Electrode body manufacturing method

Abstract

To provide a manufacturing method for an electrode body that can reduce the occurrence of cracks.SOLUTION: An electrode body manufacturing method includes a drying step of drying an electrode material by a laser while transporting a workpiece having an electrode material applied on at least one surface of a current collector, and in the drying step, the workpiece is irradiated with a laser such that an irradiation range of the laser is inclined with respect to the transport direction of a workpiece in a plan view of the workpiece.SELECTED DRAWING: Figure 2

Description

[Technical field]

[0001] The present disclosure relates to a method for manufacturing an electrode assembly. [Background technology]

[0002] Various techniques have been proposed for producing an electrode assembly such as that disclosed in Patent Document 1. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2019-029256 A Summary of the Invention [Problem to be solved by the invention]

[0004] In conventional technology, when drying the electrode material while conveying it with a laser, the current collector, which is an intermittent part where the electrode material is not coated, tends to accumulate heat, so if the intermittent part is irradiated with a laser at the same time, there is a risk that the electrode material-coated part near the intermittent part will dry out more than necessary. In addition, when drying is performed using hot air or IR instead of a laser, it is difficult to control the irradiation width.

[0005] The present disclosure has been made in consideration of the above-mentioned circumstances, and has as its main object to provide a manufacturing method for an electrode assembly that can reduce the occurrence of cracks. [Means for solving the problem]

[0006] That is, the present disclosure includes the following aspects. <1> A method for manufacturing an electrode assembly, comprising the steps of: a drying step of drying the electrode material by a laser while transporting a workpiece having an electrode material applied on at least one surface of a current collector; A method for manufacturing an electrode body, wherein in the drying process, the laser is irradiated onto the workpiece so that the irradiation range of the laser is inclined with respect to the transport direction of the workpiece when viewed in a plane.

[0007] <2> In a plan view of the workpiece, a width direction of the electrode material is perpendicular to a transport direction of the workpiece, the inclination angle of the laser irradiation range with respect to the width direction of the electrode material is 10° or more and 60° or less; <1> A method for producing the electrode assembly according to claim 1. Effect of the Invention

[0008] The manufacturing method of the electrode assembly according to the present disclosure can reduce the occurrence of cracks. [Brief description of the drawings]

[0009] [Figure 1] FIG. 1 is a schematic diagram showing an example of a conventional drying process. [Diagram 2] FIG. 2 is a schematic diagram showing an example of the drying step of the present disclosure. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] Hereinafter, the embodiments of the present disclosure will be described. Note that matters other than those specifically mentioned in this specification and necessary for implementing the present disclosure (for example, the general configuration and manufacturing process of the electrode body that do not characterize the present disclosure) can be understood as design matters of a person skilled in the art based on the prior art in the field. The present disclosure can be implemented based on the contents disclosed in this specification and the technical common sense in the field. Furthermore, the dimensional relationships (length, width, thickness, etc.) in the drawings do not reflect the actual dimensional relationships.

[0011] The present disclosure provides a method for producing an electrode assembly, comprising: a drying step of drying the electrode material by a laser while transporting a workpiece having an electrode material applied on at least one surface of a current collector; The present invention provides a method for manufacturing an electrode body, wherein in the drying step, the laser is irradiated onto the workpiece such that an irradiation range of the laser is inclined with respect to a transport direction of the workpiece when viewed in a plane.

[0012] FIG. 1 is a schematic diagram showing an example of a conventional drying process. 1, the workpiece 1 has an electrode material 2 coated on a current collector, and has intermittent portions 3 that are uncoated portions of the electrode material 2. The workpiece 1 is transported in the transport direction, and a laser is irradiated parallel to the width direction of the electrode material 2 (perpendicular to the transport direction) in a plan view, so that heat is simultaneously stored in the intermittent portions 3, increasing the amount of heat transferred to the coated portions of the electrode material 2, and the electrode material 2 is prone to cracking.

[0013] FIG. 2 is a schematic diagram showing an example of the drying step of the present disclosure. As shown in Figure 2, by irradiating the workpiece 1 with a laser at an inclination angle with respect to the width direction of the electrode material 2 when viewed in a plane, heat is less likely to accumulate in the intermittent portion 3, the amount of heat transferred to the coated portion of the electrode material 2 is reduced, and cracks are less likely to occur in the electrode material 2.

[0014] In the present disclosure, by tilting the laser irradiation range with respect to the conveying direction of the workpiece, heat is not concentrated and accumulated in the current collector, which is the intermittent portion where the electrode material is not applied, and the electrode material can be dried under favorable conditions, thereby reducing the occurrence of cracks in the obtained electrode body. In addition, high-speed drying can be achieved by making the drying time of the intermittent portion and the electrode material-coated portion the same. Furthermore, segregation of the binder, which causes battery resistance, can be suppressed, and the amount of binder added in the electrode material can be reduced, thereby improving the performance of the battery using the obtained electrode body.

[0015] (drying process) The method for producing an electrode assembly according to the present disclosure includes a drying step. The drying step is a step of drying the electrode material by a laser while transporting a workpiece having a current collector coated on at least one surface thereof. In the drying step, a laser device may be used to dry the electrode material. In addition to the laser device, a conventionally known device capable of drying the electrode material, such as a hot air device or an IR (infrared) device, may be used as a drying device. In the drying step, the electrode material may be completely dried until the moisture content is several hundred ppm or less. In the drying step, the electrode material may be dried in a drying furnace. In the drying step, the workpiece may be placed on a carrier and transported. The transport speed may be, for example, 30 m / min or more. The drying temperature for the electrode material may be 100°C to 200°C. The drying time of the electrode material is not particularly limited. After the drying step, the electrode material becomes an electrode layer, and an electrode body including a current collector and an electrode layer formed on at least one surface of the current collector is obtained.

[0016] In the drying process, the workpiece is irradiated with a laser so that the irradiation range of the laser is inclined with respect to the conveying direction of the workpiece when viewed in a plan view. In a plan view of the workpiece, the width direction of the electrode material may be perpendicular to the workpiece transport direction, and the inclination angle of the laser irradiation range with respect to the width direction of the electrode material may be more than 0° and less than 90°, may be 5° or more and 80° or less, or may be 10° or more and 60° or less. In other words, the inclination angle of the laser irradiation range with respect to the workpiece transport direction may be more than 0° and less than 90°, may be 10° or more and 85° or less, or may be 30° or more and 80° or less. Methods for tilting the laser irradiation range include, for example, tilting the laser head body, placing multiple laser heads, using a vertical cavity surface emitting laser (VCSEL), and installing a shielding plate. The laser energy density is 2W / cm 2 It may be more than that.

[0017] The workpiece includes a current collector and an electrode material applied to at least one surface of the current collector. The workpiece may be for a bipolar electrode having a current collector coated on both sides with electrode material, where the electrode material coated on one side of the current collector is a positive electrode material and the electrode material coated on the other side of the current collector is a negative electrode material.

[0018] The current collector may be a negative electrode current collector, a positive electrode current collector, a bipolar current collector, or the like. Examples of materials for the current collector include metals such as aluminum, copper, SUS, and nickel. The thickness of the current collector is, for example, 0.1 μm or more and 100 μm or less. The shape of the current collector may be a sheet or the like.

[0019] The electrode material is applied to at least one of the surfaces of the current collector, that is, a first surface. The electrode material may be applied only to the first surface of the current collector, or may be applied to both the first surface and a second surface opposite to the first surface of the current collector. The method for applying the electrode material is not particularly limited, and any conventionally known method can be used. The electrode material can be prepared by mixing a mixture containing an active material, a binder, a conductive material, an electrolyte, a thickener, etc., together with a solvent. The electrode material may be a positive electrode material or a negative electrode material. The electrode material may contain moisture of about 10,000 ppm or less. The width of the electrode material is not particularly limited and may be 1000 mm or more.

[0020] The active material may be a positive electrode active material. Examples of the positive electrode active material include oxide active materials. Examples of the oxide active material include LiCoO2, LiMnO2, LiNiO2, LiVO2, and LiNi 1 / 3 Co 1 / 3 Mn 1 / 3 O2, etc., rock salt layered active materials, LiMn2O4, Li(Ni 0.5 Mn 1.5 )O4 and the like; and olivine type active materials such as LiFePO4, LiMnPO4, LiNiPO4, and LiCuPO4.

[0021] The active material may be a negative electrode active material. Examples of the negative electrode active material include carbon active materials, oxide active materials, and metal active materials. Examples of the carbon active material include graphite, mesocarbon microbeads (MCMB), highly oriented graphite (HOPG), hard carbon, and soft carbon. Examples of the oxide active material include Nb2O5, Li4Ti5O 12 and SiO. Examples of the metal active material include In, Al, Si, Sn, and the like.

[0022] Examples of binders include fluorine-containing binders such as polyvinylidene fluoride (PVDF) and polytetrafluoroethylene (PTFE), rubber-based binders such as styrene-butadiene rubber (SBR), and acrylic binders.

[0023] Examples of conductive materials include carbon materials, metal particles, conductive polymers, etc. Examples of carbon materials include particulate carbon materials such as acetylene black (AB) and ketjen black (KB), and fibrous carbon materials such as carbon fibers, carbon nanotubes (CNT), and carbon nanofibers (CNF).

[0024] Examples of thickeners include polysaccharides such as carboxymethyl cellulose (CMC) and methyl cellulose.

[0025] Examples of the electrolyte include solid electrolytes such as sulfide solid electrolytes and oxide solid electrolytes. Examples of the sulfide solid electrolyte include solid electrolytes containing Li, X (X is at least one of P, As, Sb, Si, Ge, Sn, B, Al, Ga, and In), and S. The sulfide solid electrolyte may further contain at least one of O and halogen elements. Examples of the halogen elements include F, Cl, Br, and I.

[0026] Examples of oxide solid electrolytes include Li2O-B2O3-P2O5, Li2O-SiO2, Li2O-B2O3, Li 1.3 Al 0.3 Ti 0.7 (PO4)3, Li5La3Ta2O 12 , Li7La3Zr2O 12 , Li6BaLa2Ta2O 12 , Li 3.6 S 0.6 P 0.4 O4, Li4SiO4, Li3PO4, Li3PO 4-3 / 2x N x (x≦1).

[0027] Examples of the solvent include aqueous solvents and organic solvents. The aqueous solvent means water or a mixed solvent containing water and a polar organic solvent. For example, an appropriate solvent can be selected depending on the types of active material, binder, etc. As the aqueous solvent, water is preferably used because of its ease of handling. Examples of polar organic solvents that can be used in the mixed solvent include alcohols such as methanol, ethanol, and isopropyl alcohol, ketones such as acetone, and ethers such as tetrahydrofuran. An example of the organic solvent is N-methyl-2-pyrrolidone (NMP).

[0028] The electrode assembly obtained by the manufacturing method of the present disclosure includes a current collector and an electrode layer formed by drying an electrode material coated on at least one surface of the current collector. The electrode layer may be a positive electrode layer or a negative electrode layer. The electrode layer may contain one of a positive electrode active material and a negative electrode active material, and may further contain a binder, a conductive material, an electrolyte, etc. These materials are as described above. The current collector may be a negative electrode current collector, a positive electrode current collector, a bipolar current collector, etc. The material of the current collector, the thickness of the current collector, and the shape of the current collector are as described above.

[0029] The electrode assembly of the present disclosure is typically used in the manufacture of batteries. The electrode assembly may be a positive electrode, a negative electrode, or a bipolar electrode. A bipolar electrode comprises a positive electrode layer on one side of a current collector and a negative electrode layer on the other side of the current collector. The type of battery in which the electrode body is used is not particularly limited, and may be, for example, a lithium ion secondary battery. The battery may be a liquid battery using an electrolytic solution as an electrolyte, or a solid battery using a solid electrolyte as an electrolyte. Applications of the battery include, for example, power sources for vehicles such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), electric vehicles (BEVs), gasoline automobiles, and diesel automobiles. In particular, the battery may be used as a driving power source for hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), or electric vehicles (BEVs). The battery may also be used as a power source for moving objects other than vehicles (for example, railways, ships, and aircraft), and may also be used as a power source for electrical appliances such as information processing devices. EXAMPLES

[0030] (Examples 1 to 6, Comparative Example 1) The electrode material used was a negative electrode material containing graphite as a negative electrode active material, CMC as a thickener, and SBR as a binder. The width of the electrode material was 1000 mm. A workpiece was prepared by coating one surface of a current collector with an electrode material, and the workpiece was irradiated with a laser to dry the electrode material, thereby obtaining an electrode body. The laser energy density is 2W / cm 2 The laser irradiation area was 1200 mm x 300 mm. As shown in Table 1, in each of the examples and comparative examples, the quality of the coated edge was evaluated when the inclination angle of the laser irradiation range with respect to the width direction of the electrode material was changed. The quality was evaluated by visually checking whether the electrode body had any cracks. The results are shown in Table 1.

[0031] [Table 1]

[0032] As shown in Table 1, it has been demonstrated that the electrode assembly obtained by the manufacturing method of the present disclosure can reduce the occurrence of cracks. [Explanation of symbols]

[0033] 1. Work 2. Electrode material 3. Intermittent section

Claims

1. A method for manufacturing an electrode assembly, comprising the steps of: a drying step of drying the electrode material by a laser while transporting a workpiece having an electrode material applied on at least one surface of a current collector; A method for manufacturing an electrode body, wherein in the drying process, the laser is irradiated onto the workpiece so that the irradiation range of the laser is inclined with respect to the transport direction of the workpiece when viewed in a plane.

2. In a plan view of the workpiece, a width direction of the electrode material is perpendicular to a transport direction of the workpiece, The method for manufacturing an electrode body according to claim 1 , wherein an inclination angle of the laser irradiation range with respect to the width direction of the electrode material is 10° or more and 60° or less.

Images