Emulsified cosmetic and hair cosmetic

Abstract

To provide a cosmetic which is superior in both the ability to set and to be restyled, and further has superior spreadability.SOLUTION: The present invention provides an emulsified cosmetic or hair cosmetic comprising the following components (A) to (D): (A) a solid oil; (B) hydrogenated polyisobutene; (C) a film former; and (D) polyethylene glycol in an amount of less than 10 mass%, where the mass ratio (A) / (D) of component (A) to component (D) is 1 to 10, and the mass ratio (B) / (D) of component (B) to component (D) is 0.2 to 1.2.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a cosmetic preparation, an emulsion cosmetic preparation, a hair cosmetic preparation, and the like. [Background technology]

[0002] Emulsion cosmetics are a commonly used formulation for cosmetics, and for example, water-in-oil emulsion cosmetics are widely used in foundations, primers, sunscreens, etc. because of the light spreadability of the oily outer phase and the long-lasting makeup. On the other hand, oil-in-water emulsion cosmetics are preferred when imparting a moisturizing effect to the skin.

[0003] Also, hair cosmetics for hair, eyelashes, eyebrows, etc. are known. For example, hair cosmetics for hair, such as aerosol type hair cosmetics and hair wax, are known as hair cosmetics for styling hair. However, aerosol type hair cosmetics generally use the fixing power of a hair setting polymer to fix hair, but once the hair style is broken after fixing the hair, there is a problem that the hair cannot be fixed again. Also, hair wax is known to have a high hair setting power, but this hair wax usually has a problem that it is poorly restyling. Also, when used on hair or skin, cosmetics that have a sense of spreading and are easy to use are preferable for users.

[0004] For example, Patent Document 1 proposes a hair cosmetic composition that contains a fluorine-modified silicone and / or a fluorine-modified methylphenylpolysiloxane represented by a specific general formula, and a hair setting agent resin. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Publication No. 10-167933 Summary of the Invention [Problem to be solved by the invention]

[0006] Therefore, a main object of the present invention is to provide a cosmetic composition that is excellent in both setting power and restyling ability, and also in spreadability. [Means for solving the problem]

[0007] As a result of intensive research, the present inventors have found that by using component (A) solid oil, component (B) hydrogenated polyisobutene, component (C) film-forming agent, and component (D) polyethylene glycol and adjusting the ratio of these quantities (content, content by mass, etc.), a cosmetic composition excellent in at least both setting power and hair restyling ability can be provided, and have completed the present invention. Furthermore, the present invention can provide a cosmetic composition excellent in both setting power and hair restyling ability, as well as excellent spreadability.

[0008] The present invention relates to the following components (A) to (D); (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: Less than 10% by mass wherein the mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10, and the mass ratio (B) / (D) of the component (B) to the component (D) is 0.2 to 1.2.

[0009] The present invention also relates to the following components (A) to (D): (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: Less than 10% by mass wherein the mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10, and the mass ratio (B) / (D) of the component (B) to the component (D) is 0.2 to 1.2.

[0010] The cosmetic may be an oil-in-water emulsion type cosmetic. The component (A) solid oil may be a polar wax. The component (B) hydrogenated polyisobutene has a kinetic viscosity at 98.9°C of 50 to 10,000 mm 2 / s may also be used. The polyethylene glycol of component (D) may be a polyethylene glycol having a number average molecular weight of 10,000 or more. The component (C) film-forming agent may be a nonionic film-forming resin and / or a cationic film-forming resin. The mass ratio (A) / (B) of the component (A) to the component (B) may be 1-15. The mass ratio (B) / (C) of the component (B) to the component (C) may be 0.2-3. Effect of the Invention

[0011] The present invention can provide a cosmetic composition that is excellent in both setting power and restyling ability, and also in spreadability. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0012] A preferred embodiment for carrying out the present technology will be described below. The embodiment described below shows an example of a typical embodiment of the present technology, and the scope of the present invention is not narrowly interpreted by this. In this specification, percentages are expressed by mass unless otherwise specified. In addition, the upper limit value (or less) and the lower limit value (or more) of each numerical range (~) can be arbitrarily combined as desired. In addition, the quantitative ratio of the content or the content mass ratio can be appropriately adopted as the quantitative ratio of the usage amount or the usage content ratio.

[0013] 1. Overview of this technology A hair cosmetic product is required to have a setting power capable of fixing the style of hair and maintaining the style that has been created, while at the same time having a hair-styling ability that allows the hair to be readjusted into a desired shape or style using a comb, fingers, etc. after setting. However, there have been many cosmetics that have excellent setting power but poor hair restyling ability, or excellent hair restyling ability but poor setting power, and it is technically difficult to resolve this trade-off relationship in which both effects cannot be achieved at the same time. Therefore, the inventors of the present invention aimed to develop a cosmetic that has excellent setting power and excellent hair restyling ability by eliminating the relationship between tray and off.

[0014] As a result of intensive research, the present inventors have completed a cosmetic composition according to the present technology, which has excellent setting power and excellent restyling properties, by using component (A) solid oil, component (B) hydrogenated polyisobutene, component (C) film-forming agent, and component (D) polyethylene glycol, and adjusting the quantitative ratio (content, mass ratio, etc.) of these components (A) to (D). Based on this adjusted cosmetic composition, the present technology can be used in an emulsified state, and since it is an emulsified composition, it can be used in a wide range of formulations and applications. In addition, since the present technology uses a film-forming agent and solid oil, it is considered that it can also be used for makeup, protection of hair, skin, etc.

[0015] Furthermore, from the viewpoint of user's usability, it is preferable that the cosmetic of the present technology has good spreadability when used. However, conventionally, cosmetic products with excellent setting power tend to have problems such as poor spreadability. The present inventors have also found that, based on the cosmetic of the present technology, it is possible to provide a cosmetic product that has excellent spreadability (good spreadability) in addition to setting power and hair re-styling ability by adjusting the components (A) to (D) and their quantitative ratios (contents, mass ratios, etc.) as shown in the Examples below. The present technology that can achieve the second object can also provide a cosmetic product with better spreadability (good spreadability) when used by the user, and for example, the hair cosmetic of the present technology can be adjusted to the user's desired shape or style (for example, fine bundles) when setting. As a more specific example, when the hair cosmetic of the present technology is applied to the hair and set, it can be adjusted to the desired shape or style, and even when the hair is set again without applying a new cosmetic product after setting, it can be readjusted to the desired shape or style. That is, the second main objective of the present technology is to provide a cosmetic composition that is excellent in both setting power and hair restyling properties, and also has excellent spreadability.

[0016] Furthermore, as shown in the Examples below, the present inventors have found that by adjusting the components (A) to (D) and their quantitative ratios (contents, mass ratios, etc.) based on the cosmetic composition of the present technology, a cosmetic composition can be provided that is excellent in stability over time (particularly emulsion stability over time) in addition to the setting power and hair restyling properties. This has the advantage that the quality of the emulsion state in the present technology can be maintained for a long period of time, and the claimed effects are also likely to be maintained for a long period of time. In other words, the third main objective of the present technology is to provide a cosmetic composition that is excellent in both setting power and hair restyling properties and is also excellent in stability over time.

[0017] Furthermore, as shown in the Examples below, the present inventors have also found that, based on the cosmetic composition according to the present technology, a cosmetic composition excellent in setting power, hair restyling ability, spreadability, and stability over time can be provided by adjusting components (A) to (D) and their quantitative ratios (contents, mass ratios contained, etc.) etc. In other words, the present technology can also have as its fourth main objective the provision of a cosmetic composition excellent in both setting power and hair restyling ability, as well as spreadability and stability over time.

[0018] In this specification, the contents of each configuration and each method (each component, each quantitative ratio, etc.) explained in any of the sections such as "1.", "2.", "3.", "4.", etc. may be omitted as appropriate in the explanation of each section, and the technology or components explained in other sections may be adopted and applied as appropriate to the explanation of each section (each configuration, each method, etc.).

[0019] 2. Cosmetics related to this technology Although embodiments according to the present technology will be described below, the present invention and the embodiments are not limited thereto.

[0020] This technology can provide a cosmetic preparation containing component (A) solid oil, component (B) hydrogenated polyisobutene, component (C) a film-forming agent, and component (D) polyethylene glycol. A preferred embodiment of the present technology is an emulsion cosmetic or hair cosmetic. The emulsion cosmetic or hair cosmetic may more preferably be either an oil-in-water emulsion cosmetic or a water-in-oil emulsion cosmetic, and is even more preferably an oil-in-water emulsion cosmetic or an oil-in-water emulsion hair cosmetic.

[0021] In this specification, "hair" is used in a broad sense and includes head hair, eyebrows, eyelashes, beard, and whiskers, and in this technology, it is preferable to target hair that is applied with makeup or groomed.

[0022] Furthermore, as a preferred embodiment of the present technology, it is preferable from the viewpoint of at least setting power and restyling ability to specify a quantitative ratio based on a combination of one or more selected from component (A) solid oil, component (B) hydrogenated polyisobutene, component (C) film-forming agent, and component (D) polyethylene glycol. Furthermore, the present technology can provide a cosmetic preparation with excellent spreadability and / or stability over time. The quantitative ratio may be the content of each component and / or the mass ratio of the combination of each component. "Containing" may also mean "used" and may be the amount used and / or the mass ratio used. Hereinafter, simply "% by mass" will be abbreviated to "%" as appropriate.

[0023] 2-1. Component (A) Solid oil The component (A) solid oil used in the present technology is not particularly limited, and is preferably an oil that is solid at 35°C. Solid oils used in cosmetics and the like can be used, and can be obtained appropriately from commercial products or known manufacturing methods. Furthermore, from the viewpoint of setting power and hair restyling ability, the melting point of the solid oil is preferably 50°C or higher as a suitable lower limit, more preferably 60°C or higher, and is preferably 110°C or lower as a suitable upper limit, more preferably 100°C or lower, even more preferably 90°C or lower, more preferably 80°C or lower, and the preferred numerical range is preferably a melting point of 60 to 90°C. Specifying the above numerical range is also desirable from the viewpoint of further improving spreadability and / or stability over time. For spreadability, a lower melting point is desirable, and for stability over time, a higher melting point is desirable.

[0024] The solid oil is not particularly limited, but examples thereof include waxes such as carnauba wax, candelilla wax, beeswax, synthetic wax, polyethylene wax, montan wax, Japan wax, ozokerite wax, ethylene-propylene copolymer, microcrystalline wax, Fischer-Tropsch wax, solid paraffin wax, ceresin, rice wax, and silicone wax; fatty acids such as behenic acid; and fatty acid esters such as glyceryl tribehenate; and the like, which are usually used as solid oils having a melting point of 60 to 90° C. In addition, examples of solid oils having a melting point of 90 to 110° C. include waxes such as ethylene-propylene copolymer, Fischer-Tropsch wax, and polypropylene wax; and the like. In addition, examples of solid oils having a melting point of 60 to 110° C. include, but are not limited to, waxes such as ceresin wax, microcrystalline wax, polyethylene wax, and ozokerite wax; however, depending on the molecular weight, etc., some of these waxes are classified as having a melting point of 90 to 110° C., and others as having a melting point of 60 to 90° C. Carnauba wax, candelilla wax, and beeswax are also called carnauba wax, candelilla wax, and beeswax, respectively.

[0025] As the component (A) solid oil used in the present technology, one or more types selected from the above-mentioned solid oils having a melting point of 60 to 90° C., solid oils having a melting point of 90 to 110° C., and solid oils having a melting point of 60 to 110° C. can be used. These three exemplified types of solid oils may be appropriately combined, and one or more types selected from these may be used.

[0026] Among the solid oils, wax is preferred from the viewpoint of setting power and restyling ability, and is also desirable from the viewpoint of improving spreadability and / or stability over time. The wax may be either polar or non-polar, and is more preferably in the broad sense including wax. One or more of the above-mentioned solid oils or waxes can be used.

[0027] As the solid oil used in the present technology, polar wax is preferable from the viewpoint of setting power and ease of restyling, and is further desirable from the viewpoint of improving spreadability and / or stability over time. The polar wax is not particularly limited, and those used in cosmetics and the like can be used, and may be either natural wax or synthetic wax (also called natural wax or synthetic wax). Natural waxes include, for example, biological waxes such as beeswax derived from animals and carnauba wax derived from plants; fossil waxes such as paraffin wax derived from crude oil and ceresin derived from minerals; and the like. One or more types selected from these may be used.

[0028] The polar wax is preferably a wax having a polar group such as a fatty acid, ester, alcohol, etc., and the polar group is composed of carbon and hydrogen atoms and includes at least one highly electronegative heteroatom, such as an oxygen, nitrogen, silicon, or phosphorus atom.

[0029] The polar wax used in the present technology is not particularly limited, but examples thereof include beeswax, candelilla wax, carnauba wax, rice wax, Japan wax, and safflower wax. Among these, beeswax, candelilla wax, and carnauba wax are more preferable from the viewpoint of setting power and restyling ability, and are also preferable from the viewpoint of improving spreadability. Commercially available products include WHITE BEESWAX (manufactured by Miki Chemical Co., Ltd., melting point: 60 to 67°C), refined candelilla wax SR-3 (manufactured by Nippon Natural Products Co., Ltd., melting point: 70 to 75°C), and carnauba wax (manufactured by Machado Chemical Co., Ltd., melting point: 83°C). One or more types selected from these can be used.

[0030] The content of the solid oil component (A) in the present technology is not particularly limited, but from the viewpoint of the setting power and hair restyling ability, the suitable upper limit is preferably less than 25% by mass, more preferably less than 20%, even more preferably 19, 18, 17 or 16% or less, more preferably 15% or less, more preferably 13% or less, and the suitable lower limit is preferably 0.5% or more, more preferably 1% or more, even more preferably 2% or more, more preferably 3% or more, more preferably 4% or more, more preferably 5% or more. From the viewpoint of improving the spreadability and stability over time, the amount of solid oil is preferably less than 20%. From the viewpoint of the setting power and hair restyling ability, the suitable numerical range of the content of the component (A) is preferably 1% or more and less than 20%, more preferably 5 to 15%, based on the total amount of the cosmetic. It is also desirable to specify the numerical range as above from the viewpoint of improving the spreadability and / or stability over time.

[0031] In the present technology, from the viewpoint of setting power and hair restyling ability, it is preferable that the solid oil (A) contains a polar wax, and the polar wax in the solid oil (A) is not particularly limited, but is preferably 50% or more, more preferably 60% or more, even more preferably 70% or more, more preferably 80% or more, more preferably 90% or more, and more preferably 95% or more of the total amount of the solid oil. Specifying the above numerical range is also desirable from the viewpoint of improving spreadability and / or stability over time.

[0032] The content of the polar wax in the total amount of the cosmetic in the present technology is not particularly limited, but from the viewpoint of the setting power and hair restyling ability, the suitable upper limit is preferably less than 25% by mass, more preferably less than 20%, even more preferably 19, 18, 17 or 16% or less, more preferably 15% or less, more preferably 13% or less, and the suitable lower limit is preferably 0.5% or more, more preferably 1% or more, even more preferably 2% or more, more preferably 3% or more, more preferably 4% or more, more preferably 5% or more. From the viewpoint of improving the spreadability and stability over time, it is desirable to have a small amount of polar wax, and it is preferable that the amount is less than 20% of the total amount of the cosmetic. From the viewpoint of the setting power and hair restyling ability, the suitable numerical range of the content of the polar wax is preferably 1% or more and less than 20%, more preferably 5 to 15% of the total amount of the cosmetic. It is also desirable to specify the numerical range as above from the viewpoint of improving the spreadability and / or stability over time.

[0033] 2-2. Component (B) Hydrogenated polyisobutene

[0034] The component (B) hydrogenated polyisobutene used in the present technology is not particularly limited, and hydrogenated polyisobutene used in cosmetics and the like can be used, and can be obtained appropriately from a commercially available product or a known manufacturing method. Hydrogenated polyisobutene is generally considered to be a mixture of branched saturated hydrocarbons. Examples of hydrogenated polyisobutene include light liquid isoparaffin, liquid isoparaffin, and heavy liquid isoparaffin. In addition, examples of hydrogenated polyisobutene include those having a kinetic viscosity at 98.9°C of 200 to 10,000 mm 2 / s heavy liquid isoparaffin. The average molecular weight of component (B) is preferably 500 to 3,000. Commercially available products of component (B) include, for example, purified polybutene HV-100F (SB) (manufactured by Nippon Natural Products Co., Ltd.), Pearleem 18 (average carbon number 72 / average molecular weight: 1000 / 98.9°C kinematic viscosity 290mm 2 / s), Pearleem 24 (average carbon number 96 / average molecular weight: 1350 / 98.9℃ kinematic viscosity 740mm 2 / s), Pearleem 46 (average carbon number 184 / average molecular weight: 2650 / 98.9℃ kinematic viscosity 5000mm 2 / s) (all manufactured by NOF Corporation) (see JP 2014-221722 A). One or more types selected from these can be used.

[0035] From the viewpoint of setting power and hair restyling ability, the hydrogenated polyisobutene has a kinematic viscosity at 98.9° C. (210° F. in the case of a kinematic viscosity test in Fahrenheit) (hereinafter also referred to as "kinematic viscosity" or "98.9° C. kinematic viscosity") of preferably 50 mm 2 / s or more, preferably 100 mm 2 / s or more, more preferably 150m 2 / s or more, and more preferably 200m 2 / s or more, and more preferably 250m 2 / s or more, more preferably 260 or 270 m 2 / s or more, and the preferred upper limit is preferably 10,000 mm 2 / s or less, preferably 8,000 mm 2 / s or less, preferably 5,000 mm 2 / s or less, preferably 3,000 mm 2 / s or less, preferably 1,000 mm 2 / s or less, preferably 800 mm 2 / s or less, more preferably 500 or 400 mm 2 From the viewpoint of improving ductility, it is desirable to have a low kinetic viscosity of 1,000 mm 2 The preferred range of the kinetic viscosity of the hydrogenated polyisobutene is 50 to 10,000 mm / s from the viewpoint of setting power and ease of restyling. 2 / s, more preferably 50 to 5,000 mm 2 / s, and more preferably 100 to 1,000 mm 2 / s, more preferably 200 to 500 mm 2 It is preferable to specify the above numerical range from the viewpoint of improving the ductility and / or stability over time.

[0036] In this technology, the "kinematic viscosity of hydrogenated polyisobutene" can be measured according to the method described in JIS K 2283 (Crude oil and petroleum products-Kinematic viscosity test method and viscosity index calculation method).

[0037] The content of hydrogenated polyisobutene (B) in the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the preferred upper limit is preferably less than 9%, more preferably less than 8%, even more preferably less than 7%, more preferably 6% or less, even more preferably 5% or less, and the preferred lower limit is preferably 0.05% or 0.1% or more, more preferably 0.5% or more, even more preferably 1% or more, and even more preferably 2% or more. From the viewpoint of improving spreadability and stability over time, the hydrogenated polyisobutene is preferably less than 9%, and is preferably less than 9%. From the viewpoint of setting power and hair restyling ability, the preferred numerical range of the content of the component (B) is preferably 0.1% or more and less than 9%, more preferably 0.5% or more and less than 7%, and even more preferably 1% or more and less than 6%. It is also desirable to specify the above numerical range from the viewpoint of improving spreadability and / or stability over time.

[0038] 2-3. Component (C) Film-forming agent The film-forming agent (C) used in the present technology is not particularly limited, but is preferably a film-forming resin, and a film-forming agent or film-forming resin used in cosmetics or the like can be used, and can be obtained appropriately from a commercially available product or a known manufacturing method. Examples of the film-forming resin include cationic, anionic, amphoteric, and nonionic film-forming resins, and one or more selected from these can be used. In the present technology, cationic and / or nonionic resins are preferred from the viewpoint of setting power and restyling ability, and are also desirable from the viewpoint of improving spreadability and stability over time. Furthermore, the film-forming agent or resin is preferably a water-soluble film-forming agent or resin from the viewpoints of setting power and ease of restyling, and is also preferable from the viewpoints of improving spreadability and stability over time. These water-soluble agents or resins can be appropriately obtained as commercially available products or by known production methods.

[0039] In the present technology, "film formation" refers to a process in which a solution in which the corresponding component is dissolved at 40% in a soluble solvent is applied to a glass plate with a 400 μm-thick applicator, and a film is preferably formed after drying at room temperature for 24 hours. Examples of the soluble solvent include water and / or organic solvents (e.g., ethyl acetate, acetone, etc.) (see, for example, paragraph

[0052] of JP 2020-29443 A).

[0040] In the present technology, the "copolymer" may be, for example, a copolymer of (monomer name) and (monomer name) (e.g., a copolymer of vinylpyrrolidone monomer and vinyl acetate monomer), or a (monomer name) / (monomer name) copolymer (e.g., vinylpyrrolidone / vinyl acetate copolymer), but is not particularly limited to these expressions.

[0041] The cationic film-forming resin is not particularly limited, but examples thereof include cationic polysaccharides (e.g., cationic guar gum, cationic starch, cationic cellulose, etc.), cationic (meth)acrylic acid copolymers, cationic vinylpyrrolidone polymers, polyquaternium compounds (-4, -5, -6, -7, -8, -9, -10, -11, -12, -14, -15, -16, -17, -18, -19, -20, -22, -24, -27, -28, -29, -30, -31, -32, -33, -34, -35, -36, -37, -39, -42, -43, -45, -46, -47, -69, etc.), and salts thereof. One or more types selected from these may be used.

[0042] The cationic cellulose is not particularly limited, but examples thereof include hydroxyethyl cellulose dimethyl diallyl ammonium chloride (polyquaternium 4), -O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethyl cellulose chloride (polyquaternium 10), -O-[2-hydroxy-3-(lauryldimethylammonio)propyl]hydroxyethyl cellulose chloride (polyquaternium 24), and the like. One or more types selected from these may be used.

[0043] The cationic (meth)acrylic acid copolymer (excluding cationic polyvinylpyrrolidone copolymer) is not particularly limited, and examples thereof include dimethyldiacrylammonium chloride / acrylamide copolymer (Polyquaternium 7), dimethyldiallylammonium chloride / acrylic acid copolymer (Polyquaternium 22), acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer (Polyquaternium 39), 2-methacryloyloxyethylphosphorylcholine / butyl methacrylate copolymer (Polyquaternium 51), N,N-dimethylamine copolymer (Polyquaternium 52), and the like. Examples of the copolymer include diethyl methacrylate sulfate / N,N-dimethylacrylamide / polyethylene glycol dimethacrylate (polyquaternium 52), 2-methacryloyloxyethyl phosphorylcholine / stearyl methacrylate copolymer (polyquaternium 61), methacryloyloxyethylene phosphorylcholine, butyl methacrylate and sodium methacrylate (polyquaternium 65), hydroxyethyl cellulose hydroxypropyl trimethyl ammonium chloride ether, and the like. One or more selected from these may be used. In the present technology, "(meth)acrylic acid" means "acrylic acid" and / or "methacrylic acid".

[0044] The cationic vinylpyrrolidone copolymer is not particularly limited, and examples thereof include a copolymer of vinylpyrrolidone / N,N-dimethylaminoethyl methacrylic acid or a salt thereof (e.g., diethyl sulfate) (e.g., Polyquaternium 11), a copolymer of vinylpyrrolidone / quaternized vinylimidazole (e.g., Polyquaternium 16), a copolymer of vinylpyrrolidone / methacrylamidopropyltrimethylammonium (e.g., Polyquaternium 28), a copolymer of 3-methyl-1-vinylimidazolium methylsulfonate / N-vinylpyrrolidone (e.g., Polyquaternium 29), Examples of suitable copolymers include vinylpyrrolidone / methacrylamide / vinylpyrrolidone / quaternized vinylimidazole terpolymers (e.g., polyquaternium 44), vinylcaprolactam / vinylpyrrolidone / quaternized vinylimidazole terpolymers (e.g., polyquaternium 46), vinylpyrrolidone / methacrylamide / vinylimidazole / methylvinylimidazolium methyl sulfate copolymers, methylvinylimidazolium chloride / vinylpyrrolidone copolymers, methylvinylimidazolium / vinylpyrrolidone copolymers or salts thereof (e.g., methyl sulfate), and vinylpyrrolidone / N,N-dimethylaminoethyl methacrylic acid copolymers or salts thereof (diethyl sulfate, dimethyl sulfate, hydrochloride, etc.).

[0045] The anionic film-forming resin is not particularly limited, but examples thereof include anionic polymers (homopolymers or copolymers) and anionic polysaccharides, and one or more types selected from these can be used. The anionic polysaccharide is not particularly limited, but examples thereof include carboxymethylcellulose, xanthan gum, carrageenan, sodium alginate, gum arabic, pectin, etc., and one or more types selected from these can be used.

[0046] The anionic polymer is not particularly limited, but examples thereof include carboxyvinyl polymers, acrylic resin alkanolamines which are copolymers of (meth)acrylic acid and (meth)acrylic acid alkyl esters, methyl vinyl ether and maleic acid monoalkyl ester copolymers, copolymers of acrylic acid, acrylic acid alkyl esters and N-alkylacrylamide, methyl vinyl ether / maleic anhydride alkyl half ester copolymers, vinyl acetate / crotonic acid copolymers, vinyl acetate / crotonic acid / vinyl neodecanoate copolymers, vinyl acetate / crotonic acid / vinyl propionate copolymers, vinyl acetate / maleic acid monobutyl ester / isobornyl acrylate copolymers, acrylic acid / acrylic acid alkyl ester / alkyl acrylamide copolymers, (acrylates / diacetone acrylamide) copolymer AMP, (acrylates / alkyl (C1-18) acrylate / alkyl (C1-8) acrylamide) copolymer AMP; vinyl pyrrolidone-based copolymers such as polyvinyl pyrrolidone / acrylate / (meth)acrylic acid copolymers; and the like. One or more selected from these may be used. In addition, "AMP" in the film-forming resin is an abbreviation for 2-amino-2-methyl-1-propanol.

[0047] The amphoteric film-forming resin is not particularly limited, but examples thereof include monochloroacetic acid amphoteric products of dialkylaminoethyl methacrylate / alkyl methacrylate ester copolymers, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymers, (acrylates / lauryl acrylate / stearyl acrylate / ethylamine oxide methacrylate) copolymers, and (octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymers, and one or more types selected from these can be used.

[0048] Examples of nonionic film-forming resins include, but are not limited to, vinyl acetate / N-vinyl-5-methyl-2-oxazoline copolymers; nonionic vinylpyrrolidone polymers (homopolymers and copolymers) such as polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer (also referred to as (VP / VA) copolymer), polyvinylpyrrolidone / vinyl acetate copolymer, and polyvinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer; and the like. One or more types selected from these may be used. In the film-forming agents or film-forming resins of the present technology, vinyl acetate may be abbreviated as "VA", vinylpyrrolidone as "VP", and polyvinylpyrrolidone as "PVP".

[0049] Commercially available examples of vinylpyrrolidone / vinyl acetate copolymers include PVA-6450 Acorn M ((VP / VA) copolymer) (manufactured by Osaka Organic Chemical Industry Co., Ltd.), PVP / VA S-630, PVP / VA E-735 (manufactured by ISP), LUVISCOL VA37E, LUVISCOL VA55E, LUVISCOL VA64P, and LUVISCOL VA73E (manufactured by BASF), and examples of N-vinylpyrrolidone / (meth)acrylamide / vinylimidazole copolymers include, but are not limited to, Luviset Clear (manufactured by BASF).

[0050] In addition, among the film-forming agents (C) used in the present technology, vinylpyrrolidone polymers and / or vinyl acetate polymers (excluding those having a vinylpyrrolidone structure in the molecule) are preferred, and examples of these polymers include, but are not limited to, those listed above. Among these, vinylpyrrolidone polymers are more preferred, and examples of vinylpyrrolidone polymers include homopolymers (also called "polyvinylpyrrolidone") produced only from vinylpyrrolidone monomers, and vinylpyrrolidone copolymers (copolymers) produced from vinylpyrrolidone monomers and other monomers. Furthermore, among the vinylpyrrolidone polymers, one or more selected from cationic, nonionic, and amphoteric are preferred, and more preferably cationic vinylpyrrolidone copolymers and / or nonionic vinylpyrrolidone polymers, and examples of these include those listed above.

[0051] Of the film-forming agents (C) used in the present technology, one or more selected from polyvinylpyrrolidone (also referred to as PVP), vinylpyrrolidone / vinyl acetate copolymer (also referred to as (VP / VA) copolymer), and vinylpyrrolidone / N,N-dimethylaminoethyl methacrylic acid copolymer or a salt thereof (e.g., polyquaternium-11, etc.) are more preferred, and among these, vinylpyrrolidone / vinyl acetate copolymer is more preferred.

[0052] In the present technology, even if a vinyl acetate structure is present in the molecule, when the vinyl pyrrolidone structure is present, it is preferable to include it in the vinyl pyrrolidone-based polymer. For example, a vinyl pyrrolidone / vinyl acetate copolymer is preferable to be included in the vinyl pyrrolidone-based copolymer.

[0053] The content of the film-forming agent (C) in the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the suitable upper limit is preferably less than 10%, more preferably less than 8%, even more preferably less than 5%, and more preferably 4% or less, relative to the total amount of the cosmetic, and the suitable lower limit is preferably 0.1% or more, even more preferably 0.5% or more, and more preferably 1% or more. From the viewpoint of improving spreadability, the film-forming agent is preferably less than 10%, and preferably less than 10%. From the viewpoint of setting power and hair restyling ability, the suitable numerical range of the content of the component (C) is preferably 0.1% or more and less than 10%, more preferably 0.5% or more and less than 5%, and more preferably 1% or more and less than 4% relative to the total amount of the cosmetic. It is also desirable to specify the numerical range as above from the viewpoint of improving spreadability and / or stability over time.

[0054] Furthermore, the content of the cationic and / or nonionic resin in the cosmetic of the present technology may be determined by appropriately adopting a suitable upper limit value or a suitable lower limit value of the content of the film-forming agent of component (C) and combining these appropriately. A suitable numerical range is preferably less than 10%, more preferably 0.1% or more and less than 10%, more preferably 0.5% or more and less than 5%, and more preferably 1% or more and 4% or less, relative to the total amount of the cosmetic.

[0055] In the present technology, from the viewpoint of setting power and hair restyling ability, it is preferable that the component (C) film-forming agent contains a vinylpyrrolidone polymer (preferably a cationic and / or nonionic vinylpyrrolidone polymer), and the content of the vinylpyrrolidone polymer in the component (C) film-forming agent is not particularly limited, but is preferably 50% or more, more preferably 60% or more, even more preferably 70% or more, more preferably 80% or more, more preferably 90% or more, and more preferably 95% or more of the total amount of the film-forming agent. Specifying the value range as above is also desirable from the viewpoint of improving spreadability and / or stability over time.

[0056] The content of the vinylpyrrolidone polymer in the cosmetic of the present technology is not particularly limited, but from the viewpoint of the setting power and hair restyling ability, the suitable upper limit is preferably less than 10%, more preferably less than 8%, even more preferably less than 5%, and more preferably 4% or less, and the suitable lower limit is preferably 0.1% or more, more preferably 0.5% or more, more preferably 1% or more, and even more preferably 2% or more. From the viewpoint of improving the spreadability, the vinylpyrrolidone polymer is preferably less than 10% of the total amount of the cosmetic. From the viewpoint of the setting power and hair restyling ability, the suitable numerical range of the vinylpyrrolidone polymer is preferably 0.1% or more and less than 10%, more preferably 0.5% or more and less than 5%, and more preferably 1% or more and less than 4% of the total amount of the cosmetic. It is also desirable to specify the numerical range as above from the viewpoint of improving the spreadability and / or stability over time.

[0057] The content of the cationic and / or nonionic vinylpyrrolidone-based polymer in the cosmetic of the present technology may be determined by appropriately adopting a suitable upper limit value or a suitable lower limit value of the content of the vinylpyrrolidone-based polymer as described above and combining these appropriately. A suitable numerical range is preferably less than 10%, more preferably 0.1% or more and less than 10%, more preferably 0.5% or more and less than 5%, and more preferably 1% or more and 4% or less, based on the total amount of the cosmetic.

[0058] 2-4. Component (D) Polyethylene glycol The polyethylene glycol component (D) used in this technology can be any polyethylene glycol used in cosmetics, etc., and can be obtained from commercial products or known manufacturing methods. Polyethylene glycol is a polyether polymer compound with a polymerized structure of ethylene glycol, and is also abbreviated as PEG. The general structural formula is HO-(CH2-CH2-O) n-H, and specific examples (INCI names) of polyethylene glycol include, for example, PEG-100, PEG-200, PEG-240, PEG-300, PEG-400, PEG-600, PEG-800, and PEG-2M, and one or more selected from these can be used. For example, the INCI name PEG-400 means polyethylene glycol with an average n of 400, and other names include PEG(400), polyethylene glycol 20000, and PEG20000. When using a commercially available product, n can be understood from the numerical portion of the PEG-numerical portion of the INCI name of the commercially available product.

[0059] Among the above polyethylene glycols, from the viewpoint of setting power and ease of restyling, those in the range of PEG-240 to PEG-2M are preferred, those in the range of PEG-200 to PEG-800 are more preferred, and those in the range of PEG-240 to PEG-400 are even more preferred, and one or more selected from these may be used, and are also preferred from the viewpoint of improving spreadability and / or stability over time. Of these, PEG-400 is more preferred.

[0060] The number average molecular weight of the polyethylene glycol component (D) is not particularly limited, but from the viewpoint of the setting power and hair restyling ability, the suitable lower limit is preferably 5,000 or more, more preferably 10,000 or more, and even more preferably 15,000 or more. The suitable upper limit is not particularly limited, but the upper limit is naturally determined by the upper limit value of PEG available in commercially available products, etc., and can be, for example, 200,000 or 100,000, etc., and is preferably 80,000 or less, more preferably 50,000 or less, and even more preferably 30,000 or less. From the viewpoint of improving the spreadability, the number average molecular weight is preferably low, and is preferably 100,000 or less. From the viewpoint of the setting power and hair restyling ability, the suitable numerical range of the number average molecular weight of the component (D) is preferably 10,000 or more and 100,000 or less, more preferably 10,000 or more and 50,000 or less. It is also desirable to specify the above numerical range from the viewpoint of improving the spreadability and / or stability over time.

[0061] The average molecular weight of polyethylene glycol in this technology can be expressed as a number average molecular weight (Mn). The number average molecular weight (Mn) can be determined by GPC analysis, and polystyrene can be used as a standard.

[0062] Commercially available polyethylene glycol products include polyethylene glycol 20000 (manufactured by NOF Corporation), PEG11000 (manufactured by NOF Corporation), and FOAMYSENSE N10 POLYMER (manufactured by Dow-Toray Industries, Inc.).

[0063] The content of component (D) polyethylene glycol in the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the suitable upper limit is preferably less than 13%, more preferably less than 10%, even more preferably 9% or less, more preferably 8% or less, more preferably 7% or less, and more preferably 5% or less, and the suitable lower limit is preferably 0.1% or more, even more preferably 0.5% or more, more preferably 1% or more, more preferably 2% or more, and more preferably 3% or more. From the viewpoint of improving spreadability and stability over time, it is desirable to have a small amount of polyethylene glycol, and it is preferable to have less than 10% of the total amount of the cosmetic. From the viewpoint of setting power and hair restyling ability, the suitable numerical range of the content of said component (D) is preferably 0.1% or more and less than 10%, more preferably 2% or more and 8% or less, based on the total amount of the cosmetic. It is also desirable to specify the above numerical range from the viewpoint of improving spreadability and / or stability over time.

[0064] In the present technology, from the viewpoint of setting power and hair restyling property, the component (D) polyethylene glycol preferably contains one or more kinds selected from the range of PEG-240 to PEG-800, more preferably one or more kinds selected from the range of PEG-240 to PEG-400, and even more preferably PEG-400. In this case, the content of PEG-400 in the component (D) polyethylene glycol is not particularly limited, but is preferably 50% or more, more preferably 60% or more, even more preferably 70% or more, more preferably 80% or more, more preferably 90% or more, and more preferably 95% or more of the total amount of polyethylene glycol. Specifying the value range as above is also desirable from the viewpoint of further improving spreadability and / or stability over time.

[0065] The content of PEG-400 in the cosmetic of the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the suitable upper limit is preferably less than 13%, more preferably less than 10%, even more preferably 9% or less, more preferably 8% or less, more preferably 7% or less, and more preferably 5% or less, and the suitable lower limit is preferably 0.1% or more, even more preferably 0.5% or more, more preferably 1% or more, more preferably 2% or more, and more preferably 3% or more. From the viewpoint of improving spreadability and stability over time, it is desirable to have a small amount of PEG-400, and it is preferable to have less than 10% of the total amount of the cosmetic. From the viewpoint of setting power and hair restyling ability, the suitable numerical range of the PEG-400 is preferably 0.1% or more and less than 10%, more preferably 2% or more and 8% or less, based on the total amount of the cosmetic. It is also desirable to specify the numerical range as above from the viewpoint of improving spreadability and / or stability over time.

[0066] 2-5. Mass ratio of each component in this technology From the viewpoints of setting power and hair restyling ability, the preferred lower limit of the content mass ratio (A) / (D) in the cosmetic of the present technology is preferably more than 0.8 or more, more preferably 0.9 or more, and even more preferably 1 or more, and the preferred upper limit is preferably 10 or less, more preferably 7 or less, even more preferably 5 or less, and even more preferably 3 or less, and from the viewpoints of setting power and hair restyling ability, the preferred numerical range is preferably 1 to 10, more preferably 1 to 7, and even more preferably 1 to 5. Specifying the numerical range as above is also desirable from the viewpoints of improving spreadability and / or stability over time.

[0067] From the viewpoint of setting power and hair restyling ability, the preferred lower limit of the mass ratio (B) / (D) in the cosmetic of the present technology is preferably more than 0.1, more preferably 0.2 or more, even more preferably 0.3 or more, and more preferably 0.4 or more, and the preferred upper limit is preferably 1.3 or less, more preferably 1.2 or less, even more preferably 1.1 or less, more preferably 1.0 or less, and more preferably 0.9 or less, and the preferred numerical range is preferably 0.2 to 1.2, and more preferably 0.2 to 1.0. Specifying the numerical range as above is also desirable from the viewpoint of improving spreadability and / or stability over time.

[0068] The content mass ratio (A) / (B) in the cosmetic of the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the suitable lower limit is preferably 1.0 or more, more preferably 1.3 or more, even more preferably 1.5 or more, more preferably 2.0 or more, and more preferably 2.5 or more, and the suitable upper limit is preferably 15 or less, more preferably 10 or less, even more preferably 8.0 or less, more preferably 7.5 or less, and more preferably 5.0 or less, and the suitable numerical range from the viewpoint of setting power and hair restyling ability is preferably 1.0 to 15, more preferably 1.5 to 10, even more preferably 2.0 to 10, and more preferably 2.0 to 5.0. Specifying the numerical range as above is also desirable from the viewpoint of improving spreadability and / or stability over time.

[0069] The content mass ratio (B) / (C) in the cosmetic of the present invention is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the preferred lower limit is preferably 0.15 or more, more preferably 0.2 or more, even more preferably 0.3 or more, more preferably 0.4 or more, more preferably 0.5 or more, and more preferably 0.6 or more, and the preferred upper limit is preferably 3.0 or less, more preferably 2.5 or less, even more preferably 2.0 or less, more preferably 1.5 or less, and more preferably 1.3 or less, and the preferred numerical range from the viewpoint of setting power and hair restyling ability is preferably 0.2 to 3.0, more preferably 0.2 to 2.5, even more preferably 0.2 to 2.0, and more preferably 0.3 to 2.0. Specifying the numerical range as above is also desirable from the viewpoint of further improving spreadability and / or stability over time.

[0070] The content mass ratio [((A)+(B)) / ((C)+(D))] in the cosmetic of the present invention is not particularly limited, but from the viewpoint of setting power and hair restyling ability, a suitable lower limit is preferably 0.5 or more, more preferably 0.8 or more, even more preferably 0.9 or more, more preferably 1.0 or more, more preferably 1.1 or more, and more preferably 1.3 or more, and a suitable upper limit is preferably 5.0 or less, more preferably 4.0 or less, even more preferably 3.0 or less, more preferably 2.5 or less, more preferably 2.4 or less, more preferably 2.2 or less, and more preferably 2.0 or less, and the suitable numerical range from the viewpoint of setting power and hair restyling ability is preferably 0.8 to 3.0, more preferably 1.0 to 3.0, and more preferably 1.0 to 2.0. Specifying the numerical range as above is also desirable from the viewpoint of improving spreadability and / or stability over time.

[0071] 2-6. Other ingredients In addition to the above-mentioned components, the cosmetic of the present technology may contain or use water, oily components, surfactants (nonionic, anionic, cationic, amphoteric), moisturizers, gelling agents, cosmetic ingredients, herbal medicines, pH adjusters, chelating agents, preservatives, antioxidants, cooling agents, vitamins, proteins, antibacterial agents, UV absorbers, pigments, fragrances, powders, etc. In addition, when the cosmetic of the present invention is applied to emulsion cosmetics or hair cosmetics, etc., it may contain or use optional components that can be contained or used depending on the composition to be applied, the use or purpose, etc., within a range that does not impair the effects of the present invention.

[0072] This technology can use water and / or liquid oil, which may be used as a component of an oil-in-water or water-in-oil emulsion cosmetic.

[0073] The water used in the present technology is not particularly limited, but may be water used in cosmetics and the like. Examples of the water include tap water, purified water, ion-exchanged water, hot spring water, deep sea water, steam-distilled water derived from plants such as lavender water, rose water, and orange flower water, and one or more types selected from these may be used.

[0074] The oily component other than the above-mentioned components used in the present technology is not particularly limited, but oily components used in cosmetics and the like can be used, and for example, oils can be used regardless of their properties such as liquid, paste, solid, etc., volatile or non-volatile, and their origins such as animal oil, vegetable oil, synthetic oil, etc., and examples of oils include hydrocarbons, oils and fats, ester oils including ultraviolet absorbents, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, etc., and one or more types selected from these can be used.

[0075] Of the oily components, liquid oil can be used. The liquid oil is preferably an oil that is liquid at 25° C., and the oil can be an oil used in cosmetics and the like. The liquid oil is not particularly limited, but examples thereof include hydrocarbon oils, vegetable oils, ester oils (e.g., fatty acid esters), fatty acids, higher alcohols, silicone oils, etc., which may be either volatile or non-volatile. In the case of volatile hydrocarbon oils, hydrocarbons having a boiling point of 260°C or less at normal pressure are preferred, and examples thereof include hydrocarbons having side chains such as isooctane, isododecane, isohexadecane, isoeicosaene, etc., isoparaffin, or mixtures thereof, isobutene, n-butene, etc., polymerized or copolymerized (the degree of polymerization is preferably 4 to 6), and then hydrogenated. One or more types selected from these can be used.

[0076] The content of water in the cosmetic of the present technology is not particularly limited, but from the viewpoint of setting power and hair restyling ability, the preferred lower limit is preferably 40% or more, more preferably 45% or more, even more preferably 50% or more, more preferably 55% or more, and more preferably 60% or more, and the preferred upper limit is not particularly limited, but is preferably 95% or less, more preferably 90% or less, even more preferably 85% or less, and more preferably 80% or less. From the viewpoint of improving spreadability and stability over time, the more water, the more desirable, and 45% or more is preferable, based on the total amount of the cosmetic. The preferred numerical range, when applied to the case of an oil-in-water emulsion type, is preferably 40% or more, more preferably 40 to 90%, and more preferably 45 to 85%, based on the total amount of the cosmetic.

[0077] In the present technology, a surfactant may be used in addition to the above components, for example, an anionic surfactant (e.g., C12-C22 higher fatty acid metal salt, etc.) and / or a nonionic surfactant (e.g., C12-22 fatty acid monoester, etc.) may be used. The content of the surfactant is not particularly limited, and the preferred lower limit is preferably 0.01, 0.1, 0.5, or 1% or more, and the preferred upper limit is preferably 5, 4, or 3% or less, based on the total cosmetic. This can further improve the emulsion stability.

[0078] The cosmetic of the present technology can be produced into a composition for a desired application or a composition for a desired dosage form by selecting one or more means or methods selected from stirring, mixing, heating, dissolving, emulsifying, dispersing, etc., using a known method, other than the composition taking into consideration each component and each amount ratio described above, and the production method is not particularly limited. As a production method, in order to uniformly mix each component, it can also be produced preferably under heating conditions (for example, about 70 to 100 ° C.). This allows, for example, emulsion cosmetics such as oil-in-water type, hair cosmetics such as hair styling cosmetics, etc. to be produced, but the compositions that can be produced in the present invention are not limited to these. In addition, examples of production equipment used in the production of the present invention include dispersion / emulsion equipment such as general dispersions, but are not limited to these.

[0079] The pH of the cosmetic of the present technology is not particularly limited, but is preferably 3.0 to 8.0, more preferably 4.0 to 8.0, and even more preferably 5.0 to 8.0 at 25° C. These ranges are desirable from the viewpoint of achieving excellent setting power and hair restyling while also improving spreadability and / or stability over time. In the present technology, pH can be measured at 25° C. using a pH meter, and a glass electrode type hydrogen ion concentration meter (manufactured by Horiba, Ltd.) was used for the measurements in the Examples.

[0080] A more preferred specific example of the production method for the cosmetic preparation of the present technology includes, for example, heating and mixing components (C) and (D), adding components (A) and (B) that have been heated and mixed in advance thereto, uniformly mixing the mixture with a dispersion, and then cooling the mixture to obtain the cosmetic preparation; however, the production method of the present technology is not limited to this.

[0081] 3. Composition according to the present technology The composition according to the present technology is preferably applied to cosmetics, and the cosmetics may be in any form selected from, for example, hair cosmetics such as hair cosmetics, eyelash cosmetics, and eyebrow cosmetics; basic cosmetics such as emulsions, creams, lotions, beauty essences, packs, all-in-one gels, sunscreens, and cleansers; makeup cosmetics such as makeup bases, BB creams, foundations, blushers, and lipsticks; makeup protection cosmetics; skin care cosmetics such as eye creams, balms, massage cosmetics, hand creams, and body creams; topical skin preparations; dispersions, ointments, solutions, aerosols, patches, poultices, liniments, etc. The composition according to the present technology may also be applied to topical skin preparations such as medicines, quasi-drugs, skin care products, and skin protection agents, and may be either cosmetics or topical skin preparations.

[0082] In addition, the cosmetic of the present technology contains a film-forming agent and a solid oil, and has a setting power and hair restyling property, so it is considered that a flexible film is formed after application to the skin or hair. Therefore, the cosmetic of the present technology can also be used as a cosmetic for protecting objects such as hair, hair styling, skin, nails, or makeup, and this includes cosmetics called finishing cosmetics, overcoats, etc. Examples of makeup protection include maintaining the state after applying one or more types of makeup selected from foundation, face powder, face powder (white powder), concealer, eye color (eye shadow), eyeliner, eyebrow, mascara, blush, lipstick, etc. on the skin of the face or after makeup (preventing makeup from coming off, etc.).

[0083] The cosmetic of the present technology may be in any formulation, such as aqueous, solubilized, oil-in-water (O / W) emulsion, water-in-oil (W / O) emulsion, oil-based, etc., and may be in any form, such as liquid, emulsion, cream, gel, solid, etc., and may be applied by spraying or coating on the skin, hair, or makeup. In the case of hair cosmetics (preferably hair cosmetics), they can be formulated as a foam type using an aerosol foam or pump foam container by blending a propellant, and can be used as hair milk, hair cream, hair gel, hair wax, hair mousse, hair spray, pomade, hair lotion, hair color, shampoo, conditioner, hair pack, hair oil, hair cologne, hair essence, hair straightener, perm agent, etc.

[0084] The hair cosmetic composition can be applied to the hair, eyebrows, eyelashes, scalp, eyelashes, the roots of eyebrows, etc., for example, by coating on the hair. The hair cosmetic composition is preferably applied as a hair cosmetic, eyebrow cosmetic, or eyelash cosmetic. Examples of hair cosmetics include hair styling products, shampoos, hair rinses, rinse-in-shampoos, hair treatments, hair conditioners, hair growth products, etc.; examples of eyelash cosmetics include mascara, mascara overcoats, mascara bases, etc.; and examples of eyebrow cosmetics include eyebrow products, eyebrow beauty serums, etc., but are not limited to these product forms.

[0085] 4. This technology can also adopt the following configuration.

[0086] 〔1〕 The following components (A) to (D); (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent A cosmetic preparation or composition containing (D) polyethylene glycol. In the cosmetic preparation or composition, the (A) is preferably less than 20% by mass with respect to the total amount of the cosmetic preparation or composition, and / or the component (D) is preferably less than 10% by mass with respect to the total amount of the cosmetic preparation or composition, and / or the mass ratio (A) / (D) of the component (A) to the component (D) is preferably 1 to 10, and / or the mass ratio (B) / (D) of the component (B) to the component (D) is preferably 0.2 to 1.2. The cosmetic or composition is preferably an emulsion cosmetic or hair cosmetic, and more preferably an oil-in-water emulsion cosmetic or an oil-in-water emulsion hair cosmetic.

[0087] 〔2〕 The following components (A) to (D); (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: Less than 10% by mass Contains The emulsion cosmetic or composition, in which the content mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10. The emulsion cosmetic or composition is preferably an oil-in-water type or a water-in-oil type. 〔3〕 The following components (A) to (D); (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: Less than 10% by mass wherein the content mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10. The hair cosmetic or composition is preferably a hair cosmetic, and more preferably a hair styling product. [4] The cosmetic or composition according to the above item [2] or [3], wherein the mass ratio (B) / (D) of the component (B) to the component (D) is 0.2 to 1.2. [5] The cosmetic or composition according to any one of [1] to [4] above, wherein the cosmetic or composition is an oil-in-water emulsion type cosmetic. [6] The cosmetic or composition according to any one of [1] to [5] above, wherein the component (A) solid oil is a polar wax. The polar wax preferably has a melting point of 60 to 90°C, and is preferably one or more types selected from beeswax, candelilla wax, and carnauba wax. [7] The component (B) hydrogenated polyisobutene has a kinetic viscosity at 98.9°C of 50 to 10,000 mm 2 The cosmetic or composition according to any one of [1] to [6] above, wherein [8] The cosmetic preparation or composition according to any one of [1] to [7] above, wherein the component (D) polyethylene glycol is a polyethylene glycol having a number average molecular weight of 10,000 or more. The number average molecular weight of the component (D) is preferably 100,000 or less. The polyethylene glycol is preferably one or more types selected from PEG-240, PEG-300, PEG-400, and PEG-600. [9] The cosmetic preparation or composition according to any one of [1] to [8] above, wherein the component (C) film-forming agent is a nonionic film-forming resin and / or a cationic film-forming resin. The resin is preferably a vinylpyrrolidone-based polymer (homopolymer or copolymer).

[10] The cosmetic or composition according to any one of [1] to [9] above, wherein the mass ratio (A) / (B) of the component (A) to the component (B) is 1 to 15.

[11] The cosmetic or composition according to any one of [1] to

[10] above, wherein the mass ratio (B) / (C) of the component (B) to the component (C) is 0.2 to 3.

[12] The cosmetic or composition according to any one of [1] to

[11] above, wherein the (A) is less than 20 mass % of the total amount of the cosmetic.

[13] The cosmetic or composition according to any one of [1] to

[12] above, wherein the content of the component (B) is less than 7 mass% based on the total amount of the cosmetic.

[14] The cosmetic or composition according to any one of [1] to

[13] above, wherein the content of the component (C) is less than 10 mass% based on the total amount of the cosmetic.

[15] The cosmetic or composition according to any one of [1] to

[14] above, which has improved holdability and ease of restyling. EXAMPLES

[0088] Hereinafter, the present technology will be described in more detail based on examples, etc. Note that the examples, etc. described below are examples of representative examples, etc. of the present technology, and the scope of the present technology is not to be interpreted narrowly by these.

[0089] Emulsion cosmetics having each composition shown in Table 1 were prepared by a conventional method, and the prepared compositions were used as hair styling products and subjected to various evaluation tests, the results of which are also shown in Table 1. Each composition in Table 1 (total amount of cosmetic) is 100% by mass.

[0090] [Manufacturing method] A: Heat ingredients 9 to 11 and ingredients 14 to 16 to 70 to 80°C and mix uniformly. B: Heat ingredients 1-5, 12, and 13 to 90-100°C and mix uniformly. C: Add B to A and mix until uniformly emulsified. D: C was cooled to room temperature, ingredients 6 to 8 were added, and mixed uniformly to obtain a hair styling product (oil-in-water type).

[0091] (Evaluation method 1: Spreadability, setting power, ease of restyling) For spreadability, setting power and ease of restyling, each sample was evaluated and scored by a panel of 10 experts in cosmetic evaluation, who assessed it according to the following criteria. The average score for each sample was then calculated from the total scores of all panelists, and the results were judged according to the four-level judging criteria below. Regarding spreadability, each sample was applied to hair and evaluated for its ability to spread on the hair. Regarding setting power, each sample was applied to hair, and the setting power after adjusting into the desired shape or style was evaluated. Regarding re-styling properties, each sample was applied to hair, adjusted into a desired shape or style, and then the ease of styling when the hair was adjusted again into the desired shape or style was evaluated. <Absolute evaluation criteria> [Score]: [Evaluation result] 4 points: very good 3 points: Good 2 points: slightly poor 1 point: Defective <4-level evaluation criteria> [Judgment]: [Average score] ◎(Excellent): 3.5 points or more ○ (Good): 2.8 points or more and less than 3.5 points △ (slightly poor): 2.0 points or more and less than 2.8 points × (poor): Less than 2.0 points

[0092] (Evaluation method 2: (Stability over time (50℃ / 1M)) 30 g of each sample was placed in a No. 6 standard glass bottle (Kawaguchi Pharmaceutical Co., Ltd.) and stored in a thermostatic chamber at 50°C for one month (1M), after which the condition was observed. Based on the results, the stability over time was evaluated according to the following three-level evaluation criteria. <Three-level reputation criteria> [Evaluation]: [Judgment] ◎(Excellent): Almost no change in appearance ○ (Good): No separation is observed, but one of the following is observed: deterioration of texture or the occurrence of bumps. × (Fail): Separation is observed, the texture is very poor, and lumps are visible.

[0093] [Table 1]

[0094] (Note 1) WITHE BEES WAX (Miki Chemical Co., Ltd.) (polarity, melting point 60-67°C) (Note 2) Refined Candelilla Wax SR-3 (Nippon Natural Products Co., Ltd.) (polarity, melting point 70-75°C) (Note 3) Carnauba wax (manufactured by Machado Chemical Co.) (polarity, melting point 83°C) (Note 4 PERFORMA SW-87 (Nippon Surfactant Industries Co., Ltd.) (non-polar, melting point 83-92°C) (Note 5) Pearleem 18 (NOF Corp.) (Kinematic viscosity at 98.9°C: 300mm 2 / s) (Note 6) Acorn M (50% pure, manufactured by Osaka Organic Chemical Industry Co., Ltd.) (nonionic film-forming resin) (Note 7 PVP K-90 (ISP Co., Ltd.) (nonionic film-forming resin) (Note 8) HC Polymer 2L (20% purity, manufactured by Osaka Organic Chemical Industry Co., Ltd.) (cationic film-forming resin) (Note 9 Polyethylene glycol 20000 (NOF Corp.) (number average molecular weight: 20,000) (Note 10) PEG11000 (NOF Corp.) (number average molecular weight: 11,000) (Note 11 FOAMYSENSE N10 POLYMER (Dow Toray) (number average molecular weight: 100,000)

[0095] As shown in Table 1, the compositions of Comparative Examples 1 to 3 could not satisfy both the setting power and the hair restyling property. On the other hand, the compositions of Examples 1 to 16 were rated at least "○ (good evaluation)" for both the setting power and the hair restyling property, and were excellent in both the setting power and the hair restyling property. Furthermore, the compositions of Examples 1 to 16 had good spreading and excellent spreadability. Furthermore, the compositions of Examples 1 to 16 were applied to compositions in an emulsified state, and could be used as emulsion cosmetics, and as described later, had excellent emulsion stability over time. Furthermore, the compositions of Examples 1 to 16 could be applied to hair, and therefore could be preferably used as hair cosmetics, and more preferably as hair styling products. The present inventors believe that the compositions of Examples 1 to 16 have both excellent setting power and hair restyling property, and therefore form a soft film after application, and therefore it is possible to provide cosmetics with a wide range of uses and formulations that take advantage of the properties of this soft film. The compositions of Examples 1 to 16 had a pH of 5.0 to 8.0.

[0096] On the other hand, in Comparative Example 1, where the content mass ratio (B) / (D) of component (B) to component (D) in Table 1 exceeds 1.2, spreadability, setting power, and stability over time may be poor. Also, in Comparative Example 2, where the content mass ratio (B) / (D) is less than 0.2, setting power may be poor. Furthermore, in Comparative Example 3, where the content mass ratio (A) / (D) of component (A) to component (D) is less than 1, spreadability, restyling ability, and stability over time may be poor.

[0097] From Table 1, it is considered preferable to use a combination of components (A) solid oil, (B) hydrogenated polyisobutene, (C) film-forming agent, and (D) polyethylene glycol as the composition. In addition, considering Examples 1 to 16 and Comparative Example 3, it is considered preferable that the content of component (D) is less than 10 mass%. It is considered that component (A) is preferably a polar wax rather than a nonpolar wax, and component (C) is preferably a nonionic or cationic film-forming resin, and further, it is considered that vinylpyrrolidone polymer is preferable.

[0098] Considering Examples 1 to 16, it is considered that the content mass ratio of (A) / (D) is preferably 1 to 10, and more preferably 1 to 5. Also, considering Examples 1 to 16, it is considered that the content mass ratio of (A) / (B) is preferably 1 to 15, and more preferably 1 to 10. Also, considering Examples 1 to 16 and Comparative Examples 1 and 2, it is considered that the content mass ratio of (B) / (D) is more preferably 0.2 to 1.2. Also, considering Examples 1 to 16, it is considered that the content mass ratio of (B) / (C) is more preferably 0.2 to 3.0. Also, considering Examples 1 to 16, it is considered that the content ratio of [(A+B) / (C+D)] is more preferably 0.8 to 3.0.

[0099] Furthermore, in each of the compositions of Examples 1 to 16, the spreadability (ease of spreading) was at least "○ (good evaluation)" or higher, and thus, each of the compositions of Examples 1 to 16 was excellent in setting power, ease of restyling, and spreadability. The present inventors believe that, since the spreadability is also excellent in Examples 1 to 16, it is preferable to apply them to cosmetics that are applied to a subject by spreading (for example, gel, wax, solid, mousse, etc.).

[0100] Furthermore, each of the compositions of Examples 1 to 16 had excellent stability over time (50°C / 1M), and in the "evaluation of stability over time", Examples 1 and 3 to 16 were rated "Excellent" (A), and Example 2 was rated "Good" (O). Thus, each of the compositions of Examples 1 to 16 was excellent in setting power, hair restyling ability, spreadability, and stability over time. The present inventors believe that each of the compositions of Examples 1 to 16 is also suitable as an oil-in-water emulsion cosmetic.

[0101] Example 17: Hair cream (component) (mass%) (1) Cetearyl alcohol 1.5 (2) Isopropyl myristate 1 (3) Hydrogenated polyisobutene Component (B) (Note 5 1 (4) Beeswax Component (A) (Note 1 7 (5) Glyceryl stearate 0.5 (6) Stearyltrimonium chloride 0.5 (7) PEG-400 component (D) (Note 9 5 (8) (VP / VA) copolymer component (C) (Note 6 2 (9) Remaining purified water

[0102] (Manufacturing method) A: Heat ingredients (1) to (6) at 90°C and mix and dissolve uniformly. B: Components (7) to (9) were heated to 80°C and mixed uniformly, and A was added to B, emulsified, and cooled to obtain a hair cream (pH 4.5). This hair cream was an oil-in-water emulsion type.

[0103] Example 17 had both excellent setting power and restyling ability, and also had excellent spreadability and emulsion stability over time.

[0104] Example 18: Hair wax (Component) (mass%) (1) Behenyl alcohol 5 (2) Cetearyl alcohol 1 (3) Triethylhexanoin 5 (4) Hydrogenated polyisobutene Component (B) (Note 12 1 (5) Beeswax Component (A) (Note 1 7 (6) Stearic acid 2 (7) Hydrogenated rapeseed oil fatty acid glycerides 1 (8) PEG-400 component (D) (Note 9 5 (9) (VP / VA) copolymer component (C) (Note 6 2 (10) Sodium hydroxide 0.1 (11) Remaining purified water (Note 12 Pearleem 24 (manufactured by NOF Corp.)

[0105] (Manufacturing method) A: Heat ingredients (1) to (7) at 100°C and mix and dissolve uniformly. B: Components (8) to (11) were heated to 80°C and mixed uniformly, and A was added to B and emulsified, followed by cooling to obtain a hair wax (pH 7.5). This hair wax was an oil-in-water emulsion type.

[0106] Example 18 had both excellent setting power and restyling ability, and also had excellent spreadability and emulsion stability over time.

[0107] Example 19: Emulsion (Component) (mass%) (1) Cetearyl alcohol 0.5 (2) Hydrogenated lecithin 1 (3) Triethylhexanoin 3 (4) Hydrogenated polyisobutene Component (B) (Note 5 1 (5) Beeswax Component (A) (Note 1 7 (6) PEG-400 component (D) (Note 9 5 (7) (VP / VA) copolymer component (C) (Note 6 2 (8) (Sodium acrylate / sodium acryloyldimethyltaurate) copolymer 0.01 (9) (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.01 (10) Sodium hydroxide 0.005 (11) Remaining purified water

[0108] (Manufacturing method) A: Heat ingredients (1) to (5) at 100°C and mix and dissolve uniformly. B: Components (6) to (11) were heated to 80°C and mixed uniformly, and A was added to B, emulsified, and cooled to obtain a milky lotion (pH 6.0). This milky lotion was an oil-in-water emulsion type.

[0109] Example 19 formed a soft film on the skin, providing an excellent feeling of firmness, and also had excellent spreadability and emulsion stability over time.

Claims

1. The following components (A) to (D): (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: less than 10% by mass Contains a mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10; the mass ratio (B) / (D) of the component (B) to the component (D) is 0.2 to 1.2; Emulsified cosmetics.

2. The following components (A) to (D): (A) Solid oil (B) Hydrogenated polyisobutene (C) Film-forming agent (D) Polyethylene glycol: less than 10% by mass Contains a mass ratio (A) / (D) of the component (A) to the component (D) is 1 to 10; the mass ratio (B) / (D) of the component (B) to the component (D) is 0.2 to 1.2; Hair cosmetics.

3. The cosmetic according to claim 1 or 2, wherein the cosmetic is an oil-in-water emulsion type cosmetic.

4. The cosmetic preparation according to claim 1 or 2, wherein the solid oil (A) is a polar wax.

5. The component (B) hydrogenated polyisobutene has a kinetic viscosity at 98.9°C of 50 to 10,000 mm ２ The cosmetic preparation according to claim 1 or 2, wherein the formula is a 1-hydroxyethyl ether.

6. 3. The cosmetic preparation according to claim 1, wherein the component (D) polyethylene glycol is a polyethylene glycol having a number average molecular weight of 10,000 or more.

7. 3. The cosmetic preparation according to claim 1, wherein the component (C) film-forming agent is a nonionic film-forming resin and / or a cationic film-forming resin.

8. 3. The cosmetic preparation according to claim 1, wherein a content mass ratio (A) / (B) of the component (A) to the component (B) is 1 to 15.

9. 3. The cosmetic preparation according to claim 1, wherein a content mass ratio (B) / (C) of the component (B) to the component (C) is 0.2 to 3.

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