Space purifying device

Abstract

To provide a space purifying device stably generating a desired amount of hypochlorous acid gas without supplying any aqueous solution including a chloride ion from outside for a long time.SOLUTION: An air purifying device 1 includes: an electrolysis tank 10 for storing a first aqueous solution L1; a supply tank 20 for storing a second aqueous solution L2 and supplying a chloride ion to the first aqueous solution L1; an electrolysis tank side positive electrode 11 and an electrolysis tank side negative electrode 12 provided to the electrolysis tank 10; a supply tank side negative electrode 21 provided to the supply tank 20; a negative ion exchange membrane 30 connecting the electrolysis tank 10 and the supply tank 20 so as to transmit the negative ion; and an electric current control part 40 supplying the chloride ion included in the second aqueous solution L2 to the first aqueous solution L1 through the negative ion exchange membrane 30 by controlling an electric current so as to compensate the chloride ion included in the first aqueous solution L1 reduced by electrolysis.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a space purification device. [Background technology]

[0002] Patent Document 1 discloses an air purifier that removes bacteria, fungi, viruses, odors, and the like from the air using hypochlorous acid generated by electrolyzing an aqueous solution containing chloride ions. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2019-174032 A Summary of the Invention [Problem to be solved by the invention]

[0004] When a conventional space purification device is miniaturized, the tank for storing the aqueous solution used for electrolysis is also made smaller. When the tank is made smaller, the amount of aqueous solution that can be stored is reduced compared to conventional space purification devices. Therefore, when electrolysis is repeatedly performed in a miniaturized space purification device, the chloride ion concentration in the aqueous solution is likely to decrease, and there is a problem that the amount of hypochlorous acid generated is not stable.

[0005] The present invention has been made in consideration of the above problems, and provides a space purification device that can stably generate a desired amount of hypochlorous acid gas for a long period of time without supplying an aqueous solution containing chloride ions from the outside. [Means for solving the problem]

[0006] The spatial purification device according to the present invention includes an electrolytic cell for storing a first aqueous solution containing chloride ions, a supply cell for storing a second aqueous solution containing a higher concentration of chloride ions than the first aqueous solution and supplying chloride ions to the first aqueous solution, an electrolytic cell-side anode and an electrolytic cell-side cathode provided in the electrolytic cell, a supply cell-side cathode provided in the supply cell, an anion exchange membrane connecting the electrolytic cell and the supply cell to allow anions to pass therethrough based on a voltage applied between the electrolytic cell-side anode and the supply cell-side cathode, and a first voltage applied between the electrolytic cell-side anode and the electrolytic cell-side cathode provided in the electrolytic cell. the anion exchange membrane electrolysis unit is provided between the electrolytic cell and the supply cell and performs membrane electrolysis via the anion exchange membrane by passing a second current between the electrolytic cell-side anode and the supply cell-side cathode; and the current control unit controls the second current so as to replenish chloride ions contained in the second aqueous solution that have been reduced by the diaphragm-less electrolysis, thereby causing the chloride ions contained in the second aqueous solution to pass through the anion exchange membrane and be supplied to the first aqueous solution. Effect of the Invention

[0007] According to the present invention, it is possible to provide a space purification device that can stably generate a desired amount of hypochlorous acid gas for a long period of time without supplying an aqueous solution containing chloride ions from the outside. [Brief description of the drawings]

[0008] [Figure 1] FIG. 1 is a perspective view showing a spatial purification device according to the first embodiment. [Diagram 2] FIG. 2 is a partial cross-sectional front view showing the spatial purification device of FIG. [Diagram 3] FIG. 3 is a block diagram showing a current control unit according to the first embodiment. [Figure 4] FIG. 4 is a front cross-sectional view showing Modification 1 of the electrolytic cell and the supply cell included in the spatial purification device according to the first embodiment. [Diagram 5] FIG. 5 is a front cross-sectional view showing Modification 2 of the electrolytic cell and the supply cell included in the spatial purification device according to the first embodiment. [Figure 6] FIG. 6 is a schematic front view showing a spatial purification device according to the second embodiment. [Figure 7] FIG. 7 is a plan view showing the spatial purification device according to the second embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] Hereinafter, specific embodiments of the present invention will be described in detail with reference to the drawings.

[0010] The right-handed xyz coordinate system shown in the drawings is for the convenience of explaining the positional relationship of the components. Unless otherwise specified, the positive direction of the z axis is the vertical upward direction. In addition, the xy plane is a horizontal plane, and is common to all drawings. <Embodiment 1> 1 is a perspective view showing an outline of the space purification device 1 according to the first embodiment. The space purification device 1 performs electrolysis of a first aqueous solution L1 containing chloride ions in an electrolytic cell 10 described later, to generate and volatilize hypochlorous acid. The space purification device 1 removes bacteria, fungi, viruses, odors, and the like contained in the air in the external space of the space purification device 1 by causing the volatilized hypochlorous acid to flow out of a housing B constituting the space purification device 1.

[0011] The space purification device 1 is installed indoors. The installation location of the space purification device 1 is preferably a location where air flow can occur. More specifically, the installation location of the space purification device 1 includes, for example, inside a so-called air conditioner, around an electric fan, around a circulator, around a ceiling fan, inside a humidifier, inside an air purifier, on a desk, etc.

[0012] The spatial purification device 1 includes a housing B, an electrolytic cell 10, a supply cell 20, an anion exchange membrane 30, and a current control unit 40.

[0013] The housing B houses the electrolytic cell 10, the supply cell 20, the anion exchange membrane 30, and the current control unit 40. That is, the space purification device 1 may be a unit integrated with the housing B. The shape of the housing B can be appropriately changed depending on the location where the space purification device 1 is installed, and may be, for example, a rectangular parallelepiped or cylindrical shape. The space purification device 1 has a small size that can be stored inside an air conditioner, for example, about 10 cm x 7 cm x 4 cm.

[0014] The electrolytic cell 10 is a cell for storing a first aqueous solution L1 containing chloride ions. The electrolytic cell 10 has, for example, a box-like shape. Fig. 1 shows a state in which the first aqueous solution L1 is stored in the electrolytic cell 10. The first aqueous solution L1 is, for example, a dilute sodium chloride aqueous solution or a dilute potassium chloride aqueous solution having a predetermined chloride ion concentration.

[0015] The "predetermined chloride ion concentration" of the first aqueous solution L1 includes both a chloride ion concentration having a predetermined numerical range and a chloride ion concentration having a predetermined numerical value. More specifically, the chloride ion concentration of the first aqueous solution L1 may be, for example, 1 g / L to 50 g / L, or 10 g / L. In other words, the mass percent concentration of, for example, a dilute sodium chloride aqueous solution or a dilute potassium chloride aqueous solution may be 0.1% to 5%, or 1%. By setting the predetermined chloride ion concentration to the numerical range or numerical value, hypochlorous acid necessary for space purification can be generated while suppressing the generation of chlorine that may be generated at the same time.

[0016] The supply tank 20 is a tank for storing the second aqueous solution L2 containing chloride ions. The chloride ions contained in the second aqueous solution L2 in the supply tank 20 permeate through the anion exchange membrane 30 and are supplied to the first aqueous solution L1 in the electrolysis tank 10.

[0017] The supply tank 20 is a tank for storing the second aqueous solution L2 containing chloride ions and supplying the chloride ions to the first aqueous solution L1. FIG. 1 shows a state in which the second aqueous solution L2 is stored in the supply tank 20. The chloride ion concentration of the second aqueous solution L2 is higher than that of the first aqueous solution L1. The second aqueous solution L2 is, for example, a saturated aqueous sodium chloride solution, a high-concentration aqueous sodium chloride solution, a saturated aqueous potassium chloride solution, a high-concentration aqueous potassium chloride solution, or a high-concentration aqueous hydrochloric acid solution. More specifically, the second aqueous solution L2 is, for example, a 10% to 27% aqueous sodium chloride solution, a 10% to 29% aqueous potassium chloride solution, or a 10% to 25% aqueous hydrochloric acid solution. The second aqueous solution L2 may be in a state in which sodium chloride or potassium chloride is precipitated and precipitated at the bottom of the supply tank 20.

[0018] Assuming continuous use for 8 hours every day for a year, the respective volumes of the electrolytic cell 10 and the supply cell 20 are preferably set such that, for example, the volume of the supply cell 20 is about 12 times or more the volume of the electrolytic cell 10. By setting such a volume ratio, the supply cell 20 can store the second aqueous solution L2 containing a sufficient amount of chloride ions required to be supplied to the first aqueous solution L1 of the electrolytic cell 10. Therefore, chloride ions can be stably supplied from the second aqueous solution L2 stored in the supply cell 20 to the first aqueous solution L1 stored in the electrolytic cell 10. The amount of the first aqueous solution L1 stored in the electrolytic cell 10 is, for example, about 2 to 10 mL.

[0019] The anion exchange membrane 30 is a membrane-like member that connects the electrolytic cell 10 and the supply cell 20 in a manner that allows anions to pass therethrough, based on a voltage applied between the electrolytic cell 10 and the supply cell 20. More specifically, when a voltage is applied between the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21, which will be described later, membrane-type electrolysis is performed via the anion exchange membrane 30. By the membrane-type electrolysis using the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21, chloride ions contained in the second aqueous solution L2 permeate the anion exchange membrane 30 and are supplied to the first aqueous solution L1 (indicated by a thick black arrow in the negative direction of the x-axis).

[0020] The anion exchange membrane 30 in this embodiment is not a type of anion exchange membrane through which anions permeate due to osmotic pressure without using electricity. In addition, the anion exchange membrane 30 does not allow sodium ions, which are cations, to permeate. More specifically, when chloride ions contained in the second aqueous solution L2 are permeated through the anion exchange membrane 30 and supplied to the first aqueous solution L1 by membrane electrolysis using the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21, sodium ions, which are cations, do not permeate the anion exchange membrane 30. The anion exchange membrane 30 is, for example, a hydrocarbon-based anion exchange membrane, and includes membranes having monovalent anion selective permeability, alkali resistance, and high temperature resistance.

[0021] The anion exchange membrane 30 is disposed between the electrolytic cell 10 and the supply cell 20. For example, the surface of the electrolytic cell 10 facing the supply cell 20 (the yz plane on the positive side of the x-axis) and the surface of the supply cell 20 facing the electrolytic cell 10 (the yz plane on the negative side of the x-axis) may each be formed of a frame-shaped member. When the opposing surfaces of the electrolytic cell 10 and the supply cell 20 are each formed of a frame-shaped member, the anion exchange membrane 30 may be disposed so as to be fitted into the frame-shaped member.

[0022] The current control unit 40 controls the current used in the diaphragmless electrolysis and the diaphragm-containing electrolysis. More specifically, the current control unit 40 controls the current used in the diaphragmless electrolysis performed using a pair of electrolytic cell side anode 11 and electrolytic cell side cathode 12 arranged in the electrolytic cell 10. The current control unit 40 also controls the current used in the diaphragm-containing electrolysis performed via the anion exchange membrane 30 using a pair of electrolytic cell side anode 11 and supply cell side cathode 21 across the electrolytic cell 10 and the supply cell 20. The electrolytic cell side anode 11 is used for both the diaphragmless electrolysis and the diaphragm-containing electrolysis. That is, the spatial purification device 1 according to this embodiment includes one anode and two cathodes, that is, a total of three electrodes. Since the supply cell 20 includes only a cathode, No chlorine is produced through the chemical reaction described below.

[0023] Hereinafter, the details of each component will be described more specifically with reference to FIGS.

[0024] As shown in FIG. 1, the electrolytic cell 10 includes an electrolytic cell-side anode 11 , an electrolytic cell-side cathode 12 , a wire 13 , a wire 14 , an inlet 15 , a mixing space 16 and an outlet 17 .

[0025] The electrolytic cell side anode 11 and the electrolytic cell side cathode 12 are a pair of electrodes used in the electrolysis of the first aqueous solution L1. As shown in Fig. 1, no diaphragm such as an ion exchange membrane is provided between the electrolytic cell side anode 11 and the electrolytic cell side cathode 12. That is, the electrolysis of the first aqueous solution L1 performed using the pair of the electrolytic cell side anode 11 and the electrolytic cell side cathode 12 is membrane-less electrolysis. Hypochlorous acid used for space purification is generated by the membrane-less electrolysis of the first aqueous solution L1 performed using the pair of the electrolytic cell side anode 11 and the electrolytic cell side cathode 12.

[0026] The electrolytic cell side anode 11 and the electrolytic cell side cathode 12 each have a plate shape. That is, the electrolytic cell side anode 11 is an electrolytic cell side anode plate 11 having a plate shape, and the electrolytic cell side cathode 12 is an electrolytic cell side cathode plate 12 having a plate shape. The plate shape includes a rectangular shape and a rectangular shape. Hereinafter, the electrolytic cell side anode 11 is also referred to as the electrolytic cell side anode plate 11. The electrolytic cell side cathode 12 is also referred to as the electrolytic cell side cathode plate 12.

[0027] As an example, a case where the plate shape of the electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12 are rectangular will be described. The electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12 are arranged such that the short side direction of the rectangle is along the vertical direction (z-axis direction). This arrangement can prevent bubbles generated by chemical reactions from adhering to both sides of the rectangle of each electrode. Furthermore, compared to a case where the long side direction of the rectangle is arranged along the vertical direction (z-axis direction), when the short side direction is arranged along the vertical direction (z-axis direction), it is possible to prevent bubbles generated at the lower part (negative side of the z-axis) of the electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12 from adhering to the upper part (positive side of the z-axis) of the electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12.

[0028] The electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are arranged such that the longitudinal direction of the rectangle is along the horizontal direction (y-axis direction). In other words, the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are arranged such that the planes (yz planes) of their respective rectangles face each other with a predetermined distance between them. The predetermined distance is a distance suitable for electrolysis performed using a pair of the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12.

[0029] The electrolytic cell-side anode plate 11 comprises an electrolytic cell-side anode plate immersed portion 11a and an electrolytic cell-side anode plate protruding portion 11b. Similarly, the electrolytic cell-side cathode plate 12 comprises an electrolytic cell-side cathode plate immersed portion 12a and an electrolytic cell-side cathode plate protruding portion 12b.

[0030] The electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12 are inserted from the outside of the electrolytic cell 10 toward the inside. In FIG. 1, as an example, the electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12 are inserted from the side of the electrolytic cell 10 (the xz plane side on the y-axis negative side) toward the horizontal direction (y-axis direction). The electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a inserted into the electrolytic cell 10 are disposed on the inside side of the electrolytic cell 10, and are entirely immersed in the first aqueous solution L1. In other words, the first aqueous solution L1 is stored in the electrolytic cell 10 such that the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a are entirely immersed. That is, the first aqueous solution L1 is stored in the electrolytic cell 10 so that the liquid level S1 of the first aqueous solution L1 exceeds the upper ends (the ends on the positive side of the z-axis) of the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a.

[0031] The electrolytic cell side anode plate protrusion 11b and the electrolytic cell side cathode plate protrusion 12b are provided on the outside of the electrolytic cell 10. The wiring 13 and the wiring 14 are lines through which a current flows. The electrolytic cell-side anode plate protrusion 11b is electrically connected to a current control unit 40 via the wiring 13, and the electrolytic cell-side cathode plate protrusion 12b is electrically connected to a current control unit 40 via the wiring 13.

[0032] As the electrolytic cell side anode plate 11 and the electrolytic cell side cathode plate 12, for example, a platinum iridium titanium electrode, a platinum electrode, a ruthenium titanium electrode, an iridium titanium oxide electrode, or the like may be used.

[0033] The inlet 15 is an opening through which air from the external space of the housing B flows in. That is, the inlet 15 is an opening through which air from the external space of the spatial purification device 1 flows in. In FIG. 1, the inlet 15 is provided on the upper surface of the electrolytic cell 10 (xy plane on the z-axis positive side) as an example, but it is sufficient that the inlet 15 is located above the liquid level S1 of the first aqueous solution L1. The shape of the inlet 15 may be, for example, cylindrical as shown in FIG. 1, or may be a square tube.

[0034] The mixing space 16 is a space formed on the upper side (z-axis positive side) of the electrolytic cell 10 in a state where the first aqueous solution L1 is stored in the electrolytic cell 10. The mixing space 16 is a space for mixing hypochlorous acid generated by membrane-free electrolysis of the first aqueous solution L1 using a pair of electrolytic cell-side anode plate 11 and electrolytic cell-side cathode plate 12 with air in the external space flowing in from the inlet 15. The hypochlorous acid generated by membrane-free electrolysis includes hypochlorous acid gas that has been volatilized and gasified, and hypochlorous acid dissolved in the first aqueous solution L1. The hypochlorous acid gas is contained in the air that flows in from the inlet 15 and flows out to the external space from the outlet 17 described later. The hypochlorous acid dissolved in the first aqueous solution L1 flows out to the external space from the outlet 17 described later by gas-liquid contact with the air that flows in from the inlet 15.

[0035] The outlet 17 is an opening through which the mixed air, which is a mixture of the air flowing in from the inlet 15 and the hypochlorous acid generated by the membraneless electrolysis of the first aqueous solution L1, flows out to the external space of the housing B. That is, the outlet 17 is an opening through which the mixed air flows out to the external space of the space purification device 1. In FIG. 1, the outlet 17 is provided on the upper surface (xy plane on the z-axis positive side) of the electrolytic cell 10 as an example, similar to the inlet 15, but it may be located above the liquid level of the first aqueous solution L1. The shape of the outlet 17 is similar to that of the inlet 15, and may be, for example, cylindrical as shown in FIG. 1, or may be rectangular.

[0036] The inlet 15 and the outlet 17 may be provided with a cover (not shown) that can be opened or closed or that can be attached or detached. The cover may be configured to be in a closed state when the space purification device 1 is transported or moved, and to be opened or detached when the space purification device 1 is used. In addition, although the inlet 15 and the outlet 17 are described as having separate configurations, the inlet 15 and the outlet 17 may each serve as both an inlet and an outlet depending on the direction of the wind flowing into the space purification device 1.

[0037] The air containing hypochlorous acid that flows out from the outlet 17 to the space outside the space purification device 1 purifies the space. That is, the air containing hypochlorous acid removes bacteria, fungi, viruses, odors, and the like contained in the air in the space outside the housing B.

[0038] The supply tank 20 includes a supply tank side cathode 21, a wiring 22, and an outlet 23. The supply tank side cathode 21 is an electrode used in combination with the electrolytic cell side anode 11 for electrolysis of the second aqueous solution L2. As shown in FIG. 1, an anion exchange membrane 30 is disposed between the electrolytic cell side anode 11 and the supply tank side cathode 21. That is, the electrolysis of the second aqueous solution L2 performed using the pair of the electrolytic cell side anode 11 and the supply tank side cathode 21 is electrolysis with a diaphragm. That is, the electrolytic cell side anode 11 is used for both electrolysis without a diaphragm and electrolysis with a diaphragm. Chloride ions are supplied from the second aqueous solution L2 to the first aqueous solution L1 by the electrolysis with a diaphragm of the second aqueous solution L2 performed using the pair of the electrolytic cell side anode 11 and the supply tank side cathode 21.

[0039] The supply tank side cathode 21 is a supply tank side cathode plate 21 having a plate shape. The plate shape includes a rectangular shape and a rectangular shape. Hereinafter, the supply tank side cathode 21 will also be referred to as a supply tank side cathode plate 21.

[0040] As an example, a case will be described where the supply tank side cathode plate 21 is also rectangular in plate shape, like the electrolytic tank side anode plate 11. As shown in Fig. 1, the supply tank side cathode plate 21 is arranged such that the short side of the rectangle is aligned along the vertical direction (z-axis direction). Moreover, the supply tank side cathode plate 21 is arranged such that the long side of the rectangle is aligned along the horizontal direction (y-axis direction).

[0041] The electrolytic cell side anode plate 11 and the supply cell side cathode plate 21 are each in close proximity to the anion exchange membrane 30. In this specification, "close proximity" includes both a state in which the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21 are close to the anion exchange membrane 30 with a predetermined gap therebetween, and a state in which the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21 are in contact with the anion exchange membrane 30.

[0042] The plane (yz plane on the x-axis positive side) of the rectangular plate on the anion exchange membrane 30 side of the electrolytic cell side anode plate 11 is defined as plane P1. The plane (yz plane on the x-axis negative side) of the rectangular plate on the anion exchange membrane 30 side of the supply cell side cathode plate 21 is defined as plane P2. The planes P1 and P2 are disposed opposite each other via the anion exchange membrane 30. This arrangement allows a uniform electric field to be generated between the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21.

[0043] The electrolytic cell-side anode plate 11 is disposed between the electrolytic cell-side cathode plate 12 and the anion exchange membrane 30. This arrangement makes it possible to keep the potential difference between the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12, and the potential difference between the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21 small.

[0044] The supply tank side cathode plate 21 includes a supply tank side cathode plate immersed portion 21a and a supply tank side cathode plate protruding portion 21b. The supply tank side cathode plate 21 is inserted from the outside of the electrolytic cell 10 toward the inside. In FIG. 1, as an example, the supply tank side cathode plate 21 is inserted from the side of the electrolytic cell 10 (the xz plane side on the y-axis negative side) toward the horizontal direction (y-axis direction). The supply tank side cathode plate immersed portion 21a inserted into the supply tank 20 is disposed on the inside side of the supply tank 20 and is entirely immersed in the second aqueous solution L2. In other words, the second aqueous solution L2 is stored in the supply tank 20 so that the entire supply tank side cathode plate immersed portion 21a is immersed. That is, the second aqueous solution L2 is stored in the supply tank 20 so that the liquid level S2 of the second aqueous solution L2 exceeds the upper end (the end on the z-axis positive side) of the supply tank side cathode plate immersed portion 21a.

[0045] 1, the supply tank side cathode plate protrusion 21b is disposed on the external side of the supply tank 20. The wiring 22 is a line through which a current flows. The supply tank side cathode plate protrusion 21b is electrically connected to a current control unit 40 via the wiring 22.

[0046] As the supply tank side cathode plate 21, for example, a platinum iridium titanium electrode, a platinum electrode, a ruthenium titanium electrode, an iridium titanium oxide electrode, or the like may be used.

[0047] The outlet 23 is an opening for discharging hydrogen gas generated by the diaphragm electrolysis of the second aqueous solution L2 to the external space of the housing B. The outlet 23 may be, for example, a check valve. When a check valve is used as the outlet 23, hydrogen gas inside the supply tank 20 is discharged to the external space, but the inflow of gas such as air from the external space can be suppressed. When the diaphragm electrolysis of the second aqueous solution L2 is repeated, hydrogen gas accumulates inside the supply tank 20, and the internal pressure of the supply tank 20 increases. The pressure opens the check valve, and hydrogen gas is discharged to the external space of the supply tank 20.

[0048] FIG. 2 is a partial front cross-sectional view showing the space purification device 1 shown in FIG. The case B is omitted. As shown in Fig. 2, the space purification device 1 may further include a water level detection unit 18 and a water supply unit 19. The water level detection unit 18 detects the position of the liquid level S1 in the first aqueous solution L1. The water level detection unit 18 is, for example, a water level sensor. The water level detection unit 18 is disposed above (on the positive side of the z-axis) the upper ends (parts on the positive side of the z-axis) of at least the electrolytic cell side anode plate immersed portion 11a, the electrolytic cell side cathode plate immersed portion 12a, and the supply cell side cathode plate immersed portion 21a.

[0049] The water supply unit 19 supplies water to the electrolytic cell 10 based on the position of the liquid level S1 detected by the water level detection unit 18. More specifically, the water level supply unit 19 supplies water to the electrolytic cell 10 so that the water level does not fall below the upper ends (portions on the z-axis positive side) of the electrolytic cell-side anode plate immersed portion 11a, the electrolytic cell-side cathode plate immersed portion 12a, and the supply cell-side cathode plate immersed portion 21a. The water supply unit 19 may be, for example, a Peltier element that can cool and condense moisture contained in the air into droplets, or a water tank that can store water. The water supply unit 19 may be located at a position where it can supply water to the electrolytic cell 10, and may be located on the upper side, side, or bottom side of the electrolytic cell 10.

[0050] When the spatial purification device 1 includes the water level detection unit 18 and the water supply unit 19, the electrolytic cell-side anode plate immersed portion 11a and the electrolytic cell-side cathode plate immersed portion 12a can be maintained immersed in the first aqueous solution L1. This prevents the electrolytic cell-side anode plate immersed portion 11a and the electrolytic cell-side cathode plate immersed portion 12a from being exposed to air due to a decrease in the first aqueous solution L1, thereby maintaining the electrolysis efficiency of the diaphragm-less electrolysis.

[0051] 2, the spatial purification device 1 according to this embodiment includes a non-diaphragm electrolysis unit E1 and a diaphragm electrolysis unit 20. The current control unit 40 can control the chemical reaction occurring in the non-diaphragm electrolysis unit E1 and the chemical reaction occurring in the diaphragm electrolysis unit E2 by controlling a first current passed through the non-diaphragm electrolysis unit E1 and a second current passed through the diaphragm electrolysis unit E2.

[0052] The diaphragm-free electrolysis unit E1 is provided in the electrolytic cell 10. The diaphragm-free electrolysis unit E1 produces hypochlorous acid by electrolyzing the first aqueous solution L1 without a diaphragm by passing a first current between the electrolytic cell-side anode 11 and the electrolytic cell-side cathode 12. In other words, the diaphragm-free electrolysis unit E1 includes the electrolytic cell-side anode 11 and the electrolytic cell-side cathode 12.

[0053] The membrane-equipped electrolysis unit E2 is provided across the electrolytic cell 10 and the supply cell 20. A second current is passed between the electrolytic cell-side anode 11 and the supply cell-side cathode 21, thereby performing membrane-equipped electrolysis via the anion exchange membrane 30. In other words, the membrane-equipped electrolysis unit E2 includes the electrolytic cell-side anode 11, the supply cell-side cathode 21, and the anion exchange membrane 30.

[0054] Here, a detailed description will be given of the chemical reaction occurring in the membrane-less electrolysis section E1 provided in the electrolytic cell 10 and the chemical reaction occurring in the membrane-containing electrolysis section E2 provided between the electrolytic cell 10 and the supply cell 20. The following describes the case where the first aqueous solution L1 and the second aqueous solution L2 containing chloride ions are aqueous sodium chloride solutions. [Diaphragmless electrolysis section E1 (electrolytic cell 10)] Sodium chloride (NaCl) contained in a sodium chloride solution is Na + and Cl - When a certain voltage is applied to the membrane-less electrolysis section E1, a current flows, electrons move, and the following chemical reaction occurs: Reaction formula (a): Electrolyzer anode 11 (chlorine generation)

[0055] [ka] Reaction formula (b): Electrolyzer side cathode 12 (hydrogen generation)

[0056] [ka] Reaction formula (c): Electrolyzer anode 11 (oxygen generation)

[0057] [ka] Reaction formula (d): In the first aqueous solution L1 (hypochlorous acid generation)

[0058] [ka] Reaction formula (e): Hypochlorous acid generation reaction at the electrolytic cell side anode 11 (formula (a) + formula (d))

[0059] [ka] Reaction formula (f): Anion exchange membrane 30 A voltage is applied to the membrane-less electrolysis unit E1, a current flows, and the first aqueous solution L1 stored in the electrolysis cell 10 converts electrons (e - When one of the anions is lost, chloride ions Cl are transferred from the second aqueous solution L2 stored in the supply tank 20 through the anion exchange membrane 30 to the first aqueous solution L1 in the electrolytic tank 10. - is supplied.

[0060] [ka] Here, the ratio of the current used in the hypochlorous acid generation reaction in reaction formula (e) is "x", and the ratio of the current used in the oxygen generation reaction in reaction formula (c) is "1-x". In addition, the ratio of the current used in reaction formula (b) of electrolysis without a diaphragm is "y", and the ratio of the current used in reaction formula (f) of electrolysis with a diaphragm is "1-y". Applying the above x and y to reaction formula (b) + (c) + (e) + (f), the following reaction formula (g) is obtained. Reaction (g): Reaction (b)+(c)+(e)+(f)

[0061] [ka] When membrane-free electrolysis is performed in the membrane-free electrolysis section E1, the chloride ions in the electrolytic cell 10 are consumed and therefore reduced, but in the space purification device 1 of this embodiment, chloride ions are supplied from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic cell 10.

[0062] Here, the amount of chloride ions (Cl) consumed by the membrane-free electrolysis is transferred from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic tank 10. - ) is supplied, In electrolytic cell 10, Cl - The conditions under which there is no apparent increase or decrease are as follows. In this reaction, hypochlorous acid (HClO) evaporates as a gas, so it is not included in the following formula. Reaction formula (h): Cl - Conditions under which there is no apparent increase or decrease in

[0063] [ka] After transformation, this gives the following reaction equation (i). Reaction (i): A modification of reaction (h)

[0064] [ka] Substituting y into the above reaction equation (g), we obtain the following reaction equation (j). Reaction (j): Reaction (g) + (i)

[0065] [ka] After transformation, the following reaction equation (k) is obtained. Reaction equation (k): A transformation of reaction equation (j)

[0066] [ka] According to the above reaction formula (k), for example, when two electrons flow to the non-diaphragm electrolysis unit E1, one hypochlorous acid (HClO) is generated. For example, when four electrons flow to the non-diaphragm electrolysis unit E1, one oxygen is generated. For example, when two electrons flow to the non-diaphragm electrolysis unit E1, one hydrogen is generated.

[0067] In addition, since the acid dissociation constant of hypochlorous acid (HClO) is about 7.5, it is necessary to maintain the pH of the first aqueous solution L1 unchanged. In the above reaction formula (k), the hydroxide ions and hydrogen ions, which are the cause of the change in pH, react to form water and disappear from the reaction formula. Therefore, the amount of chloride ions (Cl) consumed by the membraneless electrolysis is transferred from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic tank 10. - ) is supplied to the electrolytic cell 10, and Cl - When the condition is such that there is no apparent increase or decrease in pH, the increase or decrease in pH can also be suppressed.

[0068] When the number of electrons flowing to the membraneless electrolysis section E1 changes as described above, that is, when the ratio of the current flowing to the membraneless electrolysis section E1 and the current flowing to the membraneless electrolysis section E2 changes, the supply amount of chloride ions supplied from the supply tank 20 to the electrolysis tank 10 changes. For example, when the ratio of the current used for membraneless electrolysis changes from the supply tank 20 to the chloride ion (Cl - ) is supplied to the electrolytic cell 10. - When the current ratio is greater than the condition where the current does not increase or decrease (reaction formula (l) below), the Cl - The supply of Cl in the electrolytic cell 10 decreases. - decreases. Reaction formula (l)

[0069] [ka] Cl in electrolytic cell 10 - When the electrolysis efficiency is reduced, the electrolysis efficiency of the membrane-free electrolysis is reduced. If the membrane-free electrolysis is continued in a state where the electrolysis efficiency is reduced, the Cl in the electrolytic cell 10 gradually - increases, and Cl in the electrolytic cell 10 - reaches a level that appears to be no longer increasing or decreasing.

[0070] On the other hand, the current used for the membraneless electrolysis is such that chloride ions (Cl - ) is supplied to the electrolytic cell 10. -When the current amount is greater than the condition under which the current does not apparently increase or decrease (reaction formula (m) below), the Cl - The supply of Cl in the electrolytic cell 10 increases. - increases. Reaction formula (m)

[0071] [ka] Cl in electrolytic cell 10 - When the electrolysis efficiency is increased, the electrolysis efficiency of the membrane-free electrolysis increases. If the membrane-free electrolysis is continued in a state where the electrolysis efficiency is increased, the Cl in the electrolytic cell 10 gradually - decreases, and Cl in the electrolytic cell 10 - reaches a level that appears to be no longer increasing or decreasing.

[0072] In addition, Cl in the electrolytic cell 10 - When the amount of Cl in the electrolytic cell 10 increases, the equilibrium of reaction formula (d) shifts to the left, and the amount of chlorine generated increases. - By adjusting the current passed through the membraneless electrolysis unit E1 and the current passed through the membrane-containing electrolysis unit E2 so that the apparent increase or decrease in current does not occur, hypochlorous acid can be produced while suppressing the generation of chlorine. [Diaphragm electrolysis section E2] The reaction in supply tank 20 will be described. The only electrode arranged in supply tank 20 is supply tank side cathode 21. When a predetermined voltage is applied to membrane-equipped electrolysis section E2, a current flows, electrons move, and the following chemical reaction occurs. Reaction formula (n): Electrolyzer side cathode 12 (hydrogen generation)

[0073] [ka] Reaction formula (о): Anion exchange membrane 30 When a voltage is applied to the membrane electrolysis unit E2 and a current flows, the chloride ions (Cl - ) permeates the anion exchange membrane 30 and is supplied to the first aqueous solution L1, and the second aqueous solution L2 is supplied with electrons (e - ) 1.

[0074] [ka] The above is the details of the chemical reaction occurring in the membrane-less electrolysis section E1 provided in the electrolytic cell 10 and the chemical reaction occurring in the membrane-containing electrolysis section E2 provided between the electrolytic cell 10 and the supply cell 20.

[0075] The current control unit 40 controls the above chemical reaction. More specifically, the second current is controlled so as to replenish the chloride ions contained in the first aqueous solution L1 that have been reduced by the diaphragm-free electrolysis in the diaphragm-free electrolysis unit E1. By controlling the second current, the chloride ions contained in the second aqueous solution L2 are permeated through the anion exchange membrane 30 and supplied to the first aqueous solution L1. Details will be described below with reference to FIG. 3.

[0076] 3 is a block diagram showing the current control unit 40 according to the embodiment 1. As shown in FIG.

[0077] The voltage acquiring unit 41 acquires a voltage between the electrolytic cell side anode 11 and the electrolytic cell side cathode 12. The voltage acquiring unit 41 is, for example, a voltmeter. The calculation unit 42 calculates the conductivity of the first aqueous solution L1 based on the voltage acquired by the voltage acquiring unit 41. The estimation unit 43 estimates the chloride ion concentration of the first aqueous solution L1 based on the conductivity of the first aqueous solution L1 calculated by the calculation unit 42.

[0078] The current control unit 40 controls the first current passed through the non-diaphragm electrolysis unit E1 and the second current passed through the diaphragm electrolysis unit E2 shown in Fig. 3 so as to maintain the chloride ion concentration in the first aqueous solution L1 at a predetermined concentration. Three examples of current control by the current control unit 40 will be described below. [1. When the first and second currents flow simultaneously] When the current control unit 40 causes the first current and the second current to flow simultaneously, it performs the following controls (1) to (3). (1) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: the current ratio of the first current and the second current is changed so as to increase the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30. More specifically, the current ratio of the first current is decreased and the current ratio of the second current is increased. (2) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration: the current ratio of the first current and the second current is changed so as to reduce the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30. More specifically, the current ratio of the first current is increased and the current ratio of the second current is decreased. (3) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the current ratio of the first current to the second current is not changed. [2. When the first current flows at a specified value and the second current is controlled at the same time] When the current control unit 40 controls the second current while causing the first current to flow at a predetermined value, the current control unit 40 performs the following controls (1) to (3). (1) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: a second current is passed so as to increase the amount of chloride ions that permeate from the second aqueous solution L2 through the anion exchange membrane 30 and are supplied to the first aqueous solution L1. (2) The chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration. In the case of (a), the second current is stopped so that the supply of chloride ions from the second aqueous solution L2 to the first aqueous solution L1 is stopped. (3) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the first current and the second current are not changed. [3. When the first or second current flows] When the current control unit 40 causes the first current or the second current to flow, it performs the following controls (1) to (3). (1) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: the first current is stopped and the second current is simultaneously passed so as to increase the amount of chloride ions that permeate from the second aqueous solution L2 through the anion exchange membrane 30 and are supplied to the first aqueous solution L1. (2) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration: the second current is stopped and the first current is simultaneously passed so as to stop the supply of chloride ions from the second aqueous solution L2 to the first aqueous solution L1. (3) When the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the first current and the second current are not changed.

[0079] As described above, the current control unit 40 controls the first current and the second current, so that the necessary amount of chloride ions can be supplied to the first aqueous solution L1 in the electrolytic cell 10, and the chloride ion concentration in the first aqueous solution L1 can be maintained at a predetermined concentration.

[0080] In the above "1. When the first current and the second current are passed simultaneously," if there is an increase or decrease in the chloride ion concentration in the first aqueous solution L1, the current ratio between the first current and the second current is changed. Since the first current and the second current are passed simultaneously, the increase or decrease in the chloride ion concentration in the first aqueous solution L1 is minimized, and it is possible to maintain the concentration at an optimal predetermined level. In the case of "2. When the first current is passed at a predetermined value while the second current is controlled at the same time," when there is an increase or decrease in the chloride ion concentration in the first aqueous solution L1, mainly the second current is passed or stopped. In the case of "3. When the first current or the second current is passed," when there is an increase or decrease in the chloride ion concentration in the first aqueous solution L1, one of the first current and the second current is passed and the other is stopped. Therefore, the chloride ion concentration in the first aqueous solution L1 can be maintained at a predetermined concentration. In the above cases 2 and 3, it is only necessary to control either the first current or the second current, so current control is easy.

[0081] As described above, the chloride ions consumed by the first aqueous solution L1 can be appropriately supplied from the second aqueous solution L2, so that the space purification device 1 capable of stably generating a desired amount of hypochlorous acid gas can be provided. Therefore, the space purification device 1 capable of stably generating a desired amount of hypochlorous acid gas can be provided without supplying an aqueous solution containing chloride ions from the outside for a long period of time, such as one year.

[0082] Note that a plurality of current control units 40 may be provided to control the first current and the second current separately.

[0083] In FIG. 2, the inlet 15 and the outlet 17 are arranged on the front left side (negative side of the y-axis and negative side of the x-axis) and the back right side (positive side of the y-axis and positive side of the x-axis) when the electrolytic cell 10 is viewed in plan, but the arrangement is not limited to this. For example, the positions of the inlet 15 and the outlet 17 may be reversed, the inlet 15 and the outlet 17 may be at the same position on the x-axis, or the inlet 15 and the outlet 17 may be at the same position on the y-axis. However, when the inlet 15 and the outlet 17 are arranged, it is preferable to arrange them so that they are at the farthest positions on the xy plane. With such an arrangement, the time during which the inflowing air and hypochlorous acid are mixed in the mixing space 16 is longer, so that more hypochlorous acid can be contained in the mixed air.

[0084] In addition, a plane P1 (yz plane on the positive side of the x-axis) of the rectangular plate on the anion exchange membrane 30 side of the electrolytic cell side anode plate 11 and a rectangular plate on the anion exchange membrane 30 side of the supply cell side cathode plate 21 are Here, we will explain the case where planes P2 (yz plane on the negative side of the x-axis) in the rectangles do not face each other. When the planes in each rectangle are arranged parallel to the xy plane, a non-uniform electric field may be generated between the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21. When a non-uniform electric field is generated between the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21, the distribution of current between the electrolytic cell-side anode plate 11 and the supply cell-side cathode plate 21 also becomes non-uniform.

[0085] When the distribution of current between the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21 becomes non-uniform, regions with high and low current densities are generated. In the parts with high current density, the deterioration of the catalytic layer on the surfaces of the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21 (hereinafter also referred to as each electrode plate) is likely to progress, and in the parts with low current density, the deterioration of the catalytic layer on the surfaces of each electrode plate is unlikely to progress. That is, when a non-uniform electric field occurs between the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21, the distribution of current becomes non-uniform, and regions with different current densities may exist simultaneously on the same electrode plate. Therefore, the deterioration of the catalytic layer due to the use of each electrode plate may occur non-uniformly. If the degree of deterioration of the catalytic layer on the surface of each electrode plate differs, when electrolysis is repeatedly performed, at a certain point, there may be a region on each electrode plate that can be used as an electrode and a region that cannot be used as a result of the deterioration. When electrolysis is performed with each electrode plate including a region that cannot be used as an electrode, there is a risk that the electrolysis efficiency is likely to decrease.

[0086] In contrast, in the spatial purification device 1 according to the present embodiment, the plane P1 and the plane P2 are arranged to face each other with the anion exchange membrane 30 interposed therebetween. This arrangement allows a uniform electric field to be generated between the electrolytic cell side anode plate 11 and the supply cell side cathode plate 21, and the current between the two electrodes is also uniformly distributed. Therefore, deterioration of the catalyst layer on the surface of each electrode plate occurs uniformly, so that even when electrolysis is performed repeatedly, uneven deterioration of the catalyst layer on the surface of each electrode plate caused by an uneven electric field can be suppressed. Therefore, a decrease in electrolysis efficiency can be suppressed. <Variation 1> Hereinafter, a first modified example of the electrolytic cell 10 and the supply cell 20 according to the first embodiment will be described with reference to Fig. 4. Fig. 4 is a front cross-sectional view showing a first modified example of the electrolytic cell 10 and the supply cell 20 included in the spatial purification device 1 according to the first embodiment. The same components as those in the electrolytic cell 10 and the supply cell 20 are given the same reference numerals, and the description thereof will be omitted.

[0087] First, an electrolytic cell 50, which is a first modified example of the electrolytic cell 10, will be described. As shown in Fig. 4, the electrolytic cell 50 has a substantially L-shaped shape when viewed from the front. The electrolytic cell 50 has two ceiling surfaces with different heights (z-axis direction), a first ceiling surface 51 and a second ceiling surface 52. The first ceiling surface 51 is a ceiling surface that is lower in height (z-axis direction) than the second ceiling surface 52. The electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are inserted from the upper side (z-axis positive side) of the first ceiling surface 51 toward the inside of the electrolytic cell 50 (z-axis negative direction).

[0088] The electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a inserted into the electrolytic cell 50 are disposed inside the electrolytic cell 50 and are entirely immersed in the first aqueous solution L1. In other words, the first aqueous solution L1 is stored in the electrolytic cell 50 such that the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a are entirely immersed. That is, the first aqueous solution L1 is stored in the electrolytic cell 50 such that the liquid level S1 of the first aqueous solution L1 exceeds the upper ends (ends on the z-axis positive side) of the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a.

[0089] The electrolytic cell-side anode plate protrusion 11b and the electrolytic cell-side cathode plate protrusion 12b are disposed on the external side of the electrolytic cell 50. The electrolytic cell-side anode plate protrusion 11b is electrically connected to a current control unit 40 via wiring 13, and the electrolytic cell-side cathode plate protrusion 12b is electrically connected to a current control unit 40 via wiring 14.

[0090] Here, a case where the electrolytic cell 50 shown in Fig. 4 is provided with a water level detector 18 and a water supply unit 19 will be described. As in the electrolytic cell 10, the water level detector 18 includes at least the electrolytic cell-side anode plate immersion unit 1 The water supply unit 19 is disposed above (on the z-axis positive side) the upper ends (portions on the z-axis positive side) of the electrolytic cell-side cathode plate immersed portion 12a and the electrolytic cell-side cathode plate immersed portion 12a. The water supply unit 19 may be disposed on the second ceiling surface 52, for example, but may be disposed in any position that allows water to be supplied to the electrolytic cell 50.

[0091] Next, a supply tank 60 which is a first modified example of the supply tank 20 will be described. As shown in Fig. 4, the supply tank 60 has a shape which is a left-right inverted shape of the electrolytic tank 50 when viewed from the front. The supply tank 60 has two ceiling surfaces with different heights (z-axis direction), a first ceiling surface 61 and a second ceiling surface 62. The first ceiling surface 61 is a ceiling surface which is lower in height (z-axis direction) than the second ceiling surface 62. The supply tank-side cathode plate 21 is inserted from above the first ceiling surface 61 (z-axis positive direction) toward the inside of the supply tank 60 (z-axis negative direction).

[0092] The supply tank side cathode plate immersed portion 21a inserted into the supply tank 60 is disposed inside the supply tank 60, and is entirely immersed in the second aqueous solution L2. In other words, the second aqueous solution L2 is stored in the supply tank 60 such that the supply tank side cathode plate immersed portion 21a is entirely immersed. That is, the second aqueous solution L2 is stored in the supply tank 60 such that the liquid level S2 of the second aqueous solution L2 exceeds the upper end (the end on the z-axis positive side) of the supply tank side cathode plate immersed portion 21a.

[0093] The supply tank side cathode plate protrusion 21b is disposed on the outer side of the supply tank 60. The supply tank side cathode plate protrusion 21b is electrically connected to the current control unit 40 via the wiring 22. <Variation 2> Next, a second modification of the electrolytic cell 10 and the supply cell 20 according to the first embodiment will be described with reference to Fig. 5. Fig. 5 is a front cross-sectional view showing a second modification of the electrolytic cell 10 and the supply cell 20 included in the spatial purification device 1 according to the first embodiment. The same components as those in the electrolytic cell 10 and the supply cell 20 are given the same reference numerals, and the description thereof will be omitted. As shown in Fig. 5, the electrolytic cell 70 and the supply cell 80 have a shape obtained by turning the electrolytic cell 50 and the supply cell 60 of the first modification upside down.

[0094] First, electrolytic cell 70, which is a second modified example of electrolytic cell 10, will be described. As shown in Fig. 5, electrolytic cell 70 has a shape obtained by turning upside down a generally L-shape when viewed from the front. Electrolytic cell 70 has two bottom surfaces with different heights (z-axis direction), that is, a first bottom surface 71 and a second bottom surface 72. The first bottom surface 71 is the bottom surface of electrolytic cell 70 that is provided above (z-axis positive direction) the second bottom surface 72. The electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are inserted from the lower side (z-axis negative side) of the first bottom surface 71 toward the inside of electrolytic cell 70 (z-axis positive direction).

[0095] The electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a inserted into the electrolytic cell 70 are disposed inside the electrolytic cell 70 and are entirely immersed in the first aqueous solution L1. In other words, the first aqueous solution L1 is stored in the electrolytic cell 70 such that the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a are entirely immersed. That is, the first aqueous solution L1 is stored in the electrolytic cell 70 such that the liquid level S1 of the first aqueous solution L1 exceeds the upper ends (ends on the z-axis positive side) of the electrolytic cell side anode plate immersed portion 11a and the electrolytic cell side cathode plate immersed portion 12a.

[0096] The electrolytic cell-side anode plate protrusion 11b and the electrolytic cell-side cathode plate protrusion 12b are disposed on the external side of the electrolytic cell 70. The electrolytic cell-side anode plate protrusion 11b is electrically connected to a current control unit 40 via wiring 13, and the electrolytic cell-side cathode plate protrusion 12b is electrically connected to a current control unit 40 via wiring 14.

[0097] A case will now be described in which the electrolytic cell 70 is equipped with a water level detector 18 and a water supply unit 19. As with the electrolytic cell 10, the water level detector 18 is disposed above (on the z-axis positive side) at least the upper ends (parts on the z-axis positive side) of the electrolytic cell-side anode plate immersed portion 11a and the electrolytic cell-side cathode plate immersed portion 12a. The water supply unit 19 need only be disposed in a position capable of supplying water to the electrolytic cell 10, and may be disposed on the upper side, side, or bottom side of the electrolytic cell 70.

[0098] Next, supply tank 80, which is a second modified example of supply tank 20, will be described. Supply tank 80 has a shape that is a left-right inversion of electrolytic tank 70 when viewed from the front. Supply tank 80 has two bottom surfaces with different heights (z-axis direction), that is, a first bottom surface 81 and a second bottom surface 82. First bottom surface 81 is the bottom surface of supply tank 80 that is provided above second bottom surface 82 (z-axis positive direction). Supply tank-side cathode plate 21 is inserted from the lower side (z-axis negative side) of first bottom surface 81 toward the inside of electrolytic tank 70 (z-axis positive direction).

[0099] The supply tank side cathode plate immersed portion 21a inserted into the supply tank 80 is disposed inside the supply tank 80, and is entirely immersed in the second aqueous solution L2. In other words, the second aqueous solution L2 is stored in the supply tank 80 such that the supply tank side cathode plate immersed portion 21a is entirely immersed. That is, the second aqueous solution L2 is stored in the supply tank 80 such that the liquid level S2 of the second aqueous solution L2 exceeds the upper end (the end on the z-axis positive side) of the supply tank side cathode plate immersed portion 21a.

[0100] The supply tank side cathode plate protrusion 21b is disposed on the outer side of the supply tank 80. The supply tank side cathode plate protrusion 21b is electrically connected to the current control unit 40 via the wiring 22. <Embodiment 2> Next, the spatial purification device 2 according to the second embodiment will be described with reference to Fig. 6 and Fig. 7. The same components as those in the first embodiment are given the same reference numerals and the description thereof will be omitted. Although the shape of each component is different from that in the first embodiment, the function of each component is the same as that in the first embodiment, and therefore the description of the function of each component will be omitted.

[0101] Fig. 6 is a schematic front view showing the spatial purification device 2 according to embodiment 2. Fig. 7 is a plan view showing the spatial purification device 2 according to embodiment 2. The hatching shown in Fig. 7 is shown to clarify each component, and Fig. 7 is not a cross-sectional view.

[0102] As shown in FIG. 6, the spatial purification device 2 according to the present embodiment includes an electrolytic cell 10′, a supply cell 20′, an anion exchange membrane 30′, and a current control unit 40. The electrolytic cell 10′ and the supply cell 20′ are cylindrical in shape, with an upper surface (xy plane on the z-axis positive side) open and a bottom surface (xy plane on the z-axis negative side). The anion exchange membrane 30′ is cylindrical in shape. The anion exchange membrane 30′ is disposed between the electrolytic cell 10′ and the supply cell 20′. As shown in FIG. 6, the electrolytic cell 10′ is a part on the inner diameter side of the anion exchange membrane 30′. The cylindrical shapes of the electrolytic cell 10′, the supply cell 20′, and the anion exchange membrane 30′ include a cylindrical shape and a square cylindrical shape. Although not shown in FIG. 6 and FIG. 7, the first aqueous solution L1 is stored in the electrolytic cell 10′, and the second aqueous solution L2 is stored in the supply cell 20′.

[0103] As shown in FIG. 6, the electrolytic cell 10' includes an electrolytic cell side anode 11' and an electrolytic cell side cathode 12'. The electrolytic cell side anode 11' is an electrolytic cell side anode tube 11' having a cylindrical shape. The electrolytic cell side cathode 12' is an electrolytic cell side cathode tube 12' or an electrolytic cell side cathode bar 12' having a cylindrical or rod-shaped shape. The supply cell 20' includes a supply cell side cathode 21'. The supply cell side cathode 21' is a supply cell side cathode tube 21' having a cylindrical shape. The cylindrical shapes of the electrolytic cell side anode 11', the electrolytic cell side cathode 12', and the supply cell side cathode 21' include a cylindrical shape and a square tube shape. The rod-shaped shapes include a cylindrical shape and a spiral shape. The electrolytic cell side anode 11', the electrolytic cell side cathode 12', and the supply cell side cathode 21' are each electrically connected to the current control unit 40 via wiring (not shown).

[0104] 6 and 7, the spatial purification device 2 according to this embodiment has, for example, a cylindrical structure in which each component is nested. More specifically, from the outside, the components are arranged in the order of supply tank 20', supply tank side cathode 21', anion exchange membrane 30', electrolytic tank 10', electrolytic tank side anode 11', and electrolytic tank side cathode 12'. In other words, the diameters of the components are as follows: supply tank 20'>supply tank side cathode 21'>anion exchange membrane 30'=electrolytic tank 10'>electrolytic tank side anode 11'>electrolytic tank side cathode 12'. ', and each component is disposed at a predetermined interval from each other.

[0105] The entire electrolytic cell side anode cylinder 11' and the entire electrolytic cell side cathode cylinder 12' or the entire electrolytic cell side cathode rod 12' are immersed in the first aqueous solution L1. The entire supply cell side cathode cylinder 21' is immersed in the second aqueous solution L2. As shown in FIG. 6, the space purification device 2 according to this embodiment may further include a water level detection unit 18 and a water supply unit 19. The water level detection unit 18 is disposed above (on the positive side of the z-axis) the upper ends (ends on the positive side of the z-axis) of the electrolytic cell side anode 11', the electrolytic cell side cathode 12', and the supply cell side cathode 21'. The water supply unit 19 may be disposed at a position where it can supply water to the electrolytic cell 10', and may be disposed above (on the positive side of the z-axis) the electrolytic cell 10', for example.

[0106] The electrolytic cell side anode 11', the electrolytic cell side cathode 12' and the supply cell side cathode 21' may be made of a plate-like member, a mesh-like member, or an expanded metal.

[0107] The space purification device 2 according to the present embodiment includes a current control unit 40 similar to that of the first embodiment. The current control unit 40 controls the first current and the second current, thereby supplying a necessary amount of chloride ions to the first aqueous solution L1 in the electrolytic bath 10' and maintaining the chloride ion concentration in the first aqueous solution L1 at a predetermined concentration. Therefore, it is possible to provide a space purification device 2 capable of purifying space by stably generating a desired amount of hypochlorous acid gas.

[0108] Furthermore, the space purification device 2 according to this embodiment can accommodate the electrolytic cell 10' and the anion exchange membrane 30' inside the supply cell 20'. Therefore, it is possible to provide a space purification device 2 that is more compact and takes up less space.

[0109] The present invention is not limited to the above-described embodiment, and can be modified as appropriate without departing from the spirit and scope of the present invention.

[0110] An outline of one aspect of the present disclosure is as follows.

[0111] (Item 1) an electrolytic cell (10) for storing a first aqueous solution (L1) containing chloride ions; a supply tank (20) for storing a second aqueous solution (L2) containing chloride ions at a higher concentration than that of the first aqueous solution (L1) and supplying the chloride ions to the first aqueous solution (L1); an electrolytic cell-side anode (11) and an electrolytic cell-side cathode (12) provided in the electrolytic cell (10); a supply tank-side cathode (21) provided in the supply tank (20); an anion exchange membrane (30) connecting the electrolytic cell (10) and the supply cell (20) so as to be permeable to anions based on a voltage applied between the electrolytic cell-side anode (11) and the supply cell-side cathode (21); a membrane-free electrolysis unit (E1) provided in the electrolytic cell (10), which generates hypochlorous acid by performing membrane-free electrolysis of the first aqueous solution (L1) by passing a first current between the electrolytic cell-side anode (11) and the electrolytic cell-side cathode (12); a membrane-containing electrolysis section (E2) provided between the electrolytic cell (10) and the supply cell (20), for performing membrane-containing electrolysis via the anion exchange membrane (30) by passing a second current between the electrolytic cell-side anode (11) and the supply cell-side cathode (21); a current control unit (40) for controlling the second current so as to replenish chloride ions contained in the first aqueous solution (L1) that have been reduced by the membrane-less electrolysis, thereby causing chloride ions contained in the second aqueous solution (L2) to permeate through the anion exchange membrane (30) and supply them to the first aqueous solution (L1). Space purification device (1).

[0112] (Item 2) The current control unit (40) applies the first current and the second current at a predetermined ratio, thereby maintaining the chloride ion concentration of the first aqueous solution (L1) at a predetermined concentration. The space purification device (1) according to item 1.

[0113] (Item 3) The current control unit (40) a voltage acquisition unit (41) that acquires a voltage between the electrolytic cell side anode (11) and the electrolytic cell side cathode (12); a calculation unit (42) that calculates the conductivity of the first aqueous solution (L1) based on the voltage acquired by the voltage acquisition unit (41); an estimation unit (43) that estimates a concentration of the first aqueous solution (L1) based on the electrical conductivity calculated by the calculation unit (42), The current control unit (40) The first current and the second current are caused to flow simultaneously; when the chloride ion concentration of the first aqueous solution (L1) is lower than a predetermined concentration, a current ratio between the first current and the second current is changed so that an amount of chloride ions permeating from the second aqueous solution (L2) through the anion exchange membrane (30) and supplied to the first aqueous solution (L1) is increased; when the chloride ion concentration of the first aqueous solution (L1) is higher than the predetermined concentration, a current ratio between the first current and the second current is changed so that an amount of chloride ions permeating from the second aqueous solution (L2) through the anion exchange membrane (30) and supplied to the first aqueous solution (L1) is reduced. The space purification device (1) according to item 1. (Item 4) When the chloride ion concentration of the first aqueous solution (L1) is the predetermined concentration, the current ratio of the first current and the second current is not changed. The space purification device (1) according to item 3. (Item 5) a voltage acquisition unit (41) that acquires a voltage between the electrolytic cell side anode (11) and the electrolytic cell side cathode (12); a calculation unit (42) that calculates the conductivity of the first aqueous solution (L1) based on the voltage acquired by the voltage acquisition unit (41); an estimation unit (43) that estimates a concentration of the first aqueous solution (L1) based on the electrical conductivity calculated by the calculation unit (42), The current control unit (40) The first current is caused to flow at a predetermined value while the second current is controlled; The control of the second current includes: When the chloride ion concentration of the first aqueous solution (L1) is lower than a predetermined concentration, the second current is applied so as to increase the amount of chloride ions that permeate from the second aqueous solution (L2) through the anion exchange membrane (30) and are supplied to the first aqueous solution (L1); When the chloride ion concentration of the first aqueous solution (L1) is higher than the predetermined concentration, the second current is stopped so that the supply of chloride ions from the second aqueous solution (L2) to the first aqueous solution (L1) is stopped. The space purification device (1) according to item 1. (Item 6) a voltage acquisition unit (41) that acquires a voltage between the electrolytic cell side anode (11) and the electrolytic cell side cathode (12); a calculation unit (42) that calculates the conductivity of the first aqueous solution (L1) based on the voltage acquired by the voltage acquisition unit (41); The calculation unit (42) estimates the concentration of the first aqueous solution (L1) based on the calculated electrical conductivity. and an estimation unit (43) for determining The current control unit (40) When the chloride ion concentration of the first aqueous solution (L1) is lower than a predetermined concentration, the first current is stopped and the second current is simultaneously applied so that an amount of chloride ions permeating from the second aqueous solution (L2) through the anion exchange membrane (30) and being supplied to the first aqueous solution (L1) is increased, When the chloride ion concentration of the first aqueous solution (L1) is higher than a predetermined concentration, stopping the second current and simultaneously supplying the first current so as to stop the supply of chloride ions from the second aqueous solution (L2) to the first aqueous solution (L1); The space purification device (1) according to item 1. (Item 7) the electrolytic cell-side anode (11), the electrolytic cell-side cathode (12), and the supply cell-side cathode (21) are, respectively, plate-shaped electrolytic cell-side anode plate (11), electrolytic cell-side cathode plate (12), and supply cell-side cathode plate (21), the electrolytic cell-side anode plate (11) and the electrolytic cell-side cathode plate (12) are inserted into the electrolytic cell (10) from the outside of the electrolytic cell (10), and the supply cell-side cathode plate (21) is inserted into the supply cell (20) from the outside of the supply cell (20), the electrolytic cell-side anode plate (11) comprises an electrolytic cell-side anode plate immersion portion (11a) arranged inside the electrolytic cell (10) and an electrolytic cell-side anode plate protrusion portion (11b) arranged outside the electrolytic cell (10); the electrolytic cell-side cathode plate (12) comprises an electrolytic cell-side cathode plate immersion portion (12a) arranged on the inside of the electrolytic cell (10) and an electrolytic cell-side cathode plate protrusion portion (12b) arranged on the outside of the electrolytic cell (10); the supply tank-side cathode plate (21) includes a supply tank-side cathode plate immersion portion (21a) arranged on the inside of the supply tank (20) and a supply tank-side cathode plate protrusion portion (21b) arranged on the outside of the supply tank (20); The electrolytic cell side anode plate immersed portion (11a) and the electrolytic cell side cathode plate immersed portion (12a) as a whole are Immersed in the first aqueous solution (L1), The entire supply tank side cathode plate immersed portion (21a) is Immersed in the second aqueous solution (L2); The space purification device (1) according to item 1. (Item 8) the electrolytic cell side anode (11) and the supply cell side cathode (21) are an electrolytic cell side anode tube (11′) and a supply cell side cathode tube (21′) each having a cylindrical or rectangular tubular shape, the electrolytic cell-side cathode (12) is an electrolytic cell-side cathode tube (12′) or an electrolytic cell-side cathode bar (12′) having a cylindrical, rectangular tubular, or rod-like shape, The entirety of the electrolytic cell side anode cylinder (11') and the entirety of the electrolytic cell side cathode cylinder (12') or the electrolytic cell side cathode rod (12') are Immersed in the first aqueous solution (L1), The entire supply tank side cathode cylinder (21') is Immersed in the second aqueous solution (L2); The space purification device (1) according to item 1. (Item 9) a water level detector (18) for detecting a liquid level of the first aqueous solution (L1); a water supply unit (19) which supplies water to the electrolytic cell (10) so that the level of the liquid detected by the water level detection unit (18) does not fall below the upper ends of the electrolytic cell side anode plate immersed portion (11a) and the electrolytic cell side cathode plate immersed portion (12a), or the electrolytic cell side anode cylinder (11') or the electrolytic cell side cathode rod (12') and the electrolytic cell side cathode cylinder (12'). Item 9. The spatial purification device (1) according to item 7 or 8. (Item 10) The electrolytic cell side anode plate (11) and the supply cell side cathode plate (21) are adjacent to the anion exchange membrane (30), The flat surfaces of the plates are arranged opposite each other via the anion exchange membrane (30), The electrolytic cell side cathode plate (12) is The flat surface of the plate is disposed opposite to the flat surface of the electrolytic cell side anode plate (11). Item 7. The space purification device (1) according to item 7. (Item 11) The electrolytic cell side anode plate (11), the electrolytic cell side cathode plate (12), and the supply cell side cathode plate (21) are The plate shape is rectangular, The short side direction of the rectangle is arranged along the vertical direction, The longitudinal direction of the rectangle is arranged along the horizontal direction. Item 7. The space purification device (1) according to item 7. (Item 12) The non-diaphragm electrolysis section (E1) is The electrolytic cell side anode (11), The electrolytic cell-side cathode (12), The membrane electrolysis section (E2) comprises: The electrolytic cell side anode (11), The supply tank side cathode (21), The anion exchange membrane (30), The space purification device (1) according to item 1. (Item 13) a housing (B) for housing the electrolytic cell (10) and the supply cell (20); an inlet (15) that is disposed in the casing (B) above a liquid level of the first aqueous solution (L1) stored in the electrolytic cell (10), and through which air flows in from an external space of the casing (B); a mixing space (16) for mixing the volatilized hypochlorous acid with the air flowing in from the inlet (15); and an outlet (17) through which the mixed air flows out to the exterior space. The space purification device (1) according to item 1. [Explanation of symbols]

[0114] 1,2 Space Purification Device 10 Electrolytic cell 11 Electrolyzer side anode 11a Electrolytic tank side anode plate immersion part 11b Electrolytic tank side anode plate protrusion 12 Electrolytic cell side cathode 12a Electrolytic tank side cathode plate immersion part 12b Electrolytic cell side cathode plate protrusion 13,14 Wiring 15 Inlet 16 Mixed space 17 Outlet 20 Supply tank 21 Supply tank side cathode 22 Wiring 30 Anion exchange membrane 40 Current control section B-Case E1 Diaphragmless electrolytic section E2 Diaphragm electrolysis section L1 1st aqueous solution L2 2nd aqueous solution 11 Electrolyzer side anode plate 12 Electrolytic cell side cathode plate 21 Supply tank side cathode plate 50 electrolytic cell 60 Supply tank 70 Electrolytic cell 71 1st bottom 72 Second bottom surface 80 Supply tank 81 1st bottom surface 82 2nd bottom surface

Claims

1. an electrolytic cell for storing a first aqueous solution containing chloride ions; a supply tank for storing a second aqueous solution containing chloride ions at a higher concentration than that of the first aqueous solution and supplying chloride ions to the first aqueous solution; an electrolytic cell-side anode and an electrolytic cell-side cathode provided in the electrolytic cell; A supply tank side cathode provided in the supply tank; an anion exchange membrane that connects the electrolytic cell and the supply cell so as to be permeable to anions based on a voltage applied between the electrolytic cell-side anode and the supply cell-side cathode; a membrane-free electrolysis unit provided in the electrolytic cell, which generates hypochlorous acid by performing membrane-free electrolysis of the first aqueous solution by passing a first current between the electrolytic cell-side anode and the electrolytic cell-side cathode; a membrane-containing electrolysis section provided between the electrolytic cell and the supply cell, which performs membrane-containing electrolysis via the anion exchange membrane by passing a second current between the electrolytic cell-side anode and the supply cell-side cathode; a current control unit that controls the second current so as to replenish chloride ions contained in the first aqueous solution that have been reduced by the membrane-free electrolysis, thereby causing chloride ions contained in the second aqueous solution to permeate through the anion exchange membrane and be supplied to the first aqueous solution. Space purification device.

2. the current control unit applies the first current and the second current at a predetermined ratio, thereby maintaining a chloride ion concentration of the first aqueous solution at a predetermined concentration. The space purification device according to claim 1 .

3. The current control unit is a voltage acquisition unit that acquires a voltage between the electrolytic cell-side anode and the electrolytic cell-side cathode; a calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit; an estimation unit that estimates a concentration of the first aqueous solution based on the electrical conductivity calculated by the calculation unit, The current control unit is The first current and the second current are caused to flow simultaneously; When the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, a current ratio of the first current and the second current is changed so that an amount of chloride ions permeating from the second aqueous solution through the anion exchange membrane and supplied to the first aqueous solution is increased; When the chloride ion concentration of the first aqueous solution is higher than the predetermined concentration, a current ratio of the first current to the second current is changed so that an amount of chloride ions permeating from the second aqueous solution through the anion exchange membrane and supplied to the first aqueous solution is reduced. The space purification device according to claim 1 .

4. When the chloride ion concentration of the first aqueous solution is the predetermined concentration, the current ratio of the first current and the second current is not changed. The space purification device according to claim 3.

5. a voltage acquisition unit that acquires a voltage between the electrolytic cell-side anode and the electrolytic cell-side cathode; a calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit; an estimation unit that estimates a concentration of the first aqueous solution based on the electrical conductivity calculated by the calculation unit, The current control unit is The first current is caused to flow at a predetermined value while the second current is controlled; The control of the second current includes: When the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the second current is applied so as to increase the amount of chloride ions permeating from the second aqueous solution through the anion exchange membrane and being supplied to the first aqueous solution; When the chloride ion concentration of the first aqueous solution is higher than the predetermined concentration, the second current is stopped so that the supply of chloride ions from the second aqueous solution to the first aqueous solution is stopped. The space purification device according to claim 1 .

6. a voltage acquisition unit that acquires a voltage between the electrolytic cell-side anode and the electrolytic cell-side cathode; a calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit; an estimation unit that estimates a concentration of the first aqueous solution based on the electrical conductivity calculated by the calculation unit, The current control unit is When the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the first current is stopped and the second current is simultaneously supplied so that an amount of chloride ions permeating the anion exchange membrane from the second aqueous solution and being supplied to the first aqueous solution is increased; When the chloride ion concentration of the first aqueous solution is higher than a predetermined concentration, stopping the second current and simultaneously supplying the first current so as to stop the supply of chloride ions from the second aqueous solution to the first aqueous solution; The space purification device according to claim 1 .

7. the electrolytic cell-side anode, the electrolytic cell-side cathode, and the supply cell-side cathode are, respectively, an electrolytic cell-side anode plate, an electrolytic cell-side cathode plate, and a supply cell-side cathode plate each having a plate-like shape; the electrolytic cell-side anode plate and the electrolytic cell-side cathode plate are inserted into the electrolytic cell from outside the electrolytic cell, and the supply cell-side cathode plate is inserted into the supply cell from outside the supply cell, The electrolytic cell-side anode plate includes an electrolytic cell-side anode plate immersion portion arranged on the inside side of the electrolytic cell, and an electrolytic cell-side anode plate protrusion portion arranged on the outside side of the electrolytic cell, the electrolytic cell-side cathode plate includes an electrolytic cell-side cathode plate immersion portion arranged on the inside of the electrolytic cell, and an electrolytic cell-side cathode plate protrusion portion arranged on the outside of the electrolytic cell, The supply tank side cathode plate includes a supply tank side cathode plate immersion portion arranged on the inside side of the supply tank and a supply tank side cathode plate protrusion portion arranged on the outside side of the supply tank, The entire anode plate immersed portion on the electrolytic cell side and the cathode plate immersed portion on the electrolytic cell side are Immersed in the first aqueous solution; The entire supply tank side cathode plate immersion portion is Immersed in the second aqueous solution; The space purification device according to claim 1 .

8. the electrolytic cell side anode and the supply cell side cathode are an electrolytic cell side anode tube and a supply cell side cathode tube, respectively, each having a cylindrical or rectangular tubular shape, The electrolytic cell side cathode is an electrolytic cell side cathode tube or an electrolytic cell side cathode bar having a cylindrical, rectangular tubular, or rod-like shape, The entire electrolytic cell side anode cylinder, and the entire electrolytic cell side cathode cylinder or the entire electrolytic cell side cathode bar are Immersed in the first aqueous solution; The entire supply tank side cathode cylinder is Immersed in the second aqueous solution; The space purification device according to claim 1 .

9. a water level detector for detecting a liquid level of the first aqueous solution; a water supply unit that supplies water to the electrolytic cell so that the liquid level detected by the water level detection unit does not fall below an upper end of the electrolytic cell side anode plate immersion portion and the electrolytic cell side cathode plate immersion portion, or an upper end of the electrolytic cell side anode tube, the electrolytic cell side cathode rod, and the electrolytic cell side cathode tube. The space purification device according to claim 7 or 8.

10. The electrolytic cell side anode plate and the supply cell side cathode plate are adjacent to the anion exchange membrane, The flat surfaces of the plates are arranged opposite each other via the anion exchange membrane, The electrolytic cell side cathode plate is The flat surface of the plate is disposed opposite to the flat surface of the electrolytic cell side anode plate. The space purification device according to claim 7.

11. The electrolytic cell side anode plate, the electrolytic cell side cathode plate, and the supply cell side cathode plate are The plate shape is rectangular, The short side direction of the rectangle is arranged along the vertical direction, The longitudinal direction of the rectangle is arranged along the horizontal direction. The space purification device according to claim 7.

12. The non-diaphragm electrolysis unit is The electrolytic cell side anode; The electrolytic cell-side cathode, The membrane electrolysis unit includes: The electrolytic cell side anode; The supply tank side cathode; The anion exchange membrane, The space purification device according to claim 1 .

13. a housing for housing the electrolytic cell and the supply cell; an inlet that is disposed in the housing above a liquid level of the first aqueous solution stored in the electrolytic cell, and through which air flows in from an external space of the housing; A mixing space for mixing the volatilized hypochlorous acid with the air flowing in from the inlet; and an outlet through which the mixed air flows out to the exterior space. The space purification device according to claim 1 .

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