Lipstick composition based on a mixture of volatile alkanes
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2023-03-03
- Publication Date
- 2026-03-11
Abstract
Description
[Technical field]
[0001] The present application relates to the cosmetic technical field.
[0002] More particularly, the invention relates to lipstick compositions comprising a mixture of volatile alkanes.
[0003] As part of this application, some definitions are provided.
[0004] An "alkane" is a saturated hydrocarbon consisting of only carbon and hydrogen atoms linked by single covalent bonds, with the general formula: n H 2n+2 It is.
[0005] A "straight chain alkane" is an alkane in which each carbon atom is bonded to a maximum of two carbon atoms.
[0006] A "branched chain alkane" is an alkane that has any carbon atom bonded to three or four carbon atoms.
[0007] "C x An "alkane" is an alkane of x carbon atoms, which may be linear or branched. For example, dodecane is C 12 It is an alkane.
[0008] Generally, a "volatile alkane mixture" is a mixture of alkanes having a flash point of less than or equal to 95° C., as measured according to the ASTM D93 standard.
[0009] In the present invention, the term "volatile alkane mixture" means an alkane mixture having a flash point of 55° C. or less, measured according to the ASTM D93 standard.
[0010] The flash point measured according to the ASTM D93 standard is called the "flash point". The unit of the flash point measured according to the ASTM D93 standard is degrees Celsius (℃). In addition, each value is obtained by a measurement method according to the ASTM D93 standard, and it may be the average value.
[0011] The term "mass percentage" refers to the ratio of the mass of a first compound to the total mass of a mixture or composition of compounds expressed as a percentage. For example, 10 grams of compound y in a mixture z with a total mass of 100 grams would be the mass percentage of y in z of 10%.
[0012] A "biogenic" compound or organic composition is one in which the organic carbon present in the compound or composition is 100% plant-derived (as determined by radiocarbon analysis according to any of the following standards: ASTM D6866, EN 16640, or EN 16785-1). 14 C) is defined as being.
[0013] The "naturalness index" of an organic composition is the percentage of organic carbon of plant origin ( 14 C) percentage.
[0014] In the present invention, the OECD 301F method can assess the biodegradability of a substance by a manometric respiration test.
[0015] Since isododecane was introduced into cosmetics in the 1990s, its use has expanded significantly in all areas of cosmetics, from skin care products, to makeup products such as mascara compositions and long-wearing lipsticks, and hair care products such as serums and anti-frizz dry oils.
[0016] In some of these products, isododecane constitutes up to 60% by weight of the cosmetic formulation composition.
[0017] Long-lasting make-up products currently account for approximately 25% of the global make-up market. Isododecane is the key ingredient that provides long-lasting, transfer-free and water-resistant properties while maintaining optimal comfort. This market developed from an essential ingredient, Isododecane, which is derived from petrochemicals.
[0018] However, with limited petroleum resources and a fluctuating and polluting petroleum market, meeting the demand for isododecane, or at least being able to provide equivalent properties in cosmetic formulations, has become a strategic challenge for the cosmetics industry.
[0019] The first approach to address these challenges is to develop a method for producing isododecane that does not use petroleum feedstocks.
[0020] Recently, GLOBAL BIOENEGIES Inc. disclosed in patent application WO2020188033 the production of isobutene by a biological process using genetically modified organisms such as modified E. coli.
[0021] According to patent application WO2021228824, the obtained isobutene gas is converted to isododecane by a solvent phase oligomerization reaction followed by a hydrogenation step.
[0022] This reaction, known from the chemical industry, suffers from the drawbacks of forming by-products and low yields, raising questions about the long-term viability of the approach in terms of volume and cost.
[0023] Nevertheless, GLOBAL BIOENEGIES raised more than €100 million to develop such a process between 2008 and early 2021, when it launched its first batch of cosmetic-grade isododecane.
[0024] This long-term economic investment to produce isododecane from natural feedstocks is noteworthy.
[0025] Indeed, the second strategy, reducing the amount of isododecane in current cosmetics or replacing it with another, is a challenge of an entirely different scale for the cosmetics industry.
[0026] Furthermore, as described in patent application EP3349720, finding a biodegradable alternative to isododecane would be a major advance from an environmental point of view, as such compounds could account for a mass percentage of up to 60% of a cosmetic composition.
[0027] Therefore, research was carried out to identify compounds that could be satisfactory replacements for isododecane. These compounds should have similar volatility characteristics and similar behavior in formulations, especially with regard to sensory properties such as ease of spread on skin, feel on touch, and also the "non-greasy" nature of the resulting films.
[0028] Therefore, from an economic and environmental standpoint, there is a need for cosmetic excipients that can replace isododecane as an excipient, particularly in cosmetic formulations.
[0029] Surprisingly, applicants have demonstrated that such an excipient can be obtained.
[0030] The excipient is a predefined mixture of volatile alkanes.
[0031] Preferably, the volatile alkane mixture is obtained from fatty alcohols by Guerbet alcohol reaction followed by dehydration and hydrogenation. This synthetic route advantageously makes it possible to obtain an alternative excipient to isododecane from raw materials of natural origin using an industrial process that is economically viable in relation to market needs.
[0032] Furthermore, such excipients are biodegradable according to OECD method 301F, unlike isododecane (CAS 13475-82-6).
[0033] Advantageously, the excipients of the present invention are at least 50% biodegradable according to the OECD 301F method.
[0034] The invention also demonstrates that the incorporation of this cosmetic excipient into cosmetic formulations, particularly lipsticks, long-wearing lipsticks, or lip glosses, is effective in providing the cosmetic formulations with notable cosmetic qualities such as ease of application, water resistance, good hold, and darker, brighter color, in addition to superior stability of the formulations.
[0035] Moreover, the incorporation of this cosmetic excipient makes it possible to obtain cosmetic formulations for lipsticks that exhibit a naturalness index of more than 90%.
[0036] For the purposes of the invention, the term "long-wearing" lipstick (also known as "non-transfer" lipstick) refers to a lipstick that is non-streakable, water-resistant and, in some cases, oil-resistant.
[0037] Similarly, a "lip gloss" or "lip shine" is a makeup product that adds shine and / or moisture to the lips, and sometimes adds color or shimmer to the lips. Some of these lip glosses are clear and can be applied over regular lipstick to add a glossy effect.
[0038] The invention includes a volatile alkane mixture, the volatile alkane mixture comprising: a) 20 to 100% by mass of fraction A containing at least one branched alkane of C10 or less; b) containing 0 to 80% by mass of a B fraction containing at least one linear or branched alkane above C10; The lipstick composition is characterized in that the mixture of volatile alkanes has a flash point, measured according to the ASTM D93 standard, of less than 55° C. and represents a mass percentage of at least 2% relative to the total mass of the composition.
[0039] In one embodiment, the lipstick is a non-transfer lipstick or a low transfer lipstick.
[0040] "Non-transfer lipstick" is generally defined as a product that does not risk transferring during meals or after kissing, and is an essential product that does not require reapplication during the day or at night. Non-transfer lipsticks are highly pigmented, do not leave marks, and last at least 8 hours on the lips. Thanks to fixatives, they stay clearly on the lips with less touch-ups during the day.
[0041] The invention includes a volatile alkane mixture, the volatile alkane mixture comprising: a) 20 to 100% by mass of fraction A containing at least one branched alkane of C10 or less; b) containing 0 to 80% by mass of a B fraction containing at least one linear or branched alkane above C10; The present invention relates to a composition for a non-transferable lipstick, characterized in that the volatile alkane mixture has a flash point of less than 55° C., measured according to the ASTM D93 standard, and represents a mass percentage of 25% or more relative to the total mass of the composition.
[0042] The lipstick composition of the invention is characterized in that it contains a mass percentage of isododecane less than or equal to 15% relative to the total mass of the composition.
[0043] The lipstick composition of the invention is characterized in that it contains a mass percentage of isododecane less than or equal to 10% relative to the total mass of the composition.
[0044] The inventive lipstick composition is characterized in that it contains a weight percentage of isododecane that is preferably less than or equal to 5% relative to the total weight of the composition.
[0045] The lipstick composition of the invention is preferably characterized in that it is free of isododecane.
[0046] In one embodiment, the lipstick composition of the invention comprises a linear C 10It is characterized by not containing alkanes. Traditionally, according to the book "Conception des produits cosmetique: la formulation" by Anne-Marie PENSE-LHERITIER published by LAVOISIER in 2014, lipstick compositions are mainly composed of the following two components. Base or support pigment part
[0047] The base contains a wide variety of ingredients selected primarily for their organoleptic properties. A volatile solvent for ease of application and retention. An oil that improves slip and makes it easier to apply. Wax with adjustable consistency and hardness. Fatty substances such as pasty fats and gelling agents to adjust smoothness and ease of use.
[0048] Finding a delicate balance between these different ingredients results in a lipstick.
[0049] These ingredients can be supplemented with various additives that impart specific properties: polymers, absorbent powders, stabilizing additives (antioxidants, preservatives, etc.), fragrances, and, where applicable, active ingredients.
[0050] The various components of the inventive composition are described in detail below.
[0051] Typically, the volatile solvents used in the cosmetics industry are volatile silicones or volatile isoparaffins such as isododecane.
[0052] For purposes of the present invention, the volatile solvent is defined as a "volatile alkane mixture."
[0053] Preferably, the volatile solvent does not include a volatile silicone.
[0054] In one embodiment, the lipstick composition of the invention is characterized in that the volatile alkane mixture has a flash point of 50° C. or less.
[0055] Preferably, the lipstick composition of the invention is characterized in that the flash point of said mixture of volatile alkanes is between 45°C and 50°C.
[0056] Preferably, the lipstick composition of the invention is characterized in that the volatile alkane mixture has a flash point of 45° C. or less.
[0057] More preferably, the lipstick composition of the invention is characterized in that the flash point of said mixture of volatile alkanes is between 40°C and 45°C.
[0058] Advantageously, the lipstick composition of the invention is characterized in that the mixture of volatile alkanes has a flash point of less than or equal to 40° C.
[0059] In one embodiment, the lipstick composition of the invention is characterized in that the flash point of the volatile alkane mixture is between 35°C and 40°C.
[0060] In one embodiment, a "volatile alkane mixture" is a mixture of alkanes that does not include any alkanes with more than 16 carbon atoms.
[0061] Preferably, a "volatile alkane mixture" is a mixture of alkanes that does not contain any alkanes with more than 15 carbon atoms.
[0062] Preferably, the "volatile alkane mixture" does not include isododecane.
[0063] Preferably, a "volatile alkane mixture" is a mixture of alkanes that does not contain any alkanes with more than 14 carbon atoms.
[0064] In one embodiment, the lipstick composition of the invention is characterized in that the mixture of volatile alkanes has a naturality index of 60% or more of carbon-14 (14C) determined according to any one of the standards ASTM D6866, EN 16640, or EN 16785-1.
[0065] In one embodiment, the lipstick composition of the invention comprises a volatile alkane mixture having a carbon-14( 14 C) characterized by having a naturalness index of 70% or more.
[0066] Preferably, the lipstick composition of the invention comprises a volatile alkane mixture having a carbon-14 ( 14 C) characterized by having a naturalness index of 75% or more.
[0067] Preferably, the lipstick composition of the invention comprises a volatile alkane mixture having a carbon-14 ( 14 C) characterized by having a naturalness index of 85% or more.
[0068] Preferably, the lipstick composition of the invention comprises a volatile alkane mixture having a carbon-14 ( 14 C) characterized by having a naturalness index of 90% or more.
[0069] Advantageously, the volatile alkane mixture present in the inventive composition has a carbon-14( 14 C) characterized by having a naturalness index of 100%.
[0070] In one embodiment, the lipstick composition of the invention is characterized in that the mixture of volatile alkanes is obtained from a source of plant, bacterial or animal origin.
[0071] In a preferred embodiment, the inventive lipstick composition is characterized in that said mixture of volatile alkanes is obtained from raw materials of plant origin.
[0072] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture is at least 50% biodegradable according to OECD 301F method.
[0073] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture is at least 60% biodegradable according to OECD 301F method.
[0074] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture has a biodegradability of between 50% and 80% according to the OECD 301F method.
[0075] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture has a biodegradability of between 50% and 70% according to the OECD 301F method.
[0076] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture has a biodegradability of between 50% and 60% according to the OECD 301F method.
[0077] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture has a biodegradability of between 60% and 70% according to the OECD 301F method.
[0078] In one embodiment, the inventive lipstick composition is characterized in that the volatile alkane mixture has a biodegradability of between 70% and 80% according to the OECD 301F method.
[0079] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is at least 10%.
[0080] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is at least 15%.
[0081] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is at least 20%.
[0082] The non-transfer lipstick composition of the invention is characterized in that the mass percentage of said mixture of volatile alkanes relative to the total mass of the composition is at least 25%.
[0083] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is at least 50%.
[0084] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 25% and 80%.
[0085] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 40% and 80%.
[0086] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 25% and 60%.
[0087] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 30% and 50%.
[0088] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 40% and 60%.
[0089] In one embodiment, the inventive non-transfer lipstick composition is characterized in that the weight percentage of said mixture of volatile alkanes relative to the total weight of the composition is between 60% and 80%.
[0090] The A-fraction of the volatile mixture of alkanes is selected from the group comprising branched chain C8 alkanes, branched chain C9 alkanes, branched chain C10 alkanes, and mixtures thereof.
[0091] The A-fraction of the volatile alkane mixture comprises at least one branched chain C10 or lower alkane.
[0092] In one embodiment, the lipstick composition of the invention is characterized in that the at least one branched C10 or lower alkane of the volatile alkane mixture is at least one branched C8 alkane.
[0093] In one embodiment, the lipstick composition of the invention is such that at least one of the branched C10 or less alkanes of the volatile alkane mixture is a branched C9 alkane, a branched C 10 alkanes, and mixtures thereof.
[0094] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the volatile alkane mixtures having a branched C10 or less alkane is a branched C 10 alkanes, and mixtures thereof.
[0095] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the volatile alkane mixtures having a branched C10 or less alkane is a branched C 10 alkanes, and mixtures thereof, characterized in that it does not contain branched C8 alkanes.
[0096] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the volatile alkane mixtures having a branched C10 or less alkane is a branched C 10 alkanes, and mixtures thereof, characterized in that it does not contain branched C8 alkanes and branched C9 alkanes.
[0097] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the branched C10 or lower alkane of the volatile alkane mixture is a branched C9 alkane.
[0098] In one embodiment, the lipstick composition of the invention is characterized in that the at least one branched C10 or less alkane of the volatile alkane mixture is at least one branched C9 alkane selected from the group consisting of trimethylhexanes, such as 2,2,4-trimethylhexane (CAS 16747-26-5), 2,2,5-trimethylhexane (CAS 3522-94-9), 2,2,3-trimethylhexane (CAS 16747-25-4), 2,4,4-trimethylhexane (CAS 16747-30-1), 2,3,3-trimethylhexane (CAS 16747-28-1), 3,3,4-trimethylhexane (CAS 16747-31-2), 2,3,5-trimethylhexane (CAS 1069-53-0), and 2,3,4-trimethylhexane (CAS 921-47-1).
[0099] In the present invention, the term "trimethylhexanes" refers to all C6 alkanes branched with three methyl groups.
[0100] In one embodiment, the lipstick composition of the invention is characterized in that at least one branched C10 or less alkane of the volatile alkane mixture is trimethylhexane.
[0101] In one embodiment, the lipstick composition of the invention is characterized in that the at least one branched C10 or less alkane of the volatile alkane mixture is 2,2,4-trimethylhexane (CAS 16747-26-5).
[0102] In one embodiment, the lipstick composition of the invention is characterized in that the at least one branched C10 or less alkane of the volatile alkane mixture is 2,3,5-trimethylhexane (CAS 1069-53-0).
[0103] In one embodiment, the lipstick composition of the invention is characterized in that at least one branched C10 or less alkane of the volatile alkane mixture is 2,3,4-trimethylhexane (CAS 921-47-1).
[0104] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the volatile alkane mixtures having a branched C10 or less alkane is a branched C 10 It is characterized as being an alkane.
[0105] In one embodiment, the lipstick composition of the invention is characterized in that the at least one branched C10 or less alkane of the volatile alkane mixture is selected from the group consisting of 2-methylnonane (CAS 871-83-0), 4-methylnonane (CAS 17301-94-9), 3-methylnonane (CAS 5911-04-6), 3-ethyloctane (CAS 5881-17-4), 2,2-dimethyloctane (CAS 15869-87-1), 2,3-dimethyloctane (CAS 7146-60-3), 2,5-dimethyloctane (CAS 15869-89-3), 3,5-dimethyloctane (CAS 15869-93-9), 4-propylheptane (CAS 3178-29-8), 3-ethyl-2-methylheptane (CAS 14676-29-0), 2,3,6-trimethylheptane (CAS-4032-93-3), 3,3,4-trimethylheptane (CAS 20278-87-9), 2,3,4-trimethylheptane (CAS 52896-95-4), 2,2,4-trimethylheptane (CAS 14720-74-2), 3,3-diethylhexane (CAS 17302-02-2), 2,2,3,3-tetramethylhexane (CAS 13475-81-5), 3-ethyl-2,2,3-trimethylpentane (CAS 52897-17-3), 2,2,3-trimethylheptane (CAS 52896-92-1), 2,3,5-trimethylheptane (CAS 20278-85-7), 3,3-Diethylhexane (CAS 17302-02-2), 2,2,3,3-Tetramethylhexane (CAS 13475-81-5), 3-Ethyl-2,2,3-trimethylpentane (CAS 52897-17-3), 3,3,5-Trimethylheptane (CAS 7154-80-5), 2,5,5-Trimethylheptane (CAS 1189-99-7), 2,4,6-Trimethylheptane (CAS 2613-61-8), 3,4,5-Trimethylheptane (CAS 20278-89-1), 2,2,6-Trimethylheptane (CAS 1190-83-6), 2,4,5-Trimethylheptane (CAS 20278-84-6), 2,4,4-trimethylheptane (CAS 4032-92-2) 2,3,3-trimethylheptane (CAS 52896-93-2), 3,4,Branched chain C selected from the group consisting of 4-trimethylheptane (CAS 20278-88-0) and mixtures thereof, 10 It is characterized as being an alkane.
[0106] In the present invention, the term "trimethylheptanes" refers to all C7 alkanes branched by three methyl groups.
[0107] In one embodiment, the lipstick composition of the invention is such that the at least one branched C10 or less alkane of the volatile alkane mixture is, for example, 2,2,3-trimethylheptane (CAS 52896-92-1), 2,3,5-trimethylheptane (CAS 20278-85-7), 2,3,6-trimethylheptane (CAS 4032-93-3), 3,3,4-trimethylheptane (CAS 20278-87-9), 2,3,4-trimethylheptane (CAS 52896-95-4), 2,2,4-trimethylheptane (CAS 14720-74-2), 3,3,5-trimethylheptane (CAS 7154-80-5), 2,5,5-trimethylheptane (CAS 1189-99-7), 2,4,6-trimethylheptane (CAS 2613-61-8), 3,4,5-trimethylheptane (CAS 20278-89-1), 2,2,6-trimethylheptane (CAS 1190-83-6), 2,4,5-trimethylheptane (CAS 20278-84-6), 2,4,4-trimethylheptane (CAS 4032-92-2), 2,3,3-trimethylheptane (CAS 52896-93-2), 3,4,4-trimethylheptane (CAS 20278-88-0) and mixtures thereof. 10 It is characterized as being an alkane.
[0108] The invention also relates to a lipstick composition comprising a mixture of volatile alkanes as defined above, characterized in that at least one of the C10 or lower branched alkanes of the mixture of volatile alkanes is trimethylheptane.
[0109] The invention also relates to a lipstick composition comprising a mixture of volatile alkanes as defined above, characterized in that at least one of the branched alkanes of C10 or less in the mixture of volatile alkanes is 2,3,6-trimethylheptane (CAS-4032-93-3).
[0110] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,3,5-trimethylheptane (CAS 20278-85-7).
[0111] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,2,3-trimethylheptane (CAS 52896-92-1).
[0112] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 3,3,4-trimethylheptane (CAS 20278-87-9).
[0113] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,3,4-trimethylheptane (CAS 52896-95-4).
[0114] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,2,4-trimethylheptane (CAS 14720-74-2).
[0115] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,2,3-trimethylheptane (CAS 52896-92-1).
[0116] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 3,3,5-trimethylheptane (CAS 7154-80-5).
[0117] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,5,5-trimethylheptane (CAS 1189-99-7).
[0118] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,4,6-trimethylheptane (CAS 2613-61-8).
[0119] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 3,4,5-trimethylheptane (CAS 20278-89-1).
[0120] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,2,6-trimethylheptane (CAS 1190-83-6).
[0121] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,4,5-trimethylheptane (CAS 20278-84-6).
[0122] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,4,4-trimethylheptane (CAS 4032-92-2).
[0123] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the volatile alkane mixture is 2,3,3-trimethylheptane (CAS 52896-93-2).
[0124] The invention also relates to a lipstick composition comprising a volatile alkane mixture as defined above, characterized in that at least one C10 or lower branched alkane of the volatile alkane mixture is trimethylheptane and trimethylhexane.
[0125] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is at least 20% relative to the total mass of said volatile alkane mixture.
[0126] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is greater than 50% relative to the total mass of said volatile alkane mixture.
[0127] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 20% and 100% relative to the total mass of said volatile alkane mixture.
[0128] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 20% and 70% relative to the total mass of said volatile alkane mixture.
[0129] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 51% and 100% relative to the total mass of said volatile alkane mixture.
[0130] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 30% and 60% relative to the total mass of said volatile alkane mixture.
[0131] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 40% and 70% relative to the total mass of said volatile alkane mixture.
[0132] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 70% and 100% relative to the total mass of said volatile alkane mixture.
[0133] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 30% and 50% relative to the total mass of said volatile alkane mixture.
[0134] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 40% and 60% relative to the total mass of said volatile alkane mixture.
[0135] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 50% and 70% relative to the total mass of said volatile alkane mixture.
[0136] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 70% and 90% relative to the total mass of said volatile alkane mixture.
[0137] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the A fraction of the volatile alkane mixture is between 80% and 100% relative to the total mass of said volatile alkane mixture.
[0138] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is at least 20% relative to the total mass of the volatile alkane mixture.
[0139] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of at least one C10 or lower branched alkane of the volatile alkane mixture is greater than 50% relative to the total mass of the volatile alkane mixture.
[0140] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 20% and 100% relative to the total mass of the volatile alkane mixture.
[0141] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one C10 or lower branched alkane of the volatile alkane mixture is between 20% and 70% relative to the total mass of the volatile alkane mixture.
[0142] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of at least one C10 or lower branched alkane of the volatile alkane mixture is between 51% and 100% relative to the total mass of the volatile alkane mixture.
[0143] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 30% and 60% relative to the total mass of the volatile alkane mixture.
[0144] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 40% and 70% relative to the total mass of the volatile alkane mixture.
[0145] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 70% and 100% relative to the total mass of the volatile alkane mixture.
[0146] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 30% and 50% relative to the total mass of the volatile alkane mixture.
[0147] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 40% and 60% relative to the total mass of the volatile alkane mixture.
[0148] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 50% and 70% relative to the total mass of the volatile alkane mixture.
[0149] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 70% and 90% relative to the total mass of the volatile alkane mixture.
[0150] In one embodiment, the lipstick composition of the invention is characterized in that the mass percentage of the at least one C10 or lower branched alkane of the volatile alkane mixture is between 80% and 100% relative to the total mass of the volatile alkane mixture.
[0151] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the A fraction of the volatile alkane mixture is 2,3,6-trimethylheptane (CAS 4032-93-3).
[0152] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is at least 20% relative to the total mass of the volatile alkane mixture.
[0153] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 20% and 100% relative to the total mass of the volatile alkane mixture.
[0154] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 20% and 70% relative to the total mass of the volatile alkane mixture.
[0155] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 51% and 100% relative to the total mass of the volatile alkane mixture.
[0156] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 30% and 60% relative to the total mass of the volatile alkane mixture.
[0157] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 40% and 70% relative to the total mass of the volatile alkane mixture.
[0158] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 70% and 100% relative to the total mass of the volatile alkane mixture.
[0159] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 30% and 50% relative to the total mass of the volatile alkane mixture.
[0160] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 40% and 60% relative to the total mass of the volatile alkane mixture.
[0161] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 50% and 70% relative to the total mass of the volatile alkane mixture.
[0162] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 70% and 90% relative to the total mass of the volatile alkane mixture.
[0163] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,3,6-trimethylheptane (CAS 4032-93-3), of the volatile alkane mixture is between 80% and 100% relative to the total mass of the volatile alkane mixture.
[0164] In one embodiment, the lipstick composition of the invention is characterized in that the at least one C10 or lower branched alkane of the A fraction of the volatile alkane mixture is 2,2,4-trimethylhexane (CAS 16747-26-5).
[0165] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is at least 5% relative to the total mass of the volatile alkane mixture.
[0166] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is at least 10% relative to the total mass of the volatile alkane mixture.
[0167] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is between 5% and 20% relative to the total mass of the volatile alkane mixture.
[0168] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is between 5% and 15% relative to the total mass of the volatile alkane mixture.
[0169] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is between 10% and 20% relative to the total mass of the volatile alkane mixture.
[0170] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is between 10% and 15% relative to the total mass of the volatile alkane mixture.
[0171] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one C10 or lower branched alkane, 2,2,4-trimethylhexane (CAS 16747-26-5), of the volatile alkane mixture is between 15% and 20% relative to the total mass of the volatile alkane mixture.
[0172] The B fraction of the volatile alkane mixture comprises at least one linear or branched alkane above C10.
[0173] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 11 Alkanes, C 12 Alkanes, C 13 characterized in that it is selected from the group comprising alkanes and mixtures thereof.
[0174] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 12 Alkanes, C 14 characterized in that it is selected from the group comprising alkanes and mixtures thereof.
[0175] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 12 Alkanes, C 13 Alkanes, C 14 Alkanes, C 15 Alkanes, C 16characterized in that it is selected from the group comprising alkanes and mixtures thereof.
[0176] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 11 Alkanes, C 12 Alkanes, C 13 Alkanes, C 14 Alkanes, C 15 characterized in that it is selected from the group comprising alkanes and mixtures thereof.
[0177] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is selected from the group consisting of undecane (CAS 1120-21-4), n-dodecane (CAS 112-40-3), n-tridecane (CAS 629-50-5), n-tetradecane (CAS 629-59-4), n-pentadecane (CAS 629-62-9) and mixtures thereof.
[0178] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is undecane (CAS 1120-21-4).
[0179] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is n-dodecane (CAS 112-40-3).
[0180] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is n-tridecane (CAS 629-50-5).
[0181] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is an undecane / tridecane mixture sold under the name CETIOL ULTIMATE by the company BASF.
[0182] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is n-tetradecane (CAS 629-59-4).
[0183] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 12 Branched chain alkanes, C 13 Branched chain alkanes, C 14 Branched chain alkanes, C 15 Branched chain alkanes, C 16 It is characterized in that it is selected from the group comprising branched alkanes and mixtures thereof.
[0184] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 11 They are characterized by being branched alkanes.
[0185] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture. 12They are characterized by being branched alkanes. In one embodiment, the at least one linear or branched alkane above C10 of the volatile mixture of alkanes is selected from the group consisting of 3-methylundecane (CAS 1002-43-3), 4-methylundecane (CAS 2980-69-0), 5-methylundecane (CAS 1632-70-8), 6-methylundecane (CAS 17302-33-9), 2,4-dimethyldecane (CAS 2801-84-5), 4,4-dimethyldecane (CAS 17312-39-9), 3,5-dimethyldecane (CAS 17312-48-0), 2,5-dimethyldecane (CAS 17312-50-4), 2,3-dimethyldecane (17312-44-6), 3,3-dimethyldecane (17302-38-4), 3,7-dimethyldecane (CAS 17312-54-8), 3,4,6-trimethylnonane (CAS 62184-24-1), 3,5,6-trimethylnonane (CAS 62184-26-3), 3,5,7-trimethylnonane (CAS 62184-27-4), 2,5,7-trimethylnonane (CAS 62184-14-9), 2,5,6-trimethylnonane (CAS 62184-13-8), 2,5,7-trimethylnonane (CAS 62184-14-9), 2,5,8-trimethylnonane (CAS 49557-09-7), 3,3,4,5-tetramethyloctane (CAS 62185-21-1), 2,3,4,5-tetramethyloctane (CAS 62199-27-3), 2,2,4,5-Tetramethyloctane (CAS 62183-80-6), 2,2,5,7-Tetramethyloctane (CAS 62199-19-3), 2,3,4,7-Tetramethyloctane (CAS 62199-29-5), 2,4,4,7-Tetramethyloctane (CAS 35866-96-7), 3-Ethyl-4-methylnonane (CAS 62184-45-6), 3-Ethyl-4,5-dimethyloctane (CAS 62183-72-6), 2,5-Dimethyl-6-ethyloctane (CAS 62183-50-0), 2,2,4,6,6-Pentamethylheptane (CAS 13475-82-6) and mixtures thereof.
[0186] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is at least one isododecane.
[0187] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane greater than C10 of the volatile alkane mixture is 2,2,4,6,6-pentamethylheptane (CAS 13475-82-6).
[0188] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture, the branched C 13 It is characterized as being an alkane.
[0189] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture, the branched C 14 It is characterized as being an alkane.
[0190] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture, the branched C 15 It is characterized as being an alkane.
[0191] In one embodiment, the inventive lipstick composition is characterized in that at least one linear or branched alkane above C10 of said mixture of volatile alkanes is at least a hemisqualane marketed under the name NEOSSANCE by the company AMYRIS.
[0192] In one embodiment, the lipstick composition of the invention comprises at least one C10 linear or branched alkane of the volatile alkane mixture, the C10 linear or branched alkane being at least one C10 linear or branched alkane marketed by SEPPIC under the name EMOGREEN L15. 13 -C 15It is characterized as being a mixture.
[0193] In one embodiment, the lipstick composition of the invention comprises at least one linear or branched alkane above C10 of the volatile alkane mixture, the branched C 16 It is characterized as being an alkane.
[0194] In one embodiment, the inventive lipstick composition is characterized in that the at least one linear or branched alkane above C10 of the volatile alkane mixture is at least one isohexadecane.
[0195] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 0% and 80% relative to the total mass of said volatile alkane mixture.
[0196] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 0% and 50% relative to the total mass of said volatile alkane mixture.
[0197] In one embodiment, the lipstick composition of the invention has a mass percentage of the B fraction of the volatile alkane mixture of 0% relative to the total mass of said volatile alkane mixture. 30%.
[0198] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the B fraction of the volatile alkane mixture is at least 30% relative to the total mass of said volatile alkane mixture.
[0199] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 30% and 80% relative to the total mass of said volatile alkane mixture.
[0200] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 30% and 60% relative to the total mass of said volatile alkane mixture.
[0201] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 50% and 80% relative to the total mass of said volatile alkane mixture.
[0202] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 30% and 50% relative to the total mass of said volatile alkane mixture.
[0203] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 40% and 60% relative to the total mass of said volatile alkane mixture.
[0204] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 50% and 70% relative to the total mass of said volatile alkane mixture.
[0205] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 60% and 80% relative to the total mass of said volatile alkane mixture.
[0206] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 0% and 10% relative to the total mass of said volatile alkane mixture.
[0207] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 10% and 20% relative to the total mass of said volatile alkane mixture.
[0208] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 40% and 50% relative to the total mass of said volatile alkane mixture.
[0209] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 60% and 70% relative to the total mass of said volatile alkane mixture.
[0210] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of fraction B of the volatile alkane mixture is between 70% and 80% relative to the total mass of said volatile alkane mixture.
[0211] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of said volatile alkane mixture is between 0% and 80% relative to the total mass of said volatile alkane mixture.
[0212] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of said volatile alkane mixture is between 0% and 50% relative to the total mass of said volatile alkane mixture.
[0213] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one linear or branched alkane above C10 of said volatile alkane mixture is between 0% and 30% relative to the total mass of said volatile alkane mixture.
[0214] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of said volatile alkane mixture is at least 30% relative to the total mass of said volatile alkane mixture.
[0215] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of said volatile alkane mixture is at least 50% relative to the total mass of said volatile alkane mixture.
[0216] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 30% and 80% relative to the total mass of the volatile alkane mixture.
[0217] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 30% and 60% relative to the total mass of the volatile alkane mixture.
[0218] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 50% and 80% relative to the total mass of the volatile alkane mixture.
[0219] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one linear or branched alkane above C10 of said volatile alkane mixture is between 0% and 20% relative to the total mass of said volatile alkane mixture.
[0220] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one linear or branched alkane above C10 of said volatile alkane mixture is between 10% and 30% relative to the total mass of said volatile alkane mixture.
[0221] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of said volatile alkane mixture is between 30% and 50% relative to the total mass of said volatile alkane mixture.
[0222] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 40% and 60% relative to the total mass of the volatile alkane mixture.
[0223] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 50% and 70% relative to the total mass of the volatile alkane mixture.
[0224] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 60% and 80% relative to the total mass of the volatile alkane mixture.
[0225] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one linear or branched alkane above C10 of said volatile alkane mixture is between 0% and 10% relative to the total mass of said volatile alkane mixture.
[0226] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of at least one linear or branched alkane above C10 of said volatile alkane mixture is between 10% and 20% relative to the total mass of said volatile alkane mixture.
[0227] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 20% and 30% relative to the total mass of the volatile alkane mixture.
[0228] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 40% and 50% relative to the total mass of the volatile alkane mixture.
[0229] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 60% and 70% relative to the total mass of the volatile alkane mixture.
[0230] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10 of the volatile alkane mixture is between 70% and 80% relative to the total mass of the volatile alkane mixture.
[0231] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 0% and 80% based on the total mass of the volatile alkane mixture.
[0232] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 0% and 50% by weight relative to the total weight of the volatile alkane mixture.
[0233] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 0% and 30% relative to the total mass of the volatile alkane mixture.
[0234] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is at least 10% by weight based on the total weight of the volatile alkane mixture.
[0235] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is at least 30% by weight based on the total weight of the volatile alkane mixture.
[0236] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 10% and 80% by weight relative to the total weight of the volatile alkane mixture.
[0237] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 30% and 80% by weight relative to the total weight of the volatile alkane mixture.
[0238] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 30% and 60% by weight relative to the total weight of the volatile alkane mixture.
[0239] In one embodiment, the inventive lipstick composition is characterized in that the mass percentage of the at least one linear or branched alkane above C10, n-dodecane (CAS 112-40-3), of said volatile alkane mixture is between 50% and 80% relative to the total mass of said volatile alkane mixture.
[0240] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 30% and 50% by weight relative to the total weight of the volatile alkane mixture.
[0241] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 40% and 60% by weight relative to the total weight of the volatile alkane mixture.
[0242] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 50% and 70% by weight relative to the total weight of the volatile alkane mixture.
[0243] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 60% and 80% by weight relative to the total weight of the volatile alkane mixture.
[0244] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 0% and 10% relative to the total mass of the volatile alkane mixture.
[0245] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 10% and 20% by weight relative to the total weight of the volatile alkane mixture.
[0246] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 20% and 30% by weight relative to the total weight of the volatile alkane mixture.
[0247] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 40% and 50% by weight relative to the total weight of the volatile alkane mixture.
[0248] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 50% and 60% by weight relative to the total weight of the volatile alkane mixture.
[0249] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 60% and 70% by weight relative to the total weight of the volatile alkane mixture.
[0250] In one embodiment, the inventive lipstick composition comprises at least one C10 linear or branched alkane of the volatile alkane mixture, n-dodecane (CAS 112-40-3) is between 70% and 80% by weight relative to the total weight of the volatile alkane mixture.
[0251] The invention also relates to a composition for lipstick comprising a volatile alkane mixture as defined above, wherein the volatile alkane mixture 20 to 100% trimethylheptane (CAS 4032-93-3); 0 to 80% n-dodecane (CAS 112-40-3) The present invention relates to a composition for lipstick comprising:
[0252] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 100% trimethylheptane (CAS 4032-93-3); 0 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0253] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 70% trimethylheptane (CAS 4032-93-3); 30 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0254] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 70% trimethylheptane (CAS 4032-93-3); 30 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0255] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 50 to 100% trimethylheptane (CAS 4032-93-3); 0 to 50% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0256] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 50 to 70% trimethylheptane (CAS 4032-93-3); 0 to 50% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0257] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 100% 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0258] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 100% 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0259] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 70% of 2,3,6-trimethylheptane (CAS 4032-93-3); 30 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0260] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 20 to 70% of 2,3,6-trimethylheptane (CAS 4032-93-3); 30 to 80% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0261] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 30% 2,3,6-trimethylheptane (CAS 4032-93-3); 70% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0262] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 35% 2,3,6-trimethylheptane (CAS 4032-93-3); 65% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0263] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 40% 2,3,6-trimethylheptane (CAS 4032-93-3); 60% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0264] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 45% 2,3,6-trimethylheptane (CAS 4032-93-3); 55% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0265] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 60% 2,3,6-trimethylheptane (CAS 4032-93-3), 40% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0266] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 70% 2,3,6-trimethylheptane (CAS 4032-93-3), 30% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0267] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 90% 2,3,6-trimethylheptane (CAS 4032-93-3), 10% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0268] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. It is characterized by being composed of 100% 2,3,6-trimethylheptane (CAS 4032-93-3).
[0269] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 15% trimethylhexane; 20 to 95% trimethylheptane; 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0270] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 15% trimethylhexane; 20 to 95% trimethylheptane; 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0271] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 10% 2,2,4-trimethylhexane; 20 to 60% 2,3,6-trimethylheptane; 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0272] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 10% 2,2,4-trimethylhexane; 20 to 60% 2,3,6-trimethylheptane; 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0273] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 15% 2,2,4-trimethylhexane (CAS 16747-26-5); 20 to 95% 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0274] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 15% 2,2,4-trimethylhexane (CAS 16747-26-5); 20 to 95% 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0275] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 10% 2,2,4-trimethylhexane (CAS 16747-26-5); 20 to 60% of 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized by comprising:
[0276] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5 to 10% 2,2,4-trimethylhexane (CAS 16747-26-5); 20 to 60% of 2,3,6-trimethylheptane (CAS 4032-93-3); 0 to 75% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0277] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5% 2,2,4-trimethylhexane (CAS 16747-26-5); 20% 2,3,6-trimethylheptane (CAS 4032-93-3); 75% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0278] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5% 2,2,4-trimethylhexane (CAS 16747-26-5); 30% 2,3,6-trimethylheptane (CAS 4032-93-3); 65% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0279] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5% 2,2,4-trimethylhexane (CAS 16747-26-5); 35% 2,3,6-trimethylheptane (CAS 4032-93-3); 60% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0280] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 5% 2,2,4-trimethylhexane (CAS 16747-26-5); 45% 2,3,6-trimethylheptane (CAS 4032-93-3); 50% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0281] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 10% 2,2,4-trimethylhexane (CAS 16747-26-5), 20% 2,3,6-trimethylheptane (CAS 4032-93-3); 70% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0282] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 10% 2,2,4-trimethylhexane (CAS 16747-26-5), 30% 2,3,6-trimethylheptane (CAS 4032-93-3); 60% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0283] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 10% 2,2,4-trimethylhexane (CAS 16747-26-5), 35% 2,3,6-trimethylheptane (CAS 4032-93-3); 55% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0284] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 15% 2,2,4-trimethylhexane (CAS 16747-26-5); 20% 2,3,6-trimethylheptane (CAS 4032-93-3); 65% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0285] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 15% 2,2,4-trimethylhexane (CAS 16747-26-5); 25% 2,3,6-trimethylheptane (CAS 4032-93-3); 60% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0286] In one embodiment, the lipstick composition of the invention comprises a mixture of volatile alkanes. 15% 2,2,4-trimethylhexane (CAS 16747-26-5); 30% 2,3,6-trimethylheptane (CAS 4032-93-3); 55% n-dodecane (CAS 112-40-3) The present invention is characterized in that it comprises:
[0287] In one embodiment, the inventive lipstick composition as defined above comprises a mixture of volatile alkanes, a) from 70 to 99% by weight of a mixture of volatile alkanes consisting of fractions A and B as defined above; a) 1 to 30% by mass of at least one C10 or lower linear alkane Fractionation and The present invention is characterized by comprising:
[0288] In one embodiment, the lipstick composition of the invention is characterized in that the volatile alkane mixture comprises at least one C10 or lower linear alkane selected from the group consisting of n-octane, n-nonane, and n-decane.
[0289] In one embodiment, the lipstick composition of the invention is characterized in that at least one of the C10 or lower linear alkanes contained in the volatile alkane mixture is n-decane.
[0290] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is at least 1% relative to the total weight of said mixture of volatile alkanes.
[0291] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is between 1% and 20% relative to the total weight of the mixture of volatile alkanes.
[0292] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is between 10% and 30% relative to the total weight of the mixture of volatile alkanes.
[0293] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is between 5% and 15% relative to the total weight of the mixture of volatile alkanes.
[0294] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is between 10% and 20% relative to the total weight of the mixture of volatile alkanes.
[0295] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of at least one C10 or lower linear alkane is between 20% and 30% relative to the total weight of the mixture of volatile alkanes.
[0296] In one embodiment, the inventive lipstick composition is characterized in that the mixture of volatile alkanes comprising the A, B and C fractions as defined above has a flash point of less than 55°C according to the ASTM D93 standard.
[0297] In one embodiment, the lipstick composition of the invention is characterized in that the flash point of the mixture of volatile alkanes comprising Fraction A, Fraction B and Fraction C as defined above is between 45°C and 54°C.
[0298] In one embodiment, the lipstick composition of the invention is characterized in that the flash point of the mixture of volatile alkanes comprising Fractions A, B and C as defined above is between 45°C and 50°C.
[0299] In one embodiment, the lipstick composition of the invention is characterized in that the flash point of the mixture of volatile alkanes comprising Fraction A, Fraction B and Fraction C as defined above is between 50°C and 54°C.
[0300] In one embodiment, a volatile alkane mixture comprising the A, B and C fractions as defined above is subjected to carbon-14 ( 14 C) has a percentage of 50% or more.
[0301] In one embodiment, a volatile alkane mixture comprising the A, B and C fractions as defined above is subjected to carbon-14 ( 14 C) has a percentage of 60% or more.
[0302] In one embodiment, a volatile alkane mixture comprising the A, B and C fractions as defined above is subjected to carbon-14 ( 14 C) has a percentage of 75% or more.
[0303] In one embodiment, a volatile alkane mixture comprising the A, B and C fractions as defined above is subjected to carbon-14 ( 14 C) has a percentage of 85% or more. In one embodiment, a volatile alkane mixture comprising the A, B and C fractions as defined above is subjected to carbon-14 ( 14 C) has a percentage of 90% or more.
[0304] In the context of the present application, a lipstick composition is characterized in that it comprises at least one non-volatile oil.
[0305] In the present invention, the term "non-volatile oil" means an oil having a flash point above 110° C., measured according to the ASTM D93 standard.
[0306] These oils may be of vegetable, mineral or synthetic origin.
[0307] These non-volatile oils may be hydrocarbon oils, silicone oils, fluorinated oils or fluorosilicone oils.
[0308] In the present invention, the term "hydrocarbon oil" means an oil consisting essentially of carbon atoms, hydrogen atoms and optionally oxygen atoms and / or nitrogen atoms.
[0309] Among these hydrocarbon oils, linear or branched alkanes, (poly)esters and (poly)ethers having 17 to 40 carbon atoms and in particular C2-C 24 Acids (preferably C6-C 20 ) (poly)esters, C6-C 20These include linear or branched alkanes of mineral or synthetic origin, such as triglycerides of fatty acids, vegetable oils, dialkyl carbonates, branched and / or unsaturated fatty acids, branched and / or unsaturated fatty alcohols.
[0310] As regards the non-volatile silicone oils, these are in particular selected from the group comprising phenylated silicone oils, non-volatile polydimethylsiloxanes or derivatives of non-volatile polydimethylsiloxanes, and mixtures thereof.
[0311] In a particularly preferred embodiment of the invention, the inventive lipstick composition is characterized in that the non-volatile oil is selected from the group consisting of non-volatile linear or branched alkanes.
[0312] Preferably, the inventive lipstick composition is characterized in that the non-volatile oil is selected from the group consisting of non-volatile linear or branched alkanes.
[0313] Preferably, the lipstick composition of the invention is characterized in that the non-volatile linear or branched alkanes are selected from the group consisting of linear or branched alkanes having from 17 to 40 carbon atoms.
[0314] The non-volatile oils used in the present invention are of vegetable origin.
[0315] In a preferred embodiment, the inventive lipstick composition is characterized in that the non-volatile oil is a vegetable hydrocarbon oil.
[0316] The vegetable hydrocarbon oil is in particular selected from the group comprising wheat germ oil, sunflower oil, grapeseed oil, sesame oil, coconut oil, apricot oil, castor oil, corn oil, avocado oil, soybean oil, shea oil, olive oil, sweet almond oil, cottonseed oil, palm oil, macadamia oil, rapeseed oil, jojoba oil, hazelnut oil, poppy seed oil, alfalfa oil, pumpkin oil, black currant oil, squash oil, evening primrose oil, barley oil and mixtures thereof.
[0317] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of non-volatile oil is at least 5% relative to the total weight of the composition.
[0318] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of non-volatile oil is at least 10% relative to the total weight of the composition.
[0319] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of non-volatile oil is between 5% and 25% relative to the total weight of the composition.
[0320] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of non-volatile oil is between 5 and 15% relative to the total weight of the composition.
[0321] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of non-volatile oil is between 10% and 25% relative to the total weight of the composition.
[0322] In the present invention, the term "glossy oil" means an oil having an intrinsic glossiness. "Glossy oils" are, for example, frequently used in cosmetics to ensure a "shiny effect" when applying the cosmetic composition to keratinous materials.
[0323] In the context of the present application, a lipstick composition is characterized in that it comprises at least one glossy oil.
[0324] In one embodiment, the inventive lipstick composition is characterized in that the glossy oil is a non-volatile oil.
[0325] In one embodiment, the inventive lipstick composition comprises a glossy oil comprising: Polymers such as polybutylenes, in particular POLYBUTENE® marketed or produced by the company ATAMAN, hydrogenated polyisobutylenes, polydecenes and hydrogenated polydecenes, polyfarnesenes, vinylpyrrolidone copolymers, in particular vinylpyrrolidone / eicosene copolymers, such as ANTARON V 220® marketed or produced by the company ISP, Esters such as esters of linear fatty acids having a total of more than 30 carbon atoms, aromatic esters, esters of fatty alcohols or branched fatty acids having 20 to 30 carbon atoms, The dilinoleic acid copolymer is characterized in that it is selected from the group including ester copolymers such as dimer dilinoleyl dimer dilinoleate (registered trademark LUSPLAN DD-DA5 and registered trademark LUSPLAN DD-DA7), dilinoleic acid / butanediol copolymer (registered trademark VISCOPLAST 14436H), dilinoleic acid / propanediol copolymer, and mixtures thereof.
[0326] Preferably, the glossy oils used in the context of the present invention are of vegetable origin.
[0327] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is at least 2% relative to the total weight of the composition.
[0328] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is at least 5% relative to the total weight of the composition.
[0329] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is between 2 and 20% relative to the total weight of the composition.
[0330] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is between 5 and 15% relative to the total weight of the composition.
[0331] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is between 10% and 20% relative to the total weight of the composition.
[0332] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is between 2 and 10% relative to the total weight of the composition.
[0333] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of glossy oil is between 5% and 10% relative to the total weight of the composition.
[0334] These ingredients play an important role in the formulation as they help balance the lipstick formulation in terms of creaminess during use.
[0335] In the present invention, the term "pasty fatty substance" means a lipophilic fatty compound having a liquid portion and a solid portion at room temperature (25° C.) and having a reversible solid / liquid state change.
[0336] In other words, the melting point of the pasty fatty substance is below 25°C.
[0337] In the context of the present application, a composition for a lipstick is characterized in that it further comprises at least one pasty fatty substance.
[0338] In one embodiment, the inventive composition for a lipstick is characterised in that the pasty fatty substance is selected from the group comprising synthetic pasty fatty substances, animal pasty fatty substances, vegetable pasty fatty substances and mixtures thereof.
[0339] In one embodiment, the inventive composition for a lipstick is characterized in that the synthetic pasty fatty substance is selected from the group comprising polyol ethers, petrolatum, vinyl polymers, pentaerythritol esters, polyesters and mixtures thereof.
[0340] In one embodiment, the inventive composition for a lipstick is characterized in that the animal pasty fatty substance is lanolin.
[0341] Preferably, the inventive composition for a lipstick is characterised in that the pasty fatty substance is a vegetable pasty fatty substance.
[0342] In one embodiment, the inventive composition for a lipstick is characterized in that the vegetable pasty fatty substance is selected from the group comprising vegetable butters (avocado butter, shea butter), fatty acid triglycerides, and their derivatives and mixtures thereof.
[0343] In one embodiment, the inventive composition for a lipstick is characterized in that the percentage by weight of the pasty fatty substance is between 0 and 20% relative to the total weight of the composition.
[0344] In one embodiment, the inventive composition for a lipstick is characterized in that the percentage by weight of the pasty fatty substance is between 0 and 15% relative to the total weight of the composition.
[0345] In one embodiment, the inventive composition for a lipstick is characterized in that the percentage by weight of the pasty fatty substance is between 0 and 10% relative to the total weight of the composition.
[0346] In one embodiment, the inventive composition for a lipstick is characterized in that the percentage by weight of the pasty fatty substance is between 0 and 5% relative to the total weight of the composition.
[0347] In the present invention, the term gelling agent refers to compounds that constitute an excellent textural agent for balancing the formulation in terms of smoothness and adhesion.
[0348] Additionally, certain glossy oils such as the compounds sold under the names VISCOPLAST® 14436H, LUSPLAN® DD-DA5 and LUSPLAN® DD-DA7 may also be used as gelling agents.
[0349] In one embodiment, the lipstick composition of the invention is characterized in that it comprises at least one gelling agent.
[0350] In one embodiment, the inventive lipstick composition is characterized in that the gelling agent is selected from the group comprising organic gelling agents, mineral gelling agents, polymeric gelling agents and mixtures thereof.
[0351] Preferably, the lipstick composition of the invention is characterized in that the gelling agent is of vegetable origin.
[0352] In one embodiment, the lipstick composition of the present invention is characterized in that the organogelling agent is selected from the group comprising ethyl cellulose and its derivatives, rosin-derived resins, dextrin esters, fatty acid esters and mixtures thereof.
[0353] In one embodiment, the inventive lipstick composition is characterized in that the mineral gelling agent is selected from the group comprising hectorite and its derivatives, pyrogenic silica and its derivatives, and mixtures thereof.
[0354] In one embodiment, the inventive lipstick composition is characterized in that the polymeric gelling agent is selected from the group comprising organopolysiloxanes and derivatives thereof, dimethicone copolymers and derivatives thereof, copolymer mixtures in isododecane such as polystyrene / polyisoprene copolymers, polystyrene / polybutadiene copolymers, polystyrene / copoly(ethylene-propylene) copolymers, polystyrene / copoly(ethylene-butylene) copolymers, ethylene / propylene copolymers or butylene / ethylene / styrene, polyesters and derivatives thereof, polyamide resins and mixtures thereof.
[0355] In one embodiment, the lipstick composition of the invention is characterized in that the gelling agent is dextrin palmitate or one of its derivatives.
[0356] In one embodiment, the inventive lipstick composition is characterized in that the gelling agent is a modified hectorite of the type BENTONE GEL ISD V® or one of its equivalents.
[0357] In one embodiment, the inventive lipstick composition is characterized in that the gelling agent is a modified hectorite of the VEGELIGHT BENTONE SILK SB type or one of its equivalents.
[0358] In one embodiment, the inventive lipstick composition is characterized in that the gelling agent is a modified hectorite of the disteardimonium hectorite type associated with triethyl citrate and a mixture of volatile alkanes as defined in the present invention.
[0359] In one embodiment, the lipstick composition of the invention is characterized in that the gelling agent is a mixture of copolymers in isododecane, such as ethylene / propylene copolymers.
[0360] In one embodiment, the inventive lipstick composition is characterized in that the gelling agent is a combination of dimethicone polymer and a mixture of alkanes sold under the name VEGELIGHT SILK SI 118, registered trademark of BIOSYNTHIS, or its equivalent.
[0361] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is at least 5% relative to the total weight of the composition.
[0362] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is at least 15% relative to the total weight of the composition.
[0363] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 5 and 30% relative to the total weight of the composition.
[0364] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 5% and 20% relative to the total weight of the composition.
[0365] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 15% and 30% relative to the total weight of the composition.
[0366] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 5 and 15% relative to the total weight of the composition.
[0367] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 15% and 25% relative to the total weight of the composition.
[0368] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of gelling agent is between 20% and 30% relative to the total weight of the composition.
[0369] In the present invention, the term film-forming polymer means, within the framework of the present invention, a polymer capable of forming a microscopically continuous film, in particular on the lips.
[0370] In one embodiment, the inventive lipstick composition is characterized by comprising at least one film-forming polymer.
[0371] In one embodiment, the inventive lipstick composition is characterized in that the film-forming polymer is selected from the group comprising acrylic polymers, polyurethanes, polyesters, polyamides, silicone polymers.
[0372] In one embodiment, the lipstick composition of the invention is characterized in that the film-forming polymer is trimethylsiloxysilicate, commercially available under the name TMS 803.
[0373] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the film-forming polymer is at least 1% relative to the total weight of the composition.
[0374] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the film-forming polymer is at least 10% relative to the total weight of the composition.
[0375] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of film-forming polymer is between 1 and 25% relative to the total weight of the composition.
[0376] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of film-forming polymer is between 10% and 25% relative to the total weight of the composition.
[0377] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of film-forming polymer is between 1 and 10% relative to the total weight of the composition.
[0378] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of film-forming polymer is between 10% and 20% relative to the total weight of the composition.
[0379] Waxes play an important role in the design of lipsticks since they influence certain essential criteria such as the texture, appearance and / or stickiness of the product.
[0380] In the present invention, the term "wax" refers to a lipophilic compound that has a reversible solid / liquid state change, in other words a compound that is solid at room temperature (25°C) and has a melting point above 30°C.
[0381] Preferably, in the present invention, the wax used has a melting point of 50° C. or higher.
[0382] In one embodiment, the lipstick composition of the invention is characterized in that it comprises at least one wax.
[0383] In one embodiment, the inventive lipstick composition is characterized in that it comprises at least one wax selected from the group consisting of synthetic waxes, mineral waxes, vegetable waxes and animal waxes.
[0384] In one embodiment, the inventive lipstick composition is characterized in that the wax is a mineral or synthetic wax selected from the group comprising microcrystalline waxes, paraffin waxes, ozokerite, polyethylene waxes, silicone waxes and fluorinated waxes.
[0385] "Vegetable wax" refers to a composition comprising at least one partially or fully hydrogenated oil. These vegetable waxes may comprise esters of fatty acids and fatty alcohols, and may further comprise fatty acids, free fatty alcohols, long chain linear alkanes, and / or unsaponifiable matter.
[0386] Preferably, within the meaning of the present invention, the waxes used are vegetable waxes.
[0387] In one embodiment, the inventive lipstick composition is characterized in that the wax is a vegetable or animal wax selected from the group comprising lanolin wax, rice bran wax, carnauba wax, candelilla wax, berry wax, beeswax, sunflower wax, mimosa wax, jojoba wax, castor wax, and olive wax.
[0388] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is at least 2% relative to the total weight of the composition.
[0389] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is at least 5% relative to the total weight of the composition.
[0390] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is between 2 and 20% relative to the total weight of the composition.
[0391] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is between 5 and 15% relative to the total weight of the composition.
[0392] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is between 2 and 10% relative to the total weight of the composition.
[0393] In one embodiment, the inventive lipstick composition is characterized in that the percentage by weight of wax is between 5 and 10% relative to the total weight of the composition.
[0394] In one embodiment, the inventive lipstick composition is characterized by further comprising at least one antioxidant.
[0395] In one embodiment, the inventive lipstick composition is characterized in that the antioxidant is selected from the group comprising phenolic antioxidants such as BHA, BHT, DBPC, the gallate type, so-called natural antioxidants such as dl-α-tocopherol or its derivatives, plant extracts, dibasic lipopeptides such as lysine or arginine, and mixtures thereof.
[0396] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidant is at least 0.01% relative to the total weight of the composition.
[0397] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidant is at least 0.1% relative to the total weight of the composition.
[0398] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidants is between 0.01% and 2% relative to the total weight of the composition.
[0399] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidants is between 0.01% and 1% relative to the total weight of the composition.
[0400] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidants is between 0.1 and 1% relative to the total weight of the composition.
[0401] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of antioxidants is between 0.01% and 0.1% relative to the total weight of the composition.
[0402] This part is essential for coloring. The pigments used can be synthetic, mineral or plant-based. The dosage of these is also delicate.
[0403] In one embodiment, the lipstick composition of the invention is characterized in that it comprises at least one pigment moiety.
[0404] In one embodiment, the inventive lipstick composition is characterized in that the color moiety is selected from the group comprising water-soluble dyes, liposoluble dyes, pigments, nacres, glitters and mixtures thereof.
[0405] In one embodiment, the inventive lipstick composition is characterized in that the pigment portion comprises a pigment selected from the group consisting of organic pigments such as fixed or precipitated pigments, mineral pigments such as titanium dioxide or iron oxide, sodium thiosulfate aluminosilicate, chromium oxide, bismuth oxychloride, copper phthalocyanine, metal-free phthalocyanines, chlorinated copper phthalocyanines.
[0406] Thus, the percentage of titanium oxide determines the coverage and opacity of the film.
[0407] The color and chrominance are determined by the use of precipitated lacquers or pigments.
[0408] By way of example, other types of pigments can be used, such as titanic micas, borosilicates and their derivatives, mica, silica, and the like.
[0409] Mineral pigments are used to give subtle variations in shade, while compounds such as bismuth oxychloride can be used to give specific effects (metallic, shimmery effects, etc.).
[0410] In one embodiment, the inventive lipstick composition is characterized in that the pigment portion comprises a synthetic dye selected from the group including CI100006, CI12010, CI12085, CI12120, CI12370, CI12420, CI12490, CI14270, CI14700, CI14720, CI14815, CI15525, CI15580, CI15620, CI15630, CI15850, CI15865, CI15880, CI15980, CI15985, CI1035, CI16255, CI16290, CI17200, CI18050, CI45100, CI45220, CI45380, CI45430.
[0411] In one embodiment, the inventive lipstick composition is characterized in that the pigment portion comprises a dye derived from a plant selected from fruit and / or plant extracts containing dyes.
[0412] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is at least 0.01% relative to the total weight of the composition.
[0413] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is at least 1% relative to the total weight of the composition.
[0414] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is at least 5% relative to the total weight of the composition.
[0415] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 0.01% and 20% relative to the total weight of the composition.
[0416] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 1% and 20% relative to the total weight of the composition.
[0417] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 5% and 20% relative to the total weight of the composition.
[0418] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 1% and 15% relative to the total weight of the composition.
[0419] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 5% and 15% relative to the total weight of the composition.
[0420] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 0.01% and 5% relative to the total weight of the composition.
[0421] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 5% and 10% relative to the total weight of the composition.
[0422] In one embodiment, the inventive lipstick composition is characterized in that the weight percentage of the pigment portion is between 10% and 15% relative to the total weight of the composition.
[0423] In one embodiment, the lipstick composition of the invention has a carbon-14( 14 C) characterized by having a naturalness index of 80% or more.
[0424] In one embodiment, the lipstick composition of the invention has a carbon-14( 14 C) characterized by having a naturalness index of 85% or more.
[0425] In one embodiment, the lipstick composition of the invention has a carbon-14( 14 C) characterized by having a naturalness index of 90% or more.
[0426] In one embodiment, the lipstick composition of the invention has a carbon-14( 14 C) characterized by having a naturalness index of 95% or more.
[0427] In one embodiment, the inventive lipstick composition is characterized in that at least 50% by weight of the ingredients are of natural origin, relative to the total weight of the composition.
[0428] By "naturally occurring" ingredients is meant ingredients obtained directly from the earth, soil, water, air, or plants, optionally through one or more physical processes such as grinding, refining, distilling, purifying, filtering, and the like.
[0429] By "naturally occurring" ingredient is meant an ingredient that has been subjected to one or more chemical or industrial processes resulting in modifications that do not affect the essential properties of the ingredient and / or an ingredient that comprises primarily naturally occurring constituents with or without such modifications.
[0430] Non-limiting examples of further chemical or industrial treatments resulting in modifications that do not affect the essential properties of the natural compound include treatments approved by certification bodies such as Ecocert or COSMOS.
[0431] In the present invention, the term "synthetic or artificial ingredients" refers to ingredients that do not meet the above definition of natural or naturally occurring ingredients.
[0432] In one embodiment, the inventive lipstick composition is characterized in that at least 75% by weight of the ingredients, relative to the total weight of the composition, are of natural origin.
[0433] In one embodiment, the inventive lipstick composition is characterized in that at least 90% by weight of the ingredients are of natural origin, relative to the total weight of the composition.
[0434] In one embodiment, the inventive lipstick composition is characterized in that 50% by weight of the ingredients, relative to the total weight of the composition, are of natural origin.
[0435] In one embodiment, the inventive lipstick composition is characterized in that 75% by weight of the ingredients are of natural origin, relative to the total weight of the composition.
[0436] In one embodiment, the inventive lipstick composition is characterized in that 90% by weight of the ingredients are of natural origin, relative to the total weight of the composition.
[0437] In one embodiment, the inventive lipstick composition is characterized in that after application of the composition to the lips, the drying time at 20° C. is 7 minutes or less.
[0438] In one embodiment, the lipstick composition of the invention is characterized in that the drying time of the composition on the lips is 6 minutes or less.
[0439] In one embodiment, the lipstick composition of the invention is characterized in that after application of the composition to the lips, the drying time at 20° C. is 5 minutes 30 seconds or less.
[0440] In one embodiment, the inventive lipstick composition is characterized in that upon application of the composition to the lips, the drying time at 20° C. is 6 minutes.
[0441] In one embodiment, the lipstick composition of the invention is characterized in that the drying time at 20° C. after application of the composition to the lips is 5 minutes 30 seconds.
[0442] In one embodiment, the inventive lipstick composition is characterized by a drying time of 4 minutes 30 seconds at 20° C. after application of the composition to the lips.
[0443] The lipstick compositions of the invention are characterized by their bright and very intense color.
[0444] Pleasant properties in terms of color and chroma reflect good dispersion of the pigment on the lips.
[0445] In addition to their color properties, the lipstick compositions of the invention have satisfactory coverage and hold as well as satisfactory leveling effect.
[0446] In one embodiment, the inventive lipstick composition is characterized in that it is in the form of a solid, compacted, cast, pasty or liquid composition.
[0447] In a preferred embodiment, the inventive lipstick composition is characterized in that it is in the form of a solid, compacted or cast composition.
[0448] In one embodiment, the inventive lipstick composition is characterized in that it is in the form of a solid composition, for example in the form of a stick.
[0449] In one embodiment, the lipstick composition of the invention is characterized in the form of a "non-transfer" lipstick, also known as a "long-wear" lipstick.
[0450] In one embodiment, the lipstick composition of the invention is characterized in that it is in the form of a lip gloss, also known as lip "gloss."
[0451] Furthermore, the lipstick compositions of the invention can be prepared by methods known and commonly used in the cosmetics art.
[0452] The invention also relates to a method for preparing the lipstick composition of the present invention, comprising the steps of: a) Guerbet synthesis from isoamyl alcohol (CAS 123-51-3) to produce the C10 Guerbet alcohol, 2-isopropyl-5-methylhexan-1-ol (CAS 2051-33-4). b) mixing the product produced in step 1) with at least one greater than C10 bio-based alcohol to produce a bio-based alcohol mixture. c) The bio-derived alcohol mixture produced in step 2) is dehydrated and then hydrogenated to obtain a volatile alkane mixture consisting of 2,3,6-trimethylheptane (CAS 4032-93-3) and alkanes above C10. d) adding no alkanes or one or more alkanes to the volatile alkane mixture. e) combining the resulting mixture of volatile alkanes with at least one compound selected from non-volatile oils, glossy oils, pasty fatty substances, gelling agents, film-forming polymers, waxes, pigments, dyes and mixtures thereof.
[0453] More particularly, the invention also relates to a method for preparing the lipstick composition of the present invention, comprising the steps of: a) Guerbet synthesis from isoamyl alcohol (CAS 123-51-3) to produce the C10 Guerbet alcohol, 2-isopropyl-5-methylhexan-1-ol (CAS 2051-33-4). b) Mixing the product produced in step 1) with bio-based n-dodecanol to produce a bio-based alcohol mixture. c) The mixture of bio-derived alcohols produced in step 2) is dehydrated and then hydrogenated to obtain a mixture of volatile alkanes consisting of 2,3,6-trimethylheptane (CAS 4032-93-3) and n-dodecane (CAS 112-40-3). d) adding no alkanes or one or more alkanes to the volatile alkane mixture. e) combining the resulting mixture of volatile alkanes with at least one compound selected from non-volatile oils, glossy oils, pasty fatty substances, gelling agents, film-forming polymers, waxes, pigments, dyes and mixtures thereof.
[0454] In one embodiment, the method for preparing a lipstick composition as defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out from a plant, bacterial or animal source.
[0455] In one embodiment, the method for preparing a lipstick composition as defined according to the present invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out using a base selected from the group consisting of KOH, NaOH, NaOCH3, KOCH3.
[0456] In one embodiment, the method for preparing a lipstick composition as defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out using a catalyst selected from the group comprising at least one metal from group VIII, such as copper derivatives, such as PriCat Cu 50 / 8, nickel, palladium, platinum, their derivatives and mixtures thereof.
[0457] In one embodiment, the method for preparing a lipstick composition as defined according to the present invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out at a temperature between 150°C and 300°C.
[0458] In one embodiment, the method for preparing a lipstick composition as defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out at a pressure between 1 bar and 15 bar.
[0459] In one embodiment, the method for preparing a lipstick composition as defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, is carried out for a period of between 10 hours and 24 hours.
[0460] In one embodiment, the method for preparing a lipstick composition defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, provides a mass percentage of C10 branched alcohol of 75% or more.
[0461] In one embodiment, the method for preparing a lipstick composition defined according to the invention is characterized in that step 1 of the method, i.e. the Guerbet synthesis, provides a mass percentage of C10 branched alcohol of 90% or more.
[0462] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that step 1 of the process further comprises a purification step by distillation to remove impurities.
[0463] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises the step 1 of the method, i.e., the step of preparing a lipstick composition having a carbon-14 ( 14 C) is characterized in that a C10 branched chain alcohol having a percentage of 75% or more can be obtained.
[0464] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises the step 1 of the method, i.e., the step of preparing a lipstick composition having a carbon-14 ( 14 C) is characterized in that a C10 branched chain alcohol having a percentage of 90% or more can be obtained.
[0465] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises the step 1 of the method, i.e., the step of preparing a lipstick composition having a carbon-14 ( 14 C) is characterized in that the percentage of C10 branched chain alcohol is 100%.
[0466] In one embodiment, the method for preparing a lipstick composition as defined according to the present invention is characterized in that in step 2 of the method, at least one bio-based C12 or higher alcohol selected from the group consisting of n-dodecanol, n-tetradecanol and mixtures thereof is added.
[0467] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that step 3 of the process consists of a dehydration step followed by a hydrogenation step.
[0468] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the dehydration step of step 3 of the process is carried out using a catalyst selected from the group consisting of alumina and its derivatives.
[0469] In one embodiment, the method for preparing a lipstick composition as defined according to the present invention is characterized in that the dehydration step of step 3 of the method is carried out using a catalytic support selected from the group consisting of silica wool and its derivatives.
[0470] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the dehydration step of process step 3 is carried out at a temperature between 200°C and 380°C.
[0471] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the dehydration step of step 3 of the process is carried out under an inert atmosphere.
[0472] In one embodiment, the process for preparing a lipstick composition as defined in accordance with the present invention is characterized in that the dehydration step in step 3 of the process results in 95% or greater conversion to C10 branched alkenes.
[0473] In one embodiment, the process for preparing a lipstick composition as defined in accordance with the present invention is characterized in that the dehydration step in step 3 of the process results in a conversion of 99% or more to C10 branched alkenes.
[0474] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the trimethylheptane obtained in step 3 of the process, the hydrogenation step, is 2,3,6-trimethylheptane.
[0475] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step of process step 3 is carried out using a catalyst comprising at least one metal of group VIII, such as palladium, nickel, platinum, derivatives thereof and mixtures thereof.
[0476] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step of step 3 of the process is carried out using a catalytic support selected from the group consisting of silica wool and its derivatives.
[0477] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step in step 3 of the process is carried out at a temperature between 100°C and 250°C.
[0478] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step in step 3 of the process is carried out under an inert atmosphere.
[0479] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step in process step 3 is preceded by an inerting step of the reactor with 15 bar of nitrogen.
[0480] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the reactor is subjected to three inerting steps with 5 bar of nitrogen prior to the hydrogenation step in step 3 of the process.
[0481] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step of process step 3 is carried out by adding between 2 and 15 bar of hydrogen to the reactor.
[0482] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step of process step 3 is carried out by adding 5 bar of hydrogen to the reactor.
[0483] In one embodiment, the process for the preparation of a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step of process step 3 is carried out by adding 10 bar of hydrogen to the reactor.
[0484] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step in step 3 of the process is carried out for a period of between 3 and 12 hours.
[0485] In one embodiment, the process for preparing a lipstick composition as defined according to the present invention is characterized in that the hydrogenation step in step 3 of the process is carried out for 5 hours.
[0486] In one embodiment, the process for preparing a lipstick composition as defined in accordance with the present invention is characterized in that the hydrogenation step in step 3 of the process results in a conversion of 95% or more to 2,3,6-trimethylheptane.
[0487] In one embodiment, the process for preparing a lipstick composition as defined in accordance with the present invention is characterized in that the hydrogenation step in step 3 of the process results in a conversion of 99% or more to 2,3,6-trimethylheptane.
[0488] In one embodiment, the method for preparing a lipstick composition as defined according to the present invention is characterized in that step 3 of the method results in a mixture of volatile alkanes as defined according to the present invention.
[0489] Surprisingly, the process for the preparation of a lipstick composition as defined according to the invention is characterized in that the process makes it possible to produce a deodorized or odorless volatile alkane mixture.
[0490] This organoleptic property lends itself to use in cosmetic compositions.
[0491] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention is characterized in that step 4 of the method makes it possible to obtain a mixture of volatile alkanes as defined in accordance with the present invention.
[0492] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises, by step 4 of the method, obtaining a carbon-14( 14 C) is characterized in that a volatile alkane mixture having a percentage of 75% or more can be obtained.
[0493] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises, by step 4 of the method, obtaining a carbon-14( 14 C) is characterized in that a volatile alkane mixture having a percentage of 90% or more can be obtained.
[0494] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention comprises, by step 4 of the method, obtaining a carbon-14( 14 C) is characterized in that a volatile alkane mixture having a percentage of 100% can be obtained.
[0495] In one embodiment, the method for preparing a lipstick composition as defined in accordance with the present invention is characterized in that step 5 of the method allows obtaining a lipstick composition comprising a volatile alkane mixture as defined in accordance with the present invention. Working Example
[0496] The following examples are provided to illustrate the invention. These examples are presented for illustrative purposes only and are not intended to limit the invention in any way.
[0497] The percentages given in the table below are percentages by weight. Example 1: Lipstick formulation preparation protocol
[0498] To prepare the reference lipstick (Example 2), the prior art lipstick (Example 4) and the inventive lipsticks (Examples 6 and 7), AEROSIL was dispersed in a mixture of volatile alkanes to form the first phase of the lipstick formulation.
[0499] Once the first phase was dispersed, the second phase was weighed simultaneously in a separate vessel. The same operation was carried out with the third phase, and then the second and third phases were mixed under magnetic stirring.
[0500] The mixture of phases 2 and 3 was then placed on a hot plate and allowed to sit until the RHEOPEARL KL2 was completely dispersed.The dispersed phase 1 was then added to the mixture of phases 2 and 3.
[0501] Finally, phase 4 was heated separately on a hot plate until the wax was completely melted, after which phase 4 was cooled in a 40° C. cold water bath and added to the dispersed mixture of phases 1, 2 and 3.
[0502] Lipstick formulations of Examples 2, 4, 6 and 7 were obtained. Example 2: Composition and properties of reference lipsticks Drying time on lips of benchmark lipstick formulations [Table 1]
[0503] After application to the lips of a user panel, a test to check for dryness using a nonwoven tissue from tO to tx and a nonwoven tissue marking test were performed every 30 seconds to measure the dry time at 20° C. The formulation was considered dry when there was no transfer.
[0504] The reference lipstick obtained according to the protocol of Example 1 had a drying time on the lips of 6 minutes.
[0505] This drying time was satisfactory for a lipstick or lip gloss formulation. Application characteristics of benchmark lipstick formulations on the lips To validate this study, lipstick formulations were tested on a panel of users.
[0506] In a food situation, the benchmark lipstick held up well even though the center had disappeared (though the outline remained).
[0507] In terms of other application properties, a user panel survey showed that the benchmark lipstick had no transfer and provided good adhesion and coverage.
[0508] However, it was a little sticky. Finally, the benchmark lipstick had a satisfactory staying power of 5 hours. Example 3: Stability of the Reference Lipstick Composition of Example 2 [Table 2]
[0509] The table in Example 3a above shows the stability of the benchmark lipstick formulation as a function of temperature. The stability of this test was assessed at various time points by visual observation by an operator.
[0510] The benchmark lipstick formulation was stable at low temperatures, showing slight instability from 72 hours at 50°C.
[0511] However, this slight instability at 50° C. did not increase during the 1 and 2 week observations. [Table 3]
[0512] The table in Example 3b above shows the stability of benchmark lipstick formulations to centrifugation by visual observation by an operator.
[0513] From the results shown in Table 3b, it can be inferred that the lipstick formulation is stable to centrifugation for the speed and time of the tests performed.
[0514] From the stability results of Examples 3a and 3b, it can be inferred that the benchmark lipstick formulation exhibits sufficient stability even though slight instability may be observed during storage at elevated temperatures (50° C.). Example 4: Composition and properties of lipsticks containing volatile alkane mixtures of the prior art [Table 4]
[0515] In the composition of Example 4 of the lipstick containing a mixture of volatile alkanes of the prior art patent application EP 3 773 432 A1, the isododecane (CAS 13475-82-6) contained in the first phase of the reference formulation of Example 2 was replaced by a mixture of volatile alkanes consisting of 30% n-decane (CAS 124-18-5) and 70% n-dodecane (CAS 112-40-3). Drying time for Example 4
[0516] The lipstick of Example 4 obtained by the protocol of Example 1 had a drying time on the lips of 14 minutes.
[0517] Dry time on the lips was not satisfactory for the lipstick formulations of the present invention. Application characteristics of the formulation of Example 4
[0518] To validate this study, prior art lipstick formulations were tested on a user panel.
[0519] Thus, during meals, the prior art lipstick lasted well even though the center had worn off. However, the outline remained.
[0520] As for other application properties of the prior art lipsticks, a user panel survey showed that the prior art lipsticks were non-transferable, had average adhesion and adequate coverage.
[0521] A comparison of the prior art lipstick formulations with the reference formulation was performed on samples and evaluated by the same user panel. The prior art lipsticks were shown to have lower staying power than the reference lipsticks. However, the study also showed that the prior art lipsticks were more difficult to apply because they were more runny. Furthermore, properties such as drying time, adhesion and coverage were less satisfactory than those of the reference lipstick formulation. Example 5: Stability of the prior art lipstick composition of Example 4 [Table 5]
[0522] The table in Example 5a above shows the stability of prior art lipstick formulations as a function of temperature. Stability in this test was assessed at various time points by visual observation by an operator.
[0523] The prior art formulation was stable at low temperatures and showed slight instability from 72 hours at 50° C. However, this slight instability at 50° C. did not increase during the 1 and 2 week observations. [Table 6]
[0524] The table in Example 5b above shows the stability of prior art lipstick formulations to centrifugation by visual observation by an operator.
[0525] From the results shown in Table 5b, it can be inferred that the lipstick formulation is stable to centrifugation for the speed and time of the tests performed.
[0526] From the stability results of Examples 5a and 5b, it can be inferred that prior art lipstick formulations exhibit sufficient stability even though slight instability is observed during storage at high temperatures (50° C.). Example 6: Composition and Properties of Lipsticks of the Invention [Table 7]
[0527] In the composition of Example 6 of the inventive lipstick, the isododecane (CAS 13475-82-6) contained in the first phase of the reference formulation (Example 2) was replaced with a volatile alkane mixture as defined in the present invention, which consists of 30% 2,3,6-trimethylheptane (CAS 4032-93-3) and 70% n-dodecane (CAS 112-40-3).
[0528] Drying time of the formulation of Example 6
[0529] The lipstick of Example 6 obtained by the protocol of Example 1 had a drying time on the lips of 7 minutes.
[0530] Dry time on the lips was satisfactory for a lipstick or lip gloss formulation.
[0531] Application characteristics of the formulation of Example 6
[0532] To validate this study, lipstick formulations were tested on a panel of users.
[0533] The lipstick of Example 6 provided satisfactory staying power for 5 hours.
[0534] Furthermore, in a meal situation, the lipstick of Example 6 lasted well even though the center had worn off, however the outline remained.
[0535] In terms of other application properties, a user panel survey showed that it had no color transfer, good adhesion and good coverage.
[0536] A comparison of the inventive lipstick formulation with the benchmark formulation was performed on samples and evaluated by the same panel of users. The inventive lipstick formulation was shown to have stronger color development, specifically, it was brighter and therefore less dull than the benchmark formulation.
[0537] Comparison photographs taken during the study show the difference in light intensity. In terms of application, a user panel study showed that the inventive lipstick had similar leveling effect, coverage and staying power as the benchmark lipstick. Example 7: Stability of the lipstick composition (of the present invention) of Example 6 [Table 8]
[0538] The table in Example 7a above summarizes the stability data for lipstick formulations of the present invention as a function of temperature, which was assessed at various time points by visual observation by an operator.
[0539] The formulation of the present invention, unlike the benchmark formulation of Example 2, was stable during storage at both 4°C and 50°C. [Table 9]
[0540] The table in Example 7b above summarizes data regarding the stability of lipstick formulations of the present invention during centrifugation as assessed by visual observation by an operator.
[0541] From the results shown in Table 7b, it can be inferred that this lipstick formulation is stable to centrifugation at the speeds and times of testing performed. From the stability results of Examples 7a and 7b, it can be inferred that the lipstick formulations of the present invention have satisfactory or even better stability at elevated temperatures than the benchmark lipstick formulation of Example 2. Example 8: Composition and properties of inventive lipstick [Table 10]
[0542] In the composition of inventive lipstick Example 8, the isododecane (CAS 13475-82-6) contained in the first and second phases of the reference formulation (Example 2) was replaced with a mixture of volatile alkanes as defined in the present invention.
[0543] In this example, the mixture of volatile alkanes contained in the first phase consists of 35% 2,3,6-trimethylheptane (CAS 4032-93-3) and 65% n-dodecane (CAS 112-40-3).
[0544] In this example, a Bentone gel was prepared containing disteardimonium hectorite and triethyl citrate in the second phase using a volatile alkane mixture of the invention in place of isododecane.
[0545] In this example, the Bentone gel contains a mixture of volatile alkanes consisting of 15% 2,3,6-trimethylheptane (CAS 4032-93-3) and 85% n-dodecane (CAS 112-40-3). Drying time of formulation of Example 8
[0546] The lipstick of Example 8 obtained by the protocol of Example 1 had a drying time on the lips of 5 minutes.
[0547] Dry time on the lips was satisfactory for a lipstick or lip gloss formulation. Application characteristics of the formulation of Example 8
[0548] To validate this study, lipstick formulations were tested on a panel of users.
[0549] The lipstick of Example 8 provided satisfactory staying power for 6 hours.
[0550] Additionally, in a meal situation, the lipstick of Example 8 had good staying power.
[0551] In terms of other application properties, a user panel survey showed that it had no color transfer, good adhesion and good coverage.
[0552] A comparison of the inventive lipstick formulation with the benchmark formulation was performed on samples and evaluated by the same panel of users. The inventive lipstick formulation was shown to have stronger color development, specifically, it was brighter and therefore less dull than the benchmark formulation.
[0553] Comparison photographs taken during the study show the difference in light intensity.
[0554] In terms of application, a user panel study showed that the inventive lipstick had similar leveling effect, coverage and staying power as the benchmark lipstick. Example 9: Lip gloss composition of the present invention
[0555] The procedure for formulating a lip gloss composition according to the present invention is as follows.
[0556] The pigments of the first phase were mixed with octyldodecanol to obtain a paste. Next, the Benton gel obtained by combining the volatile alkane mixture of the present invention, stearalkonium bentonite, and triethyl citrate was added. Finally, the entire first phase was dispersed.
[0557] In this embodiment, the mixture of volatile alkanes, as defined herein, constitutes 80% or more by weight based on the total weight of the Bentone gel composition.
[0558] In the second step, the second phase of the composition of Example 10 was placed in a water bath at a temperature of 80° C. until the wax was in a liquid state.
[0559] Phase 2 was cooled to 40° C. and mixed with phase 1. [Table 11]
[0560] For the purposes of this example, the volatile alkane mixture consists of 20% 2,3,6-trimethylheptane (CAS 4032-93-3) and 80% n-dodecane (CAS 112-40-3).
[0561] The lip gloss composition of Example 9 had a viscosity of 2293 cSt at 40°C.
[0562] The lip gloss composition of Example 9 had a satisfactory shine effect. Example 10: Composition of an inventive lipstick with a high naturalness index
[0563] To prepare the inventive lipsticks of Examples 10 and 11, the first phase was dispersed with a Turax.
[0564] Once phase 1 was dispersed, phase 2 was weighed into a separate container and shaken separately with the Turax. This second phase was then added to the dispersed phase 1 and mixed with the Turax. Phase 3 was added after weighing. Phase 1, phase 2 and phase 3 were mixed with the Turax.
[0565] Phases 4 and 5 were weighed into a sealed glass container and heated with moderate stirring until the wax was completely melted. Phases 4 and 5 were cooled to 40° C. and then mixed with the other phases 1, 2 and 3.
[0566] Finally, phase 6 was weighed and added to the other phases (1, 2, 3, 4, and 5). The mixture was stirred with a Turax. The formulation was then cooled to room temperature.
[0567] The composition of an inventive lipstick formulation having a high naturalness index is as follows: [Table 12]
[0568] In the composition of Example 10, the inventive lipstick is comprised of 35% 2,3,6-trimethylheptane (CAS 4032-93-3), 15% isododecane (CAS 13475-82-6) and 50% n-dodecane (CAS 112-40-3). Contains a mixture of volatile alkanes.
[0569] Interestingly, when the mass percentage of isododecane (CAS 13475-82-6) relative to the total mass of the volatile mixture of alkanes of the invention is 15%, the inventive lipstick of Example 10 has a naturalness index of 85% according to the ASTM D6866 standard. Example 11: Composition of an inventive lipstick with a high naturalness index
[0570] This formulation was prepared following a similar protocol as shown in the previous example.
[0571] The composition of the inventive lipstick having a high naturalness index is as follows: [Table 13]
[0572] In the composition of Example 11, the inventive lipstick is composed of 35% 2,3,6-trimethylheptane (CAS 4032-93-3), 15% isododecane (CAS 13475-82-6) and 50% n-dodecane (CAS 112-40-3). Contains a mixture of volatile alkanes.
[0573] In this example, the trimethylsiloxysilicate component in the first phase of Example 11 was replaced by adjusting the bio-based component of the formulation.
[0574] Interestingly, when the mass percentage of isododecane (CAS 13475-82-6) relative to the total mass of the volatile alkane mixture of the invention is 15%, the inventive lipstick has a naturalness index of 90% according to the ASTM D6866 standard. Example 12: Biodegradability of the Volatile Alkane Mixtures Used in the Lipstick Composition of the Invention
[0575] The biodegradability of the volatile alkane mixture used in the lipstick composition of the invention was measured according to OECD method 301F. For comparison, the decomposition of isododecane (CAS 13475-82-6) was also measured by the same method. [Table 14]
[0576] The OECD 301F method allows the ease of biodegradation of a substance to be characterized by a manometric respirometry test.
[0577] The mixture of volatile alkanes tested was 58% biodegradable according to the OECD 301F method, whereas isododecane (CAS 13475-82-6) was not biodegradable according to this method.
Claims
1. A lipstick composition comprising: containing a mixture of volatile alkanes, The volatile alkane mixture is a) 20 to 100 mass% of fraction A containing at least one branched alkane having 10 or less carbon atoms; b) 0 to 80% by mass of fraction B containing at least one linear or branched alkane having more than 10 carbon atoms; The volatile alkane mixture has a flash point of less than 55°C as measured in accordance with ASTM D93 standard and accounts for 2% by mass or more of the total mass of the composition. Lipstick composition.
2. It is characterized by being a non-transferring or low-transferring lipstick. The lipstick composition according to claim 1 .
3. comprising the volatile alkane mixture, The volatile alkane mixture is a) 20 to 100% by mass of fraction A containing at least one branched alkane having 10 or less carbon atoms; b) containing 0 to 80% by mass of fraction B containing at least one linear or branched alkane having more than 10 carbon atoms; The volatile alkane mixture has a flash point of less than 55°C as measured according to the ASTM D93 standard and accounts for 25% by weight or more of the total weight of the composition. The non-transfer lipstick composition according to claim 1 .
4. The volatile alkane mixture has a carbon-14 ( 14 C) is 85% or more, The lipstick composition according to claim 1 .
5. The volatile alkane mixture is obtained from a raw material of plant, bacterial or animal origin. The lipstick composition according to claim 1 .
6. The volatile alkane mixture is characterized in that it has a biodegradability of at least 50% according to the OECD 301F method. The lipstick composition according to claim 1 .
7. the at least one branched-chain alkane having 10 or less carbon atoms in the volatile alkane mixture is selected from the group consisting of branched-chain alkanes having 9 carbon atoms, branched-chain alkanes having 10 carbon atoms, or a mixture thereof; The lipstick composition according to claim 1 .
8. the at least one branched alkane having 10 or less carbon atoms in the volatile alkane mixture is a branched alkane having 10 carbon atoms; The lipstick composition according to claim 1 .
9. The volatile alkane mixture is characterized in that at least one branched alkane having 10 or less carbon atoms is 2,3,6-trimethylheptane (CAS 4032-93-3). The lipstick composition according to claim 1 .
10. the mass percentage of the A fraction of the volatile alkane mixture is between 51% and 100% relative to the total mass of the volatile alkane mixture; The lipstick composition according to claim 1 .
11. In the volatile alkane mixture, the at least one linear or branched alkane having more than 10 carbon atoms is selected from the group consisting of alkanes having 11 carbon atoms, 12 carbon atoms, 13 carbon atoms, 14 carbon atoms, 15 carbon atoms, and 16 carbon atoms, or mixtures thereof. The lipstick composition according to claim 1 .
12. The volatile alkane mixture is characterized in that at least one linear or branched alkane having more than 10 carbon atoms is n-dodecane (CAS 112-40-3). The lipstick composition according to claim 1 .
13. the mass percentage of at least one linear or branched alkane having more than 10 carbon atoms in the volatile alkane mixture is between 0% and 50% relative to the total mass of the volatile alkane mixture; The lipstick composition according to claim 1 .
14. The volatile alkane mixture contains 2,3,6-trimethylheptane (CAS 4032-93-3) and n-dodecane (CAS 112-40-3). The lipstick composition according to claim 1 .
15. At least one non-volatile oil having a flash point of 110°C or higher as measured according to ASTM D93 standard is included. The lipstick composition according to claim 1 .
16. At least 85% by weight of the composition's total weight is derived from natural products. The lipstick composition according to claim 1 .
17. The drying time after application of the composition to the lips at 20°C is 5 minutes 30 seconds or less. The lipstick composition according to claim 1 .
18. a. Producing a C10 Guerbet alcohol, 2-isopropyl-5-methyl-1-hexanol (CAS 2051-33-4), from isoamyl alcohol (CAS 123-51-3) by Guerbet synthesis; b. combining the product produced in step 1 with at least one bio-derived alcohol having more than 10 carbon atoms to produce a bio-derived alcohol mixture; c. Dehydrating the bio-derived alcohol mixture produced in step 2 and then hydrogenating it to obtain a volatile alkane mixture consisting of 2,3,6-trimethylheptane (CAS 4032-93-3) and alkanes having more than 10 carbon atoms; d. adding no volatile alkane or one or more volatile alkanes to the volatile alkane mixture; e) combining the volatile alkane mixture with at least one compound selected from the group consisting of non-volatile oils, glossy oils, pasty fatty substances, gelling agents, film-forming polymers, waxes, pigments, dyes, and mixtures thereof; 10. A method for preparing the lipstick composition of claim 1, comprising: