Processing container for lithium ion secondary battery
The processing container with bottom holes and support features effectively separates molten metals from non-molten materials in lithium-ion batteries, ensuring stable handling and efficient recovery without ignition risks.
Patent Information
- Application Number
- JP2023214486
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2023-12-20
- Publication Date
- 2025-07-02
AI Technical Summary
Existing methods for incinerating lithium-ion secondary batteries face challenges in efficiently separating molten metals like aluminum from non-molten materials, and there is a risk of unstable battery posture leading to short circuits and ignition during handling and incineration.
A processing container with bottom holes for molten metal separation, cylindrical support portions, and an inclined design to stabilize battery posture, along with features like slits and alumina coating to enhance stability and efficiency.
Stable separation of molten metals and non-molten materials is achieved, preventing short circuits and ignition, while maintaining container strength and facilitating efficient recovery.
Smart Images

Figure 2025098386000001_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to a processing container for a lithium-ion secondary battery.
Background Art
[0002] A method of incinerating a used lithium-ion secondary battery and separating and recovering valuable materials is known. For example, Patent Document 1 discloses a recovery container for molten metal used in an incinerator for incinerating a lithium-ion secondary battery containing a metal that melts at 700°C to 1000°C at a temperature higher than the melting point of the metal. The recovery container has a shape for receiving the lithium-ion secondary battery and the molten metal flowing out from the lithium-ion secondary battery, and the inner surface of the recovery container is a sticking suppression surface for suppressing the sticking of the molten metal. A support member for supporting the lithium-ion secondary battery is provided at a position higher than the inner surface of the bottom of the recovery container so that a support portion for supporting the lithium-ion secondary battery and a storage portion for storing the molten metal are formed.
[0003] Also, for example, Patent Document 2 discloses a method for recovering valuable materials from a lithium-ion battery, including a melting separation step of heating a waste lithium-ion battery using at least an aluminum material as a constituent material of a battery case at a temperature of 660°C or higher to melt the aluminum material, and separating the molten aluminum material from the non-molten material constituting the battery main body; and a pulverization step of pulverizing the non-molten material obtained in the melting separation step to obtain a pulverized product. In the melting separation step, the waste lithium-ion battery placed on a net-like body is heated at a temperature of 660°C or higher to melt the aluminum material and let it fall through the mesh of the net-like body, and the non-molten material constituting the battery main body is left on the net-like body, thereby separating the molten aluminum material from the non-molten material.
Prior Art Documents
Patent Documents
[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2021-138996 [Patent Document 2] Japanese Patent No. 6268130 [Summary of the Invention] [Problems to be Solved by the Invention]
[0005] One embodiment of the present invention aims to stably and efficiently separate molten metal such as aluminum and non-molten materials from a lithium-ion secondary battery. [Means for Solving the Problems]
[0006] The first aspect of the present invention is a processing container for a lithium-ion secondary battery that houses a lithium-ion secondary battery containing a metal that melts at 650°C or higher and 1000°C or lower, and is used when performing incineration treatment at a temperature higher than the melting point of the metal, having a plurality of holes at the bottom for separating the molten metal flowing out from the lithium-ion secondary battery during the incineration treatment to the outside of the container, and a plurality of cylindrical support portions are provided on the outer side of the bottom surface, which is a processing container for a lithium-ion secondary battery.
[0007] The second aspect of the present invention is the processing container for a lithium-ion secondary battery according to the first aspect, having an inclined portion in which at least one surface of the side surface is inclined toward the outside of the container.
[0008] The third aspect of the present invention is the processing container for a lithium-ion secondary battery according to the first aspect, wherein the plurality of holes are in a slit shape.
[0009] The fourth aspect of the present invention is the processing container for a lithium-ion secondary battery according to the third aspect, wherein the intersection of the longitudinal direction of the hole and the longitudinal direction of the support portion exists on the bottom surface.
[0010] The fifth aspect of the present invention is the processing container for a lithium-ion secondary battery according to the first aspect, wherein the total area of the plurality of holes is 10% or more and 40% or less of the bottom area of the processing container.
[0011] The sixth aspect of the present invention is a concave portion is provided on the upper side of the side surface, and when a plurality of the processing containers are stacked, the support portion of the upper processing container and the concave portion of the lower processing container are fitted together. This is the processing container for a lithium-ion secondary battery according to the first aspect.
[0012] The seventh aspect of the present invention is the processing container for a lithium-ion secondary battery according to the first aspect, wherein the depth is 50 mm or more and 400 mm or less.
[0013] The eighth aspect of the present invention is the processing container for a lithium-ion secondary battery according to the first aspect, wherein alumina is coated on the inner wall.
Advantages of the Invention
[0014] According to an embodiment of the present invention, molten metal such as aluminum and non-molten materials can be stably and efficiently separated from a lithium-ion secondary battery.
Brief Description of the Drawings
[0015]
Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Mode for Carrying Out the Invention
[0016] <Findings Obtained by the Inventor> First, the findings obtained by the inventor will be described.
[0017] For example, when a lithium ion secondary battery is arranged in a container as described in Patent Document 1 and incineration treatment is performed, there is a problem that a large amount of other battery materials are mixed into molten metal such as aluminum, making its separation difficult.
[0018] Also, for example, when a certain amount or more of lithium ion secondary batteries are arranged on a net-like body as described in Patent Document 2 and handled such as transportation, using the net-like body, the posture of the lithium ion secondary battery tends to become unstable during handling such as transportation, and the terminals may come into contact with a conductive object (such as a container), causing a short circuit and posing a risk of sudden heat generation and ignition. Also, the efficiency of recovering the non-molten materials remaining on the net-like body is not considered.
[0019] The inventor has conducted intensive studies on the above problems. As a result, a plurality of holes are provided at the bottom for separating the molten metal flowing out from the lithium-ion secondary battery during the incineration process to the outside of the container, and a plurality of cylindrical support portions are provided on the outside of the bottom surface, so that only the molten metal such as aluminum easily flows out of the container, and other battery materials (especially black mass) are likely to remain inside the container. In other words, with the above container, holes are provided at the bottom so that materials that would pass through a net can be retained inside the container. Also, during storage and transportation before incineration and when loading into the heating furnace, sudden heat generation and ignition due to terminal contact can be prevented. Furthermore, it becomes possible to efficiently recover the unmolten battery materials remaining on the bottom.
[0020] [Details of Embodiments of the Present Invention] Next, an embodiment of the present invention will be described below with reference to the drawings. It should be noted that the present invention is not limited to these examples, but is defined by the claims, and is intended to include all modifications within the meaning and scope equivalent to the claims.
[0021] In this specification, "A to B" means a numerical range of "A or more and B or less".
[0022] <The First Embodiment of the Present Invention> (1) Treatment Container for Lithium-Ion Secondary Battery First, the treatment container 10 for a lithium-ion secondary battery (hereinafter, also simply referred to as the container 10) used in this embodiment will be described. As shown in FIGS. 1(a), (b), 2, and 4, the container 10 houses a lithium-ion secondary battery 20 containing a metal that melts at 650°C or higher and 1000°C or lower, such as aluminum (hereinafter, also referred to as molten metal), and is used when performing an incineration treatment at a temperature higher than the melting point of the molten metal. Considering the heating temperature of the incineration treatment, the material of the container 10 is preferably, for example, SUS304. FIGS. 1(a) and (b) are schematic views showing an example of the container 10 used in this embodiment, FIG. 1(a) is a plan view seen from above, and FIG. 1(b) is a side view.
[0023] As shown in Fig. 1(a), the container 10 has a plurality of holes 11 at the bottom. The plurality of holes 11 are holes for separating the molten metal flowing out from the lithium-ion secondary battery 20 during the incineration process to the outside of the container 10. Thereby, the separation between the molten metal such as aluminum and other battery materials can be stably performed.
[0024] The shape and number of the holes 11 are not limited as long as they can sufficiently collect the molten metal such as aluminum and maintain the required bottom strength. However, the size of the holes is preferably such that a sphere with a diameter of 10 mm can pass through. It can be provided in a shape that is easy to process, such as circular, elliptical, or polygonal. For example, it can be in the shape of an elliptical slit. In this case, the length is preferably 50 to 200 mm, and the width is preferably 10 to 30 mm. As shown in Fig. 1(a), it is preferable that the plurality of holes 11 extend in the long side direction of the container 10 and are arranged at a predetermined interval. By providing such a plurality of holes 11 at the bottom, the separation between the molten metal and the battery material can be enabled while maintaining the strength of the container 10. The material, thickness, shape, and number of the holes at the bottom are preferably such that the posture of the lithium-ion secondary battery does not become unstable before the lithium-ion secondary battery is deactivated by the incineration process, and the bottom strength can be maintained.
[0025] The depth d of the container 10 is preferably, for example, 50 mm or more and 400 mm or less. When assuming that the height of the lithium-ion secondary battery 20 (for example, plate-shaped) to be processed is 210 mm, the above numerical range is set to a depth at which the lithium-ion secondary battery 20 can be stacked in one layer and cannot be stacked in two layers (if stacked in two layers, the lithium-ion secondary battery 20 will protrude from the container 10). Thereby, the contact between the terminals 21 of the lithium-ion secondary battery 20 can be suppressed. Note that the depth d of the container 10, as shown in Fig. 1(b), when a recess 14 is provided on the side surface, indicates the depth of the portion where the recess 14 is provided (in other words, the minimum value of the depth of the container 10).
[0026] As shown in FIG. 1(b), the container 10 preferably has an inclined portion 12 where at least one side surface inclines outwardly of the container. Thereby, when recovering the battery material from which the molten metal has been separated from within the container 10, by tilting the container 10, the battery material can be discharged from the inclined portion 12 outside the container 10, and the battery material can be recovered simply.
[0027] The inclination angle θ (see FIG. 1(b)) of the inclined portion 12 is preferably, for example, 30 degrees or more and 45 degrees or less. If the inclination angle θ is less than 30 degrees, it may be difficult to discharge the battery material. On the other hand, by setting the inclination angle θ to 30 degrees or more, it becomes easier to discharge the battery material. On the other hand, if the inclination angle θ exceeds 45 degrees, the number of lithium-ion secondary batteries 20 that can be arranged within the container 10 decreases with respect to the total length of the container 10, and the processing efficiency may decrease (because if a lithium-ion secondary battery 20 is arranged on the inclined surface, the posture is not stable and it is unsuitable). On the other hand, by setting the inclination angle θ to 45 degrees or less, the processing efficiency of the lithium-ion secondary battery 20 can be maintained.
[0028] The total area of the plurality of holes 11 is preferably 50% or less of the bottom area of the container 10, and more preferably 10% or more and 40% or less. If the total area of the plurality of holes 11 is less than 10% of the bottom area, it may be difficult to separate the molten metal outside the container 10. On the other hand, by setting the total area of the plurality of holes 11 to 10% or more of the bottom area, it becomes easier to separate the molten metal outside the container 10. On the other hand, if the total area of the plurality of holes 11 exceeds 40% of the bottom area, the strength of the container 10 may decrease. Also, during storage and transportation and when loading into the heating furnace, the posture of the lithium-ion secondary battery 20 becomes unstable, the terminals 21 of the lithium-ion secondary battery 20 may come into contact, and there is a risk of causing a fire due to a short circuit. On the other hand, by setting the total area of the plurality of holes 11 to 40% or less of the bottom area, the posture of the lithium-ion secondary battery 20 can be stabilized, contact of the terminals 21 during storage and transportation and when loading into the heating furnace can be suppressed, and the strength of the container 10 during the incineration process can be maintained. Note that the bottom area of the container 10 indicates the area of the flat portion excluding the inclined surfaces such as the inclined portion 12.
[0029] As shown in FIG. 1(b), a plurality (two in this embodiment) of cylindrical support portions 13 are provided on the outer side of the bottom surface of the container 10. The support portion 13 serves as, for example, a fork pocket when transporting the container 10 with a forklift or the like. Thereby, the container 10 can be easily transported. Further, as shown in FIG. 1(a), it is preferable that the plurality of holes 11 are arranged avoiding the portions where the support portions 13 are provided.
[0030] As shown in FIG. 1(a), in a plan view seen from above, when the plurality of holes 11 are in a slit shape, it is preferable that the longitudinal direction thereof intersects (or is orthogonal to) the longitudinal direction of the support portion 13. In other words, it is preferable that the intersection of the longitudinal direction of the plurality of holes 11 and the longitudinal direction of the support portion 13 exists on the bottom surface. Thereby, the strength of the container 10 can be improved. Further, since deformation of the container 10 during the incineration process is suppressed, the container 10 can be easily reused.
[0031] As shown in FIG. 1(a), in a plan view seen from above, it is preferable that the direction in which the inclined portion 12 is inclined and the longitudinal direction of the support portion 13 are orthogonal (or intersect). In other words, it is preferable that the intersection of the direction in which the inclined portion 12 is inclined and the longitudinal direction of the support portion 13 exists on the bottom surface. Thereby, even when the container 10 is tilted in the direction in which the inclined portion 12 is inclined with a forklift or the like, it is possible to prevent the fork from coming off.
[0032] As shown in FIG. 1(a), in a plan view seen from above, it is preferable that the longitudinal direction of the plurality of holes 11 and the direction in which the inclined portion 12 is inclined are substantially parallel (or coincide). In this specification, substantially parallel includes not only being completely parallel but also including cases where there is a deviation of 10° or less from parallel.
[0033] As shown in FIG. 1(b), it is preferable to provide a detachable lid 15 on the upper surface of the container 10. Thereby, oxidation of non-molten metals such as black mass remaining in the container can be suppressed.
[0034] Figure 2 is a schematic diagram showing a state in which a plurality of containers 10 are stacked and fixed. As shown in Figure 2, a plurality of recesses 14 can be provided on the upper side of the side surface of the container 10. When a plurality of containers 10 are stacked, it is preferable that the support portion 13 of the upper container 10a and the recess 14 of the lower container 10b are fitted together. Thereby, it becomes possible to incinerate a large number of lithium ion secondary batteries 20 together without stacking the lithium ion secondary batteries 20 in one container 10. Further, as shown in Figure 2, since the bottom of the upper container 10a serves as a lid for the lower container 10b, the oxidative combustion during incineration can be appropriately controlled without providing a lid 15 on the lower container 10b. Note that, as shown in Figure 2, it is preferable to provide a lid 15 on the upper surface of the uppermost container (container 10a in Figure 2). Further, when stacking the containers 10, a guide (not shown) may be provided on the side surface or the like so that positioning is easy.
[0035] As shown in Figure 1(b) and Figure 2, it is preferable that the lid 15 is also provided with a support portion 13. Further, as shown in Figure 2, the lid 15 can also be used as a tray for molten metal such as aluminum by being installed below the lower container 10b, for example.
[0036] It is preferable that, for example, alumina is coated on the inner wall (inside the side surface and inside the bottom surface) of the container 10. Thereby, it is possible to suppress the molten metal from staying in the container 10 for a long time and suppress the deterioration and deformation of the container 10.
[0037] (2) Method for treating lithium ion secondary battery Next, a method for treating a lithium-ion secondary battery according to the present embodiment will be described. The lithium-ion secondary battery 20 contains a metal (molten metal) that melts at 650°C or higher and 1000°C or lower, such as aluminum. The method for treating a lithium-ion secondary battery according to the present embodiment is a treatment method in which incineration is performed at a temperature higher than the melting point of the molten metal such as aluminum. FIG. 3 is a flowchart showing an example of the method for treating a lithium-ion secondary battery according to the present embodiment. The incineration treatment is preferably at 700°C or higher and 1000°C or lower, more preferably at 750°C or higher and 900°C or lower. As shown in FIG. 3, the method for treating a lithium-ion secondary battery according to the present embodiment includes, for example, an arrangement step S101, an incineration step S102, and a recovery step S103.
[0038] (Arrangement step S101) The arrangement step S101 is a step of arranging a plurality of lithium-ion secondary batteries 20 in a container 10 having a plurality of holes 11 at the bottom, for example. FIG. 4 is a schematic diagram showing an example of a case where a plurality of lithium-ion secondary batteries 20 (for example, plate-shaped) are arranged in the container 10.
[0039] In the arrangement step S101, the plurality of lithium-ion secondary batteries 20 are arranged so that the terminals 21 of the lithium-ion secondary batteries 20 do not contact each other. When the shape of the lithium-ion secondary battery 20 is a shape that is likely to fall when arranged, it is preferable to make an arrangement that is difficult to fall, for example, by narrowing the interval between the lithium-ion secondary batteries. Thereby, the posture of the lithium-ion secondary battery 20 can be stabilized, and contact of the terminals 21 during storage and transportation can be suppressed.
[0040] In the arrangement step S101, for example, as shown in FIG. 4, it is preferable to arrange the terminals 21 of the lithium-ion secondary batteries 20 facing upward. Thereby, since it becomes difficult for the terminal 21 to contact the container 10, the lithium-ion secondary battery 20 can be safely handled.
[0041] In the arrangement step S101, for example, it is preferable to arrange a plurality of lithium-ion secondary batteries 20 horizontally without stacking the lithium-ion secondary batteries 20 in the depth direction of the container 10. That is, as shown in FIG. 4, it is preferable to arrange a plurality of lithium-ion secondary batteries 20 with the directions in which the terminals 21 of the lithium-ion secondary batteries 20 face being aligned upward. Thereby, it is possible to suppress the terminals 21 of the lithium-ion secondary batteries 20 from coming into contact with each other and causing a rapid combustion.
[0042] In the arrangement step S101, for example, when the height of the lithium-ion secondary battery 20 to be processed is h, it is preferable to prepare a container 10 having a depth greater than h and less than 2h and arrange the lithium-ion secondary battery 20 therein. Thereby, since a container 10 that enables stacking of the lithium-ion secondary batteries 20 in one layer and does not enable stacking in two layers is used, it is possible to suppress the terminals 21 of the lithium-ion secondary batteries 20 from coming into contact with each other and causing a rapid combustion.
[0043] In the arrangement step S101, for example, as shown in FIG. 2, it is preferable to stack and fix a plurality (two layers in FIG. 2) of containers 10 in which the lithium-ion secondary batteries 20 are arranged and subject them to incineration treatment. Thereby, it becomes possible to collectively incinerate a large number of lithium-ion secondary batteries 20 without stacking the lithium-ion secondary batteries 20 in one container 10. Further, as shown in FIG. 2, since the bottom and the lid 15 of the upper container 10a serve as the lid of the lower container 10b, it is possible to appropriately control the oxidative combustion during the incineration treatment without providing the lid 15 to the lower container 10b. Note that, as shown in FIG. 2, it is preferable to provide the lid 15 on the upper surface of the uppermost container (container 10a in FIG. 2).
[0044] In the arrangement step S101, for example, as shown in FIG. 4, after the lithium-ion secondary battery 20 is arranged in the container 10, it is preferable to provide a lid 15 on the upper surface of the container 10. Thereby, the oxidation of the lithium-ion secondary battery 20 during the incineration process can be appropriately suppressed. Further, it is preferable that a support portion 13 having the same shape as the support portion 13 provided in the container 10 be provided below the lid 15. In this case, the support portion 13 can be used when moving the lid 15 alone. Further, in a state where the upper portion of the container 10 is closed by the lid 15, since the support portion 13 of the lid 15 is fitted into the recess 14 of the container 10, not only the oxidation suppression of the battery but also the deformation of the lid 15 and the container 10 due to heat during incineration can be suppressed. Furthermore, by providing side walls around the lid 15 to form a tray shape, the container 10 can also be loaded on the lid 15. In this case, the molten metal can be stored and recovered on the upper surface of the lid 15. Further, in order to improve the convenience during metal recovery, unevenness for forming an ingot may be provided on the upper surface of the lid 15.
[0045] (Incineration step S102) The incineration step S102 is, for example, a step of incinerating the lithium-ion secondary battery 20 and separating the molten metal flowing out from the lithium-ion secondary battery 20 to the outside of the container 10 through the hole 11. For the incineration treatment, a known heating furnace or the like can be used. The separated molten metal may be, for example, collected after arranging another collection container below the container 10 after the incineration treatment. In the arrangement step S101, when a plurality of containers 10 are stacked and fixed, in the incineration step S102, it is preferable to incinerate the plurality of containers 10 together while they are stacked. Even in this case, since the molten metal flows out from the upper container 10a to the lower container 10b and is finally separated outside the container 10, the processing efficiency of the lithium-ion secondary battery 20 can be improved.
[0046] In the incineration step S102, for example, it is preferable to incinerate the lithium-ion secondary battery 20 in a reducing atmosphere. Thereby, the oxidation of various metals contained in the lithium-ion secondary battery 20 can be suppressed. From this viewpoint, it is preferable to use the stacking of the containers 10 and the lid 15.
[0047] (Recovery step S103) The recovery step S103 is, for example, a step of removing the container 10 from the heating furnace after incineration treatment and recovering from inside the container 10 the battery material (such as metal materials other than the molten metal contained in the lithium-ion secondary battery 20) from which the molten metal has been separated.
[0048] When the container 10 has the inclined portion 12, in the recovery step S103, it is preferable to tilt the container 10 and recover the battery material from inside the container 10 from the inclined portion 12. Thereby, the battery material can be recovered simply. At this time, if a member such as a fork of a forklift is inserted into the support portion 13 and the member is moved to tilt the container 10, the battery material can be efficiently recovered.
[0049] By the above steps, the lithium-ion secondary battery 20 can be stably incinerated. Specifically, the lithium-ion secondary battery 20 can be incinerated, and the separation of the molten metal such as aluminum and other battery materials can be stably performed.
[0050] <Other embodiments of the present invention> As described above, the embodiments of the present invention have been specifically described. However, the present invention is not limited to the above-described embodiments, and various modifications can be made without departing from the gist thereof.
[0051] For example, in the above-described embodiment, as shown in FIG. 1(b), the case where the inclined portion 12 is provided only on one side of the container 10 has been described. However, the inclined portion 12 may be provided on both sides of the container 10. In this case, in the recovery step S103, when tilting the container 10 to recover the battery material from inside the container 10, the degree of freedom in the tilting direction increases. However, from the viewpoint of maintaining the processing efficiency, it is preferable to provide the inclined portion 12 only on one side of the container 10 as in the above-described embodiment because the number of lithium-ion secondary batteries 20 that can be arranged inside the container 10 decreases with respect to the total length of the container 10, and the processing efficiency may decrease.
[0052] Further, for example, in the above-described embodiment, as shown in FIG. 2, the case where the containers 10 are stacked and fixed in two stages has been described. However, in the arrangement step S101, the containers 10 may be stacked and fixed in three or more stages. In this case, more lithium ion secondary batteries 20 can be processed at once. Note that the upper limit of the number of stages of the stacked containers 10 is preferably, for example, five or less so that the total weight does not become too large.
Example
[0053] Next, examples according to the present invention will be described. These examples are an example of the present invention, and the present invention is not limited by these examples.
[0054] (Example 1) In Example 1, as shown in FIG. 1, a SUS304 container 10 having a depth of 250 mm, a length of 1630 mm, and a width of 920 mm, with the size of the slit-shaped holes being 100 mm in length and 20 mm in width and the inclined portion being about 40°, was used to perform incineration treatment on a lithium ion secondary battery 20 (height 170 mm, longitudinal width 25 mm, lateral width 100 mm). First, the lithium ion secondary batteries 20 with a total weight of 360 kg were divided into two and placed in each of the two containers 10. Specifically, 30 were vertically placed in one container 10 without gaps in the width direction of the container 10 so that the terminals were on the upper surface, and arranged in 6 rows in the length direction. The two containers 10 were stacked in two stages, and the support portion 13 of the second-stage container 10 was fitted into the recess 14 of the first-stage container 10 and fixed. Further, the second-stage container 10 was covered with a lid 15.
[0055] Next, the containers 10 stacked in two stages were carried into a heating furnace and incineration treatment was performed at 850° C. for 4 hours under reduced pressure. The molten metal (aluminum) flowing out from the lithium ion secondary battery 20 separated outside the container 10 through the plurality of holes 11 and was collected in a recovery container arranged below the container 10.
[0056] After the incineration process, the container 10 and the recovery container were each removed from the heating furnace. The fork of the forklift was inserted into the support portion 13 to lift the container 10, and then the container 10 was tilted to quickly and efficiently recover the battery materials. The weight of the recovered battery materials was 259.2 kg, and the weight of the aluminum recovered in the recovery container was 100.8 kg. It was confirmed that the aluminum was cleanly separated. Also, there was no sudden heat generation or ignition in the heating furnace during handling such as transportation.
[0057] (Comparative Example 1) In Comparative Example 1, as shown in Fig. 5(a), a box-shaped container 100 (with a lid) without a plurality of holes 11 or inclined portions 12 was used. A support member similar to that in Example 1 of Patent Document 1 (see Fig. 6 of Patent Document 1) was provided at the bottom of the container 100. The same amount of lithium-ion secondary batteries 20 as in Example 1 were put into one container 100 and incinerated. The conditions of the incineration process were the same as those in Example 1.
[0058] After the incineration process, when the inside of the container 100 was checked, although some aluminum was separated at the bottom below the support member, there was also a lot of contamination of the battery materials. As shown in Fig. 5(b), the aluminum 101 and the battery materials 102 were not sufficiently separated. Also, it was confirmed that the container 100 was deformed and a part of the lithium-ion secondary battery 20 had scattered outside the container 100.
[0059] From the above, by using the container 10 which is an embodiment of the present invention, only the molten metal aluminum flowed out of the container, and the other non-molten battery materials (especially black mass) remained inside the container. Also, during handling such as transportation, the posture of the lithium-ion secondary battery became stable and did not cause sudden heat generation or ignition due to a short circuit.
Explanation of Reference Numerals
[0060] 10, 10a, 10b Containers (Processing Containers) 11 Holes 12 Inclined Portions 13 Support Portion 14 Concave Portion 15 Lid 20 Lithium-ion secondary battery 21 Terminal 100 Container 101 Aluminum 102 Battery material S101 Arrangement process S102 Incineration process S103 Recovery process
Claims
1. A treatment container for a lithium-ion secondary battery that houses a lithium-ion secondary battery containing a metal that melts at a temperature of 650°C or higher and 1000°C or lower, and is used when incinerating at a temperature higher than the melting point of the metal, wherein it has a plurality of holes at the bottom for separating the molten metal flowing out of the lithium-ion secondary battery during incineration from the outside of the container, a plurality of cylindrical support portions are provided on the outer side of the bottom surface. A treatment container for a lithium-ion secondary battery.
2. The treatment container for a lithium-ion secondary battery according to claim 1, having an inclined portion in which at least one surface of the side surface is inclined toward the outside of the container.
3. The treatment container for a lithium-ion secondary battery according to claim 1, wherein the plurality of holes are in a slit shape.
4. The treatment container for a lithium-ion secondary battery according to claim 3, wherein the intersection of the longitudinal direction of the hole and the longitudinal direction of the support portion exists on the bottom surface.
5. The treatment container for a lithium-ion secondary battery according to claim 1, wherein the total area of the plurality of holes is 10% or more and 40% or less of the bottom area of the treatment container.
6. A recess is provided at the upper side of the side surface, The treatment container for a lithium-ion secondary battery according to claim 1, wherein when a plurality of the treatment containers are stacked, the support portion of the upper treatment container and the recess of the lower treatment container are fitted together.
7. The treatment container for a lithium-ion secondary battery according to claim 1, having a depth of 50 mm or more and 400 mm or less.
8. The treatment container for a lithium-ion secondary battery according to claim 1, wherein alumina is coated on the inner wall.
Citation Information
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