcosinate, isononyl isononanoate, ethylhexyl palmitate, isohexyl laurate, hexyl laurate, isocetyl stearate, isopropyl isostearate, isopropyl myristate, isodecyl oleate, glyceryl tri(2-ethylhexanoate), pentaerythrityl tetra(2-ethylhexanoate), 2-ethylhexyl succinate, diethyl sebacate, and mixtures thereof.

[0176] Examples of artificial triglycerides include capryl caprylyl glyceride, glyceryl trimyristate, glyceryl tripalmitate, glyceryl trilinolenate, glyceryl trilaurate, glyceryl tricaprate, glyceryl tricaprylate, capric / caprylic triglyceride, and capric / caprylic / linolenic triglyceride.

[0177] Examples of silicone oils include linear organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane, cyclic organopolysiloxanes such as cyclohexasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane, and mixtures thereof.

[0178] Preferably, the silicone oil is chosen from liquid polydialkylsiloxanes, especially liquid polydimethylsiloxanes (PDMS), and liquid polyorganosiloxanes containing at least one aryl group.

[0179] These silicone oils may also be organically modified. The organically modified silicones that may be used according to the invention are silicone oils as defined above, which contain in their structure one or more organic functional groups that are linked via a hydrocarbon-based group.

[0180] Organopolysiloxanes are more fully defined in Chemistry and Technology of Silicones by Walter Noll, Academic Press (1968). They may be volatile or nonvolatile.

[0181] When they are volatile, the silicones are more particularly chosen from those having a boiling point between 60° C. and 260° C., and even more particularly chosen from: (i) cyclic polydialkylsiloxanes containing 3 to 7, preferably 4 to 5, silicon atoms. These are, for example, octamethylcyclotetrasiloxane, sold in particular under the name Volatile Silicone® 7207 by Union Carbide or under the name Silbione® 70045 V2 by Rhodia, decamethylcyclopentasiloxane, sold in particular under the name Volatile Silicone® 7158 by Union Carbide and under the name Silbione® 70045 V5 by Rhodia, and dodecamethylcyclopentasiloxane, sold under the name Silsoft 1217 by Momentive Performance Materials, and mixtures thereof. Mention may also be made of cyclocopolymers of the following type, such as dimethylsiloxane / methylalkylsiloxane of the formula: for example Silicone Volatile® FZ 3109, sold by Union Carbide.

[0182] [ka]

[0183] Also included are mixtures of cyclic polydialkylsiloxanes and organosilicon compounds, such as a 50 / 50 mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol, and a mixture of octamethylcyclotetrasiloxane and oxy-1,1'-bis(2,2,2',2',3,3'-hexatrimethylsilyloxy)neopentane. (ii) Contains 2 to 9 silicon atoms and has a molecular weight of 5 × 10 at 25 °C -6 m 2 Linear, volatile polydialkylsiloxanes with a viscosity of less than 10000 / s. An example is decamethyltetrasiloxane, sold in particular under the name SH 200 by Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, January 1976, pages 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics. The viscosity of silicones is measured at 25°C according to ASTM Standard 445, Annex C.

[0184] Non-volatile polydialkylsiloxanes may also be used. These non-volatile silicones are more particularly chosen from the polydialkylsiloxanes, among which mention may be made mainly of the polydimethylsiloxanes containing trimethylsilyl end groups.

[0185] Among these polydialkylsiloxanes, mention may be made, but is not limited to, the following commercially available products: the Silbione® oils of the 47 and 70 047 series or Mirasil® oils sold by the company Rhodia, such as for example the 70 047 V 500 000 oil; the Mirasil® series of oils sold by the company Rhodia; - Dow Corning 200 series oils, e.g., 60,000mm viscosity 2 / s DC 200, and - Viscasil® oils manufactured by General Electric and certain oils of the SF series manufactured by General Electric (SF 96, SF 18).

[0186] Mention may also be made of polydimethylsiloxanes containing dimethylsilanol end groups, known under the name dimethiconol (CTFA), such as the 48 series oils from Rhodia.

[0187] Among the silicones containing aryl groups, mention may be made of the polydiarylsiloxanes, especially polydiphenylsiloxanes, and polyalkylarylsiloxanes, such as phenylsilicone oils.

[0188] The phenylsilicone oil may be chosen from the phenylsilicones of the formula:

[0189] [ka]

[0190] (In the formula, R1~R 10 are each independently a saturated or unsaturated, linear, cyclic or branched C1-C 30 Hydrocarbon groups, preferably C1-C 12 a hydrocarbon group, more preferably a C1 to C6 hydrocarbon group, specifically a methyl, ethyl, propyl or butyl group; m, n, p and q each independently represent an integer of 0 to 900, preferably 0 to 500, more preferably 0 to 100, inclusive; However, the sum n+m+q is not 0.

[0191] Examples that may be mentioned are products sold under the following names: - Rhodia Silbione® oils, series 70 641; Rhodorsil® 70 633 and 763 series oils from Rhodia, - Dow Corning oil Dow Corning 556 Cosmetic Grade Fluid, - PK series silicones from Bayer, e.g. product PK20, - Certain oils of the SF series manufactured by General Electric, such as SF 1023, SF 1154, SF 1250 and SF 1265.

[0192] As the phenyl silicone oil, phenyl trimethicone (wherein R1 to R 10 is methyl, p, q and n=0, and m=1).

[0193] The organically modified liquid silicones may in particular contain polyethyleneoxy and / or polypropyleneoxy groups. Mention may thus be made of the silicone KF-6017 proposed by Shin-Etsu Chemical Co., Ltd., and the oils Silwet® L722 and L77 from Union Carbide.

[0194] The hydrocarbon oil may be selected from: - Linear or branched, optionally cyclic, C6-C 16 Lower alkanes. Examples that may be mentioned include hexane, undecane, dodecane, tridecane, and isoparaffins, such as isohexadecane, isododecane and isodecane. - Linear or branched hydrocarbons containing more than 16 carbon atoms, such as liquid paraffin, liquid petroleum jelly, polydecenes and hydrogenated polyisobutenes, such as Parleam®, and squalane.

[0195] Preferred examples of hydrocarbon oils include, for example, linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oils (e.g., liquid paraffin), paraffin, petrolatum or petrolatum, naphthalene, and the like; hydrogenated polyisobutene, isoeicosane, and decene / butene copolymers; and mixtures thereof.

[0196] The term "aliphatic" in aliphatic alcohols means containing a relatively large number of carbon atoms. Thus, alcohols having 4 or more, preferably 6 or more, more preferably 12 or more carbon atoms are included within the scope of aliphatic alcohols. The aliphatic alcohols may be saturated or unsaturated. The aliphatic alcohols may be linear or branched.

[0197] The aliphatic alcohol may have the structure R-OH, where R is selected from saturated and unsaturated, linear and branched groups containing from 4 to 40 carbon atoms, preferably from 6 to 30 carbon atoms, and more preferably from 12 to 20 carbon atoms. In at least one embodiment, R is selected from C 12 ~C 20 Alkyl group and C 12 ~C 20 alkenyl groups. R may be unsubstituted or substituted with at least one hydroxyl group.

[0198] Examples of fatty alcohols include lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, oleyl alcohol, linoleyl alcohol, palmitoleyl alcohol, arachidonyl alcohol, erucyl alcohol, and mixtures thereof.

[0199] The fatty alcohol is preferably a saturated fatty alcohol.

[0200] Thus, aliphatic alcohols are linear or branched, saturated or unsaturated C6-C 30 Alcohols, preferably linear or branched, saturated C6-C 30 Alcohols, more preferably linear or branched, saturated C 12 ~C 20 The alcohol may be selected from the group consisting of alcohols.

[0201] The term "saturated fatty alcohol" as used herein means an alcohol having a long aliphatic saturated carbon chain. A saturated fatty alcohol is any linear or branched, saturated, C6-C 30 It is preferably selected from aliphatic alcohols. Linear or branched saturated C6-C 30 Among fatty alcohols, linear or branched saturated C 12 ~C 20 Fatty alcohols are preferably used. Any linear or branched saturated C 16 ~C 20 More preferably, an aliphatic alcohol can be used. 16 ~C 20 Even more preferably, an aliphatic alcohol can be used.

[0202] Examples of saturated fatty alcohols include lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, and mixtures thereof. In one embodiment, cetyl alcohol, stearyl alcohol, octyldodecanol, hexyldecanol, or mixtures thereof (e.g., cetearyl alcohol), and behenyl alcohol can be used as the saturated fatty alcohol.

[0203] According to at least one embodiment, the fatty alcohol used in the compositions of the present invention is preferably selected from octyldodecanol, hexyldecanol, and mixtures thereof.

[0204] The (f) oil is preferably selected from vegetable oils, synthetic ester oils, and mixtures thereof, preferably vegetable oils.

[0205] The amount of (f) oil in the composition of the present invention may be 0.001 mass % or more, preferably 0.01 mass % or more, more preferably 0.1 mass % or more, based on the total mass of the composition.

[0206] The amount of (f) oil in the composition of the present invention may be 50% by mass or less, preferably 45% by mass or less, and more preferably 40% by mass or less, based on the total mass of the composition.

[0207] The amount of the (f) oil in the composition of the present invention may be 0.001% by mass to 50% by mass, preferably 0.01% by mass to 45% by mass, and more preferably 0.1% by mass to 40% by mass, relative to the total mass of the composition.

[0208] (Optional Ingredients) In addition to the above-mentioned components, the composition of the present invention may contain optional components typically used in cosmetics, specifically, surfactants / emulsifiers, for example, (a) hydrophilic or lipophilic thickeners derived from synthetic polymers other than cationic polymers, volatile or non-volatile organic solvents such as monohydric or dihydric alcohols (e.g., ethanol and pentylene glycol), anionic polymers, amphoteric polymers, nonionic polymers such as β-glucan, silicones and silicone derivatives, natural extracts derived from animals or plants other than (a) cationic polymers, waxes, etc., within a range that does not impair the effects of the present invention.

[0209] The composition of the present invention may contain the above optional components in an amount of 0.01% by mass to 30% by mass, preferably 0.05% by mass to 20% by mass, and more preferably 0.1% by mass to 10% by mass, relative to the total mass of the composition.

[0210] The amount of surfactants / emulsifiers and / or synthetic thickeners in the composition of the invention may be less than 1% by weight, preferably less than 0.1% by weight, more preferably less than 0.01% by weight, relative to the total weight of the composition. It is particularly preferred that the composition of the invention does not comprise surfactants / emulsifiers or synthetic thickeners.

[0211] The amount of anionic or amphoteric polymer in the composition of the invention may be less than 1% by weight, preferably less than 0.1% by weight, more preferably less than 0.01% by weight, relative to the total weight of the composition. It is particularly preferred that the composition of the invention does not comprise anionic or amphoteric polymers.

[0212] [pH] The pH of the compositions of the invention is less than 7.0, preferably not more than 6.5, more preferably not more than 6.0, even more preferably not more than 5.5. It may be particularly preferred for the compositions of the invention to have a pH of not more than 5.0.

[0213] In other words, the compositions of the present invention are acidic.

[0214] The pH of the composition of the present invention can be adjusted by adding (b) a monovalent non-polymeric acid or its salt, and / or at least one alkaline agent and / or (c) an organic alkaline agent. The pH of the composition of the present invention can also be adjusted by adding at least one buffering agent.

[0215] [Preparation] The composition of the present invention can be prepared by mixing the essential components described above, and, where necessary, the optional components described above.

[0216] The method and means for mixing the above essential components and optional components are not limited. Any conventional method and means can be used to mix the above essential components and optional components to prepare the composition of the present invention.

[0217] The composition of the present invention can be prepared by simple or easy mixing with conventional mixing means such as stirrers and homogenizers. Also, heating may not be required. Therefore, the preparation method of the composition of the present invention can be environmentally friendly.

[0218] [Beauty use] The composition of the present invention may be intended to be used as a cosmetic composition.Accordingly, the cosmetic composition of the present invention may be intended to be applied to keratinous materials.Keratinous materials, as used herein, refer to materials that contain keratin as a main component, and examples thereof include skin, scalp, nails, lips, hair, etc.Therefore, it is preferred that the cosmetic composition of the present invention is used in a cosmetic method for keratinous materials, particularly skin.

[0219] The cosmetic composition of the present invention may be a skin cosmetic composition, preferably a skin care composition or a skin make-up composition, more preferably a skin care composition.

[0220] [form] The compositions of the present invention may be in any form.

[0221] For example, the composition of the present invention may be in the form of a solution, dispersion or gel.

[0222] The compositions of the present invention may have a clear or translucent appearance, preferably a clear appearance.

[0223] When the composition of the present invention comprises (c) water and (f) at least one oil, the composition of the present invention may be in the form of an emulsion, for example an O / W or W / O emulsion.

[0224] [Coating] The composition of the present invention can be used to easily prepare a film, in other words, the composition of the present invention can form a film.

[0225] The present invention therefore also relates to a method for preparing a film, preferably a decorative film, optionally having a thickness of more than 0.5 μm, more preferably 1.0 μm or more, even more preferably 1.5 μm or more, comprising: applying a composition of the present invention onto a substrate, preferably a keratinous material, more preferably the skin; drying the composition; The present invention may also relate to a method comprising:

[0226] There is no upper limit to the thickness of the coating of the present invention. Thus, for example, the thickness of the coating of the present invention may be 300 μm or less, preferably 200 μm or less, and more preferably 100 μm or less.

[0227] The method for preparing the film of the present invention includes a step of applying the composition of the present invention to a substrate, preferably a keratinous material, more preferably the skin, and a step of drying the composition, so the method of the present invention does not require any spin coating or spraying, and therefore even a relatively thick film can be easily prepared.Therefore, the method for preparing the film of the present invention can prepare a relatively thick film without using any special equipment such as a spin coater and a spray machine.

[0228] If the substrate is not a keratinous material such as skin, the composition of the present invention can be applied to a substrate made of any material other than keratin. The material of the non-keratinous substrate is not limited. Two or more materials may be used in combination. Therefore, a single type of material or a combination of different types of materials can be used. In any case, it is preferable that the substrate is flexible or elastic.

[0229] When the non-keratin substrate is in the form of a sheet, it may have a thickness greater than that of the coating of the present invention in order to facilitate handling of the coating attached to the substrate sheet. The thickness of the non-keratin substrate sheet is not limited, but may be 1 μm to 5 mm, preferably 10 μm to 1 mm, more preferably 50 to 500 μm.

[0230] More preferably, the film of the present invention is removable from the non-keratin substrate. The manner of removal is not limited. For example, the film of the present invention may be peeled off from the non-keratin substrate.

[0231] The present invention also provides (1) A coating, preferably a decorative coating, optionally having a thickness of preferably more than 0.5 μm, more preferably 1.0 μm or more, even more preferably 1.5 μm or more, applying a composition of the present invention onto a substrate, preferably a keratinous material, more preferably the skin; drying the composition; a film, preferably a cosmetic film, prepared by a process comprising: and (2) A coating, preferably a decorative coating, optionally having a thickness of preferably more than 0.5 μm, more preferably 1.0 μm or more, even more preferably 1.5 μm or more, (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof, and (d) at least two fatty acids A film, preferably a cosmetic film, comprising It may also relate to.

[0232] The above explanations regarding (a) the cationic polymer and (b) the monovalent non-polymeric acid or its salt, as well as (c) water and (d) the fatty acid for the composition of the present invention can be applied to the coating (2) above.

[0233] The coating of the present invention may also include (e) an organic alkaline agent and / or (f) at least one oil. The above description of the (e) organic alkaline agent and (b) oil for the composition of the present invention is applicable to those that may be included in the coating of the present invention.

[0234] The coatings of the present invention may be biocompatible and / or biodegradable.

[0235] As used herein, the term "biocompatible" means that the coating does not have excessive interactions between the coating and cells in the body, including the skin, and the coating is not recognized as foreign by the body.

[0236] As used herein, the term "biodegradable" means that the coating can be broken down or broken down in vivo, for example by the metabolism of the organism itself or by the metabolism of microorganisms that may be present in the organism. A biodegradable coating can also be broken down by hydrolysis.

[0237] When the coatings of the present invention are biocompatible and / or biodegradable, they can, for example, be less irritating or non-irritating to the skin and / or non-polluting to the environment.

[0238] Indeed, the coating of the present invention may comprise (a) at least one cationic polymer selected from chitosan, which is a biodegradable polymer.

[0239] The film of the invention can be used for the cosmetic treatment of keratinous materials, preferably the skin, especially the face. The film of the invention can be in any shape or form.

[0240] [Cosmetic methods and uses] The present invention also provides A cosmetic method for keratinous materials such as skin, comprising: applying a composition of the present invention to a keratinous material; drying the composition to form a cosmetic film on the keratinous material; A method comprising: or Use of the composition of the present invention for preparing a cosmetic film on a keratinous material such as the skin Also relates to.

[0241] Cosmetic method means herein a non-therapeutic cosmetic method for caring for and / or making up the surfaces of keratinous materials such as the skin.

[0242] After the cosmetic film of the present invention has been applied to the skin, it is also possible to apply a make-up cosmetic composition thereon.

[0243] The present invention also provides (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof; (c) water, and (d) at least two fatty acids 1. A method for stabilizing a composition comprising: The present invention relates to a method for stabilizing the pH of the composition by controlling the pH to be less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.

[0244] In one embodiment, the present invention also provides a process for the preparation of a method for the preparation of a composition comprising the steps of: (e) at least one organic alkaline agent; Use in a composition comprising: (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof, and (c) water, and (d) at least two fatty acids and for the purpose of controlling and stabilizing the pH of the composition to be less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, and even more preferably 5.5 or less.

[0245] The above descriptions regarding (a) cationic polymer, (b) monovalent non-polymeric acid or salt thereof, (c) water, and (d) fatty acid for the compositions of the present invention are applicable to the above uses.

[0246] The composition of the present invention may also contain (e) at least one organic alkaline agent and / or (f) at least one oil. The above explanations regarding (e) the organic alkaline agent and (b) the oil for the composition of the present invention can be applied to those that can be contained in the composition of the present invention. EXAMPLES

[0247] The present invention will now be described in a more detailed manner by means of examples, which should not, however, be construed as limiting the scope of the present invention.

[0248] (Examples 1 to 3 and Comparative Examples 1 to 2) [Preparation] Each of the compositions of Examples 1 to 3 and Comparative Examples 1 and 2 was prepared by mixing the components shown in Table 1. All the numerical values ​​for the amounts of the components in Table 1 are based on "mass %" of the raw materials.

[0249] [Table 1]

[0250] Vitamin F: A mixture of linoleic acid (77% by weight), oleic acid (14% by weight), palmitic acid (5% by weight), stearic acid (2% by weight) and linolenic acid (2% by weight).

[0251] [evaluation] (stability) Each of the compositions of Examples 1 to 3 and Comparative Examples 1 and 2 was stored in a transparent container and maintained at room temperature (25° C.) for two weeks. The stability of the composition was visually observed and evaluated according to the following criteria. Good: No particles observed. Fair: small particles observed. Poor: Large particles were observed.

[0252] The results are shown in Table 1.

[0253] The compositions of Examples 1 to 3 did not form large particles, they maintained a uniform appearance and were stable, whereas the compositions of Comparative Examples 1 and 2 were not stable as large particles were observed.

[0254] (Examples 4 to 5 and Comparative Examples 3 to 4) [Preparation] Each of the compositions of Examples 4 to 5 and Comparative Examples 3 to 4 was prepared by mixing the components shown in Table 2. All numerical values ​​for the amounts of components in Table 2 are based on "mass %" of the raw materials.

[0255] [Table 2]

[0256] (Instant matte effect) Each of the compositions of Examples 4 to 5 and Comparative Examples 3 to 4 was spread over the entire contrast sheet using an automatic film applicator to form a layer of 100 μm, and was left to dry at 37° C. for 24 hours.

[0257] The reflectance of the white portion of the above sheet was measured three times as a 60° gloss value using a gloss meter (GM-268, manufactured by Konika Minolta) and averaged. The 60° gloss value of the composition of Example 4 was set as the first control. The 60° gloss value of the composition of Example 5 was compared with the first control and evaluated according to the following criteria. The 60° gloss value of the composition of Comparative Example 3 was set as the second control. The 60° gloss value of the composition of Comparative Example 4 was compared with the second control and evaluated according to the following criteria. Very good: Same Good: slightly different Defective: Different Bad:Very Different

[0258] The results are shown in Table 2.

[0259] The gloss of the composition of Example 5 was the same as that of the composition of Example 4. It can be seen that the immediate mattifying effect of the composition of the present invention containing multiple fatty acids is not affected by the inclusion of oil.

[0260] The gloss of the composition of Comparative Example 4 was significantly different from that of the composition of Comparative Example 3. It can be seen that when only one fatty acid is used, the immediate matte effect is substantially affected by the inclusion of oil.

[0261] (Examples 1 and 6 to 11) [Preparation] Each of the compositions of Examples 1 and 6 to 11 was prepared by mixing the components shown in Table 3. All numerical values ​​for the amounts of components in Table 3 are based on "mass %" of the raw materials.

[0262] [Table 3]

[0263] Vitamin F: A mixture of linoleic acid (77% by weight), oleic acid (14% by weight), palmitic acid (5% by weight), stearic acid (2% by weight) and linolenic acid (2% by weight).

[0264] [evaluation] (Instant matte effect) Each of the compositions of Examples 1 and 6 to 11 was spread over the entire contrast sheet with an automatic film applicator to form a layer of 100 μm, and was left to dry at 37° C. for 24 hours.

[0265] The reflectance of the white portion of the above sheet was measured three times as the 60° gloss value using a gloss meter (GM-268, manufactured by Konika Minolta) and the average was calculated. The 60° gloss value of the composition of Example 1 was set as a control. The 60° gloss values ​​of the compositions of Examples 6 to 11 were compared with the control and evaluated according to the following criteria. Very good: Same Good: slightly different Defective: Different Bad:Very Different

[0266] The results are shown in Table 3.

[0267] The gloss of the compositions of Examples 6 to 11 was the same as that of the composition of Example 1. It can be seen that the immediate matte effect of the compositions of the present invention containing multiple fatty acids is not affected by the inclusion of oil, regardless of the amount of oil.

Claims

1. (a) at least one cationic polymer; (b) at least one monovalent non-polymeric acid or salt thereof; (c) water, and (d) at least two fatty acids A composition, preferably a cosmetic composition, more preferably a dermocosmetic composition, comprising: A composition, wherein the pH of said composition is less than 7.0, preferably 6.5 or less, more preferably 6.0 or less, even more preferably 5.5 or less.

2. 2. The composition of claim 1, wherein the (a) cationic polymer has a molecular weight (Da) of greater than 20,000.

3. 3. The composition according to claim 1 or 2, wherein the (a) cationic polymer is selected from the group consisting of cyclopolymers of alkyldiallylamine and cyclopolymers of dialkyldiallylammonium, such as (co)polydiallyldialkylammonium chloride, (co)polyamines, such as (co)polylysine and chitosan, cationic (co)polyamino acids, such as collagen, cationic cellulose polymers, and salts thereof.

4. The composition according to any one of claims 1 to 3, wherein the amount of the (a) cationic polymer in the composition is from 0.001% to 15% by weight, preferably from 0.005% to 10% by weight, more preferably from 0.01% to 5% by weight, relative to the total weight of the composition.

5. 5. The composition according to claim 1, wherein the (b) monovalent non-polymeric acid is a monovalent non-polymeric organic acid, preferably a monovalent non-polymeric carboxylic acid, more preferably a monovalent hydroxy acid, such as lactic acid and salicylic acid.

6. The composition according to any one of claims 1 to 5, wherein the amount of the (b) monovalent non-polymeric acid or salt thereof in the composition is 0.001% by weight to 15% by weight, preferably 0.005% by weight to 10% by weight, and more preferably 0.01% by weight to 5% by weight, based on the total weight of the composition.

7. The composition according to any one of claims 1 to 6, wherein the amount of (c) water in the composition is from 20% by weight to 99% by weight, preferably from 30% by weight to 95% by weight, more preferably from 50% by weight to 90% by weight, based on the total weight of the composition.

8. 8. The composition according to claim 1, wherein the (d) fatty acid is selected from linoleic acid, oleic acid, linolenic acid, palmitic acid, stearic acid, and mixtures thereof, preferably linoleic acid, oleic acid, and mixtures thereof.

9. The composition according to any one of claims 1 to 8, wherein the amount of the (d) fatty acid in the composition is from 0.001% to 30% by mass, preferably from 0.005% to 20% by mass, and more preferably from 0.01% to 10% by mass, based on the total mass of the composition.

10. 10. The composition of claim 1, further comprising: (e) at least one organic alkaline agent.

11. 11. The composition according to claim 10, wherein the (e) organic alkaline agent is selected from the group consisting of alkanolamines and basic amino acids, preferably from the group consisting of mono-, di- and triethanolamine, lysine, histidine, arginine, and mixtures thereof, more preferably from the group consisting of triethanolamine, arginine, and mixtures thereof.

12. The composition according to claim 10 or 11, wherein the amount of the (e) organic alkaline agent in the composition is 0.001% by mass to 15% by mass, preferably 0.005% by mass to 10% by mass, and more preferably 0.01% by mass to 5% by mass, based on the total mass of the composition.

13. 13. The composition of claim 1, further comprising: (f) at least one oil.

14. The composition according to claim 13, wherein the amount of the (f) oil in the composition is from 0.001% to 50% by weight, preferably from 0.01% to 45% by weight, more preferably from 0.1% to 40% by weight, based on the total weight of the composition.

15. A cosmetic method for keratinous materials such as skin, comprising: applying to said keratinous material a composition according to any one of claims 1 to 14; drying the composition to form a cosmetic film on the keratinous material; Including beauty methods.

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